Having Refractive Index Less Than 1.8 And Abbe Number Less Than 70 Patents (Class 501/903)
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Patent number: 5897678Abstract: The invention provides a method by which a crystal glass composition which employs TiO.sub.2 as a raw material substituted for PbO can be produced while effectively preventing development of a yellowish color of the glass composition which is caused by TiO.sub.2. In the production method, to a batch composition which is composed of 50 to 60 percent by weight of SiO.sub.2, 4 to 14 percent by weight of K.sub.2 O, 10 to 20 percent by weight of BaO and 3 to 10 percent by weight of TiO.sub.2, NaNO.sub.3 (sodium nitrate) is added by 1.0 to 5.0 percent by weight or BaO.sub.2 (barium peroxide) is added by 0.3 to 2.0 percent by weight for elimination of development of a color which arises from the 3 to 10 percent by weight of TiO.sub.2, and also one of Sb.sub.2 O.sub.3 (antimony oxide) and As.sub.2 O.sub.3 (arsenious acid) is added by 0.2 to 1.0 percent by weight for defoaming. Instead, NaSb(OH).sub.6 (sodium antimonate) having color development elimination and defoaming actions may be added by 0.5 to 2.Type: GrantFiled: July 23, 1997Date of Patent: April 27, 1999Assignee: Toyo Glass Company LimitedInventors: Hidetoshi Komiya, Shizue Inaba
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Patent number: 5858898Abstract: An optical glass having optical constants of refractive index within the range of 1.55-1.75 and Abbe number (.nu. d) within the range of 25-51 and having large negative anomalous dispersion which is substantially free of lead and arsenic compounds includes as its essential ingredients in weigth percent 10->40% SiO.sub.2, 12.5-35% B.sub.2 O.sub.3, 3-20% ZrO.sub.2 and 6-30% Nb.sub.2 O.sub.5.Type: GrantFiled: October 6, 1997Date of Patent: January 12, 1999Assignee: Kabushiki Kaisha OharaInventors: Muneo Nakahara, Michiko Morishita
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Patent number: 5744409Abstract: An optical glass containing, as glass components,30.about.55 wt % of SiO.sub.2,5.about.30 wt % of B.sub.2 O.sub.3,the total amount of SiO.sub.2 and B.sub.2 O.sub.3 being 56.about.70 wt % and the SiO.sub.2 /B.sub.2 O.sub.3 weight ratio being 1.3.about.12.0,7.about.12 wt % of Li.sub.2 O, in which 7 wt % is excluded,0.about.5 wt % of Na.sub.2 O,0.about.5 wt % of K.sub.2 O,the total amount of Li.sub.2 O, Na.sub.2 O and K.sub.2 O being 7 to 12 wt % in which 7 wt % is excluded,10.about.30 wt % of BaO,0.about.10 wt % of MgO,0.about.20 wt % of CaO,0.about.20 wt % of SrO, and0.about.20 wt % of ZnOthe total amount of BaO, MgO, CaO, SrO and ZnO being 10.about.30 wt %, and the total amount of SiO.sub.2, B.sub.2 O.sub.3, Li.sub.2 O and BaO being at least 72 wt %.Type: GrantFiled: January 3, 1997Date of Patent: April 28, 1998Assignee: Hoya CorporationInventors: Kazuaki Hashimoto, Koichi Sato
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Patent number: 5607886Abstract: An optical glass having optical constants of a refractive index (Nd) from 1.50 to 1.60 and an Abbe number (.nu.d) ranging from 62 to 73, a transformation temperature (Tg) of 550.degree. C. or below, and barely cracks or sticks to metal molds when the glass is subjected to mold pressing, maintains excellent chemical durability, and having softening capability at a low temperature which can be obtained by restricting the composition of the glass in weight percents within a specific range of a SiO.sub.2 --Al.sub.2 O.sub.3 --P.sub.2 O.sub.5 --R.sub.2 O system.Type: GrantFiled: October 6, 1995Date of Patent: March 4, 1997Assignee: Kabushiki Kaisya OharaInventor: Masahiro Onozawa
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Patent number: 5565389Abstract: The invention relates to a glass of high refractive index suitable for the close-vision part of multifocal, in particular phototropic multifocal, spectacle lenses. The glass has a composition (in % by weight, based on oxide) of:SiO.sub.2 28-40; B.sub.2 O.sub.3 0-8.5; Li.sub.2 O 0-1; Na.sub.2 O 0-2.5; K.sub.2 O 0-5; CaO 0-6; SrO 0-6; BaO 6-12; ZnO 9-16; PbO 32-40; TiO.sub.2 0.3-7; ZrO.sub.2 0.4-5; .SIGMA. Li.sub.2 O+Na.sub.2 O+K.sub.2 O 0-5, anda refractive index n.sub.e of 1.66-1.81, an expansion coefficient .alpha..sub.20-300 of 5.7-6.8.times.10.sup.-6 K.sup.-1, a softening point of 650.degree.-700.degree. C. and a glass transition temperature Tg of 520.degree.-560.degree. C.Type: GrantFiled: August 31, 1995Date of Patent: October 15, 1996Assignee: Deutsche Spezialglas A.G.Inventor: Reinhard Kassner
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Patent number: 5525554Abstract: This invention is directed to the production of glasses essentially free of Nb.sub.2 O.sub.5, and having refractive index close to 1.7, an Abbe number of about 35 and a density close to 3.2. The glasses consist essentially in weight percent on the oxide basis, of______________________________________ SiO.sub.2 38-45 TiO.sub.2 15-<20 ZrO.sub.2 6-10 La.sub.2 O.sub.3 0.5-4 BaO 12-19 CaO 3-8 BaO + CaO + SrO 17-25 Na.sub.2 O 2-6 K.sub.2 O 4-8 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 6-10.Type: GrantFiled: June 7, 1995Date of Patent: June 11, 1996Assignee: Corning France, S.A.Inventor: Marie J. M. Comte
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Patent number: 5525553Abstract: This invention is directed to the production of glasses useful for ophthalmic applications which exhibit excellent resistance to the development of coloration upon being exposed to x-radiation and excellent resistance to the development of solarization. The glass compositions are essentially free of lead and consist essentially, in weight percent, of______________________________________ SiO.sub.2 60-70 ZrO.sub.2 0.5-2 TiO.sub.2 0-1.5 B.sub.2 O.sub.3 0.5-5 CeO.sub.2 0.1-0.3 Sb.sub.2 O.sub.3 0-0.5 Al.sub.2 O.sub.3 2-6 Li.sub.2 O 0-2 SO.sub.3 0-0.3 Na.sub.2 O 9-14 MgO 0-5 Br 0-0.5 K.sub.2 O 3-10 SrO 0-5 Cl 0-0.5 CaO 0.5-4 BaO 0-5 F 0-0.5.Type: GrantFiled: June 5, 1995Date of Patent: June 11, 1996Inventors: Yves Brocheton, Michel Prassas, Daniel L. G. Ricoult
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Patent number: 5472918Abstract: An optical glass including as its main ingredients in weight percent 25-50% SiO.sub.2, 16-40% B.sub.2 O.sub.3, 5-25% SrO and 1-10% Li.sub.2 O has optical constants of refractive index (Nd) of 1.55-1.65 and Abbe number (.nu.d) of 55-63 and a yield point (At) below 600.degree. C. which is suited for mold pressing.Type: GrantFiled: October 28, 1994Date of Patent: December 5, 1995Assignee: Kabushiki Kaisha OharaInventor: Masahiro Onozawa
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Patent number: 5434111Abstract: Lead- and barium-free crystal glass for the production of high-quality glasses and domestic articles, having high optical transmission, a refractive index n.sub.D of greater than 1.52, a density of at least 2.45 g/cm.sup.3, high hydrolytic resistance, good solarization resistance, and a K.sub.2 O+ZnO content of greater than 10% by weight, the glass system being based on an alkali-lime-silicate glass containing TiO.sub.2, ZrO.sub.2, Nb.sub.2 O.sub.3 and possibly Ta.sub.2 O.sub.5 and/or combinations thereof.Type: GrantFiled: April 12, 1993Date of Patent: July 18, 1995Assignee: Schott GlaswerkeInventors: Marc Clement, Peter Brix, Ludwig Gaschler
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Patent number: 5376597Abstract: A glass composition is disclosed wherein the density and the refraction index and the dispersion value of light are equal to or higher than those of conventional lead-containing crystal glass while no lead is contained therein at all. The glass composition comprises 50 to 60% by weight of SiO.sub.2, 5 to 13% by weight of K.sub.2 O, 5 to 8% by weight of TiO.sub.2, 10 to 15% by weight of BaO, 5 to 10% by weight of ZnO, 3 to 10% by weight of Na.sub.2 O, 1 to 5% by weight of CaO, and 0.3 to 0.8% by weight of Sb.sub.2 O.sub.3.Type: GrantFiled: October 20, 1993Date of Patent: December 27, 1994Assignee: Toyo Glass Company LimitedInventors: Haruhiko Ogata, Hidetoshi Komiya, Shizue Inaba
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Patent number: 5340778Abstract: An optical crown glass having a negative anomalous partial dispersion .DELTA.P.sub.g,F, a refractive index n.sub.d of greater than 1.52, an Abbe number .nu..sub.d of greater than 57, and a high UV transmission has a composition (in % by weight) 40-72 B.sub.2 O.sub.3, 9-31 Al.sub.2 O.sub.3, 0-15 SiO.sub.2, 0.1-0.5 H.sub.2 O, 0-12 Li.sub.2 O, wherein the total of R.sub.2 O (R=Li, Na, K, Rb, Cs) is 0-20 and the total of MO (M=Mg, Ca, Sr, Ba) is 0-30, and wherein the total of R.sub.2 O and MO is greater than 5, and the molar ratio between Al.sub.2 O.sub.3 and B.sub.2 O.sub.3 is 0.2-0.3 and the molar ratio between (R.sub.2 O+MO) and B.sub.2 O.sub.3 is 0.1-0.4.Type: GrantFiled: June 4, 1993Date of Patent: August 23, 1994Assignee: Scott GlaswerkeInventors: Thomas Kloss, Elfi Stein, Kirsten Gerth, Andrea Wickardt
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Patent number: 5332700Abstract: An optical glass which is a SiO.sub.2 -Nb.sub.2 O.sub.5 -R'.sub.2 O (where R' is an alkali metal element)-F system of a specific composition range exhibits optical constants of a refractive index (Nd) of about 1.52-1.67 and an Abbe number (.upsilon. d) of about 32-50, is free of PbO and has an improved light transmissivity.Type: GrantFiled: May 26, 1993Date of Patent: July 26, 1994Assignee: Kabushiki Kaisha OharaInventors: Katsuhiko Yamaguchi, Futoshi Ishizaki, Naoyuki Goto, Hisao Yatsuda, Goro Enomoto, Hideo Yasui
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Patent number: 5320987Abstract: An optical glass which is a SiO.sub.2 --TiO.sub.2 --K.sub.2 O--RO (where R represents Mg, Ca, Sr, Ba and Zn metal elements) system glass of a specific content range exhibits optical constants of a refractive index (Nd) of about 1.58-1.78 and Abbe number (.nu.d) of about 28-45, is free of PbO and has an improved property against devitrification.Type: GrantFiled: October 6, 1992Date of Patent: June 14, 1994Assignee: Kabushiki Kaisha OharaInventors: Tatsuya Senoo, Katsuhiko Yamaguchi, Muneo Nakahara
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Patent number: 5320985Abstract: An optical glass which is a SiO.sub.2 --Nb.sub.2 O.sub.5 --R'.sub.2 O (R' being an alkali metal element)-F system of a specific composition range exhibits optical constants of a refractive index (Nd) of about 1.60 or below and an Abbe number (.nu.d) of about 57-40, is free of PbO and has an improved light transmissivity.Type: GrantFiled: October 1, 1992Date of Patent: June 14, 1994Assignee: Kabushiki Kaisha OharaInventor: Goro Enomoto
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Patent number: 5300467Abstract: An optical glass which is a SiO.sub.2 --B.sub.2 O.sub.3 --(TiO.sub.2 +ZrO.sub.2)--SrO--BaO--R'.sub.2 O system of a specific composition range exhibits optical constants of a refractive index (Nd) of 1.57-1.75 and Abbe number (.nu.d) of 30-55, is free of PbO and has improved stability against devitrification and tinting and improved chemical durability.Type: GrantFiled: December 24, 1992Date of Patent: April 5, 1994Assignee: Kabushiki Kaisha OharaInventors: Futoshi Ishizaki, Muneo Nakahara, Hiroshi Shishido, Katsuhiko Yamaguchi
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Patent number: 5217927Abstract: A highly refractive, low-density phototropic glass in which the carriers of phototropy are precipitates containing silver, halogens and copper oxide, and which has a density equal to or less than 3.0 g/cm.sup.3, a refractive index equal to or greater than 1.60 and an Abbe number equal to or greater than 40, consisting essentially of, in % by weight on an oxide basis:______________________________________ SiO.sub.2 35-50 B.sub.2 O.sub.3 13.5-21 .SIGMA.SiO.sub.2 and B.sub.2 O.sub.3 50-70 Li.sub.2 O 0.0-2.5 Na.sub.2 O 0.0-4.0 K.sub.2 O 0.0-10.0 .SIGMA.Alkali metal oxides 4-14 BaO.sub.2 5.0-10.5 TiO.sub.2 3.5-6.5 ZrO.sub.2 4.5-9.5 Nb.sub.2 O.sub.3 5.0-11.5, ______________________________________the total of the foregoing oxides being 100% by weight, and in addition to the basic glass composition, carriers of phototropy consisting essentially of, in % by weight: ______________________________________ Ag.sub.2 O 0.05-0.25 Br 0.07-0.25 Cl 0.06-0.35 .SIGMA.Br and Cl .ltoreq.0.5 CuO 0.003-0.015.Type: GrantFiled: October 10, 1991Date of Patent: June 8, 1993Assignee: Deutsche Spezialglas AktiengesellschaftInventors: Werner Behr, Reinhard Kassner
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Patent number: 5204292Abstract: An optical glass for a press lens composed of 25 to 41 mol % of SiO.sub.2, 10 to 30 mol % of B.sub.2 O.sub.3, 18 to 40 mol % of PbO, 1 to 10 mol % of Na.sub.2 O, 1 to 15 mol % of K.sub.2 O, 2 to 20 mol % of Li.sub.2 O, and 0.3 to 3 mol % of Al.sub.2 O.sub.3.Type: GrantFiled: April 1, 1991Date of Patent: April 20, 1993Assignee: Alps Electric Co., Ltd.Inventor: Tooru Michimata
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Patent number: 5190896Abstract: A colored, chemstrengthenable contrast enhancement, UV attenuated glass (e.g., for sunglasses) comprises, in weight percent,______________________________________ Oxide Wt. % ______________________________________ SiO.sub.2 40-72 B.sub.2 O.sub.3 0-13 Al.sub.2 O.sub.3 0.5-3 Li.sub.2 O 0-3 Na.sub.2 O 8-13 K.sub.2 O 1-10 TiO.sub.2 8.0-9.5 CeO.sub.2 2.6-3.5 Nd.sub.2 O.sub.3 5-17 Fe.sub.2 O.sub.3 1.40-2.10 CoO 0-0.07 NiO 0-0.4 CuO 0-0.5 Er.sub.2 O.sub.3 0-2 V.sub.2 O.sub.5 0-0.5 Cr.sub.2 O.sub.3 0-0.25 ______________________________________and has the following properties% T (2.0 mm) 400 nm: .ltoreq.2.2%% T (2.0 mm) 380 nm: 0.0%a: -1.0 to -7.5b: +1.0 to +10.0.Type: GrantFiled: June 25, 1992Date of Patent: March 2, 1993Assignee: Schott Glass Technologies, Inc.Inventors: Sally Pucilowski, David G. Krashkevich, Ronald A. Klimek
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Patent number: 5162826Abstract: This invention relates to the production of glasses exhibiting a refractive index between about 1.66-1.81, a softening point between about 625.degree.-675.degree. C., a strain point between about 455.degree.-490.degree. C., a linear coefficeint of thermal expansion (25.degree.-300.degree. C.) between about 53-65.times.10.sup.-7 /.degree.C., and good chemical durability which consist essentially, in weight percent, of:______________________________________ SiO.sub.2 24-42 Li.sub.2 O 0.2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 0-3.5 Al.sub.2 O.sub.3 3-7.5 Na.sub.2 O 0-2 ZrO.sub.2 0-2.5 B.sub.2 O.sub.3 2-7.5 K.sub.2 O 0-3 TiO.sub.2 0-8 PbO 35-57 La.sub.2 O.sub.3 0-8 La.sub.2 O.sub.3 + ZrO.sub.2 4-12.sub.Type: GrantFiled: June 17, 1991Date of Patent: November 10, 1992Assignee: Corning IncorporatedInventors: David W. Morgan, Michel Prassas
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Patent number: 5137850Abstract: A chemically resistant glass which can be produced at relatively low melting temperatures and has anomalous negative partial dispersion P.sub.g,F, a refractive index n.sub.d of from 1.73 to 1.83 and an Abbe coefficient v.sub.d of from 31 to 38 preferably contains (in % by weight, based on oxides):______________________________________ 0-4 SiO.sub.2 + GeO.sub.2 0-2 GeO.sub.2 0-10 MgO 26-33 B.sub.2 O.sub.3 0-1 Li.sub.2 O 0-16 CaO 19-50 PbO 0-1 Na.sub.2 O 0-16 BaO 1-6 ZrO.sub.2 0-1 K.sub.2 O 0-16 SrO 4-16 Ta.sub.2 O.sub.5 0-2 .SIGMA. alkaline earth 0-6 Al.sub.2 O.sub.3 metal oxides 0-16 ZnO 0-4 TiO.sub.2 1.5-20 .SIGMA. alkaline earth metal oxides + ZnO 0-1 WO.sub.3 0-11 La.sub.2 O.sub.3 0-7 Nb.sub.2 O.sub.5 0-5.5 Y.sub.2 O.sub.3 0-5.5 Gd.sub.2 O.sub.3 4-11 .SIGMA. La.sub.2 O.sub.3 + Y.sub.2 O.sub.3 + Gd.sub.2 O.sub.3 ______________________________________with the proviso that the .SIGMA.(SiO.sub.2 +GeO.sub.2 +B.sub.2 O.sub.3)/.SIGMA.(ta.sub.2 O.sub.5 +ZrO.sub.2 +HfO.sub.2) ratio is less than 5 and the PbO/.Type: GrantFiled: January 16, 1991Date of Patent: August 11, 1992Assignee: Schott GlaswerkeInventors: Marc Clement, Volkmar Geiler, Danuta Grabowski
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Patent number: 5104831Abstract: A highly refractive, low-density phototropic glass in which the carriers of phototropy are precipitates containing silver, halogens and copper oxide, and which has a density equal to or less than 3.0 g/cm.sup.3, a refractive index equal to or greater than 1.60 and an Abbe number equal to or greater than 40, consisting essentially of, in % by weight on an oxide basis:SiO.sub.2 : 35-50B.sub.2 O.sub.3 : 13.5-21.SIGMA.SiO.sub.2 and B.sub.2 O.sub.3 : 50-70Li.sub.2 O: 0.0-2.5Na.sub.2 O: 0.0-4.0K.sub.2 O: 0.0-10.0.SIGMA.Alkali metal oxides: 4-14BaO: 5.0-10.5TiO.sub.2 : 3.5-6.5ZrO.sub.2 : 4.5-9.5Nb.sub.2 O.sub.3 : 5.0-11.5,and in addition to the basic glass composition, carriers of phototropy consisting essentially of, in % by weight:Ag.sub.2 O; 0.05-0.25Br: 0.07-0.25Cl: 0.06-0.35.SIGMA.Br and Cl: .ltoreq.0.5CuO: 0.003-0.015.Type: GrantFiled: July 25, 1989Date of Patent: April 14, 1992Assignee: Deutsche Spezialglas AktiengesellschaftInventors: Werner Behr, Reinhard Kassner
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Patent number: 5100843Abstract: A glass having a negative anomalous partial dispersion .DELTA.P.sub.g,F, an index of refraction of n.sub.d .gtoreq.1.67 and an Abbe number of .nu..sub.d >36 has the following composition, in % by weight, 3-11 of SiO.sub.2, 0-3 of GeO.sub.2, .SIGMA. SiO.sub.2 +GeO.sub.2, 4.5-11; B.sub.2 O.sub.3, 29-35; 5-13 of Al.sub.2 O.sub.3 ; 1-3 of ZrO.sub.2 ; 0.2-3 of TiO.sub.2 ; 0.2-1.5 of Ta.sub.2 O.sub.5 ; 30-45 of PbO; 0-3 each of Li.sub.2 O, Na.sub.2 O, K.sub.2 O, Rb.sub.2 O, Cs.sub.2 O, .SIGMA. alkali metal oxide 0-3; 0-3.5 each of MgO, CaO, BaO, SrO, .SIGMA. alkaline-earth oxide 0-6, if .SIGMA. SiO.sub.2 and GeO.sub.2 .gtoreq.9; .SIGMA. alkaline-earth oxide 0-3.5, if .SIGMA. SiO.sub.2 and GeO.sub.2 <9; 0-14 of ZnO, 0-3 of La.sub.2 O.sub.3 ; 0-7 of Nb.sub.2 O.sub.3 ; 0-1 of Sb.sub.2 O.sub.3 ; 0-0.3 of As.sub.2 O.sub.3 ; 0-1.5 of WO.sub.3 ; 0-1 of F. This glass is inexpensive and can be produced in high quality, and has a high crystalization stability and good transmission values.Type: GrantFiled: May 31, 1990Date of Patent: March 31, 1992Assignee: Schott GlaswerkeInventors: Danuta Grabowski, Marc Clement, Volkmar Geiler
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Patent number: 5023209Abstract: This invention is directed to the preparation of silver halide-containing photochromic glasses exhibiting refractive indices between 1.585-1.610, Abbe numbers higher than 41, and densities less than 2.80 g/cm.sup.3 generally consisting essentially, in weight percent, of:______________________________________ SiO.sub.2 43-52 SrO 0.8-9 B.sub.2 O.sub.3 12.5-18 BaO 1-9 Al.sub.2 O.sub.3 0-3 K.sub.2 O 2-9 ZrO.sub.2 3-8 TiO.sub.2 2-8 Li.sub.2 O 1.5-3.5 Ag 0.100-0.175 Na.sub.2 O 0.3-3 Cl 0.140-0.350 Nb.sub.2 O.sub.5 4-9 Br 0.093-0.180 MgO 0-5 CuO 0.0080-0.Type: GrantFiled: September 13, 1990Date of Patent: June 11, 1991Assignee: Corning France S.A.Inventors: Luc Grateau, Michel Prassas
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Patent number: 5021366Abstract: This invention is drawn particularly to the production of glasses having essentially fluorine-free compositions consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-10 P.sub.2 O.sub.5 30-36 Na.sub.2 O 5-15 Al.sub.2 O.sub.3 0-5 K.sub.2 O 0-6 CeO.sub.2 0-2 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 15-25 SnO 0-20 ZnO 10-33 PbO 0-20 CaO 0-20 Sb.sub.2 O.sub.3 0-12 SrO 0-20 Bi.sub.2 O.sub.3 0-6 BaO 0-20 SnO + PbO + 0-20. Sb.sub.2 O.sub.3 + Bi.sub.2 O.sub.Type: GrantFiled: October 19, 1990Date of Patent: June 4, 1991Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Patent number: 4996173Abstract: The optical glass of the present invention comprising SiO.sub.2, alkali metal oxides, P.sub.2 O.sub.5 and Nb.sub.2 O.sub.5 has optical properties of 1.70 or more in refractive index nd and 30 or less in Abbe's number .nu.d and is superior in devitrification resistance and stability.Type: GrantFiled: February 13, 1989Date of Patent: February 26, 1991Assignee: Hoya CorporationInventor: Kazuo Tachiwana
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Patent number: 4990468Abstract: A fluorophosphate optical glass having optical constants, i.e. refractive index (nd) of 1.54 to 1.60 and Abbe number (.nu.d) of 68 to 75 and having abnormal partial dispersion represented by a relative partial dispersion of at least 0.537 is provided, which has a chemical composition (% by weight) comprising:______________________________________ Al(PO.sub.3).sub.3 15-32% Ba(PO.sub.3).sub.2 0-10% Sr(PO.sub.3).sub.2 0-10% Ca(PO.sub.3).sub.2 0-10% Mg(PO.sub.3).sub.2 0-10% sum of metaphosphates 20-32% BaF.sub.2 20-70% SrF.sub.2 5-40% CaF.sub.2 0-15% MgF.sub.2 0-10% AlF.sub.3 0-5% GdF.sub.3 0-5% sum of fluorides 55-75% Gd.sub.2 O.sub.3 5-22% La.sub.2 O.sub.3 0-7% Y.sub.2 O.sub.3 0-10% Yb.sub.2 O.sub.Type: GrantFiled: September 29, 1989Date of Patent: February 5, 1991Assignee: Sumita Optical Glass, Inc.Inventors: Masayuki Komiya, Masaaki Otsuka, Naruhito Sawanobori, Shinobu Nagahama
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Patent number: 4973565Abstract: There are disclosed fluoroborosilicate glasses that are particularly adapted to being drawn with lead silicate core glasses to produce clad glass fibers useful in forming fiber optic bundles to be incorporated in night vision equipment. The cladding glass has a refractive index not over about 1.465 and a coefficient of thermal expansion not over about 80.times.10.sup.-7 /.degree.C. The clad fiber has a numerical aperture approximating or equal to one.Type: GrantFiled: July 17, 1989Date of Patent: November 27, 1990Assignee: Corning IncorporatedInventor: Gerald J. Fine
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Patent number: 4868141Abstract: There are disclosed fluoroborosilicate glasses that are particularly adapted to being drawn with lead silicate core glasses to produce clad glass fibers useful in forming fiber optic bundles to be incorporated in night vision equipment. The cladding glass has a refractive index not over about 1.45 and a coefficient of thermal expansion not over about 120.times.10.sup.-7 /.degree.C. The clad fiber has a numerical aperture approximating or equal to one.Type: GrantFiled: December 2, 1988Date of Patent: September 19, 1989Assignee: Corning IncorporatedInventor: Gerald J. Fine
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Patent number: 4839314Abstract: This invention is directed to the production of glasses especially suitable for use as ophthalmic lenses which exhibit indices of refraction between about 1.699-1.703, Abbe numbers equal to or greater than 41.0, densities less than 3.25 g/cm.sup.3, and good resistance to attack by acids. The glasses are essentially free of Al.sub.2 O.sub.3 and consist essentially, in weight percent on the oxide basis, of:______________________________________ SiO.sub.2 33-37 CaO 8-9.5 B.sub.2 O.sub.3 7.5-13 SrO 2-4 SiO.sub.2 + B.sub.2 O.sub.3 44-48 La.sub.2 O.sub.3 12.3-14.5 Li.sub.2 O 5-8 ZrO.sub.2 4-6 Na.sub.2 O 0-2.5 Nb.sub.2 O.sub.5 8-10.5 K.sub.2 O 0-2 TiO.sub.2 5-7 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 5-8 As.sub.2 O.sub.3 0-0.8.Type: GrantFiled: May 6, 1988Date of Patent: June 13, 1989Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean P. Mazeau
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Patent number: 4824809Abstract: A new, CdO-and ThO.sub.2 -free optical glass with refractive indices of 1.73-1.78 and Abbe numbers of 30-34 and with particularly good devitrification stability comprises (in weight %):______________________________________ SiO.sub.2 12-20, B.sub.2 O.sub.3 10-18, PbO 50-60 Al.sub.2 O.sub.3 2-7, ZnO 0-4, ZrO.sub.2 0.5-3 La.sub.2 O.sub.3 2-10, Cs.sub.2 O 0-5, M.sub.2 O 0-1 (M.sub.2 O.dbd. Na.sub.2 O, K.sub.2 O, Li.sub.2 O) TiO.sub.2 0-5 with the SiO.sub.2 /B.sub.2 O.sub.3 -ratio being about 1.0 to ______________________________________ 1.5.Type: GrantFiled: December 28, 1987Date of Patent: April 25, 1989Assignee: Schott GlaswerkeInventors: Danuta Grabowski, Ludwig Ross
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Patent number: 4822758Abstract: This invention is related to glasses particularly useful in the fabrication of multifocal lenses for ophthalmic applications. The inventive glasses exhibit a refractive index between 1.599-1.602, an Abbe number between 40.5-41.5, a density between 2.64-2.66 g/cm.sup.3, a transmission of visible radiation at 400 nm through a thickness of 10 mm greater than 83%, a softening point between 670.degree.-680.degree. C., a birefringence upon sealing, measured as described, between -150 and +150 nm/cm, and consist essentially, expressed in terms of weight percent on the oxide basis, of:______________________________________ SiO.sub.2 52-57 K.sub.2 O 11.0-16.0 B.sub.2 O.sub.3 2.5-7.0 CaO 2-3.5 Al.sub.2 O.sub.3 0-1 ZrO.sub.2 1-1.5 Li.sub.2 O 0.3-0.8 TiO.sub.2 15.0-16.2 Na.sub.2 O 5.4-8.2 As.sub.2 O.sub.3 0.1-0.Type: GrantFiled: June 23, 1988Date of Patent: April 18, 1989Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean-Pierre Mazeau
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Patent number: 4814299Abstract: An optical glass, n.sub.d .gtoreq.1.60 and v.sub.d .gtoreq.58, having a high chemical stability as well as resistance to phase separation and crystallization, comprises in percent by weight:______________________________________ SiO.sub.2 21.5-27.0; B.sub.2 O.sub.3 23.5-30.0 SrO 16.0-24.0; La.sub.2 O.sub.3 10.0-20; Al.sub.2 O.sub.3 1.5-5.0; BaO 5.0-14.0; ZrO.sub.2 0-4.0; Li.sub.2 O 0.5-5.0; Na.sub.2 O 0.8-2.5; K.sub.2 O 0-2.0.Type: GrantFiled: July 2, 1987Date of Patent: March 21, 1989Assignee: Schott GlaswerkeInventors: Ludwig Ross, Volkmar Geiler
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Patent number: 4812423Abstract: This specification discloses optical light-weight glass having a composition of SiO.sub.2 47--70, Li.sub.2 O 5.5-21, K.sub.2 O 2-30, Na.sub.2 O 0-30 (Li.sub.2 O+Na.sub.2 O+K.sub.2 O 21-50), TiO.sub.2 9.5-24, B.sub.2 O.sub.3 0-20, CaO 0-20, MgO+SrO+BaO+ZnO 0-4, Al.sub.2 O.sub.3 0-5 and ZrO.sub.2 +La.sub.2 O.sub.3 +Ta.sub.2 O.sub.5 +WO.sub.3 0-3, all being in % by weight, and having a refractive index (n.sub.d) of 1.58-1.65, an Abbe number (.gamma..sub.d) of 35-50 and a specific gravity of 2.69 or less. This optical glass is light in weight, high in transparency and low in dispersion, and is particularly suitable for spectacle lenses, but can also be utilized for photographic lenses.Type: GrantFiled: July 17, 1985Date of Patent: March 14, 1989Assignee: Nikon CorporationInventors: Hiroyuki Kodama, Katsumi Mangyo, Takeo Ichimura
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Patent number: 4771019Abstract: Reduced boron containing glass fibers are provided which have a refractive index similar to that of higher boron-containing glass fiber compositions. The glass fibers with a refractive index in the range of greater than 1.5495 to around 1.57 have in weight percent SiO.sub.2 - 55-56.5, CaO - 20-23, Al.sub.2 O.sub.3 14.5-15.5, B.sub.2 O.sub.3 - 5 to 5.8, R.sub.2 O - 1-1.5, wherein R is an alkali metal and F.sub.2 - 0.4 to 0.6. In addition, the glass fiber composition can have minor constituents such as TiO.sub.2 of up to around 0.6 weight percent and an MgO of up to around 0.3 weight percent and ferric oxide of up to around 0.3 weight percent. Basically, the glass fibers have a reduced content of both B.sub.2 O.sub.3 and CaO over standard glass fiber compositions such as E-glass and 621-glass and also has elevated amounts of alkali and of refractory constituents such as SiO.sub.2 and Al.sub.2 O.sub.3. The glass fibers are formed with an elevated temperature of 40.degree. to 50.degree. F. (22.degree.-28.degree.Type: GrantFiled: September 29, 1986Date of Patent: September 13, 1988Assignee: PPG Industries, Inc.Inventor: James F. Sproull
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Patent number: 4742028Abstract: This invention is concerned with a glass for optical and/or ophthalmic applications having an index of refraction between about 1.78-1.82, an Abbe number greater or equal to 31, and a density less than about 3.80 g/cm.sup.3 consisting essentially, expressed in terms of weight percent on the oxide basis, of:______________________________________ SiO.sub.2 15-30 CaO 15-28 B.sub.2 O.sub.3 2-17 SrO 0-11 SiO.sub.2 + B.sub.2 O.sub.3 24-36 BaO 0-11 Al.sub.2 O.sub.3 0-6.5 MgO + CaO + 16-33 SrO + BaO Li.sub.2 O 0-5 ZnO 0-11 Na.sub.2 O 0-5 La.sub.2 O.sub.3 16-30 K.sub.2 O 0-5 ZrO.sub.2 0-10 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 0-6 Nb.sub.2 O.sub.5 5-26 MgO 0-6 TiO.sub.2 0-14.Type: GrantFiled: June 20, 1986Date of Patent: May 3, 1988Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean P. Mazeau, Michel Prassas
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Patent number: 4732876Abstract: An Ophthalmic and optical glass which is a B.sub.2 O.sub.3 - SiO.sub.2 - Li.sub.2 O - CaO - La.sub.2 O.sub.3 - TiO.sub.2 - ZrO.sub.2 -Nb.sub.2 O.sub.5 system in which relatively large amounts of B.sub.2 O.sub.3 and La.sub.2 O.sub.3 ingredients coexist has improved resistivity to devitrification while maintaining desirable optical constants, i.e., a refractive index (.eta.d) in the range of 1.75 to 1.84, Abbe number (.nu.d) in the range of 33 to 40 and specific gravity of 4.0 or less. Besides, the range of content of the Li.sub.2 O ingredient which is effective for the chemical strengthening treatment can be enlarged by this system of glass.Type: GrantFiled: May 28, 1987Date of Patent: March 22, 1988Assignee: Kabushiki Kaisha OharaInventors: Izumi Nagamine, Nobuhiro Nozawa
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Patent number: 4721690Abstract: High PbO-content glass in the optical range of flint and heavy flint glasses from the system SiO.sub.2 --PbO--M.sub.2 O wherein M.sub.2 O=alkali metal oxides, said glass having a minimum PbO content of 30 wt. % and a minimum M.sub.2 O content of 0.5 wt. %, are provided with enhanced chemical stability without loss of the desired optical position by replacing a portion of the SiO.sub.2 and PbO such that the glass contains 1.5-6 wt. % (TiO.sub.2 +ZrO.sub.2) and the ratio of TiO.sub.2 :ZrO.sub.2 is about 0.3-2.0.Type: GrantFiled: February 5, 1985Date of Patent: January 26, 1988Inventors: Ludwig Ross, Danuta Grabowski, Burkhard Speit, Volkmar Geiler
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Patent number: 4719186Abstract: An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability of chemical hardening, comprises (in % by weight):______________________________________ SiO.sub.2 50-63 B.sub.2 O.sub.3 4-8 Al.sub.2 O.sub.3 1-2 Li.sub.2 O 4-8 Na.sub.2 O 4-8 K.sub.2 O 3-7 sum of M.sub.2 O 11-20 (M = Li, Na, K) MgO 0.5-2 CaO 2-5 sum of MO 0-3 (M = Mg, Ca) TiO.sub.2 8-12.5 ZrO.sub.2 1-3 F.sup.- 0-1 As.sub.2 O.sub.3 0.05-0.15 (optional refining agent) Sb.sub.2 O.sub.3 0.0-0.Type: GrantFiled: April 16, 1986Date of Patent: January 12, 1988Assignee: Schott GlaswerkeInventors: Karl Mennemann, Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
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Patent number: 4686196Abstract: A phototropic glass with the optical characteristics of n.sub.d greater than to or equal to 1.59 and v.sub.d greater than or equal to 44, and with a density less than or equal to 3.0 g/cm.sup.-3 is provided having a composition comprising:______________________________________ SiO.sub.2 42-56 B.sub.2 O.sub.3 11-18 Al.sub.2 O.sub.3 0-5 sum of SiO.sub.2, B.sub.2 O.sub.3, and Al.sub.2 O.sub.3 55-75 Li.sub.2 O 3-9 Na.sub.2 O 0-7.98 K.sub.2 O 0-8.22 sum of alkaki metal oxides 7-15 MgO 3-12 CaO 0-3 SrO 0-3 BaO 0-6 ZnO 0-2 sum of alkali earth metal 3-12 oxides amd ZnO TiO.sub.2 3.06-6.74 ZrO.sub.2 2-11 Nb.sub.2 O.sub.5 2.28-8 La.sub.2 O.sub.3 0-3 Er.sub.2 O.sub.Type: GrantFiled: February 13, 1986Date of Patent: August 11, 1987Assignee: Schott GlaswerkeInventors: Georg Gliemeroth, Ludwig Ross, Uwe Eichhorn, Eva G. Hoelzel, Burkhard Speit
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Patent number: 4661284Abstract: Neodymium-doped phosphate glasses having a refractive index, nd>1.520; an Abbe number, Vd, <60; a density <3.0 g/cm.sup.3, a thermal expansion coefficient, .alpha., .ltoreq.110.times.10.sup.-7 .degree.C..sup.-1 ; a Young's Modulus, E, <70.times.10.sup.3 N/mm.sup.2 ; a Poisson's Ratio, .nu., <0.28; a thermal conductivity, K, >0.5 W/m.multidot.K, a thermal FOM=(1-.nu.).multidot.K/.alpha.E>0.7, consisting essentially of, in mol. %:P.sub.2 O.sub.5 : 40-70%SiO.sub.2 : 0-20%B.sub.2 O.sub.3 : 5-20%Sum SiO.sub.2 +B.sub.2 O.sub.3 : 5-35%Sum Li.sub.2 O+Na.sub.2 O+K.sub.2 O: 5-20%Sum La.sub.2 O.sub.3 +Nd.sub.2 O.sub.3 : 3-10%Sum MgO+CaO+SrO+BaO+ZnO: 0-10%and preferably containing an amount of Nd.sub.2 O.sub.3 effective for laser activity having an emission cross-section, .sigma., >3.5.times.10.sup.-20 cm.sup.2 ; a fluorescence linewidth (.DELTA..lambda..sub.f1)<23.5 nm; a first e-folding time of the Nd.sup.3+ fluorescence at 0.5 wt. % Nd.sub.2 O.sub.3 >375 .mu.Type: GrantFiled: September 25, 1985Date of Patent: April 28, 1987Assignee: The United States of America as represented by the United States Department of EnergyInventors: Lee M. Cook, Stanley E. Stokowski
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Patent number: 4642297Abstract: Optical glass compositions having refractive indexes of 1.60-1.69 and Abbe numbers higher than 54 as well as with a density of less than 3.4 g/cm.sup.3, and which are distinguished in that they have good chemical stability, comprising (in percent by weight): 5-30 percent SiO.sub.2 ; 20-55 percent B.sub.2 O.sub.3 ; 13-40 percent CaO; 3-25 percent La.sub.2 O.sub.3 ; and optionally one or more of the following: up to 7 percent ZrO.sub.2, up to 2 percent TiO.sub.2, up to 9 percent Al.sub.2 O.sub.3, up to 11 percent MgO, up to 10 percent ZnO, up to 10 percent SrO, and up to 12 percent BaO.Type: GrantFiled: January 17, 1983Date of Patent: February 10, 1987Assignee: Schott GlaswerkeInventors: Karl Mennemann, Danuta Grabowski geb. Marszalek
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Patent number: 4612295Abstract: A glass for an eye glass lens comprising a SiO.sub.2 (or B.sub.2 O.sub.3)-CaO-Nb.sub.2 O.sub.5 system as a basic system and having a refractive index of 1.79 or more, an Abbe number of 32 to 38 and a specific gravity of less than 3.6 is disclosed.Type: GrantFiled: April 26, 1984Date of Patent: September 16, 1986Assignee: Hoya CorporationInventor: Hiroji Sagara
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Patent number: 4568651Abstract: A glass for multi-focal eyeglass having a refractive index (n.sub.d) of 1.74 to 1.78, an Abbe number (.nu..sub.d) of 31 or more, a coefficient of thermal expansion of 82 to 95.times.10.sup.-7 and a softening point of 560.degree. to 640.degree. C., comprising, in % by weight,26 to 34% SiO.sub.2 +B.sub.2 O.sub.3 +Al.sub.2 O.sub.3 ;14 to 24% SiO.sub.2 ;6 to 14% B.sub.2 O.sub.3 ;0 to 4% Al.sub.2 O.sub.3 ;38 to 50% PbO;15 to 30% BaO+SrO+CaO+MgO+ZnO;2 to 24% BaO;0 to 17% SrO;0 to 15% CaO;0 to 10% MgO;0 to 12% ZnO; and0 to 3% ZrO.sub.2 ;wherein a weight ratio of B.sub.2 O.sub.3 /SiO.sub.2 ranges from 0.3 to 0.8 and a weight ratio of alkaline earth oxides/PbO ranges from 0.2 to 0.6.Type: GrantFiled: October 26, 1984Date of Patent: February 4, 1986Assignee: Hoya CorporationInventor: Hiroji Sagara
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Patent number: 4565791Abstract: This invention is concerned with the production of glasses suitable for ophthalmic applications having refractive indices of 1.523.+-.0.004, Abbe number between 51-59, densities less than 2.43 g/cm.sup.3, transmissions at 400 nm in 2 mm thickness greater than 89%, and a UV cutoff between 310-335 nm, said glasses consisting essentially, in weight percent on the oxide basis, of:______________________________________ SiO.sub.2 49-71 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 8-20 B.sub.2 O.sub.3 5-26 TiO.sub.2 1.8-6 Al.sub.2 O.sub.3 0-14 ZrO.sub.2 0-5.5 Li.sub.2 O 0-4 As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3 0-0.7 Na.sub.2 O 0-16 Cl and/or Br 0-1 K.sub.Type: GrantFiled: July 12, 1984Date of Patent: January 21, 1986Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean P. Mazeau
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Patent number: 4562161Abstract: An optical and ophthalmic glass with high refractive index, high Abbe number and low density, which is distinguished by good chemical stability, good crystallization behavior and capability for chemical hardening, comprises (in % by weight):SiO.sub.2 --47 to 75B.sub.2 O.sub.3 --1 to 20Al.sub.2 O.sub.3 --0 to 10P.sub.2 O.sub.5 --0 to 5Li.sub.2 O--0 to 15Na.sub.2 O--0 to 10K.sub.2 O--0 to 10CaO--0 to 20MgO--0 to 15SrO--0 to 4BaO--0 to 4ZnO--0 to 5TiO.sub.2 --1 to 15ZrO.sub.2 --0 to 8Nb.sub.2 O.sub.5 --0 to 5 andF----0 to 5.Type: GrantFiled: February 18, 1983Date of Patent: December 31, 1985Assignee: Schott GlaswerkeInventors: Karl Mennemann, Georg Gliemeroth, Ludwig Ross, Burkhard Speit, Volkmar Geiler, Hans-Georg Krolla, Lothar Meckel
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Patent number: 4562162Abstract: A glass for multi-focal eyeglass having a refractive index (n.sub.d) of 1.67 to 1.73, an Abbe number (.nu..sub.d) of 33 or more, a coefficient of thermal expansion of 82 to 95.times.10.sup.-7 and a softening point of 560.degree. to 640.degree. C., comprising, in % by weight,32 to 40% SiO.sub.2 +B.sub.2 O.sub.3 +Al.sub.2 O.sub.3 ;22 to 40% SiO.sub.2 ;0 to 10% B.sub.2 O.sub.3 ;0 to 4% Al.sub.2 O.sub.3 ;4 to 10% Li.sub.2 O+Na.sub.2 O+K.sub.2 O;0 to 4% Li.sub.2 O;0 to 7% Na.sub.2 O;0 to 7% K.sub.2 O;30 to 47% PbO;3 to 24% BaO+SrO+CaO+MgO+ZnO;0 to 20% BaO;0 to 15% SrO;0 to 10% CaO;0 to 8% MgO;0 to 15% ZnO; and1 to 7% ZrO.sub.2 ;wherein a weight ratio of alkali metal oxides/PbO ranges from 0.1 to 0.3.Type: GrantFiled: October 26, 1984Date of Patent: December 31, 1985Assignee: Hoya CorporationInventor: Hiroji Sagara
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Patent number: 4554259Abstract: Alkali-free borosilicate glass have been developed having coefficients of thermal expansion (+20.degree. C. to +200.degree. C.) below 40.5.times.10.sup.-7, densities less than 3.0 g/cm.sup.3 and good visible and UV transmission, and can be produced by conventional continuous melting techniques. These glasses are particularly suitable for photomask, photovoltaic and mirror substrate applications. Their compositions comprise, in weight percent:______________________________________ SiO.sub.2 50-60% B.sub.2 O.sub.3 1-6% Al.sub.2 O.sub.3 12-15% MgO 0-2.5% CaO 0-5.1% BaO 9-10% ZnO 12-18% CeO.sub.2 0-5% As.sub.2 O.sub.3 + 0-1.5% Sb.sub.2 O.sub.3 PbO 0-1% ______________________________________Sum MgO+CaO+BaO+ZnO=21-33.5.Type: GrantFiled: May 8, 1984Date of Patent: November 19, 1985Assignee: Schott Glass Technologies, Inc.Inventors: Brian Franklin, Karl-Heinz Mader
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Patent number: 4552850Abstract: A glass suitable for use in optical fibre cores has a refractive index of 1.540-1.610, Na.sub.2 O and B.sub.2 O.sub.3 in a molar ratio of 1.05-2:1, 2-12 mole percent BaO, 40-63 mole percent SiO.sub.2, and 1.5-15 mole percent ZrO.sub.2, the proportion of SiO.sub.2 and ZrO.sub.2 together not exceeding 65 mole percent. The glass can be prepared in a highly reduced state by the use of CO and a redox buffering agent. The glass is especially suitable for the production of high numerical aperture wide cored fibres.Type: GrantFiled: December 2, 1982Date of Patent: November 12, 1985Assignee: British TelecommunicationsInventors: Sally Partington, Steven F. Carter
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Patent number: 4540672Abstract: This invention relates to glasses especially suitable for optical and ophthalmic applications which exhibit densities less than about 2.65 g/cm.sup.3, refractive indices between about 1.595-1.607, and Abbe numbers between about 40-47, and which consist essentially, in weight percent on the oxide basis, of______________________________________ SiO.sub.2 45-55 MgO and/or BaO and/or B.sub.2 O.sub.3 5-13 SrO and/or La.sub.2 O.sub.3 0-6 Al.sub.2 O.sub.3 0-5 CaO 0-12 Li.sub.2 O 1-7.5 ZnO 0-8 Na.sub.2 O 1-9 ZrO.sub.2 0-7 K.sub.2 O >10-24 TiO.sub.2 9.5-17.5 As.sub.2 O.sub.3 and/or Sb.sub.2 O.sub.3 0-1 and 13.5 < TiO.sub.2 + ZrO.sub.2 + La.sub.2 O.sub.3 + MgO <23.Type: GrantFiled: July 30, 1984Date of Patent: September 10, 1985Assignee: Corning Glass WorksInventors: Jean E. Boudot, Jean P. Mazeau, Michel Prassas
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Patent number: 4526874Abstract: An optical glass with the familiar optical position of n.sub.d >1.70 and v.sub.d >22, which differs from the familiar optical glasses of the optical position due to its lower density and good chemical stability, and is composed of (in percent by weight): SiO.sub.2 25-42, TiO.sub.2 15-35, B.sub.2 O.sub.3 0.5-7, BaO 3-13, CaO 1-3, Nb.sub.2 O.sub.5 1-20, GeO.sub.2 0-2, Al.sub.2 O.sub.3 0-4, Na.sub.2 O 7.5-15, Li.sub.2 O 0-9, K.sub.2 O 2-10, SrO 0-6, ZnO 0-5, ZrO.sub.2 0-3, and WO.sub.3 0-3.Type: GrantFiled: April 27, 1983Date of Patent: July 2, 1985Assignee: Schott GlaswerkeInventors: Danuta Grabowski geb. Marszalek, Ludwig Ross, Volkmar Geiler, Karl Mennemann