Benzene Ring Bonded Directly To The Cyano Or Isocyano Group Patents (Class 504/310)
  • Patent number: 9161537
    Abstract: Compounds of the formula (I) or salts thereof in which R1 and (R2)n are as defined in Claim 1 are suitable as herbicides for the control of harmful plants or as plant growth regulators. The compounds can be prepared by the processes of Claim 7.
    Type: Grant
    Filed: December 17, 2012
    Date of Patent: October 20, 2015
    Assignee: BAYER INTELLECTUAL PROPERTY GMBH
    Inventors: Harald Jakobi, Marc Morsin, Hansjörg Dietrich, Elmar Gatzweiler, Isolde Haeuser-Hahn, Ines Heinemann, Christopher Hugh Rosinger
  • Patent number: 9049863
    Abstract: Compounds of the formula (I) or salts thereof, in each case in the optically active (3R,4R)-threo form, in which R1 is hydrogen or a hydrolysable radical, and (R2)n, (R3)m, n and m are as defined in formula (I) according to claim 1, where the stereochemical configuration at the carbon atom in position 3 of the butanoic acid derivative has a stereochemical purity of from 60 to 100% (R), preferably 70 to 100% (R), or more preferably 80 to 100% (R), in particular 90 to 100% (R), based on a mixture of threo enantiomers present, and the stereochemical configuration at the carbon atom in position 4 of the butanoic acid derivative has a stereochemical purity of from 60 to 100% (R), preferably 70 to 100% (R), more preferably 80 to 100% (R), in particular 90 to 100% (R), based on a mixture of threo enantiomers present, are suitable for use as herbicides and growth regulators, in particular for the selective use in plant crops, and can be prepared by the process of claim 9.
    Type: Grant
    Filed: March 12, 2012
    Date of Patent: June 9, 2015
    Assignee: Bayer Intellectual Property GmbH
    Inventors: Harald Jakobi, Marc Mosrin, Elmar Gatzweiler, Isolde Häuser-Hahn, Ines Heinemann, Christopher Hugh Rosinger, Alfred Angermann, Michael Gerhard Hoffmann, Stefan Schnatterer, Hans-Joachim Zeiβ
  • Publication number: 20140256554
    Abstract: The present disclosure relates to compositions comprising from 10 to 90 wt % of a mixture M of compounds A having formula R1CONR2R3, wherein R1, R2, and R3 are described herein, and from 10 to 90 wt % of at least one compound B selected from the amide solvents, optionally combined with an ester solvent, and methods for producing the same. The present disclosure further relates to phytosanitary formulations comprising such compositions.
    Type: Application
    Filed: October 11, 2012
    Publication date: September 11, 2014
    Applicant: RHODIA OPERATIONS
    Inventors: Thierry Vidal, Benoit Abribat, Valerio Bramati, Marc Balastre
  • Publication number: 20140228219
    Abstract: The present invention provides a compound having an excellent efficacy for controlling weeds. A cyclohexanone compound of the formula (I): wherein m is an integer of 1, 2 or 3; n is an integer of any one of 1 to 5; X represents CH2, O, S, S(O) or S(O)2; R1 represents a hydrogen atom or a methyl group; R2 and R3 represents a hydrogen atom, a C1-6 alkyl group and the like; R4 represents a C6-10 aryl group or a five- to six-membered heteroaryl group; G represents a hydrogen atom and the like; Z represents a halogen atom, a cyano group, a nitro group, a phenyl group, a C1-6 alkyl group and the like; is useful as an active ingredient for herbicides.
    Type: Application
    Filed: May 29, 2012
    Publication date: August 14, 2014
    Inventors: Yosuke Nakashima, Yoshinobu Jin, Masato Konobe
  • Publication number: 20140179533
    Abstract: This invention relates to the application of herbicides in sewer liens to kill tree roots inside the lines and preventing re-growth into the lines for years after application. It relates to the discovery that latex polymers, organosilicone surfactants, deposition agents and other surfactants can be used to “glue” the herbicides to pipe surfaces. This discovery allows the use of plant killing herbicides to treat roots in sewer lines—killing them—which results in their subsequent removal by decay and erosion processes. It also allows for the use of the herbicides to prevent regrowth back into the sewer lines by applying the herbicides in a compound which adheres to the sewer line surfaces and forms a long term coating on the pipe and joint surfaces where the roots might attempt to grow back in. The compound resists erosion and washing away preventing long term root re-infestations in the sewer lines.
    Type: Application
    Filed: February 25, 2014
    Publication date: June 26, 2014
    Applicant: OLVIDIUM, INC.
    Inventor: TIMOTHY WAYNE TOBIASON
  • Patent number: 8758788
    Abstract: Active compound mixtures comprising ipconazole and at least one further fungicidally active compound are highly suitable for protecting industrial materials against colonization and destruction by microorganisms.
    Type: Grant
    Filed: January 22, 2010
    Date of Patent: June 24, 2014
    Assignee: Bayer Intellectual Property GmbH
    Inventors: Rainer Bruns, Martin Kugler, Thomas Jaetsch
  • Patent number: 8741324
    Abstract: The present invention relates to liquid pesticide concentrate compositions which comprise at least one organic pesticide compound that is sparingly or even insoluble in water and which upon dilution with water form stable aqueous nanoparticulate formulations. The liquid pesticide concentrate compositions of the invention comprise: a) at least one organic pesticide compound C having a water solubility of not more than 1 g/l at 25° C./1013 mbar, b) at least one organic solvent S having a water solubility at least 10 g/l at 25° C.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: June 3, 2014
    Assignee: BASF SE
    Inventors: Charles W. Finch, Thomas Byrne, Hassan Oloumi-Sadeghi
  • Publication number: 20140057789
    Abstract: This invention provides polynucleotide molecules and methods for regulating genes in plants, e.g., by providing RNA for systemic regulation of genes. Various aspects of the invention provide polynucleotide molecules and methods for regulating endogenous genes and transgenes in a plant cell and polynucleotide molecules.
    Type: Application
    Filed: August 30, 2013
    Publication date: February 27, 2014
    Applicant: Monsanto Technology LLC
    Inventors: Robert D Sammons, Sergey Ivashuta, Hong Liu, Dafu Wang, Paul C. C. Feng, Andrei Y. Kouranov, Scott E. Andersen
  • Patent number: 8557741
    Abstract: What is described are 3-aminocarbonyl-substituted benzoylcyclohexanediones of the formula (I) as herbicides. In this formula (I), R1 to R5 are radicals such as hydrogen, organic radicals such as alkyl, and other radicals such as halogen. X is alkylene.
    Type: Grant
    Filed: February 17, 2011
    Date of Patent: October 15, 2013
    Assignee: Bayer CropScience AG
    Inventors: Chieko Ueno, Simon Dörner-Rieping, Andreas Van Almsick, Christopher Hugh Rosinger, Jan Dittgen, Dieter Feucht, Isolde Häuser-Hahn
  • Patent number: 8449917
    Abstract: The present invention concerns stable herbicidal solid compositions containing built-in adjuvant which exhibit improved herbicidal efficacy when used to control weeds in flooded rice paddies or fields.
    Type: Grant
    Filed: July 14, 2011
    Date of Patent: May 28, 2013
    Assignee: Dow AgroSciences, LLC
    Inventors: Hiteshkumar Dave, Lei Liu, Raymond E. Boucher, Jr., David G. Ouse, Richard K. Mann, James M. Gifford, Yi-hsiou Huang, Åndrea C. McVeigh-Nelson, Martin C. Logan, Ashish Batra
  • Patent number: 8431514
    Abstract: The present invention relates to bis-amide derivatives of formula (I), to processes and intermediates for preparing them, to methods of using them to control insect, acarine, nematode and mollusc pests, and to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising them.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: April 30, 2013
    Assignee: Syngenta Crop Protection LLC
    Inventors: Pierre Joseph Marcel Jung, Christopher Richard Ayles Godfrey, Ottmar Franz Hueter, Peter Maienfisch
  • Publication number: 20130102469
    Abstract: This invention relates to the application of herbicides in sewer lines to kill tree roots inside the lines and preventing re-growth into the lines for years after application. It relates to the discovery that latex polymers, organosilicone surfactants, deposition agents and other surfactants can be used to “glue” the herbicides to pipe surfaces. This discovery allows the use of plant killing herbicides to treat roots in sewer lines—killing them—which results in their subsequent removal by decay and erosion processes. It also allows for the use of the herbicides to prevent re-growth back into the sewer lines by applying the herbicides in a compound which adheres to the sewer line surfaces and forms a long term coating on the pipe and joint surfaces where the roots might attempt to grow back in. The compound resists erosion and washing away preventing long term root re-infestations in the sewer lines.
    Type: Application
    Filed: October 20, 2011
    Publication date: April 25, 2013
    Applicants: Swartz family dba Olvidium
    Inventor: Timothy Wayne Tobiason
  • Publication number: 20120178623
    Abstract: Compounds of formula (I) are suitable for use as herbicides: wherein R is methyl, ethyl, vinyl, ethynyl or cyclopropyl, R1 is hydrogen, C1-C6alkyl, C1-C6haloalkyl, C3-C7cycloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, vinyl, propenyl, ethynyl, propynyl, halogen, or optionally substituted phenyl, R2 is methyl, ethyl, vinyl, ethynyl or methoxy, R3 and R4 are hydrogen or together form a double bond, A is C3-C7cycloalkyl which is unsubstituted or substituted once or twice by C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6alkylcarbonyloxy, C2-C6alkenyl, ?O or ?N—R10, or A is cyclohexyl substituted once, at the 4-position, by one (C3-C6cycloalkyl)methoxy, C3-C6cycloalkyloxy, C2-C5alkenyl-CH2-oxy, or benzyloxy substituent, or A is decahydro-1-naphthyl or decahydro-2-naphthyl, or A is optionally substituted phenyl, and G is hydrogen or an agriculturally acceptable metal, sulfonium, ammonium or a latentiating group.
    Type: Application
    Filed: July 15, 2010
    Publication date: July 12, 2012
    Applicant: SYNGENTA CROP PROTECTION LLC
    Inventors: Daniel Jason Foley, Stephane André Marie Jeanmart, Adrian Longstaff, Robert William Parsons, Claire Janet Russell, John Benjamin Taylor, Jeffrey Steven Wailes
  • Publication number: 20110312496
    Abstract: Concentrated microemulsions comprising: 1) 10-25 parts by weight of a pesticide with a solubility in water at 20° C. lower than 1% l by weight and having a melting point from 10° C. to 60° C.; 2) 8-25 parts by weight of one or more solvents containing oxygen atoms, having a solubility in water at 20° C. lower than 5% by weight and the Hildebrand solubility parameter in the range 16-21 MPa1/2; 3) 10-20 parts by weight of a polyol; 4) 10-25 parts by weight of one or more non ionic surfactants having a HLB value from 9 to 15; 5) 2-10 parts by weight of one or more anionic surfactants; 6) water up to 100 parts by weight; wherein—the ratio by weight between 2) and 1) ranges from 0.8:1 to 1.5:1;—the ratio by weight between 4) +5) and 1) is in the range 0.5:1-3:1;—the ratio by weight between 4) and 5) ranges from 1:1 to 4.1.
    Type: Application
    Filed: August 30, 2011
    Publication date: December 22, 2011
    Applicant: SIPCAM S.P.A.
    Inventors: Marco BERNARDINI, Francesca BORGO, Luigi CAPUZZI, Pietro DOMENICHINI, Giorgio FRESCHI
  • Patent number: 7964635
    Abstract: The invention relates to compounds of the general formula (I) wherein X, Y and W have the significances given in claim 1 and optionally the enantiomers thereof. The active ingredients have advantageous pesticidal properties. They are especially suitable for controlling parasites in and on warm-blooded animals.
    Type: Grant
    Filed: January 8, 2009
    Date of Patent: June 21, 2011
    Assignee: Novartis AG
    Inventors: Noëlle Gauvry, Thomas Goebel, Pierre Ducray, François Pautrat, Ronald Kaminsky, Martin Jung
  • Publication number: 20110053778
    Abstract: 2-(3-Aminobenzoyl)-3-cyclopropyl-3-oxopropanenitriles of the formula (I) are described as herbicides. In this formula (I), X and Y are organic radicals such as alkyl and other radicals such as halogen, nitro and cyano.
    Type: Application
    Filed: July 27, 2010
    Publication date: March 3, 2011
    Applicant: BAYER CROPSCIENCE AG
    Inventors: Hartmut AHRENS, Ines Heinemann, Andreas Van Almsick, Ralf Braun, Jan Dittgen, Dieter Feucht, Martin Jeffrey Hills, Heinz Kehne, Christopher Hugh Rosinger, Stefan Lehr
  • Publication number: 20100234230
    Abstract: The invention provides aqueous pesticidal concentrates comprising at least one colloidal solid, a dispersed emulsion phase comprising at least one substantially water-insoluble pesticidally active ingredient, which is either itself an oily liquid comprising the oil phase, is a solid but is dissolved in an oily liquid present in the oil phase, is a solid and is dispersed within the oil phase or is present as a colloidal solid adsorbed to the liquid-liquid interface between the continuous aqueous phase and the dispersed oil phase and at least one Ostwald ripening inhibitor.
    Type: Application
    Filed: August 30, 2007
    Publication date: September 16, 2010
    Applicant: SYNGENTA CROP PROTECTION, INC.
    Inventor: Jeffrey Fowler
  • Publication number: 20100107283
    Abstract: The present invention provides chimeric regulatory elements constructed from gene regulatory element polynucleotide molecules isolated from the Zea mays genes fructose 1-6 bisphosphate aldolase (FDA), pyruvate orthophosphate dikinase (PPDK), or ribulose bisphosphate carboxylase activase (RUA), useful for expressing transgenes in plants. The invention further discloses compositions, polynucleotide constructs, transformed host cells, transgenic plants and seeds comprising the chimeric gene regulatory molecules, and methods for preparing and using the same.
    Type: Application
    Filed: November 23, 2009
    Publication date: April 29, 2010
    Inventors: Santanu Dasgupta, Targolli L. Jayaprakash, Shoba Cherian
  • Patent number: 7544637
    Abstract: The invention relates to 2-cyano-3-(halo)alkoxy-benzenesulfonamide compounds I where the variables Alk and R1 to R5 are as defined in claim 1, and/or to their agriculturally useful salts.
    Type: Grant
    Filed: November 24, 2005
    Date of Patent: June 9, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang von Deyn, Henricus Maria Martinus Bastiaans, Matthias Pohlman, Michael Rack, Ernst Baumann, Michael Puhl, Michael Hofmann, Livio Tedeschi, Markus Kordes, Christopher Koradin, Douglas D. Anspaugh, Deborah L. Culbertson, Henry van Tuyl Cotter, Hassan Oloumi-Sadeghi
  • Patent number: 7494956
    Abstract: The invention relates to compounds of the general formula (I) wherein X, Y and W have the significances given in claim 1 and optionally the enantiomers thereof. The active ingredients have advantageous pesticidal properties. They are especially suitable for controlling parasites in and on warm-blooded animals.
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: February 24, 2009
    Assignee: Novartis AG
    Inventors: Noëlle Gauvry, Thomas Goebel, Pierre Ducray, François Pautrat, Ronald Kaminsky, Martin Jung
  • Patent number: 7153813
    Abstract: The invention relates to novel substituted aryl ketones of the formula (I) in which Z, X, R and n are as defined in the disclosure, to processes for their preparation and to their use as crop treatment agents, and to intermediates for preparing compounds of the formula (I).
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: December 26, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen, Monika Schmitt
  • Patent number: 6949669
    Abstract: Compounds of general formula (I) wherein the substituents are as defined in claim 1 are suitable for use as herbicides
    Type: Grant
    Filed: January 23, 2001
    Date of Patent: September 27, 2005
    Assignee: Syngenta Crop Protection, Inc.
    Inventors: Gerald Wayne Craig, Martin Eberle, Martin Zeller, Steven Scott Bondy, Daniel Dennis Comer, Soan Cheng, Julie Elizabeth Penzotti, Peter Grootenhuis, Jürg Ehrler
  • Patent number: 6930208
    Abstract: What is described are derivatives of benzoylcyclohexanediones of the formula (I) and their use as herbicides. In this formula (I), R1a, R1b, R1c, R2, R3, R4 and R5 denote various radicals, X1 is a bridging atom, X2 is a carbon chain and X3 is a chalcogen atom or an oximino radical.
    Type: Grant
    Filed: April 8, 2003
    Date of Patent: August 16, 2005
    Assignee: Bayer CropScience GmbH
    Inventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Monika H. Schmitt, Thomas Auler, Hermann Bieringer, Hubert Menne
  • Patent number: 6919299
    Abstract: Herbicidal compositions comprising A) 2-[2-chloro-3-(2,2,2-trifluoroethoxymethyl)-4-methylsulfonyl-benzoyl]cyclohexane-1,3-dione and B) at least one compound from the group consisting of ethoxysulfuron, flumetsulam, halosulfuron, imazamox, imazapyr, imazaquin, imazethapyr, metosulam, nicosulfuron, primisulfuron, prosulfuron, rimsulfuron, thifensulfuron-methyl, triflusulfuron, foramsulfuron, ametryne, atrazine, bromoxynil, cyanazine, diuron, hexazinone, metribuzin, pyridate, terbuthylazine, 2,4-D, clopyralid, dicamba, diflufenzopyr, fluroxypyr, butylate, EPTC, fenoxaprop-P-ethyl, acetochlor, alachlor, dimethenamid, flufenacet, mefenacet, metolachlor, thenylchlor, S-metolachlor, fluthiacet-methyl, carfentrazone-ethyl, isoxaflutole, mesotrione, sulcotrione, 4-(4-trifluoromethyl-2-methylsulfonylbenzoyl)-5-hydroxy-1-methyl-3-methylpyrazole, glyphosate, pendimethalin, trifluralin, asulam, triaziflam, diflufenican and glufosinate-ammonium against monocotyledonous and/or dicotyledonous harmful plants are described
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: July 19, 2005
    Assignee: Bayer CropScience GmbH
    Inventors: Erwin Hacker, Hermann Bieringer, Hansjörg Krähmer
  • Patent number: 6906005
    Abstract: The present invention relates to surfactant systems and in particular herbicidal compositions comprising a water soluble herbicide and/or a salt thereof and a surfactant system, wherein the surfactant system comprises at least two surfactants selected from the group consisting of: i) alkyldiamine tetraalkoxylate surfactants; ii) N-alkyl alkyldiamine trialkoxylate surfactants; and iii) phosphated alcohol alkoxylate surfactants.
    Type: Grant
    Filed: November 30, 2001
    Date of Patent: June 14, 2005
    Assignee: Huntsman Corporation Australia Pty Ltd
    Inventors: Andrew Francis Kirby, Ashley Scott Martin, Paul Leslie Griffiths
  • Patent number: 6828276
    Abstract: There are described benzoylcyclohexanediones of the formula I, their preparation, and their use as herbicides and plant growth regulators. In this formula (I), C1, C2, C3 are cyclic radicals, X1 is a hetero atom, X2 is a chain of carbon atoms, L is a chain-like element, R1, R2, R3, R4, R5 are various radicals, and Y and Z are monoatomic bridge elements.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: December 7, 2004
    Assignee: Aventis CropScience GmbH
    Inventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Hermann Bieringer, Thomas Auler, Hubert Menne
  • Patent number: 6768025
    Abstract: Benzoylcyclohexanedione derivatives of the formula (I) and their use as herbicides are described. In this formula (I), R1, R3, and R4 are various radicals, L—(R2)n is haloalkyl, and n is 0 to 2.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: July 27, 2004
    Assignee: Aventis CropScience GmbH
    Inventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Thomas Auler, Hermann Bieringer, Hubert Menne
  • Patent number: 6764979
    Abstract: A herbicidal agent comprising: (1) water; (2) ioxynil and/or a derivative thereof; (3) a compound of the formula (I) RO—(CH2H4O)n(CH3H6O)m—R′  (I) wherein RO is an alcohol radical selected from the group consisting of branched or linear, saturated or unsaturated monohydric alcohols having from 1 to 6 carbon atoms, or a polyol radical having from 2 to 12 carbon atoms and from 2 to 6 hydroxyl groups; R′ is hydrogen or an ester group —CO—R″ wherein R″ is a branched or linear, saturated or unsaturated alkyl radical having 5 to 29 carbon atoms, n is a number between 1 and 50 and m is zero or a number between 1 and 10. The herbicidal agents permit high penetration of the herbicide into the plant.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: July 20, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
  • Patent number: 6759371
    Abstract: Herbicidal preparations which contain: (a) water; (b) a bromoxynil component; and (c) at least one compound corresponding to the general formula (I): RO—(C2H4O)n(C3H6O)m—R′  (I) wherein RO represents an alcohol moiety selected from the group consisting of C1-6 monohydric alcohols, and C2-12 polyols having from 2 to 6 hydroxyl groups; n represents a number of from 1 to 50; m represents a number of from 0 to 10; and wherein each R′ represents a substituent independently selected from the group consisting of hydrogen and an ester group of the general formula, —CO—R″, wherein each R″ independently represents an alkyl group having from 5 to 29 carbon atoms; with the proviso that at least one R′ represents —CO—R″, are described.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: July 6, 2004
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
  • Patent number: 6693063
    Abstract: The present invention relates to a herbicidal composition, comprising A) one or more compounds of the formula (I) in which Hal1 and Hal2 are identical or different halogen atoms, R1 is H, a cation or a C1-C20-carbon-containing radical and B) one or more surfactants, comprising as structural element at least 12 alkylene oxide units.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: February 17, 2004
    Assignee: Aventis CropScience GmbH
    Inventors: Gerhard Schnabel, Jean Kocur, Hans-Peter Krause, Julio Martinez de Una, Hans Philipp Huff, Udo Bickers
  • Publication number: 20040023806
    Abstract: The invention relates to novel compounds of the formula I 1
    Type: Application
    Filed: September 5, 2002
    Publication date: February 5, 2004
    Inventors: Hugo Ziegler, Saleem Farooq, Rene Zurflh
  • Publication number: 20030228982
    Abstract: The present invention relates to compounds of the formula (I) and/or salts thereof 1
    Type: Application
    Filed: December 13, 2002
    Publication date: December 11, 2003
    Inventors: Hendrik Helmke, Michael Gerhard Hoffmann, Klaus Haaf, Lothar Willms, Thomas Auler, Hermann Bieringer, Hubert Menne
  • Patent number: 6660692
    Abstract: This invention provides a method for controlling the growth of weeds (i.e. undesired vegetation) at a locus which comprises applying to the locus a herbicidally effective amount of: (a) picolinfen, a phenoxypicolinamide derivative of formula (I); and (b) a partner herbicide, selected from isoxazole, dione, urea and hydroxybenzonitrile herbicide.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: December 9, 2003
    Assignee: Aventis CropScience S.A.
    Inventor: Richard Henry Hewett
  • Patent number: 6620766
    Abstract: Compositions for preparation of wettable-powder and powder suspension herbicidal products containing low-melting agrochemical agents, such as bromoxynil esters, are provided. Preferred compositions are co-melts of bromoxynil esters with at least one additional herbicide or pesticide, particularly atrazine. The compositions of the invention have higher melting points than the bromoxynil ester component, and therefore have advantages in that the use of solvents and/or carriers in formulations can be avoided or minimized. The compositions can be processed into dry powders without the problems associated with the softening or melting of pure bromoxynil esters during grinding or milling, and without the need for dilution of the product with substantial amounts of inactive carriers. Compositions containing the alloys do not lose selectivity in the presence of oil adjuvants.
    Type: Grant
    Filed: March 19, 2002
    Date of Patent: September 16, 2003
    Assignee: Aventis Cropscience S.A.
    Inventor: Robert C. Ligon
  • Publication number: 20030158044
    Abstract: The invention relates to aqueous agents containing ioxynil or the derivatives thereof and compounds of general formula (I) in which: RO represents an alcohol residue selected from the group of branched or linear, saturated or unsaturated monohydric alcohols with 1 to 6 C atoms or of polyols with 2 to 12 C atoms and 2 to 6 hydroxyl groups; R′ represents hydrogen and/or an ester group —CO—R″, in which R″ represents a branched or liner, saturated or unsaturated alkyl residue with 5 to 29 C atoms; n is a number between 1 and 50, and; m is either equal to zero or to a number between 1 and 10. The inventive agents exhibit an increased level of penetration of the active substance into plants.
    Type: Application
    Filed: February 20, 2003
    Publication date: August 21, 2003
    Inventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
  • Patent number: 6599861
    Abstract: Compounds of formula I wherein the substituents are defined as in claim 1, as well as the agronomically acceptable salts, isomers and enantiomers of these compounds, as well as the agronomically acceptable salts/N-oxides/isomers/enantiomers of these compounds, are eminently suitable for use as herbicides.
    Type: Grant
    Filed: June 21, 2001
    Date of Patent: July 29, 2003
    Assignee: Syngenta Participations AG
    Inventors: Jürgen Schaetzer, Alain De Mesmaeker, Shy-Fuh Lee
  • Publication number: 20030125210
    Abstract: The invention relates to an aqueous means containing bromoxynil or the derivatives thereof. The invention also relates to compounds of the general formula (I): RO—(C2H4O)n(C3H6O)m—R′, wherein RO stands for an alcohol radical selected from the group of the branched or linear, saturated or unsaturated, monovalent alcohols having 1 to 6 C atoms or of the polyols having 2 to 12 C atoms and 2 to 6 hydroxyl groups and R′ stands for hydrogen and/or an ester group —CO—R″, wherein R″ means a branched or linear, saturated or unsaturated alkyl radical having 5 to 29 C atoms, n is a number between 1 and 50 and m is zero or a number between 1 and 10. An increased amount of the active agent penetrates the plant.
    Type: Application
    Filed: December 2, 2002
    Publication date: July 3, 2003
    Inventors: Horst-Werner Wollenweber, Hans-Georg Mainx, Benoit Abribat, Hans De Ruiter
  • Patent number: 6576596
    Abstract: The invention relates to 2-benzoylcyclohexane-1,3-diones of the formula I where R1, R2 are each hydrogen, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxyalkyl, alkenyl, alkynyl, —OR5, —OCOR6, —OSO2R6, —SH, —S(O)nR7, —SO2OR5, —SO2NR5R8, —NR8SO2R6 or —NR8COR6; R3 is hydrogen, cyano, alkyl, haloalkyl, —OR7, —SR7 or —NR7R10; R4 is hydrogen, substituted or unsubstituted alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkynyl, —COR9, —CO2R9, —COSR9 or —CONR8R9; X is oxygen or NR8; n is 0, 1 or 2; R5 is hydrogen, alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R6 is alkyl or haloalkyl; R7 is alkyl, haloalkyl, alkoxyalkyl, alkenyl or alkynyl; R8 is hydrogen or alkyl; R9 is alkyl, alkenyl, alkynyl, phenyl or benzyl; R10 is alkyl, haloalkyl, alkenyl or alkynyl; Q is a cyclohexane-1,3-dione ring with or without substitution attached in position 2; and agriculturally useful salts thereo
    Type: Grant
    Filed: June 23, 1999
    Date of Patent: June 10, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Regina Luise Hill, Uwe Kardorff, Michael Rack, Ernst Baumann, Wolfgang von Deyn, Stefan Engel, Guido Mayer, Martina Otten, Joachim Rheinheimer, Matthias Witschel, Ulf Misslitz, Helmut Walter, Karl-Otto Westphalen
  • Publication number: 20030104946
    Abstract: Herbicidal mixture comprising a benzoyl derivative, a fertilizer containing nitrogen and an adjuvant.
    Type: Application
    Filed: May 14, 2002
    Publication date: June 5, 2003
    Inventors: Udo Bickers, Erwin Hacker, Frank Sixl, Thomas Auler
  • Patent number: 6555500
    Abstract: Increasing the concentration of prolines such as 2-hydroxy-5-oxoproline, in the foliar portions of plants has been shown to cause an increase in carbon dioxide fixation, growth rate, dry weight, nutritional value (amino acids), nodulation and nitrogen fixation, photosynthetically derived chemical energy, and resistance to insect pests over the same properties for wild type plants.
    Type: Grant
    Filed: April 16, 2002
    Date of Patent: April 29, 2003
    Assignee: The Regents of the University of California
    Inventors: Pat J. Unkefer, Thomas J. Knight, Rodolfo A. Martinez
  • Publication number: 20030017948
    Abstract: The invention relates to a novel process for preparing N-substituted 2,4-diamino-5-fluoro-benzonitriles which are known as intermediates in the preparation of herbicides, to novel N-substituted 4-bromo-6-fluoro-1,3-phenylenediamines, to novel N-substituted 2-bromo-4-fluoro-5-nitro-anilines and to novel N-substituted 2-bromo-4-fluoro-anilines as intermediates for this process, and to processes for their preparation.
    Type: Application
    Filed: June 21, 2002
    Publication date: January 23, 2003
    Inventor: Achim Hupperts
  • Publication number: 20020115569
    Abstract: The present invention relates to a herbicidal composition, comprising
    Type: Application
    Filed: December 18, 2001
    Publication date: August 22, 2002
    Inventors: Gerhard Schnabel, Jean Kocur, Hans-Peter Krause, Julio Martinez de Una, Hans Philipp Huff, Udo Bickers
  • Patent number: 6337306
    Abstract: Phenoxyacetic acid derivatives of the formula: wherein R1, R2, Xn and A are as defined herein, and a process for preparing the derivatives. The derivatives are used as herbicides.
    Type: Grant
    Filed: November 5, 1999
    Date of Patent: January 8, 2002
    Assignee: Rhone-Poulenc Agro
    Inventors: Norio Sasaki, Atsushi Go, Hideshi Mukaida, Yukiko Oe
  • Patent number: 6265606
    Abstract: 1-Alkyl-4-benzoyl-5-hydroxypyrazole compounds in which the benzoyl moiety is substituted in the 2-position with a halo, alkyl, or alkoxy group, in the 4-position with an alkylsulfonyl group, and in the 3-position with an optionally substituted phenyl group, for example, 1-(1,1-dimethylethyl)-4-(2-methyl-4-methyl-sulfonyl-3-(4-methoxyphenyl)benzoyl-5-hydroxypyrazole, were prepared and found to be useful for the control of a variety of broadleaf and grassy weeds. The compounds can be applied either preemergently or postemergently and can be used to control undesirable vegetation selectively in small grain crops and turf or non-selectively.
    Type: Grant
    Filed: May 10, 1999
    Date of Patent: July 24, 2001
    Assignee: Dow AgroSciences LLC
    Inventors: Thomas L. Siddall, Zoltan L. Benko, Gail M. Garvin, Johnny L. Jackson, Jeffrey M. McQuiston, David G. Ouse, Thomas D. Thibault, James A. Turner, John C. Van Heertum
  • Publication number: 20010008874
    Abstract: A microcapsule (or microencapsulated product) having a uniform and smooth coating film and also an excellent performance of gradually liberating the content material is produced at a good particle size distribution while suppressing the occurrence of isolated or aggregated film material, aggregated microcapsules and isolated core material. The production process includes: a first coating step of mixing a water-soluble cationic amino resin and an anionic surfactant in the presence of a hydrophobic core material dispersed in an aqueous medium to coat the dispersed core material with a coacervate of the cationic amino resin and the anionic surfactant; and a second coating step of adding an amino resin prepolymer into an aqueous dispersion liquid containing the coated dispersed core material and polycondensating the amino resin prepolymer to further coat the coated dispersed core material with a polycondensate of the amino resin prepolymer.
    Type: Application
    Filed: January 12, 2001
    Publication date: July 19, 2001
    Inventors: Yutaka Igari, Yuzi Hori, Tsuneo Okamoto
  • Patent number: 6255252
    Abstract: A mixture of the known herbicide esters 3,5-dibromo-4-hydroxybenzonitrile (“bromoxynil” n-octanoate and bromoxynil n-heptanoate is provided having a molar ratio of n-octanoate n-heptanoate from 1:1.5 to 1.5:1, which mixture possesses an unexpectedly low melting point high solubility in hydrocarbon oils. Herbicidal compositions comprising bromoxynil n-octanoate and bromoxynil n-heptanoate in such molar ratio and a method for controlling the growth of weeds with such herbicidal compositions are also provided. The ester mixture may be formed by admixture of the esters, or by reacting bromoxynil with a mixture of n-octanoic and n-heptanoic acids or of their derivatives (e.g. acid chlorides or anhydrides).
    Type: Grant
    Filed: April 18, 1994
    Date of Patent: July 3, 2001
    Assignee: Aventis Agriculture Limited
    Inventors: Colin Charles Foan, Anthony Reginald Woodford
  • Patent number: 6251833
    Abstract: The present invention relates to novel 2-aryl-3-hydroxy-&Dgr;2-cyclopentene-1-one derivatives of the formula (I) in which A, B, D1, D2, G, W, X, Y and Z are each as defined in the description, to processes for their preparation and to their use as herbicides and pesticides.
    Type: Grant
    Filed: August 31, 1999
    Date of Patent: June 26, 2001
    Inventors: Christoph Erdelen, Ulrike Wachendorff-Neumann, Reiner Fischer, Alan Graff, Norbert Mencke, Andreas Turberg
  • Patent number: 6191071
    Abstract: The invention concerns novel plant-treatment agents comprising: at least one thermoplastically processable biodegradable polyester amide, optionally in a mixture with one or a plurality of further thermoplastically processable, biodegradable polymer components; at least one agrochemical substance; and optionally additives. The invention further concerns a process for preparing these agents, and their use in the application of agrochemical substances.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: February 20, 2001
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Simon, Hanns Peter Müller, Uwe Priesnitz, Hans-Georg Rast
  • Patent number: 6150304
    Abstract: The present invention relates to novel 2-aryl-3-hydroxy-cyclopent-2-en-1-one derivatives of the formula (I) ##STR1## in which X represents halogen, nitro, cyano, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl or halogenoalkoxy,Y represents hydrogen, halogen, nitro, cyano, alkyl, alkoxy, alkenyloxy, alkylthio, alkylsulphinyl, alkylsulphonyl, halogenoalkyl or halogenoalkoxy,Z represents halogen, nitro, cyano, alkyl, alkoxy or halogenoalkoxy andA, B, D.sup.1, D.sup.2, G and n have the meaning given in the description,several processes for their preparation and their use as compositions for controlling pests and as herbicides.
    Type: Grant
    Filed: August 6, 1998
    Date of Patent: November 21, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reiner Fischer, Jacques Dumas, Thomas Bretschneider, Christoph Erdelen, Ulrike Wachendorff-Neumann, Hans-Joachim Santel, Markus Dollinger, Andreas Turberg, Norbert Mencke
  • Patent number: 6040274
    Abstract: 2- Aroylcyclohexanediones I ##STR1## where X, Y=O or S;Ar=phenyl or heteroaryl in each case having 1-4 substituents: halogen, cyano, nitro, --N.dbd.N--Ph, C.sub.1 -C.sub.4 -alkoxycarbonyl, --N(R.sup.9)--COR.sup.10, --N(R.sup.9)--SO.sub.2 --R.sup.11, --SO.sub.2 --N(R.sup.9)R.sup.10, --S(O).sub.m --R.sup.8 or opt. subst. C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl or C.sub.1 -C.sub.4 -haloalkoxy;two adjacent C atoms of the phenyl or heteroaryl ring can also be bridged by means of a chain --C(R.sup.12).dbd.C(R.sup.13)--C(R.sup.14).dbd.C(R.sup.15)--, --Z.sup.1 --C(R.sup.12).dbd.N--, --Z.sup.1 --N.dbd.C(R.sup.12)--, --Z.sub.1 --C(R.sup.12).dbd.C(R.sup.13)--, --Z.sup.1 --C(R.sup.12).dbd.C(R.sup.13)--C(R.sup.14,R.sup.15)--, --Z.sup.1 --C (R.sup.12,R.sup.13)--C(R.sup.14,R.sup.15)--, --Z.sup.1 --C(R.sup.12,R.sup.13)--C(R.sup.14 R.sup.15)--Z.sup.2 --, --C(R.sup.12,R.sup.13)--Z.sup.1 --C(R.sup.14,R.sup.15)--C(R.sup.16,R.sup.17)--, --Z.sup.1 --N(R.sup.20)--Z.sup.2 --, --Z.sup.1 --Z.sup.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: March 21, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Jurgen Kast, Marcus Vossen, Wolfgang von Deyn, Stefan Engel, Regina Luise Hill, Uwe Kardorff, Martina Otten, Peter Plath, Helmut Walter, Karl-Otto Westphalen, Ulf Misslitz