With Alkaline Earth Metal Compound Patents (Class 501/97.3)
  • Patent number: 6313054
    Abstract: The present invention provides a silicon nitride sintered body having characteristics such as excellent wear resistance, a method for manufacturing the sintered body, and a cutting insert formed thereof. The silicon nitride sintered body is formed of a polycrystalline sintered body of predominantly &bgr;-Si3N4, wherein the oxygen content is 1.2-1.5 wt. %. The method for manufacturing the silicon nitride sintered body includes the following steps: adding an organic binder to a composition containing silicon nitride as an essential component and exhibiting a theoretical oxygen content of 2.0-3.0 wt. %; heating to remove the binder; introducing an oxygen-containing gas so as to control the carbon content to 0.10-0.60 wt. %; and sintering a resultant compact in an nitrogen atmosphere to control the oxygen content to 1.2-1.5 wt. %. The cutting insert of the present invention has excellent wear resistance.
    Type: Grant
    Filed: August 14, 2000
    Date of Patent: November 6, 2001
    Assignee: NGK Spark Plug Co., Ltd.
    Inventor: Masaru Matsubara
  • Patent number: 6294244
    Abstract: A wiring board of the present invention is equipped with an insulating board formed of a sintered product of silicon nitride containing a silicon nitride crystal phase, and a metal circuit formed on said insulating board, wherein said sintered product of silicon nitride contains a rare earth element (RE) and magnesium in a total amount of from 4 to 30 mol % calculated as oxides and at a molar ratio (RE2O3/MgO) calculated as oxides of from 0.1 to 15, and has a relative density of not smaller than 90% and a heat conductivity of not smaller than 50 W/m·K. The wiring board is equipped with the insulating board having very excellent heat-radiating property and a large strength, and is very useful as a wiring board for, for example, power modules.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: September 25, 2001
    Assignee: Kyocera Corporation
    Inventors: Toshihiro Iwaida, Teruhisa Makino, Masanobu Ishida, Tomohide Hasegawa, Hirosi Okayama
  • Patent number: 6291376
    Abstract: A composition and method of fabricating pressureless sintered 70 volume % silicon nitride—30 volume % barium aluminum silicate ceramic composites. The composites are made from 70 volume % silicon nitride, containing varying amounts and size distributions of initial &bgr;-silicon nitride, and 30 volume % barium aluminum silicate. The resulting ceramic composites contain microstructures with coarse &bgr;-silicon nitride whiskers, as well as narrow distributions of short &bgr;-silicon nitride whiskers, surrounded by fine barium aluminum silicate grains. The resulting composites exhibit improved fracture toughness and flexural strength.
    Type: Grant
    Filed: October 19, 2000
    Date of Patent: September 18, 2001
    Inventors: Kenneth W. White, Feng Yu
  • Patent number: 6284690
    Abstract: A slurry Si-base composition comprising an Si powder having a thickness of a surface oxide film ranging from 1.5 to 15 nm, 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant, the Si-base composition having a pH value adjusted to 8-12. This slurry Si-base composition is produced by a process which comprises subjecting Si powder to oxidation treatment at 200 to 800° C. in air, adding 50 to 90% by weight of water, 0.2 to 7.5% by weight, in terms of oxide, of a sintering aid and 0.05 to 3% by weight of a dispersant to the oxidized Si powder and performing such a pH adjustment that the resultant mixture has a pH value of 8 to 12. The slurry Si-base composition not only enables producing a ceramic of Si3N4 at a lowered cost without the need to install explosionproof facilities but also allows the obtained Si3N4 ceramic having a relative density of at least 96% and a flexural strength of at least 800 MPa can be obtained.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: September 4, 2001
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Seiji Nakahata, Akira Yamakawa
  • Patent number: 6242374
    Abstract: A high thermal conductive silicon nitride sintered body of this invention is characterized by containing: 2.0 to 17.5% by weight of a rare earth element in terms of the amount of an oxide thereof; 0.3 to 3.0% by weight of Mg in terms of the amount of an oxide thereof; if necessary, at most 1.5% by weight of at least one of calcium (Ca) and strontium (Sr) in terms of an oxide thereof, if necessary at most 1.5% by weight of at least one element selected from the group consisting of Ti, Zr, V, Nb, Ta, Cr, Mo and W in terms of the amount of an oxide thereof, and at most 0.3% by weight of Al, Li, Na, K, Fe, Ba, Mn and B as impurity cationic elements in terms of total amount thereof, comprising a silicon nitride crystal and a grain boundary phase. The sintered body has a ratio of a crystal compound phase formed in the grain boundary phase to the entire grain boundary phase of at least 20%, a porosity of at most 2.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: June 5, 2001
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Michiyasu Komatsu
  • Patent number: 6218325
    Abstract: A fiber-reinforced ceramic green body having enough green strength and handling strength. The fiber-reinforced ceramic green body is obtained by molding a ceramic composition comprising a ceramic powder, a sintering aid powder, an organic fiber, an aqueous dispersion medium and an optional dispersant. The organic fiber is contained in the ceramic green body in an amount of 0.2-3 parts by weight based on 100 parts by weight of a total of the ceramic powder and the sintering aid powder and uniformly dispersed throughout it. The average length of the organic fiber is 300-1000 &mgr;m and the average diameter is 2.5-30 &mgr;m. The organic fiber is preferably a synthetic high polymer such as polyester, nylon, etc., and preferably has a hydrophilic nature imparted by surface treatment.
    Type: Grant
    Filed: June 9, 1998
    Date of Patent: April 17, 2001
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Yuuji Miki, Atsushi Koizumi, Naoki Itoh