And Identified Inorganic Electron Acceptor (developer), Other Than Mere Clay Patents (Class 503/219)
  • Patent number: 8888906
    Abstract: A heat-sensitive color-developing composition containing a hydroxyquinoline compound having a methyl group and an acid anhydride compound represented by general formula (1): wherein ring A represents a substituted or unsubstituted aromatic hydrocarbon ring, and n represents an integer of 1 to 3, and a heat-sensitive recording material containing the composition in a recording layer.
    Type: Grant
    Filed: September 13, 2011
    Date of Patent: November 18, 2014
    Assignee: Yamamoto Chemicals, Inc.
    Inventors: Ryoji Yamaguchi, Toshihiro Masaoka, Keisuke Takuma
  • Patent number: 8859460
    Abstract: A heat-sensitive recording material includes at least a paper substrate, a heat-sensitive recording layer arranged on the front side of the substrate and which has at least one dye precursor and at least one color acceptor, wherein dye precursor and color acceptor react with one another under the action of heat to form color, and an authenticating security feature. The authenticating security feature is a mark which is applied to the back side of the paper substrate and which is made of a tincture having at least one organic solvent. A barrier coating is arranged between the substrate and heat-sensitive recording layer and is suitable to protect the heat-sensitive recording layer against penetration of the tincture into the heat-sensitive recording layer from the back side.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: October 14, 2014
    Assignee: Mitsubishi HiTec Paper Europe GmbH
    Inventors: Ulf Behrens, Gerhard Stork, Svenja Eisernitz, Matthias Marx
  • Patent number: 6387584
    Abstract: A photoimaging material which comprises a support and a photoimaging layer formed on the support. The photoimaging layer comprises microcapsules and a reducing agent present outside the microcapsules. The microcapsules contain a leuco dye capable of oxidative color formation, a photooxidizing agent and an organosulfur antioxidant. The reducing agent is 2,2′-methylenebis(4-methyl-6-t-butylphenol) or 2,2′-methylenebis(4-ethyl-6-t-butylphenol). The photoimaging material is capable of thermal image fixing based on a method of forming color by radical oxidation of various leuco dyes to the corresponding dyes with a photooxidizing agent. The photoimaging material is not prone to background coloring (fogging) during storage under dark or light conditions after image fixing, and does not foul the inside of the apparatus during thermal image fixing.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: May 14, 2002
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kensuke Ikeda, Makoto Ono
  • Patent number: 5350729
    Abstract: A developer composition containing a structured clay having a void volume greater than about 50%, a binder and a developer resin, and a developer sheet comprising a such developer composition on a support are described.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: September 27, 1994
    Assignee: The Mead Corporation
    Inventors: Michael G. Londo, Datta G. Mislankar
  • Patent number: 5215956
    Abstract: In the color changing print of this invention, plural areas are printed by using plural types of color changing inks which develop into different colors from the substantially invisible colorless state by reaction with a color changing agent. By the emergence of print from colorlessness and by giving changes in the appearing colors, unexpectedness and entertainingness are provided so that an attractive education may be realized.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: June 1, 1993
    Inventor: Kiyoharu Kawashima
  • Patent number: 5091280
    Abstract: A light- and heat-sensitive recording material comprising a support having thereon at least one light- and heat-sensitive layer comprising, (1) microcapsules containing an electron donative colorless dye, and (2) a light-hardenable composition containing (a) a polymerizable vinyl monomer, (b) a photopolymerization initiator, and (c) an electron acceptive developer and a light- and heat-sensitive recording material comprising a support having thereon at least one light- and heat-sensitive layer comprising, (1) microcapsules containing an electron donative colorless dye, and (2) a light-hardenable composition containing (d) an electron acceptive polymerizable vinyl monomer and (b) a photopolymerization initiator.
    Type: Grant
    Filed: August 13, 1990
    Date of Patent: February 25, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Jun Yamaguchi, Shintaro Washizu, Hirotaka Matsumoto, Ken Iwakura, Yuuichi Fukushige
  • Patent number: 5087283
    Abstract: Sympathetic ink compositions particularly adapted for use with high speed, non-impact ink printing equipment are disclosed, together with methods of use and development thereof. The inks of the invention are water-based and include of from about 4-20% by weight of a water soluble transition metal salt (e.g., nickel sulfate), together with of from about 2-4.5%, by weight of n-butanol or 2-butanol. After application using, e.g., ink jet printing equipment, the resulting inked images are invisible to the naked eye, and can be selectively developed through use of color-forming developers such as dimethylglyoxime- or oxalic acid-type aqueous compositions.
    Type: Grant
    Filed: January 2, 1990
    Date of Patent: February 11, 1992
    Inventors: Marvin P. Dixon, Haywood A. Walker, Jr.
  • Patent number: 5070067
    Abstract: A heat-sensitive recording material comprising a support and a recording layer provided on the support, said recording layer containing a colorless or pale-colored basic dye and a color developer capable of forming a color upon application of heat, wherein a hectorite clay is incorporated in at least one of layers constituting the recording material.
    Type: Grant
    Filed: August 18, 1989
    Date of Patent: December 3, 1991
    Assignee: Kanzaki Paper Mfg. Co., Ltd.
    Inventors: Hisashi Tani, Hisanori Yagi
  • Patent number: 5013709
    Abstract: Disclosed is a color developer for a pressure-sensitive recording paper, which comprises an acid-treated smectite clay mineral having a specific chemical composition, an X-ray diffraction pattern peculiar to dioctahedral smectite, a specific solid NMR spectrum and a specific cation exchange capacity. This color developer shows a high whiteness, a high initial color density, excellent light resistance and weatherability, and a low viscosity.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: May 7, 1991
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Masahide Ogawa, Teiji Sato, Kiyoshi Abe, Hisashi Tsuchida, Hiroo Inoue, Mitsuo Saito
  • Patent number: 4950330
    Abstract: An aqueous dispersion of a developer for pressure-sensitive recording sheet, having superior handling performance and storage stability in a high concentration and a process for producing the dispersion are provided, which developer is expressed by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and represent H, halogen, alkyl of 1 to 9 carbon atoms, alkylene, cycloalkyl, cycloalkylene, phenyl, nucleus-substituted phenyl, aralkyl or nucleus-aralkyl; adjacent two of R.sub.1 to R.sub.4 may form a ring; n is an integer of one or more; and M is Mg, Ca, Zn, Al, Fe, Co, Ni or a basic ion of the foregoing, and which developer has a softening point of 30.degree. C. or higher and is dispersed in water, containing a dispersing agent, the size of particles of the developer being 0.3 to 5.mu.
    Type: Grant
    Filed: September 7, 1989
    Date of Patent: August 21, 1990
    Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Toranosuke Saito, Shouichi Murata, Eiji Kawabata, Tomoharu Shiozaki, Tetsuo Shiraishi
  • Patent number: 4927802
    Abstract: The front side of at least one receptor sheet of a pressure-sensitive multi-part record unit comprises microporous material comprising a matrix consisting essentially of substantially water-insoluble thermoplastic organic polymer, a large proportion of finely divided, water-insoluble siliceous particles, and interconnecting pores.
    Type: Grant
    Filed: December 9, 1988
    Date of Patent: May 22, 1990
    Assignee: PPG Industries, Inc.
    Inventor: Dennis D. Leatherman
  • Patent number: 4917730
    Abstract: Thermally imageable composition comprising (a) at least one leuco dye, (b) a nitrate salt, (c) at least one base having a conjugate acid having pKa equal to or greater than zero. The base serves to prevent spotting or backgrounding of transparency films bearing said thermally imageable composition during the manufacturing process used in preparing the films.
    Type: Grant
    Filed: October 16, 1985
    Date of Patent: April 17, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Alan G. Miller
  • Patent number: 4851384
    Abstract: A long chain fatty acid salt, for example calcium, sodium or aluminium stearate, is included in small amounts (e.g. 2 to 10% by weight) in an otherwise conventional color developer composition of which the major active ingredient is an adsorbent inorganic material. Record material coated with such a composition exhibits better sheet-fed runnability characteristics in wet offset printing operations than if the fatty acid salt is not present.
    Type: Grant
    Filed: May 2, 1986
    Date of Patent: July 25, 1989
    Assignee: The Wiggins Teape Group Limited
    Inventor: John B. Cooper
  • Patent number: 4824825
    Abstract: A color developer sheet for pressure-sensitive recording containing as a color developer only novolak phenol resin or novolak phenol resin and a semi-synthetic solid acid, and as a binder an acrylamide-acrylic acid copolymer can prevent yellowing of the color developer sheet and give higher developed color density.
    Type: Grant
    Filed: November 17, 1987
    Date of Patent: April 25, 1989
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventor: Toshizo Iida
  • Patent number: 4794069
    Abstract: Spirobenzanthracene phthalide compounds are disclosed of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent C.sub.1 -C.sub.8 alkyl optionally substituted by C.sub.1 -C.sub.5 alkoxy; C.sub.5 or C.sub.6 cycloalkyl; or aralkyl or aryl optionally substituted by C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, and R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, and R.sup.5 and R.sup.6 taken together with the nitrogen atom to which they are attached, may form pyrrolidino, piperidino or morpholino ring, and R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently represent hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or trifluoromethyl. The compounds are used, together with a developer, in color for materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.
    Type: Grant
    Filed: July 14, 1987
    Date of Patent: December 27, 1988
    Assignee: Shin Nisso Kako Co., Ltd.
    Inventors: Yutaka Ohnishi, Shinji Yoshinaka, Toshiyuki Tanaka, Minoru Koguchi, Takeo Obitsu
  • Patent number: 4732614
    Abstract: Correction compositions for correcting markings provided on the surface of a pressure-sensitive chemical recording medium carrying a developer material which comprises an acidic developer by interaction of the developer material with a color-providing material. The compositions comprise a substantially uniform dispersion of an opacifying pigment, a polymeric film-forming material, and a Lewis acid. The composition is applied to a marking to provide a film which covers the marking, and a visible correcting marking can be provided on the film by applying a pattern of color-providing material corresponding to the corrected marking to the film.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: March 22, 1988
    Assignee: The Gillette Company
    Inventors: Lamar E. Brooks, Sue R. Liu
  • Patent number: 4720301
    Abstract: A new reversible heat sensitive recording composition for erasable recording is disclosed which is used as a recording or marking material that is capable of erasure at a specific temperature so that coloring or decoloring can be controlled to occur at desired temperature ranges. This range or the hysteresis value of the composition is determined by the .DELTA.T value of the contained ester compound. In addition, the composition can provide a wide variety of hues and can readily be prepared. The marking or recording drawn in this composition can be maintained at room temperature or less.
    Type: Grant
    Filed: December 11, 1985
    Date of Patent: January 19, 1988
    Assignee: Pilot Ink Co., Ltd.
    Inventors: Tsutomu Kito, Norikazu Nakasuji, Takashi Kataoka, Hiroshi Inagaki, Yutaka Shibahashi
  • Patent number: 4680597
    Abstract: A self-contained type pressure sensitive record sheet prepared by coating a substrate with a mixture of microcapsules containing a color former and an inorganic solid acid as a color acceptor and drying the resulting coating, the mixture containing 10 to 30% by weight of polyvinyl alcohol based on the weight of the inorganic solid acid.
    Type: Grant
    Filed: August 8, 1985
    Date of Patent: July 14, 1987
    Assignee: Kanzaki Paper Manufacturing Co. Ltd.
    Inventors: Shigeo Okamoto, Tomoharu Shiozaki