Ultraviolet Transmitting Or Absorbing Patents (Class 501/905)
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Patent number: 6177372Abstract: A heavy metal fluoride glass composition range (in mol percent) consisting essentially of: (16-30)BaF2.(8-26)HfF4.(6-24)InF3 or GaF3.(4-16)CdF2.(6-24)YbF3.(4-22)ZnF2. In an alternative embodiment, a heavy metal fluoride glass composition range (in mol percent) comprises (16-30)BaF2.(8-26)HfF4.(6-24) of (0-24)InF3, (0-24)GaF3 and (0-19)AlF3.(1-16)CdF2.(6-24)YbF3.(4-26)ZnF2. A preferred heavy metal fluoride glass produced in accordance with the present invention comprises a composition (in mol %) and comprises about 26BaF2.18HfF4.7InF3.5GaF3.10CdF2.18YbF3.16ZnF2. A preferred heavy metal fluoride glass has maximum thickness of most preferably about 3 mm. Another preferred heavy metal fluoride glass comprises a composition (in mol %) and comprises about 26BaF2.18HfF4.12AlF3.10CdF2.18YbF3.16ZnF2.Type: GrantFiled: September 26, 1997Date of Patent: January 23, 2001Assignee: Iowa State University Research Foundation, Inc.Inventors: Steven W. Martin, Jesse Huebsch
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Patent number: 6170292Abstract: The invention is a medium color gray soda-lime-silica glass composition having excellent ultra violet and infra red absorbing ability. The colorants of the glass composition consist essentially of: greater than 0.5 but less than 0.9 wt. % total iron oxide as Fe2O3; 0.1 to 1.0 wt. % manganese compound as MnO2; 0.0005 to 0.003 wt. % selenium as Se; 0.002 to 0.010 wt. % cobalt oxide as Co; up to 1.0 TiO2; the glass composition having, at 4.0 mm. thickness: 485-570 dominant wavelength, less than 5% purity of excitation, 35 to 60% light transmittance using Illuminant A, less than 40% ultra violet transmittance measured over 300-400 nm, and less than 45% infra red transmittance measured over 760-2120 nm.Type: GrantFiled: July 29, 1999Date of Patent: January 9, 2001Assignee: Visteon Global Technologies, Inc.Inventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 6165924Abstract: The invention relates to a package for foods on the basis of green colored, ultraviolet radiation absorbing soda-lime glass that is permeable to visible light and has a dominant wavelength of 500 to 575 nm, which glass, as compared with the weight of the glass, contains at least 1.5% by weight of iron, calculated as Fe.sub.2 O.sub.3, and at least 0.10% by weight of chromium, calculated as Cr.sub.2 O.sub.3.Type: GrantFiled: January 29, 1998Date of Patent: December 26, 2000Assignee: Heineken Technical Services B.V.Inventors: Adrianus Smout, Gerrit Jan Loggers
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Patent number: 6156388Abstract: A method of manufacturing a substrate coated with a transparent, colored coating stable to high temperature and UV includes coating the substrate with a coating composition including at least one element which is able to form a vitreous, crystalline, or partially crystalline oxide, in the form of a compound which on heat treatment yields the oxide and is present as a sol or solution in an at least predominantly aqueous medium, as the matrix-forming component, and at least one member selected from the group consisting of metal colloids, metal compound colloids, metal alloy colloids, and metal compounds which form metal colloids under reducing conditions, as the coloring component; and heat-curing the resulting coating. Particularly suitable substrates are glass substrates, such as (halogen) lamp bulbs and gas discharge tubes.Type: GrantFiled: April 26, 1999Date of Patent: December 5, 2000Assignee: Institut fuer neue Materialen gemeinnuetzige GmbHInventors: Klaus Endres, Marion Lindenstruth, Martin Mennig, Matthias Pietsch, Helmut Schmidt
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Patent number: 6153127Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.Type: GrantFiled: December 21, 1998Date of Patent: November 28, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Koichiro Nakamura, Koichi Maeda
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Patent number: 6124038Abstract: The invention relates to a strong UV absorbing glass consisting essentially of, expressed in cation percent, 15-30% SiO.sub.2, 50-60% B.sub.2 O.sub.3, 2-5% Al.sub.2 O.sub.3, 0-6% Li.sub.2 O, 0-3.0% Na.sub.2 O, 14-20% K.sub.2 O, 0.5-1.0% CuO, 0.4-0.7% SnO.sub.2, 0.5-1.5% Cl, and 0.7-1.5% Br. An essentially haze-free version of the glass is disclosed. A UV absorbing coating material made by suspending ground particles of the inventive glass in a suitable matrix is also disclosed.Type: GrantFiled: August 7, 1998Date of Patent: September 26, 2000Assignee: Corning IncorporatedInventor: Roger J. Araujo
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Patent number: 6114264Abstract: The present invention provides a glass composition having a neutral gray color and a luminous (visible) transmittance within a range that allows the glass to be used in the forward vision areas of a vehicle. The base glass is a soda-lime-silica composition and iron, cobalt, selenium and/or nickel are added as colorants. In one particular embodiment of the invention which is essentially nickel-free, a neutral gray colored glass with a luminous transmittance (C.I.E. illuminant A) of 60% and higher at a thickness of 3.9 millimeters may be attained by using as colorants: 0.30 to 0.70 wt. % Fe.sub.2 O.sub.3, no greater than 0.21 wt. % FeO, 3-50 PPM CoO and 1-15 PPM Se, and preferably 0.32 to 0.65 wt. % Fe.sub.2 O.sub.3, 0.065 to 0.20 wt. % FeO, 5 to 40 PPM CoO and 1 to 9 PPM Se. In an alternate embodiment of the invention which includes nickel oxide as a colorant, a neutral gray colored glass with a luminous transmittance of 60% and higher at a thickness of 3.9 millimeters may be attained by using 0.15 to 0.65 wt.Type: GrantFiled: March 31, 1995Date of Patent: September 5, 2000Assignee: PPG Industries Ohio, Inc.Inventors: John F. Krumwiede, Anthony V. Longobardo, Larry J. Shelestak
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Patent number: 6103650Abstract: The present invention provides a green colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent. The glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, chromium, and titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glass of the present invention has a color characterized by a dominant wavelength in the range of about 480 to 510 nanometers, preferably about 490 to 525 nanometers, with an excitation purity of no higher than about 20%, preferably about 5 to 15%. In one embodiment of the invention, the glass composition of a green colored, infrared and ultraviolet radiation absorbing soda-lime-silica glass article includes a solar radiation absorbing and colorant portion consisting essentially of about 0.90 to 2.0 percent by weight total iron, about 0.17 to 0.52 percent by weight FeO, about 40 to 150 PPM CoO, about 250 to 800 PPM Cr.sub.2 O.sub.3, and about 0.Type: GrantFiled: November 28, 1997Date of Patent: August 15, 2000Assignee: PPG Industries Ohio, Inc.Inventor: John F. Krumwiede
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Patent number: 6080695Abstract: A neutral gray soda-lime-silica glass having a low light transmission (less than 20%), which reduces the transmission of solar energy, such as the transmission of near infrared radiation (less than 14%) and, in a greater degree, the transmission of ultraviolet radiation (less than 12%), comprising the following components in weight percentage:______________________________________ Fe.sub.2 O.sub.3 from 1.20 to 2.0% FeO from 18 to 28% (Reduction Percentage). Co.sub.3 O.sub.4 from 0.020 to 0.030% Se from 0.0025 to 0.010% CuO from 0.0050 to 0.050% ______________________________________This glass avoids the use of the coloring compounds such as the nickel, chromium and manganese.Type: GrantFiled: December 2, 1997Date of Patent: June 27, 2000Assignee: Vidrio Plano De Mexico, S.A. De C.V.Inventors: Herbert Scheffler-Hudlet, Roberto-Marcos Cabrera-Llanos, Jose-Guadalupe Cid-Aguilar, Rafael-Enrique Pinto-Negroe
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Patent number: 6071840Abstract: A dark green colored glass comprising 100 parts by weight of a matrix component of soda lime silicate glass, and, as coloring components, from 0.5 to 2.0 parts by weight of total iron calculated as Fe.sub.2 O.sub.3, more than 1.0 to 3.0 parts by weight of total titanium calculated as TiO.sub.2, from 0.003 to 0.02 part by weight of CoO, from 0 to 0.0008 part by weight of Se, from 0 to 0.05 part by weight of total chromium calculated as Cr.sub.2 O.sub.3, from 0 to 0.5 part by weight of total vanadium calculated as V.sub.2 O.sub.5 and from 0 to 0.5 part by weight of total cerium calculated as CeO.sub.2, wherein the proportion of ferrous iron calculated as Fe.sub.2 O.sub.3 in the total iron calculated as Fe.sub.2 O.sub.3 is from 15 to 50%.Type: GrantFiled: July 23, 1997Date of Patent: June 6, 2000Assignee: Asahi Glass Company Ltd.Inventors: Mizuki Sasage, Takashi Kijima, Shiro Tanii
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Patent number: 6048812Abstract: The invention relates to brown glasses which absorb ultraviolet radiation that are used in the production of ophthalmic sun glasses, and that have the following composition, expressed in wt. %:______________________________________ SiO.sub.2 59-78 Al.sub.2 O.sub.3 2-6 B.sub.2 O.sub.3 0-3 Na.sub.2 O 7-16 K.sub.2 O 2-9 CaO 0-7 BaO 0-12 ZnO 0-12 ZrO.sub.2 0-6 TiO.sub.2 0-6 MnO.sub.2 0.25-6 V.sub.2 O.sub.5 1-3 Fe.sub.2 O.sub.3 0-1.5 NiO 0-0.5 CoO 0-0.1 Sb.sub.2 O.sub.3 0-0.7 As.sub.2 O.sub.3 0-0.7 F 0.05-1.0 With MnO.sub.2 + Fe.sub.2 O.sub.3 + V.sub.2 O.sub.5 >1.5 Al.sub.2 O.sub.3 + SiO.sub.2 .gtoreq.65.Type: GrantFiled: April 14, 1998Date of Patent: April 11, 2000Assignee: Corning IncorporatedInventors: Yves A. H. Brocheton, Marie J. M. Comte
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Patent number: 6046122Abstract: An ultraviolet and infrared radiation absorbing glass is disclosed, comprising, in % by weight:basic glass components comprising65 to 80% SiO.sub.2,0 to 5% Al.sub.2 O.sub.3,0 to 10% MgO,5 to 15% CaO,10 to 18% Na.sub.2 O,0 to 5% K.sub.2 O,5 to 15% MgO+CaO,10 to 20% Na.sub.2 O+K.sub.2 O,0 to 5% B.sub.2 O.sub.3, and0.07 to 0.18% SO.sub.3, andcoloring components comprising0.40 to 0.90% total ion oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3,1.0 to 2.0% CeO.sub.2, and0 to 1.0% TiO.sub.2,with 27 to 40% of said T-Fe.sub.2 O.sub.3 being FeO in terms of Fe.sub.2 O.sub.3.Type: GrantFiled: March 18, 1998Date of Patent: April 4, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Yukihito Nagashima, Nobuyuki Takatsuki, Isamu Kuroda
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Patent number: 6037286Abstract: A container glass composition that reduces U.V. light transmission below a wavelength of about 400 nanometers, the composition having melting and forming properties similar to soda-lime-silica glass and containing SiO.sub.2, CaO, MgO, K.sub.2 O, SO.sup.-.sub.3, and a U.V. absorbing amount of about 0.4 to 0.8 weight percent FeO+Fe.sub.2 O.sub.3, and about 2 to 4 weight percent of MnO+MnO.sub.2.Type: GrantFiled: March 20, 1998Date of Patent: March 14, 2000Assignee: Owens-Brockway Glass Container Inc.Inventors: Steven M. Weiser, James E. Fenstermacher, Joseph J. Hammel, Robert N. Clark
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Patent number: 6030911Abstract: A Green thermo-absorbent glass which includes a basic composition of lime glass, which consists essentially, by weight, of: 0.86 to 0.91% of total iron expressed as Fe.sub.2 O.sub.3 ; 23.5 to 26% of Fe.sup.-2 and 0.202 to 0.237% of FeO, expressed as Fe.sub.2 O.sub.3 ; a critical amount of 0.15 to 0.18% of SO.sub.3 which does not affects the refining properties and ability of the SO.sub.3 to eliminate bubbles, and in the absence of CeO.sub.2 ; the green glass having a visible light transmission greater than 70%, an ultra-violet radiation transmission greater than 38% and less than 40%, an infra-red radiation transmission greater than 21% and less than 26.5%. and a total solar transmission greater than 41 and less than 47%, without affecting the refining properties and ability of the SO.sub.3 to eliminate bubbles.Type: GrantFiled: September 28, 1998Date of Patent: February 29, 2000Assignee: Vitro Flotado, S.A. de C.V.Inventors: Herbert Scheffler-Hudlet, Roberto Cabrera-Llanos, Rafael Pinto-Negroe
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Patent number: 6017836Abstract: Ultraviolet and infrared radiation absorbing glass comprising, as basic glass components, 65 to 80% by weight of SiO.sub.2, 0 to 5% by weight of Al.sub.2 O.sub.3, 0 to 10% by weight of MgO, 5 to 15% by weight of CaO, 10 to 18% by weight of Na.sub.2 O, 0 to 5% by weight of K.sub.2 O, 5 to 15% by weight in total of MgO and CaO, 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, and 0.2 to 5.0% by weight of B.sub.2 O.sub.3 ; and as coloring components, 0.5 to 1.0% by weight, in terms of Fe.sub.2 O.sub.3, of total iron oxide having a ratio of FeO based on the total iron oxide of 0.20 to 0.40, 0.2 to 2.0% by weight of CeO.sub.2, and 0 to 1.0% by weight of TiO.sub.2, and ultraviolet and infrared radiation absorbing glass comprising, as basic glass components, 65 to 80% by weight of SiO.sub.2, 0 to 5% by weight of Al.sub.2 O.sub.3, 0 to 10% by weight of MgO, 5 to 15% by weight of CaO, 10 to 18% by weight of Na.sub.2 O, 0 to 5% by weight of K.sub.Type: GrantFiled: June 3, 1996Date of Patent: January 25, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Yukihito Nagashima, Koichi Sakaguchi, Takashi Uchino
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Patent number: 6017837Abstract: Ultraviolet and infrared radiation absorbing glass comprising, as basic glass components, 65 to 80% by weight of SiO.sub.2, 0 to 5% by weight of Al.sub.2 O.sub.3, 0 to 10% by weight of MgO, 5 to 15% by weight of CaO, 10 to 18% by weight of Na.sub.2 O, 0 to 5% by weight of K.sub.2 O, 5 to 15% by weight in total of MgO and CaO, 10 to 20% by weight in total of Na.sub.2 O and K.sub.2 O, and 0 to 5% by weight of B.sub.2 O.sub.3 ; and as coloring components, 0.75 to 0.95% by weight, in terms of Fe.sub.2 O.sub.3, of total iron oxide, 1.2 to 1.4% by weight of CeO.sub.2, and 0 to 0.5% by weight of TiO.sub.2, and satisfying equation (I):(0.2.times.(CeO.sub.2)-0.04).ltoreq.(FeO/T-Fe.sub.2 O.sub.3).ltoreq.(0.2.times.(CeO.sub.2)+0.08) (I)wherein (CeO.sub.2) represents the amount of CeO.sub.2 in terms of percent by weight, and (FeO/T-Fe.sub.2 O.sub.3) represents the weight ratio of FeO in terms of Fe.sub.2 O.sub.3 to the total iron oxide in terms of Fe.sub.2 O.sub.Type: GrantFiled: June 3, 1996Date of Patent: January 25, 2000Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Yukihito Nagashima, Tadakazu Hidai
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Patent number: 6017838Abstract: A universal lead free glass (ULF) has been developed having a high electrical resistivity and mechanical working properties comparable to conventional lead glasses used in the manufacture of electric lamps. The ULF glass may be used to manufacture both low and high wattage electric lamps and in particular to make filament mounts for such applications.Type: GrantFiled: September 10, 1998Date of Patent: January 25, 2000Assignee: Osram Sylvania Inc.Inventor: Richard C. Marlor
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Patent number: 5994249Abstract: A soda-lime-silica glass having, at a thickness in the range of 3 mm to 10 mm, a visible light transmittance of 35% to 75%, a total solar radiation transmittance in the range of 20% to 60%, an ultraviolet radiation transmission less than 55%, and a blue color defined by the "CIELAB" system of L=65 to 90, a*=-15 to -4, and b*=-15 to -2. The soda-lime-silica glass composition includes the essential ingredients of about 0.5% to about 0.9% weight percent total iron (as Fe.sub.2 O.sub.3), about 50 ppm to 100 ppm CoO, and about 0.1 to about 2.0 weight percent TiO.sub.2, with a ferrous iron to total iron ratio of about 20% to about 40%.Type: GrantFiled: July 23, 1998Date of Patent: November 30, 1999Assignee: Libbey-Owens-Ford Co.Inventors: Dennis R. Graber, Paige L. Higby
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Patent number: 5985780Abstract: A colored glass composition, containing the following oxides within the following limits by weight:______________________________________ SiO.sub.2 64 to 75% Al.sub.2 O.sub.3 0 to 5% B.sub.2 O.sub.3 0 to 5% CaO 5 to 15% MgO 0 to 5% Na.sub.2 O 10 to 18% and K.sub.2 O 0 to 5% ______________________________________and as coloring agents: ______________________________________ Fe.sub.2 O.sub.3 (total iron) 0.45 to 2.5% with FeO content representing from 16 to 55% ______________________________________of the total iron content expressed in the form of Fe.sub.2 O.sub.3 ______________________________________ CoO 0.001 to 0.02% Se 0 to 0.0009% ______________________________________wherein the glasses have a total energy transmission factor (T.sub.E) less than the light transmission factor under illuminant A (TL.sub.A), the factor T.sub.E being from 10 to 48% and the factor TL.sub.A from 20 to 60% for a thickness of 3.85 mm, the colored glass composition having an excitation purity equal to or less than 7.6%.Type: GrantFiled: June 7, 1995Date of Patent: November 16, 1999Assignee: Saint -Gobain Vitrage InternationalInventors: Pedro Alvarez Casariego, Jean-Jacques Massol
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Patent number: 5977002Abstract: The invention is a medium color gray soda-lime-silica glass composition having excellent ultra violet and infra red absorbing ability. The colorants of the glass composition consist essentially of: greater than 0.5 but less than 0.9 wt. % total iron oxide as Fe.sub.2 O.sub.3 ; 0.1 to 1.0 wt. % manganese compound as MnO.sub.2 ; 0.0005 to 0.003 wt. % selenium as Se; 0.002 to 0.010 wt. % cobalt oxide as Co; up to 1.0 TiO.sup.2 ; the glass composition having, at 4.0 mm. thickness: 485-570 dominant wavelength, less than 5% purity of excitation, 35 to 60% light transmittance using Illuminant A, less than 40% ultra violet transmittance measured over 300-400 nm, and less than 45% infra red transmittance measured over 760-2120 nm.Type: GrantFiled: March 26, 1998Date of Patent: November 2, 1999Assignee: Ford Motor CompanyInventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 5977000Abstract: Opaque silica glass having a density of 2.0 to 2.18 g/cm.sup.3, sodium and potassium elements concentrations in the silica glass of each 0.5 ppm or less and an OH group concentration of 30 ppm or less, and containing bubbles which are independent bubbles having the following physical values: a bubble diameter of 300 .mu.m or less, and a bubble density of 100,000 to 1,000,000 bubbles/cm.sup.3, and a production process for opaque silica glass, including: filling quartz raw material grain having a particle size of 10 to 350 .mu.m in a heat resistant mold, heating it in a non-oxidizing atmosphere from a room temperature up to a temperature lower by 50 to 150.degree. C. than a temperature at which the above raw material grain is melted at a temperature-raising speed not exceeding 50.degree. C./minute, then, slowly heating it up to a temperature higher by 10 to 80.degree. C. than the temperature at which the quartz raw material grain is melted at the speed of 10.degree. C.Type: GrantFiled: November 25, 1997Date of Patent: November 2, 1999Assignee: Shin-Etsu Quartz Products Co., Ltd.Inventors: Tatsuhiro Sato, Akira Fujinoki, Kyoichi Inaki, Nobumasa Yoshida, Tohru Yokota
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Dark bronze glass with improved UV and IR absorption and nitrate-free manufacturing process therefor
Patent number: 5962356Abstract: The invention is a dark bronze soda-lime-silica glass composition having excellent ultra violet and infra red absorbing ability. The colorants of the glass composition consist essentially of: greater than 0.5% total iron oxide as Fe.sub.2 O.sub.3 with a maximum of 1.5% Fe.sub.2 O.sub.3, wherein the redox ratio of FeO/total Fe as Fe.sub.2 O.sub.3 is less than 0.26; 0.10 to 1.00 wt. % manganese compound as MnO.sub.2 ; 0.0005 to 0.004 wt. % selenium as Se; up to 0.016 wt. % cobalt oxide as Co; 0-1.0 wt. % TiO.sub.2, the glass composition having, at 4.0 mm. thickness: 570-585 dominant wavelength, 5-30% purity of excitation, 20 to 65% light transmittance using Illuminant A (LTA), less than 35% ultra violet transmittance measured over 300-400 nm, and less than 46% infra red transmittance measured over 760-2120 nm. At 20-50% LTA, the excitation purity is 7-30%, while above 50% LTA, the excitation purity is 5-20%. This glass is particularly useful for architectural applications.Type: GrantFiled: March 26, 1998Date of Patent: October 5, 1999Assignee: Ford Motor CompanyInventors: Edward Nashed Boulos, James Victor Jones -
Patent number: 5958811Abstract: An ultraviolet and infrared radiation absorbing glass having excellent ultraviolet radiation absorbing power and a bronze or neutral gray tint which is suitably used as a window glass for vehicles of automobiles and also as a window glass for construction materials is provided. The glass comprises, in % by weight: basic glass components comprising 65 to 80% SiO.sub.2, 0 to 5% B.sub.2 O.sub.3, 0 to 5% Al.sub.2 O.sub.3, 0 to 10% MgO, 5 to 15% CaO, 10 to 18% Na.sub.2 O, 0 to 5% K.sub.2 O, 5 to 15% MgO+CaO, and 10 to 20% Na.sub.2 O+K.sub.2 O, and coloring components comprising 0.20 to 0.50% total iron oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3, 0 to 3.0% CeO.sub.2, 0.025 to 6.0% La.sub.2 O.sub.3, 0 to 2.0% TiO.sub.2, 0.0002 to 0.005% CoO, 0.0002 to 0.005% Se, 0 to 0.01% NiO, and 0 to 1.0% SnO.sub.2, wherein 5 to 25% of said T-Fe.sub.2 O.sub.3 in terms of Fe.sub.2 O.sub.3 is FeO.Type: GrantFiled: September 30, 1997Date of Patent: September 28, 1999Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Koichi Sakaguchi, Yukihito Nagashima, Shigeki Nakagaki
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Patent number: 5958809Abstract: The invention relates to fluorine-containing silica glasses, and methods of their production. The silica glass may be used for an ultraviolet light optical system in which light in a wavelength region of 200 nm or less, such as an ArF (193 nm) excimer laser, is used. The invention also relates to a projection exposure apparatus containing fluorine-containing glass of the invention.Type: GrantFiled: August 21, 1997Date of Patent: September 28, 1999Assignee: Nikon CorporationInventors: Seishi Fujiwara, Hiroyuki Hiraiwa, Kazuhiro Nakagawa, Shouji Yajima, Norio Komine, Hiroki Jinbo
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Patent number: 5955194Abstract: An improved fiber reinforced glass composite includes a boron-containing refractory fiber having its surface enriched with boron nitride in a matrix of a black glass ceramic having the empirical formula SiCxOy where x ranges from about 0.5 to about 2.0, preferably 0.9 to 1.6 and y ranges from about 0.5 to 3.0, preferably 0.7 to 1.8. Preferably the black glass ceramic is derived from cyclosiloxane or non-cyclic siloxane monomers containing a vinyl group attached to silicon and/or a hydride-silicon group. The boron nitride-containing fiber is the product of treating the boron-containing fiber with ammonia at a temperature between about 1100.degree. C. and 1250.degree. C. Fibrous failure rather than brittle failure under stress can be obtained.Type: GrantFiled: June 12, 1995Date of Patent: September 21, 1999Assignee: AlliedSignal, Inc.Inventor: Scott Sager Campbell
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Patent number: 5952255Abstract: The ultraviolet/infrared absorbent low transmittance glass has an almost neutral greenish color, middle visible light transmittance, low total solar energy transmittance, and low ultraviolet transmittance, and is suitable for a window of a vehicle or a building and capable of preventing degradation and discoloration of interior materials and protecting privacy. The glass consists of base glass including: 65 to 80 wt. % SiO.sub.2 ; 0 to 5 wt. % Al.sub.2 O.sub.3 ; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO wherein a total amount of MgO and CaO is between sand 15 wt. %; 10 to 20 wt. % Na.sub.2 O; 0 to 5 wt. % K.sub.2 O wherein a total amount of Na.sub.2 O and K.sub.2 O is between 10 to 20 wt. %; and 0 to 5 wt. % B.sub.2 O.sub.3, and colorants including: 0.7 to 0.95 wt. % total iron oxide (T-Fe.sub.2 O.sub.3) expressed as Fe.sub.2 O.sub.3 ; 1.1 to 2.3% TiO.sub.2, 0 to 2.0% CeO.sub.2, 0.013 to 0.025 wt. % CoO; 0 to 0.0008% Se; and 0.01 to 0.07% NiO.Type: GrantFiled: September 30, 1997Date of Patent: September 14, 1999Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Hiromitsu Seto, Yukihito Nagashima, Shigekazu Yoshii
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Patent number: 5948535Abstract: The preparation of objects, in particular optical components and/or devices, is described using, as precursors of optical materials, amorphous monolithic aerogels for high-precision mechanical machining.Type: GrantFiled: August 21, 1995Date of Patent: September 7, 1999Assignee: Enichem S.p.A.Inventors: Paolo Chiurlo, Guido Cogliati, Lorenzo Costa
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Patent number: 5932501Abstract: The invention relates to glasses which absorb UV radiation and which have the following composition, in wt. %: SiO.sub.2 30-52; ZnO 0-8; B.sub.2 O.sub.3 12-22; PbO 0-2; ZrO.sub.2 5-14; Y.sub.2 O.sub.3 0-15; Al.sub.2 O.sub.3 0-12; La.sub.2 O.sub.3 5-25; Li.sub.2 O 1.5-3.5; TiO.sub.2 0-2; Na.sub.2 O 0-6; HfO.sub.2 0-2; K.sub.2 O 2-9; Nb.sub.2 O.sub.5 0-2; MgO 0-5; Ta.sub.2 O.sub.5 0-2; CaO 0-5; MoO.sub.3 0-2; SrO 0-9; WO.sub.3 0-2; BaO 0-14; SnO 0-4; Sb.sub.2 O.sub.3 0-4; SnO.sub.2 0-4; AS.sub.2 O.sub.3 0-4; CdO 0-1; CuO 0.15-1; F 0-2; Cl 0-3; Br 0-3; I 0-2 with the following conditions: Li.sub.2 O+Na.sub.2 O+K.sub.2 O (X.sub.2 O) 7-14; MgO+CaO+SrO+BaO (XO) 12-20; ZrO.sub.2 +Al.sub.2 O.sub.3 <15; F+Cl+Br+I 0.2-4.0; TiO.sub.2 +PbO+Nb.sub.2 O.sub.5 .ltoreq.2; AS.sub.2 O.sub.3 +Sb.sub.2 O.sub.3 +SnO.sub.2 +SnO 0.05-4.0 and a ratio R=(M.sub.2 O+2MO-Al.sub.2 O.sub.3 -ZrO.sub.2)/B.sub.2 O.sub.3 where M.sub.Type: GrantFiled: February 2, 1998Date of Patent: August 3, 1999Assignee: Corning IncorporatedInventor: Yves A. H. Brocheton
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Patent number: 5912199Abstract: The invention relates to a packing for foods on the basis of green colored soda-lime glass absorbing UV radiation and transmitting visible light, which glass consists of: at least 2.5 wt. % iron, calculated as Fe.sub.2 O.sub.3, at least 12 wt. % sodium, calculated as Na.sub.2 O, and at most 4 wt. % aluminum, calculated as Al.sub.2 O.sub.3.Type: GrantFiled: August 18, 1997Date of Patent: June 15, 1999Assignee: Heineken Technical Services B.V.Inventors: Adrianus Smout, Gerrit Jan Loggers
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Patent number: 5905047Abstract: A dark gray colored glass comprising 100 parts by weight of a soda lime silicate glass as a matrix component and coloring components consisting essentially of from 0.8 to 1.5 parts by weight of total iron calculated as Fe.sub.2 O.sub.3, from 0.1 to 0.3 part by weight of FeO, from 0 to 1.0 part by weight of TiO.sub.2, from 0.0005 to 0.015 part by weight of Se, from 0.02 to 0.05 part by weight of CoO and from 0.002 to 0.05 part by weight of Cr.sub.2 O.sub.3.Type: GrantFiled: March 20, 1997Date of Patent: May 18, 1999Assignee: Asahi Glass Company Ltd.Inventors: Mizuki Sasage, Takashi Kijima
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Patent number: 5896222Abstract: A method of producing a fused silica glass by thermally converting a polymethylsiloxane precursor, the lens transmitting ultraviolet radiation at wavelengths below 300 nm. without undergoing a marked absorption transition, the lens so produced, and a microlithography system employing a lens of such glass.Type: GrantFiled: December 5, 1997Date of Patent: April 20, 1999Assignee: Corning IncorporatedInventors: Cynthia K. Rosplock, Daniel R. Sempolinski
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Patent number: 5877102Abstract: Soda lime glass including glass-forming constituents for soda lime glass; and coloring agents including iron, cobalt and selenium present in a form and in an amount as percent by weight of the soda lime glass as follows:from 1.00 to 1.65% of Fe.sub.2 O.sub.3 ;from 0.017 to 0.030% of Co; andfrom 0.001 to 0.010% of Se.The soda lime glass has a very dark grey color, a total luminous transmission measured for Illuminant A for a glass thickness of 4 mm (TLA4) of less than 20%, and a total energy transmission measured for a glass thickness of 4 mm (TE4) of less than 20%. This glass is particularly suitable for vehicle roof panels.Type: GrantFiled: September 3, 1996Date of Patent: March 2, 1999Assignee: GlaverbelInventors: Camille DuPont, Daniel D'Hont
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Patent number: 5877103Abstract: Soda lime glass includes glass forming constituents for soda lime glass; and coloring agents including iron, cobalt, selenium and chromium express in the form indicated and in an amount as percent by weight of the soda lime glass as follows:from 1.05 to 1.80% of Fe.sub.2 O.sub.3,from 0.0040 to 0.0180% of Co,from 0.0003 to 0.0040% of Se, andfrom 0.0010 to 0.0100% of Cr.sub.2 O.sub.3.The soda lime glass has a dark grey color, a total energy transmission measured for a glass thickness of 4mm (TE4) mm (TE4) ranging between 15 to 40%, a selectivity (SE4) which is high and is at least 1.2, and an excitation purity which does not exceed 10%. This glass is particularly suitable for automobile rear windows or rear side windows.Type: GrantFiled: September 3, 1996Date of Patent: March 2, 1999Assignee: GlaverbelInventors: Camille Dupont, Daniel D'Hont
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Patent number: 5858896Abstract: An ultraviolet and infrared radiation absorbing glass having excellent ultraviolet radiation absorbing power and green tint, which is suitably used as a window glass for automobiles and constructional materials. The glass comprises, in % by weight: basic glass components comprising 65 to 80% SiO.sub.2, 0 to 5% Al.sub.2 O.sub.3, 0 to 10% MgO, 5 to 15% CaO, 10 to 18% Na.sub.2 O, 0 to 5% K.sub.2 0, 5 to 15% MgO+CaO, 10 to 20% Na.sub.2 O+K.sub.2 O, and 0 to 5% B.sub.2 O.sub.3, and coloring components comprising 0.4 to 1.5% total iron oxide (T-Fe.sub.2 O.sub.3) in terms of Fe.sub.2 O.sub.3, 0 to 3.0% CeO.sub.2, 0 to 2.0% TiO.sub.2, and 0.025 to 6.0% La.sub.2 O.sub.3, wherein 25 to 40% of said T-Fe.sub.2 O.sub.3 in terms of Fe.sub.2 O.sub.3 is FeO.Type: GrantFiled: September 30, 1997Date of Patent: January 12, 1999Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Yukihito Nagashima, Shigekazu Yoshii
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Patent number: 5851940Abstract: The invention is a soda-lime-silica glass composition which is blue in color and having improved UV and IR absorption. The spectral properties of the blue glass at a 4.0 mm. Thickness include: 477-494 dominant wavelength and 6-40% purity of excitation. The blue glass composition, by weight, comprises a base glass composition of: 68 to 75% SiO.sub.2, 10 to 18% Na.sub.2 O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al.sub.2 O.sub.3, and 0 to 5% K.sub.2 O, where CaO+MgO is 6 to 15% and Na.sub.2 O+K.sub.2 0 is 10 to 20%; and colorants consisting essentially of: 0.4 to 2.0% total iron oxide as Fe.sub.2 O.sub.3, 0.15 to 2.00% manganese oxide as MnO.sub.2 ; 0.005 to 0.025% cobalt oxide as Co, and 0 to 1.00% titanium oxide as TiO.sub.2. The glass is useful for automotive or architectural applications. It preferably is made by a nitrite-free method which may desirably involve the use of a reducing agent during melting operations.Type: GrantFiled: July 11, 1997Date of Patent: December 22, 1998Assignee: Ford Motor CompanyInventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 5807417Abstract: The invention is nitrate-free method to manufacture a blue soda-lime-silica glass composition and improving the ultraviolet light absorption thereof while maintaining a high visible light transmission. The method comprises the steps of: adding colorants, during molten glass formation, consisting essentially of a manganese compound along with a cobalt compound, iron oxide and optionally titanium oxide to a soda-lime-silica base glass composition, and adding no sodium nitrate into the batch during molten glass formation, the materials are adding in quantities sufficient to form said blue glass composition having at a 4.0 mm. thickness: 477-494 dominant wavelength and 6-40% purity of excitation. The blue glass composition, by weight, comprises a base glass composition of: 68 to 75% SiO.sub.2, 10 to 18% Na.sub.2 O, 5 to 15% CaO, 0 to 10% MgO, 0 to 5% Al.sub.2 O.sub.3, and 0 to 5% K.sub.2 O, where CaO+MgO is 6 to 15% and Na.sub.2 O+K.sub.2 O is 10 to 20%; and colorants consisting essentially of: 0.4 to 2.Type: GrantFiled: July 11, 1997Date of Patent: September 15, 1998Assignee: Ford Motor CompanyInventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 5792559Abstract: The present invention provides a glass composite transparency having a desired color, intensity and a high performance ratio. In particular, the transparency includes at least one rigid transparent ply, e.g. a colored glass or plastic substrate, and a member secured to a major surface of the substrate, e.g. a flexible plastic layer or a coating. The member has a color that generally complements the color of the glass substrate to reduce the overall color intensity of the composite transparency. The resulting composite transparency is gray in color and has a LTA to TSET ratio of at least 1.4, preferably with LTA.gtoreq.70%.Type: GrantFiled: July 5, 1994Date of Patent: August 11, 1998Assignee: PPG Industries, Inc.Inventors: Robert B. Heithoff, Larry J. Shelestak
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Patent number: 5786289Abstract: A window glass comprising at least one sheet of glass coated with an electroconductive ITO layer, pyrolyzed from powdered components, combined with a flexible plastic material of the PVB, PU, PVC type, with an index approaching more the index of the ITO layer than the index of air, with which the said layer is coated, and a sheet of glass dyed in the mass, with the same color as the ITO layer, and with properties of reduced energy transmission also entering advantageously into the composition of the window glass is provided. The invention particularly applies to the production of heated windshields for automobiles.Type: GrantFiled: January 7, 1994Date of Patent: July 28, 1998Assignee: Saint Gobain VitrageInventors: Helene Harmand, Vincent Sauvinet, Maurice Trouve
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Patent number: 5780372Abstract: A moderate visible light transmitting soda-lime-silica glass of a blue green tint having, at a nominal 4 mm thickness, a visible light transmittance of about 10% to about 70%, and a direct solar heat transmittance of at least 5% less than the visible light transmittance. The soda-lime-silica glass composition includes the essential ingredients of about 1 to about 3 weight percent Fe.sub.2 O.sub.3, about 0.1 to about 1 weight percent TiO.sub.2, and about 0 to 500 ppm Co.sub.3 O.sub.4 with a ferrous iron to total iron content of about 10% to about 37% by weight.Type: GrantFiled: January 10, 1997Date of Patent: July 14, 1998Assignee: Libbey-Owens-Ford Co.Inventor: Paige L. Higby
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Patent number: 5776845Abstract: The invention is a green soda-lime-silica glass composition having excellent ultra violet absorbing ability while having a relatively high light transmittance. The colorants of the glass composition consist essentially of: greater than 0.5 to 1.5 wt. % total iron oxide as Fe.sub.2 O.sub.3 ; wherein the weight ratio of Fe.sup.+2 /Fe.sup.+3 is less than 0.35; 0.10 to 2.00 wt. % manganese compound as MnO.sub.2 ; and optionally any of: up to 1.00 wt. % titanium oxide as TiO.sub.2, up to 1.00 wt. % cerium oxide as CeO.sub.2 ; up to 1.00 wt. % vanadium oxide as V.sub.2 O.sub.5 ; and up to 0.20 wt. % chromium oxide as Cr.sub.2 O.sub.3 ; the glass composition having, at 4.0 mm. thickness: 55 to 80% light transmittance using Illuminant A with less than 46% ultra violet transmittance measured over the range of 300 to 400 nanometers.Type: GrantFiled: December 17, 1996Date of Patent: July 7, 1998Assignee: Ford Motor CompanyInventors: Edward Nashed Boulos, James Victor Jones
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Patent number: 5747398Abstract: A solar heat reducing and ultraviolet absorbing soda-lime-silica glass of a neutral tint and high visible light transmittance. The glass has the essential colorants of from about 0.1 to about 0.7 weight percent Fe.sub.2 O.sub.3 (total iron), and either from about 0.1 to about 1.0 weight percent of a compound selected from the group consisting of titanium dioxide, vanadium pentoxide, and ceric oxide, or alternatively from about 0.1 to about 2.0 weight percent of a combination of colorants selected from the group, and having a ferrous value of less than 35 percent.Type: GrantFiled: November 5, 1996Date of Patent: May 5, 1998Assignee: Libbey-Owens-Ford Co.Inventors: Paige L. Higby, Dean E. Vernacotola, Bret E. Penrod
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Patent number: 5723390Abstract: Glass having low solar radiation and ultraviolet ray transmittance, which consists essentially of a soda lime-silica type matrix glass containing from 0.53 to 0.70 wt % of total iron calculated as Fe.sub.2 O.sub.3, from 0.2 to 0.4 wt % of TiO.sub.2 and from 0.5 to 0.8 wt % of total cerium calculated as CeO.sub.2, wherein the weight of FeO calculated as Fe.sub.2 O.sub.3 is from 30 to 40% of the weight of the total iron calculated as Fe.sub.2 O.sub.3.Type: GrantFiled: February 12, 1996Date of Patent: March 3, 1998Assignee: Asahi Glass Company Ltd.Inventors: Takashi Kijima, Toru Kudo, Mizuki Ito, Fumio Kamei, Akira Kondo
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Patent number: 5720805Abstract: There are disclosed stabilized Ti-Sn-O nanoclusters formed by complexing Ti-Sn-O nanoclusters with a salt of an alpha-hydroxy acid and also complexed nanoclusters with increased charge transfer interaction formed by annealing the complexed nanoclusters. Also disclosed are compositions for protection against ultraviolet radiation in which the nanoclusters are utilized with the usual topical carriers in an amount to give the level of sun protection factor (SPF) desired. Further disclosed is the method of making the nanoclusters involving acid hydrolyzing a titanium alkoxide and then reacting the hydrolyzed alkoxide with a tin halide.Type: GrantFiled: September 27, 1996Date of Patent: February 24, 1998Assignee: Southwest Research InstituteInventors: Stephen T. Wellinghoff, Domnica Cernasov
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Patent number: 5719698Abstract: Recent UV-lithography is required to provide a fine and sharp pattern with a line width of 0.5 .mu.m or less. The present invention provides a silica glass member adapted for use as an optical element for UV-lithography, by giving consideration to the RMS value of wave front aberration and the slant element of refractive index, which have not been considered in the art. Also, there is provided a silica glass member excellent in durability to the ultraviolet irradiation, by introduction of hydrogen molecules at the synthesis of the silica glass, instead of using a secondary treatment for hydrogen introduction.Type: GrantFiled: September 6, 1996Date of Patent: February 17, 1998Assignee: Nikon CorporationInventors: Hiroyuki Hiraiwa, Issey Tanaka
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Patent number: 5703712Abstract: Recent UV-lithography is required to provide a fine and sharp pattern with a line width of 0.5 .mu.m or less. The present invention provides a silica glass member adapted for use as an optical element for UV-lithography, by giving consideration to the RMS value of wave front aberration and the slant element of refractive index, which have not been considered in the art. Also, there is provided a silica glass member excellent in durability to the ultraviolet irradiation, by introduction of hydrogen molecules at the synthesis of the silica glass, instead of the using a secondary treatment for hydrogen introduction.Type: GrantFiled: July 31, 1995Date of Patent: December 30, 1997Assignee: Nikon CorporationInventors: Norio Komine, Hiroki Jinbo, Seishi Fujiwara, Hiroyuki Hiraiwa
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Patent number: 5700579Abstract: Glass compositions containing, expressed in percentages by weight, from 0.75 to 1.4% total iron expressed in the form Fe.sub.2 O.sub.3, from 0.25 to 0.32% ferrous iron in the form of FeO and which has, and at a thickness of between approximately 3 and 3.3 millimeters, exibit a total light transmission factor under illuminent A (TL.sub.A) of at least 70%, a total energy transmission factor (T.sub.E) less than approximately 46% and a transmission factor for ultraviolet radiation (T.sub.UV) less than approximately 25%, and are suitable for the production of windows or panes for use in the architectural field or in automobile and industrial vehicles.Type: GrantFiled: September 19, 1994Date of Patent: December 23, 1997Assignee: Saint-Gobain VitrageInventors: Pierre Jeanvoine, Michel Lismonde, Jacques Vieslet
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Patent number: 5688730Abstract: Gamma-aluminum oxynitride ground powders, white in color and well suited for conversion into optically transparent ceramic shaped articles, 100% of the particles of which being less than 10 .mu.m in size and exhibiting a transmittance of at least 8%, are prepared by grinding particulate gamma-aluminum oxynitride agglomerates having a porosity of greater than 75%, such agglomerates themselves being produced by interreacting dry powdery admixture of aluminum nitride, alpha-alumina, and an alumina of high specific surface area or precursor thereof.Type: GrantFiled: July 19, 1996Date of Patent: November 18, 1997Assignee: Elf Atochem S.A.Inventors: Roland Bachelard, Jean-Pierre Disson, Bruno Morlhon
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Patent number: 5668067Abstract: The invention relates to the production of high purity fused silica glass which is highly resistant to optical damage by ultraviolet radiation in the laser wavelength of about 300 nm or shorter. In particular, this invention relates to a fused silica optical member or blank which exhibits substantially no optical damage up to 10.sup.7 pulses (350 mJ/cm.sup.2) at the KrF laser wavelength region of about 248 nm, and at the ArF laser wavelength region of about 193 nm.Type: GrantFiled: August 19, 1996Date of Patent: September 16, 1997Assignee: Corning IncorporatedInventors: Roger J. Araujo, Nicholas F. Borrelli, Christine L. Hoaglin, Charlene Smith
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Patent number: 5627115Abstract: The invention relates to brownish, brown to black colored borosilicate glasses which have stepped grades of transmission in the NIR range or are fully non-transmitting. The borosilicate glass, primarily the borosilicate glass 3.3, is melted with defined additives of titanium carbide and/or metallic silicon. The glasses produced in accordance with the invention are to be used as filters, glass vessels and/or decorative colored glass in construction and for decorating because of their absorption/transmission characteristics. On the other hand, the glasses produced in accordance with the invention can also be used as absorbers in solar technology when the light transmissibility in the NIR/IR range is sufficiently low.Type: GrantFiled: August 7, 1995Date of Patent: May 6, 1997Assignee: JENAer Glaswerk GmbHInventors: Eckhart Watzke, Andrea Kampfer, Thomas Kloss, Gerhard Kemmler
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Patent number: 5612262Abstract: The invention relates to gray, bluish, blue to black colored borosilicate glasses which have a stepped transmission grade in the near infrared range or are fully non-transmitting. The borosilicate glass with defined additions of titanium dioxide is melted together with a reduction agent such as Si(metallic). The glasses produced in accordance with the invention are used as filters because of their absorption/transmission characteristic or, if the light transmissibility in the near infrared/infrared ranges is sufficiently low, the glasses can also be used as absorbers in solar technology, as a glass used in areas of the home and/or as decorative colored glass in construction and for decorating.Type: GrantFiled: August 7, 1995Date of Patent: March 18, 1997Assignee: JENAer GLASWERK GmbHInventors: Thomas Kloss, Eckhart Watzke