Organic Nitrogen Containing Solvent, Emulsifier, Or Foaming Agent Of Formula R1n(r2)2 Patents (Class 504/365)
  • Patent number: 11363819
    Abstract: A combination comprising a metal chlorate; and at least another herbicide, a composition comprising the same, a method of use thereof and a kit comprising the same.
    Type: Grant
    Filed: November 13, 2018
    Date of Patent: June 21, 2022
    Assignee: UPL LTD
    Inventors: Vicente Amadeu Gongora, Luiz Henrique Marcandalli, Carlos Eduardo Fabri, Jaidev Rajnikant Shroff, Vikram Rajnikant Shroff
  • Patent number: 10231449
    Abstract: The present invention relates to a composition comprising a water-insoluble pesticide and an alkoxylated polyalkyleneimine. The invention furthermore relates to a method of preparing this composition; to the use of this composition for dispersing agrochemical active substances; to a method of controlling phytopathogenic fungi and/or undesired plant growth and/or undesired insect or mite attack and/or for regulating the growth of plants, wherein the composition is allowed to act on the respective pests, their environment or the crop plants to be protected from the respective pest, on the soil and/or on undesired plants and/or on the crop plants and/or on their environment; and furthermore to seed comprising the composition.
    Type: Grant
    Filed: May 21, 2012
    Date of Patent: March 19, 2019
    Assignee: BASF SE
    Inventors: Gerhard Schnabel, Paul Klingelhoefer
  • Patent number: 9743668
    Abstract: The invention includes aqueous compatibilized pesticidal formulations and methods of making them. In typical embodiments, formulations comprise a first electrolytic pesticide and a second electrolytic pesticide, and about 30 to about 300 g/L of at least one alkyl polyglycoside. The invention also includes methods of preparing pesticidal formulations to increase the concentration of the electrolytic pesticides. The invention also includes storage and transport systems containing formulation embodiments. The invention also includes methods inhibiting pests.
    Type: Grant
    Filed: March 4, 2010
    Date of Patent: August 29, 2017
    Assignee: Syngenta Crop Protection, LLC
    Inventors: Julia Lynne Ramsay, David Stock, Gordon Alstair Bell, Claudio Screpanti, Colin Douglas Miln, Henry Ebun Agbaje, Charles A. Jones, III, Ravi Ramachandran
  • Patent number: 9186338
    Abstract: Disclosed herein is a novel solubility enhancer capable of being employed in formulating safe and effective pharmaceutical formulations of partially soluble drugs, wherein the solubility enhancer is selected from dialkyl substituted amides of fatty acids having C6 to C16 carbon chain, preferably from N,N-dimethyl hexanamide, N,N-dimethyl octanamide, N,N-dialkyl decanamide, N,N-dialkyl dodecanamide or N,N-dialkyl hexadecanamide.
    Type: Grant
    Filed: September 22, 2006
    Date of Patent: November 17, 2015
    Inventor: Ramachandran Radhakrishnan
  • Publication number: 20140249032
    Abstract: In agricultural practice it is known to use emulsifiable oils (commonly referred to a Crop Oil Concentrates, COC) as bioefficacy enhancers for pesticides, especially herbicides. Cationic surfactants are widely known to be particularly effective bio-active enhancers for herbicides, especially for glyphosate-type herbicides. The present invention includes two novel aspects: 1) While the vast majority of COCs are petroleum-based paraffinic oils or esterified seed oils, this invention embodies a new oil phase, a hydrocarbon oil such exemplified by EXXON-MOBIL'S D-130, which when combined with the surfactants described herein, exhibits surprising enhancement of herbicidal activity in field tests; and 2) COC's are designed to form stable emulsions in water. The combination of cationic surfactants and phosphate esters in this invention not only form very stable emulsions in water, but, surprisingly, also form extremely stable emulsions in concentrated liquid fertilizers, including 32-0-0 fertilizer.
    Type: Application
    Filed: May 15, 2014
    Publication date: September 4, 2014
    Applicant: Huntsman Petrochemical LLC
    Inventors: R. Scott Tann, Howard M. Stridde, Curtis M. Elsik
  • Publication number: 20120329655
    Abstract: Described herein are compositions comprising an acidifier intermixed with an emulsifier and a co-surfactant that form stable microemulsions in water. Also described are methods of dispersing a compound in an aqueous solution using the compositions of the present invention.
    Type: Application
    Filed: September 5, 2012
    Publication date: December 27, 2012
    Applicant: Archer Daniels Midland Company
    Inventors: Shireen Baseeth, Bruce Sebree
  • Publication number: 20120264611
    Abstract: The invention relates to pesticide preparations that contain one or more pesticides and one or more N-substituted 2-pyrrolidone-4-carboxylic acid derivatives and to the use of said pesticide preparations for controlling and/or combating weeds, fungal diseases, or insect infestation. The N-substituted 2-pyrrolidone-4-carboxylic acid derivatives act as adjuvants, emulsifiers, dispersants, and/or wetting agents in the pesticide preparations.
    Type: Application
    Filed: September 18, 2010
    Publication date: October 18, 2012
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Andreas Wacker, Joachim Hess, Robert Milbradt, Franz-Xaver Scherl
  • Patent number: 8110592
    Abstract: The present invention relates to novel water-dispersible agrochemical formulations such as, for example, water-based suspension concentrates and water-dispersible granules of agrochemically active compounds comprising a penetrant from the class of the polyalkoxytriglycerides, to a process for preparing these formulations and to their use for applying the active compounds comprised therein.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: February 7, 2012
    Assignee: Bayer Cropscience AG
    Inventors: Ronald Vermeer, Peter Baur
  • Publication number: 20110021359
    Abstract: Disclosed is an emulsifiable concentrate composition characterized by containing not less than 0.5% by weight but not more than 50% by weight of a hydrophobic agrochemically active compound, not less than 5% by weight but not more than 15% by weight of a surfactant, not less than 2% by weight but not more than 60% by weight of an aromatic hydrocarbon solvent, not less than 2% by weight but not more than 40% by weight of methyl oleate, and not less than 12% by weight but not more than 90% by weight of 1,3-dimethyl-2-imidazolidinone. The emulsion composition is also characterized in that the weight ratio of 1,3-dimethyl-2-imidazolidinone to methyl oleate is within the range from 1:0.03 to 1:2.
    Type: Application
    Filed: January 21, 2009
    Publication date: January 27, 2011
    Inventors: Yumiko Kozuki, Fumiaki Tanimoto
  • Publication number: 20100331187
    Abstract: The present invention relates to physically stable oil dispersions. It also relates to a method for activating bentones that are designed for use with a low polarity organic systems. It also relates to physically stable oil dispersions comprising said activated bentone.
    Type: Application
    Filed: June 9, 2008
    Publication date: December 30, 2010
    Applicant: SYNGENTA CROP PROTECTION, INC.
    Inventors: Kirsty Jane Williams, Johathan Mark Richards
  • Publication number: 20090286684
    Abstract: The invention relates to compositions containing the following: a) one or more fatty alcohol alkoxylates or fatty alcohol alkoxylates with closed end groups of formula (I); and b) one or more tertiary amines of formula (II). Said compositions can be advantageously used as surface-active agents.
    Type: Application
    Filed: August 5, 2006
    Publication date: November 19, 2009
    Inventors: Fraz-Xaver Scherl, Christian Sowa
  • Publication number: 20090197768
    Abstract: The present invention relates to stable, agricultural oil-in-water emulsion compositions.
    Type: Application
    Filed: February 4, 2009
    Publication date: August 6, 2009
    Applicant: Dow AgroSciences LLC
    Inventors: Raymond E. Boucher, JR., Valerie Dumontet, Frederick R. Green, III, David G. Ouse, Holger Tank
  • Patent number: 7566683
    Abstract: Ethylene derivatives of formula (I): where Q is an unsubstituted or substituted phenyl or heterocyclic group, especially a 4-thiazolyl, 1- or 3-pyrazolyl, 1,3-oxazol-4-yl, phenyl or pyridyl group; E is a substituent such as a cyano group; A is a substituent such as a 4-pyrazolyl or thiazolyl group; and B is a substituent such as an alkylcarbonyl group. Agricultural chemicals and agents for preventing the attachment of aquatic organisms containing one or more such ethylene derivatives.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: July 28, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Tomoyuki Ogura, Hiroshi Murakami, Akira Numata, Rika Miyachi, Toshiro Miyake, Norihiko Mimori, Shinji Takii
  • Patent number: 7300906
    Abstract: Sulfhydryl odors in organothiophosphate formulations are suppressed by treatment of the thiophosphate compound (e.g., bensulide) during preparation of the formulation with a selected emulsifier agent, ethoxylated tallow amine. The amine and any reacting products resulting from the treatment are retained in the final formulation. The amine will continue to react with the mercaptan and other sulfhydryl compounds formed by the continuing degradation of the thiophosphate compound, thereby providing further odor control.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: November 27, 2007
    Assignee: Gowan Company, L.L.C.
    Inventor: Frank Jaime
  • Patent number: 7271200
    Abstract: A novel emulsion comprising a material which is stabilised by a polymer resin precursor having interface active molecules incorporated therein by reaction from poorly or non-surface active materials is disclosed. The process for producing such emulsions is likewise disclosed.
    Type: Grant
    Filed: March 15, 2004
    Date of Patent: September 18, 2007
    Assignee: Syngenta Limited
    Inventors: Herbert Benson Scher, Patrick Joseph Mulqueen, Nicholas David Green, Catherine Julia Piper
  • Patent number: 7060659
    Abstract: There is provided an essentially non-aqueous homogeneous liquid herbicide composition comprising: a) a lipophilic solvent soluble complex comprising the reaction product of: i) not in excess of about 35% by weight of one or more lipophobic herbicides having an acidic moiety; and ii) not in excess of about 99% by weight of one or more tertiary dimethylamines of the structure (CH3)2N—R wherein R contains an alkyl group of at least 8 carbon atoms and may contain other chemical moieties and wherein is at least one mole equivalent of such amine to each mole of lipophobic herbicide; b) not in excess of about 60% by weight of one or more essentially non-aqueous polar solvents having low volatility; c) not in excess of about 90% by weight of one or more additional solvents selected from the group consisting of low to medium HLB surfactants; and d) not in excess of about 99% by weight of one or more lipophilic carriers.
    Type: Grant
    Filed: October 17, 2001
    Date of Patent: June 13, 2006
    Assignee: Victorian Chemicals International Pty Ltd
    Inventors: Robert William Killick, Andrew Robert Killick, Peter William Jones, Peter Ronald Wrigley, John David Morrison
  • Patent number: 6992046
    Abstract: The present invention concerns an aqueous phytopathological formulation comprising a hydrosoluble salt of at least one aminophosphate or aminophosphonate type herbicide; at least one principal surfactant selected from alkylbetaines and alkyl(amidoalkyl)betaines, and at least one additive selected from at least one of the following compounds: (i) amines or etheramines comprising at least one hydrocarbon radical containing 2 to 24 carbon atoms, optionally polyalkoxylated; (ii) acid or non acid phosphate mon- or di-esters, optionally polyalkoxylated; (iii) alkali metal, alkaline-earth metal, ammonium, alkylammonium, alkanolammonium, iron, zinc or manganese salts of a mineral acid.
    Type: Grant
    Filed: June 12, 2004
    Date of Patent: January 31, 2006
    Assignee: Rhodia Chimie
    Inventors: Valerio Bramati, Joël Coret, Scott Edwards, Paul Gioia
  • Patent number: 6946426
    Abstract: Provided is a method of formulating hydrophobic pesticides comprising emulsifying an aqueous phase and a water-immiscible phase to form a formulation; wherein the aqueous phase is comprised of water and optionally a freeze/thaw agent, one or more emulsifiers, or combinations thereof, and the water-immiscible phase comprises the hydrophobic pesticide and one or more emulsifiers.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: September 20, 2005
    Assignee: FMC Corporation
    Inventors: Timothy M. Martin, MaryEllen Lavin
  • Patent number: 6831038
    Abstract: The invention pertains to new composition and a method for increasing the solubility of various agricultural compounds in water at a low pH. The compounds included in this patent are typically not soluble at pH ranges less than 7 to produce commercially viable liquid concentrates. This method requires the use of amine-containing surfactants and organic acids to lower the pH of various compounds and also keep them soluble in water.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: December 14, 2004
    Assignee: Helena Holding Company
    Inventors: Greg Volgas, Johnnie R. Roberts, Amanda Hayes
  • Publication number: 20040224846
    Abstract: The present invention concerns an aqueous phytopathological formulation comprising a hydrosoluble salt of at least one aminophosphate or aminophosphonate type herbicide; at least one principal surfactant selected from alkylbetaines and alkyl(amidoalkyl)betaines, and at least one additive selected from at least one of the following compounds:
    Type: Application
    Filed: June 12, 2004
    Publication date: November 11, 2004
    Inventors: Valerio Bramati, Joel Coret, Scott Edwards, Paul Gioia
  • Publication number: 20040151749
    Abstract: An enhancer composition for agricultural chemicals which can enhance the effectiveness of an agricultural chemical without causing any phytotoxicity to various crops, which comprises at least one nitrogen-containing compound selected from the group consisting of tertiary amine, a tertiary amine salt and a quaternary ammonium salt and a chelating agent, wherein the content of the chelating agent ranges from 0.01 to 30 mol per mol of the nitrogen-containing compound.
    Type: Application
    Filed: December 31, 2003
    Publication date: August 5, 2004
    Applicant: Kao Corporation
    Inventors: Keiko Hasebe, Tadayuki Suzuki, Yuichi Hioki
  • Patent number: 6767863
    Abstract: The present invention provides a concentrated herbicide composition containing a glyphosate isopropylammonium salt and a polyoxyalkylene alkylamine surfactant. The concentrated herbicide composition can be formulated to exhibit decreased viscosity by reducing the amount of isopropyl amine used to prepare the glyphosate salt while maintaining the high concentration of the glyphosate salt.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: July 27, 2004
    Assignee: Dow AgroSciences LLC
    Inventor: Tank Holger
  • Publication number: 20040142823
    Abstract: The present invention provides agricultural surfactant adjuvants that enhance the bioefficacy of herbicides and other pesticides. Also provided are agriculturally-valuable compositions containing such surfactant adjuvants. One advantage to an adjuvant composition according to the invention is combined high efficacy and low toxicity, including low eye and skin irritancy and low aquatic toxicity. Sequesterant agents can also be added to condition calcium or other interfering ions or species present in spray water.
    Type: Application
    Filed: November 6, 2003
    Publication date: July 22, 2004
    Inventors: Curtis M Elsik, Howard M Stridde
  • Publication number: 20040138064
    Abstract: A method of enhancing inhibition of plant growth comprising mixing a herbicide and an adjuvant to form a herbicidal mixture and applying the herbicidal mixture to the plant, wherein the adjuvant is isopropylammonium sulfate.
    Type: Application
    Filed: November 13, 2003
    Publication date: July 15, 2004
    Inventor: R. Scott Tann
  • Publication number: 20040132622
    Abstract: There is provided an agrochemical formulation aid composition for preparing bioactive and sprayable agrochemicals, wherein various components for the composition were selected from mineral oil paraffinic distillate and/or aromatic hydrocarbon distillate; 2N-octanol; oleyl-cetyl alcohol polyoxyethylene (2) oleylether; polyoxyethylene (8) nonylphenolethin and/or ethoxylated tallow amine blend; lauryl sulphate; fatty alcohol alkoxylate; terpenes, diammonium phosphate; tetrasodium ethylene diamine tetracetate; cab-o-sil; fatty acid methyl ester; (C18) free fatty acid blend; N-butanol; and methyl alcohol. Also provided are methods of preparing the formulation aid composition on site by mixing various components and methods of preparing sprayable and bioactive agrochemical systems using the formulation aid and non-formulated or formulated agrochemicals. Also provided are uses of the formulation aid in preparing sprayable and bioactive agrochemical systems for controlling pests.
    Type: Application
    Filed: February 25, 2004
    Publication date: July 8, 2004
    Inventors: James F. Stewart, Heinrich J. Reinartz, William G. Brown
  • Patent number: 6750178
    Abstract: An aqueous agrochemical composition comprises an agrochemical active ingredient such as glyphosate, paraquat or fomesafen and an adjuvant of formula (I): X—(R3O)a—R4—NR2R1 and salts thereof, wherein R1 and R2 are independently hydrogen or a lower alkyl group or a group X—(R3O)a—R4— wherein X is —OH or a lower alkoxy group; R3O is an ethoxy, propoxy or butoxy group or a random or block mixture thereof; R4 is a linear or branched chain alkylene bridging group containing from 1 to 4 carbon atoms; X is (IA)—OH or a lower alkyloxy group; or (IB) a group R5R6N— or R5R6N—R7—; or (IC) a group (I) wherein a, is from 1 to 400 or if X is of formula IC, the sum of a, b and c is from 3 to 400 and d is 0 or 1.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: June 15, 2004
    Assignee: Syngenta Limited
    Inventors: Julia Lynne (nee Cutler) Ramsay, Antony George Seville, Michael John Bean
  • Publication number: 20040063586
    Abstract: The present invention relates to surfactant systems and in particular herbicidal compositions comprising a water soluble herbicide and/or a salt thereof and a surfactant system, wherein the surfactant system comprises at least two surfactants selected from the group consisting of: i) alkyldiamine tetraalkoxylate surfactants; ii) N-alkyl alkyldiamine trialkoxylate surfactants; and iii) phosphated alcohol alkoxylate surfactants.
    Type: Application
    Filed: September 22, 2003
    Publication date: April 1, 2004
    Inventors: Andrew Francis Kirby, Ashley Scott Martin, Paul Leslie Griffiths
  • Patent number: 6713433
    Abstract: A stable, liquid concentrate herbicidal composition is provided. The composition comprises a water-soluble herbicide in a continuous aqueous phase and an oil-soluble herbicide in a discontinuous oil phase.
    Type: Grant
    Filed: February 14, 2002
    Date of Patent: March 30, 2004
    Assignee: Monsanto Technology, LLC
    Inventor: Ganiyu A. Jimoh
  • Patent number: 6710092
    Abstract: A novel emulsion comprising a material which is stabilized by a polymer resin precursor having interface active molecules incorporated therein by reaction from poorly or non-surface active materials is disclosed. The process for producing such emulsions is likewise disclosed.
    Type: Grant
    Filed: June 5, 2001
    Date of Patent: March 23, 2004
    Assignee: Syngenta Limited
    Inventors: Herbert Benson Scher, Patrick Joseph Mulqueen, Nicholas David Green, Catherine Julia Piper
  • Patent number: 6706666
    Abstract: An enhancer composition for agricultural chemicals which can enhance the effectiveness of an agricultural chemical without causing any phytotoxicity to various crops, which comprises at least one nitrogen-containing compound selected from the group consisting of a tertiary amine, a tertiary amine salt and a quaternary ammonium salt and a chelating agent, wherein the content of the chelating agent ranges from 0.01 to 30 mol per mol of the nitrogen-containing compound.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: March 16, 2004
    Assignee: Kao Corporation
    Inventors: Keiko Hasebe, Tadayuki Suzuki, Yuichi Hioki
  • Publication number: 20040038826
    Abstract: This invention provides an agricultural chemical composition comprising an enhancer for agricultural chemicals, which is excellent in stability even when compounded at high concentration, and exerts an excellent effect-enhancing action on agricultural chemicals. A specific amine oxide having a C6-30 alkyl or alkenyl group or an alkylphenyl group having a C6-17 alkyl group, and an amide alkyl group or oxyalkylene group is used as the enhancer for agricultural chemicals.
    Type: Application
    Filed: May 30, 2003
    Publication date: February 26, 2004
    Inventors: Kazuhiko Kurita, Tadayuki Suzuki
  • Publication number: 20040014603
    Abstract: A water-based composition having increased pesticidal effect is comprised of (a) glyphosate and (b) cationically derivatized sorbitol and/or cationically derivatized cyclodextrin.
    Type: Application
    Filed: April 24, 2003
    Publication date: January 22, 2004
    Inventors: Horst-Werner Wollenweber, Andreas Rathjens, Hans-Georg Mainx
  • Patent number: 6667276
    Abstract: The invention relates to surfactant systems for liquid aqueous or aqueous-organic formulations comprising a mixture of one or more basic cosurfactants and one or more surfactants from the group of the acidic phosphoric esters. The surfactant system makes possible the preparation of stable liquid formulations for active compounds, the formulations comprising (a) one or more water-soluble active compounds (type (a)) and (b) optionally one or more water-insoluble active compounds (type (b)), (c) optionally organic solvents, (d) the abovementioned surfactant system and water. The formulations are either single-phase aqueous or aqueous-organic formulations of type-(a) active compounds, for example glufosinate-ammonium or glyphosate(salts), or they are microemulsions of type-(a) and type-(b) active compounds, for example diphenyl ether herbicides.
    Type: Grant
    Filed: November 24, 1998
    Date of Patent: December 23, 2003
    Assignee: Hoechst Schering AgrEvo GmbH
    Inventors: Thomas Maier, Jochen Würtz
  • Publication number: 20030224939
    Abstract: The invention relates to a compositions useful in the field of agricultural chemistry and methods for making and using the compositions. The compositions include (i) a permeabilizing agent, and (ii) a active component, for example, a pesticide or plant growth regulator, and can include additional components as well, for example, flow agents. The permeabilizing agent, or a mixture of permeabilizing agents, acts as an adjuvant to the active component or chemicals to improve the degree of efficacy of the active component or speed of action of the active component. The permeabilizing agents are typically one or more chelating agents, cationic materials, anionic materials, and zwitterionic materials, and include polyphosphate salts. Examples of cationic materials include polyamines such as ethylenediamine and quaternary ammonium salts. The active components can be pesticides, herbicides, insecticides, fungicides, virucides, bacteriocides, and acaricides.
    Type: Application
    Filed: May 31, 2002
    Publication date: December 4, 2003
    Inventor: David Miles
  • Patent number: 6645914
    Abstract: The present invention is directed to liquid homogenous adjuvant blends that include a liquid iminodipropionate amphoteric surfactant, ammonium sulfate and water. The liquid homogenous adjuvant blends are used in spray carrier containing herbicides for conytrol of weeds or other undesired vegetation.
    Type: Grant
    Filed: May 1, 2002
    Date of Patent: November 11, 2003
    Assignee: NDSU-Research Foundation
    Inventors: Zenon J. Woznica, John Nalewaja, Calvin Messersmith, Edward Szelezniak
  • Publication number: 20030207764
    Abstract: A storage-stable high-strength aqueous glyphosate concentrate, preferably containing greater than 400 g/l glyphosate expressed as acid, comprises the potassium salt of glyphosate, an alkylglycoside surfactant and an alkoxylated alkylamine surfactant at a preferred total concentration of alkylglycoside and alkoxylated alkylamine from about 160 to 300 g/l and at a preferred ratio of alkylglycoside to alkoxylated alkylamine of from about 1 part by weight of alkylglycoside per 1 part by weight of alkoxylated alkylamine to about 5 parts by weight of alkylglycoside per 1 part by weight of alkoxylated alkylamine
    Type: Application
    Filed: March 27, 2003
    Publication date: November 6, 2003
    Inventors: Alan Victor Ottaway, Carl Andrew Formstone, Derek John Hopkins, Michael John Bean
  • Publication number: 20030191026
    Abstract: There is provided an essentially non-aqueous homogeneous liquid herbicide composition comprising: a) a lipophilic solvent soluble complex comprising the reaction product of: i) not in excess of about 35% by weight of one or more lipophobic herbicides having an acidic moiety; and ii) not in excess of about 99% by weight of one or more tertiary dimethylamines of the structure (CH3)2N—R wherein R contains an alkyl group of at least 8 carbon atoms and may contain other chemical moieties and wherein is at least one mole equivalent of such amine to each mole of lipophobic herbicide; b) not in excess of about 60% by weight of one or more essentially non-aqueous polar solvents having low volatility; c) not in excess of about 90% by weight of one or more additional solvents selected from the group consisting of low to medium HLB surfactants; and d) not in excess of about 99% by weight of one or more lipophilic carriers.
    Type: Application
    Filed: October 8, 2002
    Publication date: October 9, 2003
    Inventors: Robert William Killick, Andrew Robert Killick, Peter William Jones, Peter Ronald Wrigley, John David Morrison
  • Publication number: 20030176286
    Abstract: The present invention relates to the use of an amino compound, which is an esteramine or an amidoamine surfactant with improved biodegradability, as an adjuvant for agrochemically active compounds such as pesticides or fertilisers. The adjuvant has Formula (1) where R1 is an aliphatic group containing 7-22 carbon atoms; EO is an ethyleneoxy group; Y is 0 or NH; R2 and R3 is independently CH2CH2OH or an alkyl group with 1-5 carbon atoms, preferably 1-3 carbon atoms; n is a number between 0-10; x is a number 0-1 provided that when Y is O, then x is 1, and when Y is NH, then x is O; and m is a number 2-6, preferably 2-3, provided that when Y is NH, then m is 3-6, preferably 3; or an adduct obtained by reacting one mole of the compound with 1-5 moles of an alkylene oxide having 2-3 carbon atoms.
    Type: Application
    Filed: March 25, 2003
    Publication date: September 18, 2003
    Inventors: Bodil Gustavsson, Burkhard Weuste
  • Publication number: 20030158042
    Abstract: The present invention concerns an aqueous phytopathological formulation comprising a hydrosoluble salt of at least one aminophosphate or aminophosphonate type herbicide; at least one principal surfactant selected from alkylbetaines and alkyl(amidoalkyl)betaines, and at least one additive selected from at least one of the following compounds:
    Type: Application
    Filed: January 29, 2002
    Publication date: August 21, 2003
    Inventors: Valerio Bramati, Joel Coret, Scott Edwards, Paul Gioia
  • Publication number: 20030153462
    Abstract: Described are suspension concentrates that include glyphosate acid, herbicide compositions prepared therefrom, and methods of making and using each.
    Type: Application
    Filed: March 21, 2002
    Publication date: August 14, 2003
    Inventors: Anthony E. Herold, Richard A. Beardmore, Scott K. Parrish
  • Publication number: 20030125209
    Abstract: The present invention provides a concentrated herbicide composition containing a glyphosate isopropylammonium salt and a polyoxyalkylene alkylamine surfactant. The concentrated herbicide composition can be formulated to exhibit decreased viscosity by reducing the amount of isopropyl amine used to prepare the glyphosate salt while maintaining the high concentration of the glyphosate salt.
    Type: Application
    Filed: December 19, 2002
    Publication date: July 3, 2003
    Inventor: Holger Tank
  • Publication number: 20030125212
    Abstract: The present invention provides an agrochemical spreader composition having excellent low-temperature stability. Specifically, the present invention provides an agrochemical spreader composition comprising a surfactant (A) having a melting point of 20 to 60° C., a surfactant (B) having a melting point of not more than 0° C. and water in a specific ratio.
    Type: Application
    Filed: October 2, 2002
    Publication date: July 3, 2003
    Inventors: Katsuhiko Yamaguchi, Kazuhiko Kurita, Masaharu Hayashi
  • Publication number: 20030096708
    Abstract: Diamines or other polyamines increase the compatibility of ether amine surfactants with pesticide formulations such as those containing glyphosate or a salt or ester thereof.
    Type: Application
    Filed: November 19, 2001
    Publication date: May 22, 2003
    Applicant: Monsanto Technology LLC
    Inventors: Henry E. Agbaje, David Z. Becher, Chris Bates, Simone Seifert-Higgins, Ronald J. Brinker
  • Publication number: 20030087764
    Abstract: Aqueous pesticidial concentrate emulsions or microemulsions are described which are storage stable after exposure to temperatures ranging from 60° C. to −20° C.
    Type: Application
    Filed: November 19, 2001
    Publication date: May 8, 2003
    Applicant: Monsanto Technology LLC
    Inventors: Norman R. Pallas, Jane L. Gillespie, Lata Singh, Xiaodong C. Xu
  • Publication number: 20030083201
    Abstract: There is provided a novel pesticidal emulsifiable concentrate composition that contains a phenoxypropionate herbicide (e.g., quizalofop-p-ethyl), a polar solvent (e.g., N-methyl-2-pyrrolidone), non-polar solvent (e.g., aromatic or aliphatic hydrocarbon) and a surfactant (e.g., polyoxyethylene castor oil ether, polyoxyethylene styryl phenyl ether), and that is improved in low-temperature stability and emulsion stability.
    Type: Application
    Filed: October 7, 2002
    Publication date: May 1, 2003
    Applicant: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventor: Mamoru Kobayashi
  • Publication number: 20030045431
    Abstract: A herbicidal solution contains from 30% by weight to saturation of a water soluble glyphosate salt and from 8 to 20% by weight of surfactant comprising from 10 to 100% by weight based on the total weight of surfactant of an amphoteric surfactant and from 0 to 90% by weight based on the total weight of surfactant of ether carobxylate, said solution containing less than 0.035 % by weight of sodium ion. A pre-blended surfactant concentrate contains from 10 to 70% by weight ether carboxylate, from 20 to 80% by weight of low salt amphoteric surfactant and from 10 to 50% by weight of solvent.
    Type: Application
    Filed: September 27, 2002
    Publication date: March 6, 2003
    Applicant: HUNTSMAN INTERNATIONAL LLC
    Inventors: Fabien Herve Joseph Mille, Philip James Oxford
  • Publication number: 20030004063
    Abstract: A stable, liquid concentrate herbicidal composition is provided. The composition comprises a water-soluble herbicide in a continuous aqueous phase and an oil-soluble herbicide in a discontinuous oil phase.
    Type: Application
    Filed: February 14, 2002
    Publication date: January 2, 2003
    Applicant: Monsanto Technology, LLC
    Inventor: Ganiyu A. Jimoh
  • Patent number: 6482866
    Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.
    Type: Grant
    Filed: July 10, 2000
    Date of Patent: November 19, 2002
    Assignee: Schlumberger Technology Corporation
    Inventors: Manilal S. Dahayanake, Jiang Yang, Joseph H. Y. Niu, Paul-Joel Derian, Ruoxin Li, David Dino
  • Publication number: 20020160918
    Abstract: Disclosed herein are surfactants useful for improving the bioefficacy of herbicides. A surfactant according to the invention may comprise: (i) phosphate monoesters of tallow amine ethoxylates, alone or in combination with phosphate diesters of tallow amine ethoxylates, or (ii) alkoxylated phosphate monoesters of tallow amine ethoxylates, alone or in combination with alkoxylated phosphate diesters of tallow amine ethoxylates. The present invention also provides for herbicide compositions that contain the surfactants of the present invention. The herbicide compositions comprise a herbicidal active ingredient, a surfactant of the present invention, and optionally, one or more formulation aids. The herbicide compositions of the present invention unexpectedly have a reduced tendency to cause eye and skin irritation. The present invention additionally provides for a method of controlling unwanted weeds or vegetation using the herbicide compositions of the present invention.
    Type: Application
    Filed: April 12, 2002
    Publication date: October 31, 2002
    Applicant: Huntsman Petrochemical Corporation
    Inventors: David C. Lewis, Howard M. Stridde
  • Publication number: 20020160916
    Abstract: The invention pertains to new composition and a method for increasing the solubility of various agricultural compounds in water at a low pH. The compounds included in this patent are typically not soluble at pH ranges less than 7 to produce commercially viable liquid concentrates. This method requires the use of amine-containing surfactants and organic acids to lower the pH of various compounds and also keep them soluble in water.
    Type: Application
    Filed: February 20, 2002
    Publication date: October 31, 2002
    Inventors: Greg Volgas, Johnnie R. Roberts, Amanda Hayes