Synthetic Resin Patents (Class 502/402)
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Patent number: 11958035Abstract: Polypropylene (PP) and polyethylene (PE) blends derived from plastic waste streams and a method to prepare reusable oil sorbents. A method includes separating plastics of group-A from group-B using a float-sink technique, where group-A comprises various PP and PE materials, and group-B comprises polystyrene, polyethylene terephthalate, and polyvinyl chloride; dissolving the group-A plastics in a solvent; adding a cavity forming agent to the solution; applying the solution onto a solid substrate through spin-coating followed by controlled heating; and extracting the cavity forming agent, obtaining a thin film sorbent with swellable cavities for oil sorption. The film contains 400-800 swellable 3D cavities/cm2, each cavity capable of swelling 20-30 times the thickness of the film when contacted with oil.Type: GrantFiled: August 21, 2023Date of Patent: April 16, 2024Assignee: KING FAISAL UNIVERSITYInventors: Junaid Saleem, S K Safdar Hossain, Zubair Khalid Baig Moghal, Gordon McKay
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Patent number: 11958037Abstract: A method of preparing a superabsorbent polymer having a rapid absorption rate and an improved water retention capacity by additional heat treatment while using a thermally degradable internal crosslinking agent and an encapsulated foaming agent at the same time during polymerization. A superabsorbent polymer prepared by this method is also provided, the superabsorbent polymer having a centrifuge retention capacity (CRC) of 40 g/g to 55 g/g, as measured according to EDANA method WSP 241.3, and an absorption rate of 48 sec or less, as measured by a vortex method.Type: GrantFiled: December 12, 2019Date of Patent: April 16, 2024Assignee: LG Chem, Ltd.Inventors: Jinuk Choi, Yesol Yang, Sanghwa Lee, Gicheul Kim, Ki Hyun Kim, Seul Ah Lee
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Patent number: 11931718Abstract: Water-absorbing resin particles have a repulsion rate of 5% or more according to the formula (h3?h2)/h1×100(%) when a cylinder with an inner diameter of 25.4 mm, which has a mesh-like bottom onto which 0.2 g of the water-absorbing resin particles are sprinkled, is placed in a container having ion exchange water in an amount of 30 times a mass of the water-absorbing resin particles, where h1 represents a free swelling height (mm) of the water-absorbing resin particles after 1 minute from initiation of water absorption, h2 represents a height (mm) of the water-absorbing resin particles after a load of 1.3×103 Pa is applied to the water-absorbing resin particles for 1 minute after 1 minute from initiation of the water absorption, and h3 represents a height (mm) of the water-absorbing resin particles after 1 minute from release of the load applied when measuring h2.Type: GrantFiled: March 27, 2019Date of Patent: March 19, 2024Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Takashi Ito, Miki Sakoda, Mutsumi Matsuoka
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Patent number: 11931721Abstract: A composition for treating water including an organic soil amendment and having ions bound thereto is beneficial to aid in the removal of aqueous contaminants, such as phosphate, other phosphorus containing compounds, arsenic, arsenic containing compounds, fluorides, and PFAS from water. In these compositions the ions include rare earth cations, iron cations, and mixtures thereof. There are also methods for making these soil amendment compositions, as well as methods for using these compositions to effectively remove contaminants from water.Type: GrantFiled: April 11, 2022Date of Patent: March 19, 2024Assignee: Neo Water Treatment, LLCInventor: Mason Reames Haneline
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Patent number: 11911746Abstract: A method for manufacturing a water absorption treatment material made of a plurality of grains includes a preparing step, a pulverizing step, a core portion forming step, and a coating portion forming step. The preparing step is a step of preparing a paper powder to which water-absorbent polymers adhere, the paper powder being derived from a sanitary product. The pulverizing step is a step of pulverizing remaining polymers using a pulverizer. The core portion forming step is a step of forming a core portion constituting each of the grains The coating portion forming step is a step of forming a coating portion so as to cover the core portion, the coating portion containing the paper powder, and the remaining polymers pulverized in the pulverizing step. In the pulverizing step, the remaining polymers left in a state of adhering to the paper powder are subjected to the pulverizer.Type: GrantFiled: October 29, 2020Date of Patent: February 27, 2024Assignee: DAIKI CO., LTD.Inventor: Junji Yoshinaga
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Patent number: 11896953Abstract: Polymeric adsorbents useful for solid phase extraction (SPE) comprising a copolymer formed by copolymerizing at least one hydrophobic monomer including divinylbenzene and at least one hydrophilic monomer including acrylonitrile are provided. Also provided are SPE cartridges including a divinylbenzene-acrylonitrile hydrophilic-lipophilic balance adsorbent. Further provided are methods of using a divinylbenzene-acrylonitrile hydrophilic-lipophilic balance adsorbent in conventional and simplified SPE techniques.Type: GrantFiled: August 24, 2018Date of Patent: February 13, 2024Assignee: Sigma-Aldrich Co. LLCInventors: William Betz, Curtis Frantz, Michael Keeler, Michael Ye, Ken Espenschied, Sara Smith, Brittany A. Smith
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Patent number: 11874206Abstract: A device for extracting a molecule of interest from a sample matrix. The device includes a support comprising a support surface; a sealing layer that at least partially coats the support surface; and an extractive phase coating applied to a portion of the sealing layer. The extractive phase coating is adapted to contain the molecule of interest. The sealing layer sufficiently coats the support surface to prevent the support surface from coming in contact with the sample matrix when the extractive phase coating is fully immersed in the sample matrix. Analytical screening devices and methods of manufacture are also disclosed.Type: GrantFiled: November 20, 2020Date of Patent: January 16, 2024Assignee: JP SCIENTIFIC LIMITEDInventors: Janusz B. Pawliszyn, Abir Khaled
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Patent number: 11865496Abstract: Some aspects of the present disclosure relate to a method comprising obtaining a sorbent polymer composite material, contacting the sorbent polymer composite material with mercury vapor to form a used sorbent polymer composite material; wherein the used sorbent polymer composite material comprises oxidized mercury and wherein the used sorbent polymer composite material emits oxidized mercury vapor; and contacting the used sorbent polymer composite material with a halogen source, so as to result in a treated sorbent polymer composite material. In some embodiments, the treated sorbent polymer composite material emits less than 0.01 ?g oxidized mercury vapor per minute per gram of the treated sorbent polymer composite, compared to a used sorbent polymer composite, when measured at 65° C. in air having a relative humidity of 95%.Type: GrantFiled: May 12, 2020Date of Patent: January 9, 2024Assignee: W. L. Gore & Associates, Inc.Inventor: Steven J. Hardwick
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Patent number: 11866528Abstract: A polymer comprising a structural unit derived from a compound (A) represented by formula (I): wherein X, Y, R1, R2, R7, R8, R3, R4, R5, R6, J, and n are as defined in the description, provides a resin composition that has an excellent curability and sufficiently polymerizes for curing even in the presence of oxygen in an air atmosphere to form a cured product having excellent appearance.Type: GrantFiled: April 12, 2019Date of Patent: January 9, 2024Assignee: KURARAY CO., LTD.Inventors: Daiki Noguchi, Takashi Fukumoto, Keiji Kubo
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Patent number: 11857945Abstract: Disclosed is the use of a composite for extracting one or more metal or contaminating chemical species from an aerial or aqueous medium by selective binding, the composite including at least one porous template functionalized by at least one polymer, the polymer including one of the following chemical functions: primary, secondary or tertiary amine, amide, nitrile, pyridine, pyrole, thiol, thiolether, thiophene, thiadiazole, alcohol/hydroxyl, phenol, catechol, pyragalol, carboxylic acid, aldehyde, ester, acyl, crown ether, phosphate, phosphoryl, epoxide, halogen, haloalkane.Type: GrantFiled: January 18, 2022Date of Patent: January 2, 2024Assignee: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL)Inventors: Wendy Lee Queen, Daniel Teav Sun
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Patent number: 11857949Abstract: A packing material, wherein to a porous organic polymer carrier including 60 to 95 mol % of a repeating unit derived from glycidyl methacrylate and 5 to 40 mol % of a repeating unit derived from a polyfunctional monomer, one end of at least one alkylene group selected from a linear alkylene group, a cycloalkylene group, and a linear alkylcycloalkylene group, having 4 to 9 carbon atoms is bonded by a glycidyl group derived from glycidyl methacrylate, and an other end of the alkylene group is bonded to any one end of a polyol via an ether bond.Type: GrantFiled: June 3, 2022Date of Patent: January 2, 2024Assignee: Resonac CorporationInventors: Naoki Uchiyama, Yuzuru Kokido
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Patent number: 11850571Abstract: This disclosure provides polyamine sorbent compositions for the separation of metals from aqueous solutions. The polyamine sorbent compositions comprise a silica support, an aminosilane bound to the silica support, an epoxysilane bound to the silica support, and a polyamine where the polyamine is chemically tethered onto a solid silica support through via the epoxysilane. The polyamine may be further stabilized within the bulk sorbent through hydrogen bonding interactions with the aminosilane. The sorbent compositions resist leaching by H2O in an aqueous stream containing heavy oxyanion-based (and other) metals and demonstrate stability over a pH range of 2-14. The sorbent compositions are useful for the separation of metals from aqueous solutions. The cationic heavy metals are captured by the co-existing amine groups (—NH2, —NH, —N) from the polymeric network while additional metal capture capacity is derived from the introduction of a secondary silane linker.Type: GrantFiled: July 20, 2020Date of Patent: December 26, 2023Assignee: United States Department of EnergyInventors: McMahan L Gray, Brian W. Kail, Walter Christopher Wilfong, Qiuming Wang, Fan Shi
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Patent number: 11845837Abstract: A super absorbent polymer according to the present invention has excellent dryness while maintaining excellent absorption performance, and thus is preferably used for hygienic materials such as diapers, and can exhibit excellent performance.Type: GrantFiled: March 9, 2021Date of Patent: December 19, 2023Inventors: Dae Woo Nam, Jun Kyu Kim, Hyung Ki Yoon, Tae Hwan Jang, Bo Hyun Seong, Yeon Woo Hong, Su Jin Kim, Seong Beom Heo, Seon Jung Jung, Ji Yoon Jeong
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Patent number: 11819823Abstract: Thermo-responsive hydrogel composite (TRHC) desiccants having high adsorption capacities, fast adsorption/desorption rates, and low regeneration temperatures (Treg) compared to traditional desiccants. TRHC desiccants may be synthesized by freeze drying. The porous structures resulting from freeze drying copolymers of thermo-responsive polymers and/or hygroscopic agents may be combined with hygroscopic inorganic salts, resulting in TRHC desiccants having superior performance properties.Type: GrantFiled: September 3, 2021Date of Patent: November 21, 2023Assignees: Alliance for Sustainable Energy, LLC, The Regents of the University of CaliforniaInventors: Shuang Cui, Jason David Woods, Renkun Chen, Paul William Meyer
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Patent number: 11813589Abstract: In an improved superabsorbent complexed with aluminum ions, the aluminum ions are applied in the form of an aqueous solution comprising aluminum ions, which has the feature that it comprises aluminum ions in a proportion within the range of 0.5%-15% by weight (converted if appropriate to Al3+), based on the total mass of the solution, and further comprises anions of lactic acid (lactate ions) and phosphoric acid (phosphate ions), where the molar proportion of the lactate ions is within the range of 0.01-2.99 times the molar amount of Al3+ and the molar proportion of the phosphate ions is within the range of 0.01-2.99 times the molar amount of Al3+.Type: GrantFiled: October 31, 2018Date of Patent: November 14, 2023Assignee: BASF SEInventors: Kristine Hartnagel, Wanthip Poomsuwan, Patrick Neal Hamilton, Norbert Herfert, Thomas Daniel, Olaf Hoeller
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Patent number: 11794464Abstract: An absorbent pad has: a first, outer layer comprising a permeable or non-permeable film; a second, outer layer comprising a permeable or non-permeable film, placed on a side of the pad opposite the first, outer layer; a third layer disposed between the first layer and the second layer, and comprising a tissue laminate comprising at least a first ply and a second ply, with at least one chemical agent or system fixed in the third layer and being either activated by contact with or soluble in an aqueous liquid, the at least one chemical agent or system being in a predetermined amount distributed substantially uniformly per unit area of the surface area between the at least first ply and second ply: and a fourth layer disposed between the first layer and the second layer and comprising fluff, with or without a chemical agent or system, the third layer being joined to the fourth layer to serve as a substrate for the fourth layer.Type: GrantFiled: January 4, 2021Date of Patent: October 24, 2023Assignee: Novipax Buyer, LLCInventors: Lindsay Riehle, Brett Stoll, Frank Vaughn, Sophia Smeragliuolo, Rich Beu
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Patent number: 11786884Abstract: Superabsorbent polymers are made of copolymers including a major portion of low molecular weight monomers each individually including a backbone and a charged moiety, a minor portion of high molecular weight monomers each individually including a backbone and a charged moiety, and optionally a crosslinker. The copolymer-based superabsorbent polymers have significantly improved absorbency under load.Type: GrantFiled: April 30, 2020Date of Patent: October 17, 2023Assignee: KIMBERLY-CLARK WORLDWIDE, INC.Inventors: Xuedong Song, Kaiyuan Yang, Todd Ryan Hoare, Zohreh Jomeh Farsangi
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Patent number: 11760952Abstract: The present disclosure provides a soap thickener and methods of making the same. The soap thickener includes a metal soap of a carboxylic acid composition in a base oil, wherein the carboxylic acid composition includes a modified fatty acid composition prepared by performing a pericyclic reaction between an unsaturated small molecule and a fatty acid mixture. The present disclosure further provides lubricating compositions that include the soap thickener of the present disclosure and methods of preparing the same.Type: GrantFiled: January 8, 2022Date of Patent: September 19, 2023Assignee: INGEVITY SOUTH CAROLINA, LLCInventor: Devin Granger
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Patent number: 11760033Abstract: The polymeric composition of this invention can be used as a temporary support material in the additive manufacturing of three dimensional articles without compromising the quality of the ultimate product, reducing printing speed, increasing cost, increasing the incidence of printer jamming, or requiring printers of increased complexity. This invention more specifically discloses a polymeric composition which is particularly useful as a temporary support material for utilization in three-dimensional printing, said polymeric composition being comprised of a first polymeric component which is suitable for use as a modeling material and a second polymeric component which is immiscible with the first polymeric component, wherein the polymeric composition has a continuous phase, wherein the continuous phase is comprised of the second polymeric component, and wherein the polymeric composition has a Shore A hardness of at least 80.Type: GrantFiled: September 1, 2021Date of Patent: September 19, 2023Assignee: JF POLYMERS (SUZHOU) CO. LTD.Inventors: Xiaofan Luo, Zhaokun Pei, Haiqing Yin
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Patent number: 11738328Abstract: One or more embodiments relates to method for generating CHEFS having the steps of generating the CHEFS from a dope. One or more embodiments relates to a method for generating CHEFS having amine functional groups having the steps of generating a dope containing a BIAS with amine groups, at least one polymer, and at least one solvent; and forming CHEFS from the dope, wherein the generated CHEFS have no more than 30% amine loss compared to the BIAS.Type: GrantFiled: April 30, 2021Date of Patent: August 29, 2023Assignee: United States Department of EnergyInventors: McMahan L. Gray, Fan Shi, Shouliang Yi, Walter Chris Wilfong, Qiuming Wang
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Patent number: 11725182Abstract: Provided for are methods of producing triacylglycerol-accumulated microalgae, methods for making bioplastics from triacylglycerol-accumulated microalgae, methods for making alga-mixed plastics, and products including these bioplastics. Methods of triacylglycerol accumulation using centrifugation are also provided. Products such as plastic beads and other consumer products can be made from the bioplastics described herein.Type: GrantFiled: October 9, 2018Date of Patent: August 15, 2023Assignee: Board of Supervisors of Louisiana State UniversityInventor: Naohiro Kato
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Patent number: 11718742Abstract: A superabsorbent polymer composition exhibiting very improved antimicrobial and deodorizing properties while maintaining basic absorption performance, and can significantly reduce the generation of dust during the application for a process, and thus fulfills both stability and processability and can be usefully applied for hygienic goods such as a diaper and the like. The superabsorbent polymer composition includes: a) superabsorbent polymer particles including a crosslinked polymer of water-soluble ethylenically unsaturated monomers including acid groups, of which at least a part are neutralized, and b) an antimicrobial agent having a controlled particle size, containing a chelating agent including EDTA or an alkali metal salt thereof; a mixture of an organic acid and a silicate-based salt; and an agent for controlling a particle size.Type: GrantFiled: January 9, 2019Date of Patent: August 8, 2023Inventors: Jin Woo Lee, Youngsam Kim
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Patent number: 11679375Abstract: The present disclosure is directed to methods and systems of purifying solvents. The purified solvents can be used for cleaning a semiconductor substrate in a multistep semiconductor manufacturing process.Type: GrantFiled: August 27, 2020Date of Patent: June 20, 2023Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Stephen Earl Dyer, Brendan Thomas Lane, Patrick Adams Mahoney, Sr.
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Patent number: 11673116Abstract: The present invention relates to a superabsorbent polymer and a method for producing the same. The superabsorbent polymer includes a core layer polymerized with monomers having carboxylic group, a first shell layer formed from a surface crosslinking agent, and a second shell layer formed from zingiberaceae extracts. By a surface modification on the first shell layer performed from a specific amount of the zingiberaceae extracts, the superabsorbent polymer produced according to the method for producing the same has a good antimicrobial property and deodorizing effects, and retains an original absorbent property.Type: GrantFiled: August 10, 2021Date of Patent: June 13, 2023Assignee: FORMOSA PLASTICS CORPORATIONInventors: Zhong-Yi Chen, Cheng-Lin Lee, Feng-Yi Chen, Yu-Yen Chuang
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Patent number: 11655318Abstract: A method of preparing super absorbent polymer includes carrying out a crosslinking polymerization of a monomer mixture comprising a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups, a forming agent, a foam-promoting agent and a silicone-based surfactant in the presence of an internal crosslinking agent to form a hydrogel polymer; drying, pulverizing and classifying the hydrogel polymer to form a base polymer powder; and further crosslinking a surface of the base polymer powder in the presence of a surface crosslinking agent to form a surface crosslinked layer. The method produces super absorbent polymer having not only an excellent absorbent capacity and an absorbency under load but also the rewetting phenomenon can be effectively prevented.Type: GrantFiled: September 30, 2020Date of Patent: May 23, 2023Inventors: Sang Gi Lee, Hye Mi Nam, Min Ho Hwang, Soo Jin Lee, Tae Hwan Jang
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Patent number: 11654416Abstract: The present invention relates to a super-absorbent polymer having excellent properties, both centrifugal retention capacity (CRC) and absorption under pressure (AUP) having been improved by introducing a surface crosslinked layer crosslinked by surface-modified inorganic particles, and to a method for preparing the same. The super-absorbent polymer comprises: a base resin powder containing a crosslinked polymer of water-soluble ethylene-based unsaturated monomers having an at least partially neutralized acidic group; and a surface crosslinked layer formed on the base resin powder, wherein inorganic particles may be chemically bound to the crosslinked polymer contained in the surface crosslinked layer, via an oxygen-containing bond or a nitrogen-containing bond.Type: GrantFiled: March 5, 2021Date of Patent: May 23, 2023Inventors: Sung Soo Park, Gi Cheul Kim, Ju Eun Kim, Hyeon Choi, Hyo Sook Joo, Sung Hyun Park, Hee Jung Choi, Ki Youl Yoon
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Patent number: 11648531Abstract: The method for preparing a super absorbent polymer according to the present disclosure reduces the generating amount of a fine powder while realizing the same particle size distribution in the process of pulverizing the dried polymer, thereby reducing the load of the fine powder reassembly, drying, pulverizing and classifying steps.Type: GrantFiled: August 16, 2019Date of Patent: May 16, 2023Inventors: Yoon Jae Min, Jong Hun Song, Gicheul Kim, Jae Yul Kim, Heechang Woo
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Patent number: 11648532Abstract: An absorbent compound and method of making the same, where the absorbent compound includes an amine oxide that comprises about 30% to about 55% of the absorbent compound and a polymer that comprises about 30% to about 55% of the absorbent compound.Type: GrantFiled: December 17, 2019Date of Patent: May 16, 2023Inventor: Jason Thor
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Patent number: 11602732Abstract: Polymer sorbents selectively remove cytokines and bacterial endotoxins from whole blood and other body liquids, in particular blood plasma, lymph etc., as well as from aqueous protein solutions and aqueous organic compound solutions, also containing inorganic salts. The sorbent is able to remove both cytokines and bacterial endotoxins, improve selectivity of the polymer sorbents in respect to the compounds as well as provide a simple and effective method of producing said sorbent.Type: GrantFiled: May 17, 2018Date of Patent: March 14, 2023Assignee: EFFERON GMBHInventors: Ivan Viktorovich Bessonov, Alexey Sergeevich Morozov, Maria Nikolaevna Kopitsyna
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Patent number: 11602585Abstract: Provided herein are materials and methods of reducing contamination in a biological substance or treating contamination in a subject by one or more toxins comprising contacting the biological substance with an effective amount of a sorbent capable of sorbing the toxin, wherein the sorbent comprises a plurality of pores ranging from 50 ? to 40,000 ? with a pore volume of 0.5 cc/g to 5.0 cc/g and a size of 0.05 mm to 2 cm and sorbing the toxin. Also provided are kits to reduce contamination by one or more toxins in a biological substance comprising a sorbent capable of sorbing a toxin, wherein the sorbent comprises a plurality of pores ranging from 50 ? to 40,000 ? with a pore volume of 0.5 cc/g to 5.0 cc/g and a size of 0.05 mm to 2 cm and a vessel to store said sorbent when not in use together with packaging for same.Type: GrantFiled: April 26, 2017Date of Patent: March 14, 2023Assignee: CytoSorbents CorporationInventors: Phillip P. Chan, Vincent J. Capponi, Thomas D. Golobish, Humayra Begum Ali
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Patent number: 11577219Abstract: Method for preparing a natural organic macromolecular water treatment agent including: dissolving amylose corn starch in an alkali solution, stirring for 30 min, to obtain a suspension, freezing the suspension to fully frozen state, melting and dialyzing, to obtain a corn starch dispersion; mixing a modified flax fiber, the dispersion, nano-hybrid silica and distilled water, performing 800 W ultrasonication for 10 min, to obtain a treated suspension; taking an amount of a superabsorbent macromolecular resin with a certain shape, making it absorb water and swell into a solid hydrogel with the certain shape; mixing the solid hydrogel and the treated suspension, static defoaming, loading into a mold and solidifing, drying until the solid hydrogel is completely dehydrated, to obtain a hollow agent; spraying a catalytic degrading agent/toxin degrading agent on the surface of the hollow agent and/or the inner wall of holes thereof, to obtain the target agent.Type: GrantFiled: July 23, 2021Date of Patent: February 14, 2023Inventors: Jun Liu, Yuguo Zhuo, Jinming Zhuo
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Patent number: 11530174Abstract: The present invention discloses a method for separating propylene, propyne, propane and propadiene from mixed gas, wherein, comprising: a high purity component can be obtained as metal-organic frameworks as adsorbents through adsorptive separation and purification of a mixed gas containing propylene, propyne, propane and propadiene a general structural formula of the metal-organic framework material is [M(C4O4)(H2O)]·1.5H2O, wherein M is metal ions, the metal-organic framework material is a three-dimensional network structure formed by transition metal ions or alkaline earth metal ions and squaric acid through coordination bonds or intermolecular forces. The metal-organic framework materials of the present invention exhibit excellent adsorption and separation performances for propylene, propyne, propane and propadiene. The cheap and available raw materials for the synthesis, simple operation, and low cost make it cost-efficient for preparation of such metal-organic frameworks.Type: GrantFiled: October 24, 2019Date of Patent: December 20, 2022Assignee: ZHEJIANG UNIVERSITYInventors: Zongbi Bao, Liangying Li, Qilong Ren, Zhiguo Zhang, Yiwen Yang, Qiwei Yang
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Patent number: 11524274Abstract: An absorbent is provided, which is produced from component A, a foaming agent, and component B, a resin. Furthermore, a device and a method for producing the absorbent and a method for absorbing a liquid by means of the absorbent are provided.Type: GrantFiled: August 21, 2017Date of Patent: December 13, 2022Assignee: OTEX AGInventor: Alexandre Mäder
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Patent number: 11525028Abstract: The thermoplastic polyurethane (TPU) compositions described herein have biodegradable and/or bioabsorbable hard and soft segments. The TPU hard segment can be formed from a polyisocyanate and a 2,5-substituted diketopiperazine.Type: GrantFiled: August 6, 2020Date of Patent: December 13, 2022Assignee: Lubrizol Advanced Materials, Inc.Inventors: Cathrin G. Kirchhoefer, Andrew P. Dove, Anthony J. Walder
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Patent number: 11518699Abstract: A two-step process for recovering useable solids from food processing wastewater and for significantly reducing the pollutants, chemical, bacterial, and viral load. The first step is the addition of pretreatment chemicals such as metal-based coagulant, pH adjuster, oxidant or a combination thereof. The second step is pumping the chemically pretreated wastewater into a foam fractionation system where a gas is introduced into the chemically treated wastewater to create a rising foam that captures and remove solid materials from the remaining wastewater effluent. The solids are recovered for additional post-processing and the effluent is discharged for post-processing or to existing bodies of water.Type: GrantFiled: March 27, 2020Date of Patent: December 6, 2022Assignee: AQUA-TERRA CONSULTANTSInventor: Alan Ismond
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Patent number: 11498050Abstract: A method of preparing a superabsorbent polymer, which enables the preparation of the superabsorbent polymer exhibiting an improved absorption rate while maintaining excellent absorption performances is provided.Type: GrantFiled: November 15, 2019Date of Patent: November 15, 2022Inventors: Kyu Pal Kim, Jinuk Choi, Sang Hwa Lee, Gicheul Kim, Ki Hyun Kim, Seul Ah Lee
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Patent number: 11491463Abstract: Superabsorbent mixtures M comprising at least 70% by weight of superabsorbent A having a liquid absorption of 20 g/g (T20) of less than 300 s and/or a volumetric liquid absorption under pressure 0.3 psi (2.07 kPa) (VAUL) with a ? value of less than 400 s, and at least 5% by weight of superabsorbent B having a centrifuge retention capacity (CRC) of at least 30 g/g.Type: GrantFiled: January 2, 2019Date of Patent: November 8, 2022Assignee: BASF SEInventors: Stephan Bauer, Katrin Baumann, Markus Toennessen, Christophe Bauduin, Markus Christian Biel, Thomas Daniel
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Patent number: 11491461Abstract: A method and apparatus for removing an organosilicon component from a mixture are disclosed. The method and apparatus employ a copolymer of a di-alkenyl functional aromatic hydrocarbon and a polyorganosiloxane as the sorbent.Type: GrantFiled: February 28, 2018Date of Patent: November 8, 2022Assignee: Dow Silicones CorporationInventors: Dongchan Ahn, Aaron Greiner, Robert Huber, James Thompson
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Patent number: 11491465Abstract: A silica-based stationary phase for chromatography columns and the methods of preparing such. More particularly, but not by way of limitation, a silica-based stationary phase that is substantially free of polyethers (e.g., polymer glycols). Also, a chromatography column comprising a silica-based stationary phase substantially free of polyethers (e.g., polymer glycols) within its channels as either a thin-film coating and/or a monolith and/or a monolithic coating. More particularly, a micro-electro-mechanical system (MEMS) chromatograph comprising a silica-based monolith substantially free of polyethers (e.g., polymer glycols) as the stationary phase within the micro-channels of the column.Type: GrantFiled: November 5, 2015Date of Patent: November 8, 2022Assignees: GEOSERVICES EQUIPEMENTS, LA SOCIETE DES AMIS DE L'ECOLE SUPERIEURE DE PHYSIQUE ET CHIMIE INDUSTRIELLES DE LA VILLE DE PARISInventors: Jerome Breviere, Joachim Pragash Fleury, Jerome Vial, Didier Thiébaut, Anouar Essoussi, Imadeddine Azzouz, Kamran Danaie
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Patent number: 11472758Abstract: Disclosed herein is a method for obtaining compounds and compositions from plant and fungus materials by thermal treatment, affinity capture, filtration, and release through multi-phasic transitions between gas, solid, and liquid states. The compounds of interest are obtained by manipulating the temperature and pressure of the heating chamber. The compounds in gas phase are passed through an affinity medium which captures the compounds of interest in either solid or liquid phase by exposing the compound of interest to the localized micro-affinity environment of the medium. The compounds are separated from the medium using direct competition with solvent or buffers optimized for the specific chemical properties of compounds.Type: GrantFiled: December 15, 2021Date of Patent: October 18, 2022Assignee: Real Isolates, LLCInventors: Christina Miyabe Shields, Andrew Michiel Westerkamp
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Patent number: 11465125Abstract: A water-absorbing resin that exhibits excellent absorption performance and a high permeation rate with respect to liquids to be absorbed, and that effectively reduces liquid leakages, even in an absorbent body using a large amount of the water-absorbing resin. The water-absorbing resin is formed from a polymer of a water-soluble ethylenically unsaturated monomer, and when a cross-sectional image of the water-absorbing resin obtained by X-ray computer tomography is observed, the percent area of cavity portions in the cross-sectional image is 2-10%. The liquid flow rate index when a physiological saline liquid column flow rate test is performed on the water-absorbent resin having a particle diameter of 250 to 500 ?m at 37° C. is 5-20.Type: GrantFiled: March 2, 2018Date of Patent: October 11, 2022Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Mikito Chiba, Yuichi Onoda
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Patent number: 11465126Abstract: The production method includes: a gel-crushing step of grinding a crosslinked hydrogel polymer to obtain a particulate crosslinked hydrogel polymer; a heating drying step of obtaining dried particles from the particulate crosslinked hydrogel polymer by using a continuous stirring drying machine; a post-crosslinking step of post-crosslinking the particulate crosslinked hydrogel polymer or the dried particles; and a sizing step of adjusting a particle size of the dried particles or the post-crosslinked dried particles to obtain water-absorbent resin powder. The particulate crosslinked hydrogel polymer contains a gel fluidizer. A gel temperature of the particulate crosslinked hydrogel polymer containing the gel fluidizer, the gel temperature being measured by a contact thermometer, is not lower than 50° C. In the production method, the dried particles or the post-crosslinked dried particles is forcedly cooled before the sizing step.Type: GrantFiled: November 16, 2017Date of Patent: October 11, 2022Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Hiroyasu Watabe, Mai Sato, Ryota Wakabayashi, Yoshihiro Shobo, Shin-ya Katsube, Motohiro Imura, Koji Honda, Yoshifumi Adachi, Tsuyoshi Yorino, Masafumi Inoue, Tomoyuki Arake, Hiroki Hayashi, Naoki Katakura, Shin-ichi Fujino, Kunihiko Ishizaki, Tokio Shuto
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Patent number: 11459159Abstract: The present invention relates to a material suitable for use in packages comprising nano-sized cellulose and an ethylene scavenging or ethylene absorbing agent. The invention also relates to methods for manufacturing such material, which may be paper, label, paperboard, plastic or film products.Type: GrantFiled: July 3, 2017Date of Patent: October 4, 2022Assignee: Stora Enso OYJInventors: Kaj Backfolk, Isto Heiskanen, Esa Saukkonen, Seppo Lampainen, Simo Siitonen, Marianne Andersson
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Patent number: 11453636Abstract: A method is provided for separating a dicarboxylic acid product from a mixture containing such dicarboxylic acids. The method involves: providing a dicarboxylic acid-containing mixture of which at least 35% of the carboxylic acid content of the mixture is a dicarboxylic acid product of interest; running an extraction of said dicarboxylic acid-containing mixture through a chromatographic column configured with an amphoteric resin, such that the dicarboxylic acid product elutes preferentially from the dicarboxylic acid-containing mixture. In certain embodiments, the dicarboxylic acid product of interest can be a glucaric or gluconic acid product from a mixture of either or both of these with still other carboxylic acids.Type: GrantFiled: June 20, 2018Date of Patent: September 27, 2022Assignee: ARCHER DANIELS MIDLAND COMPANYInventors: Pam Anklam, William Chris Hoffman, Mitchell Schultz, John G. Soper
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Patent number: 11420184Abstract: Disclosed are water-absorbent resin particles comprising a crosslinked polymer comprising a monomer unit derived from a water-soluble ethylenically unsaturated monomer, wherein an artificial menstrual blood volume increase rate as measured in an artificial menstrual blood swelling test conducted in the order of i), ii), and iii) is 70% or more. i) putting 1.0 g of water-absorbent resin particles into a measuring cylinder with an inner diameter of 27 mm. ii) injecting 10 ml of artificial menstrual blood into the cylinder at once to swell the water-absorbent resin particles. iii) measuring a volume (A) of the swollen water-absorbent resin particles after 60 seconds from the injection and calculating an artificial menstrual blood volume increase rate according to Equation (I) below. Artificial menstrual blood volume increase rate (%)=(A?B)/B×100 . . . (I), A . . . Volume (ml) of swollen water-absorbent resin particles, B . . . Volume (ml) of injected artificial menstrual blood.Type: GrantFiled: March 28, 2018Date of Patent: August 23, 2022Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Hiroki Yabuguchi, Hiromi Miyashita, Hideki Yokoyama
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Patent number: 11413602Abstract: The present invention relates to an organic polymer adsorbent, an organic polymer adsorbent composition, and a method for preparing an organic polymer adsorbent and, more specifically, to an organic polymer adsorbent to be used for a ventilation device such as a desiccant dehumidifier. According to the present invention, an adsorbent material is changed to an organic polymer adsorbent such that the mechanical stability and durability of the material itself can be ensured, and the specific surface area of interconnected inner pores and adsorbents and the size of formed pores can be controlled since toluene is contained as a pore generator of the adsorbent. Therefore, the adsorbent of the present invention has superior adsorption performance over that of other conventional organic polymer adsorbents containing a salt-type carboxyl group and has remarkably improved desorption performance, and thus has an effect of very remarkable energy efficiency.Type: GrantFiled: January 2, 2018Date of Patent: August 16, 2022Assignee: LG ELECTRONICS INC.Inventors: Taegyu Jin, Yong Ki Jeong, Janghee Park
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Patent number: 11407665Abstract: The invention relates to environment management, particularly to methods for purifying a wastewater in order to climate a toxic impact of heavy and radioactive metals. A method for purifying fresh, combined and saline wastewater from radioactive and heavy metals using an electrolysis and a special active substance (sorbent), wherein the wastewater is fed to an electrolyzer with a chamber that is separated by a special membrane that is permeable for ions of metals separately of water, then changes of the pH occur in order to form complex compounds, which comprise ions of radioactive and heavy metals. Afterwards, the adsorption of the obtained compounds by the special active substance (sorbent) and filtering-off on a precoat filter that retains ions of heavy and radioactive metals are performed. The obtained filtrate is cemented without drying and evaporation in order to perform final deposition of the radioactive compounds.Type: GrantFiled: December 14, 2018Date of Patent: August 9, 2022Assignee: Unique Equipment Solutions LLCInventor: Oleksandr Yuriiovych Mykytiuk
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Patent number: 11383221Abstract: The present disclosure relates to a preparation method of a super absorbent polymer capable of improving absorption performance of the super absorbent polymer by adding a simple additive later. The preparation method includes the steps of: forming a hydrogel polymer by cross-linking and polymerizing a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups in the presence of an internal cross-linking agent; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; forming a surface cross-linked layer by further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent, adding a monovalent to trivalent metal cation on the surface cross-linked base resin powder at a temperature of 25° C. to 80° C., and maintaining and aging the resulting metal cation-added product at a temperature of 40° C. to 60° C. for 10 to 30 minutes.Type: GrantFiled: November 18, 2019Date of Patent: July 12, 2022Inventors: Jungmin Sohn, Tae Young Won, Hyemin Lee
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Patent number: 11383220Abstract: The method and materials of this invention make possible substantially faster techniques for organic-aqueous extractions and routine chemical reactions work-ups. The inventive material uses silicone elastomer-coated glass powders, magnetic powders, and sponges as absorbents to extract organic products from an aqueous mixture. After separation from the mixture, these different forms now loaded with organic products can serve as a convenient input for flash chromatographic separations or other processing. With these techniques, tedious liquid-liquid extractions are replaced by a simple solid filtration or transfer and emulsion formation is eliminated. These versatile sorbents can also be used for larger scale work-ups, various extractions of organics from an aqueous solution (e.g., water purification) or gas phase and various analytical or other applications.Type: GrantFiled: February 22, 2019Date of Patent: July 12, 2022Assignee: Faster Chemistry LLCInventors: Gerald B Hammond, Bo Xu
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Patent number: 11364480Abstract: A chromatography medium includes a porous matrix and nonporous globules bound on the inner and outer surfaces of the porous matrix. The average radius of the microglobules is not more than 30% of the average pore diameter of the porous matrix. The chromatography medium can be used in affinity chromatography. A method for preparing the chromatography medium may include providing a porous starting matrix, providing a polymerization solution, and initiating polymerization of the polymerization solution in the presence of the porous starting matrix to form insoluble nonporous microglobules that are bound to the inner and outer surfaces of the porous starting matrix.Type: GrantFiled: January 16, 2018Date of Patent: June 21, 2022Assignee: Sartorius Stedim Biotech GmbHInventors: Adrian Ley, Florian Taft, Jan Schwellenbach, Louis Villain