Abstract: The present invention relates to drilling fluids which reduce fluid and cutting loss during the drilling of subterranean wells. More specifically, the drilling fluids disclosed herein comprise natural and synthetic polymer blends that are effective to provide the fluid with a high viscosity under low shear rates and a low viscosity under high shear rates. The present invention also relates to methods for using the drilling fluids for reducing fluid and cutting loss during drilling.

Abstract: The present invention relates to a composition for scavenging hydrogen sulphide and/or mercaptans in hydrocarbon streams, the composition comprising an oxazolidine compound and a synergistic additive.

Abstract: This disclosure relates to compositions including a poly-alkene maleic anhydride copolymer, a PEG, and a crosslinker selected from an ethyleneamine, a benzenetricarboxylic acid, a benzimidazole, and combinations thereof. The poly-alkene maleic anhydride copolymer includes repeat units I and II: where R1, R1?, R2, and R2? are each independently selected from —H and —(C1-C5)alkyl. The disclosure also provides methods of treating a subterranean formation or cement construction using the compositions.

Abstract: This disclosure relates to methods of treating a subterranean formation or cement construction in the presence of one or more contaminants using a hydrogel composition that contains a poly-alkene maleic anhydride copolymer, a polyethylene glycol, and an aqueous carrier.

Abstract: Methods are provided to inhibit corrosion in low hardness water systems. The corrosion inhibiting treatment comprises: calcium salts of low molecular weight polymer polycarboxylic acids. These calcium salts may be added preformed to the water system in need of treatment or formed in-situ in the system. This method of corrosion inhibition is not a source of addition phosphorous or heavy metal to the treated system.

Abstract: A silane-modified colloidal silica in the form of a Pickering emulsion and a method for enhancing recovery of hydrocarbons and improving conformance using it. When injected into an oil well, the silane-modified colloidal silica separates into an aqueous phase and oil/oleic phase. The aqueous phase forms a gel that blocks the flow of water and the oleic phase that forms permits oil to flow out of the well.

Abstract: An example system is configured to detect saturation levels of a target, such as a core sample of a reservoir, using magnetic fields generated by hydrophilic magnetic nanoparticles within the target. The target contains both a hydrocarbon, such as oil or gas, and a mixture comprised of water and the hydrophilic magnetic nanoparticles. The system includes magnetic field detectors for spatial distribution across a dimension of the target. The magnetic field detectors are configured to detect a magnetic field associated with the hydrophilic magnetic nanoparticles. A data processing system is configured—for example, programmed—to determine a saturation profile of the target based on the magnetic field.

Abstract: A method for drilling a tunnel through a formation must address environmental concerns. One tunneling method comprises the steps of: preparing a mixed metal-viscosified drilling fluid including bentonite, a mixed metal viscosifier and controlling pH to 8.5 to 9.5 to permit a reaction between the bentonite and the mixed metal viscosifier; adding at least one of: (i) calcium sulfate and (ii) a potassium salt; and pumping the drilling fluid while drilling the tunnel with the pH lowered to 7-9. The amount of mixed metal viscosifier used can be limited such that the weight ratio of mixed metal viscosifier to MBT reaches up to 1:30. In the event that there is a problematic increase in viscosity, a non-toxic anionic thinner can be added to the drilling fluid. One such anionic thinner is a polyacrylate.

Abstract: Drilling fluid compositions and methods of using them are described. The drilling fluid compositions comprise nanocomposites comprising core-shell morphology, wherein the core material comprises a nanoparticle having an average particle size of about 5 nm to 100 nm, and the shell material comprises a crosslinked polymer comprising acrylamide repeat units. The nanocomposites are effective fluid loss control agents when the drilling fluids are employed in mud drilling operations.

Abstract: A method of servicing a wellbore penetrating a subterranean formation, comprising: placing a wellbore servicing fluid (WSF) into the wellbore, wherein the WSF comprises a first polymer, a second polymer, and water, wherein the first polymer is formed by polymerizing monomers comprising three of 2-Acrylamido-2-methyl propane sulfonic acid (AMPS), N,N-dimethylacrylamide (NNDMA), acrylamide, N-vinylacetamide, allyloxy-2-hydroxy propane sulfonic acid (AHPS), acrylic acid (AA), 2-acrylamido-2-tert.-butyl sulfonic acid (ATBS), or N,N-Dimethylaniline, and the second polymer is formed by polymerizing monomers and/or crosslinkers comprising AMPS, vinylpyrrolidinone, pentaerythritol allyl ether, and methylenebisacrylamide, wherein in the vinylpyrrolidinone, the 2-Pyrrolidone group can be substituted by a heterocyclic group, comprising one or more Z membered rings with Y heteroatoms, wherein Z is equal to or greater than three, and wherein Y is equal to or greater than one.

Abstract: The method for well-stimulation through a wellbore in a rock formation is hydraulic fracturing under high temperature conditions. The method includes injecting a fracturing fluid system to the rock formation; fracturing the rock formation at a temperature between 150-260 degrees Celsius; and recovering fluid components of the fracturing fluid system from the wellbore and setting the proppant in the fractures. The fracturing fluid system includes proppant and a plurality of fluid components. The fluid components can include water, a gelling agent, and a stabilizer made of ascorbic acid ranging from 50-100 ppt so as to adjust pH and delay said cross linking agent.

Abstract: The present invention provides improved methods for purifying and/or removing multiply charged cations and suspended solids from water. In particular the process relates to an additive composition that has the appropriate surfactant characteristics for effectively removing multiply charged cations and suspended solids from an aqueous or oil/aqueous mixed phase via foam fractionation. According to the invention, a hydrophobically modified polymer that acts as an associative thickener is used in the presence of a source of alkalinity or anionic reactant as well as surfactant in appropriate ratios to facilitate multiply charged cation and suspended solids removal for water purification in any of a number of commercial, environmental and industrial applications.

Abstract: The invention relates to the field of drilling fluid, and discloses a strong plugging drilling fluid composition and preparation method thereof, and use thereof. The strong plugging drilling fluid composition comprises water, bentonite, Na2CO3, a shale inhibitor, a filtrate reducer, a viscosity reducer, an anti-collapse agent, a nanometer plugging agent, a lubricant and a weighting agent. The shale inhibitor is modified asphalt, the anti-collapse agent is ultra-fine calcium carbonate, and the nanometer plugging agent is polyethylene glycol surface-modified nano-graphene.

Abstract: The present invention provides improved methods for purifying and/or removing oily particles, and/or contaminants suspended or dissolved in water. In particular the process relates to an additive composition that has the appropriate surfactant characteristics for effectively removing an oil phase from an oil/aqueous mixed phase via foam fractionation. According to the invention, a hydrophobically modified polymer that acts as an associative thickener is combined with surfactant in appropriate ratios to facilitate oil removal for water purification in any of a number of commercial, environmental and industrial applications.

Abstract: A stable, aqueous composition containing a crosslinked, nonionic, amphiphilic polymer capable of forming a yield stress fluid in the presence of a surfactant is disclosed. The yield stress fluid is capable of suspending insoluble materials in the form of particulates and/or droplets requiring suspension or stabilization.

Abstract: A composition for enhancing fluid viscosity including a mixture of at least one cationic or cationizable polymer and at least one anionic or anionizable (hydrolysable) polymer. The composition has a zeta potential at 25° C. in the range of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV, or is a precursor convertible at a temperature of 100 to 250° C. to the composition having a zeta potential at 25° C. of 0.5 to 100 mV or ?0.5 to ?100 mV, typically 1 to 60 mV or ?1 to ?60 mV. Typically the compositions exhibit salt tolerance and interaction of both polymers at very high temperatures (>300° F.) such that the system exhibits an increase of viscosity at extreme temperatures. The compositions are useful for hydraulic fracturing, enhanced oil recovery, subterranean acidization, personal care as well as home and industrial cleaners.

Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent having the formula: (Formula I should be inserted here.) wherein R is hydrogen or an alkyl group having 1 to 12 carbons, R1 is an alkylene group having 1 to 12 carbons, and R2 is an alkyl group having 1 to 12 carbons. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.

Abstract: Processes are provided for reducing the hydrodynamic friction of a turbulent brine stream including, for example, the step of injecting a mixture of a finely divided free flowing friction reducing powder into the turbulent brine stream, wherein the particles of the powder have a primary particle size between 10 and 100 microns in average particle diameter, and the brine stream comprises water with at least 90,000 ppm total dissolved solids, wherein the total dissolved solids includes at least 30,000 ppm sodium cations, 10,000 ppm calcium cations, and 1,000 ppm magnesium cations, and wherein the brine has an electrical conductivity of greater than 100.0 mS/cm at 25° C. For use with a harsher brine, the particles preferably have a primary particle size between 10 and 53 microns in average particle diameter. The friction reducing powder may, for example, be a polyacrylamide polymer.

Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for use in fracturing subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of calcium salts in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: Amphiphilic macromolecules having repeating structural units: structural units to adjust molecular weight and molecular weight distribution and charging property effects, high stereo-hindrance structural units, and amphiphilic structural units, and are suitable for fields such as oil field well drilling, well cementation, fracturing, oil gathering and transfer, sewage treatment, sludge treatment and papermaking, etc., and can be used as an oil-displacing agent for enhanced oil production, a heavy oil viscosity reducer, a fracturing fluid, a clay stabilizing agent, a sewage treatment agent, a papermaking retention and drainage aid or a reinforcing agent, etc.

Abstract: The present invention relates to glycerol based drilling fluids. In particular, the invention relates to drilling fluids comprising a 95-20 volume % glycerol/water solution capable of stabilizing water-sensitive formations during drilling and the use of such solutions for drilling a well having water-sensitive formations.

Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof; and (c) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: Embodiments disclosed herein relate to methods for stabilizing shales while drilling a wellbore into an earthen formation comprising circulating an aqueous based wellbore fluid in the wellbore while drilling through shales; wherein the aqueous-based wellbore fluid comprises a copolymer of acrylamide-type comonomers and at least one cationic comonomer.

Abstract: A rock dusting composition composed of rock dust, e.g., limestone or other mineral dust, water, pumping aid, and polymer, e.g., acrylamide homopolymers, acrylamide copolymers, and combinations thereof, and a method for applying the composition to the surface of a mine. The composition has a water content and a polymer content sufficient to allow the polymer to (i) disperse water molecules within the composition and, upon drying of the composition, (ii) dissipate forming void spaces in the dried composition. The composition is useful for suppressing propagation of a flame and/or fire caused by ignition of coal dust and/or gas within a coal mine.

Abstract: The present invention relates to treatment of subterranean formations using compositions that experience an increase in viscosity as a result of the application of heat or shear. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include obtaining or providing a composition including a linear triblock copolymer and inorganic particles. The method can include at least one of shearing and heating the composition, to increase the viscosity thereof. The method can also include contacting the composition with a subterranean material downhole.

Abstract: Methods of treating flowback water from a subterranean formation penetrated by a well bore are provided, comprising: (a) providing remediated flowback water having a ferrous iron (Fe+2) ion concentration of less than about 100 milligrams of ferrous iron ion per liter of flowback water, a barium ion (Ba+2) concentration of less than about 500 milligrams of barium ion per liter of flowback water, and a calcium ion (Ca+) concentration of at least about 1,000 milligrams of calcium ion per liter of remediated flowback water; and (b) treating the flowback water with: (i) at least one friction reducing agent; and (ii) at least one scale formation inhibiting agent and/or at least one iron precipitation control agent to provide treated flowback water which can be reused as fracturing fluid in a well drilling operation.

Abstract: Beneficiated clay viscosifying additives may include a low-quality clay and a polymer coated high-quality clay that comprises a high-quality clay at least partially coated with a polymer, wherein the ratio of low-quality clay to high-quality clay is about 90:10 to about 80:20 by weight. Such beneficiated clay viscosifying additives may be used in drilling fluids.

Abstract: The present invention refers to the use of anionic water-soluble polymers being partially or totally neutralized with an organic counter-ion for oil filed application, especially tertiary oil recovery steps.

Abstract: Drilling, drill-in and completion fluids containing nanoparticles for use in hydrocarbon drilling and recovery processes and methods related thereto are provided. The fluids also include a dual acting shield agent that shields the nanoparticles and also acts as a viscosifier. The fluids can be used in various types of hydrocarbon drilling and recovery processes, such as drilling, drill in, completion, and the like.

Abstract: The present invention relates to synthetic polymers having high molecular weights and low polydispersities and methods of synthesis. In one embodiment of the present invention, a polymer includes a polyacrylate polymer obtained from a polymerization reaction in which the polyacrylate polymer has a molecular weight of at least about 500,000 and a polydispersity index of about 1.25 or less.

Abstract: The present invention relates to synthetic polymers having high molecular weight and low polydispersities, and methods of synthesis thereof. One embodiment of the present invention provides a method of polymerizing that includes dissolving acrylate monomers in a fluid media having an olefin-containing polyalcohol amide surfactant; and initiating a polymerization reaction of the acrylate monomers with a polymerization initiator to produce a polymer having a molecular weight of at least about 500,000 and a polydispersity index of about 1.25 or less.

Abstract: The present invention relates to hollow hydrogel capsules. In various embodiments, the present invention provides a method of treating a subterranean formation with a hollow hydrogel capsule including a hydrogel shell including a hydrolyzed and crosslinked polymerized composition. The hollow hydrogel capsule also includes a hollow interior including at least one component of a downhole composition for subterranean petroleum or water well drilling, stimulation, clean-up, production, completion, abandonment, or a combination thereof. In various embodiments, the present invention provides compositions comprising the hollow hydrogel capsules and methods of making the hollow hydrogel capsules.

Abstract: The present invention relates to a polymer including at least one monomer comprising a switchable-amphiphilic functional group. Various embodiments provide a methods of treating a subterranean formation with the polymer, compositions including the polymer, and methods of making compositions including the polymer.

Abstract: A method of servicing a wellbore in a subterranean formation having one or more lost circulation zones comprising placing a wellbore servicing fluid comprising a sealing composition into the wellbore, wherein the sealing composition comprises a latex and an accelerator and wherein the latex, the accelerator or both are encapsulated with an encapsulation material. A wellbore servicing fluid comprising a latex and an accelerator wherein the latex, the accelerator, or both are encapsulated.

Abstract: A variety of methods and compositions are disclosed, including, in one embodiment, a method of treating a subterranean formation comprising: providing coated particles, wherein the coated particles comprise solid particles coated with an expandable coating; and introducing the coated particles into a permeable zone of the subterranean formation such that the coated particles form a barrier to fluid flow in the permeable zone. In another embodiment, a method of drilling a well bore may be provided, the method comprising: including coated particles in a drilling fluid, the coated particles comprising solid particles coated with an expandable coating; using a drill bit to enlarge the well bore; and circulating the drilling fluid past the drill bit.

Abstract: A corrosion control system is disclosed including an anionic oxygen inhibitor, a cationic acid inhibitor or dispersant, and a noxious species inhibitor or scavenger for use in a fluid in contact with a metallic surface at low temperature, moderate temperature and especially at high temperature. A drilling fluid, a completion fluid, a production fluid and a geothermal fluid including an effective amount of the corrosion control system is also disclosed as well as methods for making and using same.

Abstract: A sealant composition comprising an inverse emulsion polymer and methods of servicing a wellbore using the same are disclosed. In one embodiment, a method of servicing a wellbore that penetrates a subterranean formation is disclosed. The method comprises placing a sealant composition comprising an inverse emulsion polymer into the wellbore to reduce a loss of fluid to the subterranean formation during placement of the fluid in the wellbore.

Abstract: A method for treating a well penetrating subterranean formations comprising injecting into the well a composition comprising a high temperature stabilizer composition which comprises at least one mineral-reactive compound; wherein at least a part of the well is at a temperature of at least 120° C. is provided. Also provided is a composition for treating a well comprising a mineral-reactive compound.

Abstract: Methods and fluids are provided that include, but are not limited to, a drilling fluid comprising an aqueous base fluid and a fluid loss control additive that comprises at least one polymeric micro gel and a method comprising: providing an aqueous based treatment fluid comprising a fluid loss control additive that comprises at least one polymeric micro gel; placing the aqueous based treatment fluid in a subterranean formation via a well bore penetrating the subterranean formation; allowing the fluid loss control additive to become incorporated into a filter cake located on a surface within the subterranean formation; allowing the filter cake to be degraded; and producing hydrocarbons from the formation. Additional methods are also provided.

Abstract: A water-based drilling fluid comprises a polymer which is a non-ionic polymer or an anionic polymer. The polymer can be a polyacrylamide. The fluid is used for drilling subterranean formations containing heavy crude oil and bitumen-rich oil sands, and may comprise additional fluid components.

Abstract: A copolymer and preparation method and application thereof are disclosed. The copolymer is random copolymer obtained from monomers consisting of acrylamide, acrylic acid, alkenyl sulfonate, 2-acrylamido-dodecyl sulfonate, p-styrene sulfonate or isoprene sulfonate and so on. The copolymer of present invention can be used as fluid loss additive and has good fluid loss properties, which would not make the drilling fluid thicken at high temperature of 200° C. and high salt conditions of saturated brine. It has a medium-pressure fluid loss after aging and rolling for 16 h at high temperature of 200° C., as measured in accordance with the American Petroleum Institute Standard Test at room temperature, and has good properties of high temperature-resisting and salt-resisting.

Abstract: A method of drilling a gas or oil well consists of use of a water-based drilling fluids containing high molecular weight crosslinked polyacrylic acid as viscosifying agent. The drilling fluid may further contain a lubricant, weighting agent and/or a wetting agent as well as a synthetic silicate or smectite clay. The aqueous based drilling fluid exhibits a coefficient of friction which is substantially close to the coefficient of friction of oil based drilling muds. The drilling fluid exhibits stability at well temperatures in excess of 150° C.

Abstract: A method using a single additive to modify or enhance one or more properties of a drilling fluid for drilling a wellbore in a subterranean formation, prevent lost circulation during the drilling, and/or increase bonding strength during cementing of the wellbore. The additive comprises an oil absorbent material comprising homopolymers or copolymers comprising styrene butadiene, acrylate, phthalate, and carbonate salts.

Abstract: A drilling fluid is provided that comprises a non-ionic or cationic polymer having general formula I or II. The drilling fluid may be used in drilling or other oilfield operations to prevent or limit the accretion of hydrocarbons to metal components when these are in contact with highly viscous hydrocarbons such as those present in formations containing heavy crude oil or tar sand.

Abstract: Methods of stabilizing water-sensitive clays in subterranean formations may include introducing a drill-in treatment fluid into at least a portion of a subterranean formation comprising water-sensitive minerals, where providing the drill-in treatment fluid comprises an aqueous-based fluid and a hydrophobically-modified cationic polymer; and allowing the hydrophobically-modified cationic polymer to at least partially coat the water-sensitive mineral.

Abstract: Ester based drilling fluids with enhanced stability at high temperatures for drilling, running casing in, and/or cementing a borehole in a subterranean formation. The drilling fluids comprise a monomeric or polymeric carbodiimide hydrolysis inhibitor.

Abstract: A treatment fluid for treating a subterranean formation penetrated by a wellbore is formed from water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. A method of treating a subterranean formation penetrated by a wellbore is carried out by forming treatment fluid comprising water, a polyacrylamide in an amount of less than about 0.5% by weight of the fluid for reducing friction of the fluid and a stabilized peroxide breaker. The treatment fluid is introduced into the formation through the wellbore at a pressure above the fracture pressure of the formation.

Abstract: A corrosion control system is disclosed including an anionic oxygen inhibitor, a cationic acid inhibitor or dispersant, and a noxious species inhibitor or scavenger for use in a fluid in contact with a metallic surface at low temperature, moderate temperature and especially at high temperature. A drilling fluid, a completion fluid, a production fluid and a geothermal fluid including an effective amount of the corrosion control system is also disclosed as well as methods for making and using same.

Abstract: A method of servicing a wellbore in contact with a subterranean formation, comprising placing a wellbore servicing fluid comprising a drilling fluid and lost circulation material into a lost circulation zone within the wellbore, wherein the lost circulation material comprises a polyelectrolyte multilayer material and a first counterion. A wellbore servicing fluid comprising a drilling fluid and a lost circulation material comprising a polyelectrolyte multilayer material and a counterion comprising a halide, wherein the LCM has a first state that is hydrophilic. A tunable lost circulation material comprising a base material, a polyelectrolyte multilayer on said base material, wherein the polyelectrolyte multilayer comprises a first electrolyte layer, a second electrolyte layer, and a charged surface, and a counterion, wherein wettability of the lost circulation material is a function of the counterion.