And Identified Inorganic Electron Acceptor (developer), Other Than Mere Clay Patents (Class 503/219)
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Patent number: 8888906Abstract: A heat-sensitive color-developing composition containing a hydroxyquinoline compound having a methyl group and an acid anhydride compound represented by general formula (1): wherein ring A represents a substituted or unsubstituted aromatic hydrocarbon ring, and n represents an integer of 1 to 3, and a heat-sensitive recording material containing the composition in a recording layer.Type: GrantFiled: September 13, 2011Date of Patent: November 18, 2014Assignee: Yamamoto Chemicals, Inc.Inventors: Ryoji Yamaguchi, Toshihiro Masaoka, Keisuke Takuma
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Patent number: 8859460Abstract: A heat-sensitive recording material includes at least a paper substrate, a heat-sensitive recording layer arranged on the front side of the substrate and which has at least one dye precursor and at least one color acceptor, wherein dye precursor and color acceptor react with one another under the action of heat to form color, and an authenticating security feature. The authenticating security feature is a mark which is applied to the back side of the paper substrate and which is made of a tincture having at least one organic solvent. A barrier coating is arranged between the substrate and heat-sensitive recording layer and is suitable to protect the heat-sensitive recording layer against penetration of the tincture into the heat-sensitive recording layer from the back side.Type: GrantFiled: November 30, 2010Date of Patent: October 14, 2014Assignee: Mitsubishi HiTec Paper Europe GmbHInventors: Ulf Behrens, Gerhard Stork, Svenja Eisernitz, Matthias Marx
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Patent number: 6387584Abstract: A photoimaging material which comprises a support and a photoimaging layer formed on the support. The photoimaging layer comprises microcapsules and a reducing agent present outside the microcapsules. The microcapsules contain a leuco dye capable of oxidative color formation, a photooxidizing agent and an organosulfur antioxidant. The reducing agent is 2,2′-methylenebis(4-methyl-6-t-butylphenol) or 2,2′-methylenebis(4-ethyl-6-t-butylphenol). The photoimaging material is capable of thermal image fixing based on a method of forming color by radical oxidation of various leuco dyes to the corresponding dyes with a photooxidizing agent. The photoimaging material is not prone to background coloring (fogging) during storage under dark or light conditions after image fixing, and does not foul the inside of the apparatus during thermal image fixing.Type: GrantFiled: December 11, 1996Date of Patent: May 14, 2002Assignee: Fuji Photo Film Co., Ltd.Inventors: Kensuke Ikeda, Makoto Ono
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Patent number: 5350729Abstract: A developer composition containing a structured clay having a void volume greater than about 50%, a binder and a developer resin, and a developer sheet comprising a such developer composition on a support are described.Type: GrantFiled: March 2, 1993Date of Patent: September 27, 1994Assignee: The Mead CorporationInventors: Michael G. Londo, Datta G. Mislankar
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Patent number: 5215956Abstract: In the color changing print of this invention, plural areas are printed by using plural types of color changing inks which develop into different colors from the substantially invisible colorless state by reaction with a color changing agent. By the emergence of print from colorlessness and by giving changes in the appearing colors, unexpectedness and entertainingness are provided so that an attractive education may be realized.Type: GrantFiled: September 3, 1991Date of Patent: June 1, 1993Inventor: Kiyoharu Kawashima
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Patent number: 5091280Abstract: A light- and heat-sensitive recording material comprising a support having thereon at least one light- and heat-sensitive layer comprising, (1) microcapsules containing an electron donative colorless dye, and (2) a light-hardenable composition containing (a) a polymerizable vinyl monomer, (b) a photopolymerization initiator, and (c) an electron acceptive developer and a light- and heat-sensitive recording material comprising a support having thereon at least one light- and heat-sensitive layer comprising, (1) microcapsules containing an electron donative colorless dye, and (2) a light-hardenable composition containing (d) an electron acceptive polymerizable vinyl monomer and (b) a photopolymerization initiator.Type: GrantFiled: August 13, 1990Date of Patent: February 25, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Jun Yamaguchi, Shintaro Washizu, Hirotaka Matsumoto, Ken Iwakura, Yuuichi Fukushige
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Patent number: 5087283Abstract: Sympathetic ink compositions particularly adapted for use with high speed, non-impact ink printing equipment are disclosed, together with methods of use and development thereof. The inks of the invention are water-based and include of from about 4-20% by weight of a water soluble transition metal salt (e.g., nickel sulfate), together with of from about 2-4.5%, by weight of n-butanol or 2-butanol. After application using, e.g., ink jet printing equipment, the resulting inked images are invisible to the naked eye, and can be selectively developed through use of color-forming developers such as dimethylglyoxime- or oxalic acid-type aqueous compositions.Type: GrantFiled: January 2, 1990Date of Patent: February 11, 1992Inventors: Marvin P. Dixon, Haywood A. Walker, Jr.
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Patent number: 5070067Abstract: A heat-sensitive recording material comprising a support and a recording layer provided on the support, said recording layer containing a colorless or pale-colored basic dye and a color developer capable of forming a color upon application of heat, wherein a hectorite clay is incorporated in at least one of layers constituting the recording material.Type: GrantFiled: August 18, 1989Date of Patent: December 3, 1991Assignee: Kanzaki Paper Mfg. Co., Ltd.Inventors: Hisashi Tani, Hisanori Yagi
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Patent number: 5013709Abstract: Disclosed is a color developer for a pressure-sensitive recording paper, which comprises an acid-treated smectite clay mineral having a specific chemical composition, an X-ray diffraction pattern peculiar to dioctahedral smectite, a specific solid NMR spectrum and a specific cation exchange capacity. This color developer shows a high whiteness, a high initial color density, excellent light resistance and weatherability, and a low viscosity.Type: GrantFiled: September 19, 1989Date of Patent: May 7, 1991Assignee: Mizusawa Industrial Chemicals, Ltd.Inventors: Masahide Ogawa, Teiji Sato, Kiyoshi Abe, Hisashi Tsuchida, Hiroo Inoue, Mitsuo Saito
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Patent number: 4950330Abstract: An aqueous dispersion of a developer for pressure-sensitive recording sheet, having superior handling performance and storage stability in a high concentration and a process for producing the dispersion are provided, which developer is expressed by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and represent H, halogen, alkyl of 1 to 9 carbon atoms, alkylene, cycloalkyl, cycloalkylene, phenyl, nucleus-substituted phenyl, aralkyl or nucleus-aralkyl; adjacent two of R.sub.1 to R.sub.4 may form a ring; n is an integer of one or more; and M is Mg, Ca, Zn, Al, Fe, Co, Ni or a basic ion of the foregoing, and which developer has a softening point of 30.degree. C. or higher and is dispersed in water, containing a dispersing agent, the size of particles of the developer being 0.3 to 5.mu.Type: GrantFiled: September 7, 1989Date of Patent: August 21, 1990Assignees: Sanko Kaihatsu Kagaku Kenkyusho, Kanzaki Paper Manufacturing Co., Ltd.Inventors: Toranosuke Saito, Shouichi Murata, Eiji Kawabata, Tomoharu Shiozaki, Tetsuo Shiraishi
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Patent number: 4927802Abstract: The front side of at least one receptor sheet of a pressure-sensitive multi-part record unit comprises microporous material comprising a matrix consisting essentially of substantially water-insoluble thermoplastic organic polymer, a large proportion of finely divided, water-insoluble siliceous particles, and interconnecting pores.Type: GrantFiled: December 9, 1988Date of Patent: May 22, 1990Assignee: PPG Industries, Inc.Inventor: Dennis D. Leatherman
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Patent number: 4917730Abstract: Thermally imageable composition comprising (a) at least one leuco dye, (b) a nitrate salt, (c) at least one base having a conjugate acid having pKa equal to or greater than zero. The base serves to prevent spotting or backgrounding of transparency films bearing said thermally imageable composition during the manufacturing process used in preparing the films.Type: GrantFiled: October 16, 1985Date of Patent: April 17, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventor: Alan G. Miller
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Patent number: 4851384Abstract: A long chain fatty acid salt, for example calcium, sodium or aluminium stearate, is included in small amounts (e.g. 2 to 10% by weight) in an otherwise conventional color developer composition of which the major active ingredient is an adsorbent inorganic material. Record material coated with such a composition exhibits better sheet-fed runnability characteristics in wet offset printing operations than if the fatty acid salt is not present.Type: GrantFiled: May 2, 1986Date of Patent: July 25, 1989Assignee: The Wiggins Teape Group LimitedInventor: John B. Cooper
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Patent number: 4824825Abstract: A color developer sheet for pressure-sensitive recording containing as a color developer only novolak phenol resin or novolak phenol resin and a semi-synthetic solid acid, and as a binder an acrylamide-acrylic acid copolymer can prevent yellowing of the color developer sheet and give higher developed color density.Type: GrantFiled: November 17, 1987Date of Patent: April 25, 1989Assignee: Mitsubishi Paper Mills, Ltd.Inventor: Toshizo Iida
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Patent number: 4794069Abstract: Spirobenzanthracene phthalide compounds are disclosed of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent C.sub.1 -C.sub.8 alkyl optionally substituted by C.sub.1 -C.sub.5 alkoxy; C.sub.5 or C.sub.6 cycloalkyl; or aralkyl or aryl optionally substituted by C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, and R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, and R.sup.5 and R.sup.6 taken together with the nitrogen atom to which they are attached, may form pyrrolidino, piperidino or morpholino ring, and R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently represent hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or trifluoromethyl. The compounds are used, together with a developer, in color for materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.Type: GrantFiled: July 14, 1987Date of Patent: December 27, 1988Assignee: Shin Nisso Kako Co., Ltd.Inventors: Yutaka Ohnishi, Shinji Yoshinaka, Toshiyuki Tanaka, Minoru Koguchi, Takeo Obitsu
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Patent number: 4732614Abstract: Correction compositions for correcting markings provided on the surface of a pressure-sensitive chemical recording medium carrying a developer material which comprises an acidic developer by interaction of the developer material with a color-providing material. The compositions comprise a substantially uniform dispersion of an opacifying pigment, a polymeric film-forming material, and a Lewis acid. The composition is applied to a marking to provide a film which covers the marking, and a visible correcting marking can be provided on the film by applying a pattern of color-providing material corresponding to the corrected marking to the film.Type: GrantFiled: July 15, 1985Date of Patent: March 22, 1988Assignee: The Gillette CompanyInventors: Lamar E. Brooks, Sue R. Liu
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Patent number: 4720301Abstract: A new reversible heat sensitive recording composition for erasable recording is disclosed which is used as a recording or marking material that is capable of erasure at a specific temperature so that coloring or decoloring can be controlled to occur at desired temperature ranges. This range or the hysteresis value of the composition is determined by the .DELTA.T value of the contained ester compound. In addition, the composition can provide a wide variety of hues and can readily be prepared. The marking or recording drawn in this composition can be maintained at room temperature or less.Type: GrantFiled: December 11, 1985Date of Patent: January 19, 1988Assignee: Pilot Ink Co., Ltd.Inventors: Tsutomu Kito, Norikazu Nakasuji, Takashi Kataoka, Hiroshi Inagaki, Yutaka Shibahashi
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Patent number: 4680597Abstract: A self-contained type pressure sensitive record sheet prepared by coating a substrate with a mixture of microcapsules containing a color former and an inorganic solid acid as a color acceptor and drying the resulting coating, the mixture containing 10 to 30% by weight of polyvinyl alcohol based on the weight of the inorganic solid acid.Type: GrantFiled: August 8, 1985Date of Patent: July 14, 1987Assignee: Kanzaki Paper Manufacturing Co. Ltd.Inventors: Shigeo Okamoto, Tomoharu Shiozaki