Producing Lattice Imperfection Flux Pinning Sites Or Increasing Critical Current Density Through Particle Bombardment, Electromagnetic Wave Energy, Or Using Fissionable Material Patents (Class 505/320)
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Patent number: 11783953Abstract: Disclosed are a superconductor having improved critical current density when exposed to high-energy neutron radiation and high magnetic fields, such as found in a compact nuclear fusion reactor, and a method of making the same. The method includes, prior to deployment in the exposure environment, irradiating a polycrystalline (e.g. cuprate) superconductor with ionic matter or neutrons at a cryogenic temperature to create “weak” magnetic flux pinning sites, such as point defects or small defect clusters. Irradiation temperature is chosen, for example as a function of the superconducting material, so that irradiation creates the beneficial flux pinning sites while avoiding detrimental widening of the boundaries of the crystalline grains caused by diffusion of the displaced atoms. Such a superconductor in a coated-conductor tape is expected to be beneficial when used, for example, as a toroidal field coil in a fusion reactor when cooled well below its critical temperature.Type: GrantFiled: June 18, 2019Date of Patent: October 10, 2023Assignee: MASSACHUSETTS INSTITUTE OF TECHNOLOGYInventors: Brandon Nils Sorbom, Zachary Hartwig, Dennis G. Whyte
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Publication number: 20140302996Abstract: Disclosed is a method and apparatus for strongly enhancing vortex pinning by conformal crystal arrays. The conformal crystal array is constructed by a conformal transformation of a hexagonal lattice, producing a non-uniform structure with a gradient where the local six-fold coordination of the pinning sites is preserved, and with an arching effect. The conformal pinning arrays produce significantly enhanced vortex pinning over a much wider range of field than that found for other vortex pinning geometries with an equivalent number of vortex pinning sites, such as random, square, and triangular.Type: ApplicationFiled: March 7, 2014Publication date: October 9, 2014Applicant: University of Notre Dame du LacInventors: Boldizsar Janko, Cynthia Reichhardt, Charles Reichhardt, Dipanjan Ray
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Patent number: 8629087Abstract: A high temperature superconductor (=HTS) coated conductor (1), comprising an HTS layer (11) deposited epitaxially on a substrate (2), wherein the HTS layer (11) exhibits a lattice with a specific crystal axis being oriented perpendicular to the substrate plane (SP), in particular wherein the HTS layer material is of ReBCO type and the c-axis (c) is oriented perpendicular to the substrate plane (SP), wherein the HIS layer (11) comprises particle inclusions (4), in particular wherein the particle inclusions (4) may be used to introduce pinning of magnetic flux, is characterized in that at least a part (4a) of the particle inclusions (4) are formed of the same material as the HTS layer (11), and/or of chemical fractions of the material of the HTS layer (11), such that the average stoichiometry of said part (4a) of the particle inclusions (4) corresponds to the stoichiometry of the HTS layer (11), and that the particle inclusions of said part (4a) are discontinuities of the lattice of the HTS layer (11).Type: GrantFiled: July 18, 2011Date of Patent: January 14, 2014Assignee: Bruker HTS GmbHInventors: Alexander Usoskin, Klaus Schlenga
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Patent number: 8536098Abstract: Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.Type: GrantFiled: July 30, 2011Date of Patent: September 17, 2013Inventor: Amit Goyal
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Method for operating a superconductor at a temperature higher than the superconductive temperature T
Patent number: 8415276Abstract: A method of operating a superconductor in its superconductivity state at a temperature Tc(i) in the range of Tc* to Tc, where Tc* is greater than the superconductivity temperature Tc of the superconductor, includes cooling the superconductor to a temperature of Tc or less and applying energy to the superconductor after the superconductor has entered a superconducting state. The energy corresponds to the quantum energy h? in the range of a minimum energy less than E0 to less than E0, where E0 is the ground state of the two-dimensional excitation binding energy of the superconductor The superconductor is then cooled to the selected temperature Tc(i). The minimum energy is 8/9 of E0.Type: GrantFiled: December 26, 2006Date of Patent: April 9, 2013Assignee: CZT Inc.Inventors: Susana Curatolo, Kai Wai Wong -
Patent number: 8227020Abstract: Techniques to form dislocation cores along an interface of a multilayer thin film structure are described. The loading and/or deloading of isotopes of hydrogen are also described in association with core formation. The described techniques can provide be applied to superconductive structure formation, x-ray and charged particle generation, nuclear reaction processes, and/or inertial confinement fusion targets.Type: GrantFiled: March 31, 2008Date of Patent: July 24, 2012Assignee: NPL Associates, Inc.Inventor: George H. Miley
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Patent number: 8119571Abstract: Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.Type: GrantFiled: August 3, 2006Date of Patent: February 21, 2012Inventors: Amit Goyal, Sukill Kang
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Patent number: 8034745Abstract: Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic, superconducting and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.Type: GrantFiled: March 24, 2008Date of Patent: October 11, 2011Inventor: Amit Goyal
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Patent number: 7919435Abstract: The present invention relates to a method for producing a defect-containing superconducting film, the method comprising (a) depositing a phase-separable layer epitaxially onto a biaxially-textured substrate, wherein the phase-separable layer includes at least two phase-separable components; (b) achieving nanoscale phase separation of the phase-separable layer such that a phase-separated layer including at least two phase-separated components is produced; and (c) depositing a superconducting film epitaxially onto said phase-separated components of the phase-separated layer such that nanoscale features of the phase-separated layer are propagated into the superconducting film.Type: GrantFiled: September 30, 2008Date of Patent: April 5, 2011Assignee: UT-Battelle, LLCInventor: Amit Goyal
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Patent number: 7902119Abstract: Porous ceramic superconductors having a film thickness over 0.5 microns are provided. The superconducting material is applied to a vicinal substrate and optionally nanoparticles are inserted to release local strain. The resultant superconductors exhibit improved Jc values compared to nonvicinal (flat) counterparts and those having no nanoparticles.Type: GrantFiled: July 21, 2006Date of Patent: March 8, 2011Inventors: Judy Wu, Rose Emergo, Timothy Haugan, Paul Barnes
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Patent number: 7838061Abstract: Disclosed herein is a method of fabricating a high temperature superconducting film in a vacuum chamber through auxiliary cluster beam spraying using an evaporation method, wherein a high temperature superconducting material is deposited on a substrate in a vapor state by evaporating the high temperature superconducting material, and at the same time, a cluster beam material is formed into gas atoms by heating the cluster beam material charged in a housing, and the formed gas atoms pass through a nozzle of an inlet of the housing and then are sprayed and grown on the substrate in the form of the cluster beam, thereby forming pinning centers in the high temperature superconducting film.Type: GrantFiled: January 12, 2007Date of Patent: November 23, 2010Assignee: Korea Electrotechnology Research InstituteInventors: Sang Soo Oh, Ho Seop Kim, Kyu Jung Song, Do Jun Youm, Sun Mi Lim, Yong Hwan Jung, Sang Moo Lee, Ye Hyun Jung, Jae Eun Yoo
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Patent number: 7820596Abstract: A thick film superconductor includes a substrate and a superconducting thick film formed on the substrate. The thick film is 1-20 microns thick with an average twin spacing to film thickness ratio of about 0.016, and is formed from an aqueous solution of YBC ions doped with a particulate rare earth oxide having a diameter of about 50-500 nm. The coated substrate is heat treated, preferably above 650 degrees C. and cooled at a rate less than 15 degrees C. per hour, resulting in a substantially fully oxygenated YBCO layer.Type: GrantFiled: October 23, 2001Date of Patent: October 26, 2010Assignee: The Trustees of Columbia University in the City of New YorkInventor: Siu-Wai Chan
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Patent number: 7737087Abstract: A process and composition of matter are provided and involve flux pinning in thin films of high temperature superconductive oxides such as YBCO by inclusion of particles including barium and a group 4 or group 5 metal, such as zirconium, in the thin film.Type: GrantFiled: July 27, 2004Date of Patent: June 15, 2010Assignee: Los Alamos National Security, LLCInventors: Judith L. Driscoll, Stephen R. Foltyn
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Patent number: 6949490Abstract: High-Tc superconducting ceramic oxide products and macroscopic and microscopic methods for making such high-Tc superconducting products. Completely sealed high-Tc superconducting ceramic oxide provides are made by a macroscopic process including the steps of pressing a superconducting ceramic oxide powder into a hollow body of a material inert to oxygen; heat treating the superconducting ceramic oxide powder packed body under conditions sufficient to sinter the ceramic oxide powder; and then sealing any openings of the body. Optionally, a waveform or multiple pulses of alternate magnetic filed can be applied during the heat treatment.Type: GrantFiled: June 9, 2003Date of Patent: September 27, 2005Inventor: Dawei Zhou
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Patent number: 6869915Abstract: An oxide superconductor includes a textured superconducting material including an array of defects, where the defects are a compound of two elements foreign to the superconductor, plus other elements native to the superconductor. The two foreign elements include one from group A and one from group B (or alternately the two foreign elements include the element uranium and one element from group C), where group A includes Cr, Mo, W, or Nd, group B includes Pt, Zr, Pd, Ni, Ti, Hf, Ce and Th, and group C includes Zr, Pd, Ni, Ti, Hf, Ce and Th. The array of defects is dispersed throughout the superconducting material. The superconducting material may be the RE1Ba2Cu3O7?? compound, wherein RE=Y, Nd, La, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Tb; the Bi2Sr2CaCu2Ox, (Bi, Pb)2Sr2CaCu2Ox, Bi2Sr2Ca2Cu3Ox (Bi, Pb)2Sr2Ca2Cu3Ox compounds; the HgBa2Ca2Cu3O8 and HgBa2CaCu2O6 compounds, the TlCaBa2Cu2Ox or Tl2Ca2Ba2Cu3Ox compounds and compounds involving substitution such as the Nd1+xBa2?xCu3Ox compounds.Type: GrantFiled: December 31, 2001Date of Patent: March 22, 2005Inventor: Roy Weinstein
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Patent number: 6809066Abstract: Ion texturing methods and articles are disclosed.Type: GrantFiled: July 30, 2001Date of Patent: October 26, 2004Assignee: The Regents of the University of CaliforniaInventors: Ronald P. Reade, Paul H. Berdahl, Richard E. Russo, Leslie G. Fritzemeier
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Patent number: 6638895Abstract: A method of fabricating high aspect ratio ceramic structures in which a selected portion of perovskite or perovskite-like crystalline material is exposed to a high energy ion beam for a time sufficient to cause the crystalline material contacted by the ion beam to have substantially parallel columnar defects. Then selected portions of the material having substantially parallel columnar defects are etched leaving material with and without substantially parallel columnar defects in a predetermined shape having high aspect ratios of not less than 2 to 1. Etching is accomplished by optical or PMMA lithography. There is also disclosed a structure of a ceramic which is superconducting at a temperature in the range of from about 10° K. to about 90° K. with substantially parallel columnar defects in which the smallest lateral dimension of the structure is less than about 5 microns, and the thickness of the structure is greater than 2 times the smallest lateral dimension of the structure.Type: GrantFiled: October 25, 2000Date of Patent: October 28, 2003Assignee: The University of ChicagoInventors: Goran T. Karapetrov, Wai-Kwong Kwok, George W. Crabtree, Maria Iavarone
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Patent number: 6630426Abstract: A method for increasing the critical temperature, Tc, of a high critical temperature superconducting (HTS) film (104) grown on a substrate (102) and a superconducting structure (100) made using the method. The HTS film has an a-b plane parallel to the surface of the substrate and a c-direction normal to the surface of the substrate. Generally, the method includes providing the substrate, growing the HTS film on the substrate and, after the HTS film has been grown, inducing into the HTS film a residual compressive strain the a-b plane and a residual tensile strain into the c-direction.Type: GrantFiled: November 16, 2000Date of Patent: October 7, 2003Assignee: TeraComm Research Inc.Inventors: Thomas G. Ference, Kenneth A. Puzey
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Patent number: 6525002Abstract: An oxide superconductor includes a textured superconducting material including an array of defects with a neutron-fissionable element, or with at least one of the following chemical elements: uranium-238, Nd, Mn, Re, Th, Sm, V, and Ta. The array of defects is dispersed throughout the superconducting material. The superconducting material may be the RE1Ba2Cu3O7−&dgr; compound, wherein RE=Y, Nd, La, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu; the Bi2Sr2CaCu2Ox, the (Bi, Pb)2Sr2CaCu2Ox, Bi2Sr2Ca2Cu3Ox or (Bi, Pb)2Sr2Ca2Cu3Ox compound; the Tl2Ca1.5BaCu2Ox or Tl2Ca2Ba2Cu3Ox compound; or a compound involving substitution such as the Nd1+xBa2−xCu3Ox compounds. The neutron-fissionable element may be uranium-235. The oxide superconductor may include additional defects created by fission.Type: GrantFiled: May 6, 2000Date of Patent: February 25, 2003Inventor: Roy Weinstein
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Method for producing formed bodies of high temperature superconductors having high critical currents
Patent number: 6493411Abstract: Thermal neutron irradiation of superconducting body compositions into which Li or B has been incorporated as a unit cell external or internal dopant introduces by the nuclear reaction of the dopant pinning centers which substantially improve the critical current density of the body.Type: GrantFiled: October 1, 1996Date of Patent: December 10, 2002Assignee: University of Houston-University ParkInventors: Wei-Kan Chu, Jiarui Liu -
Superconductor with enhanced current carrying capability and method for making such a superconductor
Publication number: 20020165100Abstract: The present invention concerns the improvement of the supercurrent carrying capabilities, i.e. the increase of critical current densities, of bicrystalline or polycrystalline superconductor structures, especially of high-Tc superconductors. By providing an appropriate predetermined dopant profile across the superconductor structure, in particular within or in the vicinity of the grain boundaries, the space-charge layers at the grain boundaries are reduced and thereby the current transport properties of the superconductor significantly improved. Simultaneously, the influence of magnetic fields on the critical current densities is significantly reduced, which in turn enhances the overall supercurrent carrying capabilities while keeping the supercurrent transport properties of the grains at good values.Type: ApplicationFiled: March 2, 2001Publication date: November 7, 2002Inventors: Hartmut Ulrich Bielefeldt, Barbel Martha Gotz, German Hammerl, Johannes Wilhelmus Maria Hilgenkamp, Jochen Dieter Mannhart, Andreas Fritz Albert Schmehl, Christof Walter Schneider, Robert Ralf Schulz -
Publication number: 20020164418Abstract: A method for creating a long superconducting wire and tape materials that can be loaded with high current densities using MgB2. The method is based on the powder-in-the-tube technology. In this process, there is a composite consisting of a cover tube made of material with normal conductivity, and a powder of a superconducting compound or a preliminary product. This powder compound contained in this cover tube, are processed by reshaping and thermal treatment steps to the superconducting wire or tape material. According to the invention, a composite is supplied to the processing process that contains a powdery superconducting MgB2 compound or a powdery preliminary product for a superconducting MgB2 compound. The powdery preliminary product, has been only partially reacted to an MgB compound, or is a powder mixture consisting of the individual components of the desired MgB2 compound. This product is filled into the cover tube.Type: ApplicationFiled: March 21, 2002Publication date: November 7, 2002Inventors: Claus Fischer, Wolfgang Hassler, Margitta Schubert, Hans-Peter Trinks, Andreas Gumbel
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Patent number: 6083885Abstract: An oxide superconductor includes a textured superconducting material including an array of defects with a neutron-fissionable element, or with at least one of the following chemical elements: uranium-238, Nd, Mn, Re, Th, Sm, V, and Ta. The array of defects is dispersed throughout the superconducting material. The superconducting material may be the RE.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-.delta. compound, wherein RE=Y, Nd, La, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu; the Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.x, the (Bi, Pb).sub.2 Sr.sub.2 CaCu.sub.2 O.sub.x, Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x or (Bi, Pb).sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.x compound; the Tl.sub.2 Ca.sub.1.5 BaCu.sub.2 O.sub.x or Tl.sub.2 Ca.sub.2 Ba.sub.2 Cu.sub.3 O.sub.x compound; or a compound involving substitution such as the Nd.sub.1+x Ba.sub.2-x Cu.sub.3 O.sub.x compounds. The neutron-fissionable element may be uranium-235. The oxide superconductor may include additional defects created by fission.Type: GrantFiled: January 13, 1998Date of Patent: July 4, 2000Inventor: Roy Weinstein
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Patent number: 5912210Abstract: There is disclosed herein an invention for increasing the current carrying capability of high-Tc superconductor materials. The inventive method includes irradiating such superconductors with light particles, such as neutrons, protons and thermal neutrons, having energy sufficient to cause fission of one or more elements in the superconductor material at a dose rate and for a time sufficient to create highly splayed (dispersed in orientation) extended columns of damaged material therein. These splayed tracks significantly enhance the pinning of magnetic vortices thereby effectively reducing the vortex creep at high temperatures resulting in increased current carrying capability.Type: GrantFiled: August 8, 1997Date of Patent: June 15, 1999Assignee: International Business Machines CorporationInventors: Lia Krusin-Elbaum, Alan David Marwick, Paul William Lisowski, James Russell Thompson, Jr., James Francis Ziegler
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Patent number: 5856205Abstract: In a Josephson junction device comprises two superconducting electrodes formed of an oxide superconductor and connected through a Josephson junction, a temperature dependent noise of the Josephson junction becomes the minimum at a liquid nitrogen temperature.Type: GrantFiled: March 24, 1997Date of Patent: January 5, 1999Assignee: Sumitomo Electric Industries, Ltd.Inventor: Hirokazu Kugai
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Patent number: 5731270Abstract: An oxide is formed which will form an oxide superconductor containing a Cu-O atomic layer. The oxide is hydrogenated. The oxide is oxidized after it is hydrogenated. The hydrogenation and the oxidization are executed simultaneously with or after the oxide is formed. The hydrogenation and the oxidization improve the superconducting characteristics of the oxide superconductor.Type: GrantFiled: July 29, 1996Date of Patent: March 24, 1998Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kentaro Setsune, Yo Ichikawa, Akira Enokihara, Masahiro Sakai
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Patent number: 5683967Abstract: Method for increasing the critical current density in Type II superconducting materials. The generation of a regular pattern of defects for pinning vortices, where the density of pinning sites is matched to the density of vortices produced by a chosen magnetic field in the particular superconducting material, is described. It is anticipated that such a defect pattern will substantially increase the critical current density carrying capability of the superconducting material so patterned. The fabrication of thick superconductors and conductors having chosen shapes is also described.Type: GrantFiled: March 15, 1996Date of Patent: November 4, 1997Inventor: Anatoly Frenkel
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Patent number: 5677265Abstract: A process for the oxygenation of ceramic high T.sub.c superconductors is disclosed. The superconductor is formed from a sintered powdered ceramic. Microchannels are formed in the ceramic material by embedding in the powder a plurality of wires or fibers formed of a material which is thermally removable during the sintering process to leave thin, continuous, tubular channels. After sintering, the ceramic is exposed to oxygen in a high temperature, high pressure environment. The microchannels aid in the transport of oxygen into the interior of the material by providing passages along which the oxygen travels prior to diffusing into the material. The lengths of the diffusion paths in the material are thereby greatly shortened. In another embodiment, the channels are formed after sintering and prior to oxygenation by drilling, punching, or etching.Type: GrantFiled: March 3, 1995Date of Patent: October 14, 1997Assignee: Northeastern UniversityInventors: Bill C. Giessen, Robert S. Markiewicz, Bala Maheswaran, Thomas R. Gilbert
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Patent number: 5627140Abstract: Enhanced flux pinning in superconductors is achieved by embedding carbon nanotubes into a superconducting matrix. The carbon nanotubes simulate the structure, size and shape of heavy ion induced columnar defects in a superconductor such as Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.8+x. The nanotubes survive at treatment temperatures of up to approximately 800.degree. C. both in oxygen containing and in inert atmospheres. The superconducting matrix with nanotubes is heat treated at a lower temperature than the temperature used to treat the best case pure superconductor material.Type: GrantFiled: May 19, 1995Date of Patent: May 6, 1997Assignees: NEC Research Institute, Inc., Florida State UniversityInventors: Kristian Fossheim, Thomas W. Ebbesen
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Patent number: 5597782Abstract: A method for improving the phase purity of a multiphase ceramic high temperature superconductor by selective microwave heating of undesired phases in a multiphase material to cause a phase transformation of the undesired phase to the desired phase. The selective microwave heating may be employed during initial firing and sintering of the ceramic superconductor compound or as a subsequent annealing step. Plane polarized microwave energy may be employed to enhance the two dimensional anisotropy of the compound by similar selective heating.Type: GrantFiled: January 9, 1995Date of Patent: January 28, 1997Inventor: David L. Henty