Plural Ring Nitrogens In The Additional Hetero Ring Patents (Class 504/253)
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Patent number: 5707936Abstract: Methyl .alpha.-phenylbutenoates of the formula I ##STR1## where -- is a single or double bond and the index and the substituents have the following meanings:n is 0, 1, 2, 3 or 4;R.sup.1 is nitro, cyano, halogen, alkyl, haloalkyl or alkoxy;R.sup.2 is hydrogen, nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, alkylthio or alkoxycarbonyl;R.sup.3 is unsubst. or subst. alkyl, alkenyl or alkynyl;an unsubst. or subst. saturated or mono-or diunsaturated ring which, in addition to carbon atoms, can contain one to three of the following heteroatoms as ring members: oxygen, sulfur and nitrogen, oran unsubst. or subst. mono- or binuclear aromatic radical which, in addition to carbon atoms, can contain one to four nitrogen atoms or one or two nitrogen atoms and an oxygen or sulfur atom or an oxygen or sulfur atom as ring members,processes for their preparation and their use are described.Type: GrantFiled: October 31, 1996Date of Patent: January 13, 1998Assignee: BASF AktiengesellschaftInventors: Klaus Oberdorf, Hartmann Konig, Bernd Muller, Reinhard Kirstgen, Wassilios Grammenos, Hubert Sauter, Gisela Lorenz, Eberhard Ammermann, Volker Harries
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Patent number: 5707934Abstract: This invention relates to a new method of plant growth regulation whereby a 1-phenylpyrazole such as fipronil is applied to a crop or a seed.Type: GrantFiled: March 27, 1996Date of Patent: January 13, 1998Assignee: Rhone-Poulenc Inc.Inventors: Reed Nathan Royalty, Nguyen Dang Long, Michael Thomas Pilato, Nicholas Mark Hamon, Ngadi Yahmad, Djoko Prabowo Sastrosatomo
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Patent number: 5705454Abstract: The present invention relates to chemical compositions comprising imidazolinone compounds that are suitable for use in turfgrass management. The invention also provides methods for altering the growth and reducing mowing frequency, suppressing seed head formation and controlling undesirable vegetation in turfgrass.Type: GrantFiled: May 26, 1995Date of Patent: January 6, 1998Assignee: American Cyanamid CompanyInventors: Prithvi Raj Bhalla, Robert Michael Herrick, Donald Wakeford Gates
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Patent number: 5696024Abstract: The present invention provides a solid water soluble granular composition which comprises an imidazolinone herbicide alone or in combination with a second herbicide and a base, preferably wherein the base is present at a ratio of about 0.9 to 2.0 molar equivalents of base to molar equivalents of imidazolinone herbicide. Said composition is storage stable and dissolves rapidly and essentially completely in water for even application to target surfaces.Type: GrantFiled: June 6, 1995Date of Patent: December 9, 1997Assignee: American CyanmidInventors: Janos Szamosi, Mimi Schaaf
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Patent number: 5679623Abstract: Compounds of the formula ##STR1## in which R.sub.l, R.sub.2, R.sub.3, R.sub.4, Y and Z are as defined in claim 1, and, if appropriate, the tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.Type: GrantFiled: June 2, 1995Date of Patent: October 21, 1997Assignee: Ciba-Geigy CorporationInventors: Henry Szczepanski, Haukur Kristinsson
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Patent number: 5658855Abstract: Adjuvant compositions for herbicides comprising amine or ammonia compounds for adjusting the pH to the alkaline range, a neutral water soluble compound to provide a fertilizer action and a non-ionic surfactant and water. Herbicidal compositions using the adjuvant in combination with the herbicide are also included as well as methods for controlling weeds or undesirable vegetation by application of those compositions thereto.Type: GrantFiled: September 26, 1996Date of Patent: August 19, 1997Assignee: North Dakota State UniversityInventors: John D. Nalewaja, Robert Matysiak, Zenon Woznica
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Patent number: 5643854Abstract: Disclosed herein are herbicidal pyridine compounds substituted at the 2- or 6-position with an OR.sub.2 moiety where R.sub.2 is hydrogen, lower alkyl, halomethyl, lower cyanoalkyl, alkenyl or alkynyl, as well as herbicidal compositions and herbicidal use of these compounds.Type: GrantFiled: June 6, 1995Date of Patent: July 1, 1997Assignee: Rohm and Haas CompanyInventors: Donald Edwin Korte, Len Fang Lee
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Patent number: 5641727Abstract: Herbicidal tetrazolinone derivatives of the formula: ##STR1## in which R.sup.1 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, andR.sup.2 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, orR.sup.1 and R.sup.2 together with the nitrogen atom to which they are bonded form an optionally benzofused heterocyclic ring, which is optionally substituted by C.sub.1-4 alkyl,n is 0, 1, 2 or 3, andR.sup.3 each independently is nitro, halogen, alkyl, haloalkyl, alkylthio or phenoxy.Type: GrantFiled: July 6, 1995Date of Patent: June 24, 1997Assignee: Nihon Bayer Agrochem K.K.Inventors: Toshio Goto, Koichi Moriya, Fritz Maurer, Seishi Ito, Katsuaki Wada, Kazuhiro Ukawa, Ryo Watanabe, Asami Ito
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Patent number: 5622917Abstract: The invention relates to new 1H-3-aryl-pyrrolidine-2,4-dione derivatives of the formula (I) ##STR1## in which A, B, X, Y and G have the meanings given in the description, to a plurality of processes for their preparation, and to their use as pesticides.Type: GrantFiled: January 3, 1995Date of Patent: April 22, 1997Assignee: Bayer AktiengesellschaftInventors: Reiner Fischer, Thomas Bretschneider, Bernd-Wieland Kr uger, Michael Ruther, Christoph Erdelen, Ulrike Wachendorff-Neumann, Hans-Joachim Santel, Markus Dollinger
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Patent number: 5618775Abstract: Mixtures of optically active cyclohexenone oxime ethers having R- and S-configuration in the oxime ether moiety of the formula I ##STR1## (R.sup.1 =C.sub.1 -C.sub.6 -alkyl; ##STR2## X=C.sub.1-C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl; m=0-3 or 1-4 where all X's are halogen;n=0-3 or 1-5 where all X's are halogen;R.sup.2 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkenyl, substituted or unsubstituted 5-membered saturated heterocyclic structure, substituted or unsubstituted 6- or 7-membered heterocyclic structure, substituted or unsubstituted 5-membered heteroaromatic structure, substituted or unsubstituted phenyl or pyridyl)and their agriculturally useful salts and esters with C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids.Type: GrantFiled: August 11, 1994Date of Patent: April 8, 1997Assignee: BASF AktiengesellschaftInventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Wolfgang Ladner, Helmut Walter, Karl-Otto Westphalen, Uwe Kardorff, Matthias Gerber
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Patent number: 5607898Abstract: The present invention relates to pyrazole derivatives of the formula (I), ##STR1## wherein R.sup.1, R.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, p and n are as defined on claim 1, or a salt thereof, and herbicides containing them as active ingredients.Type: GrantFiled: February 1, 1996Date of Patent: March 4, 1997Assignee: Idemitsu Kosan Company, Ltd.Inventors: Kazufumi Nakamura, Kazuyoshi Koike, Masashi Sakamoto, Ichiro Nasuno
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Patent number: 5589437Abstract: It has been discovered that certain hydroxybenzimidazole compounds provide beneficial characteristics to certain agricultural species. Treatment of certain plants with an effective amount of the hydroxybenzimidazole compounds of the present invention has been observed to cause an increase in water use efficiency of plants thus treated, which reduces plant transpiration.Hydroxybenzimidazole compounds of the present invention are thus beneficial and useful for improving plant resistance to drought.Type: GrantFiled: June 13, 1994Date of Patent: December 31, 1996Inventors: Klara D. Vichnevetskaia, Terence J. Blake, Eddie Bevilacqua, Timothy J. B. Boyle
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Patent number: 5583092Abstract: Novel herbicidal compounds of the general formula ##STR1## wherein A represents an optionally substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, heteroaryl, aralkyl or heteroaralkyl group; R.sup.1 represents a hydrogen atom or an acyl group; and R.sup.2 represents an optionally substituted alkyl, alkenyl, aryl, heteroaryl, aralkyl or heteroaralkyl group.Type: GrantFiled: May 15, 1995Date of Patent: December 10, 1996Assignee: American Cyanamid CompanyInventor: Wolfgang Buck
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Patent number: 5578550Abstract: The invention pertains to a compound of the general formula ##STR1## wherein A represents an optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heteroaryl or aralkyl group, or a group of general formula X--Y--(CH.sub.2).sub.n -- where X represents an optionally substituted alkyl or aryl group, n represents 1 or 2, and Y represents an oxygen atom or a group of general formula --S(O).sub.m -- where m represents 0, 1 or 2; R.sup.1 represents a hydrogen atom or an alkyl group; and R.sup.2 represents a hydrogen atom or an optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heteroaryl, aralkyl or heteroaralkyl group which are useful as herbicides.Type: GrantFiled: October 5, 1994Date of Patent: November 26, 1996Assignee: American Cyanamid CompanyInventor: Wolfgang Buck
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Patent number: 5545608Abstract: Pyrazole-glycolic acid amides of the following formula (1) (in which R.sup.1 to R.sup.5 each represent a hydrogen atom or a substituent having a broad definition), and herbicides containing them. The compounds have a high herbicidal effect against paddy weeds, especially Echinochloa crus-galli, while highly safe for paddy rice plants.Type: GrantFiled: April 25, 1994Date of Patent: August 13, 1996Assignee: Nissan Chemical Industries, Ltd.Inventors: Katsushi Morimoto, Masatoshi Ohnari, Tsutomu Nawamaki, Shigeomi Watanabe, Kimihiro Ishikawa
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Patent number: 5506191Abstract: N-carbamoyl-2-carboxyaryl-heterocyclic and hydrazinecarboximidamide-hydrazone derivatives, intermediates and processes for their preparation, agricultural compositions containing them and their use as agricultural chemicals, in particular herbicides.Type: GrantFiled: April 8, 1994Date of Patent: April 9, 1996Assignee: Sandoz Ltd.Inventors: Richard J. Anderson, Joe T. Bamberg, Michael M. Leippe
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Patent number: 5502027Abstract: This invention relates to glutarimide compounds exhibiting herbicidal activity having the structure ##STR1## wherein A is carbonyl, thiocarbonyl or methylene, Al is carbonyl or methylene, Q is O or (CH.sub.2).sub.n where n is 0 or 1, D is CH or N and R, R.sup.1, R.sup.2, T, X, Y and Z are as defined within, compositions containing these compounds and methods of using these compounds as herbicides and algicides.Type: GrantFiled: October 14, 1994Date of Patent: March 26, 1996Assignee: Rohm and Haas CompanyInventors: Barry C. Lange, John W. Ashmore, Jane Wissinger-Cornille, Colin M. Tice
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Patent number: 5494890Abstract: The present invention relates to herbicidally, acaricidally and insecticidally active pyrazolidine-3,5-diones of the formula I ##STR1## in which R.sub.1 is ##STR2## R.sub.2 and R.sub.3 independently of one another are C.sub.1 -C.sub.6 alkyl; C.sub.3 -C.sub.6 alkenyl; or C.sub.3 -C.sub.6 alkynyl; orR.sub.2 and R.sub.3 together are a --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 --, --CH.sub.2 --CH.dbd.CH--CH.sub.2 --, --CH.sub.2 --CH.dbd.CH-- or --(CH.sub.2).sub.2 --CH.dbd.CH-- bridge which is unsubstituted or up to trisubstituted by C.sub.1 -C.sub.4 alkyl;n is 0; 1; 2; 3; or 4;m is 0; or 1; the total of m and n being less than, or equal to, 4; theR.sub.4 radicals independently of one another are halogen; nitro; cyano, C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.10 alkoxy; C.sub.1 -C.sub.4 haloalkoxy; C.sub.3 -C.sub.6 alkenyloxy; C.sub.1 -C.sub.4 alkoxy-C.sub.2 -C.sub.4 alkoxy; C.sub.3 -C.sub.6 alkynyloxy; C.sub.1 -C.sub.4 alkylcarbonyl; C.sub.1 -C.sub.4 alkoxycarbonyl; C.sub.1 -C.sub.Type: GrantFiled: June 2, 1995Date of Patent: February 27, 1996Assignee: Ciba-Geigy CorporationInventors: Frederik Cederbaum, Hans-Georg Brunner, Manfred Boger
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Patent number: 5488060Abstract: Substituted thiadiazoles which correspond to the formula: ##STR1## wherein R represents ##STR2## X represents --Br, --Cl, --F, --CH.sub.3, --OCH.sub.3, --COOCH.sub.3, --NO.sub.2, --SCH.sub.3, --SO.sub.2 CH.sub.3 or --CF.sub.3 and Y is --SCN or --SCH.sub.2 SCN.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.Type: GrantFiled: December 21, 1994Date of Patent: January 30, 1996Assignee: The Dow Chemical CompanyInventors: Ravi B. Shanker, Duane R. Romer, R. Garth Pews
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Patent number: 5484762Abstract: There is provided an aryloxy-N-(substituted phenyl)benzotriazole compound having the structural formula I ##STR1## Further provided are a composition and a method comprising that compound for the control of undesirable plant species.Type: GrantFiled: February 10, 1995Date of Patent: January 16, 1996Assignee: American Cyanamid CompanyInventors: Michael E. Condon, Alvin D. Crews, Jr., Mark C. Manfredi
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Patent number: 5478795Abstract: Synergistic herbicidal imidazolinone compositions, and methods for their use in selective postemergence control of undesirable plant species in the presence of crops; particularly for the selective control of undesirable plant species of the genera: Ipomoea, Sorghum and Euphorbia, in the presence of leguminous crops, by the postemergence application to the foliage of said plants of a novel synergistic combination of an imidazolinyl nicotinic acid, ester or salt with (1) a different imidazolinyl nicotinic acid, ester or salt, (2) an imidazolinyl-3-quino-linecarboxylic acid, ester or salt, or (3) an N-(heterocyclicaminocarbonyl)arylsulfonamide.Type: GrantFiled: October 14, 1992Date of Patent: December 26, 1995Assignee: American Cyanamid CompanyInventor: Robert M. Watkins, Jr.
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Patent number: 5476835Abstract: The present invention relates to a herbicidal extruded granular composition which is solvent free, dust free, and demonstrates improved water dispersibility properties. Said herbicidal composition also has improved environmental compatibility.Type: GrantFiled: July 5, 1994Date of Patent: December 19, 1995Assignee: American Cyanamid CompanyInventors: Jerry L. Johnson, Joseph Kimler
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Patent number: 5466661Abstract: The present invention relates to novel benzaldehyde derivatives, specifically .alpha.-azolyl-2-substituted benzaldehyde oxime derivatives, their production, and fungicidal, herbicidal and growth regulating compositions containing them.Type: GrantFiled: July 8, 1994Date of Patent: November 14, 1995Assignee: Shionogi & Co., Ltd.Inventors: Akira Takase, Hiroyuki Kai, Kuniyoshi Nishida, Koichi Morita, Michio Masuko, Kinya Ide, Yoshito Ueyama
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Patent number: 5444038Abstract: This invention relates to substituted aryl indazoles, a process for producing them and their use as herbicides. In particular this invention relates to substituted aryl indazoles of the formula ##STR1## wherein all variables are as defined in the specification.Type: GrantFiled: March 2, 1993Date of Patent: August 22, 1995Assignee: Zeneca LimitedInventors: Donald R. James, Don R. Baker, Steven D. Mielich, William J. Michaely, Steven Fitzjohn, Christopher G. Knudsen, Christopher Mathews, John M. Gerdes
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Patent number: 5428003Abstract: This disclosure is directed to certain substituted aryloxy benzotriazole compounds which are herbicidal agents. The structures of the compounds are represented by formulae I and II shown below: ##STR1## wherein M is C--X, N or N.sup.+ --O.sup.- ; W, X, Y and Z each independently represent hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy;n is 0, 1 or 2;R is hydrogen, C.sub.1 -C.sub.4 alkyl, aryl or when taken together with R.sub.1, R and R.sub.1 may form a ring in which RR.sub.1 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.1 and R.sub.2 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl or when taken together R.sub.1 and R.sub.2 may form a ring in which R.sub.1 R.sub.2 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.3 is cyano, ##STR2## CH.sub.2 OR.sub.8 or CH(OR.sub.9).sub.2 ; Q is OH, OR.sub.4 or NR.sub.5 R.sub.6 ;A is O, NOR.sub.5, NCOR.sub.5, NNR.sub.5 R.Type: GrantFiled: November 15, 1993Date of Patent: June 27, 1995Assignee: American Cyanamid CompanyInventors: Donald R. Nielsen, Thomas A. Lies
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Patent number: 5405829Type: GrantFiled: June 13, 1994Date of Patent: April 11, 1995Assignee: Schering AktiengesellschaftInventors: Uwe Hartfiel, Gabriele Dorfmeister, Helga Franke, Jens Geisler, Gerhard Johann, Richard Rees
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Patent number: 5397768Abstract: Compounds of the formula ##STR1## are fungicides and herbicides when Z is alkyl, cycloalkyl, aryl, or aralkyl; Q is a triazolyl; X is an aryl group or a heterocyclic group; and W is a variety of functional groups.Type: GrantFiled: October 1, 1993Date of Patent: March 14, 1995Assignee: Rohm and Haas CompanyInventors: Steven H. Shaber, Luong T. Nguyen
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Patent number: 5391540Abstract: Disclosed herein are herbicidal pyridine compounds substituted at the 2- or 6-position with an OR.sub.2 moiety where R.sub.2 is hydrogen, lower alkyl, halomethyl, lower cyanoalkyl, alkenyl or alkynyl, as well as herbicidal compositions and herbicidal use of these compounds.Type: GrantFiled: April 12, 1993Date of Patent: February 21, 1995Assignee: Rohm and Haas CompanyInventors: Donald E. Korte, Len F. Lee
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Patent number: 5369086Abstract: Substituted N-benzotriazoles of the general formula ##STR1## exhibit herbicidal activity. Herbicidal compositions and related methods of using the substituted N-benzotriazoles are also disclosed.Type: GrantFiled: April 28, 1993Date of Patent: November 29, 1994Assignee: Zeneca LimitedInventors: Donald R. James, Raymond A. Felix
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Patent number: 5354731Abstract: A pyridinesulfonamide derivative of the formula (I) and a salt thereof: ##STR1## wherein R.sup.1 is a halogen atom, a trifluoromethyl group, a C.sub.1 -C.sub.6 alkoxycarbonyl group, a C.sub.1 -C.sub.6 mono- or di-alkylaminocarbonyl group, a C.sub.1 -C.sub.6 alkoxy group, a C.sub.1 -C.sub.6 alkylsulfonyl group, a C.sub.1 -C.sub.6 alkylthio group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkoxy group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 mono- or poly-halogenoalkoxy group, a C.sub.1 -C.sub.6 mono- or poly-halogenoalkoxy group, a C.sub.1 -C.sub.6 mono- or di-alkylaminosulfonyl group, a C.sub.1 -C.sub.6 alkoxyaminosulfonyl group substituted by a C.sub.1 -C.sub.6 alkyl group, a nitro group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkylthio group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkylsulfonyl group, or a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkoxycarbonyl group;R.sup.Type: GrantFiled: February 11, 1992Date of Patent: October 11, 1994Assignee: Nissan Chemical Industries Ltd.Inventors: Kenzi Makino, Katsushi Morimoto, Shigeaki Akiyama, Hideaki Suzuki, Takeshi Nagaoka, Koichi Suzuki, Tsutomu Nawamaki, Shigeomi Watanabe
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Patent number: 5334576Abstract: There are provided novel 5(and/or 6)substituted 2-(2-imidazolin-2-yl) and 2-(2-imidazolidinyl)nicotinic acids, esters and salts, which are useful as herbicidal agents. There are also provided novel substituted pyrrolopyridine acetonitriles, pyrrolopyridine acetamides, imidazopyrrolopyridinediones and carbamoylnicotinic acid esters, that are useful as intermediates for the preparation of the above said herbicidal agents.Type: GrantFiled: March 23, 1992Date of Patent: August 2, 1994Assignee: American Cyanamid CompanyInventors: Robert F. Doehner, Jr., David W. Ladner, John M. Finn
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Patent number: 5324711Abstract: This invention is directed to certain substituted aryloxy benzotriazole compounds which are herbicidal agents. The structures of these compounds are represented by formulas I and II shown below: ##STR1## wherein M is C--X, N or N.sup.+ --O.sup.- ;W, X, Y and Z each independently represent hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy;n is 0, 1 or 2;R is hydrogen, C.sub.1 -C.sub.4 alkyl, aryl or when taken together with R.sub.1, R and R.sub.1 may form a ring in which RR.sub.1 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.1 and R.sub.2 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl or when taken together R.sub.1 and R.sub.2 may form a ring in which R.sub.1 R.sub.2 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.3 is cyano, ##STR2## CH.sub.2 OR.sub.8 or CH(OR.sub.9).sub.2 ; Q is OH, OR.sub.4 or NR.sub.5 R.sub.6 ;A is O, NOR.sub.5, NCOR.sub.5, NNR.sub.5 R.Type: GrantFiled: October 5, 1989Date of Patent: June 28, 1994Assignee: American Cyanamid CompanyInventors: Donald R. Nielsen, Thomas A. Lies
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Patent number: 5321002Abstract: Herbicidal compounds, compositions containing them, and a method for controlling weeds by application of the compositions are disclosed. The herbicidal compounds are 2-(1-aryl-4-cyano-5-pyrazolylmethyleneiminooxy)alkanoic acid derivatives of the structure: ##STR1## in which R is lower alkyl, lower alkenyl, or lower alkynyl, each optionally substituted with halogen, or CH(R.sup.1)--C(O)--Y--R.sup.2 ; R.sup.1 is hydrogen or lower alkyl; R.sup.2 is one of a variety of substituents; Y is O or NH; Z is lower alkyl or lower alkoxy; and Ar is 3-chloro-5-trifluoromethyl-2-pyridyl, 2,6-dichloro-4-trifluoromethylphenyl, or 2,4,6-trichlorophenyl.Type: GrantFiled: August 11, 1993Date of Patent: June 14, 1994Assignee: FMC CorporationInventor: Lester L. Maravetz
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Patent number: 5306694Abstract: The invention describes novel 1-(2-pyridyl)pyrazoles of formula (I) ##STR1## wherein typically preferred substituents are: X is S(O).sub.n R.sub.1, in which R.sub.1 is an alkyl group, preferably a methyl group, which is fully substituted by halogen atoms, and n is 0, 1 and 2;Y is hydrogen, halogen, cyano, alkylsulfenyl, alkylsulfinyl, alkylsulfonyl, alkoxy, amino, alkylamino, dialkylamino, trialkylammonium salt, cyanoalkylamino, alkoxyalkylamino, alkoxycarbonylamino, alkylcarbonylamino, haloalkylcarbonylamino, alkylaminocarbonylamino, dialkylaminocarbonylamino or alkoxyalkylideneimino, wherein the alkyl and alkoxy moieties are a linear or branched chain, containing one to four carbon atoms, and the halo-substitution consists of one or more halogen atoms, which are the same or different, up to full substitution of the alkyl moiety;Z is cyano; andR.sub.2, R.sub.3, R.sub.4, and R.sub.Type: GrantFiled: June 17, 1993Date of Patent: April 26, 1994Assignee: Rhone-Poulenc Inc.Inventors: Jennifer L. Phillips, Philip R. Timmons, Gail S. Powell, Michael T. Pilato, David T. Chou, Jamin Huang
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Patent number: 5294596Abstract: The invention relates to novel heterocyclyltriazolinones of the general formula (I) ##STR1## in which R.sup.1 represents hydrogen or represents alkyl or cycloalkyl, each of which is optionally substituted,R.sup.2 represents hydrogen, hydroxyl, mercapto or halogen or represents alkyl, alkenyl, alkinyl, cycloalkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, arylalkyl, amino or heterocyclyl, each of which is optionally substituted, andHet represents an optionally substituted heterocycle of the formula ##STR2## in which X in each case represents oxygen, sulphur, an NH group or an N-alkyl group,a process for their preparation and their use as herbicides.Type: GrantFiled: July 21, 1993Date of Patent: March 15, 1994Assignee: Bayer AktiengesellschaftInventors: Wilhelm Haas, Kurt Findeisen, Karl-Heinz Linker, Klaus Lurssen, Hans-Joachim Santel, Robert R. Schmidt
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Patent number: 5290753Abstract: The present invention provides a method for protecting or preventing a crop from injury due to the application of a combination of compounds by altering the susceptibility of the crop by incorporating a gene resistant to inhibition by at least one of the compounds in the combination into the genome of the crop.Type: GrantFiled: May 12, 1992Date of Patent: March 1, 1994Assignee: American Cyanamid CompanyInventors: Keith E. Newhouse, Thomas J. Schaefer, Gail E. Cary
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Patent number: 5278134Abstract: The present invention relates to new 3-(aminooxoacetyl)-2-(2-imidazolin-2-yl)pyridines and their salts, having herbicidal activity.Type: GrantFiled: October 27, 1992Date of Patent: January 11, 1994Assignee: Korea Research Institute of Chemical TechnologyInventors: Dae W. Kim, Hae S. Chang, Dong J. Jeon, Jae W. Ryu, In T. Hwang
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Patent number: 5266556Abstract: There are disclosed novel arylindazole derivatives of the formula: ##STR1## and agrochemically acceptable salts thereof. Also disclosed are a herbicidal composition including the above arylindazole derivative as an active ingredient and a method for exterminating undesired weeds by the application of a herbicidally effective amount of the above arylindazole derivative to an area where the undesired weeds grow or will grow.Type: GrantFiled: November 23, 1992Date of Patent: November 30, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Masayuki Enomoto, Susumu Takemura, Masaharu Sakaki, Satoru Kizawa, Eiki Nagano
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Patent number: 5262387Abstract: Pyridine derivatives of the formulae ##STR1## wherein W, X, Y and Z are each C--R.sup.4, N or N.fwdarw.O, with the proviso that the ring contains only one heteroatom, and the substituents R.sup.1, R.sup.2 and R.sup.3 have the following meanings:R.sup.1 is alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl,R.sup.2 is hydrogen,R.sup.3 is formyl, 4,5-dihydrooxazol-2-yl or --CO--A--R.sup.5 or --CO--NR.sup.6.sup.R.sup.7, whereR.sup.Type: GrantFiled: November 20, 1991Date of Patent: November 16, 1993Assignee: BASF AktiengesellschaftInventors: Gerhard Hamprecht, Norbert Goetz, Bruno Wuerzer, Karl-Otto Westphalen
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Patent number: 5260260Abstract: A nonionic surfactant blend for use with compatible herbicides. The nonionic surfactant blend includes an effective amount of an acidulated soybean soapstock. The acidulated soybean soapstock includes a range of total fatty acids of about 94%-to-96% by volume and a moisture content of not more than about 5% by volume. The present invention also includes a method for improving the performance of a herbicide. The method includes providing an effective quantity of the improved nonionic surfactant blend for combination with the herbicide.Type: GrantFiled: May 11, 1992Date of Patent: November 9, 1993Assignee: Cenex/Land O'Lakes Agronomy CompanyInventors: Joe V. Gednalske, Robert W. Herzfeld
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Patent number: 5258357Abstract: Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, a substituted or unsubstituted 5- to 6-membered heterocyclic structure or one of the groups stated for R.sup.1, orR.sup.1 and R.sup.2 together are a 4- to 7-membered chain which contains, in addition to methylene groups, one of the following groups as ring member: oxygen, sulfur, N-methyl or carbonyl;R.sup.3 and R.sup.4 are each nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, a substituted or unsubstituted 5- to 6 -membered heterocyclic structure, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y=O,S);R.sup.Type: GrantFiled: September 21, 1992Date of Patent: November 2, 1993Assignee: BASF AktiengesellschaftInventors: Peter Muenster, Gerd Steiner, Wolfgang Freund, Bruno Wuerzer, Karl-Otto Westphalen
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Herbicidal compositions safened by 5-heterocyclic-substituted oxazolidine dihaloacetamides compounds
Patent number: 5256626Abstract: The disclosure herein relates to a new family of haloalkyl oxazolidinyl derivatives as antidotal compounds to reduce injury to crop plants by a variety of herbicides. The antidotal compounds are characterized particularly by having heterocyclyl or spiroheterocyclyl radicals attached to the 5-position of haloalkyl oxazolidine compounds and are especially useful as in-can antidotes against injury by acetanilide and thiocarbamate herbicides to corn, sorghum, soybeans, wheat, rice and other crops.Type: GrantFiled: July 3, 1991Date of Patent: October 26, 1993Assignee: Monsanto CompanyInventors: Eric L. Williams, Steven M. Massey, Brett H. Bussler, Ronald J. Brinker -
Patent number: 5256632Abstract: Herbicidal sulphonylated carboxamides of the formulaR.sup.1 --CO--NH--SO.sub.2 --(A).sub.n --R.sup.2 (I)in whichn represents the numbers 0 or 1,A represents oxygen, iminio (NH) or methylene (CH.sub.2),R.sup.1 represents a five-membered heteroaryl radical which contains 1 or 2 nitrogen atoms and additionally one oxygen or sulphur atom in the ring and which is optionally substituted by halogen or by alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, dialkylamino or phenyl which are in each case optionally substituted, andR.sup.2 represents aryl or heteroaryl which are in each case optionally substituted,or salts thereof, with the exclusion of the compound 2-dimethylamino-N-(4-methyl-phenylsulphonyl)-5-thiazole carboxamide.Type: GrantFiled: June 18, 1992Date of Patent: October 26, 1993Assignee: Bayer AktiengesellschaftInventors: Hilmar Wolf, Rolf Kirsten, Hans-Joachim Santel, Klaus Lurssen, Robert R. Schmidt
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Patent number: 5256625Abstract: The disclosure herein relates to the use of certain amides of dichloroacetic acid and other compounds as safener/antidotal compounds to reduce the phytotoxicity to crop plants, especially corn, of imidazolinone-type herbicides alone or in admixture with other co-herbicidal compounds, e.g., .alpha.-haloacetamides.Type: GrantFiled: December 29, 1989Date of Patent: October 26, 1993Assignee: Monsanto CompanyInventors: Brett H. Bussler, Ronald J. Brinker
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Patent number: 5244866Abstract: This invention relates to the use of acetohydroxyacid synthase (AHAS) inhibiting herbicides to prevent or delay sprout formation in agronomic crops. More particularly, this invention relates to the application of imidazolinones on tubers, such as potatoes, to inhibit the post-harvest growth of sprouts.Type: GrantFiled: July 31, 1992Date of Patent: September 14, 1993Assignee: American Cyanamid CompanyInventor: Peter N. Tayler
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Patent number: 5217523Abstract: Pyrazole-3-carboxamides of the general formula I ##STR1## where the substituents have the following meaning: R.sup.1 hydrogen;substituted or unsubstituted C.sub.3 -C.sub.8 -cycloalkyl or C.sub.1 C.sub.6 -alkyl;R.sup.2 hydroxy; amino; C.sub.1 -C.sub.4 -alkylamino; di-C.sub.1 -C.sub.4 -alkylamino, aminocarbonyl-C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl or naphthyl,a substituted or unsubstituted 5- to 6-membered heterocyclic ring;one of the groups mentioned for R.sup.1 orR.sup.1 and R.sup.2 together denote a 4- to 7-membered chain which may contain, in addition to methylene groups one of the following groups as ring member: oxygen, sulfur N-methyl or carbonyl;R.sup.3 a substituted or unsubstituted 5- to 6-membered heterocyclic ring.substituted or unsubstituted C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl orone of the groups mentioned for R.sup.1 ;R.sup.Type: GrantFiled: May 4, 1992Date of Patent: June 8, 1993Assignee: BASF AktiengesellschaftInventors: Klaus Ditrich, Gerhard Hamprecht, Peter Plath, Bruno Wuerzer, Karl-Otto Westphalen
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Patent number: 5216171Abstract: 2-Amino-4-trichloromethylpyridines of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.4 -alkenyl or phenyl, benzyl or phenylsulfonyl,--CX--R.sup.3, --SO.sub.2 R.sup.3 or --PX(OR.sup.4).sub.2 orR.sup.1 and R.sup.2 together form .dbd.CR.sup.5 R.sup.6 or --CO--Z--CO--,X is oxygen or sulfur,R.sup.3 is C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.6 -alkenyl, amino, C.sub.1 -C.sub.6 -alkylamino, di-C.sub.1 -C.sub.6 -alkylamino, morpholino, piperidino, pyrazolidino or C.sub.1 -C.sub.8 -alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl or substituted or unsubstituted phenyl,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl, or substituted or unsubstituted phenyl,R.sup.Type: GrantFiled: April 8, 1991Date of Patent: June 1, 1993Assignee: BASF AktiengesellschaftInventors: Helmut Hagen, Hans Ziegler, Juergen Pfister, Gerhard Nilz, Gisela Lorenz, Juergen Dressel
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Patent number: 5215568Abstract: This disclosure describes new 5-oximio-2-(2-imidazolin-2-yl) pyridines having the following structure: ##STR1## wherein Y is hydrogen, C.sub.1 -C.sub.4 branched or unbranched alkyl optionally substituted with C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthiol, halogen, CO.sub.2 R.sub.4, CN, NHCOR.sub.5, OCOR.sub.4, furyl or a phenyl group optionally substituted with one or two halogens, C.sub.1 -C.sub.2 alkyl or nitro, C.sub.1 -C.sub.4 alkenyl optionally substituted with halogen or C.sub.1 -C.sub.4 alkoxy, or C.sub.1 -C.sub.4 alkynyl; and Z is hydrogen or C.sub.1 -C.sub.4 alkyl. The disclosure further describes the unique method of using the compounds as herbicidal agents and the methods for their preparation.Type: GrantFiled: October 31, 1991Date of Patent: June 1, 1993Assignee: American Cyanamid CompanyInventor: John M. Finn
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Patent number: 5213606Abstract: 4-Carboxy-2-aryloxyphenoxyalkyl substituted heterocycle compounds which are effective for the selective control of grass weed species in the presence of crops are described. Also described are a method for the selective herbicidal use of the compounds and methods for their preparation.Type: GrantFiled: November 27, 1991Date of Patent: May 25, 1993Assignee: American Cyanamid CompanyInventors: Robert L. Arotin, Michael A. Guaciaro
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Patent number: 5209769Abstract: The invention relates to new substituted triazolinones of the general formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, A, X and Y have the meanings given in the description,to a plurality of processes for their preparation, and to their use as herbicides.Type: GrantFiled: May 4, 1992Date of Patent: May 11, 1993Assignee: Bayer AktiengesellschaftInventors: Kurt Findeisen, Dietmar Kuhnt, Klaus-Helmut Muller, Michael Haug, Klaus Konig, Klaus Lurssen, Hans-Joachim Santel, Robert R. Schmidt