Abstract: An atmospheric process for the production of a coating of film upon a nickel-containing substrate. In the first step of this process, an aerosol mist containing reactants necessary to form the coating is provided. Thereafter, the mist is subjected to radio-frequency radiation while in the plasma region. Thereafter, the vaporized mixture is then deposited onto a nickel substrate. In subsequent steps, one or more other layers of vaporized material may be deposited onto the coated substrate.

Abstract: An oxide superconducting material is coated with silver or an alloy thereof and shaped into a linear body, and the linear body is subjected to diameter reduction by means of groove roll rolling, a swaging machine and the like, and then differential speed rolling and heat treatment are repeatedly performed, whereby the linear body is shaped into a tape-shaped wire material. The microstructure control in the longitudinal direction is performed uniformly and efficiently, and a superconducting wire having a high c-axis orientation ratio and a large critical current density Jc at a service temperature is obtained.

Abstract: The present invention provides a method of manufacturing superconductive products comprising heating a superconductive matter or incorporation including its precursor to a temperature higher than its or its precursor's melting point to melt it or its precursor, and then solidifying and cooling it in a direction in such a way that it is re-crystalized to have an orientation in the longitudinal direction of its incorporation.

Abstract: A multifilamentary oxide superconducting wire includes a metal matrix and a plurality of flat oxide superconductor filaments arranged in the metal matrix such that wide directions thereof are radially arranged in a section of the metal matrix. A method of manufacturing a multifilamentary oxide superconducting wire includes the steps of filling a raw material of an oxide superconductor in a through hole of a metal member to form a composite billet, subjecting the composite billet to a diameter reduction process to form a composite wire having a fan-like section, arranging composite wires so that larger arcs of the composite wires are located on the outer side, thus forming form a composite wire arrangement, covering the composite wire arrangement with a metal member to form a metal-covered composite wire arrangement, and performing a predetermined heating process of the metal-covered composite wire arrangement, thus forming the raw material into an oxide superconductor.

Abstract: A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermediate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

Abstract: A strain tolerant multifilamentary wire capable of carrying superconducting currents is provided comprising a plurality of discontinuous filaments formed from a high temperature superconducting material. The discontinuous filaments have a length at least several orders of magnitude greater than the filament diameter and are sufficiently strong while in an amorphous state to withstand compaction. A normal metal is interposed between and binds the discontinuous filaments to form a normal metal matrix capable of withstanding heat treatment for converting the filaments to a superconducting state. The geometry of the filaments within the normal metal matrix provides substantial filament-to-filament overlap, and the normal metal is sufficiently thin to allow supercurrent transfer between the overlapped discontinuous filaments but is also sufficiently thick to provide strain relief to the filaments.

Abstract: An oxide superconducting layer is formed on a base material of silver, whose single side is coated with MgO, or single-crystalline MgO for depositing a Bi.sub.2 Sr.sub.2 Ca.sub.2 Cu.sub.3 phase in a crystallographically oriented state by sputtering, CVD or laser ablation. Metal lead or lead oxide is then laid thereon by sputtering to obtain a two-layer structure, and the two-layer structure is heat treated in the atmospheric air. Thus, a bismuth oxide superconducting film, which is excellent in crystal orientation as well as denseness and thereby having high critical current density, is formed on the base material.

Abstract: Superconducting device include a type having a structure of a superconductor--a normal-conductor (or a semiconductor)--a superconductor, and a type having a superconducting weak-link portion between superconductors.The superconductors constituting the superconducting device are made of an oxide of either of perovskite type and K.sub.2 NiF.sub.4 type crystalline structures, containing at least one element selected from the group consisting of Ba, Sr, Ca, Mg, and Ra; at least one element selected from the group consisting of La, Y, Ce, Sc, Sm, Eu, Er, Gd, Ho, Yb, Nd, Pr, Lu, and Tb; Cu; and O. In addition, the c-axis of the crystal of the superconductor is substantially perpendicular to the direction of current flowing through this superconductor.

Abstract: A superconductive conductor or cable comprising a core, which comprises at least one string of a ceramic, superconductive material, and where the core is encapsulated by a metal cap. In order to manufacture a conductor or a cable with an encapsulation, and in which it is possible as well during the manufacturing process as under the operation to maintain a controlled atmosphere around the superconductive core, at least one layer of not sintered, ceramic powderous material is provided between the cap and the core, which material has a higher sintering temperature than the superconductive material in the core. The superconductive core may be sintered for formation of the superconductive ceramics by placing in the tubular metal cap a starting material in powderous form, and shaped as a core in the other ceramic powder material and subsequently forgeing the the metal cap with its content, preferably by swaging at an ambient temperature, which is below the sintering temperature of the core.

Abstract: A high-temperature oxide superconductor is provided and comprises oxide crystals oriented in a certain direction, the oxide superconductor being substantially free of or containing a controlled amount of foreign phases, a non-superconducting phase and weak superconducting phase which are harmful for superconducting characteristics in the grains of the crystals and at the grain boundaries between the crystals. The foreign phases, if any, are finely and uniformly dispersed in the grains of the oxide crystals and at the grain boundaries. A wire made from the oxide superconductor, a coil from the wire, and a magnetic field generator from the coil are disclosed, the superconductor wire having only a single layer of oxide crystal grains in the thickness direction.

Abstract: A method of fabricating a superconductive flexible conductor having a high critical temperature in which method a deposit of superconductive ceramic is applied to a metal tape of thickness lying in the range 0.1 mm to 1 mm, wherein:the deposit of thickness lying in the range 50 .mu.m to 300 .mu.m and of concentration by volume of not less than 70% runs through an infrared beam at a speed of not less than 5 cm per minute, the zone treated by the the beam having a width of less than 10 mm relative to the travel direction and a surface temperature of not less than 1200.degree. C., thereby imparting a surface superconductive layer to the deposit which is of concentration by volume close to 100%, which is textured in the travel direction, and which is of thickness lying in the range 10 .mu.m to 100 .mu.m; andannealing is then performed under oxygen.

Abstract: In an oxide superconducting film wiring, when the line width is reduced, the evaporation of a component during firing becomes so vigorous that it becomes impossible to form a desired single crystal phase, which causes a significant lowering in the properties of the oxide superconducting wiring. This problem can be solved by preventing the evaporation of the evaporable component during the firing. Examples of this include a process wherein plate is placed above the superconductor forming material film wiring pattern on the substrate so as to face each other, the plate comprising a material having no chemical influence on the superconducting wiring, and a pattern of a material containing an evaporable component is arbitrarily formed, a process wherein a pattern having a smaller line width is sandwiched between patterns having a larger line width, and a process wherein the firing atmosphere or the concentration of the evaporable component in the pattern is varied depending upon the line width.

Abstract: An oxide superconductive wire is provided by, for example, forming an oxide superconductive layer on a tape-type flexible base. A preliminary compressive strain is applied to the oxide superconductive layer in the longitudinal direction. The remaining strain can be provided by using a base having thermal expansion coefficient larger than that of the oxide superconductive layer and by cooling the same after heat treatment, due to contraction of the base. Since the preliminary compressive strain is applied to the oxide superconductive layer, degradation of superconductivity of the oxide superconductive layer can be suppressed even if the oxide superconductive wire is bent in any direction, compared with the wire without such strain. Therefore, the oxide superconductive wire can be coiled, for example, without much degrading the superconductivity.

Abstract: An elongated, flexible superconductive wire or strip is fabricated by pulling it through and out of a melt of metal oxide material at a rate conducive to forming a crystalline coating of superconductive metal oxide material on an elongated, flexible substrate wire or strip. A coating of crystalline superconductive material, such as Bi.sub.2 Sr.sub.2 CaCu.sub.2 O.sub.8, is annealed to effect conductive contact between adjacent crystalline structures in the coating material, which is then cooled to room temperature. The container for the melt can accommodate continuous passage of the substrate through the melt. Also, a second pass-through container can be used to simultaneously anneal and overcoat the superconductive coating with a hot metallic material, such as silver or silver alloy. A hollow, elongated tube casting method of forming an elongated, flexible superconductive wire includes drawing the melt by differential pressure into a heated tubular substrate.

Abstract: Disclosed herein is a ceramic superconductor comprising a ceramic superconductive member, and a high-conductivity metal layer covering the ceramic superconductive member. At least one portion of the metal layer having low electrical conductivity or low thermal conductivity. Also disclosed is a method of manufacturing a ceramic superconductor, comprising the steps of filling a ceramic superconductor or a precursor thereof in a high-conductivity metal pipe, thereby forming a composite member, rolling the composite member into a ceramic superconductor element of a desired shape, which comprises a ceramic superconductive member and a high-conductivity metal layer covering the ceramic superconductive member, performing a predetermined heat treatment on the ceramic superconductor element, and alloying a predetermined portion of the high-conductivity metal layer, thereby rendering the portion less conductive either electrically or thermally.

Abstract: An improved electric device utilizing a superconducting material. In order to avoid undesirable oxidation during firing of a ceramic to be superconducting material formed on the substrate, the superconducting material is provided only on the position in which the superconducting material does not contact the operational region of said semiconductor substrate.

Abstract: A method for producing an oxide superconducting composite wire is disclosed, which comprises the steps of: (a) molding a powdered oxide superconductor material to form a wire; (b) heat treating the wire in an oxygen atmosphere thereby forming the wire into an oxide superconducting member; (c) forming a non-oxidizing metal intermediate layer on a surface of the oxide superconducting member; (d) bundling a plurality of the oxide superconducting members containing the intermediate layer; (e) inserting the bundled oxide superconducting members into an oxidizing metal support tube; and (f) drawing the product of step (e) to reduce its diameter and heat-treating it.

Abstract: A method of manufacturing a component of the tape or filament kind out of a material based on a superconducting oxide having a high critical temperature, wherein said material is formed while it is in the vitreous state,the method being characterized by the fact that the material is subsequently crystallized:in a first step under a magnetic field and at a temperature T.sub.l lying between the vitreous transition temperature T.sub.g and the crystallization temperature T.sub.x, during which step isolated microcrystallites of submicroscopic size develop and their c axes orient themselves parallel to one another because of said applied magnetic field; andin a second step at a temperature T.sub.2 close to the crystallization temperature, in which the existing nuclei grow while retaining the texture imparted to them during said first step.

Abstract: An alloy having a low reactivity towards certain high temperature superconducting materials at temperatures up to about 10.degree. C. lower than the melting point of the alloy. The alloy is a ternary silver-based alloy consisting, by weight, of 0.5-9% palladium, 20-40% gold, balance silver. Using the alloy and a superconducting material of the type R-Ba-Cu-O, where R is yttrium or a rare earth element, composite conductors can be formed at temperatures equal or higher than the temperature of peritectic decomposition of the superconductor. The alloy may also be used as a buffer layer or cladding material on substrates having unacceptably high reactivity towards the superconducting material.

Abstract: A method of manufacturing a superconducting ceramics elongated body by forming a longitudinally continuous superconducting layer on at least a part of the surface of a flexible ceramics elongated substrate by evaporation under the presence of oxygen ions.

Abstract: A method of making a composite high-temperature superconducting wire in which a layer of a superconductive oxide is coated onto a refractory core by melting a zone of the layer uniformly all around the core as the core is drawn through the focus of a reflector having the shape of a paraboloid of revolution while directing onto the reflector a collimated beam of an energy sufficient to melt the layer. The melted layer is cooled with a substantially radially symmetrical thermal gradient to form the superconducting oxide ceramic layer on the core with radially-directed growth of columnar grains of the superconducting oxide ceramic.

Abstract: A superconductive ceramic wire material composed of rare earth elements, alkali earth metals, copper, and oxygen, which is obtained by mixing a powder containing oxides of the component elements of the superconductive ceramic with a solution containing organic compounds of the component elements, forming the mixture into a wire, and firing the wire in a temperature range from 850.degree. to 949.degree. C. in an oxygen-containing atmosphere.

Abstract: A high temperature superconducting wire or yarn has a first layer thereon yttria, a third layer of barium cuprate, and a second layer of a superconducting YBa.sub.2 Cu.sub.3 O.sub.7-x formed at the interface between the first and third layers. The wire can be yttrium and the yarn can be alumina.

Abstract: The present invention relates to a method of producing a superconducting composite wire. The method comprises forming a continuously supplied metal or metal alloy strip into a flume-shaped strip. A ceramic copper oxide superconducting powder material is filled in the interior of the flume-shaped strip. The flume-shaped strip is rolled such that a first edge of the strip approaches a second edge of the strip to form a tubing having a gap between the first and second edges and also having the powder material enveloped therein. The gap allows free access of oxygen to the powder material during a subsequent sintering step. The powder material is then sintered at a temperature of between 0 and 100.degree. C. less than the lowest melting point of any constituent of the material. The strip enveloping the sintered material is then deformed to a reduced cross-section and subjected to a heat treatment.

Abstract: Improvement in a superconducting thin film of compound oxide represented by the formula: LnBa.sub.2 Cu.sub.3 O.sub.7- .delta. (Ln is lanthanide) or (La.sub.1-x .alpha..sub.x).sub.2 CuO.sub.4 (.alpha. is Ba or Sr) deposited on a substrate or core made of MgO, SrTiO.sub.3 or ZrO.sub.2 by physical vapor deposition technique, the surface roughness R.sub.max (datum length=1,000 .mu.m) of the superconducting thin film being less than 0.2 .mu.m.

Abstract: A pseudo rod, fabricated from several plate sections joined together at their edges and having a cross-section resembling a polygon approximates a rod having a circular cross section. Using multiple plates joined at their edges permits growing a crystalline material on the planar faced substrates and if the plates are crystalline material, the crystalline material grown thereon can have improved current carrying capability.

Abstract: In order to prepare an elongated oxide superconducting material which exhibits a high critical current density, a tape-type substrate (7) of silver, for example, formed by unidirectional solidification is prepared and an excimer laser beam (9) is applied to target (8) of an oxide superconductor to deposit atoms and/or molecules being scattered from the target (8) on the substrate (7), thereby forming an oxide superconducting film on the substrate (7).

Abstract: A superconducting conductor assembly using high temperature materials. A double-walled tubular structure has at least one helical strip of superconductive material on the inner wall of the inside tube. Brittle, non-ductile superconducting materials may be used. A coolant, typically liquid nitrogen, is circulated between the tubes to maintain the superconductor below the critical temperature of the superconductor. A buffer layer is preferably included between tube wall and superconductor. A plurality of alternating layers of buffer and superconductor may be used.

Abstract: The present invention relates to a sintered oxide superconducting wire and a method of fabricating the same. The sintered superconducting wire is made by packing powders of metal oxides, or a mixture of metal oxides and metal carbonates, each having an oxidation potential (.DELTA.G.degree.) higher than or equal to that of copper in a metallic cylinder, drawing said packed cylinder and sintering said drawn cylinder in air to form said wire.

Abstract: There is provided a method of producing a protective metal coated or covered superconducting ceramic wire by applying a finely pulverized protective metal-dispersed polymeric resin onto the surface of a glass wire in amorphous state of metal oxides capable of being converted into superconductive ceramic, heating the wire to remove the polymeric resin therefrom to obtain the wire having a metal powder coating thereon, and heat-treating the wire to become superconductive. The coating is easily conducted without damaging the excellent productivity of the so-called melt-quenching and preform wire-drawing process for producing a superconducting ceramic wire.

Abstract: A superconductor structure having a substrate, the substrate defining a surface. Applied to the surface of the substrate is a barrier layer. Applied to the barrier layer is a layer of superconductive material comprising copper and oxygen. The barrier layer serves to prevent the interaction of the superconductive material with the substrate, thus destroying the stoichiometry of the superconductive material and resulting in a loss or decrease in superconductivity. A protective layer is, optionally, applied to the layer of superconductive material.

Abstract: A superconducting ceramics elongated body comprising a flexible ceramics elongated substrate and an oxide ceramics superconducting layer formed at least on a part of the surface of the ceramics elongated substrate to longitudinally extend along the ceramics elongated substrate. The superconducting ceramics elongated body further comprises a protective layer of ceramics containing a nitride, which is provided to at least cover the surface of the superconducting layer exposed on the ceramics elongated substrate. A method of manufacturing a superconducting ceramics elongated body by forming a longitudinally continuous superconducting layer on at least a part of the surface of a flexible ceramics elongated substrate. The superconducting layer is formed on the elongated substrate by a sol-gel method, a coating/sintering method, evaporation under oxygen ions, deposition from a fluoride solution or oxidation after application of corresponding fluorides.

Abstract: The structures for confining or guiding high frequency electromagnetic radiation have surfaces facing the radiation constructed of high temperature superconducting materials, that is, materials having critical temperatures greater than approximately 35.degree. K. The use of high temperature superconductors removes the constraint of the relatively low energy gaps of conventional, low temperature superconductors which precluded their use at higher frequencies. The high temperature superconductors also provide larger thermal margins and more effective cooling. Devices which will benefit from the structures of the invention include microwave cavities, millimeter-wave/far infrared cavities, gyrotron cavities, mode converters, accelerators and free electron lasers, and waveguides.

Abstract: A high temperature superconducting wire and an improved process of making the same wherein a metal wire chosen from the group consisting of: Y; Sm; Eu; Gd; Dy; Ho; Er; Tm; Yb; and Lu is oxidized and the oxidized metal wire is then coated with molten barium-copper-oxide. The process allows high-quality superconducting wire to be easily and continuously fabricated.

Abstract: A method of the production of the ceramic superconductor filament comprisesa step including mixing raw materials of ceramic superconductor, subsequently shaping the mixed ceramic superconductor into a ceramic superconductor body of a predetermined shape and preliminarily sintering thereof and further subsequently crushing the sintered ceramic superconductor body into ceramic superconductor powder;a step of filling the ceramic superconductor powder in a glass tube;a step of heating the glass tube including ceramic superconductor powder so that the ceramic superconductor powder is molten; anda step of spinning the glass tube including the ceramic superconductor materialwhereby a ceramic super conductor covered with the glass material can be obtained.

Abstract: Process for the production of an elongate body of longitudinally aligned acicular crystals (3) of the superconducting substance REBa.sub.2 Cu.sub.3 O.sub.6.5+y, with RE=rare earth metal, 0<y<1, in which fine-grained powder (1) with a particle diameter of 0.1-5 .mu.m is sintered for 1-100 h at a temperature of 600.degree.-850.degree. C. with application of a pressure of 100-5,000 bar. For the production of a filament conductor, the powder is filled into a small Ag tube (4), drawn, and pressure sintered at 800.degree. C./10 h under 2,000 bar.

Abstract: A method of manufacturing a superconducting wire consisting essentially of mixing superconducting ceramic powders selected from a group selected from a group consisting of Y-Sr-Cu-O, Y-Ba-Cu-O, La-Sr-Cu-O, La-Ba-Cu-O and Bi-Sr-Ca-Cu-O with metal powder, filling the mixture in a metal pipe and forming the mixture into wire by at least one of extrusion, drawing and swaging. The resulting wire would have superconductivity which is not reduced upon distortion by external stress.

Abstract: The present invention relates to a sintered ceramic superconducting wire which is made by placing powders of metal oxides or a mixture of powders of metal oxides and metal carbonates, said oxides and said carbonates each having an oxidation potential higher than or equal to that of copper, in a metallic cylinder formed from a high temperature oxidation-resistant material, and drawing the packed cylinder to a final size and sintering said drawn packed cylinder in air, wherein said cylinder is removed prior or subsequent to the final step of sintering.

Abstract: An improved ceramic-plus-metal superconducting composition of YBa.sub.2 Cu.sub.3 O.sub.6+x plus substantially pure aluminum for ultimate use in making superconducting devices such as wires and tapes for utilization in motors, generators, electric circuits, etc.

Abstract: Monocrystalline ceramic fibers are disclosed together with a process for preparing such fibers. Polycrystalline ceramic fibers in a tow are coated with a coating that is chemically substantially non-reactive with the ceramic (e.g. alumina fibers coated with molybdenum), and the coated fibers are drawn through a heating zone maintained at a temperature high enough to melt the fibers without melting the coating. The coated fibers are withdrawn from the heating zone and cooled rapidly enough to form a substantially monocrystalline ceramic. The protective coating may thereafter be removed to leave a tow of substantially single-crystal ceramic fibers. Monocrystalline ceramic fibers about 8-20 microns in diameter are prepared by the disclosed process.

Abstract: A process for joining ceramic superconductor fibers with a channel to fabricate a superconductor wire includes concertedly drawing the fibers and the channel together to feed the fibers into the channel. A flowable solder paste is continuously dispensed into the channel over the fibers. The combination of channel, fibers and solder paste is then subjected to a rapid rise in temperature which melts the solder. The molten solder is then frozen to encase the fibers in the solder and attach the solder to the channel to create a superconductor wire.

Abstract: Disclosed here is a shaped article superconductor comprising platelets of superconducting oxide crystals which are normally anisotropic but in which said anisotropy is reduced by joining together the oxides superconductor crystallites with a normally conductive metal layer interposed therebetween. The separation distances of the platelets are, on the average, less than the coherence length of the normally conductive metal under conditions which render the oxide crystals superconductive.

Abstract: The present invention relates to a ceramics sintered wire.Ceramics materials, such as AlN, Si.sub.3 N.sub.4 and Al.sub.2 O.sub.3, have various kinds of superior characteristic including the heat-resistance and sintered ceramics materials have been watched with interest as superconducting materials having high critical temperatures.However, various kinds of disadvantage have been pointed out for the formation of the sintered ceramics materials in the form of thin wire and the practical use thereof.The present invention eliminates such disadvantages to provide a thin and long ceramics sintered wire having a sufficient strength and toughness to an extent of avoiding the breakage.

Abstract: A strain tolerant microfilamentary wire capable of carrying superconducting currents is provided comprising a plurality of discontinuous filaments formed from a high temperature superconducting material. The discontinuous filaments have a length at least several orders of magnitude greater than the filament diameter and are sufficiently strong while in an amorphous state to withstand compaction. A normal metal is interposed between and binds the discontinuous filaments to form a normal metal matrix capable of withstanding heat treatment for converting the filaments to a superconducting state. The geometry of the filaments within the normal metal matrix provides substantial filament-to-filament overlap, and the normal metal is sufficiently thin to allow supercurrent transfer between the overlapped discontinuous filaments but is also sufficiently thick to provide strain relief to the filaments.

Abstract: A method of making a ribbon-like or sheet-like superconducting composite body is disclosed. The method is well suited for making long lengths (e.g.,>100m) of ribboon or large areas (e.g.,>100cm.sup.2) of sheet-like composite. The method comprises forming a Bi-Sr-Ca-Cu-oxide-containing layer on a metal (exemplarily Ag) substrate, and mechanically deforming (typically by rolling) the thus formed composite such that the oxide is densified to more than 80% of the theoretical density. Subsequently the oxide layer is at least partially melted and allowed to re-solidify such that a large portion of the oxide crystals has c-axis alignment. After appropriate heat treatment in an O.sub.2 -containing atmosphere, thus produced superconductor ribbons or sheets can have high J.sub.c).gtoreq.10.sup.4, frequently >10.sup.5 A/cm.sup.2) for temperatures less than about 20K and in magnetic fields less than about 5T.

Abstract: A superconductive transmission line is formed of mixed metallic oxide ceramic material, particularly Y.sub.1 Ba.sub.2 Cu.sub.3 O.sub.7-x drawn epitaxially upon a substrate. The superconductive material has basal crystallographic planes in alignment with copper oxide of the ceramic material. The planes are parallel to the substrate. The transmission line is constructed of a plurality of electrically conductive elements, each of which is formed of the superconductive material. The conductive elements are arranged with the crystalline planes parallel to an axis of the transmission line, along which axis power is to flow. Thereby, magnetic fields induced by currents flowing in the conductive elements intersect the conductive elements perpendicularly to the basal crystallographic planes to maximize the current which can flow while retaining linearity between magnetization and applied magnetic field.

Abstract: An electrical conductor particularly suited for use as a downlead to low temperature devices includes a ceramic honeycomb body having longitudinal channels wherein films of substantially single crystals of a ceramic superconductor are grown. The maximum current carrying capacity of the ceramic superconductor may be oriented parallel to the channels. Square channels arranged in alternating rows of oppositely directed current provide desirable magnetic field cancellations and permit high current flows. A method for making the electrical conductor and a method of extruding the ceramic honeycomb body are also disclosed.

Abstract: Bi-based superconducting ceramic films having high Tc's and high critical current densities are formed. The superconducting film is formed on a non-superconducting saubstrate of Bi.sub.2 Sr.sub.1-x Ca.sub.x O.sub.y. Due to crystalline similarity between the superconducting film and the underlying ceramic substrate, the crystalline structure of the film is improved. There are few impurities which contaminate the superconducting film since the constituent elements of the substrate are also the consitutents of the superconducting film.

Abstract: A superconducting composite comprising a compound oxide type superconductor and an outer metal pipe on which said superconductor is supported, characterized in that (i) said outer metal pipe is made of at least one of metals selected from a group comprising gold, silver and platinum metals and their alloys or (ii) an intermediate layer made of these precious metals is interposed between the compound oxide and the metal pipe.The composite may be in a form of a solid pipe or a hollow pipe having a superconducting thin layer deposited on an inner surface of the metal pipe.

Abstract: A process for extruding a superconducting metal oxide composition YBa.sub.2 Cu.sub.3 O.sub.7-x provides a wire (tube or ribbon) having a cohesive mass and a degree of flexibility together with enhanced electrical properties. Wire diameters in the range of 6-85 mils have been produced with smaller wires on the order of 10 mils in diameter exhibiting enhanced flexibility for forming braided, or multistrand, configurations for greater current carrying capacity. The composition for extrusion contains a polymeric binder to provide a cohesive mass to bind the particles together during the extrusion process with the binder subsequently removed at lower temperatures during sintering. The composition for extrusion further includes a deflocculent, an organic plasticizer and a solvent which also are subsequently removed during sintering. Electrically conductive tubing with an inner diameter of 52 mil and an outer diameter of 87-355 mil has also been produced.