Hetero Ring Containing Antidote Patents (Class 504/104)
  • Patent number: 10000765
    Abstract: To identify a cytochrome P450 involved in the detoxification and metabolism of a specific growth inhibitor. Provided is a gene encoding a cytochrome P450 classified into Indica rice-derived CYP72A31, comprising a polynucleotide encoding a protein comprising an amino acid sequence of SEQ ID NO: 2.
    Type: Grant
    Filed: October 12, 2012
    Date of Patent: June 19, 2018
    Assignees: NATIONAL INSITUTE OF AGROBIOLOGICAL SCIENCE, KUMIAI CHEMICAL INDUSTRY CO., LTD
    Inventors: Hiroaki Saika, Fumio Taguchi, Kiyosumi Hori, Takashi Matsumoto, Tsuyoshi Tanaka, Junko Horita, Koichiro Kaku, Tsutomu Shimizu
  • Patent number: 9856201
    Abstract: The present disclosure relates, in general, to 5-halo-3,6-dichlorosalicylic acid compounds, 5-halo-3,6-dichlorosalicyaldehyde compounds, processes for preparing 5-halo-3,6-dichlorosalicylic acid compounds, processes for preparing 5-halo-3,6-dichlorosalicyaldehyde compounds, processes for preparing 3,6-dichlorosalicylic acid compounds, and processes that employ such compounds as intermediates in the preparation of the herbicide dicamba.
    Type: Grant
    Filed: June 3, 2015
    Date of Patent: January 2, 2018
    Assignee: Monsanto Technology LLC
    Inventors: Terri L. Boehm, Mangesh Bore, Jeffery N. Carroll, G. Davis Harris, Jr., Matthew D. McReynolds, Justin R. Struble, Daniel P. Walker
  • Patent number: 9682966
    Abstract: The invention provides novel ligands of Kappa (?) opioid receptors, such as can be used to modulate a Kappa opioid receptor. Methods of synthesis and methods of use are also provided. Compounds of the invention can be used therapeutically in the treatment of dissociative disorders or pain, or to provide neuroprotection, or to induce diuresis, or to modulate the immune system, or for treatment of one or more of an affective disorders comprising depression or stress/anxiety; an addictive disorder; alcoholism, epilepsy; a cognition deficiency; schizophrenia; Alzheimer's disease; or pain.
    Type: Grant
    Filed: August 16, 2013
    Date of Patent: June 20, 2017
    Assignee: The Scripps Research Institute
    Inventors: Edward Roberts, Miguel A. Guerrero, Mariangela Urbano, Hugh Rosen
  • Patent number: 9232791
    Abstract: The invention relates to the use of one or more acylsulfonamide safener compounds of formula (I): for modifying plant development of useful plants. The use provides an increase in root growth and/or a regulation in shoot growth of the plants.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: January 12, 2016
    Assignee: Bayer Intellectual Property GmbH
    Inventors: Christopher Hugh Rosinger, Frank Ziemer
  • Patent number: 8901036
    Abstract: The invention relates to combinations of sulfonylurea herbicides (A) and their salts in which R2 is H, OH, aliphatic hydrocarbon radical or hydrocarbon-oxy radical, and R1 is an acyl radical, and the other symbols are as defined in claim 1, and safeners of type (B1) and (B2) in which the symbols are as defined in claim 1.
    Type: Grant
    Filed: March 1, 2006
    Date of Patent: December 2, 2014
    Assignee: Bayer Cropscience AG
    Inventors: Lothar Willms, Hermann Bieringer, Erwin Hacker, Gerhard Schnabel, Klaus Lorenz
  • Publication number: 20130012384
    Abstract: The present invention relates to novel compounds of the formula (I), in which W, X, Y, Z, G, A and t have the meanings given above, to a plurality of processes and intermediates for their preparation and to their use as pesticides and/or herbicides. Moreover, the invention relates to selective herbicidal compositions comprising, firstly, the spiroheterocyclic tetronic acid derivates and, secondly, a crop plant compatibility-improving compound. The present invention furthermore relates to increasing the activity of crop protection compositions comprising in particular phenyl-substituted bicyclooctane-1,3-dione derivates by adding ammonium salts or phosphonium salts and, if appropriate, penetrants, to the corresponding compositions, to processes for their preparation and to their use in crop protection as insecticides and/or acaricides and/or for preventing unwanted plant growth.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Applicant: Bayer CropScience AG
    Inventors: Thomas BRETSCHNEIDER, Reiner Fischer, Stefan Lehr, Olga Malsam, Arnd Voerste
  • Patent number: 8268747
    Abstract: Clomazone safens rice from the slight amounts of damage caused by penoxsulam at concentrations required to adequately control undesirable vegetation.
    Type: Grant
    Filed: April 26, 2010
    Date of Patent: September 18, 2012
    Assignee: Dow AgroSciences, LLC.
    Inventors: Richard K. Mann, Deborah G. Shatley
  • Publication number: 20120088667
    Abstract: A compound selected from a composition comprising an auxin, an auxin precursor, an auxin metabolite or a derivative of said auxin, auxin precursor or auxin metabolite and acetaminophen or a derivative thereof for use as a plant safener.
    Type: Application
    Filed: April 7, 2010
    Publication date: April 12, 2012
    Applicant: TAMINCO, NAAMLOZE VENNOOTSCHAP
    Inventors: Richard Williams, Peter Roose, Johan Josef De Saegher
  • Publication number: 20110130284
    Abstract: The invention relates to novel compounds of the formula (I) in which W, X, Y, Z, A and G have the meanings given above, to a plurality of processes and intermediates for their preparation and to their use as pesticides and/or herbicides, and also to selective herbicidal compositions comprising, firstly, the cis-alkoxyspirocyclic biphenyl-substituted tetramic acid derivatives of the formula (I) and, secondly, at least one crop plant compatibility-improving compound. The invention relates furthermore to increasing the activity of crop protection compositions comprising compounds of the formula (I) by adding ammonium or phosphonium salts and, if appropriate, penetrants.
    Type: Application
    Filed: November 22, 2007
    Publication date: June 2, 2011
    Applicant: Bayer CropScience AG
    Inventors: Reiner Fischer, Christian Arnold, Olga Malsam, Jan Dittgen, Dieter Feucht, Ulrich Görgens, Martin Jeffrey Hills, Christopher Hugh Rosinger
  • Publication number: 20100113270
    Abstract: Cyclohexanedione compounds of Formula (I) wherein R1 is methyl, ethyl, n-propyl, iso-propyl, cyclopropyl, halomethyl, haloethyl, halogen, vinyl, ethynyl, methoxy, ethoxy, halomethoxy or haloethoxy, R2 and R3 are, independently hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C3-C6alkenyloxy, C3-C6haloalkenyloxy, C3-C6alkynyloxy, C3-C6cycloalkyl, C1-C6alkylthio, C1-C6alkylsulfinyl, C1-C6alkylsulfonyl, C1-C6alkylsulfonyloxy, C1-C6haloalkylsulfonyloxy, cyano, nitro, phenyl, phenyl substituted by C1-C4alkyl, C1-C3Cahaloalkyl, C1-C3alkoxy, C1-C3haloalkoxy, cyano, nitro, halogen, C1-C3alkylthio, C1-C3alkylsulfinyl or C1-C3alkylsulfonyl, or heteroaryl or heteroaryl substituted by C1-C3Calkyl, d.
    Type: Application
    Filed: March 7, 2008
    Publication date: May 6, 2010
    Applicant: SYNGENTA CROP PROTECTION, INC.
    Inventors: Christopher John Mathews, John Finney, Louisa Robinson, Melloney Tyte, Michel Muehlebach, Jean Wenger
  • Publication number: 20100062939
    Abstract: The present invention relates to a herbicide/safener combination comprising components (A) and (B), where (A) denotes one or more compounds or salts thereof from the group described by the general formula (I): in which R1 is halogen, preferably fluorine or chlorine, R2 is hydrogen and R3 is hydroxyl or R2 and R3 together with the carbon atom to which they are attached are a carbonyl group C?O and R4 is hydrogen or methyl; and (B) is one or more compounds from the group of the safeners.
    Type: Application
    Filed: August 11, 2009
    Publication date: March 11, 2010
    Applicant: BAYER CROPSCIENCE AG
    Inventors: Erwin Hacker, Christopher Hugh Rosinger, Chieko Ueno, Georg Bonfig-Picard, Frank Ziemer, Shinichi Shirakura
  • Publication number: 20070238615
    Abstract: Liquid formulations in crop protection and their use Formulations with delayed release of agrochemical actives from the group of fatty acid synthetase inhibitors are suitable for reducing phytotoxicity in crop plants when said agrochemical actives are used to check unwanted detrimental organisms in the crops.
    Type: Application
    Filed: April 2, 2007
    Publication date: October 11, 2007
    Applicant: Bayer CropScience GmbH
    Inventors: Hans-Peter Krause, Gerhard Schnabel, Roland Deckwer, Udo Bickers
  • Publication number: 20070167328
    Abstract: A herbicide composition for paddy field characterized by containing (a) a herbicidal difluoromethanesulfonamide derivative represented by the formula (I) and (b) at least one herbicidal compound selected from the group consisting of pretilachlor, butachlor, alachlor, metolachlor, acetochlor, clomeprop, bromobutide, benfuresate, indanofan, pyrazolate, benzofenap, pyrazoxyfen, pyraclonil, oxaziclomefone, bensulfuron-methyl, azimsulfuron, imazosulfuron, pyrazosulfuron-ethyl, cyclosulfamuron, ethoxysulfuron, halosulfuron-methyl, orthosulfamuron, cinosulfuron, metsulfuron-methyl, penoxsulam, thiobencarb, pyributycarb, molinate, dimethametryn, simetryn, cafenstrole, quinclorac, anilofos, mefenacet, fentrazamide, pentoxazone, oxadiargyl, oxadiazon, benzobicyclon, mesotrione, AVH301 (code no.
    Type: Application
    Filed: January 12, 2007
    Publication date: July 19, 2007
    Applicant: Bayer CropScience GmbH
    Inventors: Keiji Endo, Shinichi Shirakura, Shin Nakamura, Natsuko Minegishi
  • Patent number: 7141531
    Abstract: The invention relates to combinations of sulfonylurea herbicides (A) and their salts in which R2 is H, OH, aliphatic hydrocarbon radical or hydrocarbon-oxy radical, and R1 is an acyl radical, and the other symbols are as defined in claim 1, and safeners of type (B1) and (B2) in which the symbols are as defined in claim 1.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: November 28, 2006
    Assignee: Hoechst Schering AgrEvo GmbH
    Inventors: Lothar Willms, Hermann Bieringer, Erwin Hacker, Gerhard Schnabel, Klaus Lorenz
  • Patent number: 6890885
    Abstract: A herbicidal composition that, in addition to comprising customary inert formulation adjuvants, comprises a) a compound of formula I ?wherein the substituents are as defined in claim 1, and b) a synergistically effective amount of one or more compounds of formulae 2.1 to 2.51. The compositions according to the invention may also comprise a safener.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: May 10, 2005
    Assignee: Syngenta Corp Protection, Inc.
    Inventor: Willy T. Rüegg
  • Patent number: 6855667
    Abstract: The present invention relates to protection of plants from unintended phytotoxic injury due to application of a herbicide to reduce competition for the plant of interest. A preferred herbicide used in the context of the present invention is clomazone. The unintended phytotoxic injury is avoided by application of a safening-effective amount of one or more of the compounds described by formula (I) wherein T and T1 are independently selected from the group of hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl, and alkynyl; U is oxygen or sulfur, and; V, W, X, Y, and Z are independently selected from the group of hydrogen, halogen, alkyl, haloalkyl, and alkoxy. The present invention is preferably used for growing corn, wheat, and cotton in the presence of the otherwise phytoxic effects of clomazone, for example.
    Type: Grant
    Filed: January 5, 2001
    Date of Patent: February 15, 2005
    Assignee: FMC Corporation
    Inventor: David W. Keifer
  • Patent number: 6544927
    Abstract: The invention provides methods and compositions for reducing defoliation of plants and trees. Preferably, the methods and compositions of the invention reduce defoliation associated with the application of abscission agents or herbicides to plants and trees.
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: April 8, 2003
    Assignee: University of Florida
    Inventor: Jacqueline Kay Burns
  • Publication number: 20020183205
    Abstract: The invention provides methods and compositions for reducing defoliation of plants and trees. Preferably, the methods and compositions of the invention reduce defoliation associated with the application of abscission agents or herbicides to plants and trees.
    Type: Application
    Filed: June 29, 2001
    Publication date: December 5, 2002
    Inventor: Jacqueline Kay Burns
  • Publication number: 20020055435
    Abstract: The invention relates to a herbicidal composition comprising a herbicidally acceptable carrier and/or surface active agent and, as active ingredient, a synergistically effective amount of
    Type: Application
    Filed: August 24, 2001
    Publication date: May 9, 2002
    Applicant: Intellectual Property Department
    Inventors: Helmut Siegfried Baltruschat, Astrid Brandt
  • Patent number: 6197876
    Abstract: The present invention teaches heterocyclic amine modified siloxanes and their use, a preferred of which is as adjuvants for pesticides. The heterocyclic amine modified siloxanes have siloxane backbones with pendant, terminal or intermediate heterocyclic amine groups, which may contain one or more heteroatoms, i.e., nitrogen, sulfur or oxygen. The heterocyclic amine groups or the siloxane may be functionalized further with alkyl or alkyleneoxide groups.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: March 6, 2001
    Assignee: CK Witco Corporation
    Inventors: George A. Policello, Gerald J. Murphy
  • Patent number: 5880066
    Abstract: The disclosure herein relates to the use of a variety of antidotal compounds to safen crop plants from the phytotoxicity of azolopyrimidine sulfonamide herbicides.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: March 9, 1999
    Assignee: Monsanto Company
    Inventors: Barbara Heard Wells, Harrison Ross Hakes, David James Mayonado, John Paul Chupp
  • Patent number: 5739079
    Abstract: Substituted (hetero)aryl compounds, process for their preparation, agents containing them, and their use as safenersCompounds of the formula I and their salts, as defined in claim 1, are suitable as safeners for protecting crop plants against the phytotoxic side-effects of herbicides.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: April 14, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Xenia Holdgrun, Lothar Willms, Klaus Bauer, Klaus Trinks, Hermann Bieringer
  • Patent number: 5710100
    Abstract: The disclosure herein relates to the use of certain amides of dichloroacetic acid and other compounds as safener/antidotal compounds to reduce the phytotoxicity to crop plants, especially corn, of imidazolinone-type herbicides alone or in admixture with other co-herbicidal compounds, e.g., .alpha.-haloacetamides.
    Type: Grant
    Filed: December 29, 1994
    Date of Patent: January 20, 1998
    Assignee: Monsanto Company
    Inventors: Brett Hayden Bussler, Ronald Joseph Brinker
  • Patent number: 5696050
    Abstract: There is provided a method for safening herbicides in crop plants by using substituted benzopyran or tetrahydronaphthalene compounds of formula I ##STR1## Further provided are compounds of formula II and compositions comprising a herbicide and an antidotally effective amount of a substituted benzopyran or tetrahydronaphthalene compound of formula I.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: December 9, 1997
    Assignee: American Cyanamid Company
    Inventors: Gail Ezra Cary, Nina Rose Quinn
  • Patent number: 5565408
    Abstract: Cyanoquinoline compounds Ia or Ib ##STR1## where R.sup.1 is CH.dbd.C(CN).sub.2 ; CH.dbd.N--N.dbd.CH--(5-quinolyl); methylsulfonyl; CH.dbd.NOH; halogen; hydroxyl; nitro; cyano; unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio, pyrrolidinyl; piperidinyl; morpholinyl; thiomorpholinyl; unsubstituted or substituted phenyl, phenoxy, phenylthio, phenyldithiolyl, phenylsulfonyl or pyrrolyl;m is 0, 1, 2 or 3;R.sup.2 is hydrogen; hydroxyl; halogen; C.sub.1 -C.sub.4 -alkoxy; --NR.sup.3 R.sup.4 ; --NR.sup.5 --CXR.sup.6 or --N.dbd.CR.sup.7 R.sup.8 ;R.sup.3 is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl;R.sup.4 is a radical R.sup.3 ; C.sub.1 -C.sub.4 -alkylamino; di-C.sub.1 -C.sub.4 -alkylamino; substituted C.sub.1 -C.sub.4 -alkyl; CH.dbd.N--(3-cyano-2-quinolinyl); or R.sup.3 and R.sup.4 together form C.sub.4 - or C.sub.3 -alkylene which may be interrupted by a hetero atom, or unsubstituted or substituted 1,3-butadienyl;R.sup.5 and R.sup.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: October 15, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Juergen Pfister, Gunter Brill, Gerhard Nilz, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5491123
    Abstract: Herbicides contain one or more antagonistic 3-aminobenzo[b]thiophenes I ##STR1## wherein the variables on the compound of formula I are defined in the specification.A) the group consisting of the cyclohexenone derivatives orB) the group consisting of the 4-hetaryloxyphenoxyacetic acid derivatives.
    Type: Grant
    Filed: February 4, 1994
    Date of Patent: February 13, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Gerhard Nilz, Thomas Roetsch, Helmut Walter, Andreas Landes
  • Patent number: 5488027
    Abstract: The invention relates to herbicidal compositions which contain an effective amount ofA) one or more herbicides selected from the group comprising sulfonylureas and imidazolinones andB) one or more safeners selected from the group comprisingB1) phenyl-substituted imidazole-, imidazoline- and triazolecarboxylic acid derivatives and the benzyloxazolinecarboxylic acid derivatives and/orB2) quinolin-8-oxyalkanecarboxylic acid derivatives,with the exception of combinations of imidazolinones with compounds of the formula B2.The compositions are particularly suitable for protecting plants against phytotoxic secondary effects of sulfonylurea herbicides and imidazolinone herbicides. In the case of the imidazolinone herbicides, the invention also relates to a method of protecting corn plants, by applying post-emergence an effective amount of a quinolin-8-oxyalkanecarboxylic acid derivative together with the imidazolinone herbicide to the plants or the area under cultivation.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: January 30, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Klaus Bauer, Hermann Bieringer
  • Patent number: 5484760
    Abstract: The disclosure herein relates to means for combatting the adverse phytotoxic action to crops arising from the interaction of various herbicidal compounds and biocidal compounds, e.g., insecticidal and/or fungicidal compounds. The means employed to reduce said interaction involves the safening action of various antidotal compounds.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: January 16, 1996
    Assignee: Monsanto Company
    Inventors: Brett H. Bussler, Harrison R. Hakes, David J. Mayonado
  • Patent number: 5441922
    Abstract: Herbicide/safener combinations ofA) herbicides selected from the group of the 2-acylated 1,3-dicarbonyl compounds or salts thereof, andB) safeners B1 and/or B2 ##STR1## as they are defined in claim 1, are suitable for controlling harmful plants in crops such as cereals, maize and rice.
    Type: Grant
    Filed: December 29, 1992
    Date of Patent: August 15, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Oswald Ort, Lothar Willms, Hans-Joachim Zeiss, Stephan Mller, Herbert Stark, Rainer Schutze, Klaus Bauer, Hermann Bieringer
  • Patent number: 5428000
    Abstract: An antagonism caused by the use of a herbicide for narrowleaf weeds together with a herbicide for broadleaf weeds is inhibited by using together with hydrophilic polymeric compound containing a quaternary ammonium salt and having 10,000 to 1,000,000 of molcular weight.
    Type: Grant
    Filed: March 23, 1994
    Date of Patent: June 27, 1995
    Assignee: Toho Chemical Industry Co., Ltd.
    Inventors: Haruki Innami, Teruyuki Misumi, Makoto Konnai
  • Patent number: 5422335
    Abstract: A herbicidal composition containing one or more substituted 2-aminothiophenes of the formula I ##STR1## where R.sup.1 and R.sup.2 together from a C.sub.4 -alkylene chain to which a benzene ring may be fused,R.sup.3 is --CN or CX--R.sup.6, where R.sup.6 is hydroxyl, C.sub.1 -C.sub.4 -alkoxy or amino,R.sup.4 is hydrogen or a phenyl group which may carry one or two nitro radicals,--PO(OR.sup.8).sub.2, --CX--R.sup.9, --SO.sub.2 R.sup.10, --CX--N(H) --CO--R.sup.8 or --CX--N(R.sup.7)--SO.sub.2 --R.sup.11,whereR.sup.8 is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl groupR.sup.9 is C.sub.1 -C.sub.20 -alkyl, partially or completely halogenated C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.6 -cycloalkyl, or amino, C.sub.1 -C.sub.4 -alkylamino, C.sub.3 -C.sub.8 -cycloalkylamino, phenyl or phenylamino, where the aromatic moiety may carry at least one of nitro and halogen;R.sup.10 is C.sub.1 -C.sub.4 -alkyl or phenyl, which may carry one C.sub.1 -C.sub.4 -alkyl radical;R.sup.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: June 6, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Gerhard Nilz, Helmut Walter, Andreas Landes
  • Patent number: 5407897
    Abstract: There is provided a method for safening herbicides in crop plants by using substituted benzopyran or tetrahydronaphthalene compounds of formula I ##STR1## Further provided are compounds of formula II and compositions comprising a herbicide and an antidotally effective amount of a substituted benzopyran or tetrahydronaphthalene compound of formula I.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: April 18, 1995
    Assignee: American Cyanamid Company
    Inventors: Gail E. Cary, Nina R. Quinn
  • Patent number: 5378677
    Abstract: Herbicidal agents containing at least one thiochromenone of the formula I ##STR1## where n is 1, 2, 3 or 4, and the radicals R.sup.3 may have different meanings when n is>1;R.sup.1 is hydrogen; cyano; halogen; substituted or unsubstituted alkyl, aryl or hetaryl;a group --XR.sup.4 or a group --COYR.sup.4, whereX is oxygen, sulfur and NR.sup.5,Y is oxygen and NR.sup.5,R.sup.4 is one of the following groups:hydrogen; formyl; alkyl; cycloalkyl; alkylcarbonyl; cycloalkylcarbonyl; alkylsulfonyl; cycloalkylsulfonyl;substituted or unsubstituted aryl, hetaryl, arylcarbonyl, hetarylcarbonyl, arylsulfonyl or hetarylsulfonyl;andR.sup.5 is hydrogen or substituted or unsubstituted alkyl, aryl or hetaryl;R.sup.2 is hydrogen; cyano; nitroso; nitro; halogen; substituted or unsubstituted alkyl, alkoxy, alkylthio, aryl or hetaryl;a group --NR.sup.4 R.sup.5 or a group --COYR.sup.4, whereY, R.sup.4 and R.sup.5 have the above meanings;R.sup.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: January 3, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Peter Raatz, Helmut Walter, Andreas Landes
  • Patent number: 5256626
    Abstract: The disclosure herein relates to a new family of haloalkyl oxazolidinyl derivatives as antidotal compounds to reduce injury to crop plants by a variety of herbicides. The antidotal compounds are characterized particularly by having heterocyclyl or spiroheterocyclyl radicals attached to the 5-position of haloalkyl oxazolidine compounds and are especially useful as in-can antidotes against injury by acetanilide and thiocarbamate herbicides to corn, sorghum, soybeans, wheat, rice and other crops.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: October 26, 1993
    Assignee: Monsanto Company
    Inventors: Eric L. Williams, Steven M. Massey, Brett H. Bussler, Ronald J. Brinker
  • Patent number: 5215570
    Abstract: The N-acylsulfamoylphenylureas of formula I below are suitable as counter-agents (antidotes or safeners) for protecting cultivated plants from the phytotoxic action of herbicides. Suitable crops are preferably cereals, soybeans, sorghum, maize and rice, and suitable herbicides are sulfonylureas, chloroacetanilides and aryloxyphenoxypropionic acid derivatives.The N-acylsulfamoylphenylureas have the formula I ##STR1## wherein A is a radical selected from the group ##STR2## R.sub.1 is C.sub.1 -C.sub.4 -alkoxy or each of R.sub.1 and R.sub.2, independently of the other, is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, ##STR3## or C.sub.1 -C.sub.4 alkyl substituted by C.sub.1 -C.sub.4 alkoxy or by ##STR4## or R.sub.1 and R.sub.2 together form a C.sub.4 -C.sub.6 alkylene bridge, or a C.sub.4 -C.sub.6 alkylene bridge interrupted by oxygen, sulfur, SO, SO.sub.2, NH or by --N(C.sub.1 -C.sub.4 alkyl)-, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.
    Type: Grant
    Filed: January 3, 1991
    Date of Patent: June 1, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Urs Burckhardt, Raafat Soliman, Werner Topfl, Hans-Rudolf Waespe
  • Patent number: 5201933
    Abstract: The disclosure herein relates to the use of certain amides of dichloroacetic acid and other compounds as safener/antidotal compounds to reduce the phytotoxicity to crop plants, especially corn, of benzoic acid-type herbicides alone or in admixture with other co-herbicidal compounds, e.g., .alpha.-haloacetamides.
    Type: Grant
    Filed: October 12, 1990
    Date of Patent: April 13, 1993
    Assignee: Monsanto Company
    Inventors: Knudt J. Miller, Brett H. Bussler
  • Patent number: 5087640
    Abstract: Compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are independently fluorine, chlorine or bromine atom, and R.sup.3 is a C.sub.4 -C.sub.7 alkyl having at least a branch at the C.sub.1 position, exhibit K.sup.+ channel opening activity and are useful as hypotensive agents and coronary vasodilators.
    Type: Grant
    Filed: June 27, 1990
    Date of Patent: February 11, 1992
    Assignee: Kanebo, Ltd.
    Inventors: Tominori Morita, Kazuya Yoshiizumi, Noriyasu Nishimura, Katsumi Goto, Takayuki Sukamoto, Kohichiro Yoshino