Infrared Transmitting Or Absorbing Patents (Class 501/904)
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Patent number: 8889026Abstract: A transparent heat-shielding material having a chemical formula CsXNYWO3-ZClC, characterized by being co-doped with elements of different groups in the periodic table, wherein Cs is cesium; N is tin (Sn) or antimony (Sb) or bismuth (Bi); W is tungsten; O is oxygen; and X, Y, Z, and C are positive numbers satisfying the following conditions: X?1.0, Y?1.0, Y/X?1.0, Z?0.6, and C?0.1; the transparent heat-shielding material is used to make a highly transparent and highly effective heat-shielding film which can be adhered to glass panels of buildings and automobiles to block infrared radiation in the wavelength range of 800-2000 nm, thereby insulating heat and saving energy; and the film is also applicable as a composite substrate for electronic components.Type: GrantFiled: January 22, 2013Date of Patent: November 18, 2014Assignee: Nan Ya Plastics CorporationInventors: Dein-Run Fung, Sen-Huang Hsu, Wei-Sheng Cheng
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Patent number: 8828511Abstract: The invention relates to a hollow glass article having, for a thickness of 5 mm, an overall light transmission greater than or equal to 70%, said overall light transmission being calculated by taking into consideration the illuminant C as defined by the ISO/CIE 10526 standard and the CIE 1931 standard colorimetric observer as defined by the ISO/CIE 10527 standard, and a filtering power greater than or equal to 65%, especially 70%, said filtering power being defined as being equal to the value of 100% reduced by the arithmetic mean of the transmission between 330 and 450 nm, said article having a chemical composition of soda-lime-silica type, which comprises the following optical absorbent agents in a content that varies within the weight limits defined below: Fe2O3 (total iron) 0.01 to 0.15% TiO2 0.5 to 3% Sulfides (S2?) 0.0010 to 0.0050%.Type: GrantFiled: June 12, 2009Date of Patent: September 9, 2014Assignee: Saint-Gobain EmballageInventor: Neill McDonald
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Patent number: 8647539Abstract: The present invention provides a process for producing a near infrared cut filter glass by melting and forming a glass material blended; and from 0.1 to 5% as represented by mass percentage of an oxidant of at least of a nitrate compound, a sulfate compound, a peroxide, a perchlorate and chloric acid as well as a near infrared cut filter glass.Type: GrantFiled: September 14, 2012Date of Patent: February 11, 2014Assignee: Asahi Glass Company, LimitedInventor: Hidetoshi Suzuki
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Patent number: 7751123Abstract: The refractive, transmissive or diffractive optical elements are made from a ceramic containing one or more oxides of the type X2O3, which is transmissive for visible light and/or for infrared radiation and which has a cubic crystal structure analogous to that of Y2O3. In preferred embodiments X is Y, Sc, In, or a lanthanide element, namely La to Lu, and in particular is Lu, Yb, Gd, or La. Also mixtures of oxides of the type X2O3 with oxides having different stoichiometries, such as HfO2 and/or ZrO2, may be present, as long as the cubic structure of the ceramic is maintained.Type: GrantFiled: June 13, 2007Date of Patent: July 6, 2010Assignee: Schott AGInventors: Jose Zimmer, Ulrich Peuchert, Jochen Alkemper, Martin Letz, Steffen Reichel, Yoshio Okano, Yvonne Menke
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Patent number: 7553432Abstract: The present invention provides an infrared absorbent having a light absorption peak in the infrared region and a crystallinity of 20 to 80%, an electrophotographic toner including the infrared absorbent, and an image forming apparatus having an electrophotographic image forming unit for forming a toner image on a recording medium with the electrophotographic toner and a fixing unit for fixing the toner image on the recording medium.Type: GrantFiled: February 22, 2005Date of Patent: June 30, 2009Assignee: Fuji Xerox Co., LtdInventor: Yasushige Nakamura
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Patent number: 7547652Abstract: The invention relates to vitreous compositions, in particular of the vitroceramic type, transparent to infrared, production and uses thereof. Said compositions comprise in mol. %: Ge 5-40, Ga<1, S+Se 40-85, Sb+As 4-40, MX 2-25, Ln 0-6, adjuncts 0-30, where M=at least one alkaline metal, selected from Rb, Cs, Na, K and Zn, X=at least one atom of chlorine, bromine or iodine, Ln=at least one rare earth and adjunct=at least one additive comprising at least one metal and/or at least one metal salt with the sum of all molar percentages of the components present in said composition being 100.Type: GrantFiled: July 5, 2004Date of Patent: June 16, 2009Assignees: Centre National De La Recherche Scientifique, Universite Rennes 1Inventors: Xianghua Zhang, Jacques Lucas, Hongli Ma, Jean-Luc Adam
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Patent number: 7510585Abstract: Amorphous materials, glass-ceramics and methods of making the same. Embodiments of the invention include abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.Type: GrantFiled: August 2, 2002Date of Patent: March 31, 2009Assignee: 3M Innovative Properties CompanyInventor: Anatoly Z. Rosenflanz
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Patent number: 7393802Abstract: An ultraviolet/infrared absorbent low transmittance glass is formed of base glass containing 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; greater than 2.1 to less than or equal to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is 7 to 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O wherein a total amount of Na2O and K2O is 10 to 20 wt. %; and 0 to 5 wt. % B2O3, and colorants including 1.25 to 2.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.001 to 0.018 wt. % CoO; 0 to 0.0004 wt. % Se; and 0.028 to 0.2 wt. % NiO, wherein the glass has a turquoise blue or deep green color.Type: GrantFiled: March 16, 2004Date of Patent: July 1, 2008Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Yukihito Nagashima, Isamu Kuroda, Shigekazu Yoshii
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Patent number: 7341778Abstract: The present invention relates to a radio wave-transmitting, wavelength-selective plate, which is characterized in that a layer composed of Ag fine particles is formed and that the central portions of the Ag fine particles contain an alloy (Ag alloy) formed of Ag and a metal which forms a homogeneous solid solution with Ag (hereinafter referred to as a homogeneous solid solution metal).Type: GrantFiled: March 12, 2004Date of Patent: March 11, 2008Assignee: Central Glass Company, LimitedInventors: Hiroshi Nakashima, Masaaki Yonekura, Hideo Omoto, Motoh Asakura
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Patent number: 7325417Abstract: A glass having a visible transmission of no greater than 28% and low IR transmission, and employing a colorant portion: total iron (expressed as Fe2O3): 0.7 to 1.8% cobalt oxide (e.g., Co3O4): 0.001 to 1.0% titanium oxide (e.g., TiO2): 0.25 to 3.0% selenium (e.g., Se): 0 to 0.0020% chromium oxide (e.g., Cr2O3): 0 to 0.010%.Type: GrantFiled: July 5, 2005Date of Patent: February 5, 2008Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme
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Patent number: 7151065Abstract: A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cerium, cobalt and selenium is provided. The glass allows high visible transmission, and satisfactory IR and UV absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3): ?0.25 to 0.70% cerium oxide: ?0.01 to 1.0% selenium: 0.0001 to 0.05% cobalt oxide: 0.0001 to 0.05% titanium oxide: ???0 to 1.0% glass redox: >=0.30.Type: GrantFiled: July 21, 2003Date of Patent: December 19, 2006Assignee: Guardian Industries Corp.Inventors: Scott V. Thomsen, Richard Hulme, Leonid Landa, Ksenia A. Landa
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Patent number: 7094716Abstract: The present invention is a green soda-lime-silica glass composition. The composition comprises 68 to 75% SiO2, 10 to 18% Na2O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al2O3, and 0 to 5% K20, where CaO+MgO is 6 to 15% and Na2O+K20 is 10 to 20%, and colorants comprising: 0.3 to 0.8 wt. % total iron as Fe2O3 wherein the ratio of FeO/total Fe as Fe2O3 is 0.35 to 0.62; 0.05 to 0.5 wt. % manganese compound as MnO2; 0 to 0.1 wt. % titanium oxide as TiO2; and 0 to 1 wt. % cerium oxide as CeO2. The colored glass has the following spectral properties at 4.0 mm. thickness: 65 to 81% light transmittance using Illuminant A (LTA) and using Illuminant C has a dominant wavelength of 494 to 555 nanometers with an excitation purity of 2 to 9%.Type: GrantFiled: October 4, 2002Date of Patent: August 22, 2006Assignee: Automotive Components Holdings, LLCInventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 7033967Abstract: The invention relates to a coloured soda-lime glass of blue hue, containing more than 2 wt. % of MgO, more than 1.1 wt. % of Fe2O3, less than 0.53 wt. % of FeO and less than 0.13 wt. % of MnO2, and presenting under Illuminant A and for a glass thickness of 4 mm, a transmission factor (TLA4) higher than 15%, a selectivity (SE4) higher than 1.2 and a dominant wavelength (?D) and a purity of excitation (P) such that they are located in the CIE chromaticity co-ordinate diagram inside a triangle whereof the apices are defined by the point representing the illuminant source C and the points whereof the co-ordinates (?D, P) are (490,19) and (476,49) respectively. Said glass is particularly suitable for motor vehicle side windows, rear windows and sun roof.Type: GrantFiled: February 5, 2004Date of Patent: April 25, 2006Assignee: GlaverbelInventors: Marc Foguenne, Dominique Coster
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Patent number: 7015162Abstract: The invention relates to blue colored sodiocalcic glass. It contains 0.15 to 1.1 wt. % Fe2O3, has a redox that does not exceed 45%, exhibits a dominant wavelength (?D) in the range of 490 and 493 nm and a luminous transmission (TLA4) in addition to an excitation purity (P) satisfying the relation P>?0.3×TLA4+24.5. The inventive glass is particularly suitable for windscreens, side windows and rear-window defoggers in motor vehicles and glazing in buildings.Type: GrantFiled: February 10, 2004Date of Patent: March 21, 2006Assignee: GlaverbelInventors: Dominique Coster, Laurent Delmotte, Marc Foguenne
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Patent number: 6995102Abstract: A blue glass composition comprises a soda-lime-silica base and a colorant portion consisting essentially of about 0.4 to 0.65 weight percent total iron oxide, about 0.1 to 0.3 weight percent manganese oxide, and cobalt oxide in an amount effective to produce a cobalt concentration of about 0.0002 to 0.0013 weight percent (about 2 to 13 ppm). The glass is characterized by a ratio of ferrous oxide to total iron oxide between about 0.43 and 0.58. The glass composition exhibits a combination of high visible transmittance, high infrared absorption and enhanced blue coloration. This is attributed in large part to the combination of ferrous oxide and cobalt oxide and to the effect of manganese oxide in reducing iron sulfide formation and thereby avoiding amber coloration.Type: GrantFiled: July 16, 2003Date of Patent: February 7, 2006Assignee: Visteon Global Technologies, Inc.Inventors: James V. Jones, Edward N. Boulos
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Patent number: 6953759Abstract: A glass having a visible transmission of no greater than 28% and low IR transmission, and employing a colorant portion: total iron (expressed as Fe2O3): ?0.7 to 1.8% cobalt oxide (e.g., Co3O4): 0.001 to 1.0% titanium oxide (e.g., TiO2): ?0.25 to 3.0% selenium (e.g., Se): ???0 to 0.0020% chromium oxide (e.g., Cr2O3): ???0 to 0.010%.Type: GrantFiled: August 26, 2002Date of Patent: October 11, 2005Assignee: Guardian Industries Corp.Inventors: Ksenia A. Landa, Leonid Landa, Richard Hulme
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Patent number: 6897999Abstract: Two, three dimensional color displays having uniform dispersion of red, green and blue visible light emitting micron particles. Pumping at approximately 976 nm can generate green and red colors having an approximately 4% limit efficiency. One source can generate three colors with approximately limit efficiency. Modulators, scanners and lens can move and focus laser beams to different pixels forming two dimensional color images. Displays can be formed from near infrared source beams that are simultaneously split and modulated with micro electro mechanical systems, spatial light modulators, liquid crystal displays, digital micromirrors, digital light projectors, grating light valves, liquid crystal silicon devices, polysilicon LCDs, electron beam written SLMs, and electrically switchable bragg gratings. Pixels containing: Yb,Tm:YLF can emit blue light, Yb,Er(NYF) can emit green light, and Yb,Er:KYF and Yb,Ef:YF3 can emit red light.Type: GrantFiled: December 26, 2002Date of Patent: May 24, 2005Assignee: The Research Foundation of the University of Central FloridaInventors: Michael Bass, Jason Eichenholz, Alexandra Rapaport
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Patent number: 6821918Abstract: The present invention is a bronze and gray glass composition. The composition comprises 68 to 75% SiO2, 10 to 18% Na2O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al2O3, and 0 to 5% K2O, where CaO+MgO is 6 to 15% and Na2O+K2O is 10 to 20%, and colorants comprising: 0.22 to 0.39 wt. % total iron as Fe2O3 wherein the ratio of FeO/total Fe as Fe2O3 is 0.35 to 0.64; 0.1 to 0.5 wt. % manganese compound as MnO2; 0 to 1.2 wt. % cerium oxide as CeO2; and 2 to 10 ppm selenium, and 0 to 20 ppm cobalt as cobalt oxide. The colored glass has the following spectral properties at 4.0 mm. thickness: 65 to 78% light transmittance using Illuminant A (LTA) and using Illuminant C has a dominant wavelength of 493 to 577 nanometers with an excitation purity up to 7%.Type: GrantFiled: November 21, 2002Date of Patent: November 23, 2004Assignee: Visteon Global Technologies, Inc.Inventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 6800575Abstract: The invention concerns a coloured soda-lime glass deep coloured with a green-to-blue shade. It contains 0.40 to 0.52 wt. % of FeO, present under illuminant A and for a glass thickness of 4 mm, a light transmittance (TLA4) less than 70%, a selectivity (SE4) higher than 1.65 and an ultraviolet radiation transmittance (TUV4) less than 8%. Said glass is particularly suited for lateral rear glazing and rear glazing for motor vehicles.Type: GrantFiled: March 26, 2001Date of Patent: October 5, 2004Assignee: Glaverbel, S.A.Inventors: Dominique Coster, Marc Foguenne
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Patent number: 6762875Abstract: A method for creating refractive index changes in a substrate is provided by irradiating the substrate with infrared (IR) or visible light radiation. Ultra-violet (UV) radiation is generated in the substrate responsive to the IR or visible light radiation such that the change in the refractive index of the substrate is generated responsive to the UV radiation. Preferably, the substrate comprises a glass doped with rare earth ions.Type: GrantFiled: February 7, 2002Date of Patent: July 13, 2004Assignee: Corning IncorporatedInventor: Bryce N. Samson
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Patent number: 6656862Abstract: The present invention provides a blue colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. The glass uses a standard soda-lime-silica glass base composition and additionally iron and cobalt, and optionally selenium and/or titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a color characterized by a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). In one embodiment of the invention, the glass composition of a blue colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a solar radiation absorbing and colorant portion consisting essentially of 0.9 to 2.0 percent by weight total iron, 0.15 to 0.65 percent by weight FeO, 90 to 250 PPM CoO, and optionally up to 12 PPM Se and up to 0.9 wt % TiO2, and preferably 1 to 1.Type: GrantFiled: May 12, 1998Date of Patent: December 2, 2003Assignee: PPG Industries Ohio, Inc.Inventors: John F. Krumwiede, Larry J. Shelestak
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Patent number: 6654161Abstract: A two and three dimensional display based on up conversion of near infrared light to the visible. The display medium is a transparent polymer containing particles of crystals doped with Yb3+ and other rare earth ions. The Yb3+ ions absorb light from a commercially available diode laser emitting near 975 nm and transfer that energy to the other dopant ions. Using a fluoride crystal host, NaYF4, co-doped with Tm3+ ions we obtain blue light at ˜480 nm, with Ho3+ or Er3+ ions we obtain green light at ˜550 nm and with Er3+ we obtain red light at ˜660 nm. The display medium is also used with a preferred component layout with experimentation test data, along with applications for full color, high brightness, high resolution, displays.Type: GrantFiled: July 31, 2001Date of Patent: November 25, 2003Assignee: University of Central FloridaInventors: Michael Bass, Alexandra Rapaport, Hans Jennsen
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Patent number: 6612133Abstract: A method for shifting the absorption peak wavelength in the wavelength range 900-1600 nm of an infrared radiation absorbing glass from less than 1100 nm to 1100 nm or longer without substantially changing the tint of the glass, comprising the step of irradiating with ultraviolet light of 400 nm or shorter at an energy density of 1.0×106 J/m2/hr or more to increase the content of FeO in the irradiated glass by reducing Fe (III) to Fe (II), the ultraviolet light irradiated glass thereby comprising 0.02 wt. % or more FeO in terms of Fe2O3. The glass to be irradiated comprises, in % by weight: 65 to 80% SiO2, 0 to 5% Al2O3, 0 to 10% MgO, 5 to 15% CaO, 10 to 18% Na2O, 0 to 5% K2O, 5 to 15% MgO+CaO, 10 to 20% Na2O+K2O, and 0 to 5% B2O3; 0.02% or more total iron oxide (T-Fe2O3) in terms of Fe2O3, 0 to 2.0% CeO2, 0 to 1.0% TiO2, 0 to 0.005% CoO, and 0 to 0.005% Se.Type: GrantFiled: February 26, 2001Date of Patent: September 2, 2003Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Koichi Sakaguchi, Hiromitsu Seto, Yukihito Nagashima
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Publication number: 20030130105Abstract: The present invention provides for a new improved green privacy glass. In accordance with the teachings of the present invention, the iron is oxidized with the help of inexpensive manganese oxide. No chromium, cerium nor titanium oxides are added to obtain the desired green color. The glass has a % UV less than 13% at 4.0 MM. This low UV absorption could eliminate the need for a black band in glass to prevent the fading of the color in glass.Type: ApplicationFiled: October 3, 2001Publication date: July 10, 2003Inventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 6524713Abstract: The ultraviolet/infrared absorbent low transmittance glass has an almost neutral color such as greenish gray, low visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a rear window of a vehicle and capable of protecting privacy. The glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is between 5 and 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O wherein a total amount of Na2O and K2O is between 10 and 20 wt. %; and 0 to 5 wt. % B2O3, and colorants including: 1.25 to 1.5 wt. % total iron oxide (T—Fe2O3) expressed as Fe2O3; 0.01 to 0.019 wt. % CoO; more than 0.0008 wt. % and equal to or less than 0.003 wt. % Se; and 0.055 to 0.1 wt. % NiO.Type: GrantFiled: June 21, 2001Date of Patent: February 25, 2003Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
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Publication number: 20020198094Abstract: The present invention provides a blue colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. This glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles. The glass uses a standard soda-lime-silica glass base composition and additionally iron and cobalt, and optionally selenium and/or titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a color characterized by a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). In one embodiment of such a blue colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a solar radiation absorbing and colorant portion having 0.9 to 2.0 percent by weight total iron, 0.15 to 0.Type: ApplicationFiled: January 14, 2002Publication date: December 26, 2002Inventors: Mehran Arbab, Larry J. Shelestak, Dennis G. Smith
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Patent number: 6455452Abstract: The present invention provides a bronze colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. The glass uses a standard soda-lime-silica glass base composition and additionally iron and selenium, and optionally cobalt, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a luminous transmittance (LTA) of up to 60 percent and its color is characterized by a dominant wavelength in the range of 560 to 590 nanometers and an excitation purity of 12 to 75% at a thickness of 0.160 inches (4.06 mm). In one embodiment of the invention, the glass composition of a bronze colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a colorant portion having 0.7 to 2.2 percent by weight total iron, 0.15 to 0.5 percent by weight FeO, 3 to 100 PPM Se, and optionally up to 200 PPM CoO, and preferably 1.1 to 1.4 percent by weight total iron, 0.24 to 0.Type: GrantFiled: February 22, 2000Date of Patent: September 24, 2002Assignee: PPG Industries Ohio, Inc.Inventor: John F. Krumwiede
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Patent number: 6416867Abstract: A reduced glare window glass, suitable for use in glass window, containing Neodymium Oxide, a rare earth compound. The Neodymium Oxide filters out the yellow light of the spectrum, thereby providing improved vision. Incorporation of yellow light in the light spectrum desaturates colors and reduces contrast. Improvement in contrast and a reduction in glare permits, for example, one to use this window glass in a building to reduce glare without the expense of blinds or curtains that are normally used to reduce glare. Additionally, the light transmittance is kept high, as high as 61.81 percent with a Neodymium Oxide doping of the glass in the amount of at least 0.0244 grams per square centimeter. This glass can be used for multiple layers of glass in assembled glazing.Type: GrantFiled: October 16, 2000Date of Patent: July 9, 2002Inventor: Daniel Nathan Karpen
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Patent number: 6413893Abstract: The present invention provides a green colored, infrared and ultraviolet absorbing glass article having a luminous transmittance of up to 60 percent. The composition of the glass article uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, selenium, and chromium, and titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glasses of the present invention have a color characterized by a dominant wavelength in the range of about 480 to 565 nanometers, preferably about 495 to 560 nanometers, with an excitation purity of no higher than about 20 percent, preferably no higher than about 10 percent, and more preferably no higher than about 7 percent. The glass compositions may be provided with different levels of spectral performance depending on the particular application and desired luminous transmittance.Type: GrantFiled: September 3, 1999Date of Patent: July 2, 2002Assignee: PPG Industries Ohio, Inc.Inventors: Larry J. Shelestak, Robert B. Heithoff, Andrew Calabrese, John F. Krumwiede, Anthony V. Longobardo
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Patent number: 6408650Abstract: The invention is a method of retaining selenium in a lass containing selenium by including a manganese compound and not including nitrates or nitrites routinely used in the industry to retain selenium. Particularly, a preferred embodiment involves manufacturing a gray soda-lime-silica glass composition including selenium as a colorant, the components of the gray soda-lime-silica glass have colorants consisting essentially of: greater than 0.9 to 1.9 wt. % total iron oxide as Fe2O3; 0.10 to 1.00 wt. % manganese compound as MnO2; 0.0010 to 0.0060 wt. % selenium as Se; 0.002 to 0.025 wt. % cobalt oxide as Co, and 0 to 1.0 wt. % titanium oxide as TiO2 which are combined and melted to make the glass composition. The glass composition has at 4.0 mm. thickness: 10 to 55% light transmittance using Illuminant A, less than 25% ultra violet transmittance, and less than 50% infra red transmittance.Type: GrantFiled: December 10, 1997Date of Patent: June 25, 2002Assignee: Ford Global Technologies, Inc.Inventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 6395660Abstract: An ultraviolet/infrared absorbent low transmittance glass consists of base glass, and colorants. The base glass comprises 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; greater than 2 to less than or equal to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is 7 to 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O wherein a total amount of Na2O and K2O is 10 to 20 wt. %; and 0 to 5 wt. % B2O3. The colorants without Se is formed of 1.25 to 2.2 wt. % total iron oxide (T—Fe2O3) expressed as Fe2O3; 0.001 to 0.03 wt. % CoO; and 0.003 to 0.2 wt. % NiO. The glass has a turquoise blue or deep green color, and exhibits low or middle visible light transmittance, low total solar energy transmittance and low ultraviolet transmittance.Type: GrantFiled: March 14, 2000Date of Patent: May 28, 2002Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Yukihito Nagashima, Isamu Kuroda, Shigekazu Yoshii
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Patent number: 6333287Abstract: A colored glass is disclosed in which the generation of nickel sulfide stones has been eliminated or diminished without impairing glass appearance or productivity. The colored glass contains, in % by weight, 0.5-4% total iron oxide (T-Fe2O3) in terms of Fe2O3 and 0.0002 to less than 0.01% molybdenum in terms of Mo.Type: GrantFiled: May 18, 2000Date of Patent: December 25, 2001Assignee: Nippon Sheet Glass Co., Ltd.Inventor: Hiromitsu Seto
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Patent number: 6313053Abstract: The present invention provides a blue colored glass using a standard soda-lime-silica glass base composition and additionally iron and cobalt, and optionally chromium, as solar radiation absorbing materials and colorants. In particular, the blue colored glass includes about 0.40 to 1.0 wt. % total iron, preferably about 0.50 to 0.75 wt. %, about 4 to 40 PPM CoO, preferably about 4 to 20 PPM, and 0 to 100 PPM Cr2O3. The redox ratio for the glass of the present invention is greater than 0.35 up to about 0.60, and preferably between about 0.36 to 0.50. In one particular embodiment of the invention, the glass has a luminous transmittance of at least 55% and a color characterized by a dominant wavelength of 485 to 489 nanometers and an excitation purity of about 3 to 18 percent. In another embodiment of the invention, the glass has a luminous transmittance of at least 65% at a thickness of about 0.154 inches (3.Type: GrantFiled: April 9, 1998Date of Patent: November 6, 2001Assignee: PPG Industries Ohio, Inc.Inventor: Larry J. Shelestak
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Publication number: 20010025004Abstract: The ultraviolet/infrared absorbent low transmittance glass has a grayish green color shade, low visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a rear window of a vehicle and capable of protecting privacy. The glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is between 5 and 15 wt. %; 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O wherein a total amount of Na2O and K2O is between 10 and 20 wt. %; and 0 to 5 wt. % B2O3, and colorants including: more than 0.95 wt. % and 1.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; 0.001 to 0.0180 wt. % CoO; 0.0001 to 0.0008 wt. % Se; and 0.003 to 0.2 wt. % NiO.Type: ApplicationFiled: March 27, 2001Publication date: September 27, 2001Applicant: NIPPON SHEET GLASS CO., LTDInventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
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Patent number: 6277775Abstract: A GeAs sulphide glass family of transparent glasses having transmission far into the infrared portion of the spectrum, containing a source of phosphorus ion as a co-dopant to effect dispersion of a rare earth metal ion dopant in the glass, an optical component comprising the glass, and a method of dispersing a rare earth metal ion in the glass.Type: GrantFiled: January 25, 2000Date of Patent: August 21, 2001Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Patent number: 6258740Abstract: The invention relates to an ultraviolet ray absorbing soda-lime glass. This glass contains less than 0.10 wt % of iron in terms of Fe2O3, which is optionally contained as an impurity in the glass, 0.7-2.6 wt % of CeO2, 0-1.3 wt % of TiO2, 0-0.12 wt % of V2O5, 0.08-0.30 wt % of sulfur in terms of SO3, and 0-0.0025 wt % of CoO. The glass at a thickness of 5 mm is not higher than 10% in ultraviolet radiation transmittance, is not lower than 80% in visible light transmittance, and is from 530 to 575 nm in dominant wavelength. The glass is transparent and clear, superior in ultraviolet ray absorption capability, and high in visible light transmittance.Type: GrantFiled: July 29, 1999Date of Patent: July 10, 2001Assignee: Central Glass Company, LimitedInventors: Hiroshi Machishita, Kazutoshi Nakaya
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Patent number: 6255238Abstract: The object of the present invention is brown solar glasses, absorbing UV or IR radiation, as well as solar ophthalmic lenses in said glasses. Said glasses have the following composition, expressed in percentages by weight: SiO2: 64-71; B2O3: 2-8; Al2O3: 0-4; ZrO2: 0-2; Li2O: 0-4; Na2O: 6-10; K2O: 7-16; CaO: 0-5.5; ZnO: 0-5.5; TiO2; 0-2; Fe2O3: 3-9; Co3O4: 0-0.030; NiO: 0-0.2; SeO2: 0.0030-0.1; As2O3: 0-0.1; Sb2O3: 0-0.1; SnO2: 0-0.1; Cl: 0-2; Br: 0-2; F: 0-2.Type: GrantFiled: February 7, 2000Date of Patent: July 3, 2001Assignee: Corning S.A.Inventor: Yves A. H. Brocheton
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Patent number: 6225244Abstract: A glass for a near infrared absorption filter, which has spectral characteristics that it efficiently transmits light in a wavelength region of from ultraviolet region to 600 nm and selectively absorbs light in a near infrared region of a wavelength of larger than about 600 nm, a near infrared absorption filter formed of the above glass, and a solid-state image sensing device to which the above filter is applied, the glass comprising, by cationic %, 35 to 54% of P, 20 to 47% of Zn, 0 to 8% of the total, R, of Li, Na, K and Cs which are monovalent metal elements, 0 to 17% of the total, M, of Mg, Ca, Ba, Sr and Pb which are divalent metal elements, the total of R and M being 1 to 22%, 0.1 to 7% of As, 0.2 to 9% of Cu and 0 to 6% of Al.Type: GrantFiled: January 20, 1999Date of Patent: May 1, 2001Assignee: Hoya CorporationInventor: Hironori Oguma
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Patent number: 6207284Abstract: Silicate based glass compositions with nitrogen compounds are included in the composition as performance modifiers to impart desirable color and improved energy absorbance properties. The nitrogen compound is, generally, a metal nitride which is added to the batch glass composition in amounts greater than 0.05 weight percent prior to melting the composition and method resulting in a finished glass suitable for use in architectural and automotive glazings.Type: GrantFiled: October 20, 1998Date of Patent: March 27, 2001Assignee: Libben-Owens-Ford Co.Inventors: Srikanth Varanasi, Paige L. Higby, Gwendolyn A. Young
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Patent number: 6181469Abstract: In a method for evaluating the homogeneity of the refractive index of an optical member, the refractive index distribution of the optical member is measured, the measured refractive index distribution is separated into a rotationally symmetric element and a non-rotationally symmetric element in the optical axis direction before or after correction of the power element, and the rotationally symmetric element is further subjected to 2nd/4th-order element correction. Upon execution of such comprehensive evaluation, a photolithography optical member, which can realize a fine, sharp exposure-transfer pattern (e.g., a line width of 0.3 &mgr;m or less) is provided.Type: GrantFiled: November 30, 1999Date of Patent: January 30, 2001Assignee: Nikon CorporationInventors: Hiroyuki Hiraiwa, Issey Tanaka, Katsuya Miyoshi
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Patent number: 6177372Abstract: A heavy metal fluoride glass composition range (in mol percent) consisting essentially of: (16-30)BaF2.(8-26)HfF4.(6-24)InF3 or GaF3.(4-16)CdF2.(6-24)YbF3.(4-22)ZnF2. In an alternative embodiment, a heavy metal fluoride glass composition range (in mol percent) comprises (16-30)BaF2.(8-26)HfF4.(6-24) of (0-24)InF3, (0-24)GaF3 and (0-19)AlF3.(1-16)CdF2.(6-24)YbF3.(4-26)ZnF2. A preferred heavy metal fluoride glass produced in accordance with the present invention comprises a composition (in mol %) and comprises about 26BaF2.18HfF4.7InF3.5GaF3.10CdF2.18YbF3.16ZnF2. A preferred heavy metal fluoride glass has maximum thickness of most preferably about 3 mm. Another preferred heavy metal fluoride glass comprises a composition (in mol %) and comprises about 26BaF2.18HfF4.12AlF3.10CdF2.18YbF3.16ZnF2.Type: GrantFiled: September 26, 1997Date of Patent: January 23, 2001Assignee: Iowa State University Research Foundation, Inc.Inventors: Steven W. Martin, Jesse Huebsch
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Patent number: 6170292Abstract: The invention is a medium color gray soda-lime-silica glass composition having excellent ultra violet and infra red absorbing ability. The colorants of the glass composition consist essentially of: greater than 0.5 but less than 0.9 wt. % total iron oxide as Fe2O3; 0.1 to 1.0 wt. % manganese compound as MnO2; 0.0005 to 0.003 wt. % selenium as Se; 0.002 to 0.010 wt. % cobalt oxide as Co; up to 1.0 TiO2; the glass composition having, at 4.0 mm. thickness: 485-570 dominant wavelength, less than 5% purity of excitation, 35 to 60% light transmittance using Illuminant A, less than 40% ultra violet transmittance measured over 300-400 nm, and less than 45% infra red transmittance measured over 760-2120 nm.Type: GrantFiled: July 29, 1999Date of Patent: January 9, 2001Assignee: Visteon Global Technologies, Inc.Inventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 6165924Abstract: The invention relates to a package for foods on the basis of green colored, ultraviolet radiation absorbing soda-lime glass that is permeable to visible light and has a dominant wavelength of 500 to 575 nm, which glass, as compared with the weight of the glass, contains at least 1.5% by weight of iron, calculated as Fe.sub.2 O.sub.3, and at least 0.10% by weight of chromium, calculated as Cr.sub.2 O.sub.3.Type: GrantFiled: January 29, 1998Date of Patent: December 26, 2000Assignee: Heineken Technical Services B.V.Inventors: Adrianus Smout, Gerrit Jan Loggers
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Patent number: 6117804Abstract: A process of making a mineral powder usable for manufacturing functional fiber includes pulverizing mineral ingredients including germanium of 60 weight percent, biostrome of 20 weight percent, jade of 10 weight percent, anorthite of 5 weight percent and minerals of 5 weight percent to about 100 mesh and charging the mineral ingredients into an internal furnace of copper having a wall thickness of 2-5 mm; placing feldspar pulverized to about 325 mesh between an inner surface of an electric heating plate and an outer surface of the internal furnace; heating the mineral ingredients and feldspar for seven days at about 1000.degree. C. by means of the electric heating plate; pulverizing the mineral ingredients having had thermal deformation from the internal furnace again to more than about 325 mesh; placing the pulverized mineral ingredients into the internal furnace again; charging the internal furnace with the burnt feldspar; again heating the mineral ingredients for three days at 1000.degree. C.Type: GrantFiled: April 29, 1997Date of Patent: September 12, 2000Assignee: Han IL Mulsan Co., Ltd.Inventor: Eung-Hwa Cho
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Patent number: 6103650Abstract: The present invention provides a green colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. The glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, chromium, and titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a color characterized by a dominant wavelength in the range of about 480 to 510 nanometers, preferably about 490 to 525 nanometers, with an excitation purity of no higher than about 20%, preferably about 5 to 15%. In one embodiment of the invention, the glass composition of a green colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a solar radiation absorbing and colorant portion consisting essentially of about 0.90 to 2.0 percent by weight total iron, about 0.17 to 0.52 percent by weight FeO, about 40 to 150 PPM CoO, about 250 to 800 PPM Cr.sub.2 O.sub.3, and about 0.Type: GrantFiled: November 28, 1997Date of Patent: August 15, 2000Assignee: PPG Industries Ohio, Inc.Inventor: John F. Krumwiede
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Patent number: 6080695Abstract: A neutral gray soda-lime-silica glass having a low light transmission (less than 20%), which reduces the transmission of solar energy, such as the transmission of near infrared radiation (less than 14%) and, in a greater degree, the transmission of ultraviolet radiation (less than 12%), comprising the following components in weight percentage:______________________________________ Fe.sub.2 O.sub.3 from 1.20 to 2.0% FeO from 18 to 28% (Reduction Percentage). Co.sub.3 O.sub.4 from 0.020 to 0.030% Se from 0.0025 to 0.010% CuO from 0.0050 to 0.050% ______________________________________This glass avoids the use of the coloring compounds such as the nickel, chromium and manganese.Type: GrantFiled: December 2, 1997Date of Patent: June 27, 2000Assignee: Vidrio Plano De Mexico, S.A. De C.V.Inventors: Herbert Scheffler-Hudlet, Roberto-Marcos Cabrera-Llanos, Jose-Guadalupe Cid-Aguilar, Rafael-Enrique Pinto-Negroe
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Patent number: 6074968Abstract: Chalcogenide glass fibers having a glass core with two cladding glass layers, the second cladding glass layer having a refractive index lower than that of the core glass and higher than that of the first cladding glass. The core glass does not contain germanium. Glass fiber having this core-cladding structure is mechanically strong and exhibits only small transmission loss of infrared light passing through the fiber.Type: GrantFiled: May 25, 1999Date of Patent: June 13, 2000Assignees: Hoya Corporation, Nippon Sheet Glass Company LimitedInventors: Yoshitaka Yoneda, Shozo Morimoto, Toshiharu Yamashita
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Patent number: RE37514Abstract: A dark gray colored glass comprising 100 parts by weight of a soda lime silicate glass as a matrix component and coloring components consisting essentially of from 0.8 to 1.5 parts by weight of total iron calculated as Fe2O3, from 0.1 to 0.3 part by weight of FeO, from 0 to 1.0 part by weight of TiO2, from 0.0005 to 0.015 part by weight of Se, from 0.02 to 0.05 part be weight of CoO and from 0.002 to 0.05 part by weight of Cr2O3.Type: GrantFiled: June 13, 2000Date of Patent: January 15, 2002Assignee: Asahi Glass Company Ltd.Inventors: Mizuki Sasage, Takashi Kijima
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Patent number: RE37998Abstract: The invention relates to a colored glass composition for producing glazings for use, e.g., as automobile sunroofs. The colored glass according to the invention is a soda-lime-silica glass comprising, as coloring agents, 1.4 to 4% iron oxide expressed as Fe2O3 and 0 to 0.05 % cobalt oxide, with the cobalt oxide exceeding about 0.02% when the Fe2O3 is below about 2% and, optionally, selenium and chromium oxide, whereby the sum of the CoO+Se+Cr2O3 is preferably less than about 0.24% by weight. The glass of the invention has a total light transmission factor under illuminant A equal to or below approximately 20% and a total energy transmission factor equal to or below approximately 12% for a thickness of 3.85 mm.Type: GrantFiled: September 27, 1996Date of Patent: February 18, 2003Assignee: Saint-Gobain VitrageInventors: Pierre Combes, Jean-Jacques Massol, Pedro Casariego Alvarez
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Patent number: RE42184Abstract: Two, three dimensional color displays having uniform dispersion of red, green and blue visible light emitting micron particles. Pumping at approximately 976 nm can generate green and red colors having an approximately 4% limit efficiency. One source can generate three colors with approximately limit efficiency. Modulators, scanners and lens can move and focus laser beams to different pixels forming two dimensional color images. Displays can be formed from near infrared source beams that are simultaneously split and modulated with micro electro mechanical systems, spatial light modulators, liquid crystal displays, digital micromirrors, digital light projectors, grating light valves, liquid crystal silicon devices, polysilicon LCDs, electron beam written SLMs, and electrically switchable bragg gratings. Pixels containing: Yb,Tm:YLF can emit blue light, Yb,Er(NYF) can emit green light, and Yb,Er:KYF and Yb,Ef:YF3 can emit red light.Type: GrantFiled: May 23, 2007Date of Patent: March 1, 2011Assignee: Research Foundation of the University of Central Florida, Inc.Inventors: Michael Bass, Jason Eichenholz, Alexandra Rapaport