1,2-diazoles (including Hydrogenated) Patents (Class 504/280)
  • Patent number: 5945382
    Abstract: The present invention relates to new derivatives of the family of 3-arylpyrazoles of formula (I), their methods of preparation, the compositions containing them and their utilization for the protection of plants against fungal diseases.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: August 31, 1999
    Assignee: Rhone-Poulenc Agrochimie
    Inventors: Richard Cantegril, Denis Croisat, Philippe Desbordes, Fran.cedilla.ois Guigues, Jacques Mortier, Raymond Peignier, Jean Pierre Vors
  • Patent number: 5939559
    Abstract: A pyrazole derivative represented by the general formula (1a) or (1b): whereinR.sup.1 represents a hydrogen atom or a pesticidally acceptable protecting group; R.sup.2 and R.sup.3 represent a phenyl, 1-naphthyl or 2-naphthyl group, or a 5-6 membered heterocyclic ring and the like; R.sup.4 represents a hydrogen or halogen atom, or a alkyl, alkoxy or alkylthio group; and a herbicidal composition containing the pyrazole derivative.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: August 17, 1999
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Katsushi Morimoto, Tomoyuki Ogura, Takeshi Nagaoka, Hiroyuki Furusawa, Koichi Nishio, Shigeru Ishii, Tsutomu Nawamaki, Kunimitsu Nakahira, Kimihiro Ishikawa
  • Patent number: 5869427
    Abstract: A novel substituted thiophene derivatives represented by the formula (1) in the invention: ##STR1## wherein R is a straight or branched alkyl group having 3-12 carbon atoms, straight or branched halogenoalkyl group having 3-12 carbon atoms, straight or branched alkenyl group having 3-10 carbon atoms, straight or branched halogenoalkenyl group having 3-10 carbon atoms, or cycloalkyl group having 3-10 carbon atoms, the cycloalkyl group being unsubstituted or substituted with an alkyl group having 1-4 carbon atoms, R and --NHCOAr are adjacent to each other, and Ar is a heterocyclic group; have excellent control activity on various plant disease such as Gray mold, Powdery mildew, Blast and Rust, and are useful as a plant disease control agent due to outstanding residual effect on Botrytis cinerea and excellent effect on Gibberella zeae.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: February 9, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yukihiro Yoshikawa, Kanji Tomiya, Toshio Kitajima, Hiroyuki Katsuta, Osamu Takahashi, Shunichi Inami, Yuji Yanase, Naofumi Tomura, Junro Kishi, Hideo Kawasima
  • Patent number: 5861359
    Abstract: Novel herbicidal compounds, compositions containing them, and methods for their use in controling weeds are disclosed. The novel herbicidal compounds are optionally substituted phenylmethoxy or phenylmethylthio heterocycles of the formula: ##STR1## in which Q is selected from: ##STR2## R=halogen; R.sup.1 =lower alkyl, lower alkoxy, lower haloalkyl, lower haloalkoxy, lower alkylthio, lower sulfonyl, or lower alkylsulfinyl; R.sup.2 =lower alkyl, or lower haloalkyl; X=H, halogen, or lower alkyl; W=O or S; Z, Z.sup.1, Z.sup.2 are independently selected from H, halogen, straight or branched chain lower alkyl, lower alkoxy, is lower haloalkoxy, cyano, lower cyanoalkyloxy, or aryl; or Z and Z.sup.1 are adjacent to each other on the benzene ring, and taken together are --(CH.sub.2).sub.4 --; or Z.sup.2 is OA in the 2-, 3-, or 4-position of the phenyl ring; A is a derivative of an alkanoate bonded to the phenoxy oxygen at the alpha carbon; R.sup.3 is H or lower alkyl; R.sup.
    Type: Grant
    Filed: July 18, 1996
    Date of Patent: January 19, 1999
    Assignee: FMC Corporation
    Inventor: George Theodoridis
  • Patent number: 5840653
    Abstract: Novel substituted pyrazolylpyrazoles of the formula I ##STR1## in which R.sup.1 -R.sup.6 are as defined in the description, processes for their preparation and intermediates for their preparation and their use as herbicides are described.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: November 24, 1998
    Assignee: Hoechst Schering AgrEvo GmbH
    Inventors: Michael Ganzer, Helga Franke, Uwe Hartfiel, Jurgen Bohner
  • Patent number: 5840912
    Abstract: The invention relates to new substituted pyrazol derivatives of general formula (I) in which: R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the meanings given in the description, agents with herbicidal action containing at least one compound of formula (I), and their use as herbicides.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: November 24, 1998
    Assignee: Hoechst Schering AgrEvo GmbH
    Inventors: Jens Geisler, Helga Franke, Uwe Hartfiel, Michael Ganzer, Jurgen Bohner, Richard Rees
  • Patent number: 5731267
    Abstract: Compounds of the formula I ##STR1## in which R is hydrogen, fluorine or chlorine;R.sub.1 is hydrogen, halogen, trifluoromethyl, C.sub.1 -C.sub.4 haloalkoxy, cyano, nitro or amino;A-B is a group ##STR2## in which the 2 carbon atom is bonded to the oxygen atom; W is a group ##STR3## R.sub.2 is hydrogen or C.sub.1 -C.sub.6 -alkyl; R.sub.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, cyano-C.sub.1 -C.sub.4 alkyl, hydroxy-C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy-C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyloxy-C.sub.1 -C.sub.4 -alkyl, C.sub.3 -C.sub.6 alkynyloxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.6 alkylcarbonyloxy-C.sub.1 -C.sub.6 alkyl, carboxyl, C.sub.1 -C.sub.6 alkoxycarbonyl, C.sub.1 -C.sub.6 haloalkoxycarbonyl, C.sub.3 -C.sub.6 alkenyloxycarbonyl, C.sub.3 -C.sub.6 alkynyloxycarbonyl, C.sub.3 -C.sub.6 cycloalkoxycarbonyl, C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylaminocarbonyl, di-C.sub.1 -C.sub.
    Type: Grant
    Filed: March 19, 1997
    Date of Patent: March 24, 1998
    Assignee: Novartis Corporation
    Inventors: Georg Pissiotas, Kurt Nebel, Hans-Georg Brunner
  • Patent number: 5719104
    Abstract: Bicyclic imides of formulae (I) and (II) and their agriculturally-suitable salts, are disclosed which are useful for controlling undesirable vegatation, wherein G is O or S; n and m are each independently 0; 1; 2; or 3; provided that m+n is 2 or 3; q is 1 or 2; X is CH.sub.2 ; CH(halogen); CF.sub.2 ; CHOCH.sub.2 F; CHOCF.sub.3 ; CHOCH.sub.2 CF.sub.3 ; O; S(O).sub.0-2 ; NH; N(C.sub.1 -C.sub.4 alkyl); or N(C.sub.1 -C.sub.4 haloalkyl); and R.sup.1. R.sup.2, and Q are as defined in the disclosure. Also disclosed are compositions containing the bicyclic imides of formulae (I) and (II) and a method for controlling growth of undesired vegetation comprising applying to the locus to be protected an effective amount, of the bicyclic imides formulae (I) and (II).
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: February 17, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: John J. Kilama, Karlheinz Drauz, Wonpyo Hong, Matthias Schafer
  • Patent number: 5707934
    Abstract: This invention relates to a new method of plant growth regulation whereby a 1-phenylpyrazole such as fipronil is applied to a crop or a seed.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: January 13, 1998
    Assignee: Rhone-Poulenc Inc.
    Inventors: Reed Nathan Royalty, Nguyen Dang Long, Michael Thomas Pilato, Nicholas Mark Hamon, Ngadi Yahmad, Djoko Prabowo Sastrosatomo
  • Patent number: 5674811
    Abstract: A cyanoketone derivatives of the following formula (1) ##STR1## which are characterized by excellent herbicidal activity and effectiveness against a variety of broad leafed weeds, including barnyard grass, green foxtail, velvet leaf, livid amaranth and hairy beggar ticks.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: October 7, 1997
    Assignee: Tokuyama Corporation
    Inventors: Toshio Kitajima, Tadashi Kobutani, Shozo Kato, Masao Yamaguchi, Masahiko Ishizaki, deceased
  • Patent number: 5670456
    Abstract: N-carbamoyl-2-carboxyaryl-heterocyclic and hydrazinecarboximidamidehydrazone derivatives, intermediates and processes for their preparation, agricultural compositions containing them and their use as agricultural chemicals, in particular herbicides.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: September 23, 1997
    Assignee: Sandoz Ltd.
    Inventors: Richard J. Anderson, Joe T. Bamberg, Michael M. Leippe
  • Patent number: 5668088
    Abstract: The invention herein relates to certain substituted-arylpyrazole compounds, herbicidal compositions containing same, herbicidal methods of use and processes for preparing said compounds.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 16, 1997
    Assignee: Monsanto Company
    Inventors: Bruce C. Hamper, Lisa L. Mc Dermott
  • Patent number: 5663119
    Abstract: Phenylpyrazoles of the formula: ##STR1## in which: X=H, hal, NO.sub.2, CN, SCN, alkyl (C.sub.1 -C.sub.4), alkenyl (C.sub.2 -C.sub.4), alkynyl (C.sub.2 -C.sub.4), alkoxy (C.sub.1 -C.sub.4), alkylthio (C.sub.1 -C.sub.4), phenyl, phenoxy; mono- or di- alkyl- or phenyl- amino; alkylcarbonyl, carbamoyl, carboxyl, benzoyl; alkyl- sulphinyl or sulphonyl;Y, Z=H, hal, OH, NO.sub.2, NO, CN, SCN, alkyl (C.sub.1 -C.sub.4), alkenyl (C.sub.2 -C.sub.4), alkynyl (C.sub.2 -C.sub.4), alkoxy (C.sub.1 -C.sub.4), alkylthio (C.sub.1 -C.sub.4), phenyl, phenoxy; mono- or di- alkyl- or phenyl- amino; alkylcarbonyl, carbamoyl, carboxyl, benzoyl; alkyl- sulphinyl or sulphonyl, for example; andY, Z may also form a bridge of 1 to 4 atoms, of which at least one can be a hetero atom, optionally substituted. The products are useful as fungicides in agriculture.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 2, 1997
    Assignee: Rhone-Poulenc Agrochimie
    Inventors: Alain Chene, Raymond Peignier, Jean-Pierre A. Vors, Jacques Mortier, Richard Cantegril, Denis Croisat
  • Patent number: 5629265
    Abstract: Disclosed herein are cyanoketone derivatives of the following formula (1) ##STR1## such as 1-cyano-1-piperidinocarbonyl-3-[4-(2-chloro-4-trifluoromethylphenoxy)pheno xy]-2-butanone, 1-cyano-1-piperidinocarbonyl-3-[4-(3-chloro-5-trifluoromethyl-2-pyridyloxy )phenoxy]-2-butanone, 1-cyano-1-(N-methyl-N-dichlorophenyl)aminocarbonyl-3-[4-(2-quinoxalyloxy)p henoxy]-2-butanone, 1-cyano-1-(N,N-dibutyl)aminocarbonyl-3-[4-(3-chloro-5-trifluoromethyl-2-py ridyloxy)phenoxy-2-butanone, and the like, which are characterized by excellent herbicidal activity and effectiveness against a variety of gramineous weeds.
    Type: Grant
    Filed: June 22, 1994
    Date of Patent: May 13, 1997
    Assignee: Tokuyama Corporation
    Inventors: Masahiko Ishizaki, Seiji Nagata, Junji Takenaka
  • Patent number: 5622917
    Abstract: The invention relates to new 1H-3-aryl-pyrrolidine-2,4-dione derivatives of the formula (I) ##STR1## in which A, B, X, Y and G have the meanings given in the description, to a plurality of processes for their preparation, and to their use as pesticides.
    Type: Grant
    Filed: January 3, 1995
    Date of Patent: April 22, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reiner Fischer, Thomas Bretschneider, Bernd-Wieland Kr uger, Michael Ruther, Christoph Erdelen, Ulrike Wachendorff-Neumann, Hans-Joachim Santel, Markus Dollinger
  • Patent number: 5618775
    Abstract: Mixtures of optically active cyclohexenone oxime ethers having R- and S-configuration in the oxime ether moiety of the formula I ##STR1## (R.sup.1 =C.sub.1 -C.sub.6 -alkyl; ##STR2## X=C.sub.1-C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl; m=0-3 or 1-4 where all X's are halogen;n=0-3 or 1-5 where all X's are halogen;R.sup.2 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkenyl, substituted or unsubstituted 5-membered saturated heterocyclic structure, substituted or unsubstituted 6- or 7-membered heterocyclic structure, substituted or unsubstituted 5-membered heteroaromatic structure, substituted or unsubstituted phenyl or pyridyl)and their agriculturally useful salts and esters with C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: April 8, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Wolfgang Ladner, Helmut Walter, Karl-Otto Westphalen, Uwe Kardorff, Matthias Gerber
  • Patent number: 5573999
    Abstract: .beta.-Substituted cinnamic acid derivatives of the formula 1, ##STR1## where R.sup.1 is alkyl, chlorine or bromine, --X-- is --O--, --S--, ##STR2## m is 0 or 1, --Y is --OR.sup.4, --O--N.dbd.CR.sup.5 R.sup.6, --NR.sup.7 R.sup.8, --N(OR.sup.9)R.sup.10 or --SR.sup.11, where the above-mentioned substituents R.sup.2 to R.sup.11 are alkyl, and R.sup.2, and R.sup.3 and R.sup.5 to R.sup.11 can also be hydrogen,Z is halogen, nitro, cyano, alkyl, cycloalkyl, aralkyl, aryloxyalkyl, arylthioalkyl, hetarylalkyl, hetaryloxyalkyl, hetarylthioalkyl, alkenyl, aralkenyl, aryloxyalkenyl, arylthioalkenyl, hetarylalkenyl, hetaryloxyalkenyl, hetarylthioalkenyl, alkynyl, arylalkynyl, hetarylalkynyl, aryl, hetaryl, arylazo, acylamino, --OR.sup.12, --SR.sup.13, --SOR.sup.14, --SO.sub.2 R.sup.15, --COOR.sup.16, --CONR.sup.17 R.sup.18, --COR.sup.19, --CR.sup.20 .dbd.NR.sup.21, --N.dbd.CR.sup.22, R.sup.23, --CR.sup.24 .dbd.N--OR.sup.25, --CR.sup.25 R.sup.26 --O--, N.dbd.CR.sup.27 R.sup.28, --CH.sub.2 --OCOR.sup.39 or --NR.sup.37 R.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: November 12, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Hubert Sauter, Herbert Bayer, Klaus Oberdorf, Horst Wingert, Wolfgang von Deyn, Wassilios Grammenos, Hartmann Koenig, Harald Rang, Franz Roehl, Gisela Lorenz, Eberhard Ammermann
  • Patent number: 5538940
    Abstract: .beta.-Substituted cinnamic acid derivatives of the formula 1, ##STR1## where R.sup.1 is substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl, and R.sup.1 can also be chlorine or bromine,--X-- is --O--, --S--, ##STR2## m is 0 or 1, --Y is --OR.sup.4, --O--N.dbd.CR.sup.5 R.sup.6, --NR.sup.7 R.sup.8, --NR.sup.7 R.sup.8, --N(OR.sup.9)R.sup.10 or SR.sup.11, where the abovementioned substitutes R.sup.2 to R.sup.11 are substituted or unsubstituted alkyl, alkenyl, alkynyl, cycloalkyl or cycloalkenyl, and R.sup.2, R.sup.3 and R.sup.5 to R.sup.11 can be hydrogen and Z, U, V, W are defined in the specification.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: July 23, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Hubert Sauter, Herbert Bayer, Klaus Oberdorf, Horst Wingert, Wolfgang Von Deyn, Wassilios Grammenos, Hartmann Koenig, Harald Rang, Franz Roehl, Gisela Lorenz, Eberhard Ammermann
  • Patent number: 5536700
    Abstract: Herbicidal compositions of glyphosate, its salts, diquat, or paraquat in combination with a compound of the following formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, and n are as defined. Preferred are combinations of glyphosate, its salts, diquat, or paraquat with 2-chloro-5-(4-bromo-1-methyl-5-(trifluoromethyl)-1H-pyrazol-3-yl)-4-fluoro benzoic acid, 1-methylethyl ester.
    Type: Grant
    Filed: December 20, 1993
    Date of Patent: July 16, 1996
    Assignee: Monsanto Company
    Inventors: Scott S. Woodard, Bruce C. Hamper, Kurt Moedritzer, Michael D. Rogers, Deborah A. Mischke, Gerard A. Dutra
  • Patent number: 5523280
    Abstract: Phenylpyrazoles of the formula: ##STR1## in which: X.dbd.H, hal, NO.sub.2, CN, SCN, alkyl (C.sub.1 -C.sub.4), alkenyl (C.sub.2 -C.sub.4), alkynyl (C.sub.2 -C.sub.4), alkoxy (C.sub.1 -C.sub.4), alkylthio (C.sub.1 -C.sub.4), phenyl, phenoxy; mono- or di- alkyl- or phenyl- amino; alkylcarbonyl, carbamoyl, carboxyl, benzoyl; alkyl- sulphinyl or sulphonyl;Y, Z.dbd.H, hal, OH, NO.sub.2, NO, CN, SCN, alkyl (C.sub.1 -C.sub.4), alkenyl (C.sub.2 -C.sub.4), alkynyl (C.sub.2 -C.sub.4), alkoxy (C.sub.1 -C.sub.4), alkylthio (C.sub.1 -C.sub.4), phenyl, phenoxy; mono- or di- alkyl- or phenyl- amino; alkylcarbonyl, carbamoyl, carboxyl, benzoyl; alkyl- sulphinyl or sulphonyl, for example; andY, Z may also form a bridge of 1 to 4 atoms, of which at least one can be a hetero atom, optionally substituted. The products are useful as fungicides in agriculture.
    Type: Grant
    Filed: October 9, 1992
    Date of Patent: June 4, 1996
    Assignee: Rhone-Poulenc Agrochimie
    Inventors: Alain Chene, Raymond Peignier, Jean-Pierre A. Vors, Jacques Mortier, Richard Cantegril, Denis Croisat
  • Patent number: 5496792
    Abstract: Cyclohexenone oxime ethers I ##STR1## R.sup.1 =C.sub.1 -C.sub.6 -alkyl; W=unsubstituted or C.sub.1 -C.sub.3 -alkyl-substituted C.sub.2 -C.sub.4 -alkylene chain;X=NO.sub.2, CN, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl; n=0-3 or 1-5 if all X's are halogen;R.sup.2 =C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, substituted or unsubstituted C.sub.3 -C.sub.7 -cycloalkyl, substituted or unsubstituted C.sub.5 -C.sub.7 -cycloalkenyl, a substituted or unsubstituted 5-membered saturated heterocycle containing 1 or 2 oxygen and/or sulfur atoms, substituted or unsubstituted 6- or 7-membered heterocycle having 1 or 2 non-adjacent oxygen and/or sulfur atoms and which is saturated or mono- or diunsaturated, substituted or unsubstituted 5-membered heteroaromatic containing 1 or 2N atoms and one O or S atom, phenyl or pyridyl, both of which are unsubstituted or bear 1-3 halogen, NO.sub.
    Type: Grant
    Filed: August 11, 1994
    Date of Patent: March 5, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Kaspar Bott, Helmut Walter, Karl-Otto Westphalen, Uwe Kardorff, Matthias Gerber
  • Patent number: 5489571
    Abstract: The invention herein relates to certain substituted-arylpyrazole compounds, herbicidal compositions containing same, herbicidal methods of use and processes for preparing said compounds.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: February 6, 1996
    Assignee: Monsanto Company
    Inventors: Scott S. Woodard, Bruce C. Hamper, Kurt Moedritzer, Michael D. Rogers, Deborah A. Mischke, Gerard A. Dutra
  • Patent number: 5389602
    Abstract: Tetrahydropyran-2,4-diones of the formula ##STR1## where R.sup.1 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; substituted or unsubstituted phenyl; C.sub.1 -C.sub.6 -alkylsulfonyl; substituted or unsubstituted benzenesulfonyl; C.sub.3 -C.sub.6 -alkenylcarbonyl; or substituted or unsubstituted benzoyl;R.sup.2 is C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -haloalkyl; or C.sub.3 -C.sub.6 -cycloalkyl;A, B and D are each .dbd.CH-- or .dbd.N--;E is oxygen, sulfur or --NR.sup.7 --.R.sup.7 is hydrogen; C.sub.1 -C.sub.6 -alkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkanoyl; substituted or unsubstituted benzoyl; benzyl; or substituted or unsubstituted phenyl;X is halogen; C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.3 -C.sub.6 -cycloalkyl; C.sub.2 -C.sub.6 -alkenyl; C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.6 -alkoxy; C.sub.2 -C.sub.6 -alkenyloxy; C.sub.1 -C.sub.6 -alkylthio; C.sub.1 -C.sub.
    Type: Grant
    Filed: June 15, 1993
    Date of Patent: February 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Kast, Dieter Kolassa, Norbert Meyer, Bruno Wuerzer, Karl-Otto Westphalen, Wilhelm Rademacher, Johann Jung
  • Patent number: 5380350
    Abstract: The present invention provides methods of making hygroscopic pesticidal salt formulations in the form of dispersible granules.
    Type: Grant
    Filed: October 30, 1992
    Date of Patent: January 10, 1995
    Assignee: BASF Corporation
    Inventor: Ken Fersch
  • Patent number: 5321002
    Abstract: Herbicidal compounds, compositions containing them, and a method for controlling weeds by application of the compositions are disclosed. The herbicidal compounds are 2-(1-aryl-4-cyano-5-pyrazolylmethyleneiminooxy)alkanoic acid derivatives of the structure: ##STR1## in which R is lower alkyl, lower alkenyl, or lower alkynyl, each optionally substituted with halogen, or CH(R.sup.1)--C(O)--Y--R.sup.2 ; R.sup.1 is hydrogen or lower alkyl; R.sup.2 is one of a variety of substituents; Y is O or NH; Z is lower alkyl or lower alkoxy; and Ar is 3-chloro-5-trifluoromethyl-2-pyridyl, 2,6-dichloro-4-trifluoromethylphenyl, or 2,4,6-trichlorophenyl.
    Type: Grant
    Filed: August 11, 1993
    Date of Patent: June 14, 1994
    Assignee: FMC Corporation
    Inventor: Lester L. Maravetz
  • Patent number: 5258357
    Abstract: Carboxamides of the formulae Ia to Ic ##STR1## where X is oxygen or sulfur;R.sup.1 is hydrogen or substituted or unsubstituted cycloalkyl or alkyl;R.sup.2 is hydroxy, alkoxy, cyanoalkyl, substituted or unsubstituted alkenyl, alkynyl, phenyl or naphthyl, a substituted or unsubstituted 5- to 6-membered heterocyclic structure or one of the groups stated for R.sup.1, orR.sup.1 and R.sup.2 together are a 4- to 7-membered chain which contains, in addition to methylene groups, one of the following groups as ring member: oxygen, sulfur, N-methyl or carbonyl;R.sup.3 and R.sup.4 are each nitro, cyano, halogen, substituted or unsubstituted amino, alkoxy, alkylthio, a substituted or unsubstituted 5- to 6 -membered heterocyclic structure, substituted or unsubstituted alkenyl, alkynyl, phenyl, phenoxy or phenylthio, or one of the groups stated for R.sup.1 ;R.sup.5 is formyl, 4,5-dihydrooxazol-2-yl or COYR.sup.6 (Y=O,S);R.sup.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: November 2, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Peter Muenster, Gerd Steiner, Wolfgang Freund, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5256626
    Abstract: The disclosure herein relates to a new family of haloalkyl oxazolidinyl derivatives as antidotal compounds to reduce injury to crop plants by a variety of herbicides. The antidotal compounds are characterized particularly by having heterocyclyl or spiroheterocyclyl radicals attached to the 5-position of haloalkyl oxazolidine compounds and are especially useful as in-can antidotes against injury by acetanilide and thiocarbamate herbicides to corn, sorghum, soybeans, wheat, rice and other crops.
    Type: Grant
    Filed: July 3, 1991
    Date of Patent: October 26, 1993
    Assignee: Monsanto Company
    Inventors: Eric L. Williams, Steven M. Massey, Brett H. Bussler, Ronald J. Brinker
  • Patent number: 5252540
    Abstract: Sulfonamides of the formula I ##STR1## where A is an unsubstituted or substituted aromatic or heteroaromatic radical; W is oxygen or sulfur; B is an unsubstituted or substituted furyl, thienyl, pyrrolyl, oxazolyl, isothiazolyl, imidazolyl, pyrazolyl, thiadiazolyl, oxadiazolyl or triazolyl radical, and the environmentally compatible salts thereof are prepared as described and are used as herbicides.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: October 12, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Elisabeth Heistracher, Klaus Fischer, Horst Mayer, Thomas Saupe, Gerhard Hamprecht, Klaus Ditrich, Thomas Kuekenhoehner, Matthias Gerber, Helmut Walter, Karl-Otto Westphalen
  • Patent number: 5250503
    Abstract: Monoclinic 2-chloro-(2',6'-dimethyl-N-pyrazol-1-ylmethyl)-actanilide of the formula ##STR1## which melts at 76.degree. C. Processes for its preparation and herbicides.
    Type: Grant
    Filed: July 24, 1992
    Date of Patent: October 5, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Keil, Bjoern Girgensohn, Gotthard Synnatschke, August Wigger, Hans Ziegler, Walter Gueckel
  • Patent number: 5250504
    Abstract: This application discloses herbicidal .beta.-pyrazolylacrylic acids, compositions containing them, methods of preparing them, and methods for controlling undesired plant growth by preemergent or postemergent application of the herbicidal compositions to the locus where control is desired. The herbicidal compounds have the formula ##STR1## in which X is chlorine or fluorine, X.sup.1 is hydrogen, chlorine, or fluorine, X.sup.2 is chlorine, fluorine, trifluoromethyl, or ethoxy, and X.sup.3 is hydrogen, chlorine, or fluorine; M is --CH--, --CF--, or --CCl--; and R.sup.1 is --CH.dbd.C(--R.sup.2)--C(.dbd.O)--Z--[S(O).sub.2 ].sub.n --R.sup.3 in which R.sup.2 is hydrogen or methyl; R.sup.3 is hydrogen, lower alkyl, or phenylmethyl optionally substituted with one or more of chlorine, bromine, fluorine, or methyl; Z is --O--, --S-- or --NR.sup.4 ; and n is 0 or 1; provided that when Z is --O-- or --S--, n is 0.
    Type: Grant
    Filed: January 29, 1993
    Date of Patent: October 5, 1993
    Assignee: FMC Corporation
    Inventor: Lester L. Maravetz
  • Patent number: 5228898
    Abstract: This invention relates to substituted bicycloheptadione derivatives with high herbicidal activity which are represented by general formula (I) ##STR1## (where R.sup.1 is a lower alkyl group, a phenyl group which may be substituted, an aralkyl group which may be substituted, or a heterocyclic group which may be substituted;R.sup.2 is, same or different, a halogen, an alkoxy group, an alkylthio group, an alkylsulfonyl group, an alkyl group, an alkoxyalkyl group, or an alkoxylcarbonyl group, and n is 0 to 4;R.sup.3 and R.sup.4 are, same or different, hydrogen or a lower alkyl group).
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: July 20, 1993
    Assignee: Nippon Soda Co., Ltd.
    Inventors: Akiyoshi Ueda, Shigemi Suga, Hiroyuki Adachi, Toshio Aihara, Kazuyuki Tomida, Hideki Yamagishi, Hideo Hosaka
  • Patent number: 5217523
    Abstract: Pyrazole-3-carboxamides of the general formula I ##STR1## where the substituents have the following meaning: R.sup.1 hydrogen;substituted or unsubstituted C.sub.3 -C.sub.8 -cycloalkyl or C.sub.1 C.sub.6 -alkyl;R.sup.2 hydroxy; amino; C.sub.1 -C.sub.4 -alkylamino; di-C.sub.1 -C.sub.4 -alkylamino, aminocarbonyl-C.sub.1 -C.sub.6 -alkyl; substituted or unsubstituted C.sub.1 -C.sub.4 -alkoxy, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl or naphthyl,a substituted or unsubstituted 5- to 6-membered heterocyclic ring;one of the groups mentioned for R.sup.1 orR.sup.1 and R.sup.2 together denote a 4- to 7-membered chain which may contain, in addition to methylene groups one of the following groups as ring member: oxygen, sulfur N-methyl or carbonyl;R.sup.3 a substituted or unsubstituted 5- to 6-membered heterocyclic ring.substituted or unsubstituted C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 alkynyl, 5,6,7,8-tetrahydronaphthyl or phenyl orone of the groups mentioned for R.sup.1 ;R.sup.
    Type: Grant
    Filed: May 4, 1992
    Date of Patent: June 8, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Ditrich, Gerhard Hamprecht, Peter Plath, Bruno Wuerzer, Karl-Otto Westphalen
  • Patent number: 5207816
    Abstract: Cyclohexenone derivatives of the formula ##STR1## where R.sup.1 is alkyl, R.sup.2 is alkyl, unsubstituted or halogen-substituted alkenyl or alkynyl, X is a substituted or unsubstituted five-membered heteroaromatic radical, and Z is hydrogen, methoxycarbonyl, ethoxycarbonyl, methyl or cyano, processes for their manufacture, and the use of these compounds for controlling undesirable plant growth.
    Type: Grant
    Filed: June 6, 1991
    Date of Patent: May 4, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Becker, Dieter Jahn, Michael Keil, Hans Theobald, Wolfgang Spiegler, Bruno Wuerzer
  • Patent number: 5198014
    Abstract: This application discloses hebricidal B-pyrazolylacrylic acids, compositions containing them, methods of preparing them, and methods for controlling undesired plant growth by preemergent or postemergent application of the herbicidal compositions to the locus where control is desired. The herbicidal compounds have the formula ##STR1## in which the radicals are defined in the claims.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: March 30, 1993
    Assignee: FMC Corporation
    Inventor: Lester L. Maravetz
  • Patent number: 5186737
    Abstract: Insecticidal, acaricidal, herbicidal and antimycotic 3-aryl-pyrrolidine-2,4-diones of the formula ##STR1## in which X represents alkyl, halogen or alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,Z represents alkyl, halogen or alkoxy,n represents a number from 0-3,R represents hydrogen or represents the groups --CO--R.sup.1 or --CO--O--R.sup.2,in whichR.sup.1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl which can be interrupted by hetero atoms, each of which radicals is optionally substituted by halogen, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, andR.sup.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: February 16, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reiner Fischer, Bernd Baasner, Hermann Hageman, Andreas Krebs, Albrecht Marhold, Hans-Joachim Santel, Robert R. Schmidt, Klaus Lurssen, Benedikt Becker, Klaus Schaller, Harry Strang