Having Nonchromogenic Liquid Spread-control Or Transfer-improving Agent Or Component, Color Modifier, Stabilizer Or Preservative Patents (Class 503/209)
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Patent number: 6645910Abstract: The present invention provides a thermally sensitive recording medium that possesses a thermally sensitive color developing layer containing colorless or pale colored basic leuco dye and an organic color developer as main components on a substrate, wherein said thermally sensitive recording medium contains at least one kind of an ultraviolet ray absorbent of aqueous emulsion type polymer composed of an emulsion copolymerized compound of (a) ultraviolet ray absorbing monomer, (b) vinyl compound monomer that can copolymerize with said monomer, (c) hydrophilic monomer and (d) reactive emulsifier.Type: GrantFiled: June 6, 2000Date of Patent: November 11, 2003Assignees: Nippon Paper Industries Co. Ltd., Ipposha Oil Industries Co. Ltd.Inventors: Reiko Sato, Kaoru Hamada, Yoshihide Kimura, Takaichi Yamamoto, Hiroyuki Kawabata, Seiji Sugimori
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Patent number: 6642175Abstract: A heat-sensitive recording material formed of a support having disposed thereon a heat-sensitive color-forming layer that includes an electron-donating leuco-dye and an electron-receiving compound, with the heat-sensitive color-forming layer including, N-(4-hydroxyphenyl)-p-toluenesulfonamide as the electron-donating leuco-dye. The heat-sensitive color-forming layer may include 2-benzyloxynaphthalene or a combination of 2-benzyloxynaphthalene and methylolstearic acid amide as a sensitizer, calcite-type precipitated calcium carbonate light and/or aluminium hydroxide as an inorganic pigment, polyvinyl alcohol having a degree of saponification of 85 to 99 mol % and a degree of polymerization of from 200 to 2000 as an adhesive, and 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane and/or 1,1,3-tris(2-methyl-4-hydroxy-5-cyclohexylphenyl)butane as an image stabilizer.Type: GrantFiled: October 3, 2001Date of Patent: November 4, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirofumi Mitsuo, Tsutomu Watanabe, Masayuki Iwasaki
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Publication number: 20030186808Abstract: The invention provides a thermal recording material, which includes at least one recording layer containing an electron donating dye precursor and an electron accepting compound, and additionally, the recording layer includes a polymerizable compound having an ethylenic unsaturated bond.Type: ApplicationFiled: December 18, 2002Publication date: October 2, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Shiki Ueki, Kazumori Minami
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Patent number: 6624117Abstract: A heat sensitive recording material, comprising a) at least one colour forming compound, and b) at least one developer of the formula wherein R1 is unsubstituted or substituted phenyl, naphthyl or C1-C20alkyl, X is a group of the formula A is unsubstituted or substituted phenylene, naphthylene or C1-C12alkylene, or is an unsubstituted or substituted heterocyclic group, B is a linking group of formula —O—SO2—, —SO2—O—, —NH—SO2—, —SO2—NH—, —S—SO2—, —O—CO—, —O—CO—NH—, —NH—CO—, —NH—CO—O—, —S—CO—NH—, —S—CS—NH—, —CO—NH—SO2—, —O—CO—NH—SO2—, —NH═CH—, —CO—NH—CO—, —S—, —CO—, —O—, —SO2—NH—CO—, —O&mType: GrantFiled: October 1, 2001Date of Patent: September 23, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Heneghan, Roy Alan Kirk, James Philip Taylor, John Whitworth, Robert Montgomery O'Neil, John Barry Henshall
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Patent number: 6613716Abstract: A coating composition is applied to a print stock substrate for preparing a thermally-active layer, the coating composition comprising: a developer comprising at least one or a combination of 6′-dipentylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 129473-78-5) and 6′-dibutylamino-3′-methyl-2′(phenylamino)-spiro [isobenzofuran-1(3H),9′-[9H]xanthen]-3-one (CAS No. 89331-94-2); a sensitizer comprising at least one or a combination of 1,1′-sulfonylbisbenzene (CAS No. 127-63-9) and dimethylterephthalate (CAS No. 120-61-6); and a coreactant (or developer) comprising at least one or a combination of bis(4-hydroxyphenyl)-4-methylpentane (CAS No. 6807-17-6) and 4-hydroxy-4′-isopropoxydiphenylsulfone (CAS No. 95235-30-6). Preferably, the print stock substrate will be coated with clay or the like to provide a smooth coating surface for the thermally-active layer.Type: GrantFiled: March 28, 2001Date of Patent: September 2, 2003Assignee: Miami Wabash Paper LLCInventors: Eugene V. Hoefs, Regina A. Kleinhenz
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Patent number: 6607871Abstract: An image recording medium comprising a light and heat change material capable of recording an image with laser beam is described, characterized in that therein are incorporated a heat generator having no absorption at a wavelength of 500 nm or more which undergoes exothermic decomposition to amplify heat generation when acted upon by heat and a compound which undergoes thermochemical reaction to show an absorption change at a wavelength of from 360 nm to 900 nm.Type: GrantFiled: September 21, 2000Date of Patent: August 19, 2003Assignee: Fuji Photo Film Co., Ltd.Inventors: Tatsuhiko Obayashi, Atsuhiro Ookawa
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Publication number: 20030134746Abstract: A heat-sensitive recording material in which a heat-sensitive color-developing layer containing at least an electron-donating colorless dye, an electron-accepting compound, a sensitizer and preferably an image stabilizer is disposed on a support, the heat-sensitive color-developing layer containing (1) 4-hydroxybenzenesulfonanilide as the electron-accepting compound and (2) 2-benzyloxynaphthalene and ethylenebisstearic acid amide or methylolstearic acid amide as the sensitizer, and (3) the 2-benzyloxynaphthalene (x) to ethylenebisstearic acid amide or methylolstearic acid amide (y) mass ratio (x/y) being within 95/5 to 40/60 range.Type: ApplicationFiled: July 2, 2002Publication date: July 17, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Masayuki Iwasaki, Tsutomu Watanabe, Hirofumi Mitsuo
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Patent number: 6593272Abstract: A thermosensitive recording composition includes a leuco dye, a color developer containing 4,4′-bisphenol S, and a sensitizer containing 4-acetylbiphenyl. A thermosensitive recording material has a support and a thermosensitive recording layer which is provided on the support and contains the above-mentioned thermosensitive recording composition.Type: GrantFiled: December 1, 2000Date of Patent: July 15, 2003Assignee: Ricoh Company, Ltd.Inventors: Tomohisa Kakuda, Takeshi Kajikawa, Hiroshi Yamada
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Patent number: 6586363Abstract: A substantially light-insensitive black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, an organic reducing agent therefor in thermal working relationship therewith, an image tone stabilizer and a binder, wherein the image tone stabilizer is a compound according to formula (I): wherein R1 is hydrogen, an alkali metal ion, an ammonium ion, a phosphonium ion, a sulphonium ion, an alkaline earth ion or an optionally substituted alkyl, cycloalkyl, heterocyclic, alkaryl, aralkyl, heteroaryl or aryl group; R2 is an optionally substituted alkyl, cycloalkyl, heterocyclic, alkaryl, aralkyl, heteroaryl or aryl group; or R1 and R2 together represent the atoms necessary to form a ring structure; and X is hydrogen, an alkali metal ion, an ammonium ion, a phosphonium ion, a sulphonium ion or an alkaline earth ion; and a recording process therefor.Type: GrantFiled: November 27, 2001Date of Patent: July 1, 2003Assignee: AGFA-GevaertInventors: Johan Loccufier, Ivan Hoogmartens
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Patent number: 6583086Abstract: A thermally sensitive recording medium that contains a compound represented by general formula (1) as a color developer, and a compound represented by general formula (2) or general formula (3) as a sensitizer. The said thermally sensitive recording medium has sufficient color developing sensitivity with lower impressive energy, and has good image preservability of recorded part, good resistance to humid and heat resistance of background white paper part. In the formulae, R1 represents a hydrogen atom, a methyl group or a chlorine atom, R2 and R3 represents a methyl group, an alkoxy group or an allyloxy group, m and n represents an integer of 1-5, R4 represents an alkyl group, an alkoxy group of carbon number 1-6 or an electron withdrawing group and o represents an integer of 0-2.Type: GrantFiled: June 9, 2000Date of Patent: June 24, 2003Assignee: Nippon Paper Industries Co. Ltd.Inventors: Seiki Yoneshige, Tomoyuki Nakano, Reiji Ohashi
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Publication number: 20030114306Abstract: A heat-sensitive recording material includes a support having disposed thereon a heat-sensitive recording layer and a protective layer. The heat-sensitive recording layer contains at least two components that react to develop color by imagewise heating. At least one layer contains a compound represented by the following general formula (I). In the general formula (I), R represents a hydrophobic group or a hydrophobic polymer, and n represents an integer.Type: ApplicationFiled: September 16, 2002Publication date: June 19, 2003Applicant: FUJI PHOTO FILM CO., LTD.Inventor: Toshiaki Aono
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Patent number: 6579826Abstract: A reversible thermosensitive recording medium including a substrate; a reversible thermosensitive recording layer on the substrate, which includes an electron donating coloring compound and an electron accepting compound, wherein the recording layer achieves a colored state when heated at a temperature not lower than an image forming temperature and then cooled at a first cooling speed, and the recording layer in the colored state achieves a non-colored state when heated at a temperature lower than the image forming temperature and not lower than an image erasing temperature or when heated at a temperature not lower than the image forming temperature and then cooled at a second cooling speed relatively slow compared to the first cooling speed; and a crosslinked polymer layer including a crosslinked polymer having an ultraviolet absorbing structure.Type: GrantFiled: October 10, 2001Date of Patent: June 17, 2003Assignee: Ricoh Company LimitedInventors: Hiromi Furuya, Tadafumi Tatewaki, Satoshi Arai, Takeshi Shibuya, Kyoji Tsutsui
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Patent number: 6566301Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula wherein P is selected from wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, and alkoxyalkoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen.Type: GrantFiled: December 19, 2000Date of Patent: May 20, 2003Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, John Charles DeBraal, Mark Robert Fisher, Stacey Ann Justa MacNeil, Debra Arlene Berggren
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Publication number: 20030087757Abstract: An image-recording composition comprising: a microcapsule enclosing a leuco-dye; a phenol color-developing agent; and a reaction-accelerating agent catalyzing a color-developing reaction between the leuco-dye and the phenol color-developing agent, the reaction-accelerating agent being an organic compound having at least two carboxyl groups. An image-recording sheet comprising a substrate and a color-developing layer disposed by applying the image-recording composition to the substrate is also provided.Type: ApplicationFiled: May 17, 2001Publication date: May 8, 2003Applicant: ASAHI KOGAKU KOGYO KABUSHIKI KAISHAInventors: Yukio Kubota, Minoru Suzuki, Kazuyuki Shimbo
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Patent number: 6559097Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, alkoxyalkoxy, and aralkoxyalkoxy; with the proviso that when R1, R2 and R3 are hydrogen, that R4 is not benzyloxyethoxy or alkyl-substituted benzyloxyethoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen.Type: GrantFiled: September 10, 2001Date of Patent: May 6, 2003Assignee: Appleton Papers Inc.Inventors: Ponnampalam Mathiaparanam, Mark Robert Fisher, John Charles DeBraal
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Publication number: 20030060366Abstract: There is provided a leuco dye dispersion liquid for a thermosensitive recording material wherein the leuco dye is being dispersed with an anionic surfactant and an nonionic surfactant, while average particle diameter of the leuco dye ranges from 0.10 &mgr;m to 0.30 &mgr;m and content of particles less than or equal to 0.07 &mgr;m in diameter of the dye is not greater than 1.0%. The leuco dye dispersion liquid shows no fogging, and can cause a high optical density of image on thermosensitive member with excellent brightness in background area, and a high durability for storage at elevated temperature.Type: ApplicationFiled: March 22, 2002Publication date: March 27, 2003Applicant: Ricoh Company, Ltd.Inventors: Yoshikazu Kaneko, Yasutomo Mori, Kunio Hayakawa, Mitsunobu Morita, Takeshi Kajikawa, Shuuji Miyamoto, Yuuichi kawaguchi
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Publication number: 20030050190Abstract: An image forming material for forming an image on an image recording material with an image binding force being established between the image and the image recording material, the image forming material containing an image forming substance, and a binding force reducing substance which reduces the image binding force when the image is heated. A method of removing an image formed on an image recording material with a binding force being established between the image and the recording material by contacting a stripping member with the image with heating under pressure. A binding force reducing substance may be contained in the surface of the stripping member or in the image recording material.Type: ApplicationFiled: July 31, 2002Publication date: March 13, 2003Inventors: Hidehiro Mochizuki, Tadashi Saitou
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Publication number: 20030032557Abstract: Disclosed herein is an imaging medium comprising a substrate carrying a color-change layer which develops color upon heating. The addition of a novel block copolymer surfactant containing ethylene oxide (EO) and propylene oxide (PO) into the leuco dye dispersion prevents color pre-formation during the dispersion preparation stage, and in the final coating fluid in the presence of developers and acids. The pluronic may complex the acid developer as well as the final image dye.Type: ApplicationFiled: October 3, 2001Publication date: February 13, 2003Inventors: Jayprakash C. Bhatt, Daoshen Bi, Kuang-Chou Chang, Feng Y. Dai, Lloyd Taylor
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Patent number: 6515051Abstract: Benzotriazole UV absorbers which are substituted at the 5-position of the benzo ring by an electron withdrawing group exhibit enhanced durability and very low loss rates when incorporated into automotive coatings. This is particularly the case when the 3-position of the phenyl ring is also substituted by phenyl or phenylalkyl such as &agr;-cumyl. Compounds where the 5-position of the benzo ring are substituted by perfluoroalkyl such as trifluoromethyl are particularly of interest for both their enhanced durability and for their excellent solubility and excellent color properties in some thermoplastic compositions when the phenyl ring is substituted at the 3-position by hydrogen or tert-alkyl.Type: GrantFiled: December 18, 2001Date of Patent: February 4, 2003Assignee: Ciba Specialty Chemicals CorporationInventors: Ramanathan Ravichandran, Joseph Suhadolnik, Mervin G. Wood, Anthony Debellis, Robert E. Detlefsen, Revathi Iyengar, Jean-Pierre Wolf
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Patent number: 6494950Abstract: Disclosed is a thermochromic microencapsulated pigment which comprises as four essential components (a) an electron-donating chromatic organic compound, (b) an electron-accepting compound, (c) a reaction medium determining the temperatures at which the color reactions of component (a) with component (b) take place, and (d) a color change temperature regulator, the color change temperature regulator (d) comprising one or more compounds selected from the group consisting of esters, alcohols, ketones, acid amides, hydrocarbons, and fatty acids and having a melting point Y (° C.) satisfying the relationship (X+30)° C.≦Y≦200° C., wherein X (° C.) is the melting point of component (c), and the four essential components being microencapsulated.Type: GrantFiled: September 18, 2000Date of Patent: December 17, 2002Assignee: The Pilot Ink Co., Ltd.Inventors: Katsuyuki Fujita, Kuniyuki Senga
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Patent number: 6440897Abstract: The present invention is a thermally sensitive recording medium which has excellent anti ultra violet ray property, mainly composed of an electron donating compound and an electron accepting compound, containing at least one of benzoxadinone compound represented by general formula (1) as an ultra violet ray absorbing agent. In the above mentioned formula, R represents hydrogen atom, hydroxyl group, alkyl group of carbon number 1-8, alkoxy group of carbon number 1-6, acyl group of carbon number 1-6, acyloxy group of carbon number 1-6, alkoxy carbonyl group of carbon number 1-6, carboxyl group, halogen atom or nitro group and X represents a divalent group or a direct bond.Type: GrantFiled: October 15, 1999Date of Patent: August 27, 2002Assignee: Nippon Paper Industries Co LtdInventors: Yukiko Ryu, Takashi Date, Reiji Ohashi
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Patent number: 6432875Abstract: A thermal recording material includes a condensation reaction product of a carboxylic acid component (A) with a polyhydric alcohol component (B) in a thermal recording layer as an essential component, wherein the carboxylic acid component (A) includes (poly) 4-hydroxybenzoic acid represented by the following general formula (I) as an essential component and another monocarboxylic acid and/or dicarboxylic acid as an arbitrary component, and wherein the polyhydric alcohol component (B) includes a polyhydric alcohol which is a trihydric or more alcohol as an essential component and a dihydric low molecular-weight alcohol as an arbitrary component. wherein in the general formula(I), a letter p denotes an integer ranging from 0 to 2.Type: GrantFiled: December 1, 1999Date of Patent: August 13, 2002Assignee: Asahi Denka Kogyo K.K.Inventors: Mitsuo Akutsu, Nobuhide Tominaga, Keiji Ohya, Koichi Shigeno, Takahiro Mori
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Patent number: 6407036Abstract: A thermal recording sheet which is satisfactory in sensitivity in color development, background heat resistance, and background color, is free from powdering, and has excellent image retention. The sheet comprises supporting and formed thereon a thermal color development layer containing as main components a colorless or light-colored basic dye and an organic color developer, and is characterized in that the thermal color development layer contains at least one dihydroxydiphenyl sulfone compound represented by general formula (1) as the organic color developer, and further contains either at least one saturated fatty acid monoamide represented by general formula (2) in an amount of 1.5 to 5 parts per part of the organic color developer or a combination of at least one saturated fatty acid monoamide represented by general formula (2) and at least one diphenyl sulfone derivative represented by the general formula (3).Type: GrantFiled: October 31, 2000Date of Patent: June 18, 2002Assignee: Nippon Paper Industries Co. LtdInventors: Yoshimi Midorikawa, Naomi Sumikawa, Yuji Tsuzuki, Tomoniri Sekine, Kaoru Hamada, Yoshihide Kimura
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Publication number: 20020065195Abstract: A heat-sensitive recording material formed of a support having disposed thereon a heat-sensitive color-forming layer that includes an electron-donating leuco-dye and an electron-receiving compound, with the heat-sensitive color-forming layer including, N-(4-hydroxyphenyl)-p-toluenesulfonamide as the electron-donating leuco-dye. The heat-sensitive color-forming layer may include 2-benzyloxynaphthalene or a combination of 2-benzyloxynaphthalene and methylolstearic acid amide as a sensitizer, calcite-type precipitated calcium carbonate light and/or aluminium hydroxide as an inorganic pigment, polyvinyl alcohol having a degree of saponification of 85 to 99 mol % and a degree of polymerization of from 200 to 2000 as an adhesive, and 1,1,3-tris(2-methyl-4-hydroxy-5-tert-butylphenyl)butane and/or 1,1,3-tris(2-methyl-4-hydroxy-5-cyclohexylphenyl)butane as an image stabilizer.Type: ApplicationFiled: October 3, 2001Publication date: May 30, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hirofumi Mitsuo, Tsutomu Watanabe, Masayuki Iwasaki
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Publication number: 20020065194Abstract: An object of the present invention is to provide a heat sensitive recording material which can develop color at high density by the inclusion of a novel guanidine compound which is strongly basic and superior in diffusion resistance.Type: ApplicationFiled: July 19, 2001Publication date: May 30, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Naoto Yanagihara, Hisao Yamada, Mitsuyuki Tsurumi
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Publication number: 20020061818Abstract: A heat-sensitive recording material comprising a substrate and a heat-sensitive coloring layer containing a colorless electron-donating dye, an electron-accepting compound including at least 4,4′-dihydroxydiphenylsulfone, and a sensitizer comprising 2-benzyloxynaphthalene and aliphatic monoamide in the mass ratio in a range of 30/70 to 70/30.Type: ApplicationFiled: September 12, 2001Publication date: May 23, 2002Applicant: FUJI PHOTO FILM CO., LTD.Inventors: Hirofumi Mitsuo, Masayuki Iwasaki
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Patent number: 6391440Abstract: A recording medium comprises one or more of the compounds represented by General Formula (1) and/or General Formula (2): wherein R is any of a hydrogen atom, a substituted or unsubstituted alkokyl group, a substituted or unsubstituted alkyl group, and a substituted or unsubstituted aryl group; wherein R1 is an alkyl group of 1 to 20 carbons, and R2, R3, R4, and R5 are respectively independently an alkyl group of 1 to 3 carbons.Type: GrantFiled: February 22, 2000Date of Patent: May 21, 2002Assignee: Canon Kabushiki KaishaInventors: Hitoshi Yoshino, Kenji Shinjo
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Publication number: 20020049138Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula 1Type: ApplicationFiled: September 10, 2001Publication date: April 25, 2002Inventors: Ponnampalam Mathiaparanam, Mark Robert Fisher, John Charles DeBraal
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Publication number: 20020045548Abstract: A heat-sensitive recording sheet comprises an electron donative leuco dye, an acidic developer for developing the dye, and a sensitizer. The acidic developer has a main component of a phenolic compound that contains a sulfonyl group in a molecule. The sensitizer comprises an amide compound, N-(4-tolyl) -phenylacetic amide. An amide compound to be mixed with the N-(4-tolyl)-phenylacetic amide for use in the sensitizer is at least one compound selected from the group consisting of N -cyclohexylphenylacetic amide, N-phenylphenylacetic amide, N-(2-tolyl)phenylacetic amide, N-phenylphenoxyacetic amide, N-(4-tolyl)phenoxyacetic amide, N-phenyl-(4-tolyloxy)acetic amide and N-(4-tolyl)-(4-tolyloxy)acetic amide.Type: ApplicationFiled: May 3, 2001Publication date: April 18, 2002Inventor: Toranosuke Saito
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Patent number: 6348432Abstract: Disclosed are heat sensitive coatings and record materials that are environmentally resistant and therefore do not require a protective coating. One embodiment includes an environmentally resistant heat sensitive coating that includes an acrylate polymer of the formula: wherein R1 is a hydrogen or a methyl group, R2 is a hydrogen or a methyl group, and R3 is nitrile or chlorine or wherein, when c is 0, R4 is methyl, phenyl, or substituted phenyl, and when c is greater than 0, R4 is methyl, phenyl, substituted phenyl, halogen, nitrile or hydroxyl; m is greater than 1; n is greater than 1; b is greater than or equal to 0; and c is an integer from 0 to 38.Type: GrantFiled: March 10, 2000Date of Patent: February 19, 2002Assignee: Nashua CorporationInventor: Mohamed Elmasry
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Publication number: 20020006868Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula 1Type: ApplicationFiled: December 19, 2000Publication date: January 17, 2002Inventors: Ponnampalam Mathiaparanam, John Charles DeBraal, Mark Robert Fisher, Stacey Ann Justa MacNeil, Debra Arlene Berggren
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Patent number: 6337303Abstract: A substantially light-insensitive black and white thermographic recording material comprising a thermosensitive element and a support, the thermosensitive element containing at least one substantially light-insensitive organic silver salt, at least one organic reducing agent therefor in thermal working relationship therewith, a binder, at least one stabilizer and optionally an &agr;,(&ohgr;-alkyldicarboxylic acid with a straight chain alkyl group having at least 4 carbon atoms which may be substituted, however neither including 3,5-dihydroxybenzoic acid as acidic reagent nor di-tert-butyl-p-cresol as a sole organic reducing agent, wherein the at least one stabilizer is represented by formula (I): R1—(O═C)—R2—(C═O)—R3 (I) wherein R2 is a divalent straight chain saturated hydrocarbon group with 2 or 3 carbon atoms which may be substituted with one or more of ═O, ═S, ═CR4R5, an alkyl group, a cycloalkyl group, a hydroxy group, a thiol group, a —Type: GrantFiled: May 31, 2000Date of Patent: January 8, 2002Assignee: Agfa-GevaertInventors: Philip Dooms, Peter Michiels, Ingrid Geuens
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Patent number: 6326331Abstract: A substantially light-insensitive black and white non-chlorine-containing stabilizer-containing monosheet thermographic recording material comprising a support and a thermosensitive element, the thermosensitive element containing a substantially light-insensitive organic silver salt, a reducing agent therefor in thermal working relationship therewith and a binder, characterized in that the non-chlorine-containing stabilizer is selected from the group consisting of 2-(2′-hydroxyphenyl)benzotriazole derivatives and 2-hydroxy-benzophenone derivatives; a thermographic recording process therefor; and the use thereof as a stabilizer against direct sunlight.Type: GrantFiled: November 30, 1999Date of Patent: December 4, 2001Assignee: Agfa-GevaertInventors: Bartholomeus Cyriel Horsten, Guy Denis Jansen
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Patent number: 6303540Abstract: A thermally sensitive recording medium which has thermally sensitive recording layer containing colorless or pale colored basic leuco dye and organic color developer as main components on a substrate, wherein said thermally sensitive recording layer contains diphenylsulfone bridgeable type compound represented by general formula (1) and at least one compound represented by general formula (1). In general formula (2), X and Y can be different and indicates a saturated or an unsaturated liner or grafted hydrocarbon group of carbon number 1-12 which can possess ether bond, or indicates wherein R indicates a methylene group or an ethylene group, T indicates a hydrogen atom or an alkyl group of carbon number 1-4, and R1-R6 independently indicate a halogen atom, an alkyl group of carbon number 1-6, or an alkenyl group, further, m, n, p, q, r, t indicate an integer number of 0-4 and when are bigger than 2, R1-R6 can be different, and a is an integer of 0-10.Type: GrantFiled: November 1, 1999Date of Patent: October 16, 2001Assignee: Nippon Paper Industries Co LtdInventors: Tadakazu Fukuchi, Kaoru Hamada, Yuji Tsuzuki, Yoshihide Kimura, Tomoaki Nagai, Yutaka Wakita
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Patent number: 6294502Abstract: The invention discloses a novel thermally-responsive record material comprising a support having coated thereon a thermally sensitive color forming composition comprising a chromogenic material, an acidic developer material and a certain carbamate component that does not include dodecyl-N-phenylcarbamate. The novel record material displays enhanced image intensity or improved thermal response.Type: GrantFiled: May 14, 1999Date of Patent: September 25, 2001Assignee: Bayer AktiengesellschaftInventors: Mark Robert Fisher, John Charles DeBraal, Guido Steffan, Peter P. Wenzl
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Patent number: 6261992Abstract: A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording layer further includes an erasure promoter including one or more secondary amide group having the following formulas (1), (2) or (3): wherein each of R1, R2, R3, R4 and R5 independently represents a hydrocarbon group which is optionally substituted and which may be saturated or unsaturated, and wherein R1 and R2 are optionally combined to form a ring which may include one or more of a nitrogen atom, an oxygen atom and a sulfur atom. Alternatively, the erasure promoter may include two or more secondary amide groups having formula (1), (2) or (3).Type: GrantFiled: September 24, 1999Date of Patent: July 17, 2001Assignee: Ricoh Company, Ltd.Inventors: Hiromi Furuya, Masaru Shimada, Tadafumi Tatewaki, Masafumi Torii, Fumio Kawamura, Hiroaki Matsui
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Publication number: 20010003729Abstract: A thermosensitive recording composition includes a leuco dye, a color developer containing 4,4′-bisphenol S, and a sensitizer containing 4-acetylbiphenyl. A thermosensitive recording material has a support and a thermosensitive recording layer which is provided on the support and contains the above-mentioned thermosensitive recording composition.Type: ApplicationFiled: December 1, 2000Publication date: June 14, 2001Inventors: Tomohisa Kakuda, Takeshi Kajikawa, Hiroshi Yamada
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Patent number: 6232266Abstract: There is disclosed a heat-sensitive recording material having a support and provided thereon a heat-sensitive recording layer mainly comprising a heat-sensitive recording component which forms a color by heating, the improvement wherein the heat-sensitive recording component comprises two or more kinds of compounds, and at least one of the compounds constituting the heat-sensitive recording component is contained in the heat-sensitive recording layer in the state of a particle on the surface of which is formed a color-formation controlling layer obtained by polymerizing a compound having an unsaturated carbon bond.Type: GrantFiled: November 25, 1998Date of Patent: May 15, 2001Assignee: Mitsubishi Paper Mills LimitedInventors: Takao Masuda, Yasuro Yokota
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Patent number: 6207613Abstract: A reversible thermosensitive coloring composition including an electron donating coloring agent and an electron accepting color developer, wherein the composition achieves a colored state when heated at a temperature not lower than a coloring temperature and then cooled at a cooling speed (a), and the composition in the colored state achieves a non-colored state when heated at a temperature lower than the coloring temperature and not lower than an erasing temperature, or when heated at a temperature not lower than the coloring temperature and then cooled relatively slowly compared to the cooling speed (a), and wherein the electron accepting color developer includes a phenolic compound having the following formula (1): wherein n is an integer of from 1 to 3; m is an integer of from 1 to 20; r is 0 or an integer of from 1 to 3; X and Y independently represent a divalent group including a hetero atom; R1 represents a hydrocarbon group having from 1 to 20 carbon atoms; and R2 represents a hydrocType: GrantFiled: February 16, 1999Date of Patent: March 27, 2001Assignee: Ricoh Company, Ltd.Inventors: Masafumi Torii, Hiroaki Matsui, Masaru Shimada
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Patent number: 6197724Abstract: A heat-sensitive recording material in which dispersion stability of a color-developing compound or a film improving compound contained in the heat-sensitive recording material can be improved, and images which have uniform image quality and which are excellent in transparency, glossiness, and light-fastness can be formed with high color-developing sensitivity. There is provided a heat-sensitive recording material comprising a support, a heat-sensitive recording layer which is provided on the support and contains at least two types of compounds which react with each other so as to develop color by heating imagewise, and a protective layer in this order, wherein at least one of the layers contains the compound represented by the following formula (I).Type: GrantFiled: February 19, 1999Date of Patent: March 6, 2001Assignee: Fuji Photo Film Co., Ltd.Inventor: Toshiaki Aono
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Patent number: 6174836Abstract: A reversible thermosensitive recording medium includes a reversible thermosensitive recording layer including a matrix resin and an organic low-molecular-weight material dispersed in the matrix resin, of which transparency is reversibly changeable depending upon the temperature thereof, and having (1) a transparentizing upper-limit temperature of 125° C. or more, (2) a temperature difference of 20° C. or less between said transparentizing upper-limit temperature and an opaqueness initiation lower-limit temperature, and (3) a transparentizing initiation temperature of less than 95° C., and a method of recording and erasing images, using the recording medium, a method of producing the recording medium, and the application thereof a card, a label, writable or rewritable disk cartridge, disk and tape cassette are proposed.Type: GrantFiled: July 17, 1998Date of Patent: January 16, 2001Assignees: Ricoh Company Ltd., Miyoshi Yushi Kabushiki KaishaInventors: Yoshihiko Hotta, Kunichika Moroboshi, Masafumi Torii, Kunitoshi Sugiyama, Hideyuki Kobori, Katsushi Sugiyama, Katsuaki Kokubo, Koji Kawai, Kazuo Hosoda, Masafumi Moriya
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Patent number: 6090748Abstract: A reversible thermosensitive recording material which includes a recording layer including an electron donating coloring agent and an electron accepting coloring developer and in which an image is reversibly formed and erased by appropriately heating and cooling the recording layer, wherein the recording material has an image density retention not less than about 60% when the recording material having an image is allowed to settle in a dry place at 50.degree. C. for 24 hours, a residual image density not greater than about 0.03 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image, and a residual image density after light irradiation not greater than about 0.04 when the recording material having an image is heated at 110.degree. C. for 0.5 seconds to erase the image after light of 5,000 lux is irradiated to the recording material for 100 hours.Type: GrantFiled: June 25, 1998Date of Patent: July 18, 2000Assignee: Ricoh Company, Ltd.Inventors: Hiromi Furuya, Tadafumi Tatewaki, Masafumi Torii, Fumio Kawamura, Hiroaki Matsui, Masaru Shimada, Kyoji Tsutsui
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Patent number: 6028030Abstract: A thermal sensitive recording medium which further contains poly urea compound in the thermal color developing layer containing dye precursor and color developer, which displays an excellent image preservative stability. Said poly urea compound contains units of a structure represented by general formula (1), and further contains a repeating unit represented by general formulae (2).about.(7). ##STR1## In these formulae A.sup.1 .about.A.sup.7 are a divalent group, R.sup.1 .about.R.sup.5 are an alkyl group, an alkoxy group or an electron accepting group, o, p, and q are an integer from 0 to 4, r is an integer from 2 to 12 and s and t are an integer from 0 to 8.Type: GrantFiled: March 4, 1998Date of Patent: February 22, 2000Assignee: Nippon Paper Industrie Co., Ltd.Inventors: Tomoyuki Nakano, Koichi Yanai, Junko Seki, Reiji Ohashi, Hidetoshi Yoshioka
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Patent number: 6017983Abstract: An indicator for complete polymerization and cure of base-catalyzed epoxy thermoset resin systems is disclosed. In particular, the present invention makes use of an diazo dye having amino groups which forms a salt or complex with hardeners used in various epoxy resin systems. Upon full polymerization and consumption of the hardener, a chromophoric shift of the dye can be observed.Type: GrantFiled: January 29, 1998Date of Patent: January 25, 2000Assignee: Alpha Metals, Inc.Inventor: Ken Gilleo
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Patent number: 6015771Abstract: The present invention discloses a novel thermally-responsive record material having coated thereon a thermally sensitive color forming composition comprising a chromogenic material, an acidic developer material and a carbamate of the formula ##STR1## wherein R is selected from alkyl, aryl or aralkyl. The alkyl moiety in each of the preceding is selected to be of from one to eight carbons. The novel record material displays enhanced image intensity or improved thermal response.Type: GrantFiled: May 22, 1998Date of Patent: January 18, 2000Assignee: Bayer AktiengesellschaftInventors: Mark Robert Fisher, John Charles DeBraal, Guido Steffan, Peter P. Wenzl
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Patent number: 5994262Abstract: A sheet set for temperature control comprises: a recording sheet that is provided on one surface of a substrate and has a recording layer incorporating a zinc salt of a salicylic acid derivative as a color acceptor, or a leuco dye; and an adhesive sheet that is provided on one surface of another substrate and has a first adhesive layer incorporating an adhesive, an ester derivative of the formula (1) or (2), and a leuco dye, or a zinc salt of a salicylic acid derivative as a color acceptor.Type: GrantFiled: June 12, 1998Date of Patent: November 30, 1999Assignee: OJI Paper Co., Ltd.Inventors: Takeshi Iida, Tetsuo Tsuchida
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Patent number: 5985791Abstract: A thermosensitive recording medium has a support, and thermosensitive recording layer formed thereon containing an electron-donating coloring compound, an electron-accepting compound, a binder resin, a liquid resin which is in a liquid state at room temperature, and a plasticizer.Type: GrantFiled: June 2, 1998Date of Patent: November 16, 1999Assignee: Ricoh Company, LtdInventor: Shinji Okada
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Patent number: 5972837Abstract: A reversible thermal-recording composite capable of exerting great performance for repeated use and yielding good printing quality at higher coloring concentrations is provided, wherein the coloring and fading reaction of a leuco dye with a coloring and fading agent is utilized and a specific coloring and fading agent, a specific inorganic filler and a specific amine compound and the like are used in the thermal-recording layer, and a thermal-recording sheet and a thermal-recording card using the same are also provided.Type: GrantFiled: September 30, 1997Date of Patent: October 26, 1999Assignee: Sliontec CorporationInventors: Shoko Satoh, Kazuyoshi Yatsushige, Soichi Hasegawa, Kazuo Nate
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Patent number: 5955398Abstract: An improved thermally-responsive record material useful for bar coding is disclosed comprising a support having provided thereon in substantially contiguous relationship: a substantially colorless dye precursor comprising 2-anilino-3-methyl-6-dibutylaminofluoran; a sensitizer selected from the group consisting of 1,2-diphenoxyethane and 1,2-(4-methylphenoxy)ethane; an acidic developer material comprising bis-(3-allyl-4-hydroxyphenyl)sulfone which upon being heated reacts with said dye precursor to develop color; and a binder material. The improved thermally-responsive record material and bar code of the invention has a high print contrast signal; high dimensional stability in terms of low bar width growth degradation; a high percentage of successful decodes; and high contrast of the bar code with the background. The invention overcomes difficulties in past efforts to bring together a confluence of these characteristics in one coating formulation.Type: GrantFiled: April 25, 1997Date of Patent: September 21, 1999Assignee: Appleton Papers Inc.Inventors: Mark Robert Fisher, John Charles DeBraal, Joseph Peter Gusse
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Patent number: RE36321Abstract: In a heat-sensitive recording material incorporating a colorless or pale-colored basic dye and a color acceptor which is reactive with the basic dye to form a color when contacted therewith, the recording material characterized in that at least one compound represented by the formula ?I! is contained in a heat-sensitive recording layer ##STR1## wherein X is --O-- or --COO--, R.sub.1 to R.sub.4 are each hydrogen atom, alkyl having 1 to 8 carbon atoms, aryl having 6 to 10 carbon atoms, aralkyl having 7 to 9 carbon atoms, chlorine atom, acetyl, propionyl, methoxy, methylthio, methoxycarbonyl, cyano, nitro or cyclohexenyl, substituents R.sub.1 and/or R.sub.2 or substituents R.sub.3 and R.sub.4 may link together to form aromatic ring(s), n is an integer of 1 to 10.Type: GrantFiled: June 20, 1988Date of Patent: September 28, 1999Assignees: Kansaki Paper Manufacturing Co., Ltd., Sanko Kaihatsu Kagaku Kekyusho CorporationInventors: Toshitake Suzuki, Naoto Arai, Shoji Aoyagi, Toranosuke Saito, Masakatu Kitani, Takashi Ishibashi