Abstract: A low-aspect ratio multi-filament superconductor wire includes a plurality of oxide superconductor filaments arranged in an elongated wire structure. Each filament of the wire also has a low-aspect ratio. The filaments are textured such that a crystallographic c direction of each filament is aligned with a crystallographic c direction of all other filaments with the crystallographic c directions being perpendicular to the longitudinal axis of the wire structure. The invention also features a groove rolling machine for forming a low-aspect ratio multi-filament superconductor wire by texturing a precursor tape by deforming the tape to a low-aspect ratio wire by reducing a larger dimension of the tape in such a way as to prevent buckling of the tape. A superconducting cable can be formed by planetary winding a plurality of multi-filament superconductor wires.

Abstract: Provided is an oxide superconducting conductor consisting of a plurality of metal-covered multifilamentary superconducting wires which are assembled with each other. Bending is applied to the superconducting conductor for improving its critical current density. It is possible to obtain a compact superconducting conductor having higher capacity, since its critical current density is increased by such application of bending.

Abstract: The combination of one or more high reduction drafts with controlled, low back tensions increases the range of deformation conditions over which dimensional tolerances and Je may be optimized. The method comprises the steps of: first, providing a precursor article comprising a metal matrix surrounding a plurality of filaments extending along the length of the article and comprising precursors to a desired superconducting ceramic; next, roll working the precursor article during a breakdown stage at a back tension less than the elastic to plastic transition threshold of the composite during at least one high reduction roll working draft, and, then, sintering the rolled article to obtain the desired superconducting ceramic. In a preferred embodiment, the rolling step further comprises rolling the article at a front tension less than the elastic to plastic transition threshold of the rolled, unsintered article.

Abstract: Methods for producing biaxially aligned superconducting ceramics are disclosed. The methods include fabricating a composite precursor formed of substantially planar filaments of a superconductor precursor surrounded by a matrix, and thermomechanically processing the precursor to texture at least the interfacial layers with the matrix without converting appreciable amounts of the composite precursor to the superconducting oxide to form a preliminary filament material. The method also includes reaction texturing the preliminary filament material to form and texture a superconducting oxide. Reaction texture involves first heating at relatively low oxygen pressure, then heating at higher oxygen pressure.

Abstract: Superconductor tapes are annealed under uniaxial pressure, such a compressive annealing yielding significant improvement in the resultant critical current density. This thermomechanical processing technique obtains improved critical currents with fewer processing steps.

Abstract: A method for preparing an oxide superconductor cable includes transposing a plurality of oxide superconductor strands along a longitudinal axis so as to form a cable and exposing the cable to a two step heat treatment after cabling of the oxide strands, the heat treatment comprising, (a) heating the cable to and maintaining the cable at a first temperature sufficient to partially melt the article, such that a liquid phase co-exists with the desired oxide superconductor phase; and (b) cooling the cable to and maintaining the cable at a second temperature sufficient to substantially transform the liquid phase into the desired oxide superconductor.

Abstract: A long oxide superconducting wire for a coil or a cable, manufacturing method thereof, an oxide superconducting coil and a cable conductor which have high operational frequency are provided. The wire is a tape-like oxide superconducting wire including a plurality of filaments of oxide superconductor embedded in a matrix, and each filament is twisted spirally along the longitudinal direction of the tape wire. By winding the wire in a coil, an oxide superconducting coil is obtained. When a plurality of such wires are collected, an oxide superconducting cable conductor can be obtained.

Abstract: A powder in tube method of making an HTc superconductive multifilament strand having a silver-based matrix, in which method:prior to the monofilament step:a composite multilayer material is prepared comprising at least one silver-based sheet, and at least one layer of non-superconductive ceramic material that is permeable to oxygen; andduring the monofilament step, a thickness of composite multilayer material is interposed between first and second thicknesses of silver-based material, thereby forming said first silver-based envelope.

Abstract: Process for producing an elongated superconductor with a bismuth phase having a high transition temperature and a superconductor produced according to this process. An elongated superconductor with at least one conductor core made of high-T.sub.c Bi-containing superconductor material with the 2212 or 2223 phase is to be manufactured. For this purpose, the cross section of a structure made of Ag matrix material and a precursor of the superconductor material is reduced. Subsequently the raw conductor thus obtained is annealed in an oxygen-containing atmosphere. According to this invention, a temperature variation between a higher temperature (T1) and a lower temperature (T2) is provided for the annealing. The higher temperature (T1) is at most 7 K above the decomposition temperature (Tz), and the lower temperature (T2) is at most 9 K below the decomposition temperature (Tz).

Abstract: A novel process of the production and processing of high quality, high T.sub.c BSCCO or (Bi,Pb)SCCO superconductors starts with fabrication of a forming a bundle including a plurality of billets, each billet containing at least one filament comprising a dominant amount of an tetragonal BSCCO phase with selected intermediate phases, and substantially surrounded by a constraining metal. The bundle is thermomechanically consolidated to form a multifilamentary precursor article by applying pressure and heat to the bundle under conditions cooperatively selected to cause interdiffusion of said constraining metal at the interfaces between said metal and said filaments and substantially complete elimination of voids in said bundle, and the consolidation step is completed before any high strain longitudinal deformation is performed on the bundle.

Abstract: A multifilamentary superconducting composite article comprising multiple substantially electrically decoupled domains, each including one or more fine, preferably twisted filaments of a desired superconducting oxide material. In a preferred embodiment, the article comprises a matrix, which substantially comprises a noble metal, a conductive jacketing layer surrounding the matrix, a plurality of discrete filament decoupling layers, each comprising an insulating material, disposed within the matrix to separate the matrix into a plurality of substantially electrically decoupled domains; a plurality of filaments, each comprising a desired superconducting oxide, which are disposed within and essentially encapsulated by the matrix and chemically isolated thereby from the decoupling layers, each of the electrically decoupled domains containing at least one filament.

Abstract: A process for texturing an HTc superconductor of the matrix type based on silver and the superconductor material (Bi.sub.1-x Pb.sub.x).sub.2 Sr.sub.2 Ca.sub.y Cu.sub.1+y O.sub.6+2y where x.epsilon.[0; 0,4] and y.epsilon.{0, 1, 2} includes the following steps carried out in succession: raising the temperature of the superconductor from room temperature to the melting point of the superconductor material, maintaining the temperature of the superconductor constant at the melting point of the superconductor material for a relatively short period, varying the temperature of the superconductor between the melting point of the superconductor material and its synthesis temperature, maintaining the temperature of the superconductor constant at the synthesis temperature of the superconductor material for a relatively long period and reducing the temperature of the superconductor from the synthesis temperature of the superconductor material to room temperature.

Abstract: A high temperature superconductor composite material, which is suitable for production of filaments, wires, coils and other shaped products, has a ceramic powder of a material selected from the group consisting of, for example, YBa.sub.2 Cu.sub.3 O.sub.7-x and Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 O.sub.10 ; a solution of a material selected from the group consisting of rubber silicone or lacquer silicone in a substance selected from the group consisting of toluene or acetone; and an ultra-fine silver powder dope, and is produced by using an emulsion mixture of the three major components with ultrasonic homogenization of the mixture, primer cladding of a glue-exterior layer on a silver core filament, high temperature superconductor coating of the silver core by chemical adhesion, and polymerization of the coating applied by low temperature heating, whereafter the composition is treated by magnetic treatment, gamma irradiation, and microwave supported fast heating.

Abstract: A method of forming a textured superconductor wire includes constraining an elongated superconductor precursor between two constraining elongated members placed in contact therewith on opposite sides of the superconductor precursor, and passing the superconductor precursor with the two constraining members through flat rolls to form the textured superconductor wire. The method includes selecting desired cross-sectional shape and size constraining members to control the width of the formed superconductor wire. A textured superconductor wire formed by the method of the invention has regular-shaped, curved sides and is free of flashing. A rolling assembly for single-pass rolling of the elongated precursor superconductor includes two rolls, two constraining members, and a fixture for feeding the precursor superconductor and the constraining members between the rolls.

Abstract: A novel process of the production and processing of high quality, high T.sub.c (Bi,Pb)SCCO superconductors starts with fabrication of a precursor article including selected intermediate phases with desired chemical and structural properties. The precursor fabrication includes introducing the reacted mixture having a dominant amount of the tetragonal BSCCO phase into a metal sheath, and sealing the reacted mixture within said sheath, heating the mixture at a second selected processing temperature in an inert atmosphere with a second selected oxygen partial pressure for a second selected time period, the second processing temperature and the second oxygen partial pressure being cooperatively selected to form a dominant amount of an orthorhombic BSCCO phase in the reacted mixture.

Abstract: A superconductive composite member, which has a core composed of an oxide ceramic material which is surrounded by an envelope, has an increased core density in order to achieve a higher critical current density. The increased core density is obtained during a hot-shaping step of the core material in the envelope, wherein the composite is heated to a temperature wherein the superconductor material is present in either a molten or a partially molten state.

Abstract: A low-aspect ratio multi-filament superconductor wire includes a plurality of oxide superconductor filaments arranged in an elongated wire structure. Each filament of the wire also has a low-aspect ratio. The filaments are textured such that a crystallographic c direction of each filament is aligned with a crystallographic c direction of all other filaments with the crystallographic c directions being perpendicular to the longitudinal axis of the wire structure. The invention also features a groove rolling machine for forming a low-aspect ratio multi-filament superconductor wire by texturing a precursor tape by deforming the tape to a low-aspect ratio wire by reducing a larger dimension of the tape in such a way as to prevent buckling of the tape. A superconducting cable can be formed by planetary winding a plurality of multi-filament superconductor wires.

Abstract: A process for manufacturing superconducting magnetic coils from strain-tolerant, superconducting multi-filament composite conductors is described. The method involves winding the precursor to a multi-filament composite conductor and an insulating material or its precursor around a mandrel in order to form a coil, and then exposing the coil to high temperatures and an oxidizing environment. The insulating material or its precursor is chosen to permit exposure of the superconductor precursor filaments to the oxidizing environment, and to encase the matrix-forming material enclosing the filaments, which is reversibly weakened during processing.

Abstract: A strongly-linked polycrystalline oxide superconductor article includes an oxide superconductor selected from the group consisting 124-type and 247-type oxide superconductors having fine, highly aligned oxide superconductor grains less than 50 .mu.m along a longest dimension. The oxide superconductor article has at least a 25% retention of critical current density in a 0.1 Tesla field.

Abstract: An oxide superconducting coil is formed by winding a superconducting multifilamentary wire consisting essentially of a plurality of filaments consisting essentially of an oxide superconductor and a stabilizing material, consisting of silver or a silver alloy, covering the filaments. Superconducting phases of the filaments are substantially rendered monophasic, and c-axes thereof are strongly oriented along the thickness of the wire. Crystal grains of the superconductor forming the filaments are in the form of flakes extending longitudinally along the wire, while the same are bonded to each other. In a section of the wire, a ratio obtained by dividing a sectional area occupied by the silver or the silver alloy by that occupied by the filaments is not more than 3. In a magnetic field of at least 10 T, the coil exhibits a critical current value which is at least 60% of that exhibited by the wire itself forming the coil.

Abstract: Disclosed herein is a method of preparing an oxide superconducting wire comprising the steps of coating a powder material for forming an oxide superconductor with a metal, performing deformation processing on the metal-coated powder material thereby obtaining a tape-type wire material, superposing a plurality of such tape-type wire materials, performing first heat treatment on the plurality of superposed tape-type wire materials while simultaneously diffusion-bonding the metallic coats to each other, then performing deformation processing on the plurality of superposed tape-type wire materials, and performing second heat treatment on the plurality of deformation-processed tape-type wire materials. Preferably the oxide superconductor to be obtained is a bismuth oxide superconductor having a 2223 composition in a composition of Bi-Sr-Ca-Cu or (Bi,Pb)-Sr-Ca-Cu, and the powder material consists of a superconducting phase, which is mainly composed of a 2212 phase, and non-superconducting phases.

Abstract: A method for forming unsegregated metal oxide-silver composites includes preparing a precursor alloy comprising silver and precursor elements of a desired metal oxide and oxidizing the alloy under conditions of high oxygen activity selected to permit diffusion of oxygen into silver while significantly restricting the diffusion of the precursor elements into silver, such that oxidation of the precursor elements to the metal oxide occurs before diffusion of the metallic elements into silver. Further processing of the metal oxide composite affords an oxide superconducting composite with a highly unsegregated microstructure.

Abstract: Metal oxide superconductor powder precursors are prepared in an aerosol pyrolysis process. A solution of the metal cations is introduced into a furnace at 600.degree.-1000.degree. C. for 0.1 to 60 seconds. The process produces micron to submicron size powders without the usual loss of the lead stabilizer. The resulting powders have a narrow particle size distribution, a small grain size, and are readily converted to a superconducting composition upon subsequent heat treatment. The precursors are placed in a metal body deformed to form a wire or tape and heated to form a superconducting article. The fine powders permit a substantial reduction in heat treatment time, thus enabling a continuous processing of the powders into superconducting wire, tape or multifilamentary articles by the powder-in-tube process.

Abstract: Disclosed herein is a method of preparing an oxide superconducting wire comprising the steps of coating a powder material for forming an oxide superconductor with a metal, performing deformation processing on the metal-coated powder material thereby obtaining a tape-type wire material, superposing a plurality of such tape-type wire materials, performing first heat treatment on the plurality of superposed tape-type wire materials while simultaneously diffusion-bonding the metallic coats to each other, then performing deformation processing on the plurality of superposed tape-type wire materials, and performing second heat treatment on the plurality of deformation-processed tape-type wire materials. Preferably the oxide superconductor to be obtained is a bismuth oxide superconductor having a 2223 composition in a composition of Bi--Sr--Ca--Cu or (Bi,Pb)--Sr--Ca--Cu, and the powder material consists of a superconducting phase, which is mainly composed of a 2212 phase, and non-superconducting phases.

Abstract: A strain tolerant multifilamentary wire capable of carrying superconducting currents is provided comprising a plurality of discontinuous filaments formed from a high temperature superconducting material. The discontinuous filaments have a length at least several orders of magnitude greater than the filament diameter and are sufficiently strong while in an amorphous state to withstand compaction. A normal metal is interposed between and binds the discontinuous filaments to form a normal metal matrix capable of withstanding heat treatment for converting the filaments to a superconducting state. The geometry of the filaments within the normal metal matrix provides substantial filament-to-filament overlap, and the normal metal is sufficiently thin to allow supercurrent transfer between the overlapped discontinuous filaments but is also sufficiently thick to provide strain relief to the filaments.