Abstract: An external catalyst cooler arrangement for an FCC regenerator improves the operation of the catalyst cooler by the use of a heat removal unit design utilizing a central supply tube and central heat removal conduit surrounded by external heat removal tubes connected directly to the central heat removal conduit.

Abstract: The present invention provides a method of cooling a regenerated catalyst and a device thereof, which employs low-line-speed operation, wherein a range of the superficial gas velocity is 0.005-0.7 m/s, wherein at least one fluidization wind distributor is provided, wherein the main fluidization wind enters the dense bed layer of the catalyst cooler from the distributor, and the heat removal load of the catalyst cooler and/or the temperature of the cold catalyst is controlled by adjusting the fluidization wind quantity. The method and a device thereof of the present invention has an extensive application range, and can be extensively used for various fluid catalytic cracking processes, including heavy oil catalytic cracking, wax oil catalytic cracking, light hydrocarbon catalytic conversion and the like, or used for other gas-solid fluidization reaction charring processes, including residual oil pretreating, methanol to olefin, methanol to aromatics, fluid coking, flexicoking and the like.

Abstract: Catalyst regenerators and methods of their use are provided. A catalyst regenerator includes a combustion chamber with a combustion chamber diameter and a combustion chamber bottom. A mixing chamber is fluidly coupled to the combustion chamber at the combustion chamber bottom, where the mixing chamber has an exterior wall and a mixing chamber diameter less than the combustion chamber diameter. A first and second catalyst inlet are fluidly coupled to the mixing chamber, and a mixing cylinder is within the mixing chamber. The mixing cylinder and the exterior wall define an annular space there-between, and the mixing cylinder includes a cylinder opening.

Abstract: The process herein provide a catalyst cooler with a vent that communicates fluidizing gas to a lower chamber of a regenerator. Air that is used as fluidizing gas can then be consumed in the regenerator without promoting after burn in the upper chamber.

Abstract: The invention relates to a process for incorporating sulfur in the porosity of the solid particles of a catalyst for the conversion of hydrocarbons or an adsorbent. This process is carried out off-site in the presence of hydrogen sulfide that is pure or diluted in hydrogen or nitrogen, a process in which said particles are made to rise or fall in a sulfur incorporation zone that comprises at least one vibratory helical coil that is essentially tubular in shape and that comprises at least two turns, whereby said particles are subjected to a temperature profile over the majority of their path in said coil and whereby said particles are brought into contact with at least one fluid on at least one portion of their path.

Abstract: A hydrocarbon composition comprises at least 90 wt. % of C9 to C20 non-normal olefins, non-normal saturates or combinations thereof based on the weight of the hydrocarbon composition, at least 2 wt. % and not greater than 25 wt. % of C9 hydrocarbons based on the weight of the hydrocarbon composition, and less than 15 wt. % of C17+ hydrocarbons based on the weight of the hydrocarbon composition, wherein said hydrocarbon composition has a specific gravity at 15° C. of at least 0.730 and less than 0.775. The composition is produced by oligomerization of at least one C3 to C8 olefin and an olefinic recycle stream containing no more than 10 wt. % of C10+ non-normal olefins. The composition is useful in producing fuel blends, such as jet fuel and diesel fuel.

Abstract: This invention is directed to methods of converting oxygenates to olefin products. The methods provided include steps for protecting against deactivation of active molecular sieve catalysts during the conversion process. In particular, the invention provides for methods of regenerating coked catalyst to minimize catalyst deactivation due to contact with moisture.

Abstract: A process for producing a hydrocarbon composition that comprises contacting a feed stream, that comprises at least one C3 to C8 olefin, and an olefinic recycle stream, that comprises a first olefinic recycle stream and no more than 10 wt % of C10+ non-normal olefins, with a molecular sieve catalyst in a reaction zone under olefin oligomerization conditions producing an oligomerization effluent stream; separating the oligomerization effluent stream to produce a first olefinic stream, that has a weight ratio of C4?/(C5-C8) molecules from about 0.8 to about 1.2 times the weight ratio of C4?/(C5-C8) molecules found in the oligomerization effluent stream, and a first hydrocarbon product stream, that comprises at least 1 wt % and no more than 30 wt % of C9 non-normal olefin; and splitting the first olefinic stream to produce the first olefinic recycle stream and a first purge stream.

Abstract: A hydrocarbon fluid composition that comprises species of at least two different carbon numbers, an aerobic biodegradability of greater than 40% at 28 days, a cetane number of less than 60, and a certain boiling point range; and a process for making the hydrocarbon fluid composition.

Abstract: This invention is directed to methods of converting oxygenates to olefin products. The methods provided include steps for protecting against deactivation of active molecular sieve catalysts during the conversion process. In particular, the invention provides for methods of regenerating coked catalyst to minimize catalyst deactivation due to contact with moisture.

Abstract: The invention pertains to a process for combusting coke of a coke-containing FCC catalyst in a regeneration unit of a FCC unit having the introduction of oxygen-containing gas through a gas-transport unit into the regeneration unit and combusting the coke by means of an oxygen-containing gas, in which the oxygen-containing gas is cooled in a cooling unit before it is brought in contact with the coke-containing FCC catalyst. The invention further relates to an apparatus for performing said process.

Abstract: Embodiments of the invention relate to processes and apparatus for the washing and recovery of metal-containing catalyst solids in a form suitable for reclamation. More specifically, a catalyst recovery process comprises removing an organic residue with a washing medium from a metal-containing catalyst solids, recovering washed solids, and treating the washed solids under oxidative conditions to form non-reactive solids. The treatment oxidative conditions may be effective to convert the metal(s) into an oxide form and/or may facilitate the removal of remaining organic residue from the washed solids. The treatment of the washed solids may comprise calcination. In some embodiments, the metal-containing catalyst solids may be recovered from a slurry stream, and the process further comprises passing the slurry stream though a separation unit to obtain a catalyst-enriched retentate slurry.

Abstract: A fluidized catalytic cracking process for catalytically cracking a feed to lighter products includes introducing a heated catalyst and the feed into a bottom riser of a fluidized catalytic cracking apparatus and allowing the heated catalyst and the feed to preaccelerate upwardly within the bottom riser as a mixture; flowing the mixture upwardly from the bottom riser through a plurality of microriser tubes disposed within a regenerator under conditions effective to cause a cracking reaction of the hydrocarbons and result in a mixture including coked catalyst and hydrocarbon vapors; passing the mixture from the microriser tubes through a catalyst separator for separating the coked catalyst from the hydrocarbon vapors; collecting coked catalyst in a stripper for stripping out hydrocarbon vapors carried along with the coked catalyst and introducing the coked catalyst collected into a regenerator; simultaneous with flowing the mixture, combusting the coked catalyst within the regenerator under conditions effectiv

Abstract: A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream.

Abstract: An FCC reactor and regenerator arrangement provides substantially independent control of temperature on the reactor side and regenerator side of the process. The arrangement withdraws cooled regenerated catalyst for transfer to a reactor riser and cooled regenerator catalyst for return to the regeneration zone. The process may operate with a single cooler that supplies catalyst to both the reaction side of the process and the regeneration side of the process.

Abstract: A supported Lewis acid catalyst system for catalyzing hydrocarbon conversion reactions including cationic polymerization, alkylation, isomerization and cracking reactions is disclosed, wherein the catalyst system comprises an inorganic oxide support having immobilized thereon a least one strong Lewis acid comprising at least one metal salt of a strong Bronsted acid wherein the metal is selected from the group consisting of aluminum, boron gallium, antimony, tantalum, niobium, yttrium, cobalt, nickel, iron, tin, zinc, magnesium barium strontium, calcium, tungsten, molybdenum and the metals of the lanthanide series and wherein the strong Bronsted acid is selected from the group consisting of mineral and organic acids stronger than 100% sulfuric acid.

Abstract: The invention concerns a process for thermal regulation in a continuous fluidized bed treatment process for a powdered solid, wherein the solid is treated in a fluidized bed treatment zone, at least a portion of the solid is extracted from said zone and transported to an external heat exchanger (21) containing at least one array (22) of thermal exchange tubes in which vaporizable cooling fluid circulates, fluidized or mobile bed thermal regulation by indirect heat exchange with the fluid is carried out and the portion of regulated solid is extracted for recycling into the treatment zone or to another treatment zone (1). More precisely, said portion of solid is circulated in descending mode by means of an inert or non inert fluidization fluid across the array of tubes (22) which are wound such that the current of solid intersects said tubes and that the cooling fluid is circulated in one direction in the array of tubes.

Abstract: A method and an apparatus are disclosed for desorbing TEDA by utilizing a fluidized bed so as to reuse a used impregnated active carbon for the purpose of removing toxic materials from a fluid. The impregnated active carbon is injected into a fluidized bed at a high temperature to carry out a desorbing process, in such a manner that TEDA and CH.sub.3 l are desorbed from the impregnated active carbon at a high temperature by utilizing the high volatility of TEDA and CH.sub.3 l. If a heated air is injected through an air inlet into the desorbing tower, the high temperature air and the used impregnated active carbon are met in a fluidized state, with the result that the active carbon with TEDA and CH.sub.3 l desorbed is discharged.

Abstract: A regenerative process for the preparation of olefinically unsaturated compounds by oxidation/dehydrogenation of selectively oxidizable hydrocarbons over an oxygen carrier acting as catalyst, in the absence of molecular oxygen, alternating (in repeated cycles) with regeneration of the spent oxygen carrier with a gaseous molecular oxidizing agent, in which the spent (reduced) catalyst is cooled, prior to introduction of the regenerating gas, to a temperature which is below the temperature of the reaction, regeneration being controlled in such a manner that the highest temperature occurring during regeneration does not exceed the temperature of reaction at which dehydrogenation is commenced.

Abstract: A supported Lewis acid catalyst system for catalyzing hydrocarbon conversion reactions including cationic polymerization, alkylation, isomerization and cracking reactions is disclosed, wherein the catalyst system comprises an inorganic oxide support having immobilized thereon a least one strong Lewis acid comprising at least one metal salt of a strong Bronsted acid wherein the metal is selected from the group consisting of aluminum, boron gallium, antimony, tantalum, niobium, yttrium, cobalt, nickel, iron, tin, zinc, magnesium barium strontium, calcium, tungsten, molybdenum and the metals of the lanthanide series and wherein the strong Bronsted acid is selected from the group consisting of mineral and organic acids stronger than 100% sulfuric acid.

Abstract: A catalyst cooler apparatus and process for use with a two-stage regeneration system in a fluidized catalytic cracking process having a device to remove hot catalyst from the second regeneration zone at a point above the air distribution ring under the surface of the catalyst bed equivalent to the catalyst exit to the reactor, a heat exchanger for indirect heat exchange and cooling of the catalyst and a return device for returning the cooled catalyst to the second regeneration zone at or near the bottom of the catalyst bed, beneath the air distribution ring.

Abstract: A method of regenerating a sulfur-sensitive hydrocarbon conversion catalyst by employing sulfur-contaminated heat-transfer equipment of a hydrocarbon conversion process is disclosed. This method is useful for the regeneration of reforming catalysts comprising L-zeolite.

Abstract: Apparatus and processes are disclosed for carrying out chemical reactions of the type in which a fluidized particulate solid is contacted with reactants in a reaction vessel or conduit and then separated from the reactant products and regenerated in a regeneration process, such as combusting the carbonaceous deposit which accretes on fluid catalytic cracking catalyst particles. The regeneration reaction may change the temperature of the regenerated catalyst particles and in such case it is often required to subject the particles to heat exchange to provide them at a temperature suitable for recirculation to the reaction zone. The processes and apparatus of the invention essentially provide for dividing the fluidized solids regeneration bed into an uppermost bed zone and at least one lower bed zone by a horizontal occlusion zone disposed at a vertically intermediate portion of the bed.

Abstract: A method of heating or cooling particulate material by indirect heat exchange of the particles with a heat exchange fluid in a heat exchanger is improved by the use of a gas vent that operates to pump catalyst into and out of a heat exchanger. A periodic build-up of fluidizing medium in a particle cycling zone intermittently causes catalyst to flow into out of a heat exchanger. The method and apparatus of this invention are particularly useful for the cooling of FCC catalyst and simplifies the addition of a cooler by allowing the use of small size catalyst transfer lines.

Abstract: An FCC reactor achieves greater utilization of the space within the reactor vessel by using a vented riser arrangement having an inlet opening at the bottom of a vented riser collector. The inlet opening at the bottom of the vented riser collector allows plug flow of the catalyst and hydrocarbon vapors through the upper and lower section of the reactor vessel without any substantial degradation and separation efficiency between the catalyst and the hydrocarbon vapors. This permits almost the entire tangent length of the reactor vessel to be used for the purpose of catalyst and hydrocarbon contact.

Abstract: A process and apparatus for fluidized catalytic cracking (FCC) with cooling of FCC catalyst during regeneration in a baffled heat exchanger attached to the regenerator. The heat exchanger has a vertical baffle defining an inlet and an outlet side. Lift gas added to the outlet side induces flow from the regenerator, around the baffle and back to the regenerator. A symmetrical design, with reversing flow can equalize wear on heat exchanger tubes and permit selected cooling if the heat exchanger outlet is near the regenerated catalyst outlet.

Abstract: An alkane-containing feedstream is passed through one or more tubes, which may contain alkane-dehydrogenation catalyst, immersed in a bed of fluidized particles. The bed is at an elevated temperature which maintains the temperature within the tube(s) at an alkane-dehydrogenation temperature. The particles may be inert, chemically active and/or catalytically active. In one embodiment, cracking catalyst particles are circulated between a reaction zone wherein they contact a cracker feedstock which is converted to cracked hydrocarbon products and a regenerator (22) wherein carbonaceous deposits on the catalyst particles are exothermically removed by contact with an oxygen-containing gas (24). Hot regenerated particles from the regenerator (22) are recirculated (27) to the reaction zone for re-use therein.

Abstract: An arrangement of apparatus and process thereof for cooling hot fluid solid particles, especially hot regenerated catalytic particles are disclosed. The apparatus comprises a substantially vertical, cylindrical and close ended heat removal vessel through the shell sid passage of which is passed the fluid solid particles that flow downwardly in the form of dense phase fluidized bed, and one or more seperate heat exchange tube units through the tube side passage of which the coolant is passed and evaporized, each of said heat exchange tube units comprising a supply coolant inlet tube, a supply coolant collecting chamber, one or more heat exchange tubes, a vapour collecting chamber and a resulting vapour discharge tube, all of which constitute a close type coolant-to-vapour circulation.

Abstract: A method of heating or cooling particulate material by indirect heat exchange of the particles with the heat exchange fluid in a heat exchanger located outside and offset from the vessel that supplies the particulate material and to which the particulate material returns uses the addition of an open conduit to increase catalyst circulation through the heat exchanger. The open conduit has been found to be effective when used internally or externally. The internal use of the open conduit minimizes structural changes required to retrofit the conduit to existing back mix coolers. The use of the conduit for increased catalyst circulation allows a flow through type cooler duty to be produced in an amount of space that would ordinarily only permit the use of a backmix type cooler.

Abstract: The invention relates to a method of and an apparatus for fluidised bed regeneration of a catalyst containing coke.The catalyst and some of the regeneration fumes are drawn off from the dense bed of a regenerator (1) and are introduced by gravity into an external exchanger at a junction point below the level of the dense bed of the regenerator. Heat exchange is carried out in the lower part of the exchanger (7) below the junction point. From the bottom end of the exchanger up to above the junction point a dense bed zone is created the level of which is established substantially at the height of the dense bed in the regenerator and a zone (15) of suitable size for the escape of regeneration gases and fluidisation gas. The gases and fumes are drawn off into the dilute fluidised phase (18) of the regenerator through a duct (17) while the catalyst is recycled to the dense bed of the regenerator through a different duct (25) from that in which the fluidisation air is circulating.

Abstract: A method of heating or cooling particulate material by indirect heat exchange of the particles with a heat exchange fluid in a heat exchanger is improved by the use of a gas vent that operates to pump catalyst into and out of a heat exchanger through a single opening. The build-up of a fluidizing medium in a particle cycling zone cycles catalyst into and out of a heat exchanger by opening and closing the single vent line. The method and apparatus of this invention are particularly useful for the cooling of FCC catalyst and simplifies the addition of a cooler by allowing the use of small size catalyst transfer lines. In addition, the method allows the catalyst cooler to be located a greater distance away from the FCC unit than possible in previous catalyst cooler designs.

Abstract: A fluidized catalytic cracking process and apparatus operates with a single or multi- stage refluxed catalyst stripper. Recycle, or reflux, of stripped catalyst to the stripping zone improves stripping. Preferably, a two stage hot stripper is used. Addition of regenerated catalyst to spent catalyst from the reactor heats spent catalyst in a first stripping stage, which preferably uses stripping steam. Catalyst from the first stripping stage passes up through a second stage stripping zone with a heat removal means, e.g., a stab-in tube bundle. Steam or flue gas fluidizes catalyst, improves heat transfer and strips the catalyst. Some catalyst from the second stage stripper is preferably recycled to the inlet to the first stripping stage. Additional hot regenerated catalyst may be added downstream of the first catalyst stage to heat the second stripping stage, added to catalyst removed from the primary stripping zone which is sent to the regeneration zone.

Abstract: An arrangement of apparatus and process thereof for cooling hot fluid solid particles, especially hot regenerated catalytic particles are disclosed. The apparatus comprises a substantially vertical, cylindrical and close ended heat removal vessel through the shell side passage of which is passed the fluid solid particles that flow downwardly in the form of dense phase fluidized bed, and one or more separate heat exchange tube units through the tube side passage of which the coolant is passed and vaporized, each of said heat exchange tube units comprising a supply coolant inlet tube, a supply coolant collecting chamber, one or more heat exchange tubes, a vapour collecting chamber and a resulting vapour discharge tube, all of which constitute a close type coolant-to-vapour circulation.

Abstract: The provision and operation of backmix coolers is facilitated by a cooler arrangement that has the backmix portion of the cooler in an inverted position. In this position the heat exchange portion of the cooler is located above the source of hot catalyst. Hot catalyst for heat exchange in the cooler enters and leaves the heat exchange zone from below the location of the heat exchange tubes. The inverted position prevents any collection of debris in the bottom of the cooler, eliminates high velocity impingement of fluidizing medium on the tube, and facilitates the incorporation of the cooler in FCC units by avoiding interference with other equipment.

Abstract: A catalyst cooler arrangement for an FCC regenerator improves the operation of the cooler by the use of a full or partial screen arrangement at the cooler outlet of the regenerator to remove material that interferes with the operation of the cooler and especially the distribution of fluidizing gas within the cooler.

Abstract: A process and apparatus for achieving hot catalyst stripping of spent FCC catalyst in a stripper mounted over a bubbling bed regenerator. Hot catalyst stripping is achieved by indirect transfer of heat from the regenerator to the stripper. Heat pipes, surface modifications such as fins on the stripper vessel, or use of a stripper in, or connective with, a heat exchange tube bundle may be used to heat spent catalyst with heat from the regenerator dilute phase, without transferring catalyst from the regenerator. The benefits of hotter catalyst stripping are achieved, without increasing catalyst traffic in the regenerator.

Abstract: A process and apparatus for fluidized bed catalyst regeneration. A mixture of spent catalyst, recycled hot regenerated catalyst and regeneration gas are charged to a riser having an outlet connective with a coke combustor immersed in a fluidized bed of catalyst. The coke combustor outlet is covered by the dense phase fluidized bed. Additional combustion air may be added to the fluidized bed of catalyst covering the coke combustor outlet for additional catalyst regeneration. Indirect heat exchange may heat spent catalyst in the riser and/or the coke combustor.

Abstract: A process and apparatus for high efficiency regeneration of spent FCC catalyst in an existing, single dense bed FCC regenerator is disclosed. Spent catalyst is added to a coke combustor immersed within the existing regenerator vessel catalyst bed. A dilute phase transport riser, above and connective with the coke combustor discharges a mixture of regenerated catalyst and flue gas. Regenerated catalyst collects around and under the coke combustor. The spent catalyst inlet, and combustion air inlet, are preferably immersed in, and in a heat exchange relationship with, the bed of hot regenerated catalyst. Heat pipes, or fins may be used to increase heat transfer into the coke combustor from the dense bed. Heating the coke combustor by indirect heat exchange, rather than recycle of hot regenerated catalyst, reduces particulates emissions and saves the energy needed to recycle catalyst in the regenerator.

Abstract: The duty of a side-mounted, backmix type catalyst cooling zone is increasd by having one conduit that delivers catalyst to the top of the cooling zone and another conduit that uses fluidizing gas to vent catalyst from the top of the cooling zone back to a regenerator. The catalyst cooling zone is used to cool catalyst in a fluidized catalytic cracking process. The cooling zone comprises a heat exchanger located remote from an FCC regenerator that supplies hot catalyst particles to the cooling zone from a dense phase catalyst bed. Hot catalyst particles enter the top end of the cooling zone through a first conduit. Fluidizing gas, added to the cooling zone for backmixing and heat transfer purposes, exits the top of the cooling zone through a second conduit that communicates the top of the cooler with a dilute phase catalyst zone in the regenerator. Gas flow into and through the second conduit transports catalyst from the cooling zone to the regenerator.

Abstract: A process and apparatus for the heat regulation of fluidized or fluid catalyst beds are described, the apparatus having a fluid bed heat exchanger. According to the invention, a pulverulent solid is made to flow essentially from the base of an enclosure (1) into a heat exchanger (6) having an internal separating partition (22) which defines two elongated, adjacent compartments (23, 24) communicating at their lower part. In the compartment in which the pulverulent solid flows downwards, the fluidization speed or rate is between 0.1 cm to 2 m/s, whereas in the compartment wherein the pulverulent solid rises again into the heat exchanger (6), the fluidization speed is between 0.1 and 6 m/s. The invention can be used for refining reaction (e.g., catalytic reforming), for the regeneration of a fluidized bed catalytic cracking catalyst of a petroleum or oil charge, or for the combustion of coal.

Abstract: A two-stage process and apparatus for the regeneration of fluidized catalytic cracking (FCC) catalyst is disclosed. A primary regenerator, a single dense bed with a spent catalyst inlet, a source of oxygen-containing gas, a flue gas outlet and a regenerated catalyst outlet, is supplemented with a secondary regenerator. The secondary regenerator has its own source of air for combustion and takes particles from a lower portion of the dense bed in the primary regenerator. Combustion gases, and some solids, are discharged from the secondary regenerator into the primary regenerator. Hot, decoked material is withdrawn from the base of the secondary regenerator for use in the catalytic cracking reaction. Preferably, a dense, fast settling additive is used with a conventionally sized FCC catalyst. These two materials can be added together to the primary regenerator and separated by elutriation therein into two catalyst phases.

Abstract: A process for simultaneously heating and cooling of spent FCC catalyst during regeneration in a high efficiency FCC regenerator, one using a fast fluidized bed coke combustor. The coke combustor burns coke from spent catalyst in a turbulent or fast fluidized bed, and discharges catalyst and flue gas up into a dilute phase transport riser. Catalyst is separated into flue gas and a bubbling dense bed of catalyst. The coke combustor is heated by recycling hot catalyst from the bubbling dense bed and simultaneously cooled by a backmixed heat exchanger. Catalyst flows from the combustor to the cooler and is displaced back into the combustor by adding air to the catalyst in the cooler. Heating promotes rapid coke combustion, while cooling reduces thermal and hydrothermal deactivation of the spent catalyst.

Abstract: A process and apparatus for achieving multistage, hot catalyst stripping of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. Hot catalyst stripping is achieved by lifting regenerated catalyst into the conventional stripper or to a secondary catalyst stripper under the primary stripper. Spent catalyst is heated by direct contact heat exchange with hot regenerated catalyst. Three different types of lift gas may be used to transport catalyst from the regenerator to the hot stripper, a light reactive hydrocarbon, an inert, or steam.

Abstract: Process for the continuous conversion of light olefin gas feed containing ethene, propene and butene to produce heavier hydrocarbons by contacting the light olefin feed in a fluidized bed reaction zone with a medium pore molecular sieve zeolite catalyst under oligomerization conditions to convert the light olefin feed to heavier hydrocarbons. The catalytic reaction causes the conversion of the light olefins to heavier hydrocarbons, the deposition of coke by-product on the catalyst and the absorption of hydrocarbon product on the catalyst. The deposited coke causes the partial deactivation of the catalyst. A portion of the partially deactivated catalyst containing deposited coke and absorbed hydrocarbon product is continuously withdrawn from the reaction zone and transferred to a catalyst stripping zone in which the catalyst is contacted with an inert stripping gas to remove the absorbed hydrocarbons from the catalyst.

Abstract: A process and apparatus are disclosed for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A coke combustor vessel is immersed in, and in open fluid communication with, the bubbling dense bed of the existing regenerator vessel. Spent catalyst is discharged into the coke combustor, mixes with hot regenerated catalyst which flows into the coke combustor, and regenerated with combustion air in a turbulent or fast fluidized bed. Catalyst and flue gas are discharged up into a dilute phase transport riser, preferably into cyclone which separate hot regenerated catalyst from flue gas. Regenerated catalyst is collected in the bubbling dense bed surrounding the coke combustor, and some is recycled by flowing into the coke combustor for direct contact heat exchange.

Abstract: A process and apparatus for achieving turbulent or fast fluidized bed regeneration of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A closed coke combustor vessel is added to the existing regenerator vessel, and spent catalyst is discharged into the coke combustor and regenerated in a turbulent or fast fluidized bed, and discharged up into a dilute phase transport which preferably encompasses, and is in a countercurrent heat exchange relationship with, the spent catalyst standpipe. Regenerated catalyst is discharged from the dilute phase transport riser, and collected in the bubbling dense bed surrounding the coke combustor. Catalyst may be recycled from the dense bed to the coke combustor for direct contact heat exchange. Catalyst coolers may be used on catalyst recycle lines to the coke combustor, or on the line returning regenerated catalyst to the cracking reactor.

Abstract: A process and apparatus for achieving multistage, hot catalyst stripping of spent FCC catalyst in a bubbling bed regenerator having a stripper mounted over the regenerator and a stripped catalyst standpipe within the regenerator. A secondary or hot catalyst stripper is placed under the primary stripper and within the existing regenerator vessel. Spent catalyst from the primary stripper is heated in the secondary stripper by at least one of immersion in the bubbling dense bed of hot regenerated catalyst, addition of hot regenerated catalyst recovered from the discharged into the coke combustor and regenerated in a turbulent or fast fluidized bed, and discharged up into a dilute phase transport riser which preferably encompasses, and is in a countercurrent heat exchange relationship with, the spent catalyst standpipe. Regenerated catalyst is discharged from the dilute phase transport riser, and collected in the bubbling dense bed surrounding the coke combustor.

Abstract: A method and apparatus for cooling hot FCC catalyst particles in a heat exchange zone that is separate and distinct from the regenerator having an upper portion that operates in a flow-through mode and a lower part that operates in a back mix mode. Catalyst descends from a collection zone into an upper inlet of a heater exchanger. The exchanger contains a series of tubes for indirect heat exchange of the catalyst with a cooling fluid. Catalyst leaves the exchanger through an outlet located at a mid portion of the exchanger. The section of the exchanger between the inlet and outlet comprises the flow-through portion. Catalyst undergoes further heat exchange below the outlet of the exchanger in the backmix portion. Fluidizing gas that enters at the bottom of the exchanger provides the necessary turbulence for particle interchange in the backmix section of the heat exchange zone as well as transport of the particulate material through the flow-through portion of the exchanger.

Abstract: A fluidized catalytic cracking process operates with a hot stripper to improve stripping of spent catalyst from the FCC process. The catalyst from the hot stripper is cooled by direct contact heat exchange with a source or cooled regenerated catalyst. Cooled catalyst may contact hot, stripped catalyst in the base of the stripper or downstream of the stripper. The cooled, stripped catalyst has reduced hydrogen, sulfur and coke content, improves regeneration efficiency, and reduces hydrothermal degradation of catalyst.

Abstract: An apparatus is disclosed for exchanging heat between solid particles and a heat exchange medium, comprising a housing which housing is provided with aeration means with an inlet for an aeration fluid, with an outlet opening, whereby an aeration zone is defined between the aeration means and the outlet opening, and with heat exchange means with at least one inlet and at least one outlet for the heat exchange medium and extending in at least part of the aeration zone, which apparatus further comprises an inlet conduit for solid particles that extends into the aeration zone. Use of the apparatus for the transfer of heat between a heat exchange medium and solid particles is also disclosed.