Organic Component Contains Nitrogen Attached Directly Or Indirectly To Carbon By Nonionic Bonding Patents (Class 507/129)
-
Patent number: 7378378Abstract: A method for increasing the rate of shear rehealing of fluids made with cationic, zwitterionic, and amphoteric viscoelastic surfactant fluid systems by adding an effective amount of a rheology enhancer package containing, for example a polyethylene glycol-polypropylene glycol block copolymer and a polynaphthalene sulfonate. The rheology enhancer package allows viscoelastic surfactant fluids to be used at lower viscoelastic surfactant concentrations in certain applications, for example certain oilfield treatments, for example fracturing and gravel packing. Preferred surfactants are betaines and quaternary amines.Type: GrantFiled: April 13, 2006Date of Patent: May 27, 2008Assignee: Schlumberger Technology CorporationInventors: Yiyan Chen, Jesse C. Lee, Fang Li, Manilal Dahanayake, Robert Tillotson, Allwyn Colaco
-
Patent number: 7377721Abstract: Invert emulsion compositions including an oleaginous, a non-oleaginous and an amine surfactant that are useful in the oil and gas well drilling art are disclosed. The amine surfactant is selected so that the invert emulsion can be converted form a water-in-oil type emulsion to a oil-in-water type emulsion upon the protonation of the amine surfactant. Deprotonation of the amine surfactant reverses the conversion. This solution also permits the conversion of oil-wet solids in the fluid into water-wet solids.Type: GrantFiled: January 10, 2007Date of Patent: May 27, 2008Assignee: M-I L.L.C.Inventor: Arvind D. Patel
-
Publication number: 20080070806Abstract: Compositions and methods are given for delayed breaking of viscoelastic surfactant gels inside formation pores, particularly for use in hydraulic fracturing. Breaking inside formation pores is accomplished without mechanical intervention or use of a second fluid. Bromate oxidizing agents are used along with selected breaking activators for the bromate breaking compounds. Useful bromate breaking activators include acid-generating breaking activators, oxidizing sulfur containing breaking activators, and reducing agent breaking activators.Type: ApplicationFiled: June 28, 2007Publication date: March 20, 2008Inventors: Lijun Lin, Carlos Abad, Belgin Baser, Leiming Li
-
Publication number: 20080058227Abstract: The present invention relates to a surfactant composition containing a cationic surfactant (hereinafter referred to as a compound (A)), one or more compounds (hereinafter referred to as a compound (B)) selected from anionic aromatic compounds and bromide compounds and a cationic polymer (C), wherein compound (A) and (B) are selected when meeting the following condition: a combination of the compounds (A) and (B) ensures that that the viscosity (20° C.) of a solution prepared by mixing an aqueous solution S A of the compound (A) and an aqueous solution SB of the compound (B) in the same ratio is at least two times the viscosity of any one of the aqueous solutions (20° C.) before being mixed.Type: ApplicationFiled: October 6, 2004Publication date: March 6, 2008Applicant: Kao CorporationInventors: Koji Koyanagi, Sadahara Miyamoto, Hotaka Yamamuro
-
Publication number: 20080032899Abstract: It is proposed a new family of terpolymers based on repeating units of two different types of hydrophobic moieties modified with anionic charged groups. In a preferred embodiment, the first hydrophobic moiety is an aromatic compound such as styrene and the second hydrophobic moiety is a fatty acid. Depending on the modification rate, and on the neutralization degree, the aqueous solutions of the terpolymers have different rheological behavior, ranging from yield point fluid, shear-thickening and polysoaps.Type: ApplicationFiled: June 14, 2005Publication date: February 7, 2008Inventors: Jean-Philippe Caritey, Christophe Chassenieux, Francoise Lafuma, Christille Le Chatelier-Brunet, Pierre Maroy
-
Publication number: 20080004189Abstract: Disclosed herein are methods and compositions for using effervescent materials to deliver biocides to fluids. Generally, the effervescent material is a solid that includes an acid and a base that react in aqueous medium to produce a gas, such as carbon dioxide. The effervescent material can be tablets, powder, flakes, and the like. The effervescent material includes one or more biocides, which are dispersed in the fluid by effervescent action that occurs when the material is added to the fluid. The methods and compositions are particularly suited for treating oil field fluids such as fracturing fluids.Type: ApplicationFiled: June 29, 2006Publication date: January 3, 2008Applicant: WEATHERFORD/LAMB, INC.Inventors: KEVIN SMITH, LEONARD J. PERSINSKI, MARK WANNER
-
Publication number: 20070298976Abstract: A wellbore fluid that includes an oleaginous continuous phase; a non-oleaginous phase; and a polymeric additive formed by mixing at least one lipophilic monomer and at least one crosslinking agent, wherein the at least one lipophilic monomer is at least one of an epoxide-functionalized derivative of at least one selected from soybean oil, linseed oil, rapeseed oil, cashew nut shell oil; perilla oil, tung oil, oiticia oil, safflower oil, poppy oil, hemp oil, cottonseed oil, sunflower oil, high-oleic triglycerides, triglycerides of euphorbia plants, peanut oil, olive oil, olive kernel oil, almond oil, kapok oil, hazelnut oil, apricot kernel oil, beechnut oil, lupine oil, maize oil, sesame oil, grapeseed oil, lallemantia oil, castor oil, herring oil, sardine oil, menhaden oil, whale oil, tall oil, and synthetic aliphatic or aromatic ethers, and the at least one crosslinking agent includes at least one selected from amines, alcohols, phenols, thiols, carbanions, carboxylates, and mixtures thereof is disclosed.Type: ApplicationFiled: June 8, 2007Publication date: December 27, 2007Inventor: David Antony Ballard
-
Patent number: 7312183Abstract: A water-base fluid for use in drilling, cementing, workover, fracturing and abandonment of subterranean wells through a formation containing shale which swells in the presence of water. In one illustrative embodiment, the drilling fluid is composed of an aqueous based continuous phase, a weighting agent, and a shale hydration inhibition agent. The shale hydration inhibition agent should have the general formula: in which R and R? independently selected from hydrogen, methyl, ethyl or propyl, and X has a value from 1 to 6. The shale hydration inhibition agent is present in sufficient concentration to substantially reduce the swelling of shale drilling cuttings upon contact with the drilling fluid. The drilling fluid may be formulated to include a wide variety of components of aqueous based drilling fluids, such as weighting agents, fluid loss control agents, suspending agents, viscosifying agents, rheology control agents, as well as other compounds and materials known to one of skill in the art.Type: GrantFiled: October 5, 2004Date of Patent: December 25, 2007Assignee: M-I L.L.C.Inventors: Arvind D. Patel, Emanuel Stamatakis
-
Publication number: 20070293401Abstract: A wellbore fluid that includes an oleaginous continuous phase; a non-oleaginous phase; and a modified polyesteramide surfactant; methods of formulating such wellbore fluid; and methods of drilling a subterranean formation with such wellbore fluid are disclosed.Type: ApplicationFiled: June 20, 2007Publication date: December 20, 2007Applicant: M-I LLCInventor: David Antony Ballard
-
Publication number: 20070293402Abstract: A wellbore fluid having at least two phases, the wellbore fluid including a fluid phase; and a solid phase including a powdered solid material coated with a polymer, wherein the polymer is the reaction product of a polyesteramide and a crosslinking agent is disclosed.Type: ApplicationFiled: June 20, 2007Publication date: December 20, 2007Applicant: M-I LLCInventor: David Antony Ballard
-
Patent number: 7279445Abstract: A method of increasing shale formation stability with a water based drilling fluid, the method including: delivering to the shale formation a drilling fluid formulated to include an aqueous fluid; a first reactant which is a soluble monomer, oligomer, or polymer with exposed ketone, aldehyde, or aldol groups or with groups which can be shifted to ketone or aldehyde functionality; and, a second reactant which is a primary amine, diamine, or polyamine which by condensation reaction forms a semi-soluble or precipitated filming product with the first reactant.Type: GrantFiled: March 9, 2006Date of Patent: October 9, 2007Assignee: M-I L.L.C.Inventor: Robert F. Schlemmer
-
Patent number: 7256159Abstract: The present invention concerns a water-based drilling mud for utilization in the drilling of oil wells comprising an aqueous phase wherein the aqueous phase contains an oil soluble polymer in the form of a gel as a fluid loss reducer. The subject invention further reveals a method of lubricating a drilling bit during the drilling of a well which comprises circulating a water-based drilling mud in the vicinity of the drilling bit wherein the water-based drilling mud is comprised of an aqueous phase, and wherein the aqueous phase contains an oil soluble polymer in the form of a gel as a fluid loss reducer.Type: GrantFiled: August 23, 2006Date of Patent: August 14, 2007Assignee: Eliokem S.A.S.Inventors: Bertrand Guichard, Barry Wood, Patrick Vongphouthone
-
Patent number: 7238646Abstract: A method for using an invert emulsion fluid in a well bore, comprising placing an invert emulsion fluid in a well bore, wherein the invert emulsion fluid comprises an oleaginous fluid, a non-oleaginous fluid and an emulsifier comprising one or more amines generally represented by the formula: wherein R is a radical selected from the group consisting of abietyl, hydroabietyl, dihydroabietyl, tetrahydroabietyl, and dehydroabietyl, each R? may be the same or different and is an alkyl having from about 1 to about 3 carbons, each A may be the same or different and is NH or O, and the sum of x and y ranges from about 1 to about 20, and contacting the invert emulsion fluid with an acid solution to reversibly convert the invert emulsion to an oil-in-water emulsion.Type: GrantFiled: November 18, 2005Date of Patent: July 3, 2007Assignee: Halliburton Energy Services, Inc.Inventors: Carl J. Thaemlitz, Robert S. Taylor, Ryan M. Foster
-
Patent number: 7192907Abstract: A water based drilling fluid for use in drilling a subterranean well through a subterranean formation that swells in the presence of water, the drilling fluid is formulated to include: an aqueous based continuous phase; a weigh material; a shale encapsulator and an optional shale hydration inhibition agent. The shale encapsulator has the formula: which x and y have a value so that the molecular weight of the cation is in the range of about 10,000 to about 200,000 AMU; A is selected from C1–C6 alkyl, C2–C6 ether or amide; R, R? and R? are independently selectable C1–C3 alkyl; and B? is a charge balancing anion to the quaternary amine. The shale encapsulator and the optional shale hydration inhibition agent may be present in sufficient concentrations to reduce the swelling of the subterranean formation in the presence of water.Type: GrantFiled: September 3, 2003Date of Patent: March 20, 2007Assignee: M-I L.L.C.Inventors: Arvind D. Patel, Emanuel Stamatakis, Steve Young
-
Patent number: 7178594Abstract: Invert emulsion compositions including an oleaginous, a non-oleaginous and an amine surfactant that are useful in the oil and gas well drilling art are disclosed. The amine surfactant is selected so that the invert emulsion can be converted form a water-in-oil type emulsion to a oil-in-water type emulsion upon the protonation of the amine surfactant. Deprotonation of the amine surfactant reverses the conversion. This solution also permits the conversion of oil-wet solids in the fluid into water-wet solids.Type: GrantFiled: July 13, 2004Date of Patent: February 20, 2007Assignee: M-I L.L.C.Inventor: Arvind D Patel
-
Patent number: 7166160Abstract: The present invention is directed to hydraulic cement compositions comprising set-retarding additives and methods of retarding the set of a cement composition utilizing poly(amide) set-retarding additives and methods of cementing in subterranean zones utilizing a cement composition comprising a poly(amide) set-retarding additive.Type: GrantFiled: April 22, 2003Date of Patent: January 23, 2007Assignee: Halliburton Energy Services, Inc.Inventors: B. Raghava Reddy, Bryan K. Waugh
-
Patent number: 7152697Abstract: A method of controlling and delaying the inversion of a drilling fluid and the wettability of a filtercake by using a delayed phase changing agent. The filtercake is preferably formed while drilling a subterranean formation using a drilling fluid includes: an oleaginous fluid; a non-oleaginous fluid; an amine surfactant having the structure: wherein R is a C12–C22 aliphatic hydrocarbon; R? is an independently selectable from hydrogen or C1 to C3 alkyl; A is NH or O, and 1?x+y?3. In the method, the filter cake is exposed to a delayed phase changing agent selected from the group consisting of aliphatic amine acids, salts of aliphatic amine acids and combinations thereof. In one preferred illustrative embodiment, the delayed phase changing agent is delivered in the form of a pill, the pill including a carrier fluid, a viscosifier and the delayed phase changing agent.Type: GrantFiled: February 3, 2004Date of Patent: December 26, 2006Assignee: M-I LLCInventors: Robert L. Horton, Bethicia Prasek, Frank E. Evans, Taylor Green, Mark Luyster, Steve Mason
-
Patent number: 7101829Abstract: The present invention concerns a water-based drilling mud for utilization in the drilling of oil wells comprising an aqueous phase wherein the aqueous phase contains an oil soluble polymer in the form of a gel as fluid loss reducer. The subject invention further reveals a process for preparing an oil soluble polymer fluid loss control agent comprising the steps of dissolving at least one polymer in a hydrocarbon oil to form a clear solution or a gel, adding an emulsifier to the solution or the gel, and keeping the mixture under conditions of agitation until a clear creamy mixture is obtained.Type: GrantFiled: December 17, 2003Date of Patent: September 5, 2006Assignee: Eliokem S.A.S.Inventors: Bertrand Guichard, Barry Wood, Patrick Vongphouthone
-
Patent number: 7098172Abstract: A process to substantially reduce fluid loss in which an appropriate amount of a non-flowing gel of sufficient strength is emplaced to substantially eliminate or reduce loss of the drilling fluid. The gel composition of the process includes: (1) a non-cellulose containing copolymer having vinyl phosphonate co-monomer units which may be incorporated into the polymer by copolymerization with the other co-monomer(s) comprising the polymer or by grafting upon an already existing polymer or co-polymer, (2) a crosslinking agent active upon the phosphonate groups, (3) a crosslinking initiator comprising a Bronsted Lowry base or Lewis base and (4) an aqueous solvent.Type: GrantFiled: June 5, 2003Date of Patent: August 29, 2006Assignee: M-I L.L.C.Inventors: Robert L. Horton, Bethicia Prasek, Frederick B. Growcock, John W. Vian, Catalin D. Ivan
-
Patent number: 7094738Abstract: A method of improving the lubricity of an aqueous based drilling fluid composed of an aqueous base fluid, and a weighting agent. The method involves the addition of an effective amount of a phospholipid to substantially reduce the coefficient of friction when compared to the fluid absent the phospholipids. Preferably the phospholipids have the structure: in which R and R? are C6 to C25 hydrocarbon groups; and A is an anion to counter the cationic charge.Type: GrantFiled: September 9, 2004Date of Patent: August 22, 2006Assignee: M-I L.L.C.Inventors: Arvind D. Patel, Eric Davis, Steven Young, Emanuel Stamatakis
-
Patent number: 7067460Abstract: Invert emulsion drilling system fluids comprising an oleaginous continuous phase and a non-oleaginous dispersed phase, the dispersed phase comprising organofunctional compound(s) effective to provide shale inhibition. The organofunctional compound(s) may be used either as a supplement to or as a substitute for metallic salts.Type: GrantFiled: November 14, 2002Date of Patent: June 27, 2006Assignee: Baker Hughes IncorporatedInventors: Jerry L. Summerhill, Michael A. Jarrett, Alexander J. McKellar, David B. Young, Patrick E. Grover, William J. Gusler
-
Patent number: 7063176Abstract: A method of increasing shale formation stability with a water based drilling fluid, the method including: delivering to the shale formation a drilling fluid formulated to include an aqueous fluid; a first reactant which is a soluble monomer, oligomer, or polymer with exposed ketone, aldehyde, or aldol groups or with groups which can be shifted to ketone or aldehyde functionality; and, a second reactant which is a primary amine, diamine, or polyamine which by condensation reaction forms a semi-soluble or precipitated filming product with the first reactant.Type: GrantFiled: September 17, 2003Date of Patent: June 20, 2006Assignee: M-I L.L.C.Inventor: Robert Schlemmer
-
Patent number: 7052901Abstract: It has been discovered that fluids viscosified with viscoelastic surfactants (VESs) may have their viscosities reduced (gels broken) by the direct or indirect action of a biochemical agent, such as bacteria, fungi, and/or enzymes. The biochemical agent may directly attack the VES itself, or some other component in the fluid that produces a by-product that then causes viscosity reduction. The biochemical agent may disaggregate or otherwise attack the micellar structure of the VES-gelled fluid. The biochemical agent may produce an enzyme that reduces viscosity by one of these mechanisms. A single biochemical agent may operate simultaneously by two different mechanisms, such as by degrading the VES directly, as well as another component, such as a glycol, the latter mechanism in turn producing a by-product (e.g. an alcohol) that causes viscosity reduction. Alternatively, two or more different biochemical agents may be used simultaneously.Type: GrantFiled: October 24, 2001Date of Patent: May 30, 2006Assignee: Baker Hughes IncorporatedInventor: James B. Crews
-
Patent number: 7008907Abstract: A method and product is disclosed which provides emulsion stability and filtration control to invert emulsion drilling fluids. The product comprises a blend of a carboxylic acid terminated polyamide and/or a wetting agent with a reaction product or mixture produced by the Diels-Alder reaction of dienophiles, preferably carboxylic acids, polycarboxylic acids, acid anhydrides, or combinations or mixes thereof, with a mixture of fatty acids and resin acids. The product of the invention is extremely effective, decreasing by about two-thirds the amount of emulsifier generally required to formulate an effective drilling fluid. The product of the invention also greatly reduces and in many cases eliminates the need for conventional fluid loss additives, and additionally provides electrical stability.Type: GrantFiled: July 1, 2003Date of Patent: March 7, 2006Assignee: Halliburton Energy Services, Inc.Inventors: Jeff Kirsner, Jeff Miller, Jon Bracken
-
Patent number: 6997270Abstract: A method is disclosed that affords improved stability to wellbores during drilling in argillaceous formations with water-based drilling fluids. The method comprises adding to the drilling fluid a compound of the invention having the capacity in water to generate a highly efficient membrane on argillaceous materials. The compound is soluble in the drilling fluid at least at the pH at which the compound is added to the drilling fluid or exists in the drilling fluid, but is insoluble in the water in the pores of the argillaceous formations, or at least at the pH of the water in such pores.Type: GrantFiled: December 30, 2000Date of Patent: February 14, 2006Assignees: Halliburton Energy Services, Inc.Inventors: Fersheed K. Mody, Kenneth W. Pober, Chee P. Tan, Calum J. Drummond, George Georgaklis, Darrell Wells
-
Patent number: 6989354Abstract: An invert emulsion fluid, method for making same, and method for using same as a servicing fluid in a well bore. The invert emulsion fluid contains an oleaginous fluid, a non-oleaginous fluid, and an emulsifier comprising one or more amines generally represented by the formula: wherein R is a cycloaliphatic hydrocarbon, each R? may be the same or different and is H or an alkyl having from about 1 to about 3 carbon atoms, each A may be the same or different and is NH or O, and the sum of x and y ranges from about 1 to about 20. In a preferred embodiment, R is a radical selected from the group consisting of abietyl, dihydroabietyl, tetrahydroabietyl, and dehydroabietyl, R? is H, and A is O.Type: GrantFiled: January 24, 2003Date of Patent: January 24, 2006Assignee: Halliburton Energy Services, Inc.Inventors: Carl J. Thaemlitz, Robert S. Taylor, Ryan M. Foster
-
Patent number: 6964940Abstract: This invention is a method of preparing a quaternized amidoamine surfactant comprising reacting an amidotertiaryamine of formula with methyl halide and alkylene oxide, an aqueous quaternized amidoamine surfactant composition, a gelled aqueous composition comprising the quaternized amidoamine surfactant composition and one or more salts or alcohols and use of the gelled aqueous composition for fracturing subterranean formations.Type: GrantFiled: January 8, 2003Date of Patent: November 15, 2005Assignees: Nalco Energy Services, L.P., Tomah Products, Inc.Inventors: Duane S. Treybig, Grahame N. Taylor, James A. Krogh, Michael J. Williams
-
Patent number: 6921742Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid fluid of potassium formate together with a cationic formation control additive.Type: GrantFiled: August 19, 2002Date of Patent: July 26, 2005Assignee: Clearwater International, L.L.C.Inventor: Kevin W. Smith
-
Patent number: 6914081Abstract: A method of making a rheology modified aqueous composition, particularly useful for drilling, milling and mining applications, is disclosed. The method includes admixing, with a clay and water, a material or materials whose constituents substantially conform to the proportions of the empirical formula M?mM?n(OH)(2m+3n+qa+br)(Aq)a(Br)b.xH2O, where M? is a divalent metal cation, M? is a trivalent metal cation, A and B are anions, and a, b, m, n, q, r, and x are defined herein. Calcined hydrotalcite and hydrotalcite-like materials are particularly preferred as starting materials. Optionally, an aluminum oxide, a nitrogen-containing compound, or both may be added. The resulting composition is preferably an elastic solid exhibiting stress-dependent fluidity, desirable temperature resistance, lubricity, inhibition of reactivity, relatively low cost, and pressure resistance. A dry composition and method of making are also disclosed.Type: GrantFiled: January 5, 2001Date of Patent: July 5, 2005Inventor: Edgar Franklin Hoy
-
Publication number: 20040214725Abstract: Viscoelastic surfactants are described for use in aqueous systems to generate thickened fluids. The surfactants are alkyl amidoamine salts of inorganic acids and/or organic acids. The fluids may also contain inorganic salts, organic salts or mixtures thereof. Additionally, the fluids may contain a co-surfactant. These fluids are particularly useful in oilfield applications such as hydraulic fracturing, gravel packing, drilling, completion, etc. Viscoelastic fluids of the invention are also useful in industrial and consumer product fluid applications as rheology control agents.Type: ApplicationFiled: April 25, 2003Publication date: October 28, 2004Applicant: Tomah Products, Inc.Inventor: David Kelly Moss
-
Publication number: 20040211339Abstract: The present invention is directed to hydraulic cement compositions comprising set-retarding additives and methods of retarding the set of a cement composition utilizing poly(amide) set-retarding additives and methods of cementing in subterranean zones utilizing a cement composition comprising a poly(amide) set-retarding additive.Type: ApplicationFiled: April 22, 2003Publication date: October 28, 2004Inventors: B. Raghava Reddy, Bryan K. Waugh
-
Patent number: 6806233Abstract: Invert emulsion compositions including an oleaginous, a non-oleaginous and an amine surfactant that are useful in the oil and gas well drilling art are disclosed. The amine surfactant is selected so that the invert emulsion can be converted form a water-in-oil type emulsion to a oil-in-water type emulsion upon the protonation of the amine surfactant. Deprotonation of the amine surfactant reverses the conversion. This solution also permits the conversion of oil-wet solids in the fluid into water-wet solids.Type: GrantFiled: June 22, 2001Date of Patent: October 19, 2004Assignee: M-I LLCInventor: Arvind D. Patel
-
Patent number: 6793025Abstract: A method of electrically logging subterranean wells using a conductive double emulsion fluid includes a miscible combination of an oleaginous fluid, an emulsifier capable of forming a microemulsion, an emulsifier capable of forming an invert emulsion, and an electrolytic salt. A microemulsion is the continuous phase of an invert emulsion. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The fluid may additionally contain a polar organic solvent and a carbon dioxide buffer. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like.Type: GrantFiled: June 17, 2002Date of Patent: September 21, 2004Assignee: M-I L. L. C.Inventors: Arvind D. Patel, Reginald J. Bell, Steve Young, Ahmadi Tehrani
-
Patent number: 6790811Abstract: Invert emulsion compositions including an oleaginous, a non-oleaginous and an amine surfactant that are useful in the oil and gas well drilling art are disclosed. The amine surfactant is selected so that the invert emulsion can be converted form a water-in-oil type emulsion to a oil-in-water type emulsion upon the protonation of the amine surfactant. Deprotonation of the amine surfactant reverses the conversion.Type: GrantFiled: January 26, 2001Date of Patent: September 14, 2004Assignee: M-I LLCInventor: Arvind D. Patel
-
Publication number: 20030221832Abstract: Improved methods of generating gas in and foaming aqueous well fluids introduced into a subterranean zone are provided. A method of the invention includes the steps of combining with an alkaline aqueous well fluid one or more gas generating chemicals and a mixture of foaming and foaming stabilizing surfactants so that the gas generating chemical or chemicals react with the alkaline aqueous well fluid and gas and foam are formed in the well fluid while it is being pumped, and then pumping the well fluid into the subterranean zone.Type: ApplicationFiled: May 31, 2002Publication date: December 4, 2003Inventors: B. Raghva Reddy, Krishna M. Ravi, James E. Griffith, Frank Zamora, Karen Luke, John L. Dennis, Ricky A. Cox
-
Patent number: 6642183Abstract: Improved silicate drilling fluids are produced by the addition of tetra alkyl ammonium compounds, in particular tetra methyl ammonium hydroxide to silicate drilling fluid mud to lower the co-efficient of friction between drill string and wellbore. It has also been discovered that the same tetra alkyl ammonium lubricant compounds greatly lessen the viscosity breakdown of swelled hectorite clay in the presence of silicate. This allows the preparation of silicate drilling fluids not only with enhanced lubricity but having stable rheology at the higher temperature and pressures encountered in some drilling operations.Type: GrantFiled: June 4, 2001Date of Patent: November 4, 2003Assignee: National Silicates PartnershipInventors: Jonathan L. Bass, Michael J. McDonald, John C. Urquhart
-
Patent number: 6608005Abstract: Non-aqueous base wellbore fluids characterized by enhanced electrical conductivity due to formulation with specified ionic liquids are disclosed. Drilling, completion, and workover methods utilizing the wellbore fluids are also disclosed.Type: GrantFiled: April 9, 2001Date of Patent: August 19, 2003Assignee: Schlumberger Technology CorporationInventors: Bentley J. Palmer, Diankui Fu, Roger Card, Edgar Volpert
-
Patent number: 6608006Abstract: Methods of drilling well bores using an invertible oil external-water internal emulsion drilling fluid and then inverting the drilling fluid to a water external-oil internal emulsion are provided. The methods basically comprise the steps of contacting the oil external-water internal emulsion with an aqueous acid solution containing an anionic sulfonate surfactant for preventing aqueous acid solution-crude oil emulsions and crude oil sludging and a chemical for preventing the anionic sulfonate surfactant from reacting with the emulsifier in the oil external-water internal emulsion.Type: GrantFiled: September 14, 2001Date of Patent: August 19, 2003Assignee: Halliburton Energy Services, Inc.Inventors: Robert S. Taylor, Suzanne Arnold, Tommy R. Gardner, Karen L. King
-
Publication number: 20030075360Abstract: A method of electrically logging subterranean wells using a conductive double emulsion fluid includes a miscible combination of an oleaginous fluid, an emulsifier capable of forming a microemulsion, an emulsifier capable of forming an invert emulsion, and an electrolytic salt. A microemulsion is the continuous phase of an invert emulsion. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The fluid may additionally contain a polar organic solvent and a carbon dioxide buffer. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like.Type: ApplicationFiled: June 17, 2002Publication date: April 24, 2003Inventors: Arvind D. Patel, Reginald J. Bell, Steve Young, Ahmadi Tehrani
-
Publication number: 20030073585Abstract: A viscous fluid is shown which is useful in treating subterranean formations. The fluid is formulated from an aqueous base, an alkyl sarcosinate surfactant and a buffer suitable for adjusting the pH of the blended fluid to a range in which the fluid is suitably viscosified. The fluid can also include an additional source of anions, such as chloride or fluoride ions, in order to increase the temperature stability of the fluid. The fluids have application for conventional well fracturing, coiled tubing fracturing, gravel packing and frac packing, as well as for use as selective water control additives and other applications.Type: ApplicationFiled: October 21, 2002Publication date: April 17, 2003Inventors: Gino F. Di Lullo Arias, Philip Rae, Atikah J. K. Ahmad
-
Publication number: 20030060372Abstract: Novel corrosion inhibiting compositions comprising a combination of amino thiol or amino disulfide compounds with acidic amino acid polymers inhibit carbon dioxide induced corrosion of ferrous metals in aqueous systems. Particularly effective inhibitor compositions are the natural amino acids cysteine and cystine and their decarboxylated analogues cysteamine and cystamine in combination with polyaspartic acid. The inhibitor compositions are particularly useful for preventing corrosion and scale formation in oil production applications.Type: ApplicationFiled: September 9, 2002Publication date: March 27, 2003Applicant: Donlar CorporationInventors: Joseph C. Fan, Lai-Duien Grace Fan, Jacob Mazo
-
Patent number: 6502637Abstract: Clay is stabilized in the drilling of wells and other formation treatment for hydrocarbon production by the addition to the drilling or other fluid fluid of potassium formate together with a cationic formation control additive.Type: GrantFiled: March 20, 2001Date of Patent: January 7, 2003Assignee: Clearwater, Inc.Inventor: Kevin W. Smith
-
Publication number: 20020182700Abstract: A method of fracturing a subterranean formation which surrounds a well bore comprises the steps of providing a fracturing fluid, and injecting the fracturing fluid into the well bore at a pressure sufficient to form fractures in the subterranean formation which surrounds the well bore. The pressure is then released from the fracturing fluid, after which the fluid may be removed from the well and the well placed into production. The fracturing fluid comprises an aqueous liquid, a polysaccharide soluble or dispersible in the aqueous liquid in an amount sufficient to increase the viscosity of the aqueous liquid, an enzyme breaker which degrades said polysaccharide at a temperature above 180° F. Fracturing fluid compositions and enzyme breaker systems useful for carrying out the invention are also disclosed.Type: ApplicationFiled: May 17, 2002Publication date: December 5, 2002Inventors: Robert M. Kelly, Saad A. Khan, Pascal Leduc, Akash Tayal, Robert K. Prud'homme
-
Patent number: 6478868Abstract: The present invention provides improved early-enhanced strength cement compositions and methods. The cement compositions can be utilized in surface construction projects as well as in the construction of oil, gas and water wells. The improved cement compositions of this invention are basically comprised of a hydraulic cement, water present in an amount sufficient to form a slurry and hydrophobic silica powder.Type: GrantFiled: August 26, 1999Date of Patent: November 12, 2002Assignee: Halliburton Energy Services, Inc.Inventors: Baireddy R. Reddy, Ronald J. Crook, Bryan K. Waugh, Russell M. Fitzgerald, Dennis W. Gray, Brent E. Traxel
-
Patent number: 6436877Abstract: A method of inhibiting or retarding formation of hydrates from water and a lower alkane, such as methane or ethane, involves adding additives which comprise (i) a corrosion inhibitor and (ii) a salt which is of formula [R1(R2)XR3]+Y−, wherein each of R1, R2 and R3 is bonded directly to X, each of R1 and R2, which may be the same or different is an alkyl group of at least 4 carbons, X is S, NR4 or PR4, wherein each of R3 and R4 which may be the same or different represents hydrogen or an organic group, with the proviso that at least one of R3 and R4 is an organic group of at least 4 carbons, and Y is an anion, the additives being added in an amount effective to inhibit or retard hydrate formation, to a medium susceptible to hydrate formation.Type: GrantFiled: April 4, 2000Date of Patent: August 20, 2002Assignee: BP Exploration Operating Co., Ltd.Inventors: Simon Neil Duncum, Christopher George Osborne, Antony Roland Edwards
-
Patent number: 6405809Abstract: A method of electrically logging subterranean wells using a conductive fluid includes a miscible combination of an oleaginous fluid, a polar organic solvent, an electrolytic salt, and a carbon dioxide buffer. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The polar organic solvent may be an oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like. The electrolytic salt or brine preferably includes a quaternary amine salt having the formula: wherein R is an alkyl having 8 to 18 carbon atoms, R′ is 2 to 6 carbon atoms alkyl group, B is hydrogen, oxyalkyl having 1 to 4 carbon atoms or alkyl having 1 to 4 carbon atoms, A is hydrogen or alkyl with 1 to 4 carbon atoms, x+y=1 to 15, z is 0 to 3, and M is a counter anion; or combinations thereof. The carbon dioxide buffer is preferably a trialkylanol amine.Type: GrantFiled: January 10, 2001Date of Patent: June 18, 2002Assignee: M-I LLCInventors: Arvind D. Patel, Reginald J. Bell, Burhan Hoxha, Steve Young
-
Patent number: 6365639Abstract: A method of making a rheology modified aqueous composition, particularly useful for drilling, milling and mining applications, is disclosed. The method includes admixing, with a clay and water, a material or materials whose constituents substantially conform to the proportions of the empirical formula M′mM″n(OH)(2m+3n+qa+br)(Aq)a(Br)b.Type: GrantFiled: January 6, 2000Date of Patent: April 2, 2002Inventor: Edgar Franklin Hoy
-
Publication number: 20010051593Abstract: Invert emulsion compositions including an oleaginous, a non-oleaginous and an amine surfactant that are useful in the oil and gas well drilling art are disclosed. The amine surfactant is selected so that the invert emulsion can be converted form a water-in-oil type emulsion to a oil-in-water type emulsion upon the protonation of the amine surfactant. Deprotonation of the amine surfactant reverses the conversion.Type: ApplicationFiled: January 26, 2001Publication date: December 13, 2001Applicant: M-I, L.L.C.Inventor: Arvind D. Patel
-
Patent number: 6308788Abstract: A method of electrically logging subterranean wells using a conductive fluid in which the conductive fluid includes a miscible combination of an oleaginous fluid, a polar organic solvent, and an electrolytic salt. The electrolytic salt or brine of the salt is present in a concentration sufficient to permit the electrical logging of the subterranean well. The medium may further include gelling agent, weight material, surfactant, or corrosion inhibitors. The polar organic solvent may preferably be a oil soluble glycol or glycol ether such as ethylene glycol, diethylene glycol, propylene glycol, polypropylene glycol, and the like.Type: GrantFiled: February 28, 2000Date of Patent: October 30, 2001Assignee: M-I LLCInventors: Arvind D. Patel, Rejinald J. Bell, Burhan Hoxha
-
Patent number: 6306800Abstract: The improved recovery of hydrocarbons from subterranean formations by fracturing and matrix acidizing a subterranean formation is accomplished. Well treatment fluids having a viscoelastic surfactant fluid containing worm like micelles are useful to improve recovery of hydrocarbons and limit the loss of fracturing fluid into the formation fracture face. The viscolastic surfactant-based fracturing fluids of the present Invention are stable across a wide pH spectrum, allowing them to be used for fracturing treatments at low pH, as well as matrix acidizing treatments. In addition, the stability of these fluids is enhanced in the presence of organic anions. Two-stage fracturing treatments comprised of a viscoelastic surfactant-based fracturing fluid and a polymer-based system, wherein the two fluids are either blended or pumped into the formation sequentially (the polymer last) are also presented.Type: GrantFiled: October 5, 1998Date of Patent: October 23, 2001Assignee: Schlumberger Technology CorporationInventors: Mathew M. Samuel, Keith I. Dismuke, Roger J. Card, J. Ernest Brown, Kevin W. England