Organic Component Is Carbohydrate Or Derivative Thereof (e.g., Sugar Or Gum, Such As Galactomannan, Xanthan, Etc.) Or Carboxylic Acid Ester Of An Alcohol Which Has Five Or More Hydroxy Groups Bonded Directly To Carbons Patents (Class 507/110)
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Patent number: 11634622Abstract: A method of treating a fluid, which method includes the steps of: (a) contacting a fluid containing at least one sulfide with a sulfide-reducing amount of a composition comprising an lignocellulosic liquor comprising one or more lignin-derived compounds and one or more hemicellulose sugar monomers and/or oligomers and (b) allowing the lignocellulosic liquor to react with at least a portion of the sulfide in the fluid.Type: GrantFiled: March 8, 2018Date of Patent: April 25, 2023Assignee: RHODIA POLIAMIDA E ESPECIALIDADES S.A.Inventors: Eder Rissi Torres, Edson Leme Rodrigues, Victor Ferrão
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Patent number: 11618847Abstract: The present disclosure discloses methods for preparing an in-situ nano emulsifier. The preparation method may include obtaining a solution by dissolving hydrated ferric chloride (or ferric chloride) and hydrated ferrous sulfate (or ferrous sulfate) into deionized water at a first temperature; obtaining an ethanol solution dissolved with an oil-soluble surfactant by dissolving an oil-soluble surfactant into ethanol at a second temperature; and adding a certain volume of ammonia water and the ethanol solution dissolved with the oil-soluble surfactant in the solution to obtain an in-situ nano emulsifier. The in-situ nano emulsifier may be applied to development of the oil reservoir through an application process. The application process may include preparing a nano emulsifier solution and a surfactant solution; sequentially injecting the surfactant solution and the nano emulsifier solution into a formation; and injecting a spacer liquid slug into the formation for replacement.Type: GrantFiled: April 20, 2021Date of Patent: April 4, 2023Assignee: SOUTHWEST PETROLEUM UNIVERSITYInventors: Wanfen Pu, Xing Zhao, Rui Liu, Lin Sun, Daijun Du
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Patent number: 11542424Abstract: A method of servicing a wellbore penetrating a subterranean formation, the method including placing a wellbore servicing fluid into the wellbore proximate a permeable zone. The wellbore servicing fluid comprises a base fluid and from about 3 wt. % to about 25 wt. % by total weight of the wellbore servicing fluid of a particulate material. The particulate material comprises palm kernel shells.Type: GrantFiled: December 9, 2021Date of Patent: January 3, 2023Assignee: Halliburton Energy Services, Inc.Inventors: Kingsley Ihueze Nzeadibe, Shubhajit Ghosh
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Patent number: 11414511Abstract: The invention discloses a carboxymethyl inulin graft polymer scale and corrosion inhibitor and a preparation method thereof. The main chain of the carboxymethyl inulin graft polymer scale and corrosion inhibitor consists of the following repeating unit (I): in the repeating unit (I), x:y=(20˜80):(20˜80); the range of z is from 2 to 70, the degree of carboxymethyl substitution is from 1.5 to 2.5. The beneficial effect of the technical scheme proposed in the present invention is: it has excellent scale inhibition and corrosion inhibition properties; the monomers are cheap and easily available; the reaction conditions are mild and easy to control; at the same time, the monomer raw materials don't contain phosphorus and nitrogen, and are environmentally friendly.Type: GrantFiled: April 30, 2020Date of Patent: August 16, 2022Assignees: YANGTZE UNIVERSITY, PETROCHINA COMPANY LIMITEDInventors: Weichu Yu, Aibin Wu, Jingfeng Dong, Zhenhu Lyu, Zhichen Wang, Fengjuan Zhang
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Patent number: 11230657Abstract: A water-based wellbore fluid may include an aqueous base fluid and a modified graphene shale inhibitor that comprises one or more substituents that are covalently bonded to graphene via a linking group. One of the one or more substituents may be a hydrocarbon group that has a number of carbon atoms in the range from 8 to 14.Type: GrantFiled: March 2, 2020Date of Patent: January 25, 2022Assignees: SAUDI ARABIAN OIL COMPANY, KING FAHD UNIVERSITY OF PETROLEUM & MINERALSInventors: Tawfik Abdo Saleh, Mohammed Khalid Al-Arfaj, Azeem A. Rana
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Patent number: 10947434Abstract: A method including providing a drilling fluid that comprises a base fluid, a weighting agent, and a sag stability enhancer, wherein the sag stability enhancer comprises polyethylene glycol (PEG) having a molecular weight of greater than or equal to about 200 g/mol; and placing the drilling fluid in a subterranean formation via a wellbore penetrating the subterranean formation. A method including forming a fluid comprising a base fluid, a weighting agent, and from about 0.5 ppb (1.4 kg/m3) to about 30 ppb (85.5 kg/m3) of a sag stability enhancer, wherein the sag stability enhancer comprises a glycol; and introducing the fluid into at least a portion of a well. A drilling fluid containing a base fluid, a weighting agent, and a sag stability enhancer comprising polyethylene glycol (PEG) having a molecular weight of greater than or equal to about 200 g/mol.Type: GrantFiled: March 16, 2020Date of Patent: March 16, 2021Assignee: HALLIBURTON ENERGY SERVICES, INC.Inventors: Chesnee Lae Davis, Philip Wayne Livanec, William Walter Shumway
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Patent number: 10946112Abstract: Methods include producing a gelled sanitizer composition, including preparing a hydrating fluid composition including water and one or more of alcohol and peroxide; preparing a hydratable additive; and combining the hydrating fluid composition and the hydratable additive to produce a gelled composition. Methods also include flowing a hydrating liquid composition in an extensional flow regime through an elongated passageway of an extender, wherein the hydrating liquid composition includes water and a C2-C10 solvent, and a flow rate of the hydrating liquid composition and a diameter of the elongated passageway are sufficient to achieve a Reynolds number of 20,000 or greater; and adding a hydratable additive to the hydrating liquid composition in the elongated passageway to produce a mixture comprising the hydratable additive that is at least partially hydrated.Type: GrantFiled: July 7, 2020Date of Patent: March 16, 2021Assignee: PfP Industries, LLCInventors: Asoke Kumar Deysarkar, Michael Joseph Callanan, IV, Robert Ray McDaniel, Brian James Keola DeCaires
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Patent number: 10829679Abstract: A micro-nanometer plugging anti-collapse drilling fluid and fracturing method and use thereof.Type: GrantFiled: January 15, 2020Date of Patent: November 10, 2020Assignee: SOUTHWEST PETROLEUM UNIVERSITYInventors: Yang Bai, Pingya Luo, Cheng Li, Yan Cheng, Guojun Li, Hao Zhang
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Patent number: 10703963Abstract: A method includes flowing a hydrating liquid in an extensional flow regime through an elongated passageway of an extender, wherein a flow rate of the hydrating liquid and a diameter of the elongated passageway are sufficient to achieve a Reynolds number of 20,000 or greater. A hydratable additive is added to the hydrating liquid in the elongated passageway to produce a mixture comprising the hydratable additive that is at least partially hydrated.Type: GrantFiled: August 30, 2019Date of Patent: July 7, 2020Assignee: PfP Industries, LLCInventors: Asoke Kumar Deysarkar, Michael Joseph Callanan, IV, Robert Ray McDaniel, Brian James Keola DeCaires
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Patent number: 10647906Abstract: Compositions may include a wax modifier that is the product of a reaction between a polysaccharide having a number of sugar subunits in the range of 2 to 60 and one or more fatty acid reagents, and a reservoir fluid produced from a subterranean formation comprising one or more components capable of producing waxes. Methods may include contacting a hydrocarbon fluid with a wax modifier, wherein the wax modifier is the product of the reaction of a polysaccharide and one or more fatty acid reagents. Methods may also include introducing a wax modifier into a wellbore penetrating a subterranean formation, wherein the wax modifier is the product of a reaction between a polysaccharide and one or more fatty acid reagents; producing hydrocarbons from the subterranean formation; and allowing the wax modifier to inhibit the precipitation of a wax.Type: GrantFiled: December 11, 2017Date of Patent: May 12, 2020Assignee: M-I L.L.C.Inventors: Pradyumna Avinash Deshpande, Chandrashekhar Yeshwant Khandekar
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Patent number: 10435614Abstract: A method of modifying an alteration zone of a formation near a wellbore using a non-Newtonian polymeric composition created from a reaction of a non-Newtonian combination comprises the steps of mixing an anhydrous tetraborate and a fluid to create a crosslinker solution, mixing a crosslinkable polyvinyl alcohol and water to create a polymer solution, where the crosslinker solution and the polymer solution form the non-Newtonian combination, pumping the non-Newtonian combination to a reaction zone in the wellbore, where pumping the non-Newtonian combination is configured to induce mixing of the polymer solution and the crosslinker solution, allowing the non-Newtonian combination to react to form the non-Newtonian polymeric composition, allowing the non-Newtonian polymeric composition to migrate to the alteration zone, where the non-Newtonian polymeric composition migrates due to gravity, and allowing the non-Newtonian polymeric composition to interact with the alteration zone to modify the alteration zone.Type: GrantFiled: May 16, 2019Date of Patent: October 8, 2019Assignee: Saudi Arabian Oil CompanyInventor: Abeer Mohammad Al-Olayan
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Patent number: 10435615Abstract: A method of modifying an alteration zone of a formation near a wellbore using a non-Newtonian polymeric composition created from a reaction of a non-Newtonian combination comprises the steps of mixing an anhydrous tetraborate and a fluid to create a crosslinker solution, mixing a crosslinkable polyvinyl alcohol and water to create a polymer solution, where the crosslinker solution and the polymer solution form the non-Newtonian combination, pumping the non-Newtonian combination to a reaction zone in the wellbore, where pumping the non-Newtonian combination is configured to induce mixing of the polymer solution and the crosslinker solution, allowing the non-Newtonian combination to react to form the non-Newtonian polymeric composition, allowing the non-Newtonian polymeric composition to migrate to the alteration zone, where the non-Newtonian polymeric composition migrates due to gravity, and allowing the non-Newtonian polymeric composition to interact with the alteration zone to modify the alteration zone.Type: GrantFiled: May 16, 2019Date of Patent: October 8, 2019Assignee: Saudi Arabian Oil CompanyInventor: Abeer Mohammad Al-Olayan
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Patent number: 10308861Abstract: A method of electrically logging a section of a wellbore includes circulating a wellbore fluid within the wellbore, the wellbore fluid including a base fluid; and a crosslinked and branched polymeric fluid loss control agent formed from at least an acrylamide monomer and a sulfonated anionic monomer; wherein the fluid loss control agent has an extent of crosslinking that is selected so that the fluid loss control agent has a viscosity that is within a peak viscosity response of the viscosity response curve; placing within the wellbore a wellbore logging tool capable of applying an electrical current to the wellbore; applying electrical current from the logging tool; and collecting an electrical log of the portion of the wellbore that has had electrical current applied thereto.Type: GrantFiled: January 6, 2017Date of Patent: June 4, 2019Assignee: M-I L.L.C.Inventors: Balakrishnan Panamarathupalayam, Amr Essawi
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Patent number: 10280360Abstract: A well treatment microemulsion includes an oil external phase, an internal aqueous phase and a hydrophilic surfactant. The surfactant has a hydrophile lipophile balance of between 8-18. The oil external phase may include d-Limonene, xylenes, light mineral oil, or kerosene. The surfactant is configured to emulsify the water of the internal aqueous phase into the oil of the external (continuous) phase. The surfactant may include polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tristearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monolaurate or mixtures therebetween. The use of hydrophilic surfactants to emulsify an internal aqueous phase within an oil external microemulsion produces unexpected and beneficial results.Type: GrantFiled: November 23, 2015Date of Patent: May 7, 2019Assignee: Flotek Chemistry, LLCInventors: Lakia M. Champagne, David S. Morrison
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Patent number: 10227846Abstract: Fouling caused by contaminants onto a metallic tubular, flow conduit or vessel in an underground reservoir or extending from or to an underground reservoir may be inhibited by applying onto the surface of the metallic tubular, flow conduit or vessel a treatment agent comprising a hydrophobic tail and an anchor. The anchor attaches the treatment agent onto the surface of the metallic tubular, flow conduit or vessel.Type: GrantFiled: September 19, 2014Date of Patent: March 12, 2019Assignee: Baker Hughes, a GE company, LLCInventors: Terry D. Monroe, Naima Bestaoui-Spurr, Sumit Bhaduri, Qi Qu
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Patent number: 9688902Abstract: Increasing the dispersed phase concentration in drilling fluids may decrease sag in the drilling fluids. The dispersed phase of a drilling fluid may be composed of solids (e.g., weighting agents) and emulsion droplets (for emulsified drilling fluids) dispersed in the continuous phase. For example, an exemplary drilling fluid may include a base fluid and a dispersed phase that includes at least one of: extremely low gravity solids, low gravity solids, high gravity solids, or emulsion droplets; wherein the drilling fluid has a density of about 5 pounds per gallon to about 25 pounds per gallon and has a disperse solids volume fraction greater than or equal to 0.35 and/or has a disperse phase volume fraction greater than or equal to 0.5.Type: GrantFiled: June 1, 2015Date of Patent: June 27, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Sandeep D. Kulkarni, Dale E. Jamison, Dhanashree Gajanan Kulkarni
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Patent number: 9611420Abstract: A composition including: (a) an aqueous phase; (b) a chitosan-based compound dispersed or dissolved in the aqueous phase; and (c) a crosslinker dispersed or dissolved in the aqueous phase, wherein the crosslinker has at least two functional groups independently selected from the group consisting of aldehyde, carboxylic acid, and carboxylate. A method including the step of introducing a composition according to the invention into a treatment zone of a well.Type: GrantFiled: May 6, 2013Date of Patent: April 4, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Shoy C. George, Prajakta Ratnakar Patil, Prasanta Das
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Patent number: 9410073Abstract: The present invention generally relates to one or more compositions and methods for inhibiting the formation of gas hydrate agglomerates in a fluid. The fluid may be contained, for example, in an oil or gas pipeline or refinery.Type: GrantFiled: November 26, 2013Date of Patent: August 9, 2016Assignee: Ecolab USA Inc.Inventors: Peter A. Webber, Sahana Nagappayya
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Patent number: 9222013Abstract: A well treatment microemulsion includes an oil external phase, an internal aqueous phase and a hydrophilic surfactant. The surfactant has a hydrophile lipophile balance of between 8-18. The oil external phase may include d-Limonene, xylenes, light mineral oil, or kerosene. The surfactant is configured to emulsify the water of the internal aqueous phase into the oil of the external (continuous) phase. The surfactant may include polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan tristearate, polyoxyethylene hydrogenated castor oil, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monolaurate or mixtures therebetween. The use of hydrophilic surfactants to emulsify an internal aqueous phase within an oil external microemulsion produces unexpected and beneficial results.Type: GrantFiled: November 13, 2009Date of Patent: December 29, 2015Assignee: CESI Chemical, Inc.Inventors: Lakia M. Champagne, David S. Morrison
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Patent number: 9145747Abstract: A method of mixing drilling fluids, the method including injecting a drilling fluid into a high shear mixing unit and processing the drilling fluid with the high shear mixing unit. The processing includes forcing the drilling fluid through a first row of teeth of a first stage.Type: GrantFiled: November 24, 2009Date of Patent: September 29, 2015Assignee: M-I L.L.C.Inventors: Mukesh Kapila, Paul Newman, Katerina Newman, Perry Lomond
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Publication number: 20150133346Abstract: The present invention relates to a process for preparing control agents for applications in the petroleum field, where a polymer bearing —OH, amine and/or amide functions, which is in the form of a divided solid, is reacted with at least one crosslinking agent bearing at least two —R groups capable of reacting with the —OH, amine or amide groups, under conditions where said polymer remains in solid form and where said crosslinking agent is at least partly in vapour form, The invention also relates to the control agents obtained in solid form according to this process, and also to the mixtures of these solid agents with other additives, which can be used in particular for the preparation of cement grout for oil extraction.Type: ApplicationFiled: January 25, 2013Publication date: May 14, 2015Inventor: Arnaud Cadix
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Publication number: 20150072901Abstract: A lost circulation additive including a guar chaff material. The method of forming a lost circulation fluid includes contacting the lost circulation additive with a base fluid. The method for treating a formation including injecting the loss circulation fluid into a wellbore.Type: ApplicationFiled: September 4, 2014Publication date: March 12, 2015Applicant: CLEARWATER INTERNATIONAL LLCInventors: Mathew M. Samuel, Gaston W. Curtis, Shawn Lu
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Publication number: 20150045260Abstract: Aqueous and substantially anhydrous fluids having particularly low thermal conductivities and variable densities are disclosed. The fluids include: one or more organic and/or inorganic salts and at least one aprotic polar organic solvent, a mixture of aprotic and protic polar organic solvents, and/or a polar organic solvent having both protic and aprotic polar functional group linkages. The fluids optionally include one or more viscosifying agents and are free of cross-linking agents. Methods for formulating and using the fluids are also disclosed.Type: ApplicationFiled: October 23, 2014Publication date: February 12, 2015Inventors: Jeffrey McKennis, Marshall Chiasson, Mohammad Hossaini, Nam-Sook Bae
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Publication number: 20150031588Abstract: Nanoemulsions, miniemulsions, microemulsion systems with excess oil or water or both (Winsor III) or single phase microemulsions (Winsor IV) may be formed in situ during hydrocarbon recovery operations after drilling with OBM or SBM using one or more fluid pills. The nanoemulsions, miniemulsions, microemulsion systems with excess oil or water or both or single phase microemulsions remove oil and solids from the well and wellbore surfaces. In one non-limiting embodiment, a single phase microemulsion (SPME) or other in situ-formed fluid may be created from a polar phase, a nonpolar phase, at least one viscosifier, and at least one surfactant.Type: ApplicationFiled: October 15, 2014Publication date: January 29, 2015Applicant: BAKER HUGHES INCORPORATEDInventors: LIRIO Quintero, Chad F. Christian, Alexander McKellar, Cristina Torres, David E. Clark, Thomas A. Jones
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Publication number: 20150027702Abstract: Methods of treating a subterranean formation are disclosed that include placing a treatment fluid into a subterranean formation, the treatment fluid containing a one or more polymers capable of consolidating to form a polymeric structure at a downhole location. Also disclosed are treatment fluids including a polymeric structure for treating a subterranean formation.Type: ApplicationFiled: July 23, 2014Publication date: January 29, 2015Inventors: Jazmin Godoy-Vargas, Sergey Makarychev-Mikhailov, Brent Busby, Philip Sullivan, Patrice Abivin, Marie Cambournac
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Publication number: 20140353043Abstract: A method of conversion of a water-based mud to a gel-based LCM quickly to control lost circulation in a lost circulation zone in a wellbore during continuous drilling with a drilling mud, the drilling mud comprises a volcanic ash, water, a de-foamer, a pH buffer, and a polymer. The method comprises the steps of entering the lost circulation zone, determining a lost circulation volumetric flow rate, metering a first amount of a binder into the drilling mud to create a binder containing mud, pumping the binder containing drilling mud into the wellbore, and suspending metering of the first amount of the binder to the drilling mud after a pre-defined regulating period of time effective to permit the binder containing drilling mud to create a gel-based LCM operable to alter the lost circulation zone.Type: ApplicationFiled: June 3, 2014Publication date: December 4, 2014Applicant: Saudi Arabian Oil CompanyInventors: Md Amanullah, Turki Thuwaini Mohamme Alsubaie, Abdulaziz Salah Bubshait, Omar Abdulwahab AI-Fuwaires
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Publication number: 20140352969Abstract: Various embodiments disclosed relate to a composition including a crosslinkable ampholyte polymer or a crosslinked product of the same, methods of making and using the composition, and systems including the composition. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include obtaining or providing a composition including a crosslinkable ampholyte polymer. The crosslinkable ampholyte polymer can include an ethylene repeating unit including a —C(O)NH2 group, an ethylene repeating unit including a —S(O)2OR1 group, and an ethylene repeating unit comprising an —N+R23X? group. At each occurrence, R1 can be independently selected from the group consisting of —H and a counterion. At each occurrence, R2 can be independently substituted or unsubstituted (C1-C20)hydrocarbyl. At each occurrence, X? can be independently a counterion. The composition can also include at least one crosslinker.Type: ApplicationFiled: March 11, 2014Publication date: December 4, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: HsinChen Chung, Yuntao Thomas Hu, Narongsak Tonmukayakul, Harvey Fitzpatrick
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Publication number: 20140349894Abstract: Nanomaterial compositions are useful for applications in drilling and completion fluids as enhancers of electrical and thermal conductivity, emulsion stabilizers, wellbore strength improvers, drag reduction agents, wettability changers, corrosion coating compositions and the like These nanomaterials may be dispersed in the liquid phase in low volumetric fraction, particularly as compared to corresponding agents of larger size. Nanofluids (fluids containing nano-sized particles) may be used to drill at least part of the wellbore. Nanofluids for drilling and completion applications may be designed including nanoparticles such as carbon nanotubes. These fluids containing nanomaterials, such as carbon nanotubes, meet the required rheological and filtration properties for application in challenging HPHT drilling and completions operations.Type: ApplicationFiled: August 8, 2014Publication date: November 27, 2014Applicant: BAKER HUGHES INCORPORATEDInventors: LIRIO QUINTERO, ANTONIA ENRIQUE CARDENAS, DAVID E. CLARK
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Patent number: 8895480Abstract: A well fracturing fluid is shown which includes an aqueous base fluid, a hydratable polymer, such as a guar gum, and a suitable crosslinking agent for crosslinking the hydratable polymer to form a polymer gel. The hydratable polymer has a higher molecular weight which is achieved by improvements in the processing of the guar split. The higher molecular weight polymer provides improved performance in well fracturing operations.Type: GrantFiled: June 3, 2005Date of Patent: November 25, 2014Assignee: Baker Hughes IncorporatedInventors: Jeffrey C. Dawson, Hoang Van Le
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Publication number: 20140305647Abstract: Methods of treating a subterranean formation including providing a treatment fluid comprising an aqueous base fluid and a friction reducing agent, wherein the friction reducing agent is a biosynthetic polysaccharide produced by a host cell line with DNA encoding the biosynthetic polysaccharide; and introducing the treatment fluid into the subterranean formation.Type: ApplicationFiled: March 25, 2014Publication date: October 16, 2014Applicant: Halliburton Energy Services, Inc.Inventors: Jimmie D. Weaver, David Loveless, Nathan Carl Schultheiss, Ali Alwattari
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Publication number: 20140291029Abstract: Beneficiated clay viscosifying additives may include a low-quality clay and a polymer coated high-quality clay that comprises a high-quality clay at least partially coated with a polymer, wherein the ratio of low-quality clay to high-quality clay is about 90:10 to about 80:20 by weight. Such beneficiated clay viscosifying additives may be used in drilling fluids.Type: ApplicationFiled: March 29, 2013Publication date: October 2, 2014Applicant: Halliburton Energy Services, Inc.Inventors: Thomas S. Cortner, Charles R. Landis, Eric B. Frantz
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Publication number: 20140256602Abstract: According to an embodiment, a drilling fluid comprises: water and a set accelerator, wherein the drilling fluid has a 10 minute gel strength of less than 20 lb*ft/100 sq ft, wherein the drilling fluid has a density in the range of about 9 to about 14 pounds per gallon, wherein the drilling fluid remains pourable for at least 5 days, and wherein when at least one part of the drilling fluid mixes with three parts of a cement composition consisting of water and cement, the drilling fluid cement composition mixture develops a compressive strength of at least 1,200 psi. According to another embodiment, a method of using the drilling fluid comprises the steps of: introducing the drilling fluid into at least a portion of a subterranean formation, wherein at least a portion of the drilling fluid is capable of mixing with a cement composition.Type: ApplicationFiled: May 20, 2014Publication date: September 11, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Krishna RAVI, Donald WHITFILL, Rahul PATIL, Abhimanyu DESHPANDE
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Publication number: 20140238677Abstract: The current invention relates to the use of chitin nanocrystals and chitin nanocrystal derivatives. More specifically, the present invention relates to the use of chitin nanocrystals and chitin nanocrystals used in oil and gas operations. The chitin nanocrystals and chitin nanocrystals derivatives can be used as additives to cement and wellbore fluids and can be used to inhibit corrosion in pipelines, on downhole tools and on other oil and gas related equipment.Type: ApplicationFiled: February 28, 2013Publication date: August 28, 2014Applicant: Halliburton Energy Services, Inc.Inventor: Lee Jeremy Hall
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Patent number: 8785417Abstract: Absorbent boronate-galactomannan complexes comprising a hydrophobic group are disclosed. The boronate-galactomannan complexes are solid materials capable of gel forming upon contacting with liquids. The boronate-galactomannan complexes are particularly suitable for absorbing liquids.Type: GrantFiled: February 6, 2009Date of Patent: July 22, 2014Assignee: Archer Daniels Midland Co.Inventors: Anne-Claude Couffin, Mohammed Berrada, André Laforest, Nicolas Nourry
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Publication number: 20140200168Abstract: A treatment fluid comprises: water; a carboxylate; and a corrosion inhibitor, wherein the corrosion inhibitor is environmentally-friendly, biodegradable, and is a polymer, wherein the polymer comprises a carbohydrate backbone and a quaternary amine functional group; wherein a test fluid consisting essentially of the water, the carboxylate, and the corrosion inhibitor, and in the same proportions as in the treatment fluid, is capable of providing a corrosion weight loss to a metal plate of less than 0.05 pounds per square feet (lb/ft2) under testing conditions of 200° F. (93.3° C.), a pressure of 500 psi (3.4 MPa), and a time of 24 hours whereas a substantially identical test fluid without the corrosion inhibitor provides a corrosion weight loss of greater than 0.05 lb/ft2 under the testing conditions. A method of treating a portion of a well comprises: forming the treatment fluid; and introducing the treatment fluid into the well.Type: ApplicationFiled: January 11, 2013Publication date: July 17, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Garima MISRA, Arunesh KUMAR
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Publication number: 20140128294Abstract: A corrosion control system is disclosed including an anionic oxygen inhibitor, a cationic acid inhibitor or dispersant, and a noxious species inhibitor or scavenger for use in a fluid in contact with a metallic surface at low temperature, moderate temperature and especially at high temperature. A drilling fluid, a completion fluid, a production fluid and a geothermal fluid including an effective amount of the corrosion control system is also disclosed as well as methods for making and using same.Type: ApplicationFiled: October 21, 2013Publication date: May 8, 2014Applicant: WEATHERFORD/LAMB, INC.Inventors: Larry W. Gatlin, Khalid Ali Shah
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Patent number: 8703924Abstract: This invention relates to a cross-linkable chitosan composition comprising chitosan having a degree of deacetylation between 30 and 75%, wherein the chitosan is randomly deacetylated, and a cross-linking agent, wherein the molar ratio of the cross-linking agent to chitosan is 0.2:1 or less based on the number of functional groups in the cross-linking agent and the number of accessible amino groups in the chitosan. The invention also provides a chitosan hydrogel formed therefrom and uses thereof.Type: GrantFiled: October 30, 2008Date of Patent: April 22, 2014Assignee: Viscogel, ABInventor: Mats Andersson
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Patent number: 8691732Abstract: A water-based fluid, containing: a non-ionic surfactant, which is stable in a temperature range from 10 to 90° C. and soluble in water; and a salt, wherein the non-ionic surfactant contains an alkyl polyglucoside selected from the group consisting of a C8 alkyl polyglucoside, a C10 alkyl polyglucoside, and mixtures thereof, and the salt is present, and is present in an amount up to 60%. In addition, a process for preventing the formation of a W/O inverse emulsion or resolving a W/O inverse emulsion that has already formed in an oil well in which an oil-based mud has been employed by injecting the water-based fluid into the oil well.Type: GrantFiled: June 9, 2008Date of Patent: April 8, 2014Assignee: ENI S.p.A.Inventors: Lucilla Del Gaudio, Paola Albonico, Sandra Cobianco, Chiara Neva Emiliani, Giuseppe Ripa
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Publication number: 20140090896Abstract: A method for enhancing the rheology of drilling fluids that is effective for any mud weight “clay-free” invert emulsion drilling fluid, even when drilling at high temperatures. The improved rheology is effected with addition of a silicon oil to the drilling fluid. A nonlimiting example of such a rheology additive comprises polydimethylsiloxane.Type: ApplicationFiled: September 30, 2012Publication date: April 3, 2014Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Vikrant Bhavanishankar Wagle, Sharath Savari, Sandeep D. Kulkarni
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Publication number: 20140090848Abstract: A method for treating a well penetrating subterranean formations comprising injecting into the well a composition comprising a high temperature stabilizer composition which comprises at least one mineral-reactive compound; wherein at least a part of the well is at a temperature of at least 120° C. is provided. Also provided is a composition for treating a well comprising a mineral-reactive compound.Type: ApplicationFiled: September 28, 2012Publication date: April 3, 2014Inventors: Leiming Li, Bruno Drochon, Li Jiang
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Publication number: 20140087974Abstract: Additives used in treatment fluids include particulate weighting agents comprising removable coatings which can be used in methods such as drilling and cementing operations; a method includes providing a treatment fluid for use in a subterranean formation, the treatment fluid including a coated particulate weighting agent including a core weighting agent having a first specific gravity and a removable polymer coating having a second specific gravity, the first specific gravity and the second specific gravity are not the same, introducing the treatment fluid into the subterranean formation, and allowing a portion of the removable polymer coating to be removed to alter the specific gravity of the coated particulate weighting agent down hole.Type: ApplicationFiled: September 27, 2012Publication date: March 27, 2014Applicant: Halliburton Energy Services, Inc.Inventors: Alfredo Villarreal, William Walter Shumway
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Patent number: 8673825Abstract: A drilling fluid additive, is provided, and the additive comprises: syrup solids and a liquid medium; and the sugar content of the additive is directly proportionate to the freezing point of the additive.Type: GrantFiled: June 1, 2012Date of Patent: March 18, 2014Assignee: Mudmasters Group, LLCInventors: Jerry Rayborn, Sr., Dan M. DeLaRosa
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Publication number: 20140066339Abstract: Various salt crystal and agglomeration settling inhibiting agents may aid the ability to keep salt crystals of a desired particle size undissolved and dissolved in an aqueous drilling fluid, including, whey, wine-making residues, “steepwater solubles” or an organic liquid formed from the residue of wet processing of grains, sugar cane, sugar beets, and similar plants for the food and beverage industries for consumption by human or animals, and combinations thereof. A fluid so treated has more uniform properties and a reduced tendency for the salt therein to settle out as compared to an otherwise identical fluid absent an effective proportion or amount of the salt crystal agglomeration and settling inhibiting agent, even for saturated salt fluids. The salt crystal agglomeration and settling inhibiting agents are also believed to be useful in inhibiting or preventing the formation of gas hydrates under gas hydrate forming conditions of low temperature and high pressure.Type: ApplicationFiled: November 8, 2013Publication date: March 6, 2014Applicant: Baker Hughes IncorporatedInventors: Mohammad Tej, Stephen Bruce Fry, John B. Trenery
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Publication number: 20140051607Abstract: The invention provides a method of manufacturing a solid phase barite containing material for use in a wellbore. The method includes the steps of providing the barite containing material having relatively small particles with a particle size distribution of at least 50 vol % particles having a diameter in the range of 1 ?m to 10 ?m and at least 90 vol % particles having a diameter in the range of 4 ?m to 20 ?m; and contacting the barite containing material with a liquid in order to form relatively large particles having a particle size distribution with at least 90 vol % of the particles having a diameter of at least 30 ?m. There is also described a method of treating a wellbore with a fluid including the barite containing material.Type: ApplicationFiled: January 12, 2012Publication date: February 20, 2014Applicant: M-I DRILLING FLUIDS UK LIMITEDInventors: Jarrod Massam, Richard Bingham, Mazin Philip
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Publication number: 20140041944Abstract: A water-based drilling fluid comprises a polymer which is a non-ionic polymer or an anionic polymer. The polymer can be a polyacrylamide. The fluid is used for drilling subterranean formations containing heavy crude oil and bitumen-rich oil sands, and may comprise additional fluid components.Type: ApplicationFiled: October 18, 2013Publication date: February 13, 2014Inventor: John Ewanek
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Publication number: 20140024560Abstract: A drilling fluid, comprising an aqueous continuous phase, and a surfactant system comprising a mixture of an ester phosphate and a non-ionic ethoxylated alcohol. The drilling fluid may also contain one or more of at least one salt, an alkaline material, a viscosifying agent, a starch or starch derivative, a bridging agent, a weighting material, and a diesel oil or non-aromatic oil.Type: ApplicationFiled: July 19, 2012Publication date: January 23, 2014Applicant: INTEVEP, S.A.Inventors: Jose Miguel Gonzalez Poche, Franklin Quintero Godoy, Rosa Linda Marquez Silva, Sergio Rosales, Jesus Enrique Arellano Varela, Harry Wilson Ogalde Arquero, Domingo Pernia
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Publication number: 20130324442Abstract: An environmentally responsible iron chelating additive and method for removing hydrogen sulfide or sulfide ions from drilling and packer fluids and preventing settling of precipitates. Iron chelating agents selected from the group consisting of ferrous lactate, ferrous gluconate, ferrous bis glycinate, ferrous citrate, ferrous acetate, ferrous fumarate, ferrous succinate, ferrous sacchrate, ferrous tartarate, ferrous glycine sulfate, ferrous glutamate, ferrous ascorbate, ferrous polymaltose, or a combination thereof, may be used. When the fluids are oil based, the iron chelating agents are added to the water phase of an emulsion, and the emulsion is added to the fluid. Viscosifiers may also be added to the drilling fluid with the emulsion.Type: ApplicationFiled: May 30, 2012Publication date: December 5, 2013Inventors: John Adrian Hall, Kushabhau D. Teke, Pramod Dadasaheb Nikam
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Publication number: 20130324441Abstract: A drilling fluid is provided that comprises a non-ionic or cationic polymer having general formula I or II. The drilling fluid may be used in drilling or other oilfield operations to prevent or limit the accretion of hydrocarbons to metal components when these are in contact with highly viscous hydrocarbons such as those present in formations containing heavy crude oil or tar sand.Type: ApplicationFiled: June 4, 2013Publication date: December 5, 2013Applicant: Diversity Technologies CorporationInventor: Ioan Ghesner
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Publication number: 20130316936Abstract: Drilling mud compositions and related methods are provided as embodiments of the present invention. The drilling mud compositions are water-based and contain volcanic ash. The compositions and methods of the present invention provide improved properties relative to tolerance of high salt content, cement, lime, and temperatures.Type: ApplicationFiled: July 31, 2013Publication date: November 28, 2013Applicant: Saudi Arabian Oil CompanyInventors: Md. Amanullah, Abdulaziz S. Bubshait, Omar A. Fuwaires
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Patent number: RE47362Abstract: A drilling fluid additive, is provided, and the additive comprises: syrup solids and a liquid medium; and the sugar content of the additive is directly proportionate to the freezing point of the additive.Type: GrantFiled: March 18, 2016Date of Patent: April 23, 2019Assignee: Mud Masters Acquisition CorporationInventors: Jerry Rayborn, Sr., Dan DeLaRosa