Abstract: To provide an inorganic solid material that has a hydrogen sulfide sustained releasability at ordinary temperature in the air atmosphere and is capable of being handled safely and a method for producing the same, and a method for generating hydrogen sulfide using the material. A layered double hydroxide having HS? and/or Sk2? (wherein k represents a positive integer) intercalated among layers (sulfide ion-containing LDH) is produced, and the sulfide ion-containing LDH is hermetically housed in a packaging material to provide a package. In generating hydrogen sulfide, the packaging material of the package is opened, and the sulfide ion-containing LDH is exposed to the air atmosphere to sustainably release hydrogen sulfide.

Abstract: Embodiments described herein relate to methods for preparing catalysts and catalyst supports. In one embodiment, transition metal carbide materials, having a nanotube like morphology, are utilized as a support for a precious metal catalyst, such as platinum. Embodiments described herein also relate to proton exchange membrane fuel cells that incorporate the catalysts described herein.

Abstract: Methods are disclosed for achieving the catalytic combustion of a gaseous species in low temperature humid environments. The methods comprise the steps of obtaining a combustion catalyst composition comprising an amount of a precious metal supported on an ion-exchangeable alkali metal titanate substrate, and then exposing the species to the combustion catalyst composition in the presence of an oxygen containing gas and water vapour at a catalysis temperature below 200° C. and at a relative humidity above 0.5%. A novel desiccant-coupled catalytic combustion process and system are also disclosed.

Abstract: A mineral wool batt for use as a plant growth medium, particularly in applications for growing vegetation (including plants) in which water retention and/or the avoidance of water run-off is of interest. The mineral wool batt has an absorbent layer which comprises needled mineral wool fibres; superabsorbent particles in the absorbent layer may be sandwiched between a denser upper and/or lower barrier layer(s) which assist in preventing their escape.

Abstract: An object of the present invention is to provide a novel catalyst for olefin (co)polymer production, which has high activity without using a large amount of a cocatalyst and is aimed for obtaining a particulate olefin (co)polymer. The invention relates to an olefin polymerization catalyst which comprises: a solid carrier (1) that has been brought into contact with a specific compound; and a metal catalyst component (2) that contains a transition metal compound (C) containing a transition metal M belonging to Group 9, 10, or 11 of the periodic table and has a reactive group Ra.

Abstract: An object of the present invention is to provide a novel catalyst for olefin (co)polymer production, which has high activity without using a large amount of a cocatalyst and is aimed for obtaining a particulate olefin (co)polymer. The invention relates to an olefin polymerization catalyst which comprises: a solid carrier (1) that has been brought into contact with a specific compound; and a metal catalyst component (2) that contains a transition metal compound (C) containing a transition metal M belonging to Group 9, 10, or 11 of the periodic table and has a reactive group Ra.

Abstract: The present invention concerns a process for the preparation of a catalyst comprising an active phase comprising at least one metal from group VIII selected from cobalt, nickel, ruthenium and iron, alone or as a mixture, and an oxide support which can be used in a Fischer-Tropsch synthesis process comprises at least once the linked sequence of a stage for impregnation of said oxide support, a drying stage in which said impregnated oxide support is entrained by means of a gas, said impregnated oxide support being subjected in said stage to a temperature rise ramp of between 250 and 600° C./min, the residence time of said impregnated oxide support in said drying stage being between 1 second and 1 minute, and a stage for calcination of said dried impregnated oxide support. The invention also concerns a Fischer-Tropsch synthesis process using the catalyst prepared according to the preparation process.

Abstract: An improved method of preparing an ion exchange resin catalyst by partial neutralization of the ion exchange resin catalyst with a promoter. The promoter and a fluid are introduced into a vessel or a reactor which is partially filled with the ion exchange resin catalyst forming an ion exchange resin catalyst bed in the vessel or reactor. The fluid and the promoter are recirculated in an upflow direction at a velocity sufficient to partially fluidize the ion exchange resin catalyst bed and to achieve a rapid uniform distribution of the promoter throughout the catalyst bed.

Abstract: Provided is a microwave catalyst. The microwave catalyst comprises: i) an active catalyst component comprising a metal and/or a metal oxide; ii) a microwave-absorbing component comprising at least one of CuO, ferrite spinel, and active carbon; and iii) a support. The microwave catalyst can be used for denitration by microwave catalysis, and has advantages such as high denitration efficiency, low energy consumption, environmental friendliness, and low costs. Also provided is a process for preparing the microwave catalyst and the use thereof.

Abstract: Aspects of the invention relate to hydrogenation catalysts, and hydrogenation processes using these catalysts, having particular characteristics, in terms of the amount and type of metal hydrogenation component (or catalytic constituent), as well as the support or substrate. The catalyst compositions, comprising both a noble metal and a lanthanide element on a substantially non-porous substrate, provide advantageous performance characteristics, including conversion, selectivity, and activity stability, as demanded in industrial hydrogenation and selective hydrogenation applications.

Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

Abstract: A method of producing a plurality of fiber catalyst is disclosed, the method includes the steps of: mixing a plurality of fiber material and a solvent to form a solution; putting the solution into a modeling container, to form at least one specific shape fiber body; applying a shaping process to the specific shape fiber body; and cutting or milling the specific shape fiber body to form a plurality of fiber catalyst.

Abstract: A carbon dioxide adsorbent may include an amorphous mixed metal oxide including a divalent first metal (M1), a trivalent second metal (M2) different from the divalent first metal (M1), an alkali metal (M3), and an element (A) with an electronegativity of about 2.0 to about 4.0. The alkali metal (M3) may be present in the form of a crystalline halide, an oxide, or a combination thereof. The carbon dioxide adsorbent may also be used in a method of separating carbon dioxide.

Abstract: A highly active supported bimetallic nanocatalyst and its preparation method is disclosed. During the preparation, using an ion exchange or absorption resin bearing basic functional groups as the support of the said catalyst, successively introducing the first metal precursor FeCl4? and the second metal precursor (PdCl42?, NiCl42? or CuCl42?) onto the resin through ion exchange process; then under the protection of nitrogen gas, simultaneously reducing the two metals with either NaBH4 or KBH4; washing the material with deoxygenated water and drying it, and the said catalyst is therefore obtained. The supported bimetallic material is characteristic of independent distribution of the two metals within the support. The independently distributed structure of the two metals enhances the catalytic efficiency of the second metal and the catalytic stability.

Abstract: The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.

Abstract: A process for preparing a silica-alumina composition containing of from 30 to 70% wt silica and of from 70 to 30% wt of alumina, which process comprises (a) preparing an aqueous mixture containing aluminum sulfate and having a pH in the range of from 1.0 to 6.5; (b) adding alkali metal aluminate to the mixture obtained in step (a) to increase the pH of the mixture to within the range of from 7.1 to 12; (c) adding aluminum sulfate to the mixture obtained in step (b) to lower the pH of the mixture to within the range of from 1.5 to 6.5; (d) adding alkali metal silicate to the mixture obtained in step (c) to increase the pH of the mixture to within the range of from 6.5 to 11, (e) adding aluminum sulfate to the mixture obtained in step (d) to lower the pH of the mixture to within the range of from 1.5 to 6.

Abstract: A method for making a catalyst composition suitable for various purposes, such as the reduction of nitrogen oxides, is provided. The method includes combining dawsonite or a dawsonite derivative with a catalytic active element.

Abstract: A method of manufacturing a remediation material uses a biogenic material as a substrate and involves preparing the surface of the substrate to enable a chemical reaction, and performing template-driven surface derivatization on the substrate to provide a net positive charge on the substrate. The remediation material may be placed into contact with surface water, ground water, soil, or sediment by at least one of a permeable reactive barrier, direct well injection, or direct introduction of the remediation material into soil or sediment, to remove contaminants from the surface water, ground water, soil, or sediment.

Abstract: A modified ion exchange resin catalyst having an attached dimethyl thiazolidine promoter is disclosed. Also disclosed is a process for catalyzing condensation reactions between phenols and ketones, wherein reactants are contacted with a modified ion exchange resin catalyst having an attached dimethyl thiazolidine promoter. Also disclosed is a process for catalyzing condensation reactions between phenols and ketones that does not utilize a bulk promoter.

Abstract: A method of steam reforming where a reaction occurs in which an oxygenated feed contacts a catalyst to produce hydrogen. The catalyst of the reaction comprises a metal/metal promoter on a nickel/transition metal blend catalyst supported on a high-energy lattice metal oxide.

Abstract: A method for providing superadsorption of polar organic compounds using a material system is provided. The method can comprise enhancing adsorption by means of using high surface area and mass transfer rates and decreased reactivity at surface sites attractive to the polar compounds; and employing consequence management by maintaining a high rate of adsorptivity combined with high fidelity and accuracy of the material system. A modified superadsorbent material for air sampling applications comprising a superadsorbent material treated with a solution, thereby forming a treated superadsorbent material, wherein the treated superadsorbent material is substantially hydrophobic and is capable of adsorbing polar compounds.

Abstract: Regenerable aromatization catalysts having high surface area and pore volume, as well as methods for producing these catalysts, are disclosed.

Abstract: A catalytic article for decomposition of a volatile organic compound includes a porous support body, a plurality of active centers formed on the support body and adapted for catalytic decomposition of the volatile organic compound, and a plurality of capture centers bound to the support body. Each of the active centers is composed of one of a noble metal, a transition metal oxide, and the combination thereof. Each of the capture centers includes at least one functional group that is adapted for attracting or binding the volatile organic compound. A method for preparing the catalytic article is also disclosed.

Abstract: Particles of a macro-porous ion exchange resin are dispersed in a solution of a transition metal compound, such as a compound of molybdenum, tungsten, or vanadium. The resin may be composed for anion exchange or cation ion exchange and, correspondingly, anions or cations of the metal are exchanged onto active ion exchange sites on the molecular chains of the resin. The resin is then carbonized and graphitized to form nanometer-size particles of transition metal carbide on particles of graphite. The composite metal carbide and graphite particles are electrically conductive and serve well as support particles for later deposited particles of a platinum group metal or other catalyst material in, for example, a catalytic electrode member in an electrochemical cell.

Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

Abstract: Systems for treating exhaust gas incorporating catalysts comprising metal-loaded non-zeolitic molecular sieves having the CHA crystal structure, including Cu-SAPO-34, and methods for preparing such catalysts are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stability at high reaction temperatures.

Abstract: A method for modifying the properties of a sorbent comprising washing a sorbent with a washing solution so as to achieve an exchange of ions between the sorbent and the washing solution, and applying a halogen compound to the sorbent that has been washed with the washing solution to achieve a predetermined concentration of the halogen on the sorbent.

Abstract: A process for the dimerization of isoolefins, including: contacting an isoolefin with a solid catalyst composition passivated with at least one of an ether, an alcohol, and water; wherein the solid catalyst composition comprises at least one of a solid phosphoric acid catalyst and a resin of a macroporous matrix of polyvinyl aromatic compound crosslinked with a divinyl compound and having thereon from about 3 to 5 milli equivalents of sulfonic acid groups per gram of dry resin; and wherein at least 50% to less than 100% of acid groups in the solid catalyst composition are neutralized with a metal of Al, Fe, Zn, Cu, Ni, or mixtures thereof. The catalyst may be metalized prior to placement in a reactor or may be metalized in situ.

Abstract: The invention has for its object to provide a preparation method for preparing an anion-exchangeable LDH by decarbonation of a carbonate ion type LDH, which makes sure de carbonation is implemented with safety in a continuous manner while crystal shape, crystal structure and crystallinity are kept intact. The invention provides a preparation method for preparing an anion-exchangeable, layered double hydroxide wherein a carbonate ion type layered double hydroxide (LDH) having a composition represented by a general formula: QxR(OH)z(CO32?)0.5-y/2(X?)y.nH2O where x is indicative of a numeral range of 1.8?x?4.

Abstract: Disclosed is a method of preparing hydrotalcite having superior anion exchange capability and heat stability by forming a seed so that CO32? ions are located to be maximally stable between Mg—Al layers and then conducting primary crystallization and secondary crystallization.

Abstract: A process for producing catalyst for biomass catalytic cracking is disclosed herein. The process includes modifying a phyllosilicate to produce a modified phyllosilicate having an improved yield of a pyrolysis reaction. The modification of the phyllosilicate includes leaching the clay with an acid or basic solution to form a leached clay preparation, calcining the leached clay and contacting the treated clay with a suspension comprising metal ions for ion-exchange. The modified clay catalyst can then be mixed with inorganic materials such as zeolites and dried to form fluidizable microspheres.

Abstract: A method for enhancing heterogeneous asymmetric selectivity and catalytic activity belongs to the field of catalytic asymmetric organic synthesis technology, the preparation method of the invention are as follows: firstly preparing the chiral L-amino acids intercalated LDHs by coprecipitation or ion-exchange method; exfoliating the chiral L-amino acids intercalated LDHs into dispersed system of chiral L-amino acids attached to the inorganic LDH nanosheets; then coordinating the L-amino acids in the above dispersed systems with the metal centers for different types of asymmetric catalytic reactions. The results show that the as-prepared catalyst can enhance the asymmetric selectivity effectively. Compared with the homogeneous counterparts under the same reaction conditions, the catalyst exhibits relatively higher yields and largely improves the selectivity of the asymmetric reaction products; and thus the chiral compounds with a higher optical purity can be obtained.

Abstract: A visible light sensitive photocatalyst including a compound represented by Formula 1: Aa-xM1xSib-yM2yOc??Formula 1 wherein A is one or more metals selected from Ag, Cu, and Au; M1 is one or more metals selected from Li, Na, K, Rb, and Cs; M2 is one or more metals selected from Ge, Sn, Ti, Zr, and Hf, and 1.7?a?2.3, 0.7?b?1.3, 2.7?c?3.3, 0?x<a, and 0?y<b.

Abstract: Ceramic catalyst carriers that are mechanically, thermally and chemically stable in a ionic salt monopropellant decomposition environment and high temperature catalysts for decomposition of liquid high-energy-density monopropellants are disclosed. The ceramic catalyst carrier has excellent thermal shock resistance, good compatibility with the active metal coating and metal coating deposition processes, melting point above 1800° C., chemical resistance to steam, nitrogen oxides and acids, resistance to sintering to prevent void formation, and the absence of phase transition associated with volumetric changes at temperatures up to and beyond 1800° C.

Abstract: Aspects of the invention relate to hydrogenation catalysts, and hydrogenation processes using these catalysts, having particular characteristics, in terms of the amount and type of metal hydrogenation component (or catalytic constituent), as well as the support or substrate. The catalyst compositions, comprising both a noble metal and a lanthanide element on a substantially non-porous substrate, provide advantageous performance characteristics, including conversion, selectivity, and activity stability, as demanded in industrial hydrogenation and selective hydrogenation applications.

Abstract: The present invention provides a process for producing bisphenol A by reacting phenol with actone, wherein reaction is performed at higher temperatures while maintaining high selectivity, and thus high productivity is obtained. The invention relates to a cation-exchange resin, wherein a cation-exchange group is introduced into a syndiotactic polystyrene polymer and the amount of acid is 0.8 milliequivalent/g or more, to a catalyst comprising the cation-exchange resin, and to a process for producing bisphenol A using a cation-exchange resin catalyst.

Abstract: A method for making a catalyst composition suitable for various purposes, such as the reduction of nitrogen oxides, is provided. The method includes combining dawsonite or a dawsonite derivative with a catalytic active element.

Abstract: Provided is a method of fabricating of a nanowire porous medium and a medium formed by the method. In this method, water and organic solvent are mixed and stirred to form a large amount of bubbles, and the bubbles are used such that porosity can be formed more easily and in a more amount. Therefore, the nanowire porous medium can be fabricated more easily and simply. Also, in the nanowire porous medium according to the inventive concept, absorption capacity is increased by containing nanowires, and flexibility and durability are increased by containing a polymer.

Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered in a chemical precipitation step, wherein the supernatant is mixed with at least one of an acid, a sulfide-containing compound, a base, and combinations thereof to precipitate at least 50% of metal ions in at least one of the metal residuals, wherein the precipitation is carried out at a pre-select pH. The precipitate is isolated and recovered, yielding an effluent stream. The precipitate and/or the effluent stream can be further treated to form at least a metal precursor feed which can be used in the co-precipitation reaction. The process generates an effluent to waste treatment containing less than 50 ppm metals.

Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant. In the present disclosure, the metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals is recovered as a metal precursor feed, which can be recycled for use in the co-precipitation reaction. An effluent stream from the process to waste treatment contains less than 50 ppm metal ions.

Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of the metal precursor feeds end up in the supernatant. The metals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of metal ions in at least one of the metal residuals, and for at least one of the metal residuals recovered as a metal precursor feed for use in the co-precipitation reaction. In one embodiment, the resin functions as an anion exchange resin with an acidic supernatant to recover Group VIB metal residuals, and a cation exchange resin with a basic supernatant to recover Promoter metal residuals. An effluent stream from the process to waste treatment contains less than 50 ppm metals.

Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor made in a co-precipitation reaction, up to 60% of metal ions in at least one of the metal precursor feeds do not react to form catalyst precursor and end up in the supernatant as metal residuals. In the present disclosure, the metals can be recovered via ion-exchange, wherein an exchange resin is provided for a portion of the metal ions in the supernatant to be exchanged and bound onto the resin. The previously resin-bound metals can be subsequently recovered, or the effluent stream for the exchange resin column can also be recovered, forming at least a metal precursor feed which can be used in the co-precipitation reaction.

Abstract: In a process for forming a bulk hydroprocessing catalyst by sulfiding a catalyst precursor in a co-precipitation reaction, up to 60% of the metal precursor feeds do not react to form catalyst precursor and stay in the supernatant. In one embodiment, at least a precipitant is added to the product mixture at a molar ratio of precipitant to metal residuals in the supernatant ranging from 1.5:1 to 20:1 to precipitate at least 50 mole % of metal ions in the residuals forming additional catalyst precursor. The remaining metal residuals can be recovered via any of chemical precipitation, ion exchange, electro-coagulation, and combinations thereof to generate an effluent stream containing less than 50 mole % of at least one of the metal residuals. In one embodiment, at least one of the metal residuals is recovered and recycled for use as a metal precursor feed in the co-precipitation reaction.

Abstract: Ceramic catalyst carriers that are mechanically, thermally and chemically stable in a ionic salt monopropellant decomposition environment, high temperature catalysts for decomposition of liquid high-energy-density monopropellants and ceramic processing techniques for producing spherical catalyst carrier granules are disclosed. The ceramic processing technique is used to produce spherical catalyst carrier granules with controlled porosities and desired composition and allows for reproducible packing densities of catalyst granules in thruster chambers. The ceramic catalyst carrier has excellent thermal shock resistance, good compatibility with the active metal coating and metal coating deposition processes, melting point above >2300° C., chemical resistance to steam, nitrogen oxides and nitric acid, resistance to sintering to prevent void formation, and the absence of phase transition associated with volumetric changes at temperatures up to and beyond 1800° C.

Abstract: Catalyst ink comprising one or more catalyst materials, a liquid medium and polymer particles comprising one or more proton-conducting polymers, an electrode comprising at least one catalyst ink according to the present invention, a membrane-electrode assembly comprising at least one electrode according to the invention or comprising at least one catalyst ink according to the present invention, a fuel cell comprising at least one membrane-electrode assembly according to the invention and also a process for producing a membrane-electrode assembly according to the present invention.

Abstract: The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.

Abstract: Systems for treating exhaust gas incorporating catalysts comprising metal-loaded non-zeolitic molecular sieves having the CHA crystal structure, including Cu-SAPO-34, and methods for preparing such catalysts are disclosed. The catalysts can be used to remove nitrogen oxides from a gaseous medium across a broad temperature range and exhibit hydrothermal stability at high reaction temperatures.

Abstract: Novel metal-containing silicates, in particular redox-active as well as crystalline silicates, a process for preparing metal-containing crystalline silicates, as well as use thereof as high-temperature oxidation catalyst or diesel oxidation catalyst. Further, a catalytic composition and a shaped catalyst body which contains the metal-containing crystalline silicates.

Abstract: A method is disclosed of preparing a catalyst, including contacting a substrate with at least one solution including a first promoter being Cs and at least one solution including a second promoter. The contact subjects the substrate to the addition of the first and second promoters, thereby forming the catalyst comprising the first and second promoters. In the method disclosed, the second promoter is capable of undergoing a redox reaction.

Abstract: A method and adsorbent composition for removing heavy metals from contaminated water, comprising passing a stream of water having a concentration of one or more heavy metals through an adsorbent comprising granules of a mixture of from about 1 wt % to about 15 wt % clay and a thermoplastic polymer matrix; and collecting water having a reduced concentration of said heavy metal(s) downstream of said adsorbent.