Substrate For Supporting Superconductor Patents (Class 505/239)
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Patent number: 11840045Abstract: This invention provides a relatively thick roll-bonded laminate that exhibits a high Erichsen value and excellent molding workability. Such roll-bonded laminate is composed of a stainless steel layer and a non-stainless steel metal layer, and it is characterized in that thickness T is 0.2 mm to 3 mm and a correlation between a proportion PSUS of thickness TSUS of the stainless steel layer relative to thickness T and a half width FWHM200 of a peak exhibiting a crystal plane orientation (200) determined by X-ray diffraction analysis of the stainless steel layer side satisfies the correlation represented by the formula: FWHM200?0.0057PSUS+0.4.Type: GrantFiled: March 29, 2018Date of Patent: December 12, 2023Assignee: Toyo Kohan Co., Ltd.Inventors: Yusuke Hashimoto, Kota Sadaki, Teppei Kurokawa, Takashi Koshiro, Takafumi Hatakeda
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Patent number: 11524486Abstract: It is an object to provide a method for producing a substrate for epitaxial growth having a higher degree of biaxial crystal orientation without forming an irregular part a3. The method for producing a substrate for epitaxial growth comprising a step of laminating a metal base material and a copper layer having an fcc rolling texture by surface-activated bonding, a step of applying mechanical polishing to the copper layer, and a step of carrying out orientation heat treatment of the copper layer, wherein the copper layer is laminated in such a way that, when ratios of the (200) plane of the copper layer before laminated and of the copper layer after laminated when measured by XRD are I0Cu and I0CLAD, respectively and ratios of the (220) plane of the copper layer before laminated and of the copper layer after laminated are I2Cu and I2CLAD, respectively, I0Cu<20%, I2Cu=70 to 90%, and I0CLAD<20%, I2CLAD=70 to 90% and I0CLAD?I0Cu<13%.Type: GrantFiled: October 21, 2016Date of Patent: December 13, 2022Assignees: TOYO KOHAN CO., LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD.Inventors: Teppei Kurokawa, Yusuke Hashimoto, Hironao Okayama
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Patent number: 8993064Abstract: Provided are a substrate for a superconducting compound and a method for manufacturing the substrate which can realize the excellent adhesive strength simultaneously with high orientation of copper. An absorbed material on a surface of a copper foil to which rolling is applied at a draft of 90% or more is removed by applying sputter etching to the surface of the copper foil, sputter etching is applied to a nonmagnetic metal sheet, the copper foil and the metal sheet are bonded to each other by applying a pressure to the copper foil and the metal sheet using reduction rolls, crystals of the copper in the copper foil are oriented by heating a laminated body formed by such bonding, copper is diffused into the metal sheet by heating with a copper diffusion distance of 10 nm or more, and a protective layer is laminated to a surface of the copper foil of the laminated body.Type: GrantFiled: November 12, 2010Date of Patent: March 31, 2015Assignees: Toyo Kohan Co., Ltd., Sumitomo Electric Industries, Ltd.Inventors: Hironao Okayama, Kouji Nanbu, Akira Kaneko, Hajime Ota, Kotaro Ohki, Takashi Yamaguchi, Kazuhiko Hayashi, Kazuya Ohmatsu
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Publication number: 20150087524Abstract: There is provided a method for producing a substrate (600) suitable for supporting an elongated superconducting element, wherein, e.g., a deformation process is utilized in order to form disruptive strips in a layered solid element, and where etching is used to form undercut volumes (330, 332) between an upper layer (316) and a lower layer (303) of the layered solid element. Such relatively simple steps enable providing a substrate which may be turned into a superconducting structure, such as a superconducting tape, having reduced AC losses, since the undercut volumes (330, 332) may be useful for separating layers of material. In a further embodiment, there is placed a superconducting layer on top of the upper layer (316) and/or lower layer (303), so as to provide a superconducting structure with reduced AC losses.Type: ApplicationFiled: May 17, 2013Publication date: March 26, 2015Inventor: Anders Christian Wulff
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Patent number: 8980797Abstract: A method for manufacturing a base material 2 for a superconductive conductor which includes: a conductive bed layer forming process of forming a non-oriented bed layer 24 having conductivity on a substrate 10; and a biaxially oriented layer forming process of forming a biaxially oriented layer 26 on the bed layer 24.Type: GrantFiled: August 24, 2012Date of Patent: March 17, 2015Assignee: Furukawa Electric Co., Ltd.Inventors: Yoshikazu Okuno, Hiroyuki Fukushima, Yuko Hayase, Eiji Kojima
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Patent number: 8921276Abstract: The phase transition temperature, at which the crystal lattice of LMO that constitutes an oxide layer as an intermediate layer or as a part of an intermediate layer becomes cubic, is lowered. A substrate for a superconducting wire rod includes an oxide layer (LMO layer (22)) which contains, as a principal material, a crystalline material represented by the compositional formula: Laz(Mn1?xMx)wO3+? (wherein M represents at least one of Cr, Al, Co or Ti, ? represents an oxygen non-stoichiometric amount, 0<w/z<2, and 0<x?1).Type: GrantFiled: November 2, 2011Date of Patent: December 30, 2014Assignee: Furukawa Electric Co., Ltd.Inventors: Masayasu Kasahara, Hiroyuki Fukushima, Yoshikazu Okuno, Yuko Hayase
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Patent number: 8912126Abstract: A substrate of the present invention includes a copper layer, an alloy layer containing copper and nickel, formed on the copper layer, a nickel layer formed on the alloy layer, and an intermediate layer formed on the nickel layer. The concentration of nickel in the alloy layer at the interface between the alloy layer and the nickel layer is greater than the concentration of nickel in the alloy layer at the interface between the alloy layer and the copper layer. According to the present invention, there can be provided a substrate that allows the AC loss of a superconducting wire to be reduced, a method of producing a substrate, a superconducting wire, and a method of producing a superconducting wire.Type: GrantFiled: July 7, 2010Date of Patent: December 16, 2014Assignees: Sumitomo Electric Industries, Ltd., Toyo Kohan Co., Ltd.Inventors: Takashi Yamaguchi, Masaya Konishi, Hajime Ota
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Patent number: 8745849Abstract: A method is disclosed for making a template for a superconducting coil on a former (25) from a sheet (23) of flexible biaxially-textured material having at least two joining edges, the surface texture of the sheet being defined by a plurality of grains, and the former having a substantially curved surface. The method comprises the steps of shaping the sheet so that each joining edge lies adjacent to another joining edge on application of the sheet to the former, each joining edge and its adjacent edge being a pair of edges, and so that the sheet is dimensioned to cover a part of the surface of the former and substantially to fit that part of the former; positioning the sheet on the former so that regions of the sheet either side of the pair of edges have substantially aligned grains; and forming a join between the pair of edges, the template thereby having a substantially continuous textured surface across the join.Type: GrantFiled: November 23, 2006Date of Patent: June 10, 2014Assignee: Coated Conductor Cylinders Ltd.Inventor: Eamonn Francis Maher
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Patent number: 8633137Abstract: Disclosed herein is a high-temperature superconducting tape, including: a substrate; a buffer layer formed on the substrate; and a high-temperature superconducting layer formed on the buffer layer, wherein the substrate is made of SUS310s or stainless steel containing 0.01-1% of silicon (Si) and 1-5% of molybdenum (Mo) and has an average metal crystal grain size of 12 ?m or less, and the high-temperature superconducting layer is made of a ReBCO (ReBa2Cu3O7, Re=Nd, Sm, Eu, Gd, Dy, Ho, Y)-based superconductive material. The high-temperature superconducting tape is advantageous with the result that a high-grade superconducting layer can be deposited on the thin buffer layer and thus the critical current density of the high-temperature superconducting tape can be improved, thereby remarkably improving the characteristics of the high-temperature superconducting tape.Type: GrantFiled: September 7, 2011Date of Patent: January 21, 2014Assignee: Korea Electrotechnology Research InstituteInventors: Hong Soo Ha, Sang Soo Oh, Ho Sup Kim
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Patent number: 8513163Abstract: A high-temperature superconducting thin-film strip conductor (HTSL-CC) includes a metal substrate, a buffer layer chemically generated thereon and grown crystallographically unrotated in relation to the metal substrate, and a chemically generated superconducting coating thereon. The HTSL-CC possesses high texturing of the buffer layer since the metal substrate has a surface roughness RMS<50 nm, and since and the buffer layer is grown directly onto its surface, without an intermediate layer, crystallographically unrotated in relation to the crystalline structure of the metal substrate.Type: GrantFiled: May 23, 2008Date of Patent: August 20, 2013Assignee: BASF SEInventors: Michael Baecker, Theodor Schneller, Sandip Halder
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Publication number: 20130190188Abstract: A method for manufacturing a base material 2 for a superconductive conductor which includes: a conductive bed layer forming process of forming a non-oriented bed layer 24 having conductivity on a substrate 10; and a biaxially oriented layer forming process of forming a biaxially oriented layer 26 on the bed layer 24.Type: ApplicationFiled: August 24, 2012Publication date: July 25, 2013Applicant: FURUKAWA ELECTRIC CO., LTD.Inventors: Yoshikazu Okuno, Hiroyuki Fukushima, Yuko Hayase, Eiji Kojima
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Publication number: 20130137580Abstract: An effect of suppressing diffusion of metal elements from a substrate is high and orientation of a forcibly-oriented layer is improved. A base material (2) for a superconducting thin film includes: a substrate (10) including a metal element; a bed layer (22) formed on a surface of the substrate (10), the bed layer (22) including, as a main component, a non-orientated spinel compound that has a spinel type crystal structure and includes at least one transition metal element, Mg, and oxygen; and a forcibly-oriented layer (24) formed on a surface of the bed layer (22), the forcibly-oriented layer (24) having biaxial orientation and including, as a main component, a rock salt type compound that has a rock salt type crystal structure and includes Mg.Type: ApplicationFiled: July 25, 2012Publication date: May 30, 2013Applicant: FURUKAWA ELECTRIC CO., LTD.Inventors: Yuko Hayase, Hiroyuki Fukushima, Yoshikazu Okuno, Eiji Kojima, Hisaki Sakamoto
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Publication number: 20130137581Abstract: A superconducting thin film having excellent critical current characteristics is provided. A substrate for a superconducting thin film includes a substrate body (10A) having a main surface (10B) in which the root mean square slope R?q of a roughness curve is 0.4 or less.Type: ApplicationFiled: July 2, 2012Publication date: May 30, 2013Applicant: FURUKAWA ELECTRIC CO., LTD.Inventors: Masaru Higuchi, Hisaki Sakamoto, Yoshinori Nagasu
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Publication number: 20130130915Abstract: The phase transition temperature, at which the crystal lattice of LMO that constitutes an oxide layer as an intermediate layer or as a part of an intermediate layer becomes cubic, is lowered. A substrate for a superconducting wire rod includes an oxide layer (LMO layer (22)) which contains, as a principal material, a crystalline material represented by the compositional formula: Laz(Mn1?xMx)wO3+? (wherein M represents at least one of Cr, Al, Co or Ti, ? represents an oxygen non-stoichiometric amount, 0<w/z<2, and 0<x?1).Type: ApplicationFiled: November 2, 2011Publication date: May 23, 2013Applicant: FURUKAWA ELECTRIC CO., LTD.Inventors: Masayasu Kasahara, Hiroyuki Fukushima, Yoshikazu Okuno, Yuko Hayase
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Publication number: 20130040821Abstract: Provided are a substrate for a superconducting compound and a method for manufacturing the substrate which can realize the excellent adhesive strength simultaneously with high orientation of copper. An absorbed material on a surface of a copper foil to which rolling is applied at a draft of 90% or more is removed by applying sputter etching to the surface of the copper foil, sputter etching is applied to a nonmagnetic metal sheet, the copper foil and the metal sheet are bonded to each other by applying a pressure to the copper foil and the metal sheet using reduction rolls, crystals of the copper in the copper foil are oriented by heating a laminated body formed by such bonding, copper is diffused into the metal sheet by heating with a copper diffusion distance of lOnm or more, and a protective layer is laminated to a surface of the copper foil of the laminated body.Type: ApplicationFiled: November 12, 2010Publication date: February 14, 2013Applicants: SUMITOMO ELECTRIC INDUSTRIES, LTD., TOYO KOHAN CO., LTD.Inventors: Hironao Okayama, Kouji Nanbu, Akira Kaneko, Hajime Ota, Kotaro Ohki, Takashi Yamaguchi, Kazuhiko Hayashi, Kazuya Ohmatsu
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Publication number: 20120238454Abstract: A substrate for an oxide superconductor including: a metal base; an interlayer of MgO formed on the metal base by ion beam assisted deposition method (IBAD METHOD); and a cap layer that is formed directly on the interlayer and has a higher degree of crystal orientation than that of the interlayer, in which the interlayer of MgO is subjected to a humidity treatment prior to formation of the cap layer.Type: ApplicationFiled: April 25, 2012Publication date: September 20, 2012Applicants: INTERNATIONAL SUPERCONDUCTIVITY TECHNOLOGY CENTER, FURUKAWA ELECTRIC CO., LTD., FUJIKURA LTD.Inventors: Masateru YOSHIZUMI, Hiroyuki FUKUSHIMA, Hideyuki HATAKEYAMA, Yutaka YAMADA, Hiroshi TOBITA, Teruo IZUMI
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Publication number: 20120208703Abstract: A metal laminated substrate for an oxide superconducting wire is produced by removing, in a state where a copper foil to which rolling is applied at a draft of 90% or more is held at a temperature below a recrystallization temperature, an absorbed material on a surface of the copper foil by applying sputter etching to the surface of the copper foil; removing an absorbed material on a surface of a nonmagnetic metal sheet by applying sputter etching to the surface of the nonmagnetic metal sheet; bonding the copper foil and the metal sheet to each other by reduction rolls at an applied pressure of 300 MPa to 1500 MPa; orienting crystals of the copper by heating a laminated body obtained by bonding at a crystal orientation temperature of copper or above; and forming a protective layer on a copper-side surface of the laminated body by coating.Type: ApplicationFiled: July 8, 2010Publication date: August 16, 2012Applicants: Sumitomo Electric Industries, Ltd., Toyo Kohan Co., Ltd.Inventors: Hironao Okayama, Teppei Kurokawa, Kouji Nanbu, Yoshihiko Isobe, Takashi Koshiro, Akira Kaneko, Hajime Ota, Kotaro Ohki, Takashi Yamaguchi, Kazuya Ohmastu
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Publication number: 20120165199Abstract: A tape-shaped base for a superconducting wire, which simplifies the intermediate layer and thus enables production of a superconducting wire at lower cost, and which is capable of improving the characteristics (such as electrical conduction and handling properties) of a superconducting wire; and a superconducting wire. Specifically disclosed is a tape-shaped base for a superconducting wire, which is obtained by forming an intermediate layer on a metal substrate. In the tape-shaped base for a superconducting wire a biaxially oriented layer of the intermediate layer is configured of a niobium monoxide (NbO) layer that is formed by depositing vapor deposition particles from a vapor deposition source on a film formation surface.Type: ApplicationFiled: September 6, 2010Publication date: June 28, 2012Applicant: Furukawa Electric Co., Ltd.Inventor: Hiroyuki Fukushima
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Patent number: 8148301Abstract: An oxide superconductor member is composed of a tape-shaped substrate, an intermediate layer formed on this substrate and an oxide superconductor thin film layer formed on this intermediate layer. A surface of the tape-shaped substrate is polished by continuously running the tape-shaped substrate. The polishing step includes initial polishing process and finishing process which are carried out such that the average surface roughness Ra of the substrate becomes 2 nanometers or less and the in-plane directionality of the intermediate layer becomes 5° or less after the polishing step.Type: GrantFiled: August 24, 2007Date of Patent: April 3, 2012Assignee: NIHON Micro Coating Co., Ltd.Inventors: Sanaki Horimoto, Takuya Nagamine, Takehiro Watanabe, Fumi Murokawa, Yuji Horie, Noriyuki Kumasaka, Masahiro Hosoi
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Patent number: 8143194Abstract: An oxide superconductor member is composed of a tape-shaped substrate, an intermediate layer formed on this substrate and an oxide superconductor thin film layer formed on this intermediate layer. A surface of the tape-shaped substrate is polished by continuously running the tape-shaped substrate. The polishing step includes initial polishing process and finishing process which are carried out such that the average surface roughness Ra of the substrate becomes 2 nanometers or less and the in-plane directionality of the intermediate layer becomes 5° or less after the polishing step.Type: GrantFiled: August 1, 2007Date of Patent: March 27, 2012Assignee: NIHON Micro Coating Co., Ltd.Inventors: Sanaki Horimoto, Takuya Nagamine, Takehiro Watanabe, Fumi Murokawa, Yuji Horie, Noriyuki Kumasaka, Masahiro Hosoi
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Patent number: 8114526Abstract: A composite substrate for superconductors and methods for making the same are described. The composite substrate of the present invention includes at least a core layer having and a sheath layer having a cube texture on at least a portion its surface. In certain embodiments, the core layer can include a nickel-tungsten-molybdenum alloy having about 2-10 atomic percent tungsten and 2-15 atomic percent molybdenum. In some embodiments, the sheath layer can include nickel or a nickel-tungsten alloy having about 0 to 6 atomic percent tungsten. Generally, the core layer is stronger than the sheath layer and an interdiffusion zone can exist between the core layer and the sheath layer.Type: GrantFiled: April 2, 2008Date of Patent: February 14, 2012Assignee: American Superconductor CorporationInventors: Cornelis Leo Hans Thieme, Elliott D. Thompson
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Publication number: 20120021917Abstract: Disclosed is a low-cost metal substrate which is resistant to high-temperature oxidation, has excellent strength, is non-magnetic and is ideal for a high-temperature superconducting wire to be used at or lower than liquid nitrogen temperature. Austenitic stainless steel containing 0.4 weight or more of nitrogen is used as the metal substrate for the superconducting wire. After heat treatment of 700 to 950° C. in the high-temperature superconducting layer formation step is carried out, the metal substrate has an extremely high 0.20 proof stress at liquid nitrogen temperature.Type: ApplicationFiled: September 28, 2010Publication date: January 26, 2012Applicant: FURUKAWA ELECTRIC CO., LTD.Inventors: Hisaki Sakamoto, Yoshinori Nagasu
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Publication number: 20110287943Abstract: A base for a superconducting wire, the base includes: a metal substrate; a bed layer constituted of nesosilicate and formed on the metal substrate; and an oriented layer formed on the bed layer.Type: ApplicationFiled: May 18, 2011Publication date: November 24, 2011Applicant: FURUKAWA ELECTRIC CO., LTD.Inventor: Hiroyuki FUKUSHIMA
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Publication number: 20110263433Abstract: A high-temperature superconductor layer arrangement includes at least one substrate and one textured buffer layer made of oxidic material. The buffer layer displays at least one further constituent forming a homogeneous mixed-crystal layer. The further constituent is a transition metal from the first subgroup and/or forming at least a partial melt with the oxidic buffer material at an annealing temperature of ?1,600 degrees Celsius. The further constituent can particularly be copper and/or silver.Type: ApplicationFiled: March 14, 2009Publication date: October 27, 2011Applicant: ZENERGY POWER GMBHInventors: Michael Baecker, Oliver Brunkahl, Martina Falter
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Patent number: 8030247Abstract: Disclosed herein is a precursor solution for forming a biaxially oriented buffer layer through low-temperature heat treatment, by which a highly oriented buffer layer can be formed even when the precursor solution is heat-treated at a low temperature of 1000° C. or lower at the time of forming a buffer layer through a wet chemical method. The precursor solution is prepared by adding a carboxylate or an alkoxide of bismuth, boron, lead, gallium, or the like, which is a metal salt for forming an oxide having a low melting point of 1200° C. or lower after pyrolysis in an oxygen atmosphere, to a precursor solution for forming a buffer layer through a wet chemical method.Type: GrantFiled: January 12, 2007Date of Patent: October 4, 2011Assignee: Korea Institute of Machinery & MaterialsInventors: Jai-Moo Yoo, Young-Kuk Kim, Jae-Woong Ko, Kook-Chae Chung
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Publication number: 20110177952Abstract: A method is disclosed for making a template for a superconducting coil on a former (25) from a sheet (23) of flexible biaxially-textured material having at least two joining edges, the surface texture of the sheet being defined by a plurality of grains, and the former having a substantially curved surface. The method comprises the steps of shaping the sheet so that each joining edge lies adjacent to another joining edge on application of the sheet to the former, each joining edge and its adjacent edge being a pair of edges, and so that the sheet is dimensioned to cover a part of the surface of the former and substantially to fit that part of the former; positioning the sheet on the former so that regions of the sheet either side of the pair of edges have substantially aligned grains; and forming a join between the pair of edges, the template thereby having a substantially continuous textured surface across the join.Type: ApplicationFiled: November 23, 2006Publication date: July 21, 2011Applicant: COATED CONDUCTOR CYLINDERS LTDInventor: Eamonn Maher
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Patent number: 7902119Abstract: Porous ceramic superconductors having a film thickness over 0.5 microns are provided. The superconducting material is applied to a vicinal substrate and optionally nanoparticles are inserted to release local strain. The resultant superconductors exhibit improved Jc values compared to nonvicinal (flat) counterparts and those having no nanoparticles.Type: GrantFiled: July 21, 2006Date of Patent: March 8, 2011Inventors: Judy Wu, Rose Emergo, Timothy Haugan, Paul Barnes
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Patent number: 7879763Abstract: A superconducting article is provided that includes a substrate, wherein the substrate is untextured and comprises a nickel-based alloy containing primarily nickel and not less than about 20 wt % of an alloying element, and wherein the substrate is essentially free of Mo and Mn. The superconducting article further includes a buffer layer overlying the substrate and a high-temperature superconducting (HTS) layer overlying the buffer layer.Type: GrantFiled: November 10, 2006Date of Patent: February 1, 2011Assignee: Superpower, Inc.Inventors: Venkat Selvamanickam, Yunfei Qiao
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Patent number: 7811972Abstract: A target surface of a tape-shaped substrate of an oxide superconductor with an intermediate layer formed on this target surface and an oxide superconductor thin film is polished by causing the tape-shaped substrate to continuously run. The polishing step includes an initial polishing process for carrying out random polishing of the target surface and a finishing process that is carried out after the initial polishing process for forming grooves on the target surface along the running direction of the substrate. The intermediate layer has an in-plane directionality of 7° or less. The tape-shaped substrate is fabricated by rolling nickel, a nickel alloys or stainless steel.Type: GrantFiled: August 19, 2008Date of Patent: October 12, 2010Assignee: NIHON Micro Coating Co., Ltd.Inventors: Yuji Horie, Noriyuki Kumasaka, Sanaki Horimoto
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Patent number: 7805173Abstract: A tape manufacturing system and a tape-surface-inspection unit are disclosed. The tape-surface-inspection unit is capable of continuously characterizing the surface of a non-transparent tape that is usable with or without a tape manufacturing system. The tape-surface-inspection unit includes a surface illuminator, an imager, an image processor, a tape guide, and, optionally, an indexer. The surface illuminator provides a tape surface located by the tape guide in a manner that allows the imager to capture images for characterization by the image processor. The indexer facilitates a correlation of locations along the tape and a characterization of the locations on the tape. The tape manufacturing system, in addition to at least one tape-surface-inspection unit, includes a tape-processing unit, a tape handler, and a controller.Type: GrantFiled: November 15, 2006Date of Patent: September 28, 2010Assignee: Superpower, Inc.Inventors: Jodi L. Reeves, Yunfei Qiao
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Patent number: 7718573Abstract: A method for producing an oxide superconductor by partially melting and solidifying the precursor of the oxide superconductor is a method wherein the precursor is placed on a substrate material containing pure metal or a compound which is meltable in the precursor when the precursor is in a partially molten state, and partially melting and solidifying the precursor in said state.Type: GrantFiled: January 22, 2004Date of Patent: May 18, 2010Assignee: Origin Electric Company, LtdInventors: Motohide Matsui, Masato Murakami
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Publication number: 20100016169Abstract: An oxide superconductor member is composed of a tape-shaped substrate, an intermediate layer formed on this substrate and an oxide superconductor thin film layer formed on this intermediate layer. A surface of the tape-shaped substrate is polished by continuously running the tape-shaped substrate. The polishing step includes initial polishing process and finishing process which are carried out such that the average surface roughness Ra of the substrate becomes 2 nanometers or less and the in-plane directionality of the intermediate layer becomes 5° or less after the polishing step.Type: ApplicationFiled: August 1, 2007Publication date: January 21, 2010Applicant: NIHON MICRO COATING CO., LTD.Inventors: Sanaki Horimoto, Takuya Nagamine, Takehiro Watanabe, Fumi Murokawa, Yuji Horie, Noriyuki Kumasaka, Masahiro Hosoi
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Publication number: 20090298698Abstract: A high-temperature superconductor layer arrangement includes at least one substrate and a textured buffer layer made of oxidic material that permits textured growth of a high-temperature superconductor. Surprisingly, a layer of the buffer material made of a rare-earth element cerium oxide containing lanthanum as the rare-earth element may be used to produce a homogeneous buffer layer in just one coating operation, where appropriate. The buffer layer material may be a rare-earth oxide of the general formula: Ln?2?xLn?xCe?2?yM?yO7±z, wherein 0?x, y, z?1, in which Ln? and Ln? each represents a rare-earth element, independently of each other, and M? represents a trivalent or tetravalent or pentavalent metal.Type: ApplicationFiled: March 27, 2009Publication date: December 3, 2009Applicant: ZENERGY POWER GMBHInventors: Michael BACKER, Oliver BRUNKAHL
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Patent number: 7507691Abstract: A Bi-based oxide superconductor thin film whose c-axis is oriented parallel to the substrate and whose a-axis (or b-axis) is oriented perpendicular to the substrate, is manufactured in order to obtain a high performance layered Josephson junction using a Bi-based oxide superconductor. The method of manufacturing an a-axis oriented Bi-based oxide superconductor thin film, involves an epitaxial growth process using an LaSrAlO4 single crystal substrate of a (110) plane or a LaSrGaO4 single crystal substrate of a (110) plane, for which the lattice constant matches well with a (100) plane of a Bi-2223 oxide superconductor. By this method, rather than the normally easily obtained Bi-2212, an a-axis oriented film of Bi-2223 showing an extremely high superconductive transition temperature even for a Bi-based oxide superconductor can be selectively manufactured.Type: GrantFiled: September 16, 2005Date of Patent: March 24, 2009Assignee: National Institute of Advanced Industrial Science and TechnologyInventor: Kazuhiro Endo
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Publication number: 20080146452Abstract: Disclosed herein are a (113) [121] textured Ag sheet and an HTS Tl-1223 phase coated conductor featuring a high critical current density. The Ag sheet is allowed to have an intensified (113) [121] texture by applying an additional tensile force to an Ag sheet which has undergone primary recrystallization. The HTS Tl-1223 phase coated conductor is fabricated by depositing/layering a biaxially textured Tl-1223 phase HTS film on the Ag substrate. The application of a slight tensile force suppresses the occurrence of secondary recrystallization in the Ag sheet, resulting in the intensification of (113) [121] texture components in the Ag sheet.Type: ApplicationFiled: October 26, 2006Publication date: June 19, 2008Inventors: Dae Yeong Jeong, Su Young Kim, Shigeo Horiuchi
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Patent number: 7312182Abstract: Rare earth metal containing compounds of the formula Sr2LuSbO6 and Sr2LaSbO6 have been prepared as high critical temperature thin film superconductor structures, and can be used in other ferroelectrics, pyroelectrics, piezoelectrics, and hybrid device structures.Type: GrantFiled: March 11, 2004Date of Patent: December 25, 2007Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Arthur Tauber, Robert D. Finnegan, William D. Wilber, Steven C. Tidrow, Donald W. Eckart, William C. Drach
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Patent number: 7258927Abstract: Articles are provided including a base substrate having a layer of an oriented material thereon, and, a layer of hafnium oxide upon the layer of an oriented material. The layer of hafnium oxide can further include a secondary oxide such as cerium oxide, yttrium oxide, lanthanum oxide, scandium oxide, calcium oxide and magnesium oxide. Such articles can further include thin films of high temperature superconductive oxides such as YBCO upon the layer of hafnium oxide or layer of hafnium oxide and secondary oxide.Type: GrantFiled: December 23, 2004Date of Patent: August 21, 2007Assignee: Los Alamos National Security, LLCInventors: Stephen R. Foltyn, Quanxi Jia, Paul N. Arendt
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Patent number: 7226893Abstract: A superconductive article is disclosed, having a substrate a buffer layer overlying the substrate, and a superconductive layer overlying the buffer layer. According to embodiments, the article may have low density characteristics, associated with the article as a whole and/or individual layers of the article. The article may be embodied in the form of long length conductors, coiled long length conductors, and machines incorporating such coils, for example.Type: GrantFiled: February 23, 2005Date of Patent: June 5, 2007Assignee: Superpower, Inc.Inventors: Venkat Selvamanickam, Drew W. Hazelton, Yunfei Qiao
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Patent number: 6921741Abstract: A composite substrate structure including a substrate, a layer of a crystalline metal oxide or crystalline metal oxynitride material upon the substrate, a layer of an oriented cubic oxide material having a rock-salt-like structure upon the crystalline metal oxide or crystalline metal oxynitride material layer is provided together with additional layers such as one or more layers of a buffer material upon the oriented cubic oxide material layer. Jc?s of 2.Type: GrantFiled: February 7, 2003Date of Patent: July 26, 2005Assignee: The Regents of the University of CaliforniaInventors: Paul N. Arendt, Stephen R. Foltyn, James R. Groves, Quanxi Jia
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Patent number: 6911664Abstract: The present invention generally involves an extra-substrate control system comprising a first substrate, attached to which is at least one superconducting structure, and a second substrate, connected to which is at least one element of circuitry, wherein the superconducting structure and the circuitry interact, so that a change in a state of the superconducting structure can be detected by the circuitry. The present invention also provides a quantum computing apparatus comprising a first substrate, attached to which is one or more layers of material, at least one of which is a superconducting material, a second substrate, deposited on which is a flux shield and on the flux shield is at least one element of circuitry, wherein the superconducting material and the second substrate are separated by a mean distance that is small enough to permit coupling between the element of circuitry and the superconducting material.Type: GrantFiled: April 26, 2002Date of Patent: June 28, 2005Assignee: D-Wave Systems, Inc.Inventors: Evgeni Il'ichev, Miles F. H. Steininger
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Patent number: 6764770Abstract: Materials for depositing buffer layers on biaxially textured and untextured metallic and metal oxide substrates for use in the manufacture of superconducting and other electronic articles comprise RMnO3, R1−xAxMnO3, and combinations thereof; wherein R includes an element selected from the group consisting of La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Y, and A includes an element selected from the group consisting of Be, Mg, Ca, Sr, Ba, and Ra.Type: GrantFiled: December 19, 2002Date of Patent: July 20, 2004Assignee: UT-Battelle, LLCInventors: Mariappan P. Paranthaman, Tolga Aytug, David K. Christen, Roeland Feenstra, Amit Goyal
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Patent number: 6730410Abstract: Methods and articles for controlling the surface of an alloy substrate for deposition of an epitaxial layer. The invention includes the use of an intermediate layer to stabilize the substrate surface against oxidation for subsequent deposition of an epitaxial layer.Type: GrantFiled: July 14, 2000Date of Patent: May 4, 2004Assignees: Electronic Power Research Institute, Incorporated, The Regents of the University of CaliforniaInventors: Leslie G. Fritzemeier, Qi Li, Martin W. Rupich, Elliott D. Thompson, Edward J. Siegal, Cornelis Leo Hans Thieme, Suresh Annavarapu, Paul N. Arendt, Stephen R. Foltyn
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Patent number: 6610632Abstract: The present invention provides a tape-form oxide superconductor having a high degree of c-axis alignment and in-plane alignment and an improved Jc value. On a tape-form metal substrate which is non-magnetic or weakly magnetic and has high strength, there are sequentially formed a first intermediate layer wherein YSZ or Zr2Rx2O7 particles are deposited from a target with ion irradiation from a direction inclined to the metal substrate, a second intermediate layer of CeO2 or Y2O3 is formed and an RE1+XBa2−XCu3OY superconducting layer is formed by coating metalorganic salts containing F, followed by thermal decomposition.Type: GrantFiled: October 12, 2001Date of Patent: August 26, 2003Assignees: International Superconductivity Technology Center, The Juridicial Foundation, Showa Electric Wire & Cable Co., Ltd., Fujikura Ltd., Railway Technical Research Institute, Kabushiki Kaisha ToshibaInventors: Tetsuji Honjo, Hiroshi Fuji, Yuichi Nakamura, Teruo Izumi, Takeshi Araki, Yutaka Yamada, Izumi Hirabayashi, Yuh Shiohara, Yasuhiro Iijima, Kaoru Takeda
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Patent number: 6610633Abstract: A lanthanum aluminate (LaAlO3) substrate on which thin films of layered perovskite copper oxide superconductors are formed. Lanthanum aluminate, with a pseudo-cubic perovskite crystal structure, has a crystal structure and lattice constant that closely match the crystal structures and lattice constants of the layered perovskite superconductors. Therefore, it promotes epitaxial film growth of the superconductors, with the crystals being oriented in the proper direction for good superconductive electrical properties, such as a high critical current density. In addition, LaAlO3 has good high frequency properties, such as a low loss tangent and low dielectric constant at superconductive temperatures. Finally, lanthanum aluminate does not significantly interact with the superconductors. Lanthanum aluminate can also be used to form thin insulating films between the superconductor layers, which allows for the fabrication of a wide variety of superconductor circuit elements.Type: GrantFiled: May 4, 1995Date of Patent: August 26, 2003Assignee: TRW Inc.Inventors: Randy Wayne Simon, Christine Elizabeth Platt, Alfred Euinam Lee, Gregory Steven Lee
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Patent number: 6531426Abstract: A new process for making a neodymium gallate (NGO) surface layer on the inside surface of a protective outer sheath of nickel surrounding a core of yttrium-based copper oxide (YBCO) superconductor material permits manufacture of very high performance superconducting wire and tape. The NGO surface layer acts as a diffusion barrier to prevent diffusion of nickel into the YBCO during high temperature melt-processing. The NGO is applied, preferably by slurry casting, to a flat strip of solid nickel and then sintered at temperatures above about 1000° C. The sintering binds the NGO to the nickel strip and fixes it so that it will not react chemically with the YBCO during later melt-processing. The nickel strip and NGO diffusion barrier layer are next rolled into a trough and YBCO ceramic powder inserted inside the trough. The trough is then further rolled into a tube leaving an open seam for oxygen to penetrate during the oxygen anneal procedure of melt-processing.Type: GrantFiled: August 28, 1997Date of Patent: March 11, 2003Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Gregory Kozlowski, Charles E. Oberly
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Publication number: 20030036483Abstract: An article including a substrate, a layer of an inert oxide material upon the surface of the substrate, (generally the inert oxide material layer has a smooth surface, i.e., a RMS roughness of less than about 2 nm), a layer of an amorphous oxide or oxynitride material upon the inert oxide material layer, a layer of an oriented cubic oxide material having a rock-salt-like structure upon the amorphous oxide material layer is provided together with additional layers such as at least one layer of a buffer material upon the oriented cubic oxide material layer or a HTS top-layer of YBCO directly upon the oriented cubic oxide material layer. With a HTS top-layer of YBCO upon at least one layer of a buffer material in such an article, Jc's of 1.4×106 A/cm2 have been demonstrated with projected Ic's of 210 Amperes across a sample 1 cm wide.Type: ApplicationFiled: December 6, 2000Publication date: February 20, 2003Inventors: Paul N. Arendt, Stephen R. Foltyn, James R. Groves, Terry G. Holesinger, Quanxi Jia
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Patent number: 6500568Abstract: Described is an article comprising a biaxially textured metal substrate and a layer of palladium deposited on at least one major surface of the metal substrate; wherein the palladium layer has desired in-plane and out-of-plane crystallographic orientations, which allow subsequent layers that are applied on the article to also have the desired orientations.Type: GrantFiled: June 6, 2001Date of Patent: December 31, 2002Assignee: 3M Innovative Properties CompanyInventor: William B. Robbins
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Patent number: 6487427Abstract: A compact dielectric resonator of high Qu, in which an electrode formed of an oxide superconducting material is provided on a surface of the dielectric so as to serve as an electrode. A dielectric filter, dielectric duplexer and a communications device, in which the compact resonator is incorporated, are also provided. The dielectric which constitutes the dielectric resonator of the present invention is preferably a Ba(Mg, Ma)03-based dielectric (wherein Ma is at least one pentavalent elemental metal but cannot be Ta alone), and the oxide superconducting electrode is formed of an oxide superconducting material selected from among a RE—M—Cu—O-based oxide superconducting material (wherein RE is a rare earth element and M is an alkaline earth metal element), a Bi—Sr—Ca—Cu—O-based oxide superconducting material (which encompasses those in which Bi is partially substituted by Pb), and a Tl—Ba—Ca—Cu—O-based oxide superconducting material.Type: GrantFiled: March 23, 1999Date of Patent: November 26, 2002Assignee: Murata Manufacturing Co., Ltd.Inventors: Tsutomu Tatekawa, Yuji Kintaka, Hiroshi Tamura, Akio Oota
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Patent number: 6455166Abstract: A biaxially textured face-centered cubic metal article having grain boundaries with misorientation angles greater than about 8° limited to less than about 1%. A laminate article is also disclosed having a metal substrate first rolled to at least about 95% thickness reduction followed by a first annealing at a temperature less than about 375° C. Then a second rolling operation of not greater than about 6% thickness reduction is provided, followed by a second annealing at a temperature greater than about 400° C. A method of forming the metal and laminate articles is also disclosed.Type: GrantFiled: May 11, 2000Date of Patent: September 24, 2002Assignee: The University of ChicagoInventors: Thomas G. Truchan, Dean J. Miller, Kenneth C. Goretta, Uthamalingam Balachandran, Robert Foley
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Patent number: 6410487Abstract: A bulk superconductor having a thickness of not less than about 100 microns is carried by a polycrystalline textured substrate having misorientation angles at the surface thereof not greater than about 15°; the bulk superconductor may have a thickness of not less than about 100 microns and a surface area of not less than about 50 cm2. The textured substrate may have a thickness not less than about 10 microns and misorientation angles at the surface thereof not greater than about 15°. Also disclosed is a process of manufacturing the bulk superconductor and the polycrystalline biaxially textured substrate material.Type: GrantFiled: July 20, 2000Date of Patent: June 25, 2002Assignee: The University of ChicagoInventors: Dean J. Miller, Michael B. Field