R Is Acyclic Patents (Class 504/339)
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Patent number: 11089780Abstract: The present invention relates to a composition comprising microcapsules, which comprise a polyurea shell and a core, wherein the core comprises pendimethalin and the shell comprises a polymerization product of a tetramethylxylylene diisocyanate, and a polyamine with at least three amine groups, and where the polymerization product comprises less than 5 wt % of further isocyanate monomers in polymerized form, based on the weight of the tetramethylxylylene diisocyanate; a method for preparing the composition comprising the steps of contacting water, the pendimethalin, the tetramethylxylylene diisocyanate, and the polyamine; and to a method of controlling undesired plant growth, wherein the composition is allowed to act on the soil and/or on undesired plants and/or on the crop plants and/or on their environment.Type: GrantFiled: June 8, 2016Date of Patent: August 17, 2021Assignee: BASF SEInventors: Klaus Kolb, Wolfgang Gregori, Ulrich Steinbrenner, Liliana Parra Rapado
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Patent number: 9426983Abstract: An aqueous suspension concentrate (SC) composition of a crop protection active compound is provided, the concentrate comprising: (a) 50 to 700 g/l of an active ingredient comprising at least one compound active in crop protection; and (b) a concentrate stabilizing component consisting of: (i) up to 150 g/l of at least one non-ionic dispersing agent; and/or (ii) to 150 g/l of at least one anionic dispersing agent; and 10 (c) 200 to 800 g/l of water; with the proviso that in the case that the suspension concentrate comprises an active ingredient other than an azole and the concentrate stabilizing component consists of an anionic dispersing agent only, the anionic dispersing agent is present in an amount of greater than 30 g/l; or in the case that the suspension concentrate comprises an azole derivative as the active ingredient and the concentrate stabilizing component consists of both an anionic dispersing agent and a non-ionic dispersing agent, the anionic dispersing agent is present in an amount of greater thType: GrantFiled: December 19, 2008Date of Patent: August 30, 2016Assignee: ROTAM AGROCHEM INTERNATIONAL COMPANY LIMITEDInventor: James T. Bristow
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Publication number: 20150111749Abstract: Methods and compositions for controlling plant pests, particularly weeds and/or plant phytopathogens using sarmentine and/or analogs thereof are disclosed.Type: ApplicationFiled: December 31, 2014Publication date: April 23, 2015Inventors: Huazhang Huang, Ratnakar Asolkar
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Publication number: 20150099637Abstract: An improved herbicidal suspension concentrate comprising at least one anilide herbicide compound as the active ingredient and containing at least one carbamate compound as a crystallization suppressant, the resulting formulation exhibiting improved caking, gelling and settling properties and resulting in a more even distribution of active ingredient.Type: ApplicationFiled: October 6, 2013Publication date: April 9, 2015Inventor: Bomi Framroze
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Patent number: 8981148Abstract: An esteramide compound of the following formula (I): R1OOC-A-CONR2R3??(I) is described, wherein: A is a covalent bond or a methylene group —CH2—; R1 is an optionally substituted, saturated or unsaturated aliphatic or cycloaliphatic hydrocarbon group including from 5 to 36 carbon atoms, R2 and R3, either identical or different, are groups selected from a hydrogen atom, and optionally substituted hydrocarbon groups, preferably including from 1 to 36 carbon atoms, and R2 and R3 not being simultaneously hydrogen atoms. Also described, are applications for using the esteramide compound, notably as a solvent.Type: GrantFiled: March 17, 2011Date of Patent: March 17, 2015Assignee: Rhodia OperationsInventors: Massimo Guglieri, Thierry Vidal
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Patent number: 8981150Abstract: Novel ether-amide compounds are described. Uses of the compounds, in particular as solvents, for example in phytosanitary formulations are also described.Type: GrantFiled: October 18, 2010Date of Patent: March 17, 2015Assignee: Rhodia OperationsInventors: Thierry Vidal, Massimo Guglieri, Olivier Jentzer
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Patent number: 8883686Abstract: Suggested are biocide compositions, comprising (a) Glycerol(ether)phosphates; (b) Biocides and optionally (c) Oil components or co-solvents and/or (d) Emulsifiers. The compositions show excellent adjuvant and complexing properties.Type: GrantFiled: March 16, 2011Date of Patent: November 11, 2014Assignee: Cognis IP Management GmbHInventors: Joaquin Bigorra Llosas, Daniel J. Karlik, Timothy H. Anderson
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Publication number: 20140256554Abstract: The present disclosure relates to compositions comprising from 10 to 90 wt % of a mixture M of compounds A having formula R1CONR2R3, wherein R1, R2, and R3 are described herein, and from 10 to 90 wt % of at least one compound B selected from the amide solvents, optionally combined with an ester solvent, and methods for producing the same. The present disclosure further relates to phytosanitary formulations comprising such compositions.Type: ApplicationFiled: October 11, 2012Publication date: September 11, 2014Applicant: RHODIA OPERATIONSInventors: Thierry Vidal, Benoit Abribat, Valerio Bramati, Marc Balastre
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Publication number: 20140206541Abstract: Suggested are agricultural compositions, comprising one or more esters of C6-C22 monocarboxylic acids or C2-C20 dicarboxylic acids and polyhydric alcohols selected from the group consisting of diglycerol, triglycerol, oligo- or polyglycerol and their respective alkylene oxide adducts, one or more biocides, and optionally, one or more oil components or solvents and/or one or more emulsifiers, wherein the esters are essentially free of esters of monomeric glycerol and esters of alkylene oxide adducts of monomeric glycerol. The esters are useful for forming agricultural compositions using hard water.Type: ApplicationFiled: January 24, 2013Publication date: July 24, 2014Inventors: Dean Oester, Mike White, Timothy H. Anderson
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Patent number: 8741807Abstract: A compound useful as a plant activator for activating an endogenous defense system of a plant to control disease damage is provided. A compound represented by the formula: (R3)NH—(CH2)4—N(R1)—(CH2)3—NH(R2) (one of R1 and R2 represents a linear C6-18 alkanoyl group or alkenoyl group, the other represents hydrogen atom or a protective group of amino group; and R3 represents hydrogen atom or a protective group of amino group).Type: GrantFiled: February 23, 2012Date of Patent: June 3, 2014Assignees: The University of Tokyo, National Institute of Agrobiological Sciences, RikenInventors: Tadao Asami, Masashi Hikosaka, Masaki Mori, Satoru Maeda, Fumio Matsuda, Kazuki Saito
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Patent number: 8536091Abstract: System, including methods compositions, and kits, for controlling the growth of fungi and other pathogens in plants using at least one alkamide, which may function by increasing or eliciting natural defense mechanisms of the plants against such pathogens.Type: GrantFiled: August 5, 2009Date of Patent: September 17, 2013Inventors: José López-Bucio, Jorge Molina-Torres, Luis Rafael Herrera-Estrella
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Publication number: 20130210630Abstract: A concentrate suitable for forming a stable aqueous composition upon dilution with water includes in one aspect a self-emulsifying oil comprising a modified vegetable oil which is modified with a moiety more polar than the vegetable oil and the polar moiety is attached by a covalent bond to the vegetable oil and an active ingredient.Type: ApplicationFiled: July 1, 2011Publication date: August 15, 2013Applicant: ISP Investments Inc.Inventors: Osma M. Musa, Kolazl S. Narayanan, Jenn S. Shih, Xin Qu, Tom Zhang, Giovanni Nicole Onnembo
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Patent number: 8461081Abstract: The invention relates to biocide compositions, comprising (a) at least one dialkylamide based on oleic and/or linoleic acid, and (b) at least one biocide. The compositions exhibit an improved stability even if stored at temperatures between 5° and 40° C. for an extended period.Type: GrantFiled: February 14, 2008Date of Patent: June 11, 2013Assignee: Cognis IP Management GmbHInventors: Joaquin Bigorra Llosas, Javier Raya, Bernd Fabry, Rainer Höfer, Benoit Abribat
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Publication number: 20130029847Abstract: Methods of reducing injury to crop foliage and achieving weed control using encapsulated acetamide herbicides in pre-plant or preemergence crop plant applications are described. A composition comprising a first population of a particulate microencapsulated acetamide herbicide and a second population of a particulate microencapsulated acetamide herbicide is described wherein the application mixture exhibits a bimodal acetamide release profile. The compositions provide reduced crop injury through controlled herbicide release.Type: ApplicationFiled: August 18, 2011Publication date: January 31, 2013Applicant: MONSANTO TECHNOLOGY LLCInventors: Douglas A. Findley, S. Douglas Prosch, Matthew T. Faletti, Alejandro Perez-Jones, Ronald J. Brinker
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Publication number: 20130012387Abstract: Suggested are biocide compositions, comprising (a) Glycerol(ether)phosphates; (b) Biocides and optionally (c) Oil components or co-solvents and/or (d) Emulsifiers. The compositions show excellent adjuvant and complexing properties.Type: ApplicationFiled: March 6, 2011Publication date: January 10, 2013Applicant: Cognis IP Management GmbHInventors: Joaquin Bigorra Llosas, Daniel J. Karlik, Timothy H. Anderson
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Publication number: 20120309625Abstract: Described are biocide compositions, comprising (a) carbamates, (b) biocides and optionally (c) oil components/co-solvents and/or (d) emulsifiers. The compositions have high solubility for biocides and improved emulsification properties.Type: ApplicationFiled: November 8, 2010Publication date: December 6, 2012Applicant: Cognis IP Management GmbHInventors: Stéphanie Merlet, Cindy Münzenberg, Helena Wiethoff
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Publication number: 20120192307Abstract: New plants were created from a new and efficient method of intergeneric hybridization between the genus Argyranthemum as a female parent and a plant from I. versicolor and Glebionis sp. as a male parent. The plants were created by rescuing an embryo from the cross-pollination of a tetraploid or aneu-tetraploid Argyranthemum female parent with a plant from the group I. versicolor and Glebionis sp. as a male parent. The new plants often exhibited the perennial and multi-branched habit of the female Argyranthemum parent, with large capitula size and different ray floret colors, many not previously seen in Argyranthemum. When compared to Argyranthemum, the new plants possessed improved tolerance to high growing temperatures. In addition to providing the intergeneric hybrid plants and parts thereof, the invention provides methods for making such plants and methods for creating intergeneric hybrid plants.Type: ApplicationFiled: January 26, 2011Publication date: July 26, 2012Applicant: BONZA BOTANICALS PTY LTDInventor: Andrew Bernuetz
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Publication number: 20120088668Abstract: A composition comprising a compound selected from an auxin, an auxin precursor, an auxin metabolite or a derivative of said auxin, auxin precursor or auxin metabolite or a mixture thereof and acetaminophen or a derivative thereof for use as a chemical thinning agent.Type: ApplicationFiled: April 7, 2010Publication date: April 12, 2012Applicant: TAMINCO, NAAMLOZE VENNOOTSCHAPInventors: Richard Williams, Tom Deckers, Peter Roose, Johan Josef De Saegher
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Publication number: 20110224084Abstract: New agricultural compositions comprising (a) biocides, (b) monopropylenglycol esters, and optionally (c) oil components and/or co-solvents, and/or (d) emulsifiers. The compositions show high solubility for biocides and improved emulsification properties.Type: ApplicationFiled: September 25, 2009Publication date: September 15, 2011Applicant: Cognis IP Management GmbHInventors: Stéphanie Merlet, Joaquin Bigorra Llosas
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Publication number: 20110136668Abstract: System, including methods compositions, and kits, for controlling the growth of fungi and other pathogens in plants using at least one alkamide, which may function by increasing or eliciting natural defense mechanisms of the plants against such pathogens.Type: ApplicationFiled: August 5, 2009Publication date: June 9, 2011Inventors: José López-Bucio, Jorge Molina-Torres, Luis Rafael Herrera-Estrella
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Publication number: 20110124505Abstract: New agricultural compositions are disclosed, comprising (a) one or more biocides, (b) one or more C8-C12 fatty acid dialkyl amides, (c) optionally, one or more oil components, and (d) optionally, one or more emulsifiers. The compositions show high solubility for biocides, and improved storage stability.Type: ApplicationFiled: July 14, 2009Publication date: May 26, 2011Applicant: COGNIS IP MANAGEMENT GMBHInventors: Stephanie Merlet, Maria Da Silva Marques, Janina Serres
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Publication number: 20110021358Abstract: Methods and compositions for controlling plant pests, particularly weeds and/or plant phytopathogens using sarmentine and/or analogs thereof are disclosed.Type: ApplicationFiled: July 20, 2010Publication date: January 27, 2011Applicant: Marrone Bio Innovations, Inc.Inventors: Huazhang Huang, Ratnakar Asolkar
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Publication number: 20100331189Abstract: A growth promoter according to the present invention that can be applied to a plant other than solanaceous plants is a plant growth promoter utilizing potato cyst nematodes and contains a fatty acid dialkanolamide represented by the following general formula (1) as a substance that acts on the potato cyst nematodes: R—CO—N(—R?—OH)(—R?—OH)??(1) (in the general formula (1), R represents an alkyl group that has 1 to 20 carbon atoms and may be substituted, and R? and R? may be the same or different from each other and each represent an alkylene group that has 1 to 10 carbon atoms and may be substituted). When the plant growth promoter of the present invention is sprayed on the soil where the eggs of potato cyst nematodes are present, potato cyst nematodes hatched by the effect of the above-described fatty acid dialkanolamide contained in the plant growth promoter promote the growth of a non-host plant.Type: ApplicationFiled: February 24, 2009Publication date: December 30, 2010Applicant: TOKAI UNIVERSITY EDUCATIONAL SYSTEMInventors: Akio Fukuzawa, Keita Fukui, Souhei Okumura
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Publication number: 20090156405Abstract: This invention relates to a synergistic composition made of a herbicidally effective amount of a propanil-based product, such as SUPER WHAM® and the at least one ACCase inhibitor herbicide such as CLINCHER® in an amount sufficient to facilitate the herbicidal activity of the propanil-based herbicide. It has been found that this synergistic composition, when applied to a field of rice, allows a reduction in the amount of herbicide needed, greater flexibility in timing of the application and broad spectrum of weed control.Type: ApplicationFiled: February 26, 2009Publication date: June 18, 2009Applicant: RICECO, INC.Inventor: John R. Leeper
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Publication number: 20080242548Abstract: A method of producing a controlled release form of an agricultural active material includes the provision of an organic liquid composition in which the active is present, but where the liquid composition is free from aromatic solvents and is maintained below the normal melting point of the active. The liquid composition is formed into small droplets and the droplets are enclosed by a non-water soluble shell to provide microcapsules, the shell of which is designed to release the agricultural active at a pre-selected controlled rate when the microcapsule is exposed to natural environmental conditions. Controlled release forms of agricultural actives are also provided.Type: ApplicationFiled: May 5, 2008Publication date: October 2, 2008Applicant: Monsanto Technology, L.L.C.Inventors: Jawed Asrar, Yiwei Ding, Michael E. Seitz, Ronald J. Brinker
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Patent number: 7205261Abstract: N-acylethanolamines (NAEs) that can deliver an ethylene- or cytokinin-like effect to a plant, plant part or fungus are disclosed. Also disclosed are methods of using the NAEs.Type: GrantFiled: August 7, 2003Date of Patent: April 17, 2007Assignee: Nutra-Park, Inc.Inventors: Keith Rowley, Sang Won Jeong, Keith Cowan
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Patent number: 7199082Abstract: Disclosed are compositions that comprise one or more N-acylethanolamine compounds for maintaining the freshness and appearance of cut flowers, floral products, decorative foliage, fruits, and other plant cuttings. More specifically, the present invention provides methods for treating and storing cut flowers, Christmas trees, fruits, and other severed plant parts that preserve the appearance, freshness, fragrance and/or aesthetic qualities of the botanical products. Using the disclosed compositions, the shelf life of cut flowers was substantially prolonged, in many cases 2 to 5 times longer than untreated flowers, with the treated flowers or foliage appearing healthy and viable, and without wilting, dehydration, leaf drop, or visible signs of senescence. Likewise, treatment of ornamental coniferous plants with the anti-senescent compositions delayed deterioration and leaf drop, while extending the overall appearance and quality of the plants and plant cuttings.Type: GrantFiled: October 30, 2000Date of Patent: April 3, 2007Assignee: University of North TexasInventors: Kent D. Chapman, Shea Austin-Brown
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Patent number: 6869914Abstract: A process for the preparation of a solvent-free suspension of a low-melting point water-insoluble solid agrochemical active ingredient, which comprises suspending 1-40% by weight of a silica-based carrier in 40 to 97% by weight of water in the presence of 1-40% by weight of anionic dispersant, heating the suspension thus obtained to a temperature above that of the active ingredient, and adding, with stirring, 1-25% by weight of a molten active ingredient with a melting point of <80° C. or a mixture of at least two active ingredients each having a melting point of <80° C. The present invention furthermore relates to the preparation of suspension concentrates, water-dispersible powders and water-dispersible granules based on the suspensions prepared via the abovementioned process.Type: GrantFiled: December 16, 2002Date of Patent: March 22, 2005Assignee: BASF AktiengesellschaftInventors: Matthias Bratz, Karl-Friedrich Jäger
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Patent number: 6235682Abstract: Compositions comprising a herbicide wherein it is desired that the compound not be retained by the plant foliage, and a repellant adjuvant, wherein the repellant modifies the surface properties of the composition so that retention of the composition on foliage of a cultivated plant is reduced are described. In particular, the herbicide composition comprises a repellant adjuvant that is an aqueous solution of an alkyltrialkoxysilane such as methyltrimethoxysilane and a water soluble silane coupling agent such as N-(2-aminoethyl)-3-aminopropyltrimethoxysilane or an aqueous solution of an organosiliconate such as sodium methyl siliconate. Methods are described for using these compositions to prevent weeds without injury to cultivated plants, which plants include crop plants, food plants, turfgrass, ornamental plants, and garden plants.Type: GrantFiled: July 15, 1999Date of Patent: May 22, 2001Assignees: Board of Trustees operating Michigan State University, Dow Corning CorporationInventors: Donald Penner, Christy L. Sprague, Richard F. Burow
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Patent number: 6121195Abstract: Methods and compositions for enhancing plant growth provide for foliar application of a substance which enhances the accumulation of formyltetrahydropteroyl polyglutamate (C.sub.1 -THF) in a treated plant. Treatment with substances that contribute to the structure of C.sub.1 -THF increase the rate and quantity of carbon fixation by the plant. Thereafter, plant growth is further improved either by exposure of the plant to elevated oxygen, illumination and heat or by foliar input of single carbon fragment sources. Optimal results are obtained by combined treatment with a substance that can serve as a sink for C.sub.1 fragments produced in the leaf.Type: GrantFiled: December 7, 1998Date of Patent: September 19, 2000Inventors: Arthur M. Nonomura, John N. Nishio, Andrew A. Benson
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Patent number: 5985793Abstract: A novel method is provided wherein plants are first treated with an exogenous chemical (e.g., glyphosate herbicide) and then sequentially treated with a liquid accession agent which provides improved biological (e.g., herbicidal) effectiveness such that plants are controlled with lower rates of the applied exogenous chemical (e.g., glyphosate herbicide). Sequential application has been demonstrated to reduce the antagonism to herbicidal effectiveness that can be exhibited when the accession agent is added to a herbicide in a tank mix or simple coformulation. Typical accession agents employed in the disclosed method include a class of surfactants known as superwetting agents, such as certain organosilicone-based and fluorocarbon-based surfactants.Type: GrantFiled: August 14, 1997Date of Patent: November 16, 1999Assignee: Monsanto CompanyInventors: Joseph J. Sandbrink, James M. Warner, Daniel R. Wright, Paul C. C. Feng
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Patent number: 5714439Abstract: A dispersible granular formulation has been developed which contains at least 60% propanil herbicide. This formulation also provides excellent suspensibility and dispensability characteristics and resists attrition.Type: GrantFiled: May 28, 1996Date of Patent: February 3, 1998Assignee: Rohm and Haas CompanyInventors: Richard David Houghton, Linda Louise Graham, David Prescott Krutsch
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Patent number: 5693592Abstract: A method of controlling blooming in dormant perennial plants which method includes application to the dormant perennial plant of a composition including a growth regulating compound selected from the group consisting of fatty acid esters, fatty acid amides, fatty alcohols, fatty alcohol alkoxylates, phthalate esters, phthalic acid amides and imides and mixtures of two or more thereof.Type: GrantFiled: May 22, 1996Date of Patent: December 2, 1997Assignee: SST Australia Pty. Ltd.Inventor: John Illingworth
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Patent number: 5688742Abstract: A method for preparing a dust-free beaded product from a low melting material is disclosed. The method is particularly applicable to manufacturing processes in which the last step in preparation of a product is a water wash step.Type: GrantFiled: August 18, 1995Date of Patent: November 18, 1997Assignee: Rohm and Haas CompanyInventors: William Edward Mayeros, Jr., Fereydon Abdesaken
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Patent number: 5674812Abstract: 5-(Sulfo-/carbamoylmethyl)cyclohexenone oxime ethers I ##STR1## where R.sup.1 =C.sub.1 -C.sub.6 -alkyl;R.sup.2 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.3 -alkoxy-C.sub.1 -C.sub.3 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl;R.sup.3 =C.sub.1 -C.sub.4 -alkylsulfonyl or C.sub.1 -C.sub.4 -alkylcarbonyl;Alk=a C.sub.2 -C.sub.4 -alkylene, C.sub.3 -C.sub.4 -alkenylene, C.sub.3 -C.sub.4 -alkynylene or C.sub.2 -C.sub.3 -alkyleneoxy chain, it being possible for each chain if desired to carry a C.sub.1 -C.sub.3 -alkyl group;X.sup.1, X.sup.2 and X.sup.3 =H, halogen, C.sub.1 -C.sub.4 -haloalkyl,and their salts and esters are described.Type: GrantFiled: March 31, 1995Date of Patent: October 7, 1997Assignee: BASF AktiengesellschaftInventors: Ulf Misslitz, Helmut Walter, Karl-Otto Westphalen, Matthias Gerber
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Patent number: 5635447Abstract: A herbicide composition which comprises a herbicide and a small but herbicide absorption enhancing effective amount of a water soluble, non-aromatic polyorganic acid or a salt or copolymer thereof such as polyaspartic acid.Type: GrantFiled: March 22, 1996Date of Patent: June 3, 1997Assignee: Donlar CorporationInventor: J. Larry Sanders
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Patent number: 5550100Abstract: New and improved compositions comprising particulates and an effective amount of manganese chloride to reduce significantly the wetting time and/or the dispersion time of said particulates relative to said time(s) in the absence of said salt(s) have been discovered. Methods for reducing the wetting time of particulates in liquid have also been discovered.Type: GrantFiled: June 6, 1995Date of Patent: August 27, 1996Assignee: Rohm and Haas CompanyInventor: Yili Guo
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Patent number: 5532209Abstract: A dispersable granular formulation has been developed which contains at least 60% propanil herbicide. This formulation also provides excellent suspensibility and dispersibility characteristics and resists attrition.Type: GrantFiled: June 6, 1995Date of Patent: July 2, 1996Assignee: Rohm and Haas CompanyInventors: Richard D. Houghton, Linda L. Graham, David P. Krutsch
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Patent number: 5514642Abstract: Cyclohexenone oxime ethers of the formula I ##STR1##Type: GrantFiled: February 13, 1995Date of Patent: May 7, 1996Assignee: BASF AktiengesellschaftInventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Dieter Kolassa, Helmut Walter, Karl-Otto Westphalen, Matthias Gerber, Uwe Kardorff
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Patent number: 5489569Abstract: Pesticidal and fertilizer compositions containing at least one compound of formula IR.sub.3 C(O)--N(R.sub.1)(R.sub.2) (I)wherein R.sub.1 is hydrogen or a substituted or unsubstituted C.sub.1 -C.sub.6 alkyl group; R.sub.2 is hydrogen or a substituted or unsubstituted C.sub.1 -C.sub.6 alkyl group; and R.sub.3 C(O)-- is a substituted or unsubstituted fatty acid residue of 8 to 22 carbon atoms are provided. A method of increasing the effectiveness of a pesticide which comprises applying a pesticide and an amount of a compound of formula I effective to increase the pesticidal activity of the pesticide is also provided. A method for increasing the effectiveness of a fertilizer which comprises applying to a plant in need thereof a fertilizer and an amount of a compound of formula I effective to increase the fertilizing activity of the fertilizer is also described.Type: GrantFiled: February 1, 1995Date of Patent: February 6, 1996Assignee: Buckman Laboratories International, Inc.Inventors: Stephen D. Bryant, James C. Lee, M. Sheldon Ellis
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Patent number: 5395819Abstract: Stable herbicide solutions of propanil having no or little tendency to precipitate or crystallize propanil from the solution even upon storage in a cold place are prepared by dissolving the propanil in (a) a solvent of the glycol ether-type having a solubility of not more than 5% by weight in water at 20.degree. C. and (b) dimethylsulfoxide or (c) N-methyl-2-pyrrolidone, and wherein propanil is present in an amount of 20 to 45% by weight, the glycol ether-type solvent is present in an amount of 35 to 85% by weight, and the dimethylsulfoxide or N-methyl-2-pyrrolidone is present in an amount of 1 to 20% by weight, on the basis of the total weight of the composition.Type: GrantFiled: August 17, 1993Date of Patent: March 7, 1995Assignee: Kumiai Chemical Industry Co., Ltd.Inventors: Shigeki Fujita, Kanji Nakamura
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Patent number: 5362707Abstract: The present invention relates to new plant-protection suspo-emulsions. More specifically, the invention relates to a suspo-emulsion of a solid active substance, having a melting point greater than or equal to 45.degree. C. and which is substantially insoluble in water. The suspo-emulsion comprises at least one oil; a first surface-active system comprising at least sucroglycerides; the solid active substance; and either (A) a nonionic or anionic surface-active agent, or (B) a second surface-active system containing sucroglycerides and at least one compound selected from the group consisting of an alkoxylated triglyceride, an alkoxylated fatty acid, a sorbitan ester, and an alkoxylated sorbitan ester, and optionally a phospholipid.Type: GrantFiled: December 10, 1991Date of Patent: November 8, 1994Assignee: Rhone-Poulenc ChimieInventors: Jean-Francois Fiard, Jean-Michel Mercier, Marie-Luce Prevotat
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Patent number: 5290757Abstract: A composition useful as a selective preemergence herbicide is provided, comprising an effective amount of a dipeptide selected from the group consisting of Gln-Gln, Ala-Asn, Ala-Gln, Gly-Ala, Ala-Ala and mixtures thereof, in combination with a compatible carrier vehicle.Type: GrantFiled: August 3, 1993Date of Patent: March 1, 1994Assignees: Iowa State University Research Foundation, Inc., Grain Processing CorporationInventors: Nick E. Christians, John T. Garbutt, Dianna Liu
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Patent number: 5273955Abstract: A herbicide composition containing propanil as active ingredient is now provided in the form of emulsifiable concentrated organic solution of propanil and surface-active agent(s) in non-toxic mixed organic solvents, which is readily dilutable with water to prepare a stable aqueous emulsion comprising the organic solution of propanil as the disperse phase dispersed in water as the continuous phase of the resulting aqueous emulsion without involving precipitation of propanil solids in said emulsion. Said mixed organic solvents may comprise a mixture of a glycol ether-type solvent with either one or two of dimethyl-sulfoxide and N-methyl-2-pyrrolidone, optionally along with an aromatic solvent. Also, a herbicide composition is provided in the form of a stable solution of propanil in non-toxic mixed organic solvents similar to those mentioned above, which is stable on storage and may be formulated into an emulsifiable concentrated organic solution of propanil by adding surface-active agent(s) thereinto.Type: GrantFiled: February 18, 1992Date of Patent: December 28, 1993Assignee: Kumiai Chemical Industry Co., Ltd.Inventors: Shigeki Fujita, Kanji Nakamura
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Patent number: 5228898Abstract: This invention relates to substituted bicycloheptadione derivatives with high herbicidal activity which are represented by general formula (I) ##STR1## (where R.sup.1 is a lower alkyl group, a phenyl group which may be substituted, an aralkyl group which may be substituted, or a heterocyclic group which may be substituted;R.sup.2 is, same or different, a halogen, an alkoxy group, an alkylthio group, an alkylsulfonyl group, an alkyl group, an alkoxyalkyl group, or an alkoxylcarbonyl group, and n is 0 to 4;R.sup.3 and R.sup.4 are, same or different, hydrogen or a lower alkyl group).Type: GrantFiled: February 3, 1992Date of Patent: July 20, 1993Assignee: Nippon Soda Co., Ltd.Inventors: Akiyoshi Ueda, Shigemi Suga, Hiroyuki Adachi, Toshio Aihara, Kazuyuki Tomida, Hideki Yamagishi, Hideo Hosaka
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Patent number: 5198012Abstract: A biocide composition comprises an effective amount of a biocide and an effective amount of a biocide activator selected from the group consisting of an alkyl phosphate, an alkenyl phosphate, a hydroxyalkyl phosphate, a polyoxyalkylene alkyl ether phosphate, a salt thereof, a polyoxyalkylene alkenyl ether phosphate, a salt thereof, a polyoxyalkylene hydroxyalkyl ether phosphate and a salt thereof.Type: GrantFiled: May 21, 1991Date of Patent: March 30, 1993Assignee: Kao CorporationInventor: Tetsuji Iwasaki
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Patent number: 5190573Abstract: Cyclohexenone oxime ethers ##STR1## where R.sup.1 is alkyl;A is substituted or unsubstituted alkylene or alkenylene, where methylene is replaced by an oxygen atom, a sulfur atom, a sulfoxyl group, a sulfonyl group or --NR.sup.a --,Z is phenyl or a 5- or 6-membered heteroaromatic structure;X is substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, substituted or unsubstituted benzyloxycarbony or phenyl;n is 0 to 3, or 1 to 5 where X is halogen;R.sup.Type: GrantFiled: May 8, 1991Date of Patent: March 2, 1993Assignee: BASF AktiengesellschaftInventors: Ulf Misslitz, Norbert Meyer, Juergen Kast, Norbert Goetz, Albrecht Harreus, Bruno Wuerzer, Helmut Walter, Karl-Otto Westphalen, Matthias Gerber
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Patent number: 5185024Abstract: This invention discloses methods for manufacture and use of poly(ammonium acrylate) and polyacrylamide hydrogels in agricultural applications. Such hydrogels are applied to the soil or the plants by spraying. Spraying is advantageous over other methods of application, such as mixing with soil and broadcasting because of enhanced plant contact, evenness of distribution, and reduced labor. The gels are prepared for spraying by adding water to provide a readily deformable polymer which will pass through a spray apparatus. The hydrogels sprayed may include additives including micronutrients, maconutrients, pesticides, microbes, plant growth regulators, surfactants, and freezing point modifiers. Use of the hydrogels saves irrigation water and ameliorates salting of irrigated cropland. Sprayed hydrogels may also be used to protect crops from freezing and to protect foliage from desiccation.Type: GrantFiled: October 24, 1991Date of Patent: February 9, 1993Assignee: Aqua Source Inc.Inventors: Sidney R. Siemer, Louis L. Wood, Gary J. Calton