Organic Component Contains Sulfur Attached Directly Or Indirectly To Carbon By Nonionic Bonding Patents (Class 507/134)
  • Patent number: 11124687
    Abstract: The present application discloses water-based drilling fluid systems and methods of making water-based drilling fluids systems. According to one embodiment, a drilling fluid system may include a drilling fluid and a lubricant. The lubricant may be synthesized from waste vegetable oil.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: September 21, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Md Amanullah, Jothibasu Ramasamy, Ali Radhwan
  • Patent number: 10793759
    Abstract: A sulfur- and phosphorus-free extreme pressure lubricant and a preparation method thereof is disclosed. The lubricant is prepared by using Turkey red oil, a cyclic anhydride compound, triethanolamine, nano polytetrafluoroethylene powder, an alcohol compound, and water as raw materials. The lubricant does not contain hazardous substances such as sulfur and phosphorus. This reduces the harm to the environment, equipment, and human body, and conforms to the development trend of modern industrial production. Moreover, the lubricant has excellent extreme pressure performance, and can effectively reduce the downhole friction and torque, thereby meeting the construction requirements of extended reach wells and horizontal wells.
    Type: Grant
    Filed: November 15, 2019
    Date of Patent: October 6, 2020
    Assignees: YANGTZE UNIVERSITY, Jingzhou Jiahua Technology Co., Ltd.
    Inventors: Mingbiao Xu, Fuchang You, Shanshan Hou, Jiao Wu
  • Patent number: 10570324
    Abstract: Drilling fluid compositions include invert emulsion fluids having an oleaginous phase, an aqueous phase, and an emulsifier composition that includes an ethoxylated alcohol compound and a polyaminated fatty acid compound. The ethoxylated alcohol compound has the formula R1—(OCH2CH2)n—OH, where R1 is a hydrocarbyl group having from 8 to 22 carbon atoms and n is from 1 to 8. The ethoxylated alcohol compound has a Hydrophilic-Lipophilic Balance (HLB) of less than or equal to 6. The polyaminated fatty acid compound has the formula R2—CO—NH—CH2—CH2—N(COR2)—CH2—CH2—NH—CO—R3, where R2 is a hydrocarbyl group having from 1 to 20 carbon atoms and R3 is a hydrocarbyl group having 1 to 10 carbon atoms or an alkylene carboxylate group having formula —R4—COOH, where R4 is a saturated or unsaturated hydrocarbylene having from 1 to 10 carbon atoms. Methods of drilling wells include operating a drill in a wellbore in the presence of drilling fluid compositions.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: February 25, 2020
    Assignee: Saudi Arabian Oil Company
    Inventors: Vikrant Wagle, Abdullah Al-Yami
  • Patent number: 10563110
    Abstract: Drilling fluid compositions include a base fluid, at least one additive chosen from an emulsifier, weighting material, fluid-loss additive, viscosifier, or alkali compound, and from 0.1 wt. % to 1 wt. %, based on total weight of the drilling fluid composition, of an ethoxylated alcohol compound having the formula R—(OCH2CH2)7—OH, in which R is a saturated or unsaturated, linear or branched hydrocarbyl group having from 8 to 20 carbon atoms. The base fluid may be an aqueous base fluid. Methods for drilling a subterranean well include operating a drill in a wellbore in the presence of a drilling fluid composition including the base fluid, the additive, and the ethoxylated alcohol compound.
    Type: Grant
    Filed: July 17, 2018
    Date of Patent: February 18, 2020
    Assignee: Saudi Arabian Oil Company
    Inventors: Hussain AlBahrani, Abdullah Al-Yami, Ali Safran, Abdulaziz Alhelal
  • Patent number: 10294405
    Abstract: An oil-based drilling fluid with jojoba oil as a main component. Jojoba oil is non-toxic and biodegradable. This environmentally-friendly oil-based drilling fluid also comprises water, a viscosifier, an emulsifier, and an absence of diesel and/or mineral oil.
    Type: Grant
    Filed: October 29, 2015
    Date of Patent: May 21, 2019
    Assignee: King Fahd University of Petroleum and Minerals
    Inventor: Mohammed Enamul Hossain
  • Patent number: 10138406
    Abstract: A drilling fluid lubricant includes a crude tall oil product and a derivative of ricinoleic acid that is at least partially transesterified product. A modified drilling fluid includes a water-based drilling fluid in a range of from about 95 vol. % to about 99 vol. % and a drilling fluid lubricant in a range of from about 0.1 vol. % to about 5 vol. % of the fluid. The drilling fluid lubricant includes a crude tall oil product selected from the group consisting of crude tall oil, distilled tall oil, acid tall oil, fractionated tall oil, and combinations thereof. The drilling fluid lubricant also includes at least partially transesterified derivative of ricinoleic acid product. The product comprises at least partially transesterified derivatives of ricinoleic acid that combined are in a range of from about 88 mole % to about 99 mole % of the product.
    Type: Grant
    Filed: March 2, 2017
    Date of Patent: November 27, 2018
    Assignee: M J Research & Development, LP
    Inventors: Fred P. Massey, Owen N. Massey
  • Patent number: 9834718
    Abstract: Some examples of producing water-based drilling fluids including ecofriendly lubricating additives are described. A raw material oil including fatty acids with a short chain alcohol is esterified in the presence of a catalyst to produce alkyl ester products and triglycerides. The alkyl ester products are washed and heated to remove any residual water or the short chain alcohol. A first quantity of the alkyl ester products is mixed with a second quantity of a water-based wellbore drilling fluid.
    Type: Grant
    Filed: May 6, 2014
    Date of Patent: December 5, 2017
    Assignee: Saudi Arabian Oil Company
    Inventors: Md Amanullah, Abdulaziz S. Bubshait, Omar A. Fuwaires
  • Patent number: 9719006
    Abstract: Biodegradable additive concentrate with pour point according to standard ASTM D 97 below ?5° C., improving the lubricity of water-based muds, comprising at least one compound selected from the group consisting of: the diglycerol mono- and diesters, the acids and the ester derivatives of monocarboxylic fatty acids comprising from 16 to 22 carbon atoms per chain, the acids and the ester derivatives of resin acids, the monoesters of polyol comprising more than 4 hydroxylated groups and of carboxylic fatty acids comprising from 6 to 12 carbon atoms, saturated and unsaturated by at least one unsaturation, and the mono- and polyalkoxylated esters of saturated and unsaturated dicarboxylic acids comprising from 6 to 12 carbon atoms. The use of this concentrate in a water-based mud and the water-based mud containing said concentrate that can be used for drilling.
    Type: Grant
    Filed: December 23, 2013
    Date of Patent: August 1, 2017
    Assignee: TOTAL MARKETING SERVICES
    Inventors: Géraldine Delorme, Thomas Dubois
  • Patent number: 9453157
    Abstract: A viscosity reducer based on vegetable extracts of natural origin is disclosed. The vegetable extracts include a mixture of phosphoglycerides and vegetable oils. A method of reducing the viscosity in heavy and extra heavy crude oil using the viscosity reducer is also disclosed. No aromatic base solvents are needed. A reduction in diluent usage is achieved using the viscosity reducer based on vegetable extracts. The viscosity reducer composition includes a mixture of phosphoglycerides, vegetable oil, non-aromatic solvent, polycyclic aromatic hydrocarbon and stabilizer.
    Type: Grant
    Filed: October 8, 2014
    Date of Patent: September 27, 2016
    Assignee: Oil & Gas Tech Enterprises C.V.
    Inventor: Cridal Del Valle Sencial Bello
  • Patent number: 9334436
    Abstract: A method to recover oil from an oil bearing substrate, and a reclaimed oil produced thereby having improved properties relative to the oil originally present in the substrate. Fluids comprising the recovered oil are also disclosed.
    Type: Grant
    Filed: May 13, 2015
    Date of Patent: May 10, 2016
    Assignee: Racional Energy and Environment Company
    Inventor: Ramon Perez-Cordova
  • Publication number: 20130261030
    Abstract: A fluid may contain nanoparticles and a base fluid where the base fluid may be a non-aqueous fluid. The base fluid may be, but is not limited to a drilling fluid, a completion fluid, a production fluid, and/or a stimulation fluid. The fluid may have at least one property, such as but not limited to a dielectric constant ranging from about 5 to about 10,000, an electrical conductivity ranging from about 1×10?6 S/m to about 1 S/m, and combinations thereof. The non-aqueous fluid may be a brine-in-oil emulsion, or a water-in-oil emulsion, and combinations thereof. The addition of nanoparticles to the base fluid may modify the electrical properties of the fluid.
    Type: Application
    Filed: May 28, 2013
    Publication date: October 3, 2013
    Inventors: Othon Monteiro, Daniel R. Ellis
  • Publication number: 20130130942
    Abstract: A water-based drilling fluid which includes an aqueous fluid and a water-soluble dissipative surfactant composition is described, wherein the dissipative surfactant composition includes at least one fatty acid or ester derivative of a plant or vegetable oil. Also described are methods of using such aqueous-based drilling fluids including the dissipative surfactant composition as described in hydrocarbon recovery operations associated with oil/tar sand, where such fluids act to increase the dispersant qualities of hydrocarbons within the oil/tar sand, and where such fluid exhibit a reduced coefficient of friction.
    Type: Application
    Filed: November 21, 2012
    Publication date: May 23, 2013
    Applicant: TEXAS UNITED CHEMICAL COMPANY, LLC
    Inventor: Texas United Chemical Company, LLC
  • Patent number: 8424619
    Abstract: This invention is based upon the finding that certain chlorosulfonated ?-olefin copolymers can be beneficially utilized in drilling fluids that are utilized in drilling subterreanean wells. For instance, it has been unexpectedly found that certain chlorosulfonated ?-olefin copolymers can be beneficially used as total or partial replacements for organoclays in oil based drilling fluids.
    Type: Grant
    Filed: July 12, 2011
    Date of Patent: April 23, 2013
    Assignee: Eliokem S.A.S.
    Inventors: Cecile Mazard, Bertrand Guichard, Andrea Valenti
  • Publication number: 20120149604
    Abstract: A method for analyzing formation fluid in a subterranean formation is disclosed, wherein the method includes the steps of: adding a scavenger compound to an analytical reagent to form a reagent solution; collecting an amount of formation fluid into a formation tester, wherein the formation tester includes at least one fluids analyzer comprising at least one probe, at least one flow line, at least one reagent container, and at least one spectral analyzer, wherein the fluids analyzer is configured such that the collected formation fluid is fed through the at least one flow line to the at least one spectral analyzer; mixing an amount of the collected formation fluid with an amount of the reagent solution to form a mixture; and analyzing the mixture downhole.
    Type: Application
    Filed: December 5, 2011
    Publication date: June 14, 2012
    Inventors: Jimmy Lawrence, Huilin Tu, Jane Lam, Rekha Agarwalla, Ronald E. G. van Hal
  • Patent number: 8148303
    Abstract: A method comprises providing a drilling fluid comprising: an aqueous fluid; and a microemulsion surfactant; and drilling a well bore in a subterranean formation comprising an oleaginous fluid using the drilling fluid, wherein the microemulsion surfactant forms a microemulsion with the oleaginous fluid within the well bore. In accordance with the method, the subterranean formation has a retained producibility greater than about 50%.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: April 3, 2012
    Assignee: Halliburton Energy Services Inc.
    Inventors: Ryan Van Zanten, David Horton, Per-Bjarte Tanche-Larsen
  • Patent number: 8071510
    Abstract: The lubricity of a drilling fluid or a completion fluid may be increased by incorporating into the fluid a water-soluble or water-dispersible salt of a sulfonated (sulfated) vegetable oil or a derivative thereof, such as a sulfonated (sulfated) castor oil. Suitable derivatives include the sodium, potassium, calcium, magnesium or ammonium salt. A non-ionic or anionic surfactant which is capable of enhancing the solubility of the salt may further be incorporated into the drilling fluid or completion fluid.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: December 6, 2011
    Assignee: Baker Hughes Incorporated
    Inventors: William Chrys Scoggins, Mingjie Ke
  • Patent number: 8003576
    Abstract: This invention relates to improved lubrication in drilling and completion fluids used in subterrane drilling for oil and gas. The addition of zinc dialkyl dithiophosphate (ZDDP) acts as a lubricant, an enhancer to other lubricants and rate of penetration enhancer.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: August 23, 2011
    Assignee: The Lubrizol Corporation
    Inventor: Michael J. McDonald
  • Patent number: 7998905
    Abstract: This invention is based upon the finding that certain chlorosulfonated ?-olefin copolymers can be beneficially utilized in drilling fluids that are utilized in drilling subterreanean wells. For instance, it has been unexpectedly found that certain chlorosulfonated ?-olefin copolymers can be beneficially used as total or partial replacements for organoclays in oil based drilling fluids. The chlorosulfonated a-olefin copolymers that are useful in the practice of this invention are typically chlorosulfonated ethylene/octene copolymers or chlorosulfonated ethylene/butene copolymers. The utilization of chlorosulfonated ?-olefin copolymers in oil-based drilling fluids offers (1) long service life at high operating temperatures, (2) minimal formation damage, (3) improved filtration behavior, and (4) highly effective performance at low viscosifier levels.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: August 16, 2011
    Assignee: Eliokem S.A.S.
    Inventors: Cecile Mazard, Bertrand Guichard, Andrea Valenti
  • Patent number: 7959743
    Abstract: The invention relates to a process of cleaning boreholes, boring equipment and borings with an aqueous cleaning of one more lithium salts of alkyl sulfates of formula (I): R—O—SO3?Li+??(I) in which R is a saturated, unsaturated, branched or linear alkyl group containing 8 to 22 carbon atoms, preferably the lithium salts of alkyl sulfates are comprised of a mixture of those in which R is a saturated, linear alkyl groups having 8 to 14 carbon atoms.
    Type: Grant
    Filed: July 6, 2005
    Date of Patent: June 14, 2011
    Assignee: Cognis Oleochemicals GmbH
    Inventors: Heinz Mueller, Diana Maeker, Nadja Herzog
  • Patent number: 7915203
    Abstract: A new class of secondary emulsifying agents for use in inverted mud and other inverted system is disclosed and method for making and using same.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: March 29, 2011
    Assignee: Clearwater International, LLC
    Inventors: Olusegun Matthew Falana, Arthur T. Gilmer, Edward Marshall
  • Patent number: 7842651
    Abstract: The present disclosure relates to the compositions of a water-based silicate drilling fluid comprising: (1) alkali metal silicates; (2) cationic polyacrylamide; (3) a lubricant composition; and (4) other conventional drilling fluid additives. The lubricant composition comprises a lubricating effective amount of a carrier oil and one or more lubricants selected from lecithins, sulfurized vegetable and/or lard oils or modified castor oil.
    Type: Grant
    Filed: December 8, 2008
    Date of Patent: November 30, 2010
    Assignee: Chengdu Cationic Chemistry Company, Inc.
    Inventors: Anming Wu, Xing Yan
  • Publication number: 20100298174
    Abstract: A method of slurrifying drill cuttings that includes admixing oil-contaminated drill cuttings, water, and at least one surface active agent; emulsifying at least a portion of the oil contaminants within the mixture; and forming a pourable slurry of drill cuttings in water is disclosed.
    Type: Application
    Filed: July 23, 2008
    Publication date: November 25, 2010
    Applicant: M-I L.L.C.
    Inventors: Mostafa Ahmadi Tehrani, Mary Ann George
  • Publication number: 20100267592
    Abstract: Multi-component additive for incorporation into a drilling fluid, and a drilling fluid system comprising said multi-component additive. The additive preferably comprises three primary components: (1) a rate of penetration enhancer, namely one of a number of synthetic (non-toxic) ester-based or olefin-based oils as a carrier for other additives, such as surfactants; (2) a lubricant, namely one or more of a number of chlorinated waxes, chlorinated olefins, and plant based fatty acids; and (3) a clay inhibitor/stabilizer, such as a polyglycol. Preferably, the three components are pre-mixed in a single container, for ease in use in adding to a drilling fluid system. The additive may be incorporated into a drilling fluid system at a shore based facility, and the “liquid mud” transported to a drilling rig; or the additive may be brought to the drilling rig and incorporated into a drilling fluid system on site.
    Type: Application
    Filed: December 2, 2009
    Publication date: October 21, 2010
    Applicant: AMBAR LONESTAR FLUID SERVICES LLC
    Inventor: Ronald L. Brazzel
  • Patent number: 7635667
    Abstract: Multi-component additive for incorporation into a drilling fluid, and a drilling fluid system comprising said multi-component additive. The additive preferably comprises three primary components: (1) a rate of penetration enhancer, namely one of a number of synthetic (non-toxic) ester-based or olefin-based oils as a carrier for other additives, such as surfactants; (2) a lubricant, namely one or more of a number of chlorinated waxes, chlorinated olefins, and plant based fatty acids; and (3) a clay inhibitor/stabilizer, such as a polyglycol. Preferably, the three components are pre-mixed in a single container, for ease in use in adding to a drilling fluid system. The additive may be incorporated into a drilling fluid system at a shore based facility, and the “liquid mud” transported to a drilling rig; or the additive may be brought to the drilling rig and incorporated into a drilling fluid system on site.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: December 22, 2009
    Assignee: Ambar Lonestar Fluid Services, LLC
    Inventor: Ronald L. Brazzel
  • Patent number: 7622427
    Abstract: A completion and workover fluid composition comprising, water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient selected from the group consisting of inorganic salts, shale inhibitors, corrosion inhibitor, biocide, defoamers and finely divided solids particles (e.g., bentonite, attapulgite, sepiolite, calcium carbonate, etc.), depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent is an ethoxylated raw cotton linters or a modified ethoxylated raw cotton linters. The ethoxylated raw cotton linters provides comparable or better rheology and viscosity properties compared to high molecular weight commercial HECs made from purified cotton linters. These ethoxylated raw cotton linters derivatives are suitable for applications in oil-well servicing fluids, particularly to enhance functional properties of completion and workover fluids used during oil-well drilling operations.
    Type: Grant
    Filed: February 21, 2007
    Date of Patent: November 24, 2009
    Assignee: Hercules Incorporated
    Inventors: Arjun C. Sau, Mohand Melbouci
  • Patent number: 7576039
    Abstract: Subject matter of the present invention is a drilling fluid additive based on sulfonated asphalt, which comprises a water soluble and anionic polymer component in quantities of 0.1 to 20 wt. %, with respect to the total additive in addition to the asphalt component. With this additive the water solubility of sulfonated asphalt can be markedly increased. This additive, whose polymer component is thermally highly stable, is utilized primarily in water- and/or oil-based drilling fluids and in particular in the exploration of subterraneous petroleum and natural gas deposits. Typical polymer components to consider are representatives of polycondensation products, such as phenol resins, ketone resins and sulfonated naphthalene, acetone and amino plasticizer resins (for example urea and melamine resins).
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: August 18, 2009
    Assignee: BASF Construction Polymers GmbH
    Inventors: Johann Huber, Johann Plank, Jürgen Heidlas, Gregor Keilhofer, Peter Lange
  • Patent number: 7541315
    Abstract: Disclosed are paraffin inhibitors prepared by admixing a polymer having the characteristic of inhibiting paraffin crystalline growth in formation fluid from oil and gas wells with a first solvent selected from the weak to moderate wax solvents and a second solvent selected from the strong wax solvents. Exemplary weak to moderate wax solvents include benzene, toluene, xylene, ethyl benzene, propyl benzene, trimethyl benzene and mixtures thereof. Exemplary strong wax solvents include cyclopentane, cyclohexane, carbon disulfide, decalin and mixtures thereof. The solvent system disclosed has desirably better solubility with the polymers, even at reduced temperatures, than either solvent alone. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will be used to interpret or limit the scope or meaning of the claims.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: June 2, 2009
    Assignee: Baker Hughes Incorporated
    Inventor: David Wayne Jennings
  • Publication number: 20090075846
    Abstract: Fluid producing wells may be treated with a water-in-oil emulsion for the removal or inhibition of unwanted solid particulates, including pipe dope, asphaltenes and paraffins. Such emulsions are of particular applicability in the displacement of oil base drilling muds and/or residues from such muds from producing wells. The water-in-oil emulsions may optionally contain a dispersing agent as well as a surfactant.
    Type: Application
    Filed: November 19, 2008
    Publication date: March 19, 2009
    Applicant: BJ Services Company
    Inventors: Qi Qu, Richard F. Stevens, JR., David Alleman
  • Patent number: 7470419
    Abstract: The present application relates to granules of powdery mineral particles produced by spray granulation of a liquid slurry comprising powdery minerals particles having particle size below 10 m, at least one water-reducing agent and/or at least one binder agent and/or at least one dispersing agent. The application further relates to a method for producing such granules.
    Type: Grant
    Filed: June 16, 2005
    Date of Patent: December 30, 2008
    Assignee: Elkem AS
    Inventor: Tor Soyland Hansen
  • Publication number: 20080234145
    Abstract: The invention relates to the use of compounds of general formula (I): R—O—SO—Li+, wherein R represents a saturated, unsaturated, branched or linear alkyl radical comprising 8-22 C-atoms, for cleaning boreholes, boring devices and borings.
    Type: Application
    Filed: July 6, 2005
    Publication date: September 25, 2008
    Inventors: Heinz Mueller, Diana Maeker, Nadja Herzog
  • Patent number: 7384892
    Abstract: A water-based drilling fluid composition includes water and at least one rheology modifier and/or fluid loss control agent, and at least one other ingredient of polymeric additive, inorganic salts, dispersants, shale stabilizers, weighting agents, or finely divided clay particles, depending upon the desired attributes, wherein the rheology modifier and/or the fluid loss control agent comprises carboxymethylated raw cotton linters (CM-RCL) made from the baled raw cotton linters or comminuted raw cotton linters with increased bulk density.
    Type: Grant
    Filed: July 22, 2004
    Date of Patent: June 10, 2008
    Assignee: Hercules Incorporated
    Inventors: Mohand Melbouci, Arjun C. Sau
  • Patent number: 7148183
    Abstract: Water based drilling, drill-in, and completion fluids comprising surfactant-polymer blends that are effective to generate effective rheology comprising low shear rate viscosity and effective fluid loss control properties. The water based fluids preferably are substantially solid free.
    Type: Grant
    Filed: December 14, 2001
    Date of Patent: December 12, 2006
    Assignee: Baker Hughes Incorporated
    Inventor: Lirio Quintero
  • Patent number: 7131492
    Abstract: This invention relates to divinyl sulfone crosslinking agents, viscosified treatment fluids, and methods of using these compositions in applications wherein viscosified treatment fluids may be used. In one embodiment, this invention provides a method of treating a portion of a subterranean formation comprising: providing a viscosified treatment fluid that comprises an aqueous base fluid and a crosslinked gelling agent, the crosslinked gelling agent comprising at least one alkyl sulfone bridge, and treating the portion of the subterranean formation.
    Type: Grant
    Filed: October 20, 2004
    Date of Patent: November 7, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Robert M. Kriegel
  • Patent number: 7077219
    Abstract: Methods in which temperature is used to control the foaming and/or defoaming of foamed treatment fluids comprising an aqueous liquid, an ionic foaming surfactant, and a gas are provided. A method of treating at least a portion of a subterranean formation is provided, the method comprising: providing a treatment fluid having a foam transition temperature, the treatment fluid comprising an aqueous liquid, and an ionic foaming surfactant; foaming the treatment fluid to form a foamed treatment fluid; circulating the foamed treatment fluid in a well bore penetrating the subterranean formation; and defoaming at least a substantial portion of the foamed treatment fluid, the defoaming comprising lowering the temperature of the foamed treatment fluid to about at or below the foam transition temperature.
    Type: Grant
    Filed: February 18, 2005
    Date of Patent: July 18, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Gary P. Funkhouser, Bobby J. King
  • Patent number: 6994173
    Abstract: A method for drilling a borehole employing a drilling fluid including an additive comprising a glucose derivative with pH lowering acid, buffers and surface active agents. The drilling fluid additive preferably exhibits the following properties: activity of approximately 30%–45% in water solution; pH of about 4.5 to 5.5; a light amber to clear liquid appearance and a density of approximately 1.200 grams per cubic centimeter.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: February 7, 2006
    Assignee: ACT Technologies, Inc.
    Inventor: Jerry R. West
  • Patent number: 6800592
    Abstract: A foamable drilling fluid is provided which includes an aqueous solvent; a surfactant; and a polysaccharide preferably derived from a galactomannan gum. The foamed drilling fluid includes a liquid phase consisting of the aqueous solvent, polysaccharide and surfactant, and a gas phase of air, nitrogen, natural gas, CO2 and mixtures thereof. The drilling fluid is stable in the presence of crude oil and salt and environmentally friendly.
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: October 5, 2004
    Assignee: Intevep, S.A.
    Inventors: Yenny Virginia Rojas, Alida del Carmen Aponte
  • Patent number: 6800593
    Abstract: Disclosed is a hydrophilic, water soluble polymer concentrate for addition to aqueous liquids to enhance the properties thereof, particularly to increase the viscosity or decrease the fluid loss of well drilling and servicing fluids, the concentrate comprising a hydrophobic, water insoluble liquid, an organophilic clay suspension agent, the water soluble polymer, and a stabilizing agent comprising one or more acids in an amount from about 0.001% to about 1.5%, one or more anionic surfactants in an amount from about 0.001% to about 1.0%, one or more nonionic surfactants in an amount from 0.001% to about 0.625% and, from about 0% to about 0.75% of one or more water soluble organic liquids, wherein the total concentration of the stabilizing agent is from about 0.1% to about 2.5%, these percentages being based on the weight of the concentrate.
    Type: Grant
    Filed: June 19, 2002
    Date of Patent: October 5, 2004
    Assignee: Texas United Chemical Company, LLC.
    Inventors: James W. Dobson, Jr., Shauna Leigh Hayden, Carolina Trejo Rangel
  • Patent number: 6770603
    Abstract: A wellbore fluid having a non-aqueous continuous liquid phase that exhibits an electrical conductivity increased by a factor in order of 104 to 107 compared to conventional invert emulsion comprises from about 0.2% to about 10% by volume of carbon black particles and one or more emulsifying surfactant(s) selected from the class including nonionic emulsifiers of Hydrophilic-Lipophilic Balance (HLB) less than about 12, and anionic surfactants wherein the counter-ion (cation) is any of alkali metal, ammonium, or hydrogen ions. This wellbore fluid can be used for drilling or completing a well and can be used for providing enhanced information from electrical logging tools, measurement while drilling, logging while drilling, geosteering and the like.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: August 3, 2004
    Assignee: M-I L.L.C.
    Inventors: Christopher Sawdon, Mostafa Tehrani, Paul Craddock, Anthony Lawson
  • Patent number: 6762154
    Abstract: Present invention relates to high brine carrier fluid, said carrier fluid selected from the group consisting of organic acids, organic acid salts, inorganic salts and combination of one or more organic acids or organic acid salts, a co-surfactant and an amount of a zwitterionic surfactant. The invention also relates to methods of treating a subterranean wellbore, including drilling, hydraulic fracturing, gravel placement, scale removing, mud cake removing, using said high brine carrier fluid.
    Type: Grant
    Filed: July 30, 2001
    Date of Patent: July 13, 2004
    Assignee: Schlumberger Technology Corporation
    Inventors: Bernhard Lungwitz, Mark E. Brady, Sylvie Daniel, Mehmet Parlar, Colin J. Price-Smith, Elizabeth Morris
  • Patent number: 6525003
    Abstract: A well logging fluid is provided having a relatively non-conductive fluid and an effective amount of a salt sufficient to modify the electrical characteristics the relatively non-conductive fluid resulting in a modified fluid or well logging fluid such that an electrical well-logging tool when disposed in the modified fluid can perform an electrical well-logging survey of a borehole containing the modified fluid. The non-conductive fluid is selected from the group consisting of a non-aqueous fluid and an invert emulsion of an aqueous phase in a non-conductive liquid. In an invert emulsion, the aqueous portion thereof ranges up to about 70 percent by volume. The salt has a cation and an anion, wherein the cation is selected from the group consisting of divalent and trivalent metal cations capable of forming a complex, and the anion is one that disassociates from the cation in an aqueous medium.
    Type: Grant
    Filed: April 8, 1998
    Date of Patent: February 25, 2003
    Inventors: Robert P. Schlemmer, Edward Keith Morton
  • Publication number: 20020061823
    Abstract: A well logging fluid is provided having a relatively non-conductive fluid and an effective amount of a salt sufficient to modify the electrical characteristics the relatively non-conductive fluid resulting in a modified fluid or well logging fluid such that an electrical well-logging tool when disposed in the modified fluid can perform an electrical well-logging survey of a borehole containing the modified fluid. The non-conductive fluid is selected from the group consisting of a non-aqueous fluid and an invert emulsion of an aqueous phase in a non-conductive liquid. In an invert emulsion, the aqueous portion thereof ranges up to about 70 percent by volume. The salt has a cation and an anion, wherein the cation is selected from the group consisting of divalent and trivalent metal cations capable of forming a complex, and the anion is one that disassociates from the cation in an aqueous medium.
    Type: Application
    Filed: April 8, 1998
    Publication date: May 23, 2002
    Inventors: ROBERT P. SCHLEMMER, EDWARD KEITH MORTON
  • Patent number: 6194354
    Abstract: A pourable concentrate suitable for forming structured surfactant drilling muds on dilution with aqueous electrolyte comprises: a) from 30 to 80% by weight, based on the weight of the composition, of surfactant consisting of at least 25%, based on the weight of the surfactant, of an anionic surfactant, from 0 to 70% by weight, based on the total weight of surfactant, of an alkanolamide, and from 0 to 20% based on the total weight of surfactant, of other non-ionic surfactant and/or amphoteric surfactants; b) from 3 to 60% by weight of the composition of a compound of the formula RHX where R is hydrogen or a C1-6 alkyl group and X is a random or block copolymeric chain comprising a total of from 3 to 20 ethoxy and propoxy units in a relative numerical proportion of 0 to 10:1; and c) up to 65% by weight of water.
    Type: Grant
    Filed: September 18, 1998
    Date of Patent: February 27, 2001
    Assignee: Albright & Wilson UK Limited
    Inventor: Kevan Hatchman
  • Patent number: 6166095
    Abstract: A pourable aqueous composition for use as, or for dilution to form, a drilling mud comprises a least 2% by weight of a water soluble polyvalent metal salt of an alkyl polyoxyalkylene sulphuric or carboxylic acid, and at least 1% by weight of a corresponding salt of an alkyl benzene sulphuric acid, preferably in the presence of a water soluble inorganic salt or base of said polyvalent metal.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: December 26, 2000
    Assignee: Albright & Wilson UK Limited
    Inventors: Edward Bryan, Boyd William Grover, William John Nicholson
  • Patent number: 5707940
    Abstract: An oil-in-water emulsion composition is disclosed which comprises a mixture of brine and;(A) at least one natural oil or synthetic triglyceride of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently saturated or unsaturated aliphatic groups that contain from about 7 to about 23 carbon atoms;(B) at least one alcohol, R.sup.4 OH wherein R.sup.4 is an aliphatic group containing from 1 up to about 18 carbon atoms;(C) at least one emulsifier; and(D) at least one sulfurized composition wherein (B), (C) and (D) are soluble and reside within (A).
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: January 13, 1998
    Assignee: The Lubrizol Corporation
    Inventors: James H. Bush, Richard W. Jahnke
  • Patent number: 5658860
    Abstract: A well fluid emusion having a water phase and an oil phase of a sulfurized alcohol and a naturally occuring fat, oil or derivatives thereof. Also disclosed is a method of lubricating drilling equipment used in conjunction with the drilling, completion or workover of a subterranean well. The method includes introducing the above emulsified well fluid into the well for circulation through and out of the well, and further includes contacting the surface of the drilling equipment with the emulsified well fluid to provide an interface between the equipment surface and the water phase. Suitable naturally occurring fats and oils may be obtained from the following animal oils and fats: butter, lard, tallow, grease, herring, menhaden, pilchard and sardine; and from the following vegetable oils and fats: castor, coconut, coffee, corn, cottonseed, jojoba, linseed, liticica, olive, palm, palm kernel, peanut, rapeseed, safflower, soya, sunflower, tall and tung.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: August 19, 1997
    Assignee: Baker Hughes Incorporated
    Inventors: David E. Clark, William M. Dye
  • Patent number: 5593954
    Abstract: A drilling fluid composition comprising a mixture of a brine (A) an emulsifier, and (B) an oil soluble friction modifier of the following formula: ##STR1## where X=1 to 4,z=1 to 6,Q=0 to 2R.sub.1 and R.sub.2 are independently H or an aliphatic group containing from 1 to about 16 carbon atoms, provided that the sum of R.sub.1 and R.sub.2 is between 0 and about 16,R' is an aliphatic group containing an average of from about 8 to about 24 carbon atoms, andR" is selected from the group consisting of H, an aliphatic group containing between 1 and an average of about 18 carbons, and ##STR2## where Q, X, z, R.sub.1, R.sub.2, R' and R" are defined as set forth above, and Y is 0 to 5 is disclosed. The compositions of the present invention have beneficial lubrication properties. These compositions are useful in drilling, working and completing well bore holes.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: January 14, 1997
    Assignee: The Lubrizol Corporation
    Inventor: George A. Malchow, Jr.
  • Patent number: 5593953
    Abstract: This invention relates to a composition comprising a water-in-oil emulsion formed from a brine, a liquid oil, (A) an emulsifier, (B) a friction modifier of the following formula: ##STR1## where X=1 to 4, z=1 to 6,Q=0 to 2R.sub.1 and R.sub.2 are independently H or an aliphatic group containing from 1 to about 16 carbon atoms, provided that the sum of R.sub.1 and R.sub.2 is between 0 and about 16,R' is an aliphatic group containing an average of from about 8 to about 24 carbon atoms, andR" is selected from the group consisting of H, an aliphatic group containing between 1 and an average of about 18 carbons, and ##STR2## where Q, X, z, R.sub.1, R.sub.2, R' and R" are defined as set forth above, and Y is 0 to 5. In a preferred embodiment, z is 1. In the most preferred embodiment, Q=0, R.sub.1 and R.sub.2 are both H, X, and z all equal 1, R' is n-dodecyl, and R" is H. The compositions of the present invention have beneficial lubrication properties.
    Type: Grant
    Filed: April 26, 1995
    Date of Patent: January 14, 1997
    Assignee: The Lubrizol Corporation
    Inventor: George A. Malchow, Jr.
  • Patent number: 5513712
    Abstract: A process employing a polymer enhanced foam in a wellbore as a drilling fluid during a wellbore drilling operation. The polymer enhanced foam is formed from an uncrosslinked acrylamide polymer, a surfactant, an aqueous solvent, and an added gas.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: May 7, 1996
    Assignee: Marathon Oil Company
    Inventor: Robert D. Sydansk
  • Patent number: H1000
    Abstract: The present invention relates to an improved water based drilling fluid and an improved spotting fluid utilizing unhydrogenated synthetic hydrocarbon compositions which are non-polluting and minimally toxic. The invention provides excellent drilling fluid properties under a wide variety of drilling conditions. The synthetic hydrocabons are selected from the group consisting of branched chain oligomers synthesized from one or more olefins containing a C.sub.2 to C.sub.14 chain length and wherein the oligomers have an average molecular weight of from 120 to 1000. The compositions of these hydrocarbons are free of aromatics and petroleum based toxic impurities. The synthetic hydrocarbons are unhydrogenated.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: December 3, 1991
    Assignee: M-I Drilling Fluids Company
    Inventors: Arvind D. Patel, Raymond E. McGlothlin