Plural Ring Nitrogens In The Additional Hetero Ring Patents (Class 504/253)
  • Patent number: 5707936
    Abstract: Methyl .alpha.-phenylbutenoates of the formula I ##STR1## where -- is a single or double bond and the index and the substituents have the following meanings:n is 0, 1, 2, 3 or 4;R.sup.1 is nitro, cyano, halogen, alkyl, haloalkyl or alkoxy;R.sup.2 is hydrogen, nitro, cyano, halogen, alkyl, haloalkyl, alkoxy, alkylthio or alkoxycarbonyl;R.sup.3 is unsubst. or subst. alkyl, alkenyl or alkynyl;an unsubst. or subst. saturated or mono-or diunsaturated ring which, in addition to carbon atoms, can contain one to three of the following heteroatoms as ring members: oxygen, sulfur and nitrogen, oran unsubst. or subst. mono- or binuclear aromatic radical which, in addition to carbon atoms, can contain one to four nitrogen atoms or one or two nitrogen atoms and an oxygen or sulfur atom or an oxygen or sulfur atom as ring members,processes for their preparation and their use are described.
    Type: Grant
    Filed: October 31, 1996
    Date of Patent: January 13, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Oberdorf, Hartmann Konig, Bernd Muller, Reinhard Kirstgen, Wassilios Grammenos, Hubert Sauter, Gisela Lorenz, Eberhard Ammermann, Volker Harries
  • Patent number: 5707934
    Abstract: This invention relates to a new method of plant growth regulation whereby a 1-phenylpyrazole such as fipronil is applied to a crop or a seed.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: January 13, 1998
    Assignee: Rhone-Poulenc Inc.
    Inventors: Reed Nathan Royalty, Nguyen Dang Long, Michael Thomas Pilato, Nicholas Mark Hamon, Ngadi Yahmad, Djoko Prabowo Sastrosatomo
  • Patent number: 5705454
    Abstract: The present invention relates to chemical compositions comprising imidazolinone compounds that are suitable for use in turfgrass management. The invention also provides methods for altering the growth and reducing mowing frequency, suppressing seed head formation and controlling undesirable vegetation in turfgrass.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: January 6, 1998
    Assignee: American Cyanamid Company
    Inventors: Prithvi Raj Bhalla, Robert Michael Herrick, Donald Wakeford Gates
  • Patent number: 5696024
    Abstract: The present invention provides a solid water soluble granular composition which comprises an imidazolinone herbicide alone or in combination with a second herbicide and a base, preferably wherein the base is present at a ratio of about 0.9 to 2.0 molar equivalents of base to molar equivalents of imidazolinone herbicide. Said composition is storage stable and dissolves rapidly and essentially completely in water for even application to target surfaces.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: December 9, 1997
    Assignee: American Cyanmid
    Inventors: Janos Szamosi, Mimi Schaaf
  • Patent number: 5679623
    Abstract: Compounds of the formula ##STR1## in which R.sub.l, R.sub.2, R.sub.3, R.sub.4, Y and Z are as defined in claim 1, and, if appropriate, the tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: October 21, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Henry Szczepanski, Haukur Kristinsson
  • Patent number: 5658855
    Abstract: Adjuvant compositions for herbicides comprising amine or ammonia compounds for adjusting the pH to the alkaline range, a neutral water soluble compound to provide a fertilizer action and a non-ionic surfactant and water. Herbicidal compositions using the adjuvant in combination with the herbicide are also included as well as methods for controlling weeds or undesirable vegetation by application of those compositions thereto.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: August 19, 1997
    Assignee: North Dakota State University
    Inventors: John D. Nalewaja, Robert Matysiak, Zenon Woznica
  • Patent number: 5643854
    Abstract: Disclosed herein are herbicidal pyridine compounds substituted at the 2- or 6-position with an OR.sub.2 moiety where R.sub.2 is hydrogen, lower alkyl, halomethyl, lower cyanoalkyl, alkenyl or alkynyl, as well as herbicidal compositions and herbicidal use of these compounds.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 1, 1997
    Assignee: Rohm and Haas Company
    Inventors: Donald Edwin Korte, Len Fang Lee
  • Patent number: 5641727
    Abstract: Herbicidal tetrazolinone derivatives of the formula: ##STR1## in which R.sup.1 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, andR.sup.2 is alkyl, haloalkyl, cycloalkyl, alkenyl, haloalkenyl, alkynyl or phenyl, orR.sup.1 and R.sup.2 together with the nitrogen atom to which they are bonded form an optionally benzofused heterocyclic ring, which is optionally substituted by C.sub.1-4 alkyl,n is 0, 1, 2 or 3, andR.sup.3 each independently is nitro, halogen, alkyl, haloalkyl, alkylthio or phenoxy.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: June 24, 1997
    Assignee: Nihon Bayer Agrochem K.K.
    Inventors: Toshio Goto, Koichi Moriya, Fritz Maurer, Seishi Ito, Katsuaki Wada, Kazuhiro Ukawa, Ryo Watanabe, Asami Ito
  • Patent number: 5622917
    Abstract: The invention relates to new 1H-3-aryl-pyrrolidine-2,4-dione derivatives of the formula (I) ##STR1## in which A, B, X, Y and G have the meanings given in the description, to a plurality of processes for their preparation, and to their use as pesticides.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: April 22, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reiner Fischer, Thomas Bretschneider, Bernd-Wieland Kr uger, Michael Ruther, Christoph Erdelen, Ulrike Wachendorff-Neumann, Hans-Joachim Santel, Markus Dollinger
  • Patent number: 5618775
    Abstract: Mixtures of optically active cyclohexenone oxime ethers having R- and S-configuration in the oxime ether moiety of the formula I ##STR1## (R.sup.1 =C.sub.1 -C.sub.6 -alkyl; ##STR2## X=C.sub.1-C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl; m=0-3 or 1-4 where all X's are halogen;n=0-3 or 1-5 where all X's are halogen;R.sup.2 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkenyl, substituted or unsubstituted 5-membered saturated heterocyclic structure, substituted or unsubstituted 6- or 7-membered heterocyclic structure, substituted or unsubstituted 5-membered heteroaromatic structure, substituted or unsubstituted phenyl or pyridyl)and their agriculturally useful salts and esters with C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: April 8, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Wolfgang Ladner, Helmut Walter, Karl-Otto Westphalen, Uwe Kardorff, Matthias Gerber
  • Patent number: 5607898
    Abstract: The present invention relates to pyrazole derivatives of the formula (I), ##STR1## wherein R.sup.1, R.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, p and n are as defined on claim 1, or a salt thereof, and herbicides containing them as active ingredients.
    Type: Grant
    Filed: February 1, 1996
    Date of Patent: March 4, 1997
    Assignee: Idemitsu Kosan Company, Ltd.
    Inventors: Kazufumi Nakamura, Kazuyoshi Koike, Masashi Sakamoto, Ichiro Nasuno
  • Patent number: 5589437
    Abstract: It has been discovered that certain hydroxybenzimidazole compounds provide beneficial characteristics to certain agricultural species. Treatment of certain plants with an effective amount of the hydroxybenzimidazole compounds of the present invention has been observed to cause an increase in water use efficiency of plants thus treated, which reduces plant transpiration.Hydroxybenzimidazole compounds of the present invention are thus beneficial and useful for improving plant resistance to drought.
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: December 31, 1996
    Inventors: Klara D. Vichnevetskaia, Terence J. Blake, Eddie Bevilacqua, Timothy J. B. Boyle
  • Patent number: 5583092
    Abstract: Novel herbicidal compounds of the general formula ##STR1## wherein A represents an optionally substituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, heteroaryl, aralkyl or heteroaralkyl group; R.sup.1 represents a hydrogen atom or an acyl group; and R.sup.2 represents an optionally substituted alkyl, alkenyl, aryl, heteroaryl, aralkyl or heteroaralkyl group.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: December 10, 1996
    Assignee: American Cyanamid Company
    Inventor: Wolfgang Buck
  • Patent number: 5578550
    Abstract: The invention pertains to a compound of the general formula ##STR1## wherein A represents an optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heteroaryl or aralkyl group, or a group of general formula X--Y--(CH.sub.2).sub.n -- where X represents an optionally substituted alkyl or aryl group, n represents 1 or 2, and Y represents an oxygen atom or a group of general formula --S(O).sub.m -- where m represents 0, 1 or 2; R.sup.1 represents a hydrogen atom or an alkyl group; and R.sup.2 represents a hydrogen atom or an optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, aryl, heteroaryl, aralkyl or heteroaralkyl group which are useful as herbicides.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: November 26, 1996
    Assignee: American Cyanamid Company
    Inventor: Wolfgang Buck
  • Patent number: 5545608
    Abstract: Pyrazole-glycolic acid amides of the following formula (1) (in which R.sup.1 to R.sup.5 each represent a hydrogen atom or a substituent having a broad definition), and herbicides containing them. The compounds have a high herbicidal effect against paddy weeds, especially Echinochloa crus-galli, while highly safe for paddy rice plants.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: August 13, 1996
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Katsushi Morimoto, Masatoshi Ohnari, Tsutomu Nawamaki, Shigeomi Watanabe, Kimihiro Ishikawa
  • Patent number: 5506191
    Abstract: N-carbamoyl-2-carboxyaryl-heterocyclic and hydrazinecarboximidamide-hydrazone derivatives, intermediates and processes for their preparation, agricultural compositions containing them and their use as agricultural chemicals, in particular herbicides.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: April 9, 1996
    Assignee: Sandoz Ltd.
    Inventors: Richard J. Anderson, Joe T. Bamberg, Michael M. Leippe
  • Patent number: 5502027
    Abstract: This invention relates to glutarimide compounds exhibiting herbicidal activity having the structure ##STR1## wherein A is carbonyl, thiocarbonyl or methylene, Al is carbonyl or methylene, Q is O or (CH.sub.2).sub.n where n is 0 or 1, D is CH or N and R, R.sup.1, R.sup.2, T, X, Y and Z are as defined within, compositions containing these compounds and methods of using these compounds as herbicides and algicides.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: March 26, 1996
    Assignee: Rohm and Haas Company
    Inventors: Barry C. Lange, John W. Ashmore, Jane Wissinger-Cornille, Colin M. Tice
  • Patent number: 5494890
    Abstract: The present invention relates to herbicidally, acaricidally and insecticidally active pyrazolidine-3,5-diones of the formula I ##STR1## in which R.sub.1 is ##STR2## R.sub.2 and R.sub.3 independently of one another are C.sub.1 -C.sub.6 alkyl; C.sub.3 -C.sub.6 alkenyl; or C.sub.3 -C.sub.6 alkynyl; orR.sub.2 and R.sub.3 together are a --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 --, --CH.sub.2 --CH.dbd.CH--CH.sub.2 --, --CH.sub.2 --CH.dbd.CH-- or --(CH.sub.2).sub.2 --CH.dbd.CH-- bridge which is unsubstituted or up to trisubstituted by C.sub.1 -C.sub.4 alkyl;n is 0; 1; 2; 3; or 4;m is 0; or 1; the total of m and n being less than, or equal to, 4; theR.sub.4 radicals independently of one another are halogen; nitro; cyano, C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.10 alkoxy; C.sub.1 -C.sub.4 haloalkoxy; C.sub.3 -C.sub.6 alkenyloxy; C.sub.1 -C.sub.4 alkoxy-C.sub.2 -C.sub.4 alkoxy; C.sub.3 -C.sub.6 alkynyloxy; C.sub.1 -C.sub.4 alkylcarbonyl; C.sub.1 -C.sub.4 alkoxycarbonyl; C.sub.1 -C.sub.
    Type: Grant
    Filed: June 2, 1995
    Date of Patent: February 27, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Frederik Cederbaum, Hans-Georg Brunner, Manfred Boger
  • Patent number: 5488060
    Abstract: Substituted thiadiazoles which correspond to the formula: ##STR1## wherein R represents ##STR2## X represents --Br, --Cl, --F, --CH.sub.3, --OCH.sub.3, --COOCH.sub.3, --NO.sub.2, --SCH.sub.3, --SO.sub.2 CH.sub.3 or --CF.sub.3 and Y is --SCN or --SCH.sub.2 SCN.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
    Type: Grant
    Filed: December 21, 1994
    Date of Patent: January 30, 1996
    Assignee: The Dow Chemical Company
    Inventors: Ravi B. Shanker, Duane R. Romer, R. Garth Pews
  • Patent number: 5484762
    Abstract: There is provided an aryloxy-N-(substituted phenyl)benzotriazole compound having the structural formula I ##STR1## Further provided are a composition and a method comprising that compound for the control of undesirable plant species.
    Type: Grant
    Filed: February 10, 1995
    Date of Patent: January 16, 1996
    Assignee: American Cyanamid Company
    Inventors: Michael E. Condon, Alvin D. Crews, Jr., Mark C. Manfredi
  • Patent number: 5478795
    Abstract: Synergistic herbicidal imidazolinone compositions, and methods for their use in selective postemergence control of undesirable plant species in the presence of crops; particularly for the selective control of undesirable plant species of the genera: Ipomoea, Sorghum and Euphorbia, in the presence of leguminous crops, by the postemergence application to the foliage of said plants of a novel synergistic combination of an imidazolinyl nicotinic acid, ester or salt with (1) a different imidazolinyl nicotinic acid, ester or salt, (2) an imidazolinyl-3-quino-linecarboxylic acid, ester or salt, or (3) an N-(heterocyclicaminocarbonyl)arylsulfonamide.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: December 26, 1995
    Assignee: American Cyanamid Company
    Inventor: Robert M. Watkins, Jr.
  • Patent number: 5476835
    Abstract: The present invention relates to a herbicidal extruded granular composition which is solvent free, dust free, and demonstrates improved water dispersibility properties. Said herbicidal composition also has improved environmental compatibility.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: December 19, 1995
    Assignee: American Cyanamid Company
    Inventors: Jerry L. Johnson, Joseph Kimler
  • Patent number: 5466661
    Abstract: The present invention relates to novel benzaldehyde derivatives, specifically .alpha.-azolyl-2-substituted benzaldehyde oxime derivatives, their production, and fungicidal, herbicidal and growth regulating compositions containing them.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: November 14, 1995
    Assignee: Shionogi & Co., Ltd.
    Inventors: Akira Takase, Hiroyuki Kai, Kuniyoshi Nishida, Koichi Morita, Michio Masuko, Kinya Ide, Yoshito Ueyama
  • Patent number: 5444038
    Abstract: This invention relates to substituted aryl indazoles, a process for producing them and their use as herbicides. In particular this invention relates to substituted aryl indazoles of the formula ##STR1## wherein all variables are as defined in the specification.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: August 22, 1995
    Assignee: Zeneca Limited
    Inventors: Donald R. James, Don R. Baker, Steven D. Mielich, William J. Michaely, Steven Fitzjohn, Christopher G. Knudsen, Christopher Mathews, John M. Gerdes
  • Patent number: 5428003
    Abstract: This disclosure is directed to certain substituted aryloxy benzotriazole compounds which are herbicidal agents. The structures of the compounds are represented by formulae I and II shown below: ##STR1## wherein M is C--X, N or N.sup.+ --O.sup.- ; W, X, Y and Z each independently represent hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy;n is 0, 1 or 2;R is hydrogen, C.sub.1 -C.sub.4 alkyl, aryl or when taken together with R.sub.1, R and R.sub.1 may form a ring in which RR.sub.1 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.1 and R.sub.2 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl or when taken together R.sub.1 and R.sub.2 may form a ring in which R.sub.1 R.sub.2 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.3 is cyano, ##STR2## CH.sub.2 OR.sub.8 or CH(OR.sub.9).sub.2 ; Q is OH, OR.sub.4 or NR.sub.5 R.sub.6 ;A is O, NOR.sub.5, NCOR.sub.5, NNR.sub.5 R.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: June 27, 1995
    Assignee: American Cyanamid Company
    Inventors: Donald R. Nielsen, Thomas A. Lies
  • Patent number: 5405829
    Type: Grant
    Filed: June 13, 1994
    Date of Patent: April 11, 1995
    Assignee: Schering Aktiengesellschaft
    Inventors: Uwe Hartfiel, Gabriele Dorfmeister, Helga Franke, Jens Geisler, Gerhard Johann, Richard Rees
  • Patent number: 5397768
    Abstract: Compounds of the formula ##STR1## are fungicides and herbicides when Z is alkyl, cycloalkyl, aryl, or aralkyl; Q is a triazolyl; X is an aryl group or a heterocyclic group; and W is a variety of functional groups.
    Type: Grant
    Filed: October 1, 1993
    Date of Patent: March 14, 1995
    Assignee: Rohm and Haas Company
    Inventors: Steven H. Shaber, Luong T. Nguyen
  • Patent number: 5391540
    Abstract: Disclosed herein are herbicidal pyridine compounds substituted at the 2- or 6-position with an OR.sub.2 moiety where R.sub.2 is hydrogen, lower alkyl, halomethyl, lower cyanoalkyl, alkenyl or alkynyl, as well as herbicidal compositions and herbicidal use of these compounds.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: February 21, 1995
    Assignee: Rohm and Haas Company
    Inventors: Donald E. Korte, Len F. Lee
  • Patent number: 5369086
    Abstract: Substituted N-benzotriazoles of the general formula ##STR1## exhibit herbicidal activity. Herbicidal compositions and related methods of using the substituted N-benzotriazoles are also disclosed.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: November 29, 1994
    Assignee: Zeneca Limited
    Inventors: Donald R. James, Raymond A. Felix
  • Patent number: 5354731
    Abstract: A pyridinesulfonamide derivative of the formula (I) and a salt thereof: ##STR1## wherein R.sup.1 is a halogen atom, a trifluoromethyl group, a C.sub.1 -C.sub.6 alkoxycarbonyl group, a C.sub.1 -C.sub.6 mono- or di-alkylaminocarbonyl group, a C.sub.1 -C.sub.6 alkoxy group, a C.sub.1 -C.sub.6 alkylsulfonyl group, a C.sub.1 -C.sub.6 alkylthio group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkoxy group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 mono- or poly-halogenoalkoxy group, a C.sub.1 -C.sub.6 mono- or poly-halogenoalkoxy group, a C.sub.1 -C.sub.6 mono- or di-alkylaminosulfonyl group, a C.sub.1 -C.sub.6 alkoxyaminosulfonyl group substituted by a C.sub.1 -C.sub.6 alkyl group, a nitro group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkylthio group, a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkylsulfonyl group, or a C.sub.1 -C.sub.6 alkyl group substituted by a C.sub.1 -C.sub.6 alkoxycarbonyl group;R.sup.
    Type: Grant
    Filed: February 11, 1992
    Date of Patent: October 11, 1994
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Kenzi Makino, Katsushi Morimoto, Shigeaki Akiyama, Hideaki Suzuki, Takeshi Nagaoka, Koichi Suzuki, Tsutomu Nawamaki, Shigeomi Watanabe
  • Patent number: 5334576
    Abstract: There are provided novel 5(and/or 6)substituted 2-(2-imidazolin-2-yl) and 2-(2-imidazolidinyl)nicotinic acids, esters and salts, which are useful as herbicidal agents. There are also provided novel substituted pyrrolopyridine acetonitriles, pyrrolopyridine acetamides, imidazopyrrolopyridinediones and carbamoylnicotinic acid esters, that are useful as intermediates for the preparation of the above said herbicidal agents.
    Type: Grant
    Filed: March 23, 1992
    Date of Patent: August 2, 1994
    Assignee: American Cyanamid Company
    Inventors: Robert F. Doehner, Jr., David W. Ladner, John M. Finn
  • Patent number: 5324711
    Abstract: This invention is directed to certain substituted aryloxy benzotriazole compounds which are herbicidal agents. The structures of these compounds are represented by formulas I and II shown below: ##STR1## wherein M is C--X, N or N.sup.+ --O.sup.- ;W, X, Y and Z each independently represent hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy;n is 0, 1 or 2;R is hydrogen, C.sub.1 -C.sub.4 alkyl, aryl or when taken together with R.sub.1, R and R.sub.1 may form a ring in which RR.sub.1 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.1 and R.sub.2 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl or when taken together R.sub.1 and R.sub.2 may form a ring in which R.sub.1 R.sub.2 are represented by the structure --(CH.sub.2).sub.m -- where m is an integer of 2, 3, 4 or 5;R.sub.3 is cyano, ##STR2## CH.sub.2 OR.sub.8 or CH(OR.sub.9).sub.2 ; Q is OH, OR.sub.4 or NR.sub.5 R.sub.6 ;A is O, NOR.sub.5, NCOR.sub.5, NNR.sub.5 R.
    Type: Grant
    Filed: October 5, 1989
    Date of Patent: June 28, 1994
    Assignee: American Cyanamid Company
    Inventors: Donald R. Nielsen, Thomas A. Lies
  • Patent number: 5321002
    Abstract: Herbicidal compounds, compositions containing them, and a method for controlling weeds by application of the compositions are disclosed. The herbicidal compounds are 2-(1-aryl-4-cyano-5-pyrazolylmethyleneiminooxy)alkanoic acid derivatives of the structure: ##STR1## in which R is lower alkyl, lower alkenyl, or lower alkynyl, each optionally substituted with halogen, or CH(R.sup.1)--C(O)--Y--R.sup.2 ; R.sup.1 is hydrogen or lower alkyl; R.sup.2 is one of a variety of substituents; Y is O or NH; Z is lower alkyl or lower alkoxy; and Ar is 3-chloro-5-trifluoromethyl-2-pyridyl, 2,6-dichloro-4-trifluoromethylphenyl, or 2,4,6-trichlorophenyl.
    Type: Grant
    Filed: August 11, 1993
    Date of Patent: June 14, 1994
    Assignee: FMC Corporation
    Inventor: Lester L. Maravetz
  • Patent number: 5306694
    Abstract: The invention describes novel 1-(2-pyridyl)pyrazoles of formula (I) ##STR1## wherein typically preferred substituents are: X is S(O).sub.n R.sub.1, in which R.sub.1 is an alkyl group, preferably a methyl group, which is fully substituted by halogen atoms, and n is 0, 1 and 2;Y is hydrogen, halogen, cyano, alkylsulfenyl, alkylsulfinyl, alkylsulfonyl, alkoxy, amino, alkylamino, dialkylamino, trialkylammonium salt, cyanoalkylamino, alkoxyalkylamino, alkoxycarbonylamino, alkylcarbonylamino, haloalkylcarbonylamino, alkylaminocarbonylamino, dialkylaminocarbonylamino or alkoxyalkylideneimino, wherein the alkyl and alkoxy moieties are a linear or branched chain, containing one to four carbon atoms, and the halo-substitution consists of one or more halogen atoms, which are the same or different, up to full substitution of the alkyl moiety;Z is cyano; andR.sub.2, R.sub.3, R.sub.4, and R.sub.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: April 26, 1994
    Assignee: Rhone-Poulenc Inc.
    Inventors: Jennifer L. Phillips, Philip R. Timmons, Gail S. Powell, Michael T. Pilato, David T. Chou, Jamin Huang
  • Patent number: 5294596
    Abstract: The invention relates to novel heterocyclyltriazolinones of the general formula (I) ##STR1## in which R.sup.1 represents hydrogen or represents alkyl or cycloalkyl, each of which is optionally substituted,R.sup.2 represents hydrogen, hydroxyl, mercapto or halogen or represents alkyl, alkenyl, alkinyl, cycloalkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, arylalkyl, amino or heterocyclyl, each of which is optionally substituted, andHet represents an optionally substituted heterocycle of the formula ##STR2## in which X in each case represents oxygen, sulphur, an NH group or an N-alkyl group,a process for their preparation and their use as herbicides.
    Type: Grant
    Filed: July 21, 1993
    Date of Patent: March 15, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Wilhelm Haas, Kurt Findeisen, Karl-Heinz Linker, Klaus Lurssen, Hans-Joachim Santel, Robert R. Schmidt
  • Patent number: 5290753
    Abstract: The present invention provides a method for protecting or preventing a crop from injury due to the application of a combination of compounds by altering the susceptibility of the crop by incorporating a gene resistant to inhibition by at least one of the compounds in the combination into the genome of the crop.
    Type: Grant
    Filed: May 12, 1992
    Date of Patent: March 1, 1994
    Assignee: American Cyanamid Company
    Inventors: Keith E. Newhouse, Thomas J. Schaefer, Gail E. Cary
  • Patent number: 5278134
    Abstract: The present invention relates to new 3-(aminooxoacetyl)-2-(2-imidazolin-2-yl)pyridines and their salts, having herbicidal activity.
    Type: Grant
    Filed: October 27, 1992
    Date of Patent: January 11, 1994
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Dae W. Kim, Hae S. Chang, Dong J. Jeon, Jae W. Ryu, In T. Hwang
  • Patent number: 5266556
    Abstract: There are disclosed novel arylindazole derivatives of the formula: ##STR1## and agrochemically acceptable salts thereof. Also disclosed are a herbicidal composition including the above arylindazole derivative as an active ingredient and a method for exterminating undesired weeds by the application of a herbicidally effective amount of the above arylindazole derivative to an area where the undesired weeds grow or will grow.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: November 30, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masayuki Enomoto, Susumu Takemura, Masaharu Sakaki, Satoru Kizawa, Eiki Nagano
  • Patent number: 5262387
    Abstract: Pyridine derivatives of the formulae ##STR1## wherein W, X, Y and Z are each C--R.sup.4, N or N.fwdarw.O, with the proviso that the ring contains only one heteroatom, and the substituents R.sup.1, R.sup.2 and R.sup.3 have the following meanings:R.sup.1 is alkoxy, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl,R.sup.2 is hydrogen,R.sup.3 is formyl, 4,5-dihydrooxazol-2-yl or --CO--A--R.sup.5 or --CO--NR.sup.6.sup.R.sup.7, whereR.sup.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: November 16, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Hamprecht, Norbert Goetz, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5260260
    Abstract: A nonionic surfactant blend for use with compatible herbicides. The nonionic surfactant blend includes an effective amount of an acidulated soybean soapstock. The acidulated soybean soapstock includes a range of total fatty acids of about 94%-to-96% by volume and a moisture content of not more than about 5% by volume. The present invention also includes a method for improving the performance of a herbicide. The method includes providing an effective quantity of the improved nonionic surfactant blend for combination with the herbicide.
    Type: Grant
    Filed: May 11, 1992
    Date of Patent: November 9, 1993
    Assignee: Cenex/Land O'Lakes Agronomy Company
    Inventors: Joe V. Gednalske, Robert W. Herzfeld
  • Patent number: 5258357
    Abstract: Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, a substituted or unsubstituted 5- to 6-membered heterocyclic structure or one of the groups stated for R.sup.1, orR.sup.1 and R.sup.2 together are a 4- to 7-membered chain which contains, in addition to methylene groups, one of the following groups as ring member: oxygen, sulfur, N-methyl or carbonyl;R.sup.3 and R.sup.4 are each nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, a substituted or unsubstituted 5- to 6 -membered heterocyclic structure, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y=O,S);R.sup.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: November 2, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Muenster, Gerd Steiner, Wolfgang Freund, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5256626
    Abstract: The disclosure herein relates to a new family of haloalkyl oxazolidinyl derivatives as antidotal compounds to reduce injury to crop plants by a variety of herbicides. The antidotal compounds are characterized particularly by having heterocyclyl or spiroheterocyclyl radicals attached to the 5-position of haloalkyl oxazolidine compounds and are especially useful as in-can antidotes against injury by acetanilide and thiocarbamate herbicides to corn, sorghum, soybeans, wheat, rice and other crops.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: October 26, 1993
    Assignee: Monsanto Company
    Inventors: Eric L. Williams, Steven M. Massey, Brett H. Bussler, Ronald J. Brinker
  • Patent number: 5256632
    Abstract: Herbicidal sulphonylated carboxamides of the formulaR.sup.1 --CO--NH--SO.sub.2 --(A).sub.n --R.sup.2 (I)in whichn represents the numbers 0 or 1,A represents oxygen, iminio (NH) or methylene (CH.sub.2),R.sup.1 represents a five-membered heteroaryl radical which contains 1 or 2 nitrogen atoms and additionally one oxygen or sulphur atom in the ring and which is optionally substituted by halogen or by alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkylamino, dialkylamino or phenyl which are in each case optionally substituted, andR.sup.2 represents aryl or heteroaryl which are in each case optionally substituted,or salts thereof, with the exclusion of the compound 2-dimethylamino-N-(4-methyl-phenylsulphonyl)-5-thiazole carboxamide.
    Type: Grant
    Filed: June 18, 1992
    Date of Patent: October 26, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hilmar Wolf, Rolf Kirsten, Hans-Joachim Santel, Klaus Lurssen, Robert R. Schmidt
  • Patent number: 5256625
    Abstract: The disclosure herein relates to the use of certain amides of dichloroacetic acid and other compounds as safener/antidotal compounds to reduce the phytotoxicity to crop plants, especially corn, of imidazolinone-type herbicides alone or in admixture with other co-herbicidal compounds, e.g., .alpha.-haloacetamides.
    Type: Grant
    Filed: December 29, 1989
    Date of Patent: October 26, 1993
    Assignee: Monsanto Company
    Inventors: Brett H. Bussler, Ronald J. Brinker
  • Patent number: 5244866
    Abstract: This invention relates to the use of acetohydroxyacid synthase (AHAS) inhibiting herbicides to prevent or delay sprout formation in agronomic crops. More particularly, this invention relates to the application of imidazolinones on tubers, such as potatoes, to inhibit the post-harvest growth of sprouts.
    Type: Grant
    Filed: July 31, 1992
    Date of Patent: September 14, 1993
    Assignee: American Cyanamid Company
    Inventor: Peter N. Tayler
  • Patent number: 5217523
    Abstract: Pyrazole-3-carboxamides of the general formula I ##STR1## where the substituents have the following meaning: R.sup.1 hydrogen;substituted or unsubstituted C.sub.3 -C.sub.8 -cycloalkyl or C.sub.1 C.sub.6 -alkyl;R.sup.2 hydroxy; amino; C.sub.1 -C.sub.4 -alkylamino; di-C.sub.1 -C.sub.4 -alkylamino, aminocarbonyl-C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl or naphthyl,a substituted or unsubstituted 5- to 6-membered heterocyclic ring;one of the groups mentioned for R.sup.1 orR.sup.1 and R.sup.2 together denote a 4- to 7-membered chain which may contain, in addition to methylene groups one of the following groups as ring member: oxygen, sulfur N-methyl or carbonyl;R.sup.3 a substituted or unsubstituted 5- to 6-membered heterocyclic ring.substituted or unsubstituted C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl orone of the groups mentioned for R.sup.1 ;R.sup.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: June 8, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Ditrich, Gerhard Hamprecht, Peter Plath, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5216171
    Abstract: 2-Amino-4-trichloromethylpyridines of the general formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl,R.sup.2 is C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.4 -alkenyl or phenyl, benzyl or phenylsulfonyl,--CX--R.sup.3, --SO.sub.2 R.sup.3 or --PX(OR.sup.4).sub.2 orR.sup.1 and R.sup.2 together form .dbd.CR.sup.5 R.sup.6 or --CO--Z--CO--,X is oxygen or sulfur,R.sup.3 is C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.6 -alkenyl, amino, C.sub.1 -C.sub.6 -alkylamino, di-C.sub.1 -C.sub.6 -alkylamino, morpholino, piperidino, pyrazolidino or C.sub.1 -C.sub.8 -alkylcarbonylamino, substituted or unsubstituted phenylamino or benzylamino,R.sup.4 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -haloalkyl or substituted or unsubstituted phenyl,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl, or substituted or unsubstituted phenyl,R.sup.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: June 1, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Helmut Hagen, Hans Ziegler, Juergen Pfister, Gerhard Nilz, Gisela Lorenz, Juergen Dressel
  • Patent number: 5215568
    Abstract: This disclosure describes new 5-oximio-2-(2-imidazolin-2-yl) pyridines having the following structure: ##STR1## wherein Y is hydrogen, C.sub.1 -C.sub.4 branched or unbranched alkyl optionally substituted with C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthiol, halogen, CO.sub.2 R.sub.4, CN, NHCOR.sub.5, OCOR.sub.4, furyl or a phenyl group optionally substituted with one or two halogens, C.sub.1 -C.sub.2 alkyl or nitro, C.sub.1 -C.sub.4 alkenyl optionally substituted with halogen or C.sub.1 -C.sub.4 alkoxy, or C.sub.1 -C.sub.4 alkynyl; and Z is hydrogen or C.sub.1 -C.sub.4 alkyl. The disclosure further describes the unique method of using the compounds as herbicidal agents and the methods for their preparation.
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: June 1, 1993
    Assignee: American Cyanamid Company
    Inventor: John M. Finn
  • Patent number: 5213606
    Abstract: 4-Carboxy-2-aryloxyphenoxyalkyl substituted heterocycle compounds which are effective for the selective control of grass weed species in the presence of crops are described. Also described are a method for the selective herbicidal use of the compounds and methods for their preparation.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: May 25, 1993
    Assignee: American Cyanamid Company
    Inventors: Robert L. Arotin, Michael A. Guaciaro
  • Patent number: 5209769
    Abstract: The invention relates to new substituted triazolinones of the general formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, A, X and Y have the meanings given in the description,to a plurality of processes for their preparation, and to their use as herbicides.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: May 11, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Kurt Findeisen, Dietmar Kuhnt, Klaus-Helmut Muller, Michael Haug, Klaus Konig, Klaus Lurssen, Hans-Joachim Santel, Robert R. Schmidt