And Rare Earth (i.e., Elements With Atomic Number 39 Or 57-71) Patents (Class 501/78)
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Patent number: 12122712Abstract: A glass comprising greater or equal to 30.0 mol % SiO2, the glass being free of iron, lead, antimony ant tantalum oxides, and having a refractive index nd greater than or equal to 1.75 and a linear thermal expansion coefficient ?20-300, in the temperature range 20-300° C., that is less than or equal to about 65×10?7 K?1.Type: GrantFiled: November 13, 2019Date of Patent: October 22, 2024Assignee: CORNING INCORPORATEDInventors: Jian Luo, Alexander I Priven
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Patent number: 12006257Abstract: An enamel composition, a method for preparing an enamel composition, and a cooking appliance are provided. The enamel composition may include 15 to 50 wt % of silicon dioxide (SiO2); 1 to 10 wt % of boron oxide (B2O3); 10 to 20 wt % of at least one of lithium oxide (Li2O), sodium oxide (Na2O), or potassium oxide (K2O); 1 to 5 wt % of sodium fluoride (NaF); 1 to 10 wt % of zinc oxide (ZnO); and 20 to 50 wt % of at least one of titanium dioxide (TiO2), molybdenum oxide (MoO3), bismuth oxide (Bi2O3), cerium dioxide (CeO2), manganese dioxide (MnO2), or Iron oxide (Fe2O3), which provides an enamel composition with a reduced cleaning time, and facilitates cleaning without soaking in water.Type: GrantFiled: February 20, 2020Date of Patent: June 11, 2024Assignee: LG ELECTRONICS INC.Inventors: Suyeon Choi, Young Seok Kim
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Patent number: 11958769Abstract: Disclosed are optical glass, a glass preform or an optical element made therefrom and an optical instrument. The optical glass is calculated by a mass percentage content relative to a total mass of glass converted by an oxide, and the optical glass includes: B2O3: 5˜25%, La2O3: 25?45%, Gd2O3: 15?35%, Y2O3: 0?10%, Yb2O3: 0˜10%, Nb2O5: 2?15%, SiO2: 0.5˜15%, ZrO2: 1?15%, TiO2: 0.5˜10% and WO3: 0˜10%, a weight ratio of Nb2O5 to TiO2, i.e., Nb2O5/TiO2, is 2.17?8.5, and Ta2O5 is not contained.Type: GrantFiled: August 17, 2018Date of Patent: April 16, 2024Assignee: CDGM GLASS CO., LTD.Inventor: Wei Sun
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Patent number: 11667561Abstract: A composition for a glass material comprising, on an oxide basis: one or more network formers chosen from the group of silicon dioxide (SiO2) and phosphorous pentoxide (P2O5); one or more alkali metal oxides chose from the group consisting of lithium oxide (Li2O) and sodium oxide (Na2O); 8 to 15 percent by weight zirconium oxide (ZrO2); and one transition metal oxide consisting of 9 to 45 percent by weight niobium pentoxide (Nb2O5). In an embodiment, the composition consists of: 35 to 60 percent by weight silicon dioxide (SiO2); 9.25 to 15.0 percent by weight lithium oxide (Li2O); 0.5 to 2 percent by weight sodium oxide (Na2O); 8 to 15 percent by weight zirconium oxide (ZrO2); 0 to 3.5 percent by weight phosphorous pentoxide (P2O5); and 9 to 45 percent by weight niobium pentoxide (Nb2O5). In an embodiment, the glass material is a light guide for an augmented reality device.Type: GrantFiled: November 8, 2019Date of Patent: June 6, 2023Assignee: CORNING INCORPORATEDInventors: Qiang Fu, Paulo Jorge Gaspar Marques
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Patent number: 11434164Abstract: Al2O3— rich compositions with desirable hardness and crack resistance for various functional applications. Also disclosed is a method of manufacturing the composition into various dimensions and shapes under a temperature much lower than in conventional methods.Type: GrantFiled: October 9, 2018Date of Patent: September 6, 2022Assignee: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEYInventor: Ashutosh Goel
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Patent number: 11203548Abstract: An optical glass includes, in terms of mol % of cations, a total amount of La3+, Y3+, and Gd3+ components falling within a range of from 5% to 65% and a total amount of Zr4+, Hf4+, and Ta5+ components failing within a range of from 5% to 65%, and a relationship expressed in Expression (1) given below is satisfied. (La3++Y3++Gd3+)×(Zr4+ Hf4++Ta3+)?400(%)2.Type: GrantFiled: March 19, 2020Date of Patent: December 21, 2021Assignee: NIKON CORPORATIONInventors: Kohei Yoshimoto, Motoi Ueda, Hiroshi Yamamoto, Tatsunori Kawashima
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Patent number: 10752543Abstract: A glass substrate includes at least one selected from the group consisting of Li, Na, K, Mg, Ca, Sr, Ba and Zn as a reaction factor component, and includes a surface depletion layer at a surface side of the glass substrate. A total molar concentration (mol/cm3) of the reaction factor component in the surface depletion layer is decreased relative to an inside of the glass substrate. A total depletion amount (mol/cm2) of the reaction factor component in the surface depletion layer is 1.00×10?8 or more. The glass substrate has a refractive index (nd) of 1.68 or more.Type: GrantFiled: November 26, 2019Date of Patent: August 25, 2020Assignee: AGC INC.Inventors: Tomohiro Shibuya, Shin-ichi Amma, Yosuke Amino, Daisuke Kobayashi, Michinori Suehara
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Patent number: 10578910Abstract: The present disclosure relates to a substrate for a display panel, a display panel and a display device. The substrate according to the present disclosure comprises a base doped with upconverting ions capable of converting an infrared light beam into a visible light beam, the base is made of microcrystalline glass, and the microcrystalline glass comprises at least one of matrix materials NaYF4 and NaGdF4. The substrate according to the present disclosure may be used for any of a color filter substrate, an array substrate and a coverplate of the display panel.Type: GrantFiled: March 29, 2018Date of Patent: March 3, 2020Assignees: BOE TECHNOLOGY GROUP CO., LTD., HEFEI BOE OPTOELECTRONICS TECHNOLOGY CO., LTD.Inventors: Liqing Liao, Zhifu Dong, Dong Wang, Hongmin Li
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Patent number: 10494294Abstract: The invention provides a high-refraction low-dispersion optical glass with refractive index of 1.76-1.80 and Abbe number of 47-51. The optical glass, comprising the following components by weight percentage: 0-3% of SiO2; 25-40% of B2O3; 20-40% of La2O3; 12-25% of Gd2O3; 6.5-15% of ZrO2; greater than 10% but less than or equal to 20% of ZnO; 0-5% of Ta2O5; 0-5% of Nb2O5; 0-10% of Li2O; less than 0.45 of (Ta2O5+Nb2O5)/(ZnO+Li2O); 0-10% of Y2O3; and below 625° C. of glass transition temperature Tg. With reasonable component ratio, the high-refraction low-dispersion optical glass favorable to precision molding with excellent transmittance can be easily enabled while realizing the required optical constant of the glass of the present invention.Type: GrantFiled: November 22, 2016Date of Patent: December 3, 2019Assignee: CDGM Glass Co., Ltd.Inventor: Bo Kuang
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Patent number: 10487004Abstract: The invention provides a high-refraction low-dispersion optical glass with refractive index of 1.76-1.80 and Abbe number of 47-51. The glass has an excellent transmittance when the content of Ta2O5 in glass component is reduced. The optical glass comprises the following components by molar percentage: 40-65% of B2O3; 6-21% of La2O3; 1-15% of Gd2O3; greater than 6.5% but less than or equal to 15% of ZrO2; ad 10-28% of ZnO. According to the present invention, the transmittance of glass becomes excellent without introducing SnO2; the product cost is optimized by reducing the content of Ta2O5; with reasonable component ratio, the high-refraction low-dispersion optical glass in favor of precision molding and with excellent transmittance, as well as the glass preform and optical element made of the optical glass can be easily enabled while the required optical constant of the glass is realized.Type: GrantFiled: November 22, 2016Date of Patent: November 26, 2019Assignee: CDGM Glass Co., Ltd.Inventor: Bo Kuang
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Patent number: 10343947Abstract: The invention provides a high-refraction low-dispersion optical glass with low material cost, refractive index of 1.77-1.85, and Abbe number of 40-48, wherein the following components by weight percentage: 4-20% of SiO2, 8-24% of B2O3, 20-40% of La2O3, 11-30% of Gd2O3, 0-15% of Y2O3, 0-8% of TiO2, 0-8% of Ta2O5, more than 0 but less than or equal to 8% of Nb2O5, less than 1 of Ta2O5/Nb2O5, more than 0 but less than or equal to 15% of ZrO2, and 11-30% of ZnO. The invention reduces the content of Ta2O5 and optimizes the cost of raw materials; through rational composition design, the optical glass of the invention is conducive to precision molding while achieving the required optical constant, with excellent chemical stability. A glass preform and an optical element made of the optical glass are also disclosed.Type: GrantFiled: August 14, 2017Date of Patent: July 9, 2019Assignee: CDGM GLASS CO., LTDInventor: Bo Kuang
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Patent number: 10287205Abstract: An optical glass with high refractive index and low dispersion, having refractive index nd of 1.78-1.95, Abbe number ?d of 32-50, and contains no GeO2, so it is not easily devitrified. An optical glass, represented by cation %, including: 1-20% of Si4+; 25-60% of B3+; 10-40% of La3+; 0-15% of Y3+; 0-20% of Nb5+; 0-15% of Ti4+; 0-10% of Ta5+; 0-5% of W6+; 0-15% of Zr4+; 0-10% of Zn2+; 0-10% of Bi3+. An optical glass with excellent transmittance, an optical glass preform and an optical element formed by the above optical glass. The optical element made by the above optical glass and the above glass preform or optical element blank, such as lens, can be used for optical systems.Type: GrantFiled: April 6, 2016Date of Patent: May 14, 2019Assignee: CDGM GLASS CO., LTD.Inventor: Wei Sun
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Patent number: 9487432Abstract: A high refractivity and high dispersion optical glass with light transmissivity and good devitrification resistance. The high refractivity and high dispersion optical glass, including: 1 wt % to 13 wt % of SiO2, 6 wt % to 15 wt % of B2O3, 5 wt % to 22 wt % of TiO2, 35 wt % to 60 wt % of La2O3, 1 wt % to 15 wt % of Gd2O3, 2 wt % to 10 wt % of ZrO2, 1 wt % to 15 wt % of Nb2O5, 0.5 wt % to 8 wt % of ZnO, 0 to 8 wt % of WO3 and 0 to 10 wt % of Y2O3, with Ta2O5 and GeO2 excluded. The optical glass has degree of pigmentation and light transmissivity due to no pigmenting Bi2O3, and has low cost due to no valuable oxides such as Ta2O5 and GeO2. The optical glass has devitrification resistance with a refractive index of 1.95-2.07 and Abbe number of 25-35.Type: GrantFiled: January 20, 2015Date of Patent: November 8, 2016Assignee: CDGM GLASS CO., LTDInventor: Bo Kuang
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Patent number: 9405123Abstract: To provide an optical system that lengthens the lifetime of a fiber, an optical system 13 guides light beams emitted from a plurality of light emitting parts ep into a single optical fiber 12, the plurality of light emitting parts ep are arranged to be aligned along a first direction d1, and the optical system 13 allows the light beams emitted from the plurality of light emitting parts ep to have different light collection centers which are offset from each other at least in a second direction d2.Type: GrantFiled: June 11, 2015Date of Patent: August 2, 2016Assignee: Sumita Optical Glass, Inc.Inventors: Hiroki Watanabe, Kazuya Aida
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Patent number: 9255028Abstract: The optical glass is described that may be an oxide glass including, denoted as cation %, a total of 5 to 60% of B3+ and Si4+ (with 5 to 50% of B3+), a total of equal to or higher than 5% of Zn2+ and Mg2+, a total of 10 to 50% of La3+, Gd3+, Y3+, and Yb3+, and a total of 6 to 45% of Ti4+, Nb5+, Ta5+, W6+, and Bi3+ (a total content of Ti4+ and Ta5+ being higher than 0% and a content of W6+ being higher than 5%).Type: GrantFiled: April 24, 2013Date of Patent: February 9, 2016Assignee: HOYA CORPORATIONInventors: Tomoaki Negishi, Yasuhiro Fujiwara
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Patent number: 9206074Abstract: Provided is a high refractive index glass, comprising, as a glass composition in terms of mass %, 0.1 to 60% of SiO2+Al2O3+B2O3, having a mass ratio (BaO+La2O3+Nb2O5+TiO2+ZrO2)/(SiO2+Al2O3+B2O3) of 0.1 to 50, amass ratio (MgO+CaO+SrO+BaO)/(BaO+La2O3+Nb2O5+TiO2+ZrO2) of 0 to 10, and a mass ratio (TiO2+ZrO2)/(BaO+La2O3+Nb2O5) of 0.001 to 40, and having a refractive index nd of 1.55 to 2.3.Type: GrantFiled: December 7, 2011Date of Patent: December 8, 2015Assignee: NIPPON ELECTRIC GLASS CO., LTD.Inventors: Tomoki Yanase, Takashi Murata
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Patent number: 9169152Abstract: The invention provides an optical glass, which includes 6 wt % to 10 wt % of B2O3; 10 wt % to 15% of B2O3 and SiO2, wherein the content of B2O3 is more than that of SiO2; 27 wt % to 32 wt % of La2O3; 0 wt % to 5 wt % of Gd2O3, Y2O3 and Yb2O3, wherein the content of Gd2O3 is 0 wt % to 3 wt %; more than 19 wt % but less than 25 wt % of TiO2; more than 8 wt % but less than 15 wt % of Nb2O5; 0.5 wt % to 5 wt % of ZnO; 0 wt % to 2 wt % of WO3; 2 wt % to 10 wt % of ZrO2; more than 10 wt % but less than 15 wt % of BaO; 0 wt % to 5 wt % of CaO, SrO and MgO, wherein the content of SrO is 0 wt % to 3 wt %; and 0 wt % to 0.1 wt % of Sb2O3.Type: GrantFiled: September 18, 2012Date of Patent: October 27, 2015Assignee: CDGM GLASS CO., LTD.Inventor: Bo Kuang
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Patent number: 9039942Abstract: A lead-free conductive paste composition contains a source of an electrically conductive metal, a fusible material, an optional additive, and an organic vehicle. An article such as a high-efficiency photovoltaic cell is formed by a process of deposition of the lead-free paste composition on a semiconductor substrate (e.g., by screen printing) and firing the paste to remove the organic vehicle and sinter the metal and fusible material.Type: GrantFiled: December 21, 2011Date of Patent: May 26, 2015Assignee: E I DU PONT DE NEMOURS AND COMPANYInventors: Carmine Torardi, Paul Douglas Vernooy
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Publication number: 20150119228Abstract: The optical glass is described that may be an oxide glass including, denoted as cation %, a total of 5 to 60% of B3+ and Si4+ (with 5 to 50% of B3+), a total of equal to or higher than 5% of Zn2+ and Mg2+, a total of 10 to 50% of La3+, Gd3+, Y3+, and Yb3+, and a total of 6 to 45% of Ti4+, Nb5+, Ta5+, W6+, and Bi3+ (a total content of Ti4+ and Ta5+ being higher than 0% and a content of W6+ being higher than 5%).Type: ApplicationFiled: April 24, 2013Publication date: April 30, 2015Applicant: HOYA CORPORATIONInventors: Tomoaki Negishi, Yasuhiro Fujiwara
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Patent number: 9018116Abstract: A highly refractive and highly transparent optical glass is provided. The use of such a glass, optical elements and processes for producing the glass or the optical elements are also provided.Type: GrantFiled: June 6, 2013Date of Patent: April 28, 2015Assignee: Schott AGInventors: Bianca Schreder, Karl Mennemann, Ute Woelfel, Volker Dietrich
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Patent number: 9006120Abstract: The invention relates to glasses for use in solid laser applications, particularly short-pulsed, high peak power laser applications. In particular, the invention relates to a method for broadening the emission bandwidth of rare earth ions used as lasing ions in solid laser glass mediums, especially phosphate-based glass compositions, using Nd and Yb as co-dopants. The invention further relates to a laser system using a Nd-doped and Yb-doped phosphate laser glass, and a method of generating a laser beam pulse using such a laser system.Type: GrantFiled: November 25, 2013Date of Patent: April 14, 2015Assignee: Schott CorporationInventors: Simi George, Nathan Carlie, Sally Pucilowski, Joseph Hayden
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Publication number: 20150094198Abstract: An optical glass is provided. The optical glass is suitable for use in optical elements including lenses, prisms, light guide rods, arrays, optical fibres, gradient components and optical windows in the fields of imaging, sensor technology, microscopy, medical technology, digital projection, telecommunication, optical messaging technology/information transmission, optics/illumination in the automotive sector, for solar technology, photolithography, steppers, excimer lasers, wafers, computer chips and/or integrated circuits and electronic instruments which contain such circuits and chips. The optical glass contains the components La2O3, B2O3, GeO2, HfO2 and In2O3 and in which the following components are present in the following proportions, in % by weight on an oxide basis: SiO2O2 1-8; Sb2O3 0-<2; SiO2+B2O3 1-<20; and SiO2+B2O3+GeO2+HfO2+In2O3 15-25.Type: ApplicationFiled: September 30, 2014Publication date: April 2, 2015Inventors: Silke Wolff, Simone Monika Ritter
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Patent number: 8956988Abstract: An optical Glass characterized by comprising, denoted as molar percentages: B2O5—5 to 45 percent; SiO2—0 to 6 percent (excluding 6 percent); Li2O, Na2O, K2O in total—0 to 3 percent; ZnO—10 to 40 percent; La2O3. 5 to 30 percent; Gd2O3—1 to 20 percent; and ZrO2, TaO2, TiO2, Nb2O5, WO3, and Bi2O3 in total—2.5 to 20 percent. The cation ratio of the Ti4+ content relative to the total content of Zr4+, Ta5+, Ti4+, Nb5+, W6+, and Bi3+ is 0.30 or lower; in that the temperature Tp at which a viscosity of 107.2 dPa·s is exhibited is 706° C. or lower. The refractive index nd and the Abbé number v(nu)d satisfy all of the following relations (I) to (IV): 34.0?vd<40 (I); nd?1.87 (II); nd?2.245?0.01×vd (III) and nd?2.28?0.01×vd (IV).Type: GrantFiled: November 21, 2012Date of Patent: February 17, 2015Assignee: Hoya CorporationInventor: Yasuhiro Fujiwara
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Publication number: 20150045204Abstract: An aspect of the present invention relates to optical glass, which is oxide glass, having a refractive index nd ranging from 1.95 to 2.50 and an Abbé number ?d ranging from 18 to 40, including essential components in the form of Si4+, B3+, La3+, Ti4+, Nb5+, and at least one from among Gd3+, Y3+, and Yb3+, including, denoted as cation %, 1 to 30% of Si4+, 1 to 50% of B3+, wherein a total of Si4+ and B3+ ranges from 5 to 55%, a total of 11 to 70% of La3+, Gd3+, Y3+, and Yb3+, with 10 to 50% of La3+, a total of 23 to 70% of Ti4+, Nb5+, Ta5+, and W6+, with equal to or greater than 1% of Nb5+ and greater than 22% of Ti4+.Type: ApplicationFiled: February 25, 2013Publication date: February 12, 2015Applicant: HOYA CORPORATIONInventors: Tomoaki Negishi, Toshiyuki Nishikawa
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Patent number: 8951926Abstract: The invention provides an optical glass for press molding which can satisfy all of the following requirements: (1) it contains no environmentally undesirable components; (2) it can easily achieve a low glass transition point; (3) it has a high refractive index and high dispersion; (4) it can easily provide a glass having an excellent visible light transmittance; and (5) it has excellent resistance to devitrification during preparation of a preform. The optical glass for press molding has a refractive index nd of 1.925 or more, an Abbe's number ?d of 10 to 30, and a glass composition, in % by mass, of 20 to 80% Bi2O3, 10 to 30% B2O3, and 0 to 5.5% GeO2 and is substantially free of lead component, arsenic component, and F component.Type: GrantFiled: October 17, 2013Date of Patent: February 10, 2015Assignee: Nippon Electric Glass Co., Ltd.Inventors: Takahiro Matano, Fumio Sato, Yoko Usui
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Publication number: 20150031525Abstract: An optical glass is oxide glass wherein Si4++B3+ ranges from 10-60 cation %, La3++Gd3++Y3++Yb3+ ranges from 25-70 cation %, Ti4++Nb5++W6++Bi3+ ranges from 10-20 cation %, Li+ content ranges from 0-5.0 cation %, Ge content is lower than 5.0 mass % as quantity of GeO2 based on oxides, no Pb included, a cation ratio, Si4+/B3+, is equal or lower than 0.70, a cation ratio, (La3++Gd3++Y3++Yb3+)/(Ti4++Nb5++W6++Bi3+), ranges from 1.90-7.00, a cation ratio, Y3+/(La3++Gd3++Y3++Yb3+), is equal or lower than 0.180, and Nb5+ is an essential component, with Ti4+/Nb5+ being equal or lower than 4.00, with nd of higher than 1.920 and equal or lower than 2.000, vd ranging from 28.0-34.0, and yield point higher than 645° C., and a deviation ?Pg,F from normal line of partial dispersion ratio Pg,F being equal or lower than 0.0005.Type: ApplicationFiled: March 15, 2013Publication date: January 29, 2015Applicant: HOYA CORPORATIONInventor: Tomoaki Negishi
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Patent number: 8927445Abstract: The invention includes a composition for sealing agent, generally in the form of glass frit, lead-free, comprising by weight over the total weight of the composition: 30-80% Bi2O3; 2-10% ZnO; 2-10% B2O3; 0-5% Na2O; 1-10% SiO2; 1-8% Al2O3; 0-7% BaO; and 0-8% MgO. The composition for sealing agent as defined above can be added with a filler in a quantity up to 20% by weight over the total weight of the resulting mixture. The invention also includes a sealing paste containing the composition for sealing agent, the optional filler, an organic binder and optionally an organic solvent. The invention also includes methods for producing and using the composition for sealing agent and the sealing paste, as well as an electronic device sealed with the sealing paste.Type: GrantFiled: September 16, 2010Date of Patent: January 6, 2015Assignee: Daunia Solar Cell S.r.l.Inventor: Alessio Antonini
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Patent number: 8921247Abstract: The present invention relates to an optical glass including, in terms of mass % on the basis of oxides, B2O3: 10% to 20%, SiO2: 0.5% to 12%, ZnO: 5% to 19%, Ta2O5: 3% to 17%, Li2O: 0.2% to 3%, ZrO2: 0.6% to 4.9%, WO3: 6.1% to 20%, La2O3: 32.5% to 50%, and Y2O3: 0.2% or more and less than 1.5%, in which a mass fraction (La2O3/Y2O3) of a content of La2O3 to a content of Y2O3 in terms of mass % is 40 or higher, and the optical glass has optical constants of a refractive index nd of 1.83 to 1.88 and an Abbe's number ?d of 39 to 42.Type: GrantFiled: July 22, 2013Date of Patent: December 30, 2014Assignee: Asahi Glass Company, LimitedInventor: Noriyoshi Kayaba
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Patent number: 8883664Abstract: An aspect of the present invention relates to optical glass, which is oxide glass comprising various cationic components in prescribed amounts without Pb, with a refractive index nd of 1.750 to 1.850, an Abbé number ?d of 29.0 to 40.0, and a glass transition temperature of less than 630° C.Type: GrantFiled: April 18, 2012Date of Patent: November 11, 2014Assignee: Hoya CorporationInventor: Tomoaki Negishi
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Patent number: 8859444Abstract: A high-refractivity low-dispersion optical glass of which the Ta2O5 content is suppressed is provided, the optical glass comprising, by mass %, 1 to 30% of B2O3, 0.1 to 20% of SiO2, 55 to 75% of a total of La2O3, Gd2O3, Y2O3 and Yb2O3, the content of La2O3 being 15 to 55%, the mass ratio of the content of Gd2O3 to the total content of La2O3, Gd2O3, Y2O3 and Yb2O3, Gd2O3/La2O3+Gd2O3+Y2O3+Yb2O3), being 0.17 to 0.65, 0 to 13% of Ta2O5 (exclusive of 13%), and 0 to 25% of a total of Nb2O5, TiO2, WO3 and ZrO2, the content of Nb2O5 being less than 10%, and having a refractive index nd of 1.83 to 1.92 and an Abbe's number ?d of 36 to 45.Type: GrantFiled: September 29, 2010Date of Patent: October 14, 2014Assignee: Hoya CorporationInventors: Kosuke Yamaguchi, Yoichi Hachitani
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Patent number: 8852745Abstract: An aspect of the present invention relates to an optical glass, which comprises, denoted as weight percent, 2 to 37 percent of SiO2, 0 to 25 percent of B2O3, 0 to 10 percent of GeO2, 18 to 55 percent of a combined content of Li2O, Na2O, K2O, CaO, SrO, and BaO, and 27 to 55 percent of a combined content of TiO2, Nb2O5, and WO3, wherein the weight ratio of SiO2 content relative to a combined content of SiO2 and B2O3 ranges from 0.1 to 1, a weight ratio of the Li2O content to a combined content of Li2O, Na2O, K2O, CaO, SrO, and BaO ranges from 0 to 0.4, and a weight ratio of TiO2 content relative to a combined content of TiO2, Nb2O5, and WO3 ranges from 0.35 to 1, with a refractive index nd of 1.860 to 1.990 and an Abbé number ?d of 21 to 29.Type: GrantFiled: October 12, 2012Date of Patent: October 7, 2014Assignee: Hoya CorporationInventors: Kosuke Yamaguchi, Naomi Matsumoto
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Publication number: 20140287906Abstract: The invention provides an optical glass, which includes 6 wt % to 10 wt % of B2O3; 10 wt % to 15% of B2O3 and SiO2, wherein the content of B2O3 is more than that of SiO2; 27 wt % to 32 wt % of La2O3; 0 wt % to 5 wt % of Gd2O3, Y2O3 and Yb2O3, wherein the content of Gd2O3 is 0 wt % to 3 wt %; more than 19 wt % but less than 25 wt % of TiO2; more than 8 wt % but less than 15 wt % of Nb2O5; 0.5 wt % to 5 wt % of ZnO; 0 wt % to 2 wt % of WO3; 2 wt % to 10 wt % of ZrO2; more than 10 wt % but less than 15 wt % of BaO; 0 wt % to 5 wt % of CaO, SrO and MgO, wherein the content of SrO is 0 wt % to 3 wt %; and 0 wt % to 0.1 wt % of Sb2O3.Type: ApplicationFiled: September 18, 2012Publication date: September 25, 2014Applicant: CDGM GLASS CO., LTDInventor: Bo Kuang
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Publication number: 20140284577Abstract: Thin glasses having high refractive index (nd), a layer composite assembly made from these thin glasses, a method for the production of the thin glasses, and the uses of the thin glasses are provided. The thin glasses are processed in an in line manufacturing process and have the optical properties of a classical optical glass. The thin glasses are highly transparent, crystallization-resistant, chemically resistant and highly refractive. The viscosity/temperature behavior of the thin glasses is adjusted to the manufacturing process via in line flat glass methods.Type: ApplicationFiled: March 18, 2014Publication date: September 25, 2014Applicant: Schott AGInventors: Karl Mennemann, Uwe Kolberg, Holger Wegener, Monika Gierke, Ute Woelfel, Joerg Fechner
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Patent number: 8835334Abstract: Provided is an optical glass which can satisfy all of the following requirements: (1) it contains no environmentally undesirable components; (2) it can easily achieve a low glass transition point; (3) it has a high refractive index and high dispersion; (4) it can easily provide a glass having a superior visible light transmittance; and (5) it has superior resistance to devitrification during preparation of a preform. The optical glass has a refractive index nd of 2.0 or more, an Abbe's number ?d of 20 or less, a glass transition point of 450° C. or below, and a glass composition, in % by mass, of 70 to 90% Bi2O2, 4 to 29.9% B2O2, 0.1 to 10% Li2O+Na2O+K2O, and 0 to 2.5% SiO2+Al2O2 and is substantially free of lead component, arsenic component, F component, TeO2, and GeO2.Type: GrantFiled: September 12, 2011Date of Patent: September 16, 2014Assignee: Nippon Electric Glass Co., Ltd.Inventors: Takahiro Matano, Fumio Sato
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Patent number: 8835336Abstract: Provided with the following glass components: 8 to 19.5% B2O3, 4.5 to 9% SiO2, 0 to 10% GeO2, 7 to 12.5% BaO, 0 to 14% MgO, 0 to 0.4% Li2O, 15 to 34% La2O3, 3.5 to 10% Y2O3, 8 to 13.5% TiO2, 0 to 7% ZrO2, 0 to 11% Nb2O5, and 1 to 9% WO3 by weight, wherein B2O3/SiO2 is at least 1.0, La2O3+Y2O3+ZrO2+Nb2O5+WO3 is no more than 54%, and B2O3+SiO2+GeO2+BaO+MgO+Li2O+La2O3+Y2O3+TiO2+ZrO2+Nb2O5+WO3 is at least 98%.Type: GrantFiled: September 15, 2010Date of Patent: September 16, 2014Assignee: Konica Minolta Advanced Layers, Inc.Inventor: Yoshihito Taguchi
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Patent number: 8835337Abstract: An optical glass, comprising, denoted as cation percentages: a content of Si4+ and B3+ (35 to 55); a combined content of La3+, Gd3+, and Y3+ (30 to 55), wherein Gd3+ is 5 to 20%; a content of Ti4+, Nb5+, Ta5+ and W6+ (7 to 20); Zr4+ (2 to 8); and Zn2+ (0 to 10); wherein a cation ratio of Zn2+ to Gd3+ is 0 to 0.80; a cation ratio of Gd3+ to Ti4+, Nb5+, Ta5+, and W6+ combined is 0.65 to 2.00; a cation ratio of Ta5+ to Ti4+, Nb5+, Ta5+, and W6+ combined is 0 to 0.30; a cation ratio of Ti4+ to Ti4+, Nb5+, Ta5+, and W6+ combined is 0.30 to 0.90; and a refractive index nd is 1.890 to 1.950, and an Abbé number ?d of equal to or lower than 39.0, the Abbé number ?d satisfying a relation of ?d?(2.334?nd)/0.012 relative to nd.Type: GrantFiled: November 2, 2012Date of Patent: September 16, 2014Assignee: Hoya CorporationInventor: Tomoaki Negishi
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Publication number: 20140256531Abstract: An optical glass including B3+, La3+ and Nb5+ as cationic components constituting the glass, wherein the optical glass satisfies the following expressions represented in cation percentages: 10 cat. %?B3+?50 cat. %; 40 cat. %?La3+?65 cat. %; 0 cat. %?Nb5+?40 cat. %; 80 cat. %?(total amount of B3++La3++Nb5+)?100 cat. %; and 0 cat. %?Si4+?10 cat. %; 0 cat. %?Ge4+?5 cat. %; 0 cat. %?Mg2+?5 cat. %; 0 cat. %?Ba2+?10 cat. %; 0 cat. %?Ca2+?10 cat. %; 0 cat. %?Sr2+?10 cat. %; 0 cat. %?Zn2+?20 cat. %; 0 cat. %?W6+?5 cat. %; 0 cat. %?Zr4+?5 cat. %; 0 cat. %?Ti4+?5 cat. %; 0 cat. %?Bi3+?5 cat. %; 0 cat. %?Ta5+?10 cat. %; 0 cat. %?(total amount of Y3++Gd3+)?20 cat. %; and 0 cat. %?(total amount of Yb3++Lu3+)?10 cat. %.Type: ApplicationFiled: February 26, 2014Publication date: September 11, 2014Applicants: CANON KABUSHIKI KAISHA, THE UNIVERSITY OF TOKYOInventors: Michio Endo, Shingo Eguchi, Hiroyuki Inoue, Atsunobu Masuno
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Publication number: 20140221191Abstract: The present invention is aimed to provide a cost-effective optical glass with refractive index of 1.74-1.80 and Abbe number of 47-51 but containing no Gd2O3 and an optical element made hereof. The optical glass contains the following components according to percentage by weight: more than 2.7% but less than 10% of SiO2, 20-31% of B2O3, 38-49% of La2O3, more than 12% but less than 20% of Y2O3, more than 1% but less than 4% of ZnO, more than 0.5% but less than 3% of Nb2O5, wherein the content of ZnO is more than that of Nb2O5, 0-5% of Ta2O5, 0-5% of RO, wherein the RO is one or more of CaO, SrO and MgO, and content of ZrO2 is more than 6.7% but less than 15%. The present invention is a lanthanum borate glass containing no Gd2O3. A stable glass can be obtained by adjusting the content of La2O3, B2O3 and Y2O3.Type: ApplicationFiled: September 6, 2012Publication date: August 7, 2014Applicant: CDGM GLASS CO., LTD.Inventor: Wei Sun
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Patent number: 8785339Abstract: An optical glass comprising, by mass %, 12 to 40% of SiO2, 15% or more but less than 42% of Nb2O5, 2% or more but less than 18% of TiO2, (provided that Nb2O5/TiO2 is over 0.6), 0.1 to 20% of Li2O, 0.1 to 15% of Na2O, and 0.1 to 25% of K2O, and having an Abbe's number ?d of 20 to 30, a ?Pg,F of 0.016 or less and a liquidus temperature of 1,200° C. or lower.Type: GrantFiled: June 4, 2013Date of Patent: July 22, 2014Assignee: Hoya CorporationInventors: Xuelu Zou, Yoshio Nojima, Hiroki Takazawa
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Patent number: 8778821Abstract: The invention discloses an optical glass and an optical element. The optical glass comprises 0.1 wt % -8 wt % of SiO2, 20 wt % -32 wt % of B2O3, 20 wt % -35 wt % of La2O3, 15 wt % -30 wt % of Gd2O3, 1-6 wt % of Ta2O5, 1 wt % -15 wt % of ZnO, and 0.1 wt % -2 wt % of Li2O. The optical glass claimed in the invention has a refractive index of 1.75-1.8, an Abbe number of 45-52, a transformation temperature of less than 610° C., and a wavelength of less than 390 nm at 80% transmittance. Thus the claimed optical glass meets the requirements for a modern imaging device.Type: GrantFiled: October 2, 2012Date of Patent: July 15, 2014Assignee: CDGM Glass Co., Ltd.Inventor: Wei Sun
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Publication number: 20140171287Abstract: There is provided an optical glass with a high refractive index and a low dispersion having a refractive index (nd) of not less than 1.75 and an Abbe's number (?d) of not less than 35 where the image formation characteristic is hardly affected by changes in temperature of the using environment. SiO2, B2O3 and La2O3 are contained as essential components and the ratio of the constituting components are adjusted whereby an optical glass in which a product of ? and ? where ? is an average linear expansion coefficient at ?30 to +70° C. and ? is an optical elasticity constant at the wavelength of 546.1 nm is not more than 130×10?12° C.?1×nm×cm?1×Pa?1 is able to be achieved.Type: ApplicationFiled: February 19, 2014Publication date: June 19, 2014Applicant: OHARA INC.Inventors: Junko Suzuki, Michiko Ogino, Masahiro Onozawa
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Patent number: 8748328Abstract: An optical glass having a refractive index nd of 1.70 or greater and an Abbé number of 50 or greater. Given as mole percentages, it comprises: B2O3 (20 to 80 percent), SiO2 (0 to 30 percent), Li2O (1 to 25 percent), ZnO (0 to 20 percent), La2O3 (4 to 30 percent), Gd2O3 (1 to 25 percent), Y2O3 (0 to 20 percent), ZrO2 (0 to 5 percent), MgO (0 to 25 percent), CaO (0 to 15 percent), and SrO (0 to 10 percent), with the combined quantity of the above components being 97 percent or greater. The molar ratio of {ZnO/(La2O3+Gd2O3+Y2O3)} is 0.8 or less and the molar ratio of {(CaO+SrO+BaO)/(La2O3+Gd2O3+Y2O3)} is 0.8 or less. Ta2O5 may be incorporated as an optional component, with the molar ratio {(ZrO2+Ta2O5)/(La2O3+Gd2O3+Y2O3)} being 0.4 or less.Type: GrantFiled: October 16, 2012Date of Patent: June 10, 2014Assignee: Hoya CorporationInventor: Yasuhiro Fujiwara
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Patent number: 8741796Abstract: A high-refractivity low-dispersion optical glass that can be stably supplied and has excellent glass stability and that has coloring reduced, composed of in mass %, 5 to 32% of total of SiO2 and B2O2, 45 to 65% of total of La2O2, Gd2O2 and Y2O2, 0.5 to 10% of ZnO, 1 to 20% of total of TiO2 and Nb2O5, and optionally other components. The optical glass has a refractive index nd of 1.89 to 2.0, an Abbe's number ?d of 32 to 38 and a coloring degree ?70 of 430 nm or less.Type: GrantFiled: June 24, 2013Date of Patent: June 3, 2014Assignee: Hoya CorporationInventors: Tomoaki Negishi, Xuelu Zou
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Patent number: 8741795Abstract: An optical glass having high-refractivity and low-dispersion properties and containing, by mol %, 0.1 to 40% of SiO2, 10 to 50% of B2O3, wherein the mass ratio of the content of SiO2 to the content of B2O3, SiO2/B2O3, is 1 or less, 0.5 to 22% of ZnO, 5 to 50% of La2O3, and optionally other ingredients. The optical glass has a refractive index nd of 1.86 to 1.95 and an Abbe's number ?d of (2.36?nd)/0.014 or more but less than 38, and a glass transition temperature of equal to or greater than 640° C.Type: GrantFiled: March 18, 2013Date of Patent: June 3, 2014Assignee: Hoya CorporationInventors: Xuelu Zou, Yunoshin Kanayama, Tomoaki Negishi
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Patent number: 8728963Abstract: An optical glass that is an oxide glass having a very high refractive index in spite of its low-dispersion property, having excellent glass stability and having less susceptibility to coloring.Type: GrantFiled: March 5, 2013Date of Patent: May 20, 2014Assignee: Hoya CorporationInventors: Tomoaki Negishi, Xuelu Zou
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Patent number: 8691712Abstract: There is provided an optical glass with a high refractive index and a low dispersion having a refractive index (nd) of not less than 1.75 and an Abbe's number (?d) of not less than 35 where the image formation characteristic is hardly affected by changes in temperature of the using environment. SiO2, B2O3 and La2O3 are contained as essential components and the ratio of the constituting components are adjusted whereby an optical glass in which a product of ? and ? where ? is an average linear expansion coefficient at ?30 to +70° C. and ? is an optical elasticity constant at the wavelength of 546.1 nm is not more than 130×10?12° C.?1×nm×cm?1×Pa?1 is able to be achieved.Type: GrantFiled: November 14, 2012Date of Patent: April 8, 2014Assignee: Ohara Inc.Inventors: Junko Suzuki, Michiko Ogino, Masahiro Onozawa
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Patent number: 8661853Abstract: A process for producing a glass in the production of a glass molded article formed of an optical glass by melting and clarifying a glass raw material to prepare a molten glass and molding said molten glass, the process comprising preparing a glass raw material that gives an oxide glass comprising, by cationic %, 12 to 65% of B3+, 0 to 20% of Si4+, 0 to 6% of Ge4+, 15 to 50% of total of La3+, Gd3+, Y3+, Yb3+, Sc3+ and Lu3+, 4 to 54% of total of Ta5+, Zr4+, Ti4+, Nb5+, W6+ and Bi3+, 0 to 35% of Zn2+, 0 to 9% of total of Li+, Na+ and K+, and 0 to 15% of total of Mg2+, Ca2+, Sr2+ and Ba2+, a total content of said cationic components in the oxide glass being 99 to 100%, and said glass raw material comprising carbonate and sulfate.Type: GrantFiled: November 9, 2009Date of Patent: March 4, 2014Assignee: Hoya CorporationInventors: Tomoaki Negishi, Yasuhiro Fujiwara
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Patent number: 8664133Abstract: An optical glass having optical constants of a refractive index (nd) of 1.78 or over, an Abbe number (?d) of 30 or below, and a partial dispersion ratio (?g, F) of 0.620 or below comprises SiO2 and Nb2O5 as essential components, wherein an amount of Nb2O5 in mass % is more than 40%. The optical glass further comprising, in mass % on oxide basis, less than 2% of K2O and one or more oxides selected from the group consisting of B2O3, TiO2, ZrO2, WO3, ZnO, SrO, Li2O and Na2O wherein a total amount of SiO2, B2O3, TiO2, ZrO2, Nb2O5, WO3, ZnO, SrO, Li2O and Na2O is more than 90% and TiO2/(ZrO2+Nb2O5) is less than 0.32.Type: GrantFiled: July 12, 2011Date of Patent: March 4, 2014Assignee: OHARA Inc.Inventor: Susumu Uehara
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Patent number: 8664134Abstract: A crystallizing glass solder for high-temperature applications, containing, in % by weight on an oxide basis: 45% to 60% of BaO, 25% to 40% of SiO2, 5% to 15% of B2O3, 0 to <2% of Al2O3, and at least one alkaline earth metal oxide from the group consisting of MgO, CaO and SrO, wherein CaO is 0% to 5% and the sum of the alkaline earth metal oxides MgO, CaO and SrO is 0% to 20%, preferably 2% to 15%. The glass solder is preferably free from TeO2 and PbO. Preferred embodiments of the glass solder contain from 3 to 15 wt. % of Y2O3 and have low porosity and high stability with respect to a moist fuel gas environment.Type: GrantFiled: September 21, 2011Date of Patent: March 4, 2014Assignee: Schott AGInventors: Dieter Goedeke, Peter Brix, Olaf Claussen, Joern Besinger, Bastian Schoen
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Patent number: 8647996Abstract: The present invention relates to an optical glass, a preform for precision press molding, methods for manufacturing the same, and an image pickup device. The optical glass of the present invention not only has a high refractive index, a high dispersion property, and good precision press moldability, but also has good stability with respect to devitrification when reheated (referred to as “devitrification stability upon reheating”), and is an optical glass with a good partial dispersion ratio (Pg, F).Type: GrantFiled: March 28, 2011Date of Patent: February 11, 2014Assignee: Hoya CorporationInventor: Hiroki Takazawa