Benzene Ring Bonded Directly To The Cyano Or Isocyano Group Patents (Class 504/310)
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Patent number: 9161537Abstract: Compounds of the formula (I) or salts thereof in which R1 and (R2)n are as defined in Claim 1 are suitable as herbicides for the control of harmful plants or as plant growth regulators. The compounds can be prepared by the processes of Claim 7.Type: GrantFiled: December 17, 2012Date of Patent: October 20, 2015Assignee: BAYER INTELLECTUAL PROPERTY GMBHInventors: Harald Jakobi, Marc Morsin, Hansjörg Dietrich, Elmar Gatzweiler, Isolde Haeuser-Hahn, Ines Heinemann, Christopher Hugh Rosinger
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Patent number: 9049863Abstract: Compounds of the formula (I) or salts thereof, in each case in the optically active (3R,4R)-threo form, in which R1 is hydrogen or a hydrolysable radical, and (R2)n, (R3)m, n and m are as defined in formula (I) according to claim 1, where the stereochemical configuration at the carbon atom in position 3 of the butanoic acid derivative has a stereochemical purity of from 60 to 100% (R), preferably 70 to 100% (R), or more preferably 80 to 100% (R), in particular 90 to 100% (R), based on a mixture of threo enantiomers present, and the stereochemical configuration at the carbon atom in position 4 of the butanoic acid derivative has a stereochemical purity of from 60 to 100% (R), preferably 70 to 100% (R), more preferably 80 to 100% (R), in particular 90 to 100% (R), based on a mixture of threo enantiomers present, are suitable for use as herbicides and growth regulators, in particular for the selective use in plant crops, and can be prepared by the process of claim 9.Type: GrantFiled: March 12, 2012Date of Patent: June 9, 2015Assignee: Bayer Intellectual Property GmbHInventors: Harald Jakobi, Marc Mosrin, Elmar Gatzweiler, Isolde Häuser-Hahn, Ines Heinemann, Christopher Hugh Rosinger, Alfred Angermann, Michael Gerhard Hoffmann, Stefan Schnatterer, Hans-Joachim Zeiβ
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Publication number: 20140256554Abstract: The present disclosure relates to compositions comprising from 10 to 90 wt % of a mixture M of compounds A having formula R1CONR2R3, wherein R1, R2, and R3 are described herein, and from 10 to 90 wt % of at least one compound B selected from the amide solvents, optionally combined with an ester solvent, and methods for producing the same. The present disclosure further relates to phytosanitary formulations comprising such compositions.Type: ApplicationFiled: October 11, 2012Publication date: September 11, 2014Applicant: RHODIA OPERATIONSInventors: Thierry Vidal, Benoit Abribat, Valerio Bramati, Marc Balastre
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Publication number: 20140228219Abstract: The present invention provides a compound having an excellent efficacy for controlling weeds. A cyclohexanone compound of the formula (I): wherein m is an integer of 1, 2 or 3; n is an integer of any one of 1 to 5; X represents CH2, O, S, S(O) or S(O)2; R1 represents a hydrogen atom or a methyl group; R2 and R3 represents a hydrogen atom, a C1-6 alkyl group and the like; R4 represents a C6-10 aryl group or a five- to six-membered heteroaryl group; G represents a hydrogen atom and the like; Z represents a halogen atom, a cyano group, a nitro group, a phenyl group, a C1-6 alkyl group and the like; is useful as an active ingredient for herbicides.Type: ApplicationFiled: May 29, 2012Publication date: August 14, 2014Inventors: Yosuke Nakashima, Yoshinobu Jin, Masato Konobe
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Publication number: 20140179533Abstract: This invention relates to the application of herbicides in sewer liens to kill tree roots inside the lines and preventing re-growth into the lines for years after application. It relates to the discovery that latex polymers, organosilicone surfactants, deposition agents and other surfactants can be used to “glue” the herbicides to pipe surfaces. This discovery allows the use of plant killing herbicides to treat roots in sewer lines—killing them—which results in their subsequent removal by decay and erosion processes. It also allows for the use of the herbicides to prevent regrowth back into the sewer lines by applying the herbicides in a compound which adheres to the sewer line surfaces and forms a long term coating on the pipe and joint surfaces where the roots might attempt to grow back in. The compound resists erosion and washing away preventing long term root re-infestations in the sewer lines.Type: ApplicationFiled: February 25, 2014Publication date: June 26, 2014Applicant: OLVIDIUM, INC.Inventor: TIMOTHY WAYNE TOBIASON
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Patent number: 8758788Abstract: Active compound mixtures comprising ipconazole and at least one further fungicidally active compound are highly suitable for protecting industrial materials against colonization and destruction by microorganisms.Type: GrantFiled: January 22, 2010Date of Patent: June 24, 2014Assignee: Bayer Intellectual Property GmbHInventors: Rainer Bruns, Martin Kugler, Thomas Jaetsch
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Patent number: 8741324Abstract: The present invention relates to liquid pesticide concentrate compositions which comprise at least one organic pesticide compound that is sparingly or even insoluble in water and which upon dilution with water form stable aqueous nanoparticulate formulations. The liquid pesticide concentrate compositions of the invention comprise: a) at least one organic pesticide compound C having a water solubility of not more than 1 g/l at 25° C./1013 mbar, b) at least one organic solvent S having a water solubility at least 10 g/l at 25° C.Type: GrantFiled: July 5, 2005Date of Patent: June 3, 2014Assignee: BASF SEInventors: Charles W. Finch, Thomas Byrne, Hassan Oloumi-Sadeghi
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Publication number: 20140057789Abstract: This invention provides polynucleotide molecules and methods for regulating genes in plants, e.g., by providing RNA for systemic regulation of genes. Various aspects of the invention provide polynucleotide molecules and methods for regulating endogenous genes and transgenes in a plant cell and polynucleotide molecules.Type: ApplicationFiled: August 30, 2013Publication date: February 27, 2014Applicant: Monsanto Technology LLCInventors: Robert D Sammons, Sergey Ivashuta, Hong Liu, Dafu Wang, Paul C. C. Feng, Andrei Y. Kouranov, Scott E. Andersen
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Patent number: 8557741Abstract: What is described are 3-aminocarbonyl-substituted benzoylcyclohexanediones of the formula (I) as herbicides. In this formula (I), R1 to R5 are radicals such as hydrogen, organic radicals such as alkyl, and other radicals such as halogen. X is alkylene.Type: GrantFiled: February 17, 2011Date of Patent: October 15, 2013Assignee: Bayer CropScience AGInventors: Chieko Ueno, Simon Dörner-Rieping, Andreas Van Almsick, Christopher Hugh Rosinger, Jan Dittgen, Dieter Feucht, Isolde Häuser-Hahn
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Patent number: 8449917Abstract: The present invention concerns stable herbicidal solid compositions containing built-in adjuvant which exhibit improved herbicidal efficacy when used to control weeds in flooded rice paddies or fields.Type: GrantFiled: July 14, 2011Date of Patent: May 28, 2013Assignee: Dow AgroSciences, LLCInventors: Hiteshkumar Dave, Lei Liu, Raymond E. Boucher, Jr., David G. Ouse, Richard K. Mann, James M. Gifford, Yi-hsiou Huang, Åndrea C. McVeigh-Nelson, Martin C. Logan, Ashish Batra
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Patent number: 8431514Abstract: The present invention relates to bis-amide derivatives of formula (I), to processes and intermediates for preparing them, to methods of using them to control insect, acarine, nematode and mollusc pests, and to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising them.Type: GrantFiled: April 14, 2010Date of Patent: April 30, 2013Assignee: Syngenta Crop Protection LLCInventors: Pierre Joseph Marcel Jung, Christopher Richard Ayles Godfrey, Ottmar Franz Hueter, Peter Maienfisch
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Publication number: 20130102469Abstract: This invention relates to the application of herbicides in sewer lines to kill tree roots inside the lines and preventing re-growth into the lines for years after application. It relates to the discovery that latex polymers, organosilicone surfactants, deposition agents and other surfactants can be used to “glue” the herbicides to pipe surfaces. This discovery allows the use of plant killing herbicides to treat roots in sewer lines—killing them—which results in their subsequent removal by decay and erosion processes. It also allows for the use of the herbicides to prevent re-growth back into the sewer lines by applying the herbicides in a compound which adheres to the sewer line surfaces and forms a long term coating on the pipe and joint surfaces where the roots might attempt to grow back in. The compound resists erosion and washing away preventing long term root re-infestations in the sewer lines.Type: ApplicationFiled: October 20, 2011Publication date: April 25, 2013Applicants: Swartz family dba OlvidiumInventor: Timothy Wayne Tobiason
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Publication number: 20120178623Abstract: Compounds of formula (I) are suitable for use as herbicides: wherein R is methyl, ethyl, vinyl, ethynyl or cyclopropyl, R1 is hydrogen, C1-C6alkyl, C1-C6haloalkyl, C3-C7cycloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, vinyl, propenyl, ethynyl, propynyl, halogen, or optionally substituted phenyl, R2 is methyl, ethyl, vinyl, ethynyl or methoxy, R3 and R4 are hydrogen or together form a double bond, A is C3-C7cycloalkyl which is unsubstituted or substituted once or twice by C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6alkylcarbonyloxy, C2-C6alkenyl, ?O or ?N—R10, or A is cyclohexyl substituted once, at the 4-position, by one (C3-C6cycloalkyl)methoxy, C3-C6cycloalkyloxy, C2-C5alkenyl-CH2-oxy, or benzyloxy substituent, or A is decahydro-1-naphthyl or decahydro-2-naphthyl, or A is optionally substituted phenyl, and G is hydrogen or an agriculturally acceptable metal, sulfonium, ammonium or a latentiating group.Type: ApplicationFiled: July 15, 2010Publication date: July 12, 2012Applicant: SYNGENTA CROP PROTECTION LLCInventors: Daniel Jason Foley, Stephane André Marie Jeanmart, Adrian Longstaff, Robert William Parsons, Claire Janet Russell, John Benjamin Taylor, Jeffrey Steven Wailes
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Publication number: 20110312496Abstract: Concentrated microemulsions comprising: 1) 10-25 parts by weight of a pesticide with a solubility in water at 20° C. lower than 1% l by weight and having a melting point from 10° C. to 60° C.; 2) 8-25 parts by weight of one or more solvents containing oxygen atoms, having a solubility in water at 20° C. lower than 5% by weight and the Hildebrand solubility parameter in the range 16-21 MPa1/2; 3) 10-20 parts by weight of a polyol; 4) 10-25 parts by weight of one or more non ionic surfactants having a HLB value from 9 to 15; 5) 2-10 parts by weight of one or more anionic surfactants; 6) water up to 100 parts by weight; wherein—the ratio by weight between 2) and 1) ranges from 0.8:1 to 1.5:1;—the ratio by weight between 4) +5) and 1) is in the range 0.5:1-3:1;—the ratio by weight between 4) and 5) ranges from 1:1 to 4.1.Type: ApplicationFiled: August 30, 2011Publication date: December 22, 2011Applicant: SIPCAM S.P.A.Inventors: Marco BERNARDINI, Francesca BORGO, Luigi CAPUZZI, Pietro DOMENICHINI, Giorgio FRESCHI
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Patent number: 7964635Abstract: The invention relates to compounds of the general formula (I) wherein X, Y and W have the significances given in claim 1 and optionally the enantiomers thereof. The active ingredients have advantageous pesticidal properties. They are especially suitable for controlling parasites in and on warm-blooded animals.Type: GrantFiled: January 8, 2009Date of Patent: June 21, 2011Assignee: Novartis AGInventors: Noëlle Gauvry, Thomas Goebel, Pierre Ducray, François Pautrat, Ronald Kaminsky, Martin Jung
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Publication number: 20110053778Abstract: 2-(3-Aminobenzoyl)-3-cyclopropyl-3-oxopropanenitriles of the formula (I) are described as herbicides. In this formula (I), X and Y are organic radicals such as alkyl and other radicals such as halogen, nitro and cyano.Type: ApplicationFiled: July 27, 2010Publication date: March 3, 2011Applicant: BAYER CROPSCIENCE AGInventors: Hartmut AHRENS, Ines Heinemann, Andreas Van Almsick, Ralf Braun, Jan Dittgen, Dieter Feucht, Martin Jeffrey Hills, Heinz Kehne, Christopher Hugh Rosinger, Stefan Lehr
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Publication number: 20100234230Abstract: The invention provides aqueous pesticidal concentrates comprising at least one colloidal solid, a dispersed emulsion phase comprising at least one substantially water-insoluble pesticidally active ingredient, which is either itself an oily liquid comprising the oil phase, is a solid but is dissolved in an oily liquid present in the oil phase, is a solid and is dispersed within the oil phase or is present as a colloidal solid adsorbed to the liquid-liquid interface between the continuous aqueous phase and the dispersed oil phase and at least one Ostwald ripening inhibitor.Type: ApplicationFiled: August 30, 2007Publication date: September 16, 2010Applicant: SYNGENTA CROP PROTECTION, INC.Inventor: Jeffrey Fowler
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Publication number: 20100107283Abstract: The present invention provides chimeric regulatory elements constructed from gene regulatory element polynucleotide molecules isolated from the Zea mays genes fructose 1-6 bisphosphate aldolase (FDA), pyruvate orthophosphate dikinase (PPDK), or ribulose bisphosphate carboxylase activase (RUA), useful for expressing transgenes in plants. The invention further discloses compositions, polynucleotide constructs, transformed host cells, transgenic plants and seeds comprising the chimeric gene regulatory molecules, and methods for preparing and using the same.Type: ApplicationFiled: November 23, 2009Publication date: April 29, 2010Inventors: Santanu Dasgupta, Targolli L. Jayaprakash, Shoba Cherian
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Patent number: 7544637Abstract: The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts.Type: GrantFiled: November 24, 2005Date of Patent: June 9, 2009Assignee: BASF AktiengesellschaftInventors: Wolfgang von Deyn, Henricus Maria Martinus Bastiaans, Matthias Pohlman, Michael Rack, Ernst Baumann, Michael Puhl, Michael Hofmann, Livio Tedeschi, Markus Kordes, Christopher Koradin, Douglas D. Anspaugh, Deborah L. Culbertson, Henry van Tuyl Cotter, Hassan Oloumi-Sadeghi
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Patent number: 7494956Abstract: The invention relates to compounds of the general formula (I) wherein X, Y and W have the significances given in claim 1 and optionally the enantiomers thereof. The active ingredients have advantageous pesticidal properties. They are especially suitable for controlling parasites in and on warm-blooded animals.Type: GrantFiled: November 5, 2004Date of Patent: February 24, 2009Assignee: Novartis AGInventors: Noëlle Gauvry, Thomas Goebel, Pierre Ducray, François Pautrat, Ronald Kaminsky, Martin Jung
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Patent number: 7153813Abstract: The invention relates to novel substituted aryl ketones of the formula (I) in which Z, X, R and n are as defined in the disclosure, to processes for their preparation and to their use as crop treatment agents, and to intermediates for preparing compounds of the formula (I).Type: GrantFiled: February 12, 2003Date of Patent: December 26, 2006Assignee: Bayer AktiengesellschaftInventors: Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen, Monika Schmitt
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Patent number: 6949669Abstract: Compounds of general formula (I) wherein the substituents are as defined in claim 1 are suitable for use as herbicidesType: GrantFiled: January 23, 2001Date of Patent: September 27, 2005Assignee: Syngenta Crop Protection, Inc.Inventors: Gerald Wayne Craig, Martin Eberle, Martin Zeller, Steven Scott Bondy, Daniel Dennis Comer, Soan Cheng, Julie Elizabeth Penzotti, Peter Grootenhuis, Jürg Ehrler
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Patent number: 6930208Abstract: What is described are derivatives of benzoylcyclohexanediones of the formula (I) and their use as herbicides. In this formula (I), R1a, R1b, R1c, R2, R3, R4 and R5 denote various radicals, X1 is a bridging atom, X2 is a carbon chain and X3 is a chalcogen atom or an oximino radical.Type: GrantFiled: April 8, 2003Date of Patent: August 16, 2005Assignee: Bayer CropScience GmbHInventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Monika H. Schmitt, Thomas Auler, Hermann Bieringer, Hubert Menne
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Patent number: 6919299Abstract: Herbicidal compositions comprising A) 2-[2-chloro-3-(2,2,2-trifluoroethoxymethyl)-4-methylsulfonyl-benzoyl]cyclohexane-1,3-dione and B) at least one compound from the group consisting of ethoxysulfuron, flumetsulam, halosulfuron, imazamox, imazapyr, imazaquin, imazethapyr, metosulam, nicosulfuron, primisulfuron, prosulfuron, rimsulfuron, thifensulfuron-methyl, triflusulfuron, foramsulfuron, ametryne, atrazine, bromoxynil, cyanazine, diuron, hexazinone, metribuzin, pyridate, terbuthylazine, 2,4-D, clopyralid, dicamba, diflufenzopyr, fluroxypyr, butylate, EPTC, fenoxaprop-P-ethyl, acetochlor, alachlor, dimethenamid, flufenacet, mefenacet, metolachlor, thenylchlor, S-metolachlor, fluthiacet-methyl, carfentrazone-ethyl, isoxaflutole, mesotrione, sulcotrione, 4-(4-trifluoromethyl-2-methylsulfonylbenzoyl)-5-hydroxy-1-methyl-3-methylpyrazole, glyphosate, pendimethalin, trifluralin, asulam, triaziflam, diflufenican and glufosinate-ammonium against monocotyledonous and/or dicotyledonous harmful plants are describedType: GrantFiled: December 4, 2002Date of Patent: July 19, 2005Assignee: Bayer CropScience GmbHInventors: Erwin Hacker, Hermann Bieringer, Hansjörg Krähmer
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Patent number: 6906005Abstract: The present invention relates to surfactant systems and in particular herbicidal compositions comprising a water soluble herbicide and/or a salt thereof and a surfactant system, wherein the surfactant system comprises at least two surfactants selected from the group consisting of: i) alkyldiamine tetraalkoxylate surfactants; ii) N-alkyl alkyldiamine trialkoxylate surfactants; and iii) phosphated alcohol alkoxylate surfactants.Type: GrantFiled: November 30, 2001Date of Patent: June 14, 2005Assignee: Huntsman Corporation Australia Pty LtdInventors: Andrew Francis Kirby, Ashley Scott Martin, Paul Leslie Griffiths
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Patent number: 6828276Abstract: There are described benzoylcyclohexanediones of the formula I, their preparation, and their use as herbicides and plant growth regulators. In this formula (I), C1, C2, C3 are cyclic radicals, X1 is a hetero atom, X2 is a chain of carbon atoms, L is a chain-like element, R1, R2, R3, R4, R5 are various radicals, and Y and Z are monoatomic bridge elements.Type: GrantFiled: August 30, 2001Date of Patent: December 7, 2004Assignee: Aventis CropScience GmbHInventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Hermann Bieringer, Thomas Auler, Hubert Menne
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Patent number: 6768025Abstract: Benzoylcyclohexanedione derivatives of the formula (I) and their use as herbicides are described. In this formula (I), R1, R3, and R4 are various radicals, L—(R2)n is haloalkyl, and n is 0 to 2.Type: GrantFiled: April 4, 2002Date of Patent: July 27, 2004Assignee: Aventis CropScience GmbHInventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Thomas Auler, Hermann Bieringer, Hubert Menne
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Patent number: 6764979Abstract: A herbicidal agent comprising: (1) water; (2) ioxynil and/or a derivative thereof; (3) a compound of the formula (I) RO—(CH2H4O)n(CH3H6O)m—R′ (I) wherein RO is an alcohol radical selected from the group consisting of branched or linear, saturated or unsaturated monohydric alcohols having from 1 to 6 carbon atoms, or a polyol radical having from 2 to 12 carbon atoms and from 2 to 6 hydroxyl groups; R′ is hydrogen or an ester group —CO—R″ wherein R″ is a branched or linear, saturated or unsaturated alkyl radical having 5 to 29 carbon atoms, n is a number between 1 and 50 and m is zero or a number between 1 and 10. The herbicidal agents permit high penetration of the herbicide into the plant.Type: GrantFiled: February 20, 2003Date of Patent: July 20, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
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Patent number: 6759371Abstract: Herbicidal preparations which contain: (a) water; (b) a bromoxynil component; and (c) at least one compound corresponding to the general formula (I): RO—(C2H4O)n(C3H6O)m—R′ (I) wherein RO represents an alcohol moiety selected from the group consisting of C1-6 monohydric alcohols, and C2-12 polyols having from 2 to 6 hydroxyl groups; n represents a number of from 1 to 50; m represents a number of from 0 to 10; and wherein each R′ represents a substituent independently selected from the group consisting of hydrogen and an ester group of the general formula, —CO—R″, wherein each R″ independently represents an alkyl group having from 5 to 29 carbon atoms; with the proviso that at least one R′ represents —CO—R″, are described.Type: GrantFiled: December 2, 2002Date of Patent: July 6, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
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Patent number: 6693063Abstract: The present invention relates to a herbicidal composition, comprising A) one or more compounds of the formula (I) in which Hal1 and Hal2 are identical or different halogen atoms, R1 is H, a cation or a C1-C20-carbon-containing radical and B) one or more surfactants, comprising as structural element at least 12 alkylene oxide units.Type: GrantFiled: December 18, 2001Date of Patent: February 17, 2004Assignee: Aventis CropScience GmbHInventors: Gerhard Schnabel, Jean Kocur, Hans-Peter Krause, Julio Martinez de Una, Hans Philipp Huff, Udo Bickers
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Publication number: 20040023806Abstract: The invention relates to novel compounds of the formula I 1Type: ApplicationFiled: September 5, 2002Publication date: February 5, 2004Inventors: Hugo Ziegler, Saleem Farooq, Rene Zurflh
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Publication number: 20030228982Abstract: The present invention relates to compounds of the formula (I) and/or salts thereof 1Type: ApplicationFiled: December 13, 2002Publication date: December 11, 2003Inventors: Hendrik Helmke, Michael Gerhard Hoffmann, Klaus Haaf, Lothar Willms, Thomas Auler, Hermann Bieringer, Hubert Menne
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Patent number: 6660692Abstract: This invention provides a method for controlling the growth of weeds (i.e. undesired vegetation) at a locus which comprises applying to the locus a herbicidally effective amount of: (a) picolinfen, a phenoxypicolinamide derivative of formula (I); and (b) a partner herbicide, selected from isoxazole, dione, urea and hydroxybenzonitrile herbicide.Type: GrantFiled: December 13, 2001Date of Patent: December 9, 2003Assignee: Aventis CropScience S.A.Inventor: Richard Henry Hewett
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Patent number: 6620766Abstract: Compositions for preparation of wettable-powder and powder suspension herbicidal products containing low-melting agrochemical agents, such as bromoxynil esters, are provided. Preferred compositions are co-melts of bromoxynil esters with at least one additional herbicide or pesticide, particularly atrazine. The compositions of the invention have higher melting points than the bromoxynil ester component, and therefore have advantages in that the use of solvents and/or carriers in formulations can be avoided or minimized. The compositions can be processed into dry powders without the problems associated with the softening or melting of pure bromoxynil esters during grinding or milling, and without the need for dilution of the product with substantial amounts of inactive carriers. Compositions containing the alloys do not lose selectivity in the presence of oil adjuvants.Type: GrantFiled: March 19, 2002Date of Patent: September 16, 2003Assignee: Aventis Cropscience S.A.Inventor: Robert C. Ligon
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Publication number: 20030158044Abstract: The invention relates to aqueous agents containing ioxynil or the derivatives thereof and compounds of general formula (I) in which: RO represents an alcohol residue selected from the group of branched or linear, saturated or unsaturated monohydric alcohols with 1 to 6 C atoms or of polyols with 2 to 12 C atoms and 2 to 6 hydroxyl groups; R′ represents hydrogen and/or an ester group —CO—R″, in which R″ represents a branched or liner, saturated or unsaturated alkyl residue with 5 to 29 C atoms; n is a number between 1 and 50, and; m is either equal to zero or to a number between 1 and 10. The inventive agents exhibit an increased level of penetration of the active substance into plants.Type: ApplicationFiled: February 20, 2003Publication date: August 21, 2003Inventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
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Patent number: 6599861Abstract: Compounds of formula I wherein the substituents are defined as in claim 1, as well as the agronomically acceptable salts, isomers and enantiomers of these compounds, as well as the agronomically acceptable salts/N-oxides/isomers/enantiomers of these compounds, are eminently suitable for use as herbicides.Type: GrantFiled: June 21, 2001Date of Patent: July 29, 2003Assignee: Syngenta Participations AGInventors: Jürgen Schaetzer, Alain De Mesmaeker, Shy-Fuh Lee
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Publication number: 20030125210Abstract: The invention relates to an aqueous means containing bromoxynil or the derivatives thereof. The invention also relates to compounds of the general formula (I): RO—(C2H4O)n(C3H6O)m—R′, wherein RO stands for an alcohol radical selected from the group of the branched or linear, saturated or unsaturated, monovalent alcohols having 1 to 6 C atoms or of the polyols having 2 to 12 C atoms and 2 to 6 hydroxyl groups and R′ stands for hydrogen and/or an ester group —CO—R″, wherein R″ means a branched or linear, saturated or unsaturated alkyl radical having 5 to 29 C atoms, n is a number between 1 and 50 and m is zero or a number between 1 and 10. An increased amount of the active agent penetrates the plant.Type: ApplicationFiled: December 2, 2002Publication date: July 3, 2003Inventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
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Patent number: 6576596Abstract: The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereoType: GrantFiled: June 23, 1999Date of Patent: June 10, 2003Assignee: BASF AktiengesellschaftInventors: Regina Luise Hill, Uwe Kardorff, Michael Rack, Ernst Baumann, Wolfgang von Deyn, Stefan Engel, Guido Mayer, Martina Otten, Joachim Rheinheimer, Matthias Witschel, Ulf Misslitz, Helmut Walter, Karl-Otto Westphalen
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Publication number: 20030104946Abstract: Herbicidal mixture comprising a benzoyl derivative, a fertilizer containing nitrogen and an adjuvant.Type: ApplicationFiled: May 14, 2002Publication date: June 5, 2003Inventors: Udo Bickers, Erwin Hacker, Frank Sixl, Thomas Auler
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Patent number: 6555500Abstract: Increasing the concentration of prolines such as 2-hydroxy-5-oxoproline, in the foliar portions of plants has been shown to cause an increase in carbon dioxide fixation, growth rate, dry weight, nutritional value (amino acids), nodulation and nitrogen fixation, photosynthetically derived chemical energy, and resistance to insect pests over the same properties for wild type plants.Type: GrantFiled: April 16, 2002Date of Patent: April 29, 2003Assignee: The Regents of the University of CaliforniaInventors: Pat J. Unkefer, Thomas J. Knight, Rodolfo A. Martinez
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Publication number: 20030017948Abstract: The invention relates to a novel process for preparing N-substituted 2,4-diamino-5-fluoro-benzonitriles which are known as intermediates in the preparation of herbicides, to novel N-substituted 4-bromo-6-fluoro-1,3-phenylenediamines, to novel N-substituted 2-bromo-4-fluoro-5-nitro-anilines and to novel N-substituted 2-bromo-4-fluoro-anilines as intermediates for this process, and to processes for their preparation.Type: ApplicationFiled: June 21, 2002Publication date: January 23, 2003Inventor: Achim Hupperts
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Publication number: 20020115569Abstract: The present invention relates to a herbicidal composition, comprisingType: ApplicationFiled: December 18, 2001Publication date: August 22, 2002Inventors: Gerhard Schnabel, Jean Kocur, Hans-Peter Krause, Julio Martinez de Una, Hans Philipp Huff, Udo Bickers
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Patent number: 6337306Abstract: Phenoxyacetic acid derivatives of the formula: wherein R1, R2, Xn and A are as defined herein, and a process for preparing the derivatives. The derivatives are used as herbicides.Type: GrantFiled: November 5, 1999Date of Patent: January 8, 2002Assignee: Rhone-Poulenc AgroInventors: Norio Sasaki, Atsushi Go, Hideshi Mukaida, Yukiko Oe
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Patent number: 6265606Abstract: 1-Alkyl-4-benzoyl-5-hydroxypyrazole compounds in which the benzoyl moiety is substituted in the 2-position with a halo, alkyl, or alkoxy group, in the 4-position with an alkylsulfonyl group, and in the 3-position with an optionally substituted phenyl group, for example, 1-(1,1-dimethylethyl)-4-(2-methyl-4-methyl-sulfonyl-3-(4-methoxyphenyl)benzoyl-5-hydroxypyrazole, were prepared and found to be useful for the control of a variety of broadleaf and grassy weeds. The compounds can be applied either preemergently or postemergently and can be used to control undesirable vegetation selectively in small grain crops and turf or non-selectively.Type: GrantFiled: May 10, 1999Date of Patent: July 24, 2001Assignee: Dow AgroSciences LLCInventors: Thomas L. Siddall, Zoltan L. Benko, Gail M. Garvin, Johnny L. Jackson, Jeffrey M. McQuiston, David G. Ouse, Thomas D. Thibault, James A. Turner, John C. Van Heertum
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Publication number: 20010008874Abstract: A microcapsule (or microencapsulated product) having a uniform and smooth coating film and also an excellent performance of gradually liberating the content material is produced at a good particle size distribution while suppressing the occurrence of isolated or aggregated film material, aggregated microcapsules and isolated core material. The production process includes: a first coating step of mixing a water-soluble cationic amino resin and an anionic surfactant in the presence of a hydrophobic core material dispersed in an aqueous medium to coat the dispersed core material with a coacervate of the cationic amino resin and the anionic surfactant; and a second coating step of adding an amino resin prepolymer into an aqueous dispersion liquid containing the coated dispersed core material and polycondensating the amino resin prepolymer to further coat the coated dispersed core material with a polycondensate of the amino resin prepolymer.Type: ApplicationFiled: January 12, 2001Publication date: July 19, 2001Inventors: Yutaka Igari, Yuzi Hori, Tsuneo Okamoto
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Patent number: 6255252Abstract: A mixture of the known herbicide esters 3,5-dibromo-4-hydroxybenzonitrile (“bromoxynil” n-octanoate and bromoxynil n-heptanoate is provided having a molar ratio of n-octanoate n-heptanoate from 1:1.5 to 1.5:1, which mixture possesses an unexpectedly low melting point high solubility in hydrocarbon oils. Herbicidal compositions comprising bromoxynil n-octanoate and bromoxynil n-heptanoate in such molar ratio and a method for controlling the growth of weeds with such herbicidal compositions are also provided. The ester mixture may be formed by admixture of the esters, or by reacting bromoxynil with a mixture of n-octanoic and n-heptanoic acids or of their derivatives (e.g. acid chlorides or anhydrides).Type: GrantFiled: April 18, 1994Date of Patent: July 3, 2001Assignee: Aventis Agriculture LimitedInventors: Colin Charles Foan, Anthony Reginald Woodford
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Patent number: 6251833Abstract: The present invention relates to novel 2-aryl-3-hydroxy-&Dgr;2-cyclopentene-1-one derivatives of the formula (I) in which A, B, D1, D2, G, W, X, Y and Z are each as defined in the description, to processes for their preparation and to their use as herbicides and pesticides.Type: GrantFiled: August 31, 1999Date of Patent: June 26, 2001Inventors: Christoph Erdelen, Ulrike Wachendorff-Neumann, Reiner Fischer, Alan Graff, Norbert Mencke, Andreas Turberg
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Patent number: 6191071Abstract: The invention concerns novel plant-treatment agents comprising: at least one thermoplastically processable biodegradable polyester amide, optionally in a mixture with one or a plurality of further thermoplastically processable, biodegradable polymer components; at least one agrochemical substance; and optionally additives. The invention further concerns a process for preparing these agents, and their use in the application of agrochemical substances.Type: GrantFiled: May 4, 1999Date of Patent: February 20, 2001Assignee: Bayer AktiengesellschaftInventors: Joachim Simon, Hanns Peter Müller, Uwe Priesnitz, Hans-Georg Rast
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Patent number: 6150304Abstract: The present invention relates to novel 2-aryl-3-hydroxy-cyclopent-2-en-1-one derivatives of the formula (I) ##STR1## in which X represents halogen, nitro, cyano, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl or halogenoalkoxy,Y represents hydrogen, halogen, nitro, cyano, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl or halogenoalkoxy,Z represents halogen, nitro, cyano, alkyl, alkoxy or halogenoalkoxy andA, B, D.sup.1, D.sup.2, G and n have the meaning given in the description,several processes for their preparation and their use as compositions for controlling pests and as herbicides.Type: GrantFiled: August 6, 1998Date of Patent: November 21, 2000Assignee: Bayer AktiengesellschaftInventors: Reiner Fischer, Jacques Dumas, Thomas Bretschneider, Christoph Erdelen, Ulrike Wachendorff-Neumann, Hans-Joachim Santel, Markus Dollinger, Andreas Turberg, Norbert Mencke
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Patent number: 6040274Abstract: 2- Aroylcyclohexanediones I ##STR1## where X, Y=O or S;Ar=phenyl or heteroaryl in each case having 1-4 substituents: halogen, cyano, nitro, --N.dbd.N--Ph, C.sub.1 -C.sub.4 -alkoxycarbonyl, --N(R.sup.9)--COR.sup.10, --N(R.sup.9)--SO.sub.2 --R.sup.11, --SO.sub.2 --N(R.sup.9)R.sup.10, --S(O).sub.m --R.sup.8 or opt. subst. C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl or C.sub.1 -C.sub.4 -haloalkoxy;two adjacent C atoms of the phenyl or heteroaryl ring can also be bridged by means of a chain --C(R.sup.12).dbd.C(R.sup.13)--C(R.sup.14).dbd.C(R.sup.15)--, --Z.sup.1 --C(R.sup.12).dbd.N--, --Z.sup.1 --N.dbd.C(R.sup.12)--, --Z.sub.1 --C(R.sup.12).dbd.C(R.sup.13)--, --Z.sup.1 --C(R.sup.12).dbd.C(R.sup.13)--C(R.sup.14,R.sup.15)--, --Z.sup.1 --C (R.sup.12,R.sup.13)--C(R.sup.14,R.sup.15)--, --Z.sup.1 --C(R.sup.12,R.sup.13)--C(R.sup.14 R.sup.15)--Z.sup.2 --, --C(R.sup.12,R.sup.13)--Z.sup.1 --C(R.sup.14,R.sup.15)--C(R.sup.16,R.sup.17)--, --Z.sup.1 --N(R.sup.20)--Z.sup.2 --, --Z.sup.1 --Z.sup.Type: GrantFiled: March 18, 1997Date of Patent: March 21, 2000Assignee: BASF AktiengesellschaftInventors: Jurgen Kast, Marcus Vossen, Wolfgang von Deyn, Stefan Engel, Regina Luise Hill, Uwe Kardorff, Martina Otten, Peter Plath, Helmut Walter, Karl-Otto Westphalen, Ulf Misslitz