Monolith With Specified Shape Or Dimension Of Cell Opening (e.g., Honeycomb, Rings, Etc.) Patents (Class 502/527.19)
Cross-Reference Art Collections
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Patent number: 11759772Abstract: A honeycomb structure includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells, wherein a major component of the partition wall is cordierite, a porosity of the partition wall is 45 to 55%, an average pore diameter of the partition wall is 8 to 19 ?m, a cumulative pore volume of the partition wall is such that a pore volume ratio of the pores having a pore diameter larger than a thickness of the partition wall relative to an overall pore volume of the partition wall is 3.0% or less, and a pore volume ratio of the pores having a pore diameter of 10 ?m or less relative to the overall pore volume of the partition wall is 30% or more, and a pore diameter distribution of the partition wall is a unimodal distribution, or a multimodal distribution.Type: GrantFiled: August 10, 2020Date of Patent: September 19, 2023Assignee: NGK INSULATORS, LTD.Inventors: Yudai Kurimoto, Shogo Hirose
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Patent number: 11759740Abstract: A honeycomb filter includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells and a plugging portion, wherein the partition wall is composed of a material containing cordierite as a main component thereof, porosity of the partition wall measured by a mercury press-in method is 60 to 68%, an average pore diameter of the partition wall measured by a mercury press-in method is 8 to 12 and in a pore diameter distribution which indicates a cumulative pore volume of the partition wall measured by a mercury press-in method, with a pore diameter (?m) on an abscissa axis and a log differential pore volume (cm3/g) on an ordinate axis, a first peak that includes a maximum value of the log differential pore volume has a pore diameter value of 10 ?m or less, the pore diameter value corresponding to a ? value width of the maximum value.Type: GrantFiled: January 18, 2021Date of Patent: September 19, 2023Assignee: NGK INSULATORS, LTD.Inventors: Fumihiko Yoshioka, Yuji Sasaki, Kimiko Kishine, Sachiko Ishida, Kyohei Kato
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Patent number: 11759741Abstract: A honeycomb filter includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells and a plugging portion, wherein the partition wall is composed of a material containing cordierite as a main component thereof, porosity of the partition wall measured by a mercury press-in method is 60 to 68%, an average pore diameter of the partition wall measured by a mercury press-in method is 13 to 18 ?m, and in a pore diameter distribution indicating a cumulative pore volume of the partition wall measured by a mercury press-in method, with a pore diameter (?m) on an abscissa axis and a log differential pore volume (cm3/g) on an ordinate axis, a first peak including a maximum value of the log differential pore volume has a pore diameter value of 15 ?m or less, the pore diameter value corresponding to a ? value width of the maximum value.Type: GrantFiled: January 18, 2021Date of Patent: September 19, 2023Assignee: NGK INSULATORS, LTD.Inventors: Fumihiko Yoshioka, Yuji Sasaki, Kimiko Kishine, Sachiko Ishida, Kyohei Kato
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Patent number: 11731097Abstract: A catalytic system is provided which comprises a tubular reactor and at least one catalyst particle located within the tubular reactor. The catalyst particles have a particular geometric form which promotes heat transfer with the tubular reactor. Certain specific catalyst particles are also provided.Type: GrantFiled: November 19, 2019Date of Patent: August 22, 2023Assignee: HALDOR TOPSØE A/SInventors: Moritz Bo Belstrup, Peter Rahbek, Martin Østberg
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Patent number: 9018130Abstract: A honeycomb structural body and a method for the manufacturing thereof. The manufacturing method includes (i) providing a plurality of silicon carbide honeycomb segments, each having a cell structure and at least one outer wall; (ii) subjecting the honeycomb segments to an oxidizing thermal treatment forming a surface layer of silicon oxides on the at least one outer wall; and (iii) bonding the plurality of oxidized honeycomb segments so as to form the honeycomb structural body in the substantial absence of organic binders with the interposition of a sealing material including a mixture of one or more silicon carbide powders, one or more ceramic fibers, and one or more inorganic binders.Type: GrantFiled: September 30, 2008Date of Patent: April 28, 2015Assignee: Pirelli & C. Eco Technology S.p.A.Inventors: Tiziano Ambrosini, Agustin Sin Xicola
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Patent number: 8927454Abstract: An exhaust gas-purifying catalyst includes a support provided with one or more through-holes through which exhaust gas flows, and a catalytic layer supported by the support and containing an oxygen storage material. The exhaust gas-purifying catalyst includes a first section to which the exhaust gas is supplied, and a second section to which the exhaust gas having passed through the first section is supplied. The catalytic layer includes a layered structure of a first catalytic layer containing platinum and/or palladium and a second catalytic layer containing rhodium in the first catalytic section and further includes a third layer containing rhodium in the second section. The second section is smaller in oxygen storage material content per unit volumetric capacity than the first section.Type: GrantFiled: October 27, 2011Date of Patent: January 6, 2015Assignee: Cataler CorporationInventors: Minoru Itou, Michihiko Takeuchi, Tetsuya Shinozaki, Takaaki Kanazawa, Masaya Kamada, Tadashi Suzuki, Satoru Katoh, Naoki Takahashi
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Patent number: 8921258Abstract: Disclosed is a catalyst which can convert ammonia contained in exhaust gas from an engine of a vehicle equipped with a Urea-SCR (Urea-Selective Catalytic Reduction) system, to nitrogen, and a method for preparating the same. The catalyst can convert ammonia which is failed to participate in a conversion reaction of NOx to N2 and slipped out of the SCR catalyst, to nitrogen via a SCO (Selective Catalytic Oxidation) reaction, before the ammonia is released to the air.Type: GrantFiled: November 19, 2010Date of Patent: December 30, 2014Assignee: SK Innovation Co., Ltd.Inventors: Seong Ho Lee, Woo Jin Lee, Young Eun Cheon, Seung Hoon Oh, Sung Hwan Kim, Hong Seok Jung, Yong Woo Kim, Gi Ho Goh
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Patent number: 8906330Abstract: The present invention relates to a catalyst composition comprising a carrier substrate, a layer (i) coated on said carrier substrate comprising at least one precious group metal, a layer (ii) comprising Rh, and a layer (iii) comprising Pd and/or Pt and being substantially free of Ce, Ba and Rh, wherein the layer (iii) has a lower weight than the layer (i) or the layer (ii). Furthermore, the present invention relates to a method for treating an exhaust gas stream using said catalyst composition.Type: GrantFiled: May 4, 2010Date of Patent: December 9, 2014Assignee: BASF CorporationInventors: Marcus Hilgendorff, Wen Mei Xue, Cesar Tolentino
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Patent number: 8883100Abstract: The present invention relates to a particle filter comprising a porous carrier body, an SCR active component and an oxidation catalyst, wherein the SCR active component is present as coating on the exhaust-gas entry surface and the inner surface of the porous carrier body and the oxidation catalyst as coating on the exhaust-gas exit surface of the porous carrier body. According to the invention the oxidation catalyst changes its function depending on operating conditions. In normal operation it serves as NH3 slip catalyst for oxidizing excess NH3 and during filter regeneration it operates according to the 3-way principle for converting NOx and CO. The invention also relates to a method for producing the particle filter, the use of the particle filter for treating exhaust gases from the combustion of fossil, synthetic or biofuels as well as an exhaust-gas cleaning system which contains the particle filter according to the invention.Type: GrantFiled: November 4, 2009Date of Patent: November 11, 2014Assignee: Sued-Chemie IP GmbH & Co. KGInventors: Martin Paulus, Klaus Wanninger
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Patent number: 8859454Abstract: The invention relates to a method for producing a catalyst, wherein the catalyst has a high activity and selectivity with regard to the oxidation of CO and NO. The invention also relates to the catalyst produced using the method according to the invention, the use of the catalyst as oxidation catalyst as well as a catalyst component which contains the catalyst according to the invention. Finally, the invention is directed towards an exhaust-gas cleaning system which comprises the catalyst component containing the catalyst according to the invention.Type: GrantFiled: January 27, 2010Date of Patent: October 14, 2014Assignee: Clariant Produkte (Deutschland) GmbHInventors: Andreas Bentele, Klaus Wanninger, Gerd Maletz, Martin Schneider
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Patent number: 8858904Abstract: Described is a catalyzed soot filter wherein the inlet coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the outlet coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the outlet coating is lower than the Pt concentration in the inlet coating and wherein the weight ratio of Pt:Pd in the outlet coating is in the range of from 0:1 to 2:1; and wherein the inlet coating and the outlet coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.5 to 1.5, calculated as ratio of the loading of the inlet coating (in g/inch3 (g/(2.54 cm)3)):loading of the outlet coating (in g/inch3 (g/(2.54 cm)3)). Systems include such catalyzed soot filters, methods of diesel engine exhaust gas treatment and methods of manufacturing catalyzed soot filters are also described.Type: GrantFiled: February 22, 2011Date of Patent: October 14, 2014Assignee: BASF CorporationInventors: Alfred Helmut Punke, Gerd Grubert, Yuejin Li, Ruediger Wolff, Stanley Roth, Torsten Müller-Stach, Attilio Siani, Kenneth Voss, Torsten Neubauer
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Patent number: 8853123Abstract: Disclosed is a lean NOx trap (LNT) catalyst with enhanced NOx storage capacity at low temperature. More particularly, an LNT catalyst with enhanced NOx storage capacity at low temperature and significantly inhibited thermal desorption is prepared by coating a washcoat on a honeycomb-type carrier and drying and baking the same. The washcoat contains a first catalyst powder in which barium (Ba) and a precious metal are supported on a ceria support, and a second catalyst powder in which a precious metal is supported on a magnesium (Mg)-substituted alumina support The LNT catalyst of the present invention is useful as a NOx reducing catalyst for a passenger diesel vehicle.Type: GrantFiled: April 1, 2013Date of Patent: October 7, 2014Assignee: Hyundai Motor CompanyInventor: Chang Ho Jung
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Patent number: 8834972Abstract: The invention relates to a process and an apparatus for coating a plurality of catalyst support bodies.Type: GrantFiled: July 22, 2010Date of Patent: September 16, 2014Assignee: Umicore AG & Co., KGInventor: Wolfgang Hasselmann
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Patent number: 8802044Abstract: The invention relates to a filtration structure, for filtering a gas coming from a diesel engine, which is laden with gaseous pollutants of the nitrogen oxide NOx type and with solid particles, of the particulate filter type, said filtration structure being characterized in that it includes a catalytic system comprising at least one noble metal or transition metal suitable for reducing the NOx and a support material, in which said support material comprises or is made of a zirconium oxide partially substituted with a trivalent cation M3+ or with a divalent cation M?2+, said zirconium oxide being in a reduced, oxygen-sub-stoichiometric, state.Type: GrantFiled: December 16, 2009Date of Patent: August 12, 2014Assignees: Saint-Gobain Centre de Recherches et d'Etudes Europeen, Centre National de la Recherche ScientifiqueInventors: Philippe Vernoux, Abdelkader Hadjar, Agnes Princivalle, Christian Guizard
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Patent number: 8741242Abstract: A NOx storage component comprises caesium silicate (Cs2SiO3) and at least one platinum group metal. The invention also includes a NOx absorber catalyst comprising a NOx storage component according to the invention disposed on a substrate monolith; a method of treating exhaust gas containing NOx from a lean burn internal combustion engine comprising the steps of contacting a NOx storage component comprising caesium silicate (Cs2SiO3) and at least one platinum group metal with lean exhaust gas containing NOx to adsorb NOx thereon; and periodically desorbing adsorbed NOx by contacting the NOx storage component with stoichiometric or rich exhaust gas; and a method of making a NOx storage component according to the invention comprising the steps of combining and reacting an aqueous salt of at least one platinum group metal, an aqueous caesium salt and a source of silica.Type: GrantFiled: October 20, 2011Date of Patent: June 3, 2014Assignee: Johnson Matthey PLCInventors: Jonathan Ashley Cooper, Michael Anthony Howard
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Patent number: 8734743Abstract: Described is a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer provided on the substrate, the first washcoat layer comprising a nitrogen oxide storage material, a second washcoat layer provided on the first washcoat layer, the second washcoat layer comprising a hydrocarbon trap material, wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing selective catalytic reduction, preferably wherein the hydrocarbon trap material comprises substantially no element or compound in a state in which it is capable of catalyzing a reaction wherein nitrogen oxide is reduced to N2, said catalyst further comprising a nitrogen oxide conversion material which is either comprised in the second washcoat layer and/or in a washcoat layer provided between the first washcoat layer and the second washcoat layer.Type: GrantFiled: June 9, 2011Date of Patent: May 27, 2014Assignee: BASF SEInventors: Torsten W. Müller-Stach, Susanne Stiebels, Edith Schneider, Torsten Neubauer
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Patent number: 8716162Abstract: The zeolite structure is a porous zeolite structure constituted of a formed article obtained by extruding a zeolite raw material containing zeolite particles and an inorganic binding material including at least basic aluminum chloride, a ratio P1 (P1=V2/V1×100) of a volume V2 of the inorganic binding material in the zeolite structure with respect to a volume V1 of the zeolite structure is from 10 to 50 vol %, and a relation of equation (1) is satisfied: P2/P1?1.0??(1), in which P1 is the ratio of the volume V2 of the inorganic binding material in the zeolite structure with respect to the volume V1 of the zeolite structure and P2 (P2=Vb/Va×100) is a ratio of volumes Vb of pores having pore diameters of 0.003 to 0.03 ?m with respect to the whole pore volume Va of the zeolite structure.Type: GrantFiled: March 17, 2011Date of Patent: May 6, 2014Assignee: NGK Insulators, Ltd.Inventors: Yoshio Kikuchi, Haruo Otsuka
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Patent number: 8640440Abstract: Disclosed herein is a catalytically active particulate filter, an exhaust gas cleaning system and a process for cleaning the exhaust gases of predominantly stoichiometrically operated internal combustion engines, which are suitable, as well as the gaseous CO, HC and NOx pollutants, also for removing particulates from the exhaust gas. The particulate filter comprises a filter body and a catalytically active coating consisting of two layers. The first layer is in contact with the incoming exhaust gas, the second layer with the outgoing exhaust gas. Both layers contain alumina. The first layer contains palladium. The second layer contains, in addition to rhodium, an oxygen-storing cerium/zirconium mixed oxide.Type: GrantFiled: April 16, 2008Date of Patent: February 4, 2014Assignee: Umicore AG & Co. KGInventors: Raoul Klingmann, Martin Roesch, Dieter Lindner
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Patent number: 8603942Abstract: There is provided a honeycomb catalyst body comprising a honeycomb base body having porous partition walls forming a plurality of divided cells which extend from one end face of honeycomb base body to its other end face and which function as a fluid passage, and an outer wall present at the outermost peripheral portion of honeycomb base body, plugged portions provided so as to plug part of the plurality of divided cells, and a catalyst loaded on the partition walls of honeycomb base body. The plurality of divided cells include outermost peripheral cells formed by the partition walls and the outer wall, and of the outermost peripheral cells, those cells whose hydraulic diameter is 5 to 75% of the hydraulic diameter of a cell other than the outermost peripheral cells, are through-cells having no plugged portion.Type: GrantFiled: February 18, 2011Date of Patent: December 10, 2013Assignee: NGK Insulators, Ltd.Inventors: Chika Goto, Masataka Yamashita, Toshio Yamada, Yukio Miyairi
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Patent number: 8562926Abstract: A method and device for catchment of platinum group metals (PGM) in a gaseous steam, where the method comprises using a catalyst comprising a porous ceramic body in which at least a part of the surface area is covered by one or more PGM-catching metal(s)/alloy(s), and where the device comprises the porous ceramic body in which at least a part of the surface area is covered by one or more PGM-catching metal(s)/alloy(s). In a further aspect, the invention also relates to a method for producing the inventive device.Type: GrantFiled: November 7, 2011Date of Patent: October 22, 2013Assignee: Yara International ASAInventors: David Waller, David M. Brackenbury, Ketil Evjedal
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Patent number: 8563460Abstract: A catalyst unit is described comprising a cylinder with a length C and a diameter D, wherein said unit has five holes arranged in a pentagonal pattern extending longitudinally therethrough, with five flutes running along the length of the unit, said flutes positioned equidistant adjacent holes of said pentagonal pattern. The catalyst may be used particularly in steam reforming reactors.Type: GrantFiled: August 24, 2009Date of Patent: October 22, 2013Assignee: Johnson Matthey PLCInventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
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Patent number: 8557728Abstract: A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has one or more holes extending therethrough, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst or catalyst unit preferably has one or more flutes miming along its length. The catalyst may be used particularly in steam reforming reactors.Type: GrantFiled: August 24, 2009Date of Patent: October 15, 2013Assignee: Johnson Matthey PLCInventors: David James Birdsall, Mileta Babovic, Mikael Per Uno Carlsson, Samuel Arthur French, Michiel Nijemeisland, William Maurice Sengelow, Edmund Hugh Stitt
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Patent number: 8557203Abstract: A device is described which provides thermally durable NO2 generation in conjunction with efficient heat-up performance for filter regeneration, and low temperature HC (hydrocarbon) and CO activity. Importantly, it provides both functions while minimizing PGM (platinum group metals) utilization and its associated impact on catalyst cost.Type: GrantFiled: November 3, 2009Date of Patent: October 15, 2013Assignee: Umicore AG & Co. KGInventors: Owen Herman Bailey, Matthew Hedgecock, Frank-Walter Schuetze, Anke Woerz
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Patent number: 8557729Abstract: A catalyst unit is described in the form of a cylinder having a length C and diameter D, which has two or more flutes running along its length, wherein said cylinder has domed ends of lengths A and B, such that (A+B+C)/D is in the range 0.50 to 2.00, and (A+B)/C is in the range 0.40 to 5.00. The catalyst may be used particularly in reactions where hydrogen is a reactant such as hydroprocessing, hydrogenation, water-gas shift reactions, methanation, hydrocarbon synthesis by the Fischer-Tropsch reaction, methanol synthesis and ammonia synthesis.Type: GrantFiled: August 24, 2009Date of Patent: October 15, 2013Assignee: Johnson Matthey PLCInventors: Daniel Lee Cairns, Mileta Babovic, Terence James Fitzpatrick, Elizabeth Margaret Holt, Colin William Park, William Maurice Sengelow, Edmund Hugh Stitt
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Patent number: 8551910Abstract: The invention relates to a porous structure comprising a ceramic material comprising mainly or consisting of an oxide material of the pseudobrookite type comprising titanium, aluminum, magnesium and zirconium in proportions such that the phase of the pseudobrookite type substantially satisfies the formula: (Al2TiO5)x(MgTi2O5)y(MgTiZrO5)z. This material satisfies the following composition, in mol % on the basis of just the oxides Al2O3, TiO2, MgO and ZrO2: 90<2a+3m<110; 100+a<3t<210?a; and a+t+m+zr=100, in which: a is the molar content of Al2O3; t is the molar content of TiO2; m is the molar content of MgO; and zr is the molar content of ZrO2.Type: GrantFiled: July 2, 2009Date of Patent: October 8, 2013Assignee: Saint-Gobain Centre de Recherches et d'Etudes EuropeenInventors: Stephane Raffy, Philippe Auroy
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Patent number: 8518855Abstract: A honeycomb structure includes aluminum titanate, cell walls, and pore portions. The cell walls extend along a longitudinal direction of the honeycomb structure to define cells between the cell walls. The pore portions have an average pore diameter of about 10 ?m to about 20 ?m. A length of a longest pore portion among the pore portions in a binary image including substrate portions and the pore portions is about 8 times or less of the average pore diameter. The binary image is converted from a microscopic image of a cross section of the cell walls in parallel with the longitudinal direction. The length is measured along a line drawn in a direction perpendicular to a thickness direction of the cell walls.Type: GrantFiled: April 8, 2010Date of Patent: August 27, 2013Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Kazunori Yamayose
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Patent number: 8518857Abstract: Provided is a catalyst support structure for use as either a NOx catalyst support or as a DPF having a hydrophobic coating. The hydrophobic coating affords a catalyst support structure exhibiting reduced or low absorption when exposed to both liquid catalytic coating or other aqueous media and thus protecting the catalyst support structure from cracking and spalling during drying. Methods are also provided for making a catalyst support structure with a hydrophobic coating.Type: GrantFiled: December 16, 2004Date of Patent: August 27, 2013Assignee: Corning IncorporatedInventors: Max P. Bliss, Dana C. Bookbinder, Robert J. Paisley, Christopher J. Warren
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Patent number: 8501662Abstract: In a ceramic honeycomb structure, a catalyst material used for burning soot discharged from an internal combustion engine is supported on partition walls that are inner surfaces of cells. For example, a catalyst material to be used for burning carbon includes silver and alumina as components, and the catalyst material has a dumbbell-shaped O—Ag—O structure. Thus, the ceramic honeycomb structure can burn soot at low temperature using the supported catalyst material without corroding the honeycomb structure.Type: GrantFiled: March 19, 2008Date of Patent: August 6, 2013Assignee: Denso CorporationInventor: Yasushi Hayashi
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Patent number: 8501665Abstract: The present invention provides a method for manufacturing a film catalyst, including forming a catalyst layer on one side or each side of a base material to obtain a film catalyst, bending the film catalyst, and optionally cutting the film catalyst, wherein the bending step is conducted by bending the film catalyst with a bending tool composed of two gears that are oppositely arranged as meshing each other while a protective material having a compressibility of 40 to 95% is inserted between the catalyst layer of the film catalyst and the two gears.Type: GrantFiled: April 3, 2009Date of Patent: August 6, 2013Assignee: Kao CorporationInventors: Kunio Matsui, Masayasu Sato, Yoshimi Yamashita
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Patent number: 8496899Abstract: An exhaust gas purifying catalyst 1 has a catalyst substrate 3 and catalyst coating layers 5, 7 that are formed on the catalyst substrate 3 and contain (a) Rh, (b) Pt, (c) an alkali metal or alkaline earth element, and (d) an inorganic oxide. The catalyst coating layers 5, 7 has a layered structure including an inside layer 5 where the component (a) is substantially locally existing, and an outside layer 7 where the component (b) is substantially locally existing. The inside layer 5 also contains a zirconia oxide.Type: GrantFiled: January 25, 2008Date of Patent: July 30, 2013Assignee: Cataler CorporationInventor: Hiroto Imai
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Patent number: 8481454Abstract: A honeycomb structure includes aluminum titanate and cell walls. The cell walls extend along a longitudinal direction of the honeycomb structure to form a plurality of cells between the cell walls. A porosity of the honeycomb structure is from about 40% to about 60%. In a binary image of substrate portions and pore portions of each of the cell walls, an area ratio (%) of the pore portions to a whole area in a rectangularly-divided image is in a range from (the porosity?about 25%) to (the porosity+about 25%). The binary image is converted from a microscopic image of a cross section of each of the cell walls in parallel with the longitudinal direction. The rectangularly-divided image is formed by dividing the binary image in a direction parallel to a thickness direction of each of the cell walls at a predetermined width.Type: GrantFiled: May 12, 2010Date of Patent: July 9, 2013Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Kazunori Yamayose
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Patent number: 8445773Abstract: A thermoelectric generator has a hot side heat exchanger having a silicon carbide (SiC) honeycomb support with a plurality of passages. The passage walls are coated with a pyrophoric solid fuel such as red oxide (Fe2O3) in combination with a silicon (Si) binder. A quantum well thermoelectric device is positioned between the hot side heat exchanger and heat sink. The performance of the thermoelectric generator is comparable to fuel cells. The thermoelectric generator is small and portable.Type: GrantFiled: February 25, 2010Date of Patent: May 21, 2013Assignee: The United States of America as represented by the Secretary of the NavyInventor: Thanh Nhon Tran
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Patent number: 8349758Abstract: A catalyst with large surface area structure, in particular for steam-reforming catalysts, which is characterized in that the large surface area structure is formed of a large number of round or parallel penetrating holes of polygonal cross-section, wherein the catalyst carrier is prepared in the injection molding process, coated with a washcoat and then impregnated with the active component. The catalyst carrier includes at least one sinterable material and has a lateral pressure resistance of at least 700 N. Also, a process for the preparation of such catalysts and the use thereof in a reactor.Type: GrantFiled: September 25, 2008Date of Patent: January 8, 2013Assignee: Sud-Chemie AGInventors: Wolfgang Gabriel, Ingo Hanke
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Patent number: 8334230Abstract: A honeycomb structure includes at least one honeycomb unit which includes walls. The walls have a thickness of from about 0.10 mm to about 0.50 mm and extend along a longitudinal direction of the honeycomb structure to define through-holes. The honeycomb structure has a center area inside a boundary line passing through positions located at substantially a half of a length from a center of the honeycomb structure to a periphery of the honeycomb structure in a cross section perpendicular to the longitudinal direction. The honeycomb structure has a peripheral area outside the boundary line. A thickness of the walls located in the peripheral area is larger than a thickness of the walls located in the center area. A first opening ratio in the center area in the cross section is larger than a second opening ratio in the peripheral area in the cross section.Type: GrantFiled: July 22, 2009Date of Patent: December 18, 2012Assignee: Ibiden Co., Ltd.Inventors: Kazushige Ohno, Masafumi Kunieda, Takahiko Ido
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Patent number: 8318632Abstract: An exhaust gas purification catalyst includes a substrate, and a first catalyst layer formed on the substrate, the first catalyst layer containing palladium and/or platinum and alumina doped with an alkaline-earth metal element. The exhaust gas purification catalyst has a correlation coefficient ?Al,AE given by the following formula of 0.75 or more: ? Al , AE = C Al , AE ? Al ? ? AE .Type: GrantFiled: June 17, 2011Date of Patent: November 27, 2012Assignee: Cataler CorporationInventors: Satoshi Matsueda, Akimasa Hirai, Kenichi Taki, Keiichi Narita, Yuji Yabuzaki, Daisuke Ochiai
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Patent number: 8302557Abstract: A device and a method which is capable of uniformly coating, without waste, any flow passages formed in a raw material with a slurry even if a slurry having high viscosity is fed thereto by an amount required for the use of coating without excess and shortage. When the slurry (S) fed to one end of the base material (M) in which a large number of flow passages (2 . . . ) are formed parallel with each other is forced into the flow passages (2 . . . ) by an air pressure to coat the inner walls (2w) of the flow passages, the slurry (S) is fed from a slurry feeding device (6) by a required amount to a slurry storage part (5) formed at the upper surface part of the base material (M) disposed so that both ends of the flow passages (2 . . . ) can be opened in the upper and bottom surfaces thereof. Then, before the slurry (S) is forced into the flow passages (2 . . .Type: GrantFiled: July 7, 2005Date of Patent: November 6, 2012Assignee: Cataler CorporationInventors: Tomoyuki Goshima, Shigeji Matsumoto, Kosuke Shinomiya
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Patent number: 8258070Abstract: An emission control catalyst that exhibits improved CO and HC reduction performance includes supported precious group metal catalysts that are coated onto different layers of the substrate for the emission control catalyst. Zeolites of one or more types are added to the emission control catalyst as a hydrocarbon absorbing component to boost the low temperature performance of the emission control catalyst. Y zeolite is used by itself or mixed with other zeolites to enhance hydrocarbon storage at low temperatures.Type: GrantFiled: November 9, 2009Date of Patent: September 4, 2012Inventors: Kyle L. Fujdala, Timothy J. Truex, Juan Cai, Chaitanya Sampara
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Patent number: 8211818Abstract: A honeycomb structural body includes at least one honeycomb unit which has a longitudinal direction. The at least one honeycomb unit includes plural cell walls, an inorganic binder, and inorganic particles. The plural cell walls extends along the longitudinal direction from one end face to another end face of the at least one honeycomb unit to define plural cells. The inorganic particles include ceria particles, and a ceramic material which has a degree of self-sintering lower than a degree of self-sintering of the ceria particles.Type: GrantFiled: October 9, 2008Date of Patent: July 3, 2012Assignee: Ibiden Co., Ltd.Inventors: Masafumi Kunieda, Shinnosuke Goto, Toshiyuki Miyashita
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Patent number: 8207078Abstract: A close coupled three-way catalyst for purification of exhaust gas of motor vehicle and the preparation thereof. The support is selected from cordierite honeycomb ceramic materials having a pore volume of 0.25-0.35 ml/g. The coating layer is the mixture of hexaaluminate and perovskite-type composite oxide, cerium-zirconium solid solution, rare-earth oxide and alumina, alkali-earth oxide and zeolite having a high Si/Al ratio. The active components are palladium-rhodium, rare-earth oxide and transition metal in the hexaaluminate and perovskite-type composite oxide. The catalyst has not only the function of low-temperature catalytic oxidation of hydrocarbons, but also the function of reduction of nitrogen oxides, and can be used for purifying the exhaust gas of motor vehicles using gasoline, liquid gas, or CNG as fuel.Type: GrantFiled: February 14, 2007Date of Patent: June 26, 2012Assignee: East China University of Science and TechnologyInventors: Guanzhong Lu, Yun Guo, Zhigang Zhang
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Patent number: 8178469Abstract: A catalyst for purifying exhaust gas in vehicles may include a precious metal and porous structures that serve as a supporting material for the precious metal. The porous structures are comprised of a plurality of channels which are connected with each other by a plurality of bridges. The channels may have multiple entrances that allow reactants to pass through and react with the precious metal.Type: GrantFiled: July 22, 2011Date of Patent: May 15, 2012Assignee: Hyundai Motor CompanyInventor: Hyokyung Lee
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Patent number: 8148297Abstract: A porous ceramic material is disclosed having a principal cordierite phase, the porous ceramic material exhibiting a normalized strength greater than 20 MPa. The cordierite phase has a reticular microstructure. A method for forming a porous ceramic body having a predominant phase of cordierite is provided which includes forming a body from a plasticized mixture of inorganic ceramic-forming ingredients that include a magnesia source, a silica source, and an alumina source, the alumina source including alumina-containing elongated particles, wherein at least 90 wt % of the alumina-containing elongated particles have a length of 50 to 150 ?m, and then firing the body.Type: GrantFiled: November 30, 2009Date of Patent: April 3, 2012Assignee: Corning IncorporatedInventors: Monika Backhaus-Ricoult, Christopher Raymond Glose, James William Zimmermann
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Patent number: 8114354Abstract: Catalyzed soot filters comprising a wall flow monolith having microcracks and pores and a catalyst comprising support particles with particle sizes greater than about the size of the microcracks and less than about the size of the pores are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.Type: GrantFiled: December 18, 2007Date of Patent: February 14, 2012Assignee: BASF CorporationInventor: Yuejin Li
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Patent number: 8088707Abstract: A supported catalyst with a solid sphere structure of the present invention includes an oxide supporting body and a metal such as Ni, Co, Fe, or a combination thereof distributed on the surface and inside of the supporting body. The supported catalyst with a solid sphere structure can maintain a spherical shape during heat treatment and can be used with a floating bed reactor due to the solid sphere structure thereof.Type: GrantFiled: December 17, 2009Date of Patent: January 3, 2012Assignee: Cheil Industries Inc.Inventors: Byeong Yeol Kim, Yun Tack Lee, Seung Yong Bae, Young Sil Lee
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Patent number: 8071061Abstract: The invention relates to a device for the catalytic treatment of exhaust gases of motor vehicles which comprises a catalyst substrate designed as a hollow cylinder, an inlet-side and an outlet-side gas baffle and an outer wall, wherein the gas baffles enclose the catalyst substrate and the outlet-side gas baffle and the catalyst substrate form a first cavity into which an exhaust-gas stream can be fed, passing through the catalyst substrate and entering a second cavity which is surrounded by outer wall, gas baffles and catalyst substrate, wherein the outlet-side gas baffle has gas vents, and wherein the recessed part of the outlet-side gas baffle is beaded, with the result that the catalyst substrate is fixed. The invention also relates to a process for the production of the device according to the invention and its use, plus a method for cleaning exhaust gases of motor vehicles.Type: GrantFiled: March 18, 2008Date of Patent: December 6, 2011Assignee: Alantum CorporationInventors: Michael Goevert, Stefan Ebener, Thomas Scheerer, Thomas Krusenbaum
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Patent number: 8062521Abstract: A filtering medium and method for removing contaminants from an organic-based feed stream which includes the use of a layer of ceramic filter units having a plurality of elliptical or trisoidal openings extending therethrough to filter organic-based feed streams and to provide liquid distribution upstream of the catalyst beds.Type: GrantFiled: May 27, 1999Date of Patent: November 22, 2011Assignee: Crystaphase Products, Inc.Inventor: John N. Glover
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Patent number: 8052936Abstract: In a particulate filter, a catalyst layer containing Pt-carried activated alumina particles, CeZr-based mixed oxide particles and ZrNd-based mixed oxide particles is formed, the proportion of the total amount of the CeZr-based mixed oxide particles and the ZrNd-based mixed oxide particles in the total amount of the Pt-carried activated alumina particles, the CeZr-based mixed oxide particles and the ZrNd-based mixed oxide particles is 10% to 60% by mass, both inclusive, and the mass ratio of the CeZr-based mixed oxide particles to the ZrNd-based mixed oxide particles is 20/80 to 80/20, both inclusive. This configuration enhances the particulate burning property and the low-temperature exhaust gas conversion efficiency.Type: GrantFiled: July 9, 2008Date of Patent: November 8, 2011Assignee: Mazda Motor CorporationInventors: Koichiro Harada, Kenji Suzuki, Kenji Okamoto, Hiroshi Yamada, Akihide Tamani
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Patent number: 8048820Abstract: The invention relates to a shaped catalyst body for preparing maleic anhydride, which comprises mixed oxides of vanadium and of phosphorus as catalyst components. To develop a generic shaped catalyst body further so that it has improved properties, it is proposed that the basic geometric body enveloping the shaped catalyst body (100; 200) be a prism (180) having a first triangular face and a second triangular face and the shaped catalyst body (100; 200) be provided with three through openings (111, 121, 131; 211, 221, 231) which extend from a first face of the shaped body (100; 200) which contacts the first triangular face of the prism (180) to a second face of the shaped body (100; 200) which contacts the second triangular face of the prism (180).Type: GrantFiled: October 31, 2006Date of Patent: November 1, 2011Assignee: Sud-Chemie AGInventors: Willi Brandstädter, Leopold Streifinger, Marvin Estenfelder
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Patent number: 8038956Abstract: Catalyzed soot filters comprising a wall flow monolith having microcracks and pores and a catalyst comprising support particles with particle sizes greater than about the size of the microcracks and less than about the size of the pores are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.Type: GrantFiled: December 16, 2008Date of Patent: October 18, 2011Assignee: BASF CORPORATIONInventor: Yuejin Li
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Patent number: 8038954Abstract: An emission treatment system including a catalyzed soot filter comprising a wall flow monolith and a catalyst comprising at least two types of support particles is described. The first support particle contains at least a platinum component, the second support particles contains at least a palladium component. The wall flow monolith may be washcoated with a slurry comprising at least two types of particles without applying a passivation layer to the wall flow monolith.Type: GrantFiled: February 14, 2008Date of Patent: October 18, 2011Assignee: BASF CorporationInventor: Yuejin Li
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Patent number: 8034311Abstract: An oxidation catalyst that efficiently promotes oxidation of NO to NO2 even in a low temperature range, and an exhaust-gas purification system and method that efficiently removes exhaust-gas components even in a low temperature range are provided. This invention provides an oxidation catalyst comprising platinum and palladium as catalytically active components, which promotes oxidation of nitrogen monoxide to nitrogen dioxide, wherein the oxidation catalyst comprises 1 to 55 parts by weight of the palladium relative to 100 parts by weight of the platinum.Type: GrantFiled: February 17, 2010Date of Patent: October 11, 2011Assignees: ICT Co., Ltd., International Catalyst Technology, Inc.Inventors: Masanori Ikeda, Naohiro Kato