Phosphorus Containing Active Ingredient Wherein The Phosphorus Is Other Than Solely As Part Of An Inorganic Ion In An Addition Salt Patents (Class 504/127)
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Patent number: 5998332Abstract: Aqueous concentrate herbicidal compositions are provided comprising a herbicidally effective amount of ammonium salt of N-phosphonomethylglycine wherein the molar ratio of ammonia to N-phosphonomethylglycine provides a pH of about 6 to about 7, and a herbicidal efficacy enhancing amount of one or more surfactants. Compositions of the invention are storage-stable over a wide range of temperatures. Also provided is a method of killing or controlling vegetation comprising diluting a composition of the invention in water and applying the diluted composition to foliage of the vegetation.Type: GrantFiled: July 21, 1998Date of Patent: December 7, 1999Assignee: Monsanto CompanyInventors: Tatsuo Sato, Masuo Kuchikata, Akio Amano, Masayasu Fujiyama, Daniel Richard Wright
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Patent number: 5994269Abstract: This invention relates to a novel aqueous agriculturally acceptable formulation, a process used to prepare it and a pesticidal method of using it in application to plants or weeds to kill or control plants or weeds. The formulation comprises an effective amount of N-phosphonomethylglycine or an agriculturally acceptable salt of N-phosphonomethylglycine and an effective amount of at least one C.sub.5 to C.sub.16 or preferably a C.sub.8 to C.sub.12 agriculturally acceptable fatty acid itself or in the form of an agriculturally acceptable water soluble salt or mixtures thereof. Other ingredients are optional, including surfactant(s), antifoam(s) and antimicrobial(s) or other ingredients such as pesticides including herbicides, insecticides and fungicides.Type: GrantFiled: January 29, 1997Date of Patent: November 30, 1999Assignee: Monsanto CompanyInventors: M. Wayne Bugg, Kristin A. Arnold, Randall J. White
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Patent number: 5990045Abstract: This invention relates to herbicidal mixtures comprising sulfonylureas together with glyphosate, herbicidal compositions of said mixtures, and a method for the use of said mixtures to control undesired vegetation.Type: GrantFiled: October 13, 1998Date of Patent: November 23, 1999Assignee: E.I. du Pont de Nemours and CompanyInventors: Daniel Carl Leep, Francis T. Lichtner
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Patent number: 5990047Abstract: Herbicidal compositions comprisingA) at least one compound from the group of the substituted phenylsulfonylureas of the formula I and their agriculturally acceptable salts ##STR1## in which R.sup.1 is (C.sub.1 -C.sub.8)alkyl, (C.sub.3 -C.sub.4)alkenyl, (C.sub.3 -C.sub.4)alkynyl or (C.sub.1 -C.sub.4)alkyl which is mono- to tetrasubstituted by radicals selected from the group consisting of halogen and (C.sub.1 -C.sub.2)alkoxy,andB) at least one herbicidally active compound from the group of compounds composed ofBa) herbicides which act selectively against grasses in cereals and/or maize,Bb) herbicides which act selectively against dicots in cereals and/or maize,Bc) herbicides which act selectively against grasses and dicots in cereals and/or maize andBd) herbicides which act non-selectively against grass weeds and broad-leaved weeds in non-crop areas and/or selectively against grass weeds and broad-leaved weeds in transgenic crops.Type: GrantFiled: June 6, 1996Date of Patent: November 23, 1999Assignee: Hoechst Schering AgrEvo GmbHInventors: Erwin Hacker, Martin Hess, Heinz Kehne
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Patent number: 5981432Abstract: Herbicidal compositions comprising S-metolachlor and at least one additional herbicide selected from atrazine, terbuthylazine, flumetsulan, pendimethalin, metosulam, pyridate, glyphosate, glufosinate, cyanazine, dicamba, halosulfuron, prosulfuron, primisulfuron, sulcotrione, metribuzin, BAY FOE 5043, and salts thereof. The compositions may also contain the safener benoxacor.Type: GrantFiled: February 2, 1998Date of Patent: November 9, 1999Assignee: Novartis Crop ProtectionInventors: Manfred Hudetz, Dan Worden Kidder, Robert Franklin Milliken, Norbert Nelgen
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Patent number: 5977028Abstract: This invention relates to certain phenylhetercyclic compounds, herbicidal compositions thereof and a method for their use as general and selective preemergent or postemergent herbicides or plant growth regulants.Type: GrantFiled: May 7, 1997Date of Patent: November 2, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Thomas P. Selby, Thomas M. Stevenson
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Patent number: 5928995Abstract: This invention relates to herbicidal mixtures of triflusulfuron methyl and glyphosate, herbicidal compositions of said mixtures, and a method for the use of said mixtures to control undesired vegetation.Type: GrantFiled: November 3, 1997Date of Patent: July 27, 1999Assignee: E. I. du Pont de Nemours and CompanyInventor: Francis Thomas Lichtner, Jr.
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Patent number: 5902772Abstract: Described are .omega.,.omega. -?.alpha.,.omega.-alkanediylbis(alkylimino)!bis(alkanolpolyethoxylates) in which (i) the alkane group has in the range of 4 to 12 carbon atoms, (ii) the alkyl groups can be the same or different and contain up to about 24 carbon atoms each, and (iii) the number of ethyleneoxy groups in each polyethoxylate group is in the range of 2 to about 50. These compounds are effective adjuvants for use with pesticides, especially herbicides and plant growth regulants, such as glyphosate.Type: GrantFiled: December 3, 1997Date of Patent: May 11, 1999Assignee: Albemarle CorporationInventors: Ralph W. Magin, Joe D. Sauer
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Patent number: 5898019Abstract: A method and device are used for controlling growth of plants in pavement splits by preventing seeds from germinating and by preventing growth of plants from existing roots in the vicinity of the splits. The growth of plants is controlled for extended periods of time (2 to 20 years). A pre-emergence herbicide and a systemic herbicide are incorporated into a polymeric matrices. The polymeric matrices are formed into shaped objects, such as, bands or cords which are then inserted into splits. The split is then filled with a sealer which permits easy migration of the herbicides therethrough. The herbicides gradually released from the shaped objects at a rate sufficient to maintain a minimal effective level of herbicide outside said sealer for a predetermined period of time.Type: GrantFiled: September 5, 1997Date of Patent: April 27, 1999Assignee: Battelle Memorial InstituteInventors: Peter Van Voris, Dominic A. Cataldo, Frederick G. Burton, W. Eugene Skiens
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Patent number: 5877114Abstract: The present invention is directed to the use of certain auxin transport inhibiting semicarbazones to potentiate the herbicidal activity of other herbicides. The present invention includes potentiating herbicidal compositions of these auxin transport inhibitors and glyphosate. These potentiating herbicidal compositions have been found especially useful in combating or controlling the growth of weeds such as grassy and nutsedge weeds, especially when applied postemergence to the locus of these weeds.Type: GrantFiled: July 14, 1997Date of Patent: March 2, 1999Inventors: Richard J. Anderson, Ian S. Cloudsdale, Robert J. Lamoreaux, Kristine Schaefer, Jost Harr
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Patent number: 5872078Abstract: This invention relates to dry, water soluble, agriculturally acceptable herbicidal compositions, to a herbicidal method of use thereof and and to a process for preparing such compositions. This invention also relates to dry, water soluble and/or water dispersible, agriculturally acceptable herbicidal compositions containing two or more herbicides, a herbicidal method of use thereof and to a process for preparing such compositions.Type: GrantFiled: July 22, 1997Date of Patent: February 16, 1999Assignee: Monsanto Europe S.A.Inventors: Masuo Kuchikata, Erhard J. Prill, Ronald O. Richardson, Tatsuo Sato, John M. Surgant, Daniel R. Wright
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Patent number: 5763495Abstract: Described are .omega.,.omega.'-?.alpha.,.omega.-alkanediylbis(alkylimino)!bis(alkanolpol yethoxylates) in which (i) the alkane group has in the range of 4 to 12 carbon atoms, (ii) the alkyl groups can be the same or different and contain up to about 24 carbon atoms each, and (iii) the number of ethyleneoxy groups in each polyethoxylate group is in the range of 2 to about 50. These compounds are effective adjuvants for use with pesticides, especially herbicides and plant growth regulants, such as glyphosate.Type: GrantFiled: September 30, 1996Date of Patent: June 9, 1998Assignee: Albemarle CorporationInventors: Ralph W. Magin, Joe D. Sauer
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Patent number: 5736486Abstract: This invention relates to herbicidal mixtures of anilofos with propanil, or one or more of the compounds selected from azimsulfuron, metsulfuron methyl, chlorimuron ethyl, bensulfuron methyl, ethametsulfuron methyl, nicosulfuron, rimsulfuron, sulfometuron methyl, thifensulfuron methyl, tribenuron methyl, triflusulfuron methyl, methyl 2-????(4,6-dimethoxy-2-pyrimidinyl)amino!carbonyl!amino!sulfonyl!-6-(trifl uoro-methyl)-3-pyridinecarboxylate, chlorsulfuron, and hexazinone, herbicidal compositions of said mixtures, and a method for the use of said mixtures to control undesired vegetation.Type: GrantFiled: October 27, 1995Date of Patent: April 7, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Thalia Pappas-Fader, Daniel Carl Leep, Marc Ruggiero, William Francis Smith, III, Alexander Yung-Shing Yang
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Patent number: 5700475Abstract: Flowable composites are disclosed which comprise a) microcapsules comprising one or more non-aqueous pesticidally active compositions enclosed in an inert water-soluble wall material; b) a non-aqueous liquid in an amount sufficient to maintain the composite flowable; the non-aqueous pesticidally active composition and the non-aqueous liquid being reactive with each other and the inert water-soluble wall material being insoluble in and impermeable to the non-aqueous liquid and the pesticidally active composition. Also disclosed are composites in which the pesticidally active compositions are internally-reactive in the presence of a non-aqueous liquid or solvent. Processes for production of the composites and their utilization as pesticides are also disclosed.Type: GrantFiled: December 29, 1995Date of Patent: December 23, 1997Assignee: Monsanto CompanyInventors: Brent D. Massman, Maria L. Miller
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Patent number: 5686384Abstract: A compatibility agent comprising a block copolymer of ethylene oxide and propylene oxide comprising about 30-80% ethylene oxide and about 20-70% propylene oxide which has been found useful for making pesticidal compositions compatible when combined.Type: GrantFiled: March 14, 1995Date of Patent: November 11, 1997Assignee: Zeneca LimitedInventor: Dennis M. Hester
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Patent number: 5683959Abstract: Described and claimed are methods and compositions for the control of unwanted vegetation. According to the subject invention, a fatty acid or mixture of fatty acids can be combined with one or more chemical herbicides to achieve synergistic control of a broad range of plants.Type: GrantFiled: June 6, 1995Date of Patent: November 4, 1997Assignee: Mycogen CorporationInventors: Jerry Caulder, R. Hugh Crowley, Paul S. Zorner, Steven L. Evans
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Patent number: 5665672Abstract: Fungicidal compositions for the protection of turfgrass against crown and root rot are disclosed. The compositions comprise, as the active material, a mixture of (a) a monoester salt of a phosphorous acid (preferably aluminum ethyl phosphite), and (b) an ethylene bisdithiocarbamate contact fungicide (preferably manganese-zinc ethylene bisdithiocarbamate). Preferred compsitions comprise one part by weight of the monosester salt to two parts by weight of the ethylene bisdithiocarbamate.Type: GrantFiled: February 1, 1996Date of Patent: September 9, 1997Assignee: North Carolina State UniversityInventor: Leon T. Lucas
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Patent number: 5650373Abstract: Combinations of active substances of the formula (I) ##STR1## (i.e., sulcotrione), with herbicides from the group comprising fenoxaprop-ethyl, fenoxaprop-P-ethyl, quinchlorac, molinate, thiobencarb, butachlor, pretilachlor, mefenacet, esprocarb, dimepiperate, HW-52, cinmethylin, anilophos, benfuresate, triazofenamide, benzofenap, pyrazoxyfen and TFH-450, have advantages on application, for example a synergistic increase in action, in particular in the case of important weeds in cereals, maize and rice.Type: GrantFiled: June 5, 1995Date of Patent: July 22, 1997Assignee: Hoechst AktiengesellschaftInventors: Oswald Ort, Lothar Willms, Hans-Joachim Zeiss, Klaus Bauer, Hermann Bieringer
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Patent number: 5635445Abstract: Granular herbicidal water-soluble composition based either on aminotriazole alone or on aminotriazole combined with at least one other herbicide selected from the group comprising alkaline, alkaline-earth metal and ammonium thiocyanates, glyphosate, MCPA sodium salt, sulfosate, glufosinate, paraquat and metribuzen. It is provided in the form of granules of cylindrical shape, with a composition and a diameter which are substantially identical from one granule of cylindrical shape to another for a given granular herbicidal composition, the diameter and the length of the said granules of cylindrical shape being respectively of the order of 0.4 to 2 mm, preferably of 0.8 to 1.4 mm, and of the order of 5 to 10 millimeters.Type: GrantFiled: July 18, 1995Date of Patent: June 3, 1997Assignee: CFPIInventors: Joseph Schapira, Ange C. Guerin, Jacques Schild, Jean-Jacques Fuchs, Jean-Paul Fournials
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Patent number: 5635447Abstract: A herbicide composition which comprises a herbicide and a small but herbicide absorption enhancing effective amount of a water soluble, non-aromatic polyorganic acid or a salt or copolymer thereof such as polyaspartic acid.Type: GrantFiled: March 22, 1996Date of Patent: June 3, 1997Assignee: Donlar CorporationInventor: J. Larry Sanders
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Patent number: 5597778Abstract: The addition of DMSO to herbicidal compositions makes it possible to decrease the amount of active herbicidal agent required for desired activity without loss of effectiveness against target plants. The most preferred compositions for application to the plates contain 1-2.5% DMSO. However, in some instances, it may be advisable to use as much as 3% DMSO. The addition of the DMSO also results in increased stability to the composition.Type: GrantFiled: June 7, 1995Date of Patent: January 28, 1997Inventor: Bernard Smale
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Patent number: 5565409Abstract: There is disclosed a liquid concentrate herbicidal composition comprising:at least 15% by weight based on the total composition of N-phosphonomethylglycine or of a salt thereof or of a mixture of salts thereof (calculated as acid equivalent);a water-insoluble diphenyl ether type herbicide (oxyfluorfen or acifluorfen) in the ratio by weight of N-phosphonomethylglycine a.e. to diphenyl ether type herbicide of from about 10:1 to about 100:1;about 5 to about 25% by weight of a surface active component comprising a mixture of an alkoxylated fatty amine with a surfactant chemically different from the alkoxylated fatty amine;0 to about 10% by weight of solvent, the surface active component optionally with admixture of the solvent being capable of dissolving the diphenyl ether herbicide;about 1 to about 25% by weight of a compatibility agent; andwater if necessary to total 100%.Type: GrantFiled: March 28, 1994Date of Patent: October 15, 1996Assignee: Monsanto CompanyInventors: Tatsuo Sato, Shuaib A. Khan, Robert W. Mitchell
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Patent number: 5556840Abstract: Optically active compounds of the formula ##STR1## wherein n is 1 or 2 and m is 0, 1, 2 or 3 have antiviral activity. Compounds of the formula wherein at least one of the internecleotide phosphorothioate linkages is of the Sp configuration possess increased antiviral activity and/or metabolic stability.Type: GrantFiled: December 2, 1994Date of Patent: September 17, 1996Assignee: Temple University - Of The Commonwealth System of Higher EducationInventors: Robert J. Suhadolnik, Wolfgang Pfleiderer
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Patent number: 5543562Abstract: A solid, non-hygroscopic salt of the Formula (I) ##STR1## wherein R.sup.1 is hydroxy or alkyl;A is C.sub.1 to C.sub.Type: GrantFiled: April 14, 1995Date of Patent: August 6, 1996Assignee: Monsanto Europe S.A./N.V.Inventors: Fulgencio Powell Moreno, Laszlo Litkei, Vilmos Galamb, Imre Gulyas, Jan os Repasi, Agota Repasine Veres, Jozsef Vigh, Istvanne Koczka, Edit Fehervari, Laszlone Roka, Laszlone Pethe, Jozsef Neu
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Patent number: 5543383Abstract: A herbicidal composition including isocyanate capped high molecular weight diols, triols and polyols. Glyphosate and/or a herbicidally active derivative thereof such as a glyphosate salt is combined with hydrophilic isocyanate end-capped prepolymers in order to significantly improve the efficacy of the herbicide. A combination of surfactant, glyphosate, and a hydrated polymer or hydrophilic prepolymer consisting of isocyanate capped prepolymers which are substantially comprised of ethylene oxide, propylene oxide or butylene oxide units or a combination thereof demonstrates increased efficacy over conventional glyphosate formulations. The liquid herbicidal compositions of the present invention can be prepared by simply mixing the various constituents. The order of addition can be used effectively to cap free isocyanate groups in the hydrophilic prepolymer.Type: GrantFiled: December 30, 1994Date of Patent: August 6, 1996Assignee: Hampshire Chemical Corp.Inventors: Brian A. Parker, Longin V. Holejko
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Patent number: 5543385Abstract: Novel water-dispersible granules of plant protection agents, in particular of herbicides and growth regulators, are obtained when a dispersion or solution in water of 10 to 90% by weight of active substance with 10 to 90% by weight of solid wetting agents from the group containing of alkanesulfonates, alkylsulfonates, alkylnaphthalenesulfonates, alkylbenzenesulfonates, long-chain olefinsulfonates, alkyl polyol ether sulfonates, alkyl ether sulfates, alkyl ether phosphates, alkylsulfosuccinic monoesters, fatty acid isethionates and fatty acid N-methyltaurides, or of an ammonium salt, or of a mixture of an ammonium salt and one or more of the above solid wetting agents, and 0 to 50% by weight of customary formulation agents is prepared and the dispersion or solution is granulated using the cocurrent or counter-current process.Type: GrantFiled: June 28, 1994Date of Patent: August 6, 1996Assignee: Hoechst AktiengesellschaftInventors: Hans Rochling, Jean Kocur, Konrad Albrecht
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Patent number: 5541149Abstract: A composition exhibiting increased defoliation and growth inhibition efficacy comprises the mixture of an amide-sulfuric acid adduct and a phosphonic acid and/or phosphonic acid derivative or salt.Type: GrantFiled: November 7, 1994Date of Patent: July 30, 1996Assignee: Union Oil Company of CaliforniaInventor: Mark L. Atwater
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Patent number: 5525577Abstract: A method minimizing herbicidal injury to agricultural plants and crops while controlling undesirable weeds associated with said agricultural plants comprises applying thereto an effective quantity of N-phosphonomethyl-glycine and 4-trifluoromethyl-4-nitrodiphenyl ether, particularly acifluorfen.Type: GrantFiled: November 17, 1994Date of Patent: June 11, 1996Assignee: BASF CorporationInventors: James C. Turner, Scott W. Gibson
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Patent number: 5457083Abstract: Synergistic antimicrobial combinations of polyether polyamino methylene phosphonates and one or more members selected from the group consisting essentially of the following non-oxidizing biocides:didecyl dimethyl ammonium chloride;dodecylguanidine hydrochloride;methylene bisthiocyanate;2,2-dibromo-3-nitrilo-propionamide;2-(thiocyanomethylthio)benzothiazole glutaraldehyde;potassium dimethyldithiocarbamate;5-chloro-2-methyl-4-isothiazolin-3-one;2-methyl-4-isothiazolin-3-one;tetrahydro-3,5-dimethyl-2,H-1,3,5-thiadiazin-2-thione;1,2-dibromo-2,4-dicyanobutane;are useful for inhibiting microbial growth in a variety of aqueous systems.Type: GrantFiled: October 15, 1992Date of Patent: October 10, 1995Assignee: Calgon CorporationInventors: Ramon A. Muia, Nancy S. Sherwood
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Patent number: 5451562Abstract: A herbicidal composition which comprises a phosphonate or phosphinate of the formula ##STR1## where R and R.sup.1, which may be the same or different, each represent straight or branch-chained alkyl of 1 to 12 carbon atoms, and x and y are each 1 or 2, the sum of x an y being 3; and phenmedipham, desmedipham, metamitron, lenacil, ethofumesate or chloridazon in association with a suitable carrier and/or surface active agent, and a method of combating weeds.Type: GrantFiled: February 28, 1994Date of Patent: September 19, 1995Assignee: Schering AktiengesellschaftInventor: Reinhart Rusch
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Patent number: 5436220Abstract: A conditioner containing a regrowth inhibitor containing glyphosate, sulfosate, or a salt of either is used at 0-50% open boll to condition cotton plants before chemical defoliation to prevent vegetative regrowth after defoliation. The conditioner can also contain at least one of the Krebs cycle acids, preferably an acid-containing extract from pentosan-containing seed hulls, to increase yields of high quality fibers and vigorous seeds.Type: GrantFiled: March 23, 1994Date of Patent: July 25, 1995Assignee: Micro Flo CompanyInventor: Joseph A. Hickey
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Patent number: 5410075Abstract: A solid, non-hygroscopic salt of the Formula (I) ##STR1## wherein R.sup.1 is dydroxy or alkyl;A is C.sub.1 to C.sub.Type: GrantFiled: February 4, 1994Date of Patent: April 25, 1995Assignee: Alkaloida Vegyeszeti Gyar Rt.Inventors: Fulgencio Powell Moreno, Laszlo Litkei, Vilmos Galamb, Imre Gulyas, Janos Repasi, Agota Repasine Veres, Jozsef Vigh, Istvanne Koczka, Edit Fehervari, Laszlone Roka, Laszlone Pethe, Jozsef Neu
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Organophosphorus compounds and insecticidal, acaricidal and nematocidal compositions containing same
Patent number: 5405961Abstract: Insecticidal, acaricidal or nematocidal compositions which comprise a series of organophosphorus compounds represented by the compounds represented by the following structural formulae: ##STR1## show excellent effect for controlling harmful insects, mites and nematodes, do not give off a bad or irritating odor and exhibit very low toxicity to warm-blooded animals.Type: GrantFiled: August 12, 1993Date of Patent: April 11, 1995Assignee: Agro-Kanesho Co., Ltd.Inventors: Katsumi Nanjo, Akinori Kariya, Shinya Henmi -
Patent number: 5397766Abstract: There are provided compositions comprising a concentrated amount of an herbicidally active agent, or combination of agents, in a solid state suspended in a water immiscible solvent containing an anionic surfactant and a nonionic surfactant and optionally containing an antifoam agent and a suspending or thickening agent. Upon dilution with hard or soft water, said compositions readily form sprayable herbicidal emulsions.Type: GrantFiled: August 31, 1993Date of Patent: March 14, 1995Assignee: American Cyanamid CompanyInventor: Robin W. Dexter
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Patent number: 5369082Abstract: The invention relates to comparatively low viscosity aqueous preparations which contain glufosinate and at least one further herbicide active substance dispersed in the aqueous phase, a combination of all .alpha.-olefin sulfonate and co-surfactants such as condensation products based on aromatics, alkanols, formaldehyde and disulfite or condensation products based on naphthalenesulfonic acid or ligninsulfonates being employed as surfactants.Type: GrantFiled: August 23, 1993Date of Patent: November 29, 1994Assignee: Hoechst AktiengesellschaftInventors: Gerhard Frisch, Thomas Maier
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Patent number: 5332714Abstract: The invention relates to defoamed aqueous solutions of surfactants and to low-foam concentrated liquid preparations of plant protection agents, which contain sulfato- or sulfonato-containing surfactants as wetting agents and surfactants from the group comprising the perfluoro(C.sub.6 -C.sub.18)alkylphosphinic acids and/or -alkylphosphonic acids and/or their salts, as defoamer.Type: GrantFiled: July 6, 1990Date of Patent: July 26, 1994Assignee: Hoechst AktiengesellschaftInventors: Konrad Albrecht, Jean Kocur
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Patent number: 5324708Abstract: A solid, non-hygroscopic salt of the Formula (I) ##STR1## wherein R.sup.1 is hydroxy or alkyl;A is C.sub.1 to C.sub.Type: GrantFiled: April 16, 1992Date of Patent: June 28, 1994Assignee: Aklaloida Vegyeszeti Gyar Rt.Inventors: Fulgencio P. Moreno, Laszlo Litkei, Vilmos Galamb, Imre Gulyas, Janos Repasi, Agota R. Veres, Jozsef Vigh, Istavanne Koczka, Edit Fehervari, Laszlone Roka, Laszlone Pethe, Jozsef Neu
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Patent number: 5288692Abstract: Herbicidal compositions having systemic herbicidal activity comprise solutions containing one or more systemic herbicides and an amount of an amide and sulfuric acid of the following formula sufficient to accentuate the activity of the systemic herbicide: ##STR1## wherein X is chalcogen, and each of R.sub.1, R.sub.2 and R.sub.3 is independently selected from hydrogen and organic radicals. As used herein, "amide" encompasses all compounds of formula (1) regardless of the chalcogen employed. The molar ratio of amide to sulfuric acid is usually within the range of about 1/4 to less than 2 so that at least some of the sulfuric acid is present as the monoamide-sulfuric acid adduct. The monoamide adduct also acts as a contact herbicide and thereby assists in the immediate control of treated vegetation. Solid compositions comprising combinations of systemic herbicides, sulfuric acid and the useful amides, with and without surfactants, and methods of using the solutions are also disclosed.Type: GrantFiled: December 27, 1990Date of Patent: February 22, 1994Assignee: Union Oil Company of CaliforniaInventor: Donald C. Young
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Patent number: 5284819Abstract: The subject invention pertains to novel methods and compositions utilizing novel fatty acid esters which exhibit excellent herbicidal activity in controlling unwanted vegetation. The novel compositions and methods described here facilitate effective weed control using a wide range of fatty acids.Type: GrantFiled: May 1, 1992Date of Patent: February 8, 1994Assignee: Mycogen CorporationInventors: Paul S. Zorner, Yasuko Tsujino, Osamu Kamioka
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Patent number: 5258358Abstract: The invention relates to liquid herbicidal compositions comprising a compound of the formula ##STR1## and an alkyl polyglycoside or an alkyl polyglycoside and at least one surfactant from the series comprising fatty alcohol polyglycol ether sulfate, alkyldimethylamine oxide, alkyldimethylbenzylammonium chloride and coconut alkyldimethylaminoacetic acid or a salt thereof. The invention furthermore relates to a process for the preparation of these compositions and their use for controlling undesired vegetation.Type: GrantFiled: April 24, 1992Date of Patent: November 2, 1993Assignee: Hoechst AktiengesellschaftInventors: Jean Kocur, Thomas Maier, Peter Langeluddeke, Martin Hess
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Patent number: 5242891Abstract: The invention described here concerns the unique utility of fatty acids and their derivatives to act as fruit thinning agents. Proper use of the methods and compositions will result in the advantageous thinning of fruit which can improve the quality of the harvested fruit and result in more consistent crops from one year to the next.Type: GrantFiled: May 1, 1992Date of Patent: September 7, 1993Assignee: Mycogen CorporationInventors: Thomas E. Larsen, Kenneth D. Abercrombie, R. Hugh Crowley
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Patent number: 5238904Abstract: The invention relates to comparatively low viscosity aqueous preparations which contain glufosinate and at least one further herbicide active substance dispersed in the aqueous phase, a combination of an .alpha.-olefin sulfonate and co-surfactants such as condensation products based on aromatics, alkanals, formaldehyde and disulfite or condensation products based on naphthalenesulfonic acid or ligninsulfonates being employed as surfactants.Type: GrantFiled: January 17, 1992Date of Patent: August 24, 1993Assignee: Hoechst AktiengesellschaftInventors: Gerhard Frisch, Thomas Maier
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Patent number: 5219825Abstract: The invention relates to synergistic herbicidally active compositions. The quantity required for a given herbicidal effect is substantially lower than that required for the herbicide itself. The compositions of the invention comprise in combination a herbicide which brings about active oxygen species formation in plants and a substance which binds copper or zinc, or a substance which reacts with a thiol moiety of a thiol containing enzyme. The herbicide and metal binding or thiol binding component can be applied together or separately.Type: GrantFiled: November 9, 1987Date of Patent: June 15, 1993Assignee: Yeda Research and Development Co., Ltd.Inventors: Jonathan Gressel, Joseph Shaaltiel
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Patent number: 5196044Abstract: Described and claimed are methods and compositions for the control of unwanted vegetation. According to the subject invention, a fatty acid or mixture of fatty acids can be combined with one or more chemical herbicides to achieve synergistic control of a broad range of plants.Type: GrantFiled: January 8, 1991Date of Patent: March 23, 1993Assignee: Mycogen CorporationInventors: Jerry Caulder, R. Hugh Crowley, Paul S. Zorner, Steven L. Evans