By Heat Patents (Class 502/56)
  • Patent number: 11644153
    Abstract: Natural gas storage units and methods for reducing effects of fluctuating demand on natural gas, a natural gas storage facility including an adsorbed natural gas storage unit containing carbon-based adsorbents; a temperature control system coupled to the adsorbed natural gas storage unit to regulate temperature of the adsorbed natural gas storage unit; and a compressor system coupled to the adsorbed natural gas storage unit to regulate pressure of the adsorbed natural gas storage unit.
    Type: Grant
    Filed: November 8, 2019
    Date of Patent: May 9, 2023
    Inventors: Yuguo Wang, Rashid Othman, Richard Gunther, Ahmed Aman
  • Patent number: 11491437
    Abstract: A process for the production of a hydrogen gas stream having a CO content of less than 1 ppm having a production cycle comprising two phases: phase 1 includes a) purifying a synthesis gas in a PSA unit, b) recovering a hydrogen gas stream comprising a CO content of greater than 1 ppm, c) purifying the gas stream by adsorption in a TSA unit, and recovery a hydrogen gas stream exhibiting a CO content of less than 1 ppm, and phase 2 includes e) purifying the synthesis gas in a PSA unit, f) recovering a hydrogen gas stream having a CO content of less than 1 ppm, where throughout steps e) and f), the TSA unit is bypassed by the hydrogen gas stream and is regenerated.
    Type: Grant
    Filed: July 13, 2018
    Date of Patent: November 8, 2022
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Daniel Gary, Laurent Allidieres
  • Patent number: 11471831
    Abstract: A method for regenerating a deNOx catalyst includes contacting the catalyst with steam at a temperature in the range of from 250 to 390° C. The method also includes reducing the amount of nitrogen oxide components in a process gas stream that includes a) contacting the process gas with a deNOx catalyst which results in the conversion of nitrogen oxide components as well as a decline in the NOx conversion over the deNOx catalyst; and b) regenerating the deNOx catalyst to improve the NOx conversion by contacting the deNOx catalyst with steam at a temperature in the range of from 250 to 390° C.
    Type: Grant
    Filed: September 25, 2017
    Date of Patent: October 18, 2022
    Assignee: SHELL USA, INC.
    Inventors: Wenzhong Zhang, Geert Marten Bakker, Steven Russell Lee
  • Patent number: 11414371
    Abstract: A method for producing methyl methacrylate including: a distillation step including: supplying a reaction solution, which is obtained by subjecting methacrolein, methanol, and molecular oxygen to oxidative esterification in an oxidative esterification reactor and which contains the methyl methacrylate as a reaction product, to a first distillation column located at downstream of the oxidative esterification reactor, extracting a fraction containing the methacrolein and the methanol from a medium section of the first distillation column, and extracting a column bottom liquid containing the methyl methacrylate from a column bottom of the first distillation column, wherein a concentration of the methanol in the column bottom liquid is 1% by mass or more and 30% by mass or less.
    Type: Grant
    Filed: April 15, 2020
    Date of Patent: August 16, 2022
    Assignee: ASAHI KASEI KABUSHIKI KAISHA
    Inventors: Hideyuki Saito, Takamasa Ito, Masahiko Idemoto
  • Patent number: 11364481
    Abstract: A system and method for producing a modified coal ash involves collecting a bulk quantity of such coal ash, generally after it has been produced or landfilled, or is otherwise at temperatures closer to ambient, as opposed to power plant operational temperatures. In one possible implementation, the method herein involves removing carbon from the coal ash, such removal occurring by exposing the carbon to indirect heat, that is, externally-applied heat. For coal ashes with higher ash content. This removal is accomplished by subjecting the coal ash stream to heat, in one implementation, ranging between 850° F. and 1200° F., and such heat exposure occurring from about 10 minutes to about 30 minutes. The range of exposure time for the coal ash is determined so as to reduce the LOI from its initial level to a level acceptable for intended re-use or recycling. In one application, the LOI of carbon in the ash is reduced to 3% or less carbon.
    Type: Grant
    Filed: January 23, 2018
    Date of Patent: June 21, 2022
    Assignee: MERCURY CAPTURE INTELLECTUAL PROPERTY, LLC
    Inventor: Christopher L. Poling
  • Patent number: 11318443
    Abstract: In a process for thermally desorbing a phase material (20), in particular for conditioning a fiber for carrying out a solid-phase microextraction, the phase material (20) is heated along a temperature curve. The temperature curve of the phase material (20) during desorption includes at least one low point.
    Type: Grant
    Filed: September 20, 2019
    Date of Patent: May 3, 2022
    Assignee: CTC ANALYTICS AG
    Inventors: Stefan Anton Cretnik, Beat Schilling, Chiew Mei Chong
  • Patent number: 11179673
    Abstract: Various embodiments disclosed relate to sorbents for the oxidation and removal of mercury. The present invention includes removing mercury from a mercury-containing gas using a halide-promoted and optionally ammonium-protected sorbent that can include carbon sorbent, non-carbon sorbent, or a combination thereof.
    Type: Grant
    Filed: December 22, 2017
    Date of Patent: November 23, 2021
    Assignee: Midwwest Energy Emission Corp.
    Inventors: John H. Pavlish, Edwin S. Olson, Michael J. Holmes
  • Patent number: 11045757
    Abstract: A reclaiming apparatus includes: a container; an absorption-liquid supply line for supplying the container with an absorption liquid containing an absorption agent; a water supply line for supplying the container with a water; a steam discharge line for discharging steam from the container; a heating device for heating a liquid containing at least one of the water or the absorption liquid; and a control device configured to determine, on the basis of a temperature of the liquid stored in the container, an ending timing of an absorption-agent recovery process of recovering steam containing the absorption agent via the steam discharge line by heating of the liquid with the heating device.
    Type: Grant
    Filed: October 10, 2018
    Date of Patent: June 29, 2021
    Assignee: Mitsubishi Heavy Industries Engineering, Ltd.
    Inventors: Osamu Miyamoto, Takashi Kamijo, Tatsuya Tsujiuchi
  • Patent number: 10987623
    Abstract: Various embodiments disclosed relate to sorbents for the oxidation and removal of mercury. The present invention includes removing mercury from a mercury-containing gas using a halide-promoted and optionally ammonium-protected sorbent that can include carbon sorbent, non-carbon sorbent, or a combination thereof.
    Type: Grant
    Filed: December 22, 2017
    Date of Patent: April 27, 2021
    Assignee: Midwest Energy Emission Corp
    Inventors: John H. Pavlish, Edwin S. Olson, Michael J. Holmes
  • Patent number: 10881867
    Abstract: A method for making a dielectric substrate configured for incorporation into a hermetically sealed feedthrough is described. The method includes forming a via hole through a green-state dielectric substrate. A platinum-containing paste is filled into at least 90% of the volume of the via hole. The green-state dielectric substrate is then subjected to a heating protocol including: a binder bake-out heating portion performed at a temperature ranging from about 400° C. to about 700° C. for a minimum of 4 hours; a sintering heating portion performed at a temperature ranging from about 1,400° C. to about 1,900° C. for up to 6 hours; and a cool down portion at a rate of up to 5°/minute from a maximum sintering temperature down to about 1,000° C., then naturally to room temperature. The thusly manufacture dielectric substrate is then positioned in an opening in a ferrule that is configured to be attached to a metal housing of an active implantable medical device.
    Type: Grant
    Filed: December 10, 2019
    Date of Patent: January 5, 2021
    Assignee: Greatbatch Ltd.
    Inventors: Robert A. Stevenson, Xiaohong Tang, William C. Thiebolt, Christine A. Frysz, Keith W. Seitz, Richard L. Brendel, Thomas Marzano, Jason Woods, Dominick J. Frustaci, Steven W. Winn
  • Patent number: 10865347
    Abstract: The present invention relates to a process for the treatment of refinery purge streams, containing a hydrocarbon component in slurry phase having a boiling point higher than or equal to 140° C., characterized by the presence of quantities of asphaltenes higher than or equal to 5% by weight and characterized by the presence of a solid content higher than or equal to 5% by weight. The process provides that said purge be mixed with a suitable fluxing agent according to appropriate ratios and under certain conditions, forming a suspension with a content higher than or equal to 10% by weight of compounds having a boiling point TbP lower than or equal to 350° C. After mixing, the suspension is sent to a liquid/solid separation step which operates under suitable conditions, separating a solid phase containing a residual organic component and a solid component, called cake, and a liquid phase containing residual solids. The solid phase obtained is cooled to below 60° C.
    Type: Grant
    Filed: December 21, 2016
    Date of Patent: December 15, 2020
    Assignee: ENI S.p.A.
    Inventor: Andrea Bartolini
  • Patent number: 10682628
    Abstract: A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with a median diameter between 1.6 mm and 2.5 mm and an apparent bulk density between 0.6 and 0.3 g/cc. Also a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
    Type: Grant
    Filed: November 1, 2018
    Date of Patent: June 16, 2020
    Assignee: UOP LLC
    Inventors: Manuela Serban, Matthew C. Cole, Ellen Arnold, Guanghui Zhu
  • Patent number: 10682629
    Abstract: A catalyst for a selective conversion of hydrocarbons. The catalyst includes a first component selected from the group consisting of Group VIII noble metals and mixtures thereof, a second component selected from the group consisting of alkali metals or alkaline-earth metals and mixtures thereof, and a third component selected from the group consisting of tin, germanium, lead, indium, gallium, thallium and mixtures thereof. The catalyst is a support formed as a spherical catalyst particle with an average pore diameter between 200 to 350 Angstroms, a porosity of at least 75% and an apparent bulk density between 0.60 and 0.3 g/cc. Also, a process of using such a catalyst for a selective hydrocarbon conversion reaction and a process for regenerating such a catalyst by removing coke from same.
    Type: Grant
    Filed: November 1, 2018
    Date of Patent: June 16, 2020
    Assignee: UOP LLC
    Inventors: Manuela Serban, Matthew C. Cole, Ellen Arnold, Guanghui Zhu
  • Patent number: 10561989
    Abstract: A system includes an engine and an exhaust conduit in communication with the engine. A water separation device has exhaust gas passageways in communication with the exhaust conduit. The water separation device has a substrate and a membrane on the substrate. The substrate has inner walls surrounding the exhaust gas passageways with at least one of the inner walls being common to at least two of the exhaust gas passageways. The membrane is between the exhaust gas passageways and the substrate and has capillary condensation pores extending from the exhaust gas passageways to the substrate.
    Type: Grant
    Filed: September 10, 2018
    Date of Patent: February 18, 2020
    Assignee: Tenneco Automotive Operating Company Inc.
    Inventors: Michael C. Bradford, Melanie Moses DeBusk, Brian L. Bischoff
  • Patent number: 10537874
    Abstract: Provided is a method for producing a particulate water absorbing agent, the method including the steps of: a polymerization step of polymerizing an acrylic acid (salt)-based aqueous monomer solution so as to obtain a crosslinked hydrogel polymer; a drying step of drying the crosslinked hydrogel polymer so as to obtain a dried polymer; a classification step of classifying a polymer subjected to classification so as to obtain a water-absorbing resin powder having a specific particle size; and a surface-crosslinking step of surface-crosslinking the water-absorbing resin powder that is not surface crosslinked, wherein the classification step is carried out at least either or both of before and/or after the surface-crosslinking step but after said drying step, and wherein a hole shape of a classification sieve used in the classification step is an irregular polygonal or non-circular.
    Type: Grant
    Filed: March 30, 2016
    Date of Patent: January 21, 2020
    Assignee: NIPPON SHOKUBAI CO., LTD.
    Inventors: Kazushi Torii, Kunihiko Ishizaki, Shinichi Fujino, Ryota Wakabayashi, Motohiro Imura
  • Patent number: 10500402
    Abstract: A hermetically sealed feedthrough for attachment to an active implantable medical device includes a dielectric substrate configured to be hermetically sealed to a ferrule or an AIMD housing. A via hole is disposed through the dielectric substrate from a body fluid side to a device side. A conductive fill is disposed within the via hole forming a filled via electrically conductive between the body fluid side and the device side. A conductive insert is at least partially disposed within the conductive fill. Then, the conductive fill and the conductive insert are co-fired with the dielectric substrate to form a hermetically sealed and electrically conductive pathway through the dielectric substrate between the body fluid side and the device side.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: December 10, 2019
    Assignee: Greatbatch Ltd.
    Inventors: Robert A. Stevenson, Xiaohong Tang, William C. Thiebolt, Christine A. Frysz, Keith W. Seitz, Richard L. Brendel, Thomas Marzano, Jason Woods, Dominick J. Frustaci, Steven W. Winn
  • Patent number: 9943828
    Abstract: The invention relates to a process for regeneration of an adsorber (A) by contact with a stream (S1), wherein the stream (S1) is heated in advance by at least two heat exchange units (HEU1) and (HEU2). As outflow of the adsorber (A) a stream (S2) is obtained, which is passed through at least two heat exchange units (HEU1) and (HEU2) traversed by stream (S1), wherein the temperature of stream (S2) fed into each heat exchange unit is higher than the temperature of stream (S1) fed into the heat exchange units (HEU1) and (HEU2), in order to directly transfer heat from stream (S2) to stream (S1).
    Type: Grant
    Filed: October 9, 2014
    Date of Patent: April 17, 2018
    Assignee: BASF SE
    Inventors: Hans-Guenter Wagner, Christoph Bayer, Lothar Karrer, Sven Crone, Markus Eggersmann, Guenther Kirchner, Gabriele Zimmer, Kam Wing Wong, Patrik Pietz, Heinz Ruetter
  • Patent number: 9895687
    Abstract: The invention relates to a catalyst regeneration process for a tar reforming catalyst within a catalyst bed in a tar reformer. The process comprises the steps of:—Admitting a main gas stream with controlled temperature and oxygen content to an inlet into the tar reformer;—Passing the main gas stream through the catalyst bed to form an oxygen depleted gas stream;—Exiting the oxygen depleted gas stream from the tar reformer; and—Recycling at least a part of the oxygen depleted gas stream exiting from the tar reformer back into said main gas stream upstream said tar reformer. The temperature of said main gas stream at the inlet is controlled to be within the range from about 500° C. to about 1000° C.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: February 20, 2018
    Assignee: Haldor Topsoe A/S
    Inventors: John Bøgild Hansen, Jørgen Madsen, Klas Jerker Andersson
  • Patent number: 9896401
    Abstract: Provided is a method for easily and safely removing, from a reactor, a catalyst used in a reaction that is performed using hydrogen fluoride in the presence of the catalyst. In a reaction performed in a reactor containing at least hydrogen fluoride and a catalyst, the catalyst is removed through a process comprising a heating step of performing heat-treatment so that the ambient temperature of the reactor is 80° C. or more after completion of the reaction, and a purge step of flowing inert gas into the reactor to discharge the hydrogen fluoride to the outside of the reactor after completion of the reaction.
    Type: Grant
    Filed: December 2, 2015
    Date of Patent: February 20, 2018
    Assignee: DAIKIN INDUSTRIES, LTD.
    Inventors: Masami Nishiumi, Daisuke Karube
  • Patent number: 9889306
    Abstract: A hermetically sealed feedthrough for attachment to an active implantable medical device includes a dielectric substrate configured to be hermetically sealed to a ferrule or an AIMD housing. A via hole is disposed through the dielectric substrate from a body fluid side to a device side. A conductive fill is disposed within the via hole forming a filled via electrically conductive between the body fluid side and the device side. A conductive insert is at least partially disposed within the conductive fill. Then, the conductive fill and the conductive insert are co-fired with the dielectric substrate to form a hermetically sealed and electrically conductive pathway through the dielectric substrate between the body fluid side and the device side.
    Type: Grant
    Filed: July 11, 2015
    Date of Patent: February 13, 2018
    Assignee: Greatbatch Ltd.
    Inventors: Robert A. Stevenson, Xiaohong Tang, William C. Thiebolt, Christine A. Frysz, Keith W. Seitz, Richard L. Brendel, Thomas Marzano, Jason Woods, Dominick J. Frustaci, Steven W. Winn
  • Patent number: 9861976
    Abstract: Disclosed herein is a process for the regeneration of oxidative dehydrogenation (OXO-D) catalyst in an alternate or separate regeneration reactor by employing controlled steam:air and time/pressure/temperature conditions. The process avoids destruction of the catalyst, and wear/tear on an OXO-D reactor. The regenerated catalyst is an iron based oxide catalyst which can be zinc or zinc-free. The iron based oxide catalyst is regenerated in the regeneration reactor by feeding an air/steam stream over a set amount of time, preferably about 6 days to yield a regenerated OXO-D catalyst. The regenerated catalyst is activated and re-utilized to produce butadienes.
    Type: Grant
    Filed: March 1, 2017
    Date of Patent: January 9, 2018
    Assignee: TPC Group LLC
    Inventors: Joseph G. Duff, Jillian M. Horn
  • Patent number: 9731275
    Abstract: Provided is a catalytic converter in which the entire catalyst constituting the catalytic converter can be efficiently utilized to purify exhaust gas, and the emission of hydrogen sulfide can be suppressed. A catalytic converter 10 includes catalyst layers 2A, 2B formed of a noble metal catalyst that are formed on cell wall surfaces of a substrate 1 having a cell structure in a longitudinal direction of the substrate 1 in which gas flows, in which the substrate 1 has a center region 1A having a relatively high cell density and a peripheral region 1B having a relatively low cell density, and lengths of the catalyst layers 2A, 2B of the center region 1A and the peripheral region 1B in the longitudinal direction are the same as each other, or the length of the catalyst layer 2B in the longitudinal direction is shorter than that of the catalyst layer 2A.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: August 15, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yuki Aoki, Hiromasa Suzuki, Hiroyuki Matsubara
  • Patent number: 9701544
    Abstract: A method for calcination includes providing a heated coarse solid particle stream with a carbon dioxide rich sorbent to a reactor having a rotatable container.
    Type: Grant
    Filed: January 6, 2017
    Date of Patent: July 11, 2017
    Assignee: General Electric Technology GmbH
    Inventors: Michael Charles Balfe, Gerhard Heinz, Olaf Stallmann, Christoph Weingärtner
  • Patent number: 9687662
    Abstract: A hermetically sealed feedthrough for attachment to an active implantable medical device includes a dielectric substrate configured to be hermetically sealed to a ferrule or an AIMD housing. A via hole is disposed through the dielectric substrate from a body fluid side to a device side. A conductive fill is disposed within the via hole forming a filled via electrically conductive between the body fluid side and the device side. A conductive insert is at least partially disposed within the conductive fill. Then, the conductive fill and the conductive insert are co-fired with the dielectric substrate to form a hermetically sealed and electrically conductive pathway through the dielectric substrate between the body fluid side and the device side.
    Type: Grant
    Filed: July 11, 2015
    Date of Patent: June 27, 2017
    Assignee: Greatbatch Ltd.
    Inventors: Robert A. Stevenson, Xiaohong Tang, William C. Thiebolt, Christine A. Frysz, Keith W. Seitz, Richard L. Brendel, Thomas Marzano, Jason Woods, Dominick J. Frustaci, Steven W. Winn
  • Patent number: 9573848
    Abstract: A method for calcination of a carbon dioxide rich sorbent (containing CaCO3) includes combusting in a furnace a fuel with an oxidizer, supplying heat transfer (HT) solids into the furnace and heating them, transferring the HT solid particles from the furnace to a reactor having a rotatable container, supplying a carbon dioxide rich solid sorbent (containing CaCO3) into the rotatable container, rotating the rotatable container for mixing the solid particles and the carbon dioxide rich solid sorbent for transferring heat from the solid particles to the carbon dioxide rich solid sorbent and generating carbon dioxide and carbon dioxide lean solid sorbent (mainly CaO), discharging the carbon dioxide and the carbon dioxide lean solid sorbent from the rotatable container and the subsequent classification of the HT solids from the lean sorbent.
    Type: Grant
    Filed: June 17, 2015
    Date of Patent: February 21, 2017
    Assignee: General Electric Technology GmbH
    Inventors: Michael Charles Balfe, Gerhard Heinz, Olaf Stallmann, Christoph Weingärtner
  • Patent number: 9566570
    Abstract: A process for facilitating the unloading of a fixed bed of cobalt/metal oxide catalyst particles from a reactor tube by (i) feeding a gas comprising 10 to 30 (vol/vol) percent of oxygen to the reactor tube with a GHSV for oxygen of 0.5 to 50 Nl/l/hr, and (ii) removing the catalyst particles from the reactor tube. In the fixed bed of catalyst particles to which the oxygen comprising gas is fed in step (i) at most 10 mole % of the element cobalt is present in Co3O4 and/or CoO, calculated on the total amount of moles of cobalt in the catalyst particles.
    Type: Grant
    Filed: November 4, 2014
    Date of Patent: February 14, 2017
    Assignee: SHELL OIL COMPANY
    Inventors: Thomas Joris Remans, Gerrit Leendert Bezemer, Franciscus Johannes Maria Schrauwen
  • Patent number: 9533259
    Abstract: Disclosed is a method for regenerating a SCR denitration catalyst assisted by microwaves. The method comprises: (1) a poisoned SCR denitration catalyst is immersed in deionized water, and the SCR denitration catalyst is cleaned by a bubbling method; (2) the SCR denitration catalyst is transferred to a container containing a pore-expanding solution for a soaking treatment; (3) the SCR denitration catalyst is transferred to a microwave device and treated for 1-10 minutes; (4) the SCR denitration catalyst is transferred to a container with an activating liquid and impregnated for 1-4 hours; (5) the SCR denitration catalyst is dried with microwaves for 1-20 minutes; and (6) the SCR denitration catalyst is calcined under conditions of 500-600° C. for 4-7 hours. The present invention has readily available raw materials, is simple and energy-saving in device and process, and is suitable for industrial scale regeneration.
    Type: Grant
    Filed: October 9, 2013
    Date of Patent: January 3, 2017
    Assignee: ZHEJIANG UNIVERSITY
    Inventors: Xiang Gao, Zhongyang Luo, Kefa Cen, MingJiang Ni, Hao Song, Weihong Wu, Hongmin Yu, Zhenglun Shi, Jinsong Zhou, Mengxiang Fang, Chunjiang Yu, Shurong Wang, Lemin Cheng, Qinhui Wang
  • Patent number: 9463414
    Abstract: A dehumidifying unit, a layered temperature control dehumidifying element, a drying device and a temperature control method thereof are provided. The dehumidifying element has a plurality of dehumidifying units. The dehumidifying units are made of a direct heating desorption material and used for dehumidifying air by adsorption and capable of being regenerated by desorption. By performing temperature compensation through a preheater and performing a layered temperature control method on the dehumidifying element, the disclosure achieves a uniform temperature control on the air flow passage of the dehumidifying element so as to improve regeneration performance of the dehumidifying element and reduce energy consumption of the drying device.
    Type: Grant
    Filed: March 30, 2015
    Date of Patent: October 11, 2016
    Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTE
    Inventors: Ming-Lang Hung, Pen-Chang Tseng, Yu-Hao Kang, Hsing-Ting Chen, Jyi-Ching Perng, Shih-Kai Chien, Ching-Eenn Tsai
  • Patent number: 9272265
    Abstract: In a NOx removal catalyst used for removing nitrogen oxides in flue gas, when a silica (Si) component as an inhibitor that causes an increase in a SO2 oxidation rate accumulates on a surface of the catalyst, the silica component accumulating on the surface of the catalyst is dissolved, thereby regenerating the catalyst. Accordingly, the inhibitor such as the silica component covering the surface of the NOx removal catalyst can be removed, thereby enabling to provide a catalyst without having an increase in the SO2 oxidation rate of the regenerated NOx removal catalyst.
    Type: Grant
    Filed: September 5, 2012
    Date of Patent: March 1, 2016
    Assignee: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Katsumi Nochi, Masashi Kiyosawa
  • Patent number: 9205417
    Abstract: Provided is a simple method for regenerating a zeolite membrane which has been exposed to water. The method for regenerating a zeolite membrane is a method for regenerating a zeolite membrane which is formed on a ceramic porous body and subjected to removal treatment of structure directing agent. Heating is performed at a regeneration temperature at which the difference in ratio of thermal expansion amount between the ceramic porous body and the zeolite membrane is 0.3% or less when 40° C. is set as datum. The regeneration temperature is preferably a temperature not exceeding the oxidative pyrolysis temperature of the structure directing agent used in the formation of the zeolite membrane.
    Type: Grant
    Filed: April 27, 2015
    Date of Patent: December 8, 2015
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Miyahara, Makiko Ichikawa, Shinji Nakamura, Ryujiro Nagasaka
  • Patent number: 9040653
    Abstract: This disclosure provides methods of controlled polymerization of cyclic compounds catalyzed by carbene derivatives having a general formula as shown below, and to obtain a biodegradable polymeric material having a large molecular weight, a narrow dispersity, and no metallic impurity.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: May 26, 2015
    Assignee: NANJING UNIVERSITY OF TECHNOLOGY
    Inventors: Zhenjiang Li, Pingkai Ouyang, He Huang
  • Patent number: 9029281
    Abstract: A regenerated spent hydroprocessing catalyst treated with a chelating agent and having incorporated therein a polar additive.
    Type: Grant
    Filed: August 11, 2011
    Date of Patent: May 12, 2015
    Assignee: Shell Oil Company
    Inventors: Alexei Grigorievich Gabrielov, Ed Ganja, Salvatore Philip Torrisi
  • Patent number: 8951928
    Abstract: A method for regenerating an adsorber or absorber on board a submarine, wherein the adsorber or absorber is present in the interior of the submarine for binding metabolically generated CO2-containing harmful gases, and wherein the metabolically generated CO2-containing harmful gases are transferred outboard via a compressor. The thermal energy for regenerating the adsorber or absorber is generated by burning a hydrocarbonaceous energy carrier with oxygen, wherein at least one combustion product, together with the metabolically generated CO2-containing harmful gases, is transferred outboard via the compressor.
    Type: Grant
    Filed: June 14, 2011
    Date of Patent: February 10, 2015
    Assignee: Astrium GmbH
    Inventors: Willigert Raatschen, Lutz Schauer, Helmut Westermann, Carsten Matthias
  • Publication number: 20150038321
    Abstract: A method for treating powdered activated carbon (PAC) and/or coal combustion residues (CCRs) by heating at least one of a spent PAC and/or a CCR to separate at least one heavy metal from the at least one of the spent PAC and/or the CCR to create a clean stream and a heavy metal stream, combining the heavy metal stream with a water soluble alkaline-earth metal sulfide to create a combined stream, and removing at least a portion of the at least one heavy metal from the combined stream. The heating may further include heating the at least one of the spent PAC and/or the CCR in an inert atmosphere. Further, the combining may include combining the heavy metal stream with the water soluble alkaline-earth metal sulfide and a catalyst and/or a surfactant or hyperdispersant.
    Type: Application
    Filed: March 14, 2013
    Publication date: February 5, 2015
    Applicant: MERCUTEK LLC
    Inventors: Peter D'Amico, Christopher Poling, Thomas Lesniak
  • Patent number: 8932454
    Abstract: This invention relates to the composition, method of making and use of a hydrocracking catalyst that is comprised of a new Y zeolite which exhibits an exceptionally low small mesoporous peak around the 40 ? (angstrom) range as determined by nitrogen adsorption measurements. The hydrocracking catalysts of invention exhibit improved distillate yield and selectivity as well as improved conversions at lower temperatures than conventional hydrocracking catalysts containing Y zeolites. The hydrocracking catalysts herein are particularly useful in the hydrocracking processes as disclosed herein, particularly for conversion of heavy hydrocarbon feedstocks such as gas oils and vacuum tower bottoms and an associated maximization and/or improved selectivity of the distillate yield obtained from such hydrocracking processes.
    Type: Grant
    Filed: December 19, 2012
    Date of Patent: January 13, 2015
    Assignee: ExxonMobile Research and Engineering Co.
    Inventors: Jianxin Jason Wu, Ajit B. Dandekar, Christopher G. Oliveri
  • Patent number: 8877668
    Abstract: The invention involves a process that reduces the potential for catalyst fluidization in a reduction vessel of a continuous catalyst regeneration system. The gas exit area from the catalyst reduction zone is increased by ventilating the cylindrical baffle of the upper reduction zone. This provides an increased exit cross-sectional area for the upper reduction gas to escape and reduce the overall exit velocity of the combined upper and lower reduction gases and reduces the potential for catalyst fluidization.
    Type: Grant
    Filed: June 6, 2012
    Date of Patent: November 4, 2014
    Assignee: UOP LLC
    Inventors: Ka L. Lok, Mary Jo Wier, Pengfei Chen, Alexander V. Sabitov
  • Patent number: 8877667
    Abstract: The invention relates to a process for regenerating catalysts containing mixed oxides from the group of alkali metal and/or alkaline earth metal oxides, aluminium oxide and silicon oxide, characterized in that the regeneration comprises the following features: i) treatment of the catalyst in situ, ii) contacting of the catalyst with water, iii) treatment of the catalyst within a temperature range from 100 to 400° C., iv) treatment of the catalyst within a pressure range from 0.1 to 2 MPa, v) treatment of the catalyst over a period of 0.1 to 24 h, vi) treatment of the catalyst with a specific catalyst hourly space velocity of 0.1 to 100 h?1.
    Type: Grant
    Filed: June 16, 2010
    Date of Patent: November 4, 2014
    Assignee: Evonik Degussa GmbH
    Inventors: Christian Boeing, Dirk Roettger, Reiner Bukohl, Markus Winterberg, Dietrich Maschmeyer
  • Patent number: 8871665
    Abstract: The method includes a pretreatment step during an operation of a boiler in which in a predetermined period of time before shutdown of the boiler, a part of combustion gas that has bypassed an economizer provided in a flue gas duct for flue gas from the boiler is supplied to an upstream of a NOx removal device having a NOx removal catalyst and mixed with the combustion flue gas from the economizer to generate mixed gas having a predetermined temperature equal to or higher than 360° C. (360° C. to 450° C.), the mixed gas is introduced into the NOx removal catalyst, thereby decomposing VOSO4 adhering to and accumulating on the NOx removal catalyst into V2O5.
    Type: Grant
    Filed: August 9, 2012
    Date of Patent: October 28, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsumi Nochi, Masashi Kiyosawa, Hideo Miyanishi
  • Patent number: 8865608
    Abstract: Systems and processes for regenerating catalyst are provided herein that include a catalyst regeneration tower having a cooling zone that receives a catalyst cooling stream generated by a cooling gas loop. The systems and processes include a first thermocompressor that utilizes a first motive vapor and a second thermocompressor that utilizes a second motive vapor in order to provide the catalyst cooling stream to the regeneration tower. The second thermocompressor operates in parallel with the first thermocompressor. The first thermocompressor can utilize combustion air as the motive vapor. The second thermocompressor can utilize nitrogen as the motive vapor.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: October 21, 2014
    Assignee: UOP LLC
    Inventors: Brian Nabozny, William D. Schlueter, Kate Tuson
  • Publication number: 20140274659
    Abstract: Adsorbed natural gas (ANG) technology is an energy efficient approach for storing NG at room temperature and low pressure. ANG technology can be applied to several aspects of the NG industry. The usage of an adsorbent material in natural gas storage and transport may provide increased storage density of NG at a given pressure and decreased pressure of gaseous fuel at a given gas density. Such adsorbent materials have been shown to store substantial quantities of natural gas at relatively modest pressures. Because lower-pressure vessels can be far less expensive than comparable sized high-pressure vessels, ANG based storage can be used to lower the cost of storing natural gas in various applications.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: OSCOMP SYSTEMS INC.
    Inventors: Jimmy ROMANOS, Pedro T. SANTOS, Scott RACKEY
  • Patent number: 8835340
    Abstract: A regenerated exhaust gas treatment catalyst (17) can be produced by coarsely grinding a used exhaust gas treatment catalyst (11); separating a coarsely ground material into coarse pieces (12) and a fine powder (13); finely grinding the coarse pieces (12); kneading the fine powder together with other raw materials, molding a kneaded material, and drying and burning a molded material to produce a base material (14); grinding a fresh exhaust gas treatment catalyst (15); forming a slurry solution of the ground product of the fresh exhaust gas treatment catalyst (15); coating the surface of the base material (14) with the slurry solution (16); and drying the base material (14) that has been coated with the slurry solution (16) and burning the base material (14) at a temperature higher than the burning temperature employed in the production of the exhaust gas treatment catalyst (15).
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: September 16, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Yoshiaki Obayashi, Masashi Kiyosawa, Masanori Demoto
  • Patent number: 8822364
    Abstract: An example method includes determining that a selective catalytic reduction (SCR) component having a zeolite-based catalyst is contaminated with platinum (Pt). The method further includes elevating the temperature of the SCR component to at least 600° C. in response to the determining the catalytic component is contaminated with Pt, and maintaining the elevated temperature of the catalytic component for a predetermined time period thereby restoring reduction activity of the catalyst.
    Type: Grant
    Filed: April 19, 2012
    Date of Patent: September 2, 2014
    Assignee: Cummins Inc.
    Inventors: Xu Chen, Krishna Kamasamudram, Neal W. Currier, Aleksey Yezerets
  • Patent number: 8785341
    Abstract: Provided is a method of regenerating an exhaust gas treatment catalyst 11 having ash adhered to a surface thereof. The method includes a crushing step S1 in which the exhaust gas treatment catalyst 11 is crushed such that 70 to 95 wt % of the whole exhaust gas treatment catalyst 11 becomes coarse pieces 12 having a size exceeding a threshold size S (any value in a range of 0.105 to 1.0 mm); a separating step S2 in which the fragments obtained by crushing the exhaust gas treatment catalyst 11 are separated into the coarse pieces 12 having a size exceeding threshold size S and fine particles 13 having a size not larger than the threshold size S; a pulverizing step S3 in which the coarse pieces 12 thus separated are pulverized to a fine powder having an average particle diameter of not larger than 0.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: July 22, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Yoshiaki Obayashi, Masashi Kiyosawa
  • Publication number: 20140194275
    Abstract: A method of reactivating a spent catalyst comprising a metal and a catalyst support, the method comprising redispersing the metal in the spent catalyst to produce a redispersed spent catalyst, contacting the redispersed spent catalyst with a reactivating composition to produce a redispersed, reactivated spent catalyst, and thermally treating the redispersed, reactivated spent catalyst to produce a reactivated catalyst.
    Type: Application
    Filed: January 20, 2014
    Publication date: July 10, 2014
    Applicant: Chevron Phillips Chemical Company LP
    Inventor: An-Hsiang Wu
  • Patent number: 8765622
    Abstract: A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. Filtering in the deoiling zone can comprise filtering the slurry and solvent through a cross-flow microfiltration unit, recovering a retentate stream of the cross-flow microfiltration unit, combining the retentate stream of the cross-flow microfiltration unit with solvent to form a combined retentate-solvent stream, and filtering the combined retentate-solvent stream through a cross-flow microfiltration unit.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: July 1, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Lalit S. Shah, Christopher A. Powers, James R. Stoy, Fred D. Brent, Bruce E. Reynolds, Andre R. Da Costa
  • Publication number: 20140162865
    Abstract: An engine oil including a base oil in a range of about 70 to 85 wt %. The engine oil includes at least one additive in a range of about 15 to 30 wt %, such as, an antioxidant, a cleaning agent/detergent, a dispersing agent, a wear resistant agent, a viscosity index improving agent, a pour point depressant, a rust/corrosion inhibiting agent, a foam inhibiting agent, and an extreme pressure agent. The engine oil further includes an additive including an organometallic compound of a catalyst consisting of a catalytic element in a range of about 0.001 to 0.05 wt %.
    Type: Application
    Filed: December 11, 2012
    Publication date: June 12, 2014
    Applicant: Caterpillar Inc.
    Inventors: Paul W. Park, Hind M. Abi-Akar
  • Patent number: 8722559
    Abstract: In a NOx removal catalyst used for removing nitrogen oxide in flue gas, when a silica (Si) component as an inhibitor that causes an increase in an SO2 oxidation rate accumulates on a surface of the NOx removal catalyst, the silica component accumulating on the surface of the NOx removal catalyst is dissolved, thereby regenerating the catalyst. Accordingly, the inhibitor such as the silica component covering the surface of the NOx removal catalyst can be removed, thereby enabling to provide a catalyst without having an increase in the SO2 oxidation rate of the regenerated NOx removal catalyst.
    Type: Grant
    Filed: July 23, 2012
    Date of Patent: May 13, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Katsumi Nochi, Masashi Kiyosawa
  • Patent number: 8722558
    Abstract: Provided is a process for producing a regenerated hydrotreating catalyst by regenerating a spent hydrotreating catalyst in a prescribed temperature range, wherein the prescribed temperature range is a temperature range of T1?30° C. or more and T2+30° C. or less, as determined by subjecting the spent hydrotreating catalyst to a differential thermal analysis, converting a differential heat in a measuring temperature range of 100° C. or more and 600° C. or less to a difference in electromotive force, differentiating the converted value twice by temperature to provide a smallest extreme value and a second smallest extreme value, and representing a temperature corresponding to the extreme value on the lower-temperature side as T1 and a temperature corresponding to the extreme value on the higher-temperature side as T2.
    Type: Grant
    Filed: June 18, 2010
    Date of Patent: May 13, 2014
    Assignee: JX Nippon Oil & Energy Corporation
    Inventors: Souichirou Konno, Yoshimu Iwanami, Wataru Sahara, Nobuharu Kimura
  • Patent number: 8722556
    Abstract: A method of recovering unsupported fine catalyst from heavy oil comprises combining a slurry comprising unsupported fine catalyst in heavy oil with solvent to form a combined slurry-solvent stream. The combined slurry-solvent stream is filtered in a deoiling zone. A stream comprising unsupported fine catalyst and solvent is recovered from the deoiling zone. Unsupported fine catalyst is separated from the stream comprising unsupported fine catalyst and solvent. The deoiling zone can comprise a membrane that is rapidly displaced in a horizontal direction.
    Type: Grant
    Filed: December 20, 2007
    Date of Patent: May 13, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Andre R. DaCosta, Paul Bryan
  • Patent number: 8716160
    Abstract: This invention relates to the field of Fischer-Tropsch catalysis, in particular to activation of a Fischer-Tropsch catalyst. More particularly the invention relates to a method of activating an iron based Fischer-Tropsch catalyst which includes iron in a positive oxidation state by contacting in a reactor said iron based catalyst with a reducing gas selected from the group consisting of CO and a combination of H2 and CO; at a temperature of at least 245° C. and below 280° C.; at a reducing gas pressure of above 0.5 MPa and not more than 2.2 MPa; and at a GHSV of total gas fed to the reactor of at least 6000 ml(N)/g cat/h, thereby reducing the iron that is in a positive oxidation step in the catalyst.
    Type: Grant
    Filed: August 5, 2008
    Date of Patent: May 6, 2014
    Assignee: Sasol Technology (PTY) Limited
    Inventors: Johannes Jacobus Huyser, Matthys Josephus Janse van Vuuren, Ryno Kotze