Hetero Ring Is Six-membered Consisting Of Two Nitrogens And Four Carbons (e.g., 1,4-diazines, Etc.) Patents (Class 504/235)
  • Patent number: 5939359
    Abstract: Substituted pyrazine derivatives of the general formula I ##STR1## where X is an oxygen or sulfur atom or a sulfoxyl or sulfonyl group;n is 0, 1 or 2;Z is a group ##STR2## where Y is oxygen or sulfur, R.sup.6 is hydrogen, alkyl, alkoxy, halogen or haloalkyl and p is 0 or 1;and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 have the meanings stated in claim 1,and agriculturally useful salts of the compounds I are useful in herbicides.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: August 17, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Engel, Christoph Nubling, Uwe Kardorff, Jurgen Kast, Wolfgang von Deyn, Peter Plath, Helmut Walter, Karl-Otto Westphalen, Matthias Gerber
  • Patent number: 5919731
    Abstract: The present invention relates to the use of diquat bromide as a root control agent. It is based, at least in part, on the results of green house testing in which application of diquat bromide as a dense foam to tree roots resulted in the destruction of the test roots without causing damage to the upper portion of the trees. Without being bound to any particular theory, it is believed that by applying diquat bromide to produce a high local concentration on the target root, the inactivating effects of local organic substances are overcome, and the diquat bromide kills root tissue by its dessicating activity. The inactivation of diquat bromide by organic materials, under these circumstances, becomes an advantage, as it prevents toxic levels of diquat bromide from traveling downstream from the point of application.
    Type: Grant
    Filed: April 22, 1998
    Date of Patent: July 6, 1999
    Inventors: Anthony Malavenda, Kevin Duke
  • Patent number: 5824624
    Abstract: New herbicidal pyridine and pyrimidine derivatives of general formula (I), ##STR1## wherein Z represents a nitrogen atom or a C--H group; A represents an optionally substituted aryl group or an optionally substituted 5- or 6-membered nitrogen-containing heteroaromatic group; n represents an integer from 0 to 2 and R.sup.1 or each R.sup.1 independently represents a hydrogen atom or an optionally substituted alkyl, alkoxy, alkylthio or dialkylamino group; m represents an integer from 0 to 5 and R.sup.2 or each R.sup.2 independently represents a hydrogen or a halogen atom or an optionally substituted alkyl, haloalkyl, haloalkoxy, alkoxy, alkylthio group or a nitro, cyano or a halosulphonyl group; and X represents an oxygen or sulphur atom.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: October 20, 1998
    Assignee: American Cyanamid Company
    Inventors: Axel Kleeman, Helmut Siegfried Baltruschat, Thelka Hulsen
  • Patent number: 5776858
    Abstract: 1-Azinyl-tetraozolinones of the following formulae (I) and (II): ##STR1## wherein R.sup.1 and R.sup.2 are independently represent alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or optionally substituted phenyl, orR.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, may form a 5- or 6-membered heterocyclic ring which may optionally contain a further heteroatom, and said heterocyclic ring may optionally be benzo-condensed and/or be substituted by one or more of C.sub.1-4 alkyl(s), andR.sup.3 is a 6-membered heterocyclic aromatic group consisting of carbon atoms and 2 or 3 nitrogen atoms, which may optionally be substituted by halogen, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, C.sub.1-4 alkylthio, di(C.sub.1-4 alkyl)amino or phenyl.The compounds of the formula (I) exhibit an excellent herbicidal activity and the compounds of the formula (II) are useful as starting materials in the production of the compounds of the formula (I).
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: July 7, 1998
    Assignee: Nihon Bayer Agrochem K.K.
    Inventors: Toshio Goto, Seishi Ito, Natsuko Minegishi, Tatsuya Yamaoka, Chieko Ueno, Koichi Moriya, Fritz Maurer, Ryo Watanabe
  • Patent number: 5777162
    Abstract: Described herein are compounds of Formula (XX) and Formula (XXIV), shown below, and processes of making same. ##STR1## wherein p is 0 ##STR2## wherein p is 1, and Y is chlorine or bromine.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: July 7, 1998
    Assignee: Zeneca Limited
    Inventors: Ian Richard Matthews, Christopher Richard Ayles Godfrey, John Martin Clough
  • Patent number: 5759956
    Abstract: A compound of the general formula (I) ##STR1## wherein A represents a group of general formula ##STR2## and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, X, Q.sup.2, Q.sup.3, and n are as described in the specification. The compounds of formula (I) are useful as agricultural herbicides.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: June 2, 1998
    Assignee: American Cyanamid Company
    Inventors: Hans-Peter Niedermann, Rudi Eisenacht
  • Patent number: 5750469
    Abstract: Substituted lactic acid derivatives having an N-organic radical in the .beta.-position, of the formula I ##STR1## where substituents R to R.sup.5, X and Y have the meanings mentioned in the description and N is one of the radicals:a) --N.sub.3, --NC, --NCS or --NCOb) ##STR2## where R.sup.14 and R.sup.15 have the meanings described in the descriptionc) ##STR3## in which R.sup.16 is hydrogen, alkyl, haloalkyl, alkenyl, alkynyl, cycloalkyl or unsubstituted or substituted phenyl; andB is a group ##STR4## OR.sup.19 or --NR.sup.14 R.sup.15, where R.sup.14, R.sup.15, R.sup.17 and R.sup.19 have the meanings described in the description, or ##STR5## where R.sup.14 and R.sup.15.sub.1, have the abovementioned meanings; or ##STR6## where R.sup.20 and R.sup.21, which can be identical or different, are: hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl or phenyl, where the organic radicals can in each case be substituted;or R.sup.20 and R.sup.21 together form an unsubstituted or substituted C.sub.4 -C.sub.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: May 12, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Ernst Baumann, Joachim Rheinheimer, Uwe Josef Vogelbacher, Matthias Gerber, Wilhelm Rademacher, Helmut Walter, Karl-Otto Westphalen
  • Patent number: 5747423
    Abstract: The novel 6-thienyl pyridines and 4-thienyl pyrimidines of formula I: ##STR1## (A, R.sub.1 to R.sub.5 and Z are defined in the specification) show selective herbicidal activity.The new compounds can be prepared according to known methods and can be used as herbicides in agriculture and related fields.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: May 5, 1998
    Assignee: American Cyanamid Company
    Inventors: Stefan Scheiblich, Thomas Maier, Helmut Siegfried Baltruschat, Joseph Luke Pont
  • Patent number: 5736487
    Abstract: Compounds of formula (I): ##STR1## (wherein: R.sup.1 is optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy, or optionally substituted alkylthio; R.sup.2 is hydrogen, optionally substituted alkyl, cycloalkyl, optionally substituted alkenyl, optionally substituted alkynyl or a group of formula --YR.sup.7 ; R.sup.3 is optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy group, optionally substituted alkenyl, optionally substituted alkynyl, halogen, nitro or a group of formula --COR.sup.8, wherein R.sup.8 is hydrogen, alkyl, cycloalkyl or alkoxy; R.sup.4 and R.sup.5 are each hydrogen atom or alkyl; R.sup.6 is optionally substituted alkyl, cycloalkyl, optionally substituted alkoxy group, optionally substituted alkenyl, optionally substituted alkynyl, halogen, nitro, or a group of formula --COR.sup.8, as defined above;A, Q and X are each oxygen or sulfur; Y is a group of formula --CO--, --COO--, --CH.sub.2 O--, --CH.sub.2 S--, --CH.sub.2 CH.sub.2 O--, --CH.sub.2 CH.sub.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: April 7, 1998
    Assignee: Sankyo Company, Limited
    Inventors: Soji Sugai, Hiroyuki Komai, Noriaki Kudo, Kazuo Sato, Toyokuni Honma, Junji Kadotani, Kiyoshi Koi, Mitsuru Ito
  • Patent number: 5686393
    Abstract: Described herein are arthropodicidal compounds, compositions and use of compounds of Formula (I) wherein the substituents are defined in the disclosure ##STR1##
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: November 11, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: George Philip Lahm, Thomas Martin Stevenson
  • Patent number: 5679623
    Abstract: Compounds of the formula ##STR1## in which R.sub.l, R.sub.2, R.sub.3, R.sub.4, Y and Z are as defined in claim 1, and, if appropriate, the tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 21, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Henry Szczepanski, Haukur Kristinsson
  • Patent number: 5674811
    Abstract: A cyanoketone derivatives of the following formula (1) ##STR1## which are characterized by excellent herbicidal activity and effectiveness against a variety of broad leafed weeds, including barnyard grass, green foxtail, velvet leaf, livid amaranth and hairy beggar ticks.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: October 7, 1997
    Assignee: Tokuyama Corporation
    Inventors: Toshio Kitajima, Tadashi Kobutani, Shozo Kato, Masao Yamaguchi, Masahiko Ishizaki, deceased
  • Patent number: 5670453
    Abstract: Herbicidal substituted hydroxybenzyl-heteroaryl compounds and derivatives thereof of the formula ##STR1## wherein Ar is a substituted or unsubstituted 5- or 6-membered heteroaryl group having 2 or 3 ring nitrogen atoms or a substituted or unsubstituted 5-membered heteroaryl group having two ring heteroatoms, one of the ring heteroatoms being nitrogen and the other being sulfur or oxygen. Herbicidal compositions containing such substituted hydroxybenzyl-heteroaryl compounds and derivatives thereof and methods of controlling undesirable vegetation employing these compounds and derivatives are also disclosed. The compounds in which XR is hydroxyl are also useful as intermediates for producing the disclosed substituted hydroxybenzyl-heteroaryl derivatives.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 23, 1997
    Assignee: Zeneca Limited
    Inventors: Hsiao-Ling M. Chin, Yi-Qiu Wei, Nhan H. Nguyen, David B. Kanne
  • Patent number: 5668086
    Abstract: The present invention relates to a herbicide composition comprising (a) paraquat and/or diquat, (b) an anionic surfactant and (c) a chelating agent, wherein a molar ratio (c)/(a) of the component (c) to the component (a) is 0.1-3. The herbicidal effect is markedly enhanced by the incorporation of the chelating agent.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: September 16, 1997
    Assignee: Kao Corporation
    Inventors: Suzuki Tadayuki, Hasabe Keiko, Kurita Kazuhiko, Hioki Yuichi
  • Patent number: 5654257
    Abstract: 1-cycloalkenyltetrazolinone derivatives of the following herbicidal formula ##STR1## R.sup.1 is cycloalkenyl which may optionally be substituted by halogen C.sub.1-4 alkyl, or bicycloalkenyl which may optionally be substituted by halogen or C.sub.1-4 alkyl, andR.sup.2 and R.sup.3 each independently is alkyl, cycloalkyl, phenyl (optionally substituted by a member selected from the group consisting of nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and alkylthio), alkenyl and alkynyl,orR.sup.2 and R.sup.3 together with the N-atom to which they are bonded form, a 5- or 6-membered heterocyclic ring which may optionally contain a further hetero atom, said heterocyclic ring optionally being benzo-condensed, or a C-.sub.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: August 5, 1997
    Assignee: Nihon Bayer Agrochem K.K.
    Inventors: Toshio Goto, Yoshinori Kitagawa, Seishi Ito, Katsuhiko Shibuya, Tatsuya Yamaoka, Chieko Ueno, Yoshiko Kyo
  • Patent number: 5643855
    Abstract: Compounds such as Formula I having herbicidal utility are disclosed: ##STR1## wherein Q is ##STR2## R.sub.1 is H; alkyl, haloalkyl or halogen R.sup.2 is C.sub.1 -C.sub.2 alkyl optionally substituted with one or more halogens, OR.sup.8, CN, COR.sup.9, CO.sub.2 R.sup.31 or CONR.sup.32 R.sup.33 ; CN; CO.sub.2 R.sup.34 ; CONR.sup.35 R.sup.36 ; S(O).sub.n R.sup.8 ; S(O).sub.n NR.sup.19 R.sup.8 or COR.sup.37 ; orR.sup.1 and R.sup.2 can be taken together along with the carbon to which they are attached to form C.dbd.CHCO.sub.2 R.sup.31 ; C.dbd.(CH.sub.3)CO.sub.2 R.sup.31 ; C.dbd.(C.sub.2 H.sub.5)CO.sub.2 R.sup.31 ; C.dbd.CHCONR.sup.32 R.sup.33 ; C.dbd.C(CH.sub.3)CONR.sup.32 R.sup.33 or C.dbd.C(C.sub.2 H.sub.5)CONR.sup.32 R.sup.33.
    Type: Grant
    Filed: June 15, 1995
    Date of Patent: July 1, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: John Jolly Kilama
  • Patent number: 5641727
    Abstract: Herbicidal tetrazolinone derivatives of the formula: ##STR1## in which R.sup.1 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, andR.sup.2 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, orR.sup.1 and R.sup.2 together with the nitrogen atom to which they are bonded form an optionally benzofused heterocyclic ring, which is optionally substituted by C.sub.1-4 alkyl,n is 0, 1, 2 or 3, andR.sup.3 each independently is nitro, halogen, alkyl, haloalkyl, alkylthio or phenoxy.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: June 24, 1997
    Assignee: Nihon Bayer Agrochem K.K.
    Inventors: Toshio Goto, Koichi Moriya, Fritz Maurer, Seishi Ito, Katsuaki Wada, Kazuhiro Ukawa, Ryo Watanabe, Asami Ito
  • Patent number: 5633218
    Abstract: Compounds of Formula I, and their N-oxides and agriculturally-suitable salts, are disclosed which are useful for controlling undesired vegetation ##STR1## wherein: ##STR2## T is O or S; W is a single bond, O, S or NR.sup.6 ;X is N or CH;Y is N or CH;Z is N or CR.sup.7 provided that when Z is CR.sup.7, then Y is N;R.sup.6 is H, CH.sub.3 or OCH.sub.3 ;m is 1 or 2; andR.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.7 are as defined in the disclosure.Also disclosed are compositions containing the compounds of Formula I and a method for controlling undesired vegetation which involves contacting the vegetation or its environment with an effective amount of a compound of Formula I.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: May 27, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Donna L. Spedding, Thomas M. Stevenson
  • Patent number: 5629265
    Abstract: Disclosed herein are cyanoketone derivatives of the following formula (1) ##STR1## such as 1-cyano-1-piperidinocarbonyl-3-[4-(2-chloro-4-trifluoromethylphenoxy)pheno xy]-2-butanone, 1-cyano-1-piperidinocarbonyl-3-[4-(3-chloro-5-trifluoromethyl-2-pyridyloxy )phenoxy]-2-butanone, 1-cyano-1-(N-methyl-N-dichlorophenyl)aminocarbonyl-3-[4-(2-quinoxalyloxy)p henoxy]-2-butanone, 1-cyano-1-(N,N-dibutyl)aminocarbonyl-3-[4-(3-chloro-5-trifluoromethyl-2-py ridyloxy)phenoxy-2-butanone, and the like, which are characterized by excellent herbicidal activity and effectiveness against a variety of gramineous weeds.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: May 13, 1997
    Assignee: Tokuyama Corporation
    Inventors: Masahiko Ishizaki, Seiji Nagata, Junji Takenaka
  • Patent number: 5618775
    Abstract: Mixtures of optically active cyclohexenone oxime ethers having R- and S-configuration in the oxime ether moiety of the formula I ##STR1## (R.sup.1 =C.sub.1 -C.sub.6 -alkyl; ##STR2## X=C.sub.1-C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl; m=0-3 or 1-4 where all X's are halogen;n=0-3 or 1-5 where all X's are halogen;R.sup.2 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkenyl, substituted or unsubstituted 5-membered saturated heterocyclic structure, substituted or unsubstituted 6- or 7-membered heterocyclic structure, substituted or unsubstituted 5-membered heteroaromatic structure, substituted or unsubstituted phenyl or pyridyl)and their agriculturally useful salts and esters with C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: April 8, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Wolfgang Ladner, Helmut Walter, Karl-Otto Westphalen, Uwe Kardorff, Matthias Gerber
  • Patent number: 5602075
    Abstract: Substituted N-aryl[1,2,4]triazolo[1,5-a]-pyrazine-2-sulfonamide compounds, such as 5-bromo-N-(2,6-dichlorophenyl)-8-methoxy[1,2,4]triazolo[1,5-a]-pyrazine-2- sulfonamide, were prepared by condensation of a substituted 2-chlorosulfonyl[1,2,4]triazolo[1,5-a]pyrazine compound, such as 5-bromo-2-chlorosulfonyl-8-methoxy[1,2,4]triazolo[1,5-a]pyrazine with a substituted arylamine compound, such as 2,6-dichloroaniline, and found to possess herbicidal utility.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: February 11, 1997
    Assignee: DowElanco
    Inventors: Zoltan Benko, John J. Jachetta, Mark J. Costales, Kim E. Arndt
  • Patent number: 5578622
    Abstract: As isothiazole derivative represented by the formula (I), ##STR1## wherein R.sup.1, R.sup.2, Y and Z have the same meanings as defined in the description of the specification, and it is useful as an active ingredient for fungicidal and/or bactericidal compositions for use in industry, agriculture and medical treatment.
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: November 26, 1996
    Assignee: Asamura Patent Office
    Inventors: Kenichi Ikeda, Katsutoshi Endo, Tsutomu Nishiguchi, Yoshimi Niwano
  • Patent number: 5556829
    Abstract: Compounds of formula ##STR1## wherein R, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and X have the meanings reported in the description, can be used in compositions for agricultural use in particular as herbicides in the defense of useful crops from weeds.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: September 17, 1996
    Assignees: Zambon Group S.p.A., Agrimont S.p.A.
    Inventors: Giovanni Camaggi, Dario Chiarino, Mario Fantucci, Giovanni Meazza
  • Patent number: 5554581
    Abstract: The present invention relates to 3,4,5,6-tetrahydrophthalamide derivatives and 3,4,5,6-tetrahydroisophthalimide derivatives having excellent effects as effective active ingredients of herbicides, and processes for preparing the same, and provides the compounds having a more efficient herbicidal activity, and efficient and industrial processes for the preparation thereof.More specifically, the tetrahydrophthalimide derivative obtained by reacting a halogen-substituted 5-cycloalkyloxyaniline derivative with a 3,4,5,6-tetrahydrophthalic anhydride, or the tetrahydroisophthalimide derivative of the present invention is reacted with various types of amines to prepare a tetrahydrophthalamide derivative represented by the general formula (I): ##STR1## These tetrahydrophthalamide derivatives and the tetrahydroisophthalimide derivatives exhibit excellent herbicidal activities in the soil treatment in the paddy field and field and the stem-foliar treatment.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: September 10, 1996
    Assignees: Sagami Chemical Research Center, Kaken Pharmaceutical Co., Ltd.
    Inventors: Kenji Hirai, Tomoko Matsukawa, Tomoyuki Yano, Emiko Ejiri, Kiyomi Aizawa, Koichi Shikakura, Tomoko Yoshii, Sadayuki Ugai, Osamu Yamada, Shigeki Kishi
  • Patent number: 5534484
    Abstract: There are provided novel (2-imidazolin-2-yl) fused heteropyridine compounds, and intermediate compounds for the preparation thereof, and a method for controlling a wide variety of annual and perennial plant species therewith.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: July 9, 1996
    Assignee: American Cyanamid Company
    Inventors: Barrington Cross, Marinus Los, Robert F. Doehner, Jr., David W. Ladner, Jerry L. Johnson
  • Patent number: 5532207
    Abstract: There are provided novel (2-imidazolin-2-yl) fused heteropyridine compounds, and intermediate compounds for the preparation thereof, and a method for controlling a wide variety of annual and perennial plant species therewith.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: July 2, 1996
    Assignee: American Cyanamid Company
    Inventors: Barrington Cross, Marinus Los, Robert F. Doehner, Jr., David W. Ladner, Jerry L. Johnson
  • Patent number: 5529975
    Abstract: The systemic activity of systemic active ingredients in sprayed foliar systemic compositions is improved by incorporating water soluble polyacrylamide in the sprayed composition. The polyacrylamide can have a molecular weight sufficiently low that its presence does not substantially affect the spray pattern of the composition, and the polyacrylamide can have low solution viscosity such that a convenient concentrate can comprise an aqueous solution of the active ingredient and the polymer. Alternatively, the polymer can be supplied as a powder or as a reverse phase emulsion or dispersion. The sprayable composition is preferably formulated such that the spray droplets have a small particle size.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: June 25, 1996
    Assignee: Allied Colloids Limited
    Inventor: Peter Chamberlain
  • Patent number: 5525575
    Abstract: The systemic activity of systemic active ingredients in sprayed foliar systemic compositions is improved by incorporating water soluble polymer. The polymer can have a molecular weight sufficiently low that its presence does not substantially affect the spray pattern of the composition and such that the polymer can initially be supplied as an aqueous solution having 1 to 25% concentration. When the active ingredient is water soluble, for instance glyphosate or chlormequat, a concentrate can comprise an aqueous solution of the active ingredient and the polymer.
    Type: Grant
    Filed: May 24, 1993
    Date of Patent: June 11, 1996
    Assignee: Allied Colloids Limited
    Inventor: Peter Chamberlain
  • Patent number: 5521145
    Abstract: There is disclosed an iminothiazoline derivative of the general formula: ##STR1## wherein R.sub.1 is (halo)alkyl, (halo)alkenyl, (halo)alkynyl or the like; R.sub.2 is (halo)alkyl, optionally substituted aryl, formyl, cyano or the like; R.sub.3 is hydrogen, (halo)alkyl or the like; and Q is a group of the particular general formula. Also disclosed are a herbicide containing a herbicidally effective amount of the iminothiazoline derivative and a method for controlling unfavorable weeds, which includes applying a herbicidally effective amount of the iminothiazoline derivative to an area where the unfavorable weeds grow or will grow.
    Type: Grant
    Filed: April 3, 1995
    Date of Patent: May 28, 1996
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Minoru Takano, Masayuki Enomoto, Kazuo Saito, Satoru Kizawa
  • Patent number: 5518989
    Abstract: An increase in the quality of maize seed, especially with respect to improved seed vigor, is achieved by defoliating maize plants during a specific period after pollination. A maize seed assemblage then is obtained that is characterized by an enhanced seed vigor.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: May 21, 1996
    Assignee: Pioneer Hi-Bred International
    Inventors: Barry Martin, John Schoper, Laurie Carrigan
  • Patent number: 5506190
    Abstract: The present invention relates to 3,4,5,6-tetrahydrophthalamide derivatives and 3,4,5,6-tetrahydroisophthalimide derivatives having excellent effects as effective active ingredients of herbicides, and processes for preparing the same, and provides the compounds having a more efficient herbicidal activity, and efficient and industrial processes for the preparation thereof.More specifically, the tetrahydrophthalimide derivative obtained by reacting a halogen-substituted 5-cycloalkyloxyaniline derivative with a 3,4,5,6-tetrahydrophthalic anhydride, or the tetrahydroisophthalimide derivative of the present invention is reacted with various types of amines to prepare a tetrahydrophthalamide derivative represented by the general formula (I): ##STR1## These tetrahydrophthalamide derivatives and the tetrahydroisophthalimide derivatives exhibit excellent herbicidal activities in the soil treatment in the paddy field and field and the stem-foliar treatment.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: April 9, 1996
    Assignees: Sagami Chemical Research Center, Kaken Pharmaceutical Co. Ltd.
    Inventors: Kenji Hirai, Tomoko Matsukawa, Tomoyuki Yano, Emiko Ejiri, Kiyomi Aizawa, Koichi Shikakura, Tomoko Yoshii, Sadayuki Ugai, Osamu Yamada, Shigeki Kishi
  • Patent number: 5474973
    Abstract: Heterocyclic-alkylene guinoxalinyloxyphenoxypropanoate compounds exhibit unexpectedly desirable selective herbicidal activity. Also disclosed are compositions comprising such compounds as well as a method of controlling the growth of undesirable plants employing such compounds.
    Type: Grant
    Filed: March 29, 1994
    Date of Patent: December 12, 1995
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Robert G. Davis, Allyn R. Bell, John A. Minatelli
  • Patent number: 5451563
    Abstract: Fungicidal heterocyclic silyl compounds of the general formula ##STR1## have been discovered wherein Het is a six membered heterocyclic moiety; R is hydrogen or a trisubstituted silyl group; R.sup.1, R.sup.2 and R.sup.3 are independently selected from substituted or unsubstituted alkyl, alkenyl, alkynyl, aryl, arylalkyl or pyridyl groups; m is 0 or 1 and n is zero, one or two.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: September 19, 1995
    Assignee: Rohm and Haas Company
    Inventors: Steven H. Shaber, Edward M. Szapacs, Reynolds Charles H.
  • Patent number: 5441924
    Abstract: Substituted triazolinones of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and X having the meanings defined in the specification, are useful as herbicides.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: August 15, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt Findeisen, Hans-Joachim Santel, Klaus Lurssen, Robert R. Schmidt
  • Patent number: 5424275
    Abstract: Novel biphenyl derivatives represented by the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, X.sup.1, X.sup.2, X.sup.3 and Y are as defined hereinafter.
    Type: Grant
    Filed: October 14, 1993
    Date of Patent: June 13, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Mitsunori Hiratsuka, Toru Uekawa, Naonori Hirata, Kazuo Saito, Hiroyuki Yogai
  • Patent number: 5407901
    Abstract: This patent application relates to Certain tricyclic ether herbicidal compounds and their use to control a broad spectrum of undesirable plant growth.
    Type: Grant
    Filed: November 16, 1993
    Date of Patent: April 18, 1995
    Assignee: E. I. Du Pont de Nemours
    Inventor: Eric de G. Taylor
  • Patent number: 5405830
    Abstract: This invention relates to certain herbicidal ethers, agriculturally suitable compositions thereof, and a method for their use as broad spectrum preemergent or postemergent herbicides.
    Type: Grant
    Filed: July 29, 1993
    Date of Patent: April 11, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Alan R. Rendina, Wendy S. Taylor
  • Patent number: 5366955
    Abstract: There are disclosed novel pyrimidone derivatives of the formula I: ##STR1## wherein X is hydrogen, chlorine, methyl or ethyl, R.sup.2 is hydrogen or methyl, and Q is ##STR2## A is fluorine, chlorine or bromine; and R.sup.1 is alkyl, alkenyl, alkynyl, alkoxyalkyl or haloalkyl.Also disclosed are a herbicidal composition containing a herbicidally effective amount of the compound (I) as an active ingredient and a method for exterminating undesired weeds by applying a herbicidally effective amount of the compound (I) to an area where the undesired weeds grow or will grow.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: November 22, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Eiki Nagano, Susumu Takemura, Masayuki Enomoto, Masaharu Sakaki, Satoru Kizawa
  • Patent number: 5364831
    Abstract: Quinoxaline derivatives having the formula I ##STR1## wherein X represents a halogen atom; R represents ##STR2## --CH.dbd.CH--COOR.sup.2 (R.sup.2 represents a C.sub.1 -C.sub.4 alkyl group); --CN or --CH.sub.2 OH, and R.sup.1 represents ##STR3## --S--R.sup.3 (R.sup.3 represents a C.sub.1 -C.sub.4 alkyl or alkenyl group or phenyl or chlorophenyl group), --NH--R.sup.4 (R.sup.4 represents a C.sub.1 -C.sub.4 alkoxy carbonylalkyl group, hydroxy alkyl group, phenyl group; C.sub.1 -C.sub.4 alkoxy alkyl group or di C.sub.1 -C.sub.4 alkyl amino group), are remarkably effective as selective herbicides.
    Type: Grant
    Filed: August 6, 1980
    Date of Patent: November 15, 1994
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Yasukazu Ura, Gozyo Sakata, Kenzi Makino, Yasuo Kawamura, Yuzi Kawamura, Takasi Ikai, Tosihiko Oguti
  • Patent number: 5354729
    Abstract: The present invention relates to novel N-acyldihydroquinoline derivatives, a method for producing the same and their use as herbicides.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: October 11, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Toru Uekawa, Mitsunori Hiratsuka, Naonori Hirata, Kazuo Saito, Hiroyuki Yogai
  • Patent number: 5326743
    Abstract: Piperazine-2,3-diones of the formula I ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is alkyl, alkenyl or alkynyl, where these groups may carry from one to five halogen atoms;monocyclic or polycyclic cycloalkyl, cycloalkenyl, cycloalkylmethyl or cycloalkenylmethyl, where the rings may carry from one to three alkyl groups or a phenyl ring; orphenyl, phenylalkyl or phenylalkenyl, where the aromatic radicals may carry from one to five halogen atoms and/or from one to three of the following groups: nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio,methods for their manufacture, agents containing them and the use thereof.
    Type: Grant
    Filed: August 6, 1993
    Date of Patent: July 5, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Costin Rentzea, Albrecht Harreus, Andreas Landes, Helmut Walter, Wilhelm Rademacher
  • Patent number: 5304530
    Abstract: The invention provides compounds of formula I ##STR1## wherein W, D, R.sup.1, R.sup.2, R.sup.3, X, m, n and p are as defined in the description. The compound have valuable pesticidal activity especially against fungi, insects, nematodes, acarids and weeds.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: April 19, 1994
    Assignee: Schering Agrochemicals Limited
    Inventors: Geoffrey R. Cliff, Ian C. Richards
  • Patent number: 5280009
    Abstract: Pyrimidine derivatives of the Formula Ia or Ib ##STR1## where the substituents have the following meanings: R.sup.1 is hydrogen or alkyl;A is a substituted or unsubstituted bi- or tricyclic carbo- or heterocyclic radical which may contain one or several double bonds;R.sup.5 is H or alkyl;X is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or haloalkylthio; and addition salts thereof with organic or inorganic acids and the use of said pyrimidine derivative to control undesirable plant growth.
    Type: Grant
    Filed: July 16, 1992
    Date of Patent: January 18, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Hamprecht, Klaus Ditrich, Karl-Otto Westphalen, Matthias Gerber, Helmut Walter
  • Patent number: 5278134
    Abstract: The present invention relates to new 3-(aminooxoacetyl)-2-(2-imidazolin-2-yl)pyridines and their salts, having herbicidal activity.
    Type: Grant
    Filed: October 27, 1992
    Date of Patent: January 11, 1994
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Dae W. Kim, Hae S. Chang, Dong J. Jeon, Jae W. Ryu, In T. Hwang
  • Patent number: 5256633
    Abstract: Oxazole- and thiazolecarboxamides of the formulae Ia and Ib ##STR1## where the substituents have the following meanings: oxygen or sulfur;hydrogen; halogen; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, benzyl, cycloalkyl, alkenyl, alkynyl, phenyl, phenoxy or phenylthio; alkoxy; alkylthio; haloalkoxy; haloalkylthio; or a substituted or unsubstituted 5- or 6-membered heterocyclic radical;formyl, 4,5-dihydrooxazol-2-yl or --COYR.sup.5 ;oxygen or sulfur;hydrogen; cycloalkyl; substituted or unsubstituted alkyl, phenyl, benzyl, alkenyl, cycloalkenyl or alkynyl; a substituted or unsubstituted 5- or 6-membered heterocyclic radical; phthalimido; tetrahydrophthalimido; succinimido; maleiimido; one equivalent of a cation; or--N.dbd.CR.sup.6 R.sup.7 ;R.sup.6, R.sup.7 hydrogen; alkyl; cycloalkyl; phenyl; furyl or together a methylene chain or 4 to 7 members;hydrogen or substituted or unsubstituted alkyl or cycloalkyl;R.sup.
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: October 26, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Ditrich, Volker Maywald, Gerhard Hamprecht, Albrecht Harreus, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5252538
    Abstract: There are provided novel (2-imidazolin-2-yl) fused heteropyridine compounds, and intermediate compounds for the preparation thereof, and a method for controlling a wide variety of annual and perennial plant species therewith.
    Type: Grant
    Filed: January 16, 1990
    Date of Patent: October 12, 1993
    Assignee: American Cyanamid Company
    Inventors: Barrington Cross, Marinus Los, Robert F. Doehner, Jr., David W. Ladner, Jerry L. Johnson, Michael E. Jung, Victor M. Kamhi, Shin-Shyong Tseng, John M. Finn, Peter J. Wepplo
  • Patent number: 5244893
    Abstract: New compounds of the formula (I) ##STR1## in which R.sup.1 -R.sup.6 have the meanings given in the description, their preparation and use in plant protection, the protection of materials and in the field of human and veterinary medicine.Formula (I) gives a definition of the compounds which can be prepared by analogous processes, for example from suitable benzothiophene derivatives by oxidation.
    Type: Grant
    Filed: April 29, 1992
    Date of Patent: September 14, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Ludwig Elbe, Dieter Berg, Heinz-Wilhelm Dehne, Stefan Dutzmann, Georg-Wilhelm Ludwig, Manfred Plempel
  • Patent number: 5234894
    Abstract: A cyanoketone derivative of the following formula (1) ##STR1## wherein A.sub.1 is a substituted or unsubstituted phenyl or naphthyl group or a substituted or unsubstituted heterocyclic group;each of X.sub.1, X.sub.2 and X.sub.3 is independently an oxygen or sulfur atom;each of B.sub.1, B.sub.2 and B.sub.3 is independently a hydrogen atom or C.sub.1 -C.sub.6 -alkyl group;each of Y.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 is independently a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.6 -alkyl group; andA.sub.2 is a substituted or unsubstituted group selected from the group consisting of a C.sub.1 -C.sub.6 -alkyl group, a C.sub.2 -C.sub.6 -alkenyl group, a C.sub.2 -C.sub.6 -alkynyl group, a C.sub.1 -C.sub.4 -alkoxy group, a C.sub.1 -C.sub.4 -alkylthio group, a C.sub.1 -C.sub.6 -alkoxycarbonyl group, an unsubstituted benzoyl group, a halogen-substituted benzoyl group, a cyano group or a group as defined in A.sub.1 ;provided that when B.sub.1 is a hydrogen atom and B.sub.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: August 10, 1993
    Assignee: Tokuyama Soda Kabushiki Kaisha
    Inventors: Masahiko Ishizaki, Seiji Nagata, Tadashi Kobutani
  • Patent number: 5223018
    Abstract: The invention relates to new 1-phenyl-piperidine-2,6-diones of the formula I ##STR1## wherein R is C.sub.3 -C.sub.7 -cycloalkyl,R.sub.1 is hydrogen or halogen;R.sub.2 is hydrogen, cyano, nitro or halogen; andA is hydrogen, cyano, nitro or is an ether or carboxylic acid radical as defined in the description. The salts, complexes as well as the stereoisomeric forms of these compounds, their preparations, use and agrochemical compositions which contains them form also part of this invention.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: June 29, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Moser, Georg Pissiotas, Hans-Georg Brunner
  • Patent number: 5221744
    Abstract: Arylaminocarbonyl compounds of the formula (I) ##STR1## wherein R.sub.2-6, X.sub.1, A and m are as defined in the disclosure, intermediates therefore, synthesis thereof, and the use of said compounds for the control of weeds are described.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: June 22, 1993
    Assignee: Sandoz Ltd.
    Inventors: Karl Seckinger, Karlheinz Milzner, Fred Kuhnen, Sasank S. Mohanty