Inorganic Component Is Elemental Metal Or Alloy Patents (Class 507/270)
  • Patent number: 10273401
    Abstract: A hydraulic fracturing process comprises combining an aqueous carrier with a superabsorbent polymer and a plurality of proppant particles to form a fracturing fluid; and disposing the fracturing fluid in a downhole environment. When the aqueous carrier has a total dissolved solid content of equal to or less than 400 parts per million and a hardness of less than 100 parts per million as calcium carbonate, the superabsorbent polymer comprises particles having a size of about 145 microns to about 600 microns. When the aqueous carrier has a total dissolved solid content of greater than 400 parts per million to less than 8,000 parts per million and a hardness of greater than 100 parts per million to less than 2,500 parts per million as calcium carbonate, the superabsorbent polymer comprises particles having a size of about 145 microns to about 300 microns.
    Type: Grant
    Filed: January 4, 2017
    Date of Patent: April 30, 2019
    Assignee: BAKER HUGHES, A GE COMPNAY, LLC
    Inventors: Hong Sun, Paul S. Carman, Alyssa Michelle Volk, Johnny Chapman
  • Patent number: 10030493
    Abstract: It is often desirable to suppress the growth of bacteria when conducting oilfield operations, particularly in the subterranean environment. Methods for suppressing growth of bacteria can comprise: providing a plurality of biocidal proppant particulates, the biocidal proppant particulates comprising a biocidal coating upon proppant particulates, the biocidal coating comprising a plurality of biocidal nanoparticles dispersed within a binder material; introducing the biocidal proppant particulates into a wellbore penetrating a subterranean formation; localizing at least a portion of the biocidal proppant particulates within the subterranean formation; and suppressing growth of one or more types of bacteria with the biocidal nanoparticles in the wellbore or in the subterranean formation.
    Type: Grant
    Filed: September 24, 2014
    Date of Patent: July 24, 2018
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Philip D. Nguyen, Prashant D. Chopade, David Loveless
  • Patent number: 9970265
    Abstract: Systems and methods for creating and/or using multi-functional surfactant complexes that may enhance surfactant treatments in subterranean formations are provided. In some embodiments, the methods comprise: providing a treatment fluid comprising an aqueous base fluid and one or more multi-functional surfactant complexes that comprise at least one surfactant and at least one polymeric additive, wherein the surfactant and the polymeric additive carry opposite charges; and introducing the treatment fluid into a well bore at a well site penetrating at least a portion of a subterranean formation.
    Type: Grant
    Filed: June 28, 2017
    Date of Patent: May 15, 2018
    Assignee: Multi-Chem Group, LLC
    Inventors: Liang Xu, Jayant Rane, Kai He
  • Patent number: 9145511
    Abstract: A method includes providing and adding a measured dose amount of manufactured metallic nanoparticle material to a carrier material for pre-treatment of the carrier material prior to use of the carrier material and the manufactured metallic nanoparticle material in the sub-surface earth activity. Another method includes accessing a sub-surface earth opening used with a sub-surface earth activity, introducing an amount of manufactured metallic nanoparticle material into the sub-surface earth opening, and treating a sub-surface earth condition present at a sub-surface earth location accessible via the sub-surface earth opening. The sub-surface earth condition is treated with the manufactured metallic nanoparticle material. Another method includes accessing a product from a sub-surface earth location that is extracted in conjunction with the sub-surface earth activity, measuring and introducing a dose amount of manufactured metallic nanoparticle material with the product from the sub-surface earth location.
    Type: Grant
    Filed: February 7, 2012
    Date of Patent: September 29, 2015
    Assignee: Pure Liquid Solutions, LLC
    Inventors: Ray Woodrow McCubbins, Jr., Nathan Jared Whiting, Fred Vincent Schillreff, Larry George Miller, Theron Glade Miller
  • Patent number: 9038719
    Abstract: A pourable aqueous cement composition is disclosed. The cement composition comprises a hydraulic cement, water and a selectively removable material comprising a plurality of selectively corrodible metal powder particles dispersed within the cement or a nanomatrix powder compact, or a combination thereof. An article, including a downhole article, and more particularly a reconfigurable downhole article is disclosed. The article includes a hydraulic cement, wherein the hydraulic cement has at least partially set into a permanent form. The article also includes a selectively removable material dispersed within the cement, the selectively removable material comprising a plurality of selectively corrodible metal powder particles dispersed within the cement or a nanomatrix powder compact, or a combination thereof, wherein the selectively removable material is configured for removal in response to a predetermined wellbore condition.
    Type: Grant
    Filed: September 20, 2011
    Date of Patent: May 26, 2015
    Assignee: Baker Hughes Incorporated
    Inventor: James Crews
  • Patent number: 9029299
    Abstract: Agents, chemicals and particles may be controllably released at remote locations, such as pre-selected or predetermined portions of subterranean formations, by binding or associating or trapping them with an association of micelles formed by a viscoelastic surfactant (VES) in an aqueous base fluid to increase the viscosity of the fluid. An internal breaker within the association of micelles disturbs the association of micelles at some later, predictable or predetermined time thereby reducing the viscosity of the aqueous viscoelastic treating fluid and releasing the agent, chemical or particle at a predetermined or selected location.
    Type: Grant
    Filed: March 16, 2009
    Date of Patent: May 12, 2015
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang
  • Patent number: 9018143
    Abstract: A method for breaking the viscosity of an aqueous fluid gelled with a water soluble polymer or a VES is disclosed. The method includes providing an aqueous fluid. The method also includes adding to the aqueous fluid, in any order: a water soluble polymer in an amount sufficient to form a gelled aqueous fluid having a viscosity, a water soluble oxidizing agent configured to generate free radicals and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid, the metallic particles configured to dissolve in the gelled aqueous fluid and provide a reducing agent to accelerate the generation of free radicals. The method further includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective accelerate the generation of free radicals and reduce the viscosity.
    Type: Grant
    Filed: November 18, 2011
    Date of Patent: April 28, 2015
    Assignee: Baker Hughes Incorporated
    Inventor: James B. Crews
  • Publication number: 20140357534
    Abstract: In some embodiments, the present invention pertains to methods of detecting a contamination of an environment by a fracture fluid that comprises magnetic particles. In some embodiments, such methods include: (1) collecting a sample from the environment; and (2) measuring a magnetic susceptibility of the sample in order to detect the presence or absence of the magnetic particles. Further embodiments of the present invention pertain to methods of tracing fracture fluids in a mineral formation. In some embodiments, such methods include: (1) associating the fracture fluids with magnetic particles; (2) introducing the fracture fluids into the mineral formation; and (3) measuring a magnetic susceptibility of the fracture fluids. Additional embodiments of the present invention pertain to fracture fluids containing the aforementioned magnetic particles, the actual magnetic particles, and methods of making said magnetic particles.
    Type: Application
    Filed: December 10, 2012
    Publication date: December 4, 2014
    Applicants: William Marsh Rice University, University of Alberta
    Inventors: Andrew Ross Barron, David Keith Potter, Samuel J. Maguire-Boyle, Emil Pena, Lauren Morrow
  • Publication number: 20140262249
    Abstract: Method of stimulating subterranean formations for are given in which a thermite is placed downhole and then ignited. The thermite may be ignited with a downhole tool, the fracture may be mapped, and the thermite-affected region of the formation may be reconnected to the surface after the thermite reaction through the original or a second wellbore.
    Type: Application
    Filed: March 15, 2013
    Publication date: September 18, 2014
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dean M. Willberg, James Ernest Brown
  • Publication number: 20140216749
    Abstract: A method of treating a well including the steps of: (A) treating a first aqueous fluid comprising seawater with electrocoagulation to obtain a second aqueous fluid, wherein the second aqueous fluid has a reduced concentration of magnesium ions relative to the original concentration of magnesium ions in the first aqueous fluid; (B) forming a treatment fluid comprising: (i) an aqueous phase, wherein the aqueous phase comprises the second aqueous fluid, and (ii) a viscosity-increasing agent in the aqueous phase; and (C) introducing the treatment fluid into a well. The aqueous phase can have a pH of at least about 9 or the treatment fluid can be introduced into a well at a design temperature of at least about 93° C. (200° F.).
    Type: Application
    Filed: February 1, 2013
    Publication date: August 7, 2014
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Paul D. Lord, Jim D. Weaver, Renee A. LeBas
  • Publication number: 20140213488
    Abstract: Mineral particles may provide for wellbore fluids with tailorable properties and capabilities. In some instances, a dry wellbore additive may comprise a plurality of first mineral particles having a specific gravity of about 2.6 to about 20; a plurality of second mineral particles having a specific gravity of about 5.5 to about 20; a plurality of lubricant particles having a specific gravity of about 2.6 to about 20; wherein the first mineral particles, the second mineral particles, and the lubricant particles are different; and wherein the first mineral particles, the second mineral particles, and the lubricant particles have a multiparticle specific gravity of about 3 to about 20.
    Type: Application
    Filed: January 29, 2013
    Publication date: July 31, 2014
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Dale E. Jamison, Charles Landis, Jay Deville, Cato McDaniel
  • Publication number: 20140187452
    Abstract: This invention relates to treated geothermal brine compositions containing reduced concentrations of iron, silica, and manganese compared to the untreated brines. Exemplary compositions contain a concentration of manganese less than 10 mg/kg, a concentration of silica ranging from less than 10 mg/kg, and a concentration of iron less than 10 mg/kg, and the treated geothermal brine is derived from a Salton Sea geothermal reservoir.
    Type: Application
    Filed: March 5, 2014
    Publication date: July 3, 2014
    Applicant: Simbol Inc
    Inventors: Stephen Harrison, John Burba, III
  • Publication number: 20140187450
    Abstract: A method of treating a subterranean formation. The method may include providing a fluid-loss control pill that comprises an aqueous base fluid, a gelling agent, and an internal breaker that is selected from the group consisting of inorganic delayed acids or inorganic salts. The method can include introducing the fluid-loss control pill into a subterranean formation, allowing the internal breaker to reduce the viscosity of the pill after a delay period, and allowing the fluid-loss control pill to break.
    Type: Application
    Filed: December 28, 2012
    Publication date: July 3, 2014
    Applicant: Superior Energy Services, L.L.C.
    Inventor: Sumitra Mukhopadhyay
  • Patent number: 8697611
    Abstract: A composition and method for use in drilling or completing a subterranean well comprising a solidsfree, high-density brine composed of alkali metal polytungstate and blends thereof. These high-density brines are also useful as wellbore fluids and other non-oilfield fluids requiring high density properties.
    Type: Grant
    Filed: December 14, 2005
    Date of Patent: April 15, 2014
    Assignee: M-I L.L.C.
    Inventors: Hui Zhang, Robert L. Horton, Bethicia B. Prasek, Mary L. K. Dimataris
  • Publication number: 20140094394
    Abstract: A wellbore treatment fluid comprising one or more high-density weighting materials selected from the group consisting of tungsten-containing materials, bismuth-containing materials, and tin-containing materials.
    Type: Application
    Filed: October 2, 2012
    Publication date: April 3, 2014
    Applicant: Chevron Phillips Chemical Company LP
    Inventors: Marshall D. BISHOP, John E. ANDERSON
  • Publication number: 20130274153
    Abstract: The present invention relates to proppants and the manufacture of proppants by contacting a substrate with an alkali-activated composition that cures to form a continuous polymer coating.
    Type: Application
    Filed: October 28, 2011
    Publication date: October 17, 2013
    Applicant: GEOPROPPANTS INC.
    Inventor: Thomas Urbanek
  • Publication number: 20130217603
    Abstract: The present invention relates to particles that are useful for enhancing hindered settling in suspensions. One embodiment of the present invention provides a method of providing a subterranean treatment fluid including a base fluid and a weighting agent having a first average settling velocity; and a neutral-density particle; and mixing the subterranean treatment fluid with the neutral-density particle thereby reducing the weighting agent to a second average settling velocity.
    Type: Application
    Filed: February 17, 2012
    Publication date: August 22, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Dale E. Jamison, Stephen W. Almond
  • Publication number: 20130175037
    Abstract: A method of reducing the presence of particles in a downhole environment, comprising contacting sediment particles contained in a downhole environment, with a composition comprising: a metallic composition, an inorganic oxide-based polymer, and a solvent; the contacting occurring in the presence of a fluid capable of decomposing the metallic composition
    Type: Application
    Filed: January 8, 2013
    Publication date: July 11, 2013
    Applicant: Baker Hughes Incorporated
    Inventors: James Crews, Othon R. Monteiro
  • Patent number: 8455402
    Abstract: Fluid systems may contain elements to provide changes in bulk fluid density in response to various environmental conditions. One environmental driver to the variable density is pressure; other environmental drivers include, but are not limited to, temperature or changes in chemistry. The variable density of the fluid is beneficial for controlling sub-surface pressures within desirable pore pressure and fracture gradient envelopes. The variability of fluid density permits construction and operation of a wellbore with much longer hole sections than when using conventional single gradient fluids.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: June 4, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: Larry A. Watkins, Roger W. Fincher
  • Publication number: 20130130948
    Abstract: A method for breaking the viscosity of an aqueous fluid gelled with a water soluble polymer or a VES is disclosed. The method includes providing an aqueous fluid. The method also includes adding to the aqueous fluid, in any order: a water soluble polymer in an amount sufficient to form a gelled aqueous fluid having a viscosity, a water soluble oxidizing agent configured to generate free radicals and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid, the metallic particles configured to dissolve in the gelled aqueous fluid and provide a reducing agent to accelerate the generation of free radicals. The method further includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective accelerate the generation of free radicals and reduce the viscosity.
    Type: Application
    Filed: November 18, 2011
    Publication date: May 23, 2013
    Applicant: BAKER HUGHES INCORPORATED
    Inventor: James B. Crews
  • Patent number: 8445414
    Abstract: Alkaline earth metal compounds may be fluid loss control (FLC) agents for viscoelastic surfactant (VES) fluids used for fluid loss control pills, lost circulation material pills and kill pills in hydrocarbon recovery operations. The FLC agents may include, but not be limited to oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The FLC agent may alternatively be transition metal oxides and/or transition metal hydroxides. The FLC agent appears to associate with the VES micelles and together form a novel pseudo-filter cake quasi-crosslinked viscous fluid layer that limits further VES fluid flow into the porous media. The FLC agent solid particles may be added along with VES fluids. The pills may also contain internal breakers to reduce the viscosity thereof so that the components of the pill may be recovered.
    Type: Grant
    Filed: February 2, 2012
    Date of Patent: May 21, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang
  • Publication number: 20130123151
    Abstract: A method for breaking the viscosity of an aqueous fluid gelled with a viscoelastic surfactant (VES) is disclosed. The method includes providing an aqueous fluid and adding to the aqueous fluid, in any order: at least one VES comprising a non-ionic surfactant, cationic surfactant, amphoteric surfactant or zwitterionic surfactant, or a combination thereof, in an amount sufficient to form a gelled aqueous fluid comprising a plurality of elongated micelles and having a viscosity, and a plurality of metallic particles to produce a mixture comprising dispersed metallic particles dispersed within the gelled aqueous fluid. The method also includes dissolving the metallic particles in the gelled aqueous fluid to provide a source of at least one transition metal ion in an amount effective to reduce the viscosity.
    Type: Application
    Filed: November 14, 2011
    Publication date: May 16, 2013
    Applicant: BAKER HUGHES INCORPORATED
    Inventor: James B. Crews
  • Publication number: 20130109597
    Abstract: The present invention relates to nanoparticle smart tags and the use of nanoparticle smart tags in the detection of analyte. In particular, the present invention relates to nanoparticle smart tags that may be used in subgeologic formations to detect analytes of interest in real-time. One embodiment of the present invention provides a suspension having a nanoparticle smart tag analyte complex formed by an interaction having a nanoparticle smart tag and an analyte; and a subterranean treatment fluid.
    Type: Application
    Filed: October 31, 2011
    Publication date: May 2, 2013
    Applicant: Halliburton Energy Services, Inc.
    Inventors: Diptabhas Sarkar, Charles R. Landis, Ryan P. Collins
  • Patent number: 8372787
    Abstract: A composition for wellbore consolidation comprises fibers having a core formed from a material that is electrically and/or magnetically susceptible, and a polymeric coating. When the composition is placed in a wellbore in a zone to be consolidated and an electric current or magnetic field is applied, the fibers bond together by melting or setting of the polymeric coating.
    Type: Grant
    Filed: June 11, 2009
    Date of Patent: February 12, 2013
    Assignee: Schlumberger Technology Corporation
    Inventor: Nicolas Droger
  • Publication number: 20130029886
    Abstract: A composite particle comprises a core, a shielding layer deposited on the core, and further comprising an interlayer region formed at an interface of the shielding layer and the core, the interlayer region having a reactivity less than that of the core, and the shielding layer having a reactivity less than that of the interlayer region, a metallic layer not identical to the shielding layer and deposited on the shielding layer, the metallic layer having a reactivity less than that of the core, and optionally, an adhesion metal layer deposited on the metallic layer.
    Type: Application
    Filed: July 29, 2011
    Publication date: January 31, 2013
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Oleg A. Mazyar, Michael Johnson, Randall Guest, Nicholas Carrejo, Wayne Furlan, Sean Gaudette, Zhiyue Xu
  • Publication number: 20130014945
    Abstract: A proppant having low surface friction is described, which is useful in hydrocarbon recovery. Methods of making low surface friction proppants are further described, as well as uses thereof.
    Type: Application
    Filed: July 13, 2012
    Publication date: January 17, 2013
    Applicant: OXANE MATERIALS, INC.
    Inventors: Christopher Y. Fang, Dilip K. Chatterjee, Robert D. Skala, Christopher E. Coker, John R. Loscutova
  • Patent number: 8343894
    Abstract: Fluid systems may contain elements to provide changes in bulk fluid density in response to various environmental conditions. One environmental driver to the variable density is pressure; other environmental drivers include, but are not limited to, temperature or changes in chemistry. The variable density of the fluid is beneficial for controlling sub-surface pressures within desirable pore pressure and fracture gradient envelopes. The variability of fluid density permits construction and operation of a wellbore with much longer hole sections than when using conventional single gradient fluids.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: January 1, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: Larry A. Watkins, Roger W. Fincher
  • Patent number: 8286705
    Abstract: Apparatus and methods comprising a plurality of particles which are magnetically attracted to one another in response to exposure to an magnetic field, and which maintain attraction to one another after removal of the magnetic field, the attraction being disabled when the particles are demagnetized, whereby the particles operate to alter the rheological properties of a fluid in which the particles are mixed when the attraction is enabled or disabled is disclosed.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: October 16, 2012
    Assignee: Schlumberger Technology Corporation
    Inventors: Murat Ocalan, Francois Auzerais, Partha Ganguly, Agathe Robisson, Jahir Pabon
  • Publication number: 20120247765
    Abstract: Disintegrative particles are designed to be blended with and pumped with typical proppant materials, e.g. sand, ceramics, bauxite, etc, into the fractures of a subterranean formation. With time and/or change in wellbore or environmental condition, these particles will either disintegrate partially or completely, in non-limiting examples, by contact with downhole fracturing fluid, formation water, or a stimulation fluid such as an acid or brine. Once disintegrated, the proppant pack within the fractures will lead to greater open space enabling higher conductivity and flow rates. The disintegrative particles may be made by compacting and/or sintering metal powder particles, for instance magnesium or other reactive metal or their alloys. Alternatively, particles coated with compacted and/or sintered nanometer-sized or micrometer sized coatings could also be designed where the coatings disintegrate faster or slower than the core in a changed downhole environment.
    Type: Application
    Filed: March 26, 2012
    Publication date: October 4, 2012
    Applicant: Baker Hughes Incorporated
    Inventors: Gaurav Agrawal, James B. Crews, Zhiyue Xu
  • Publication number: 20120190598
    Abstract: A method includes providing and adding a measured dose amount of manufactured metallic nanoparticle material to a carrier material for pre-treatment of the carrier material prior to use of the carrier material and the manufactured metallic nanoparticle material in the sub-surface earth activity. Another method includes accessing a sub-surface earth opening used with a sub-surface earth activity, introducing an amount of manufactured metallic nanoparticle material into the sub-surface earth opening, and treating a sub-surface earth condition present at a sub-surface earth location accessible via the sub-surface earth opening. The sub-surface earth condition is treated with the manufactured metallic nanoparticle material. Another method includes accessing a product from a sub-surface earth location that is extracted in conjunction with the sub-surface earth activity, measuring and introducing a dose amount of manufactured metallic nanoparticle material with the product from the sub-surface earth location.
    Type: Application
    Filed: February 7, 2012
    Publication date: July 26, 2012
    Applicant: PURE LIQUID SOLUTIONS, LLC
    Inventors: Ray Woodrow McCubbins, JR., Nathan Jared Whiting, Fred Vincent Schillreff, Larry George Miller, Theron Glade Miller
  • Publication number: 20120181020
    Abstract: Proppants having added functional properties are provided, as are methods that use the proppants to track and trace the characteristics of a fracture in a geologic formation. Information obtained by the methods can be used to design a fracturing job, to increase conductivity in the fracture, and to enhance oil and gas recovery from the geologic formation. The functionalized proppants can be detected by a variety of methods utilizing, for example, an airborne magnetometer survey, ground penetrating radar, a high resolution accelerometer, a geophone, nuclear magnetic resonance, ultra-sound, impedance measurements, piezoelectric activity, radioactivity, and the like. Methods of mapping a subterranean formation are also provided and use the functionalized proppants to detect characteristics of the formation.
    Type: Application
    Filed: March 28, 2012
    Publication date: July 19, 2012
    Applicant: OXANE MATERIALS, INC.
    Inventors: Andrew R. Barron, Robert D. Skala, Christopher E. Coker, Dilip K. Chatterjee, Yuming Xie
  • Publication number: 20120135894
    Abstract: Disclosed herein is a method comprising disposing in a formation fracture, a proppant and/or a fracturing fluid that comprises a radiation susceptible material that comprises indium and/or vanadium; irradiating the radiation susceptible material with neutrons; measuring gamma-radiation emitted from the radiation susceptible material in a single pass; wherein the single pass does not involve measuring of background radiation from previous or subsequent logging passes; and determining formation fracture height from the measured gamma-radiation.
    Type: Application
    Filed: February 2, 2012
    Publication date: May 31, 2012
    Inventors: Robert R. McDaniel, Scott M. Mccarthy, Michael Smith
  • Publication number: 20120129737
    Abstract: A method of heterogeneous proppant placement in a subterranean fracture is disclosed. The method comprises injecting well treatment fluid including proppant and a channelant through a wellbore into the fracture, heterogeneously placing the proppant in the fracture in a plurality of proppant clusters or islands spaced apart by the channelant, and removing the channelant filler material to form open channels around the pillars for fluid flow from the formation through the fracture toward the wellbore. The proppant and channelant can be segregated within the well treatment fluid, or segregated during placement in the fracture. The channelant can be dissolvable particles, initially acting as a filler material during placement of the proppant, and later dissolving to leave the flow channels between the proppant pillars. The well treatment fluid can include fibers to provide reinforcement and consolidation of the proppant and/or to inhibit settling of the proppant in the treatment fluid.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 24, 2012
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Timothy Lesko, J. Ernest Brown, Dean M. Willberg, Ivan Kosarev, Anatoly Medvedev
  • Patent number: 8178477
    Abstract: Proppants which can be used to prop open subterranean formation fractions are described. Proppant formulations which use one or more proppants of the present invention are described, as well as methods to prop open subterranean formation fractions, and other uses for the proppants and methods of making the proppants.
    Type: Grant
    Filed: September 14, 2011
    Date of Patent: May 15, 2012
    Assignee: Oxane Materials, Inc.
    Inventors: Robert D. Skala, John R. Loscutova, Christopher E. Coker
  • Patent number: 8168570
    Abstract: Proppants having added functional properties are provided, as are methods that use the proppants to track and trace the characteristics of a fracture in a geologic formation. Information obtained by the methods can be used to design a fracturing job, to increase conductivity in the fracture, and to enhance oil and gas recovery from the geologic formation. The functionalized proppants can be detected by a variety of methods utilizing, for example, an airborne magnetometer survey, ground penetrating radar, a high resolution accelerometer, a geophone, nuclear magnetic resonance, ultra-sound, impedance measurements, piezoelectric activity, radioactivity, and the like. Methods of mapping a subterranean formation are also provided and use the functionalized proppants to detect characteristics of the formation.
    Type: Grant
    Filed: May 19, 2009
    Date of Patent: May 1, 2012
    Assignee: Oxane Materials, Inc.
    Inventors: Andrew R. Barron, Robert D. Skala, Christopher E. Coker, Dilip K. Chatterjee, Yuming Xie
  • Publication number: 20120080189
    Abstract: Compositions, apparatus incorporating a composition, and methods of use are described, one composition embodiment consisting essentially of one or more reactive metals in major proportion, and one or more alloying elements in minor proportion, with the provisos that the composition is high-strength, controllably reactive, and degradable under defined conditions. Compositions of the invention may exist in a variety of morphologies, including a reactive metal or degradable alloy processed into an alloy of crystalline, amorphous or mixed structure that may constitute the matrix of other composition, for instance a composite. Methods of using apparatus comprising a composition, particularly in oilfield operations are also described (e.g. flow and displacement control, sensors, actuators). This abstract allows a searcher or other reader to quickly ascertain the subject matter of the disclosure. It will not be used to interpret or limit the scope or meaning of the claims.
    Type: Application
    Filed: November 21, 2011
    Publication date: April 5, 2012
    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Manuel P. Marya, Rashmi B. Bhavsar, Gary L. Rytlewski
  • Patent number: 8129318
    Abstract: Disclosed herein is a method comprising disposing in a formation fracture, a proppant and/or a fracturing fluid that comprises a radiation susceptible material that comprises indium and/or vanadium; irradiating the radiation susceptible material with neutrons; measuring gamma-radiation emitted from the radiation susceptible material in a single pass; wherein the single pass does not involve measuring of background radiation from previous or subsequent logging passes; and determining formation fracture height from the measured gamma-radiation.
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: March 6, 2012
    Assignee: Momentive Specialty Chemicals Inc.
    Inventors: Robert R. McDaniel, Scott M. McCarthy, Michael Smith
  • Patent number: 8114820
    Abstract: Alkaline earth metal compounds may be fluid loss control (FLC) agents for viscoelastic surfactant (VES) fluids used for fluid loss control pills, lost circulation material pills and kill pills in hydrocarbon recovery operations. The FLC agents may include, but not be limited to oxides and hydroxides of alkaline earth metal, and in one case magnesium oxide where the particle size of the magnesium oxide is between 1 nanometer to 0.4 millimeter. The FLC agent may alternatively be transition metal oxides and/or transition metal hydroxides. The FLC agent appears to associate with the VES micelles and together form a novel pseudo-filter cake quasi-crosslinked viscous fluid layer that limits further VES fluid flow into the porous media. The FLC agent solid particles may be added along with VES fluids. The pills may also contain internal breakers to reduce the viscosity thereof so that the components of the pill may be recovered.
    Type: Grant
    Filed: May 29, 2007
    Date of Patent: February 14, 2012
    Assignee: Baker Hughes Incorporated
    Inventors: James B. Crews, Tianping Huang
  • Publication number: 20120031613
    Abstract: Articles and methods utilizing radiation susceptible materials are provided herein. In one aspect, a proppant, a treatment fluid, or both, may comprise a radiation susceptible material. In another aspect, a method is provided comprising disposing in a formation fracture, a proppant and/or a treatment fluid that comprises a radiation susceptible material, irradiating the radiation susceptible material with neutrons, measuring gamma-radiation emitted from the radiation susceptible material in a single pass, and determining formation fracture height from the measured gamma-radiation. The single-pass may be a continuous process or a periodic process.
    Type: Application
    Filed: October 14, 2011
    Publication date: February 9, 2012
    Inventor: John W. Green
  • Publication number: 20110290506
    Abstract: The subject disclosure discloses an apparatus and method of conveying magnetic particles into a wellbore. A plurality of particles which are magnetically attracted to one another in response to exposure to a magnetic field are delivered downhole via a degradable material. The degradable material confines the particles and conveys the particles to a desired location downhole. The structure comprising the degradable material and the confined particles can be lowered into a subterranean well by a cable or wire, or alternatively released into the well under the influence of gravity and flow induced forces. The material degrades in response to conditions encountered in a subterranean environment thus releasing the particles.
    Type: Application
    Filed: May 28, 2010
    Publication date: December 1, 2011
    Applicant: Schlumberger Technology Corporation
    Inventors: Murat Ocalan, Manuel Marya
  • Patent number: 8047288
    Abstract: Proppants used to prop open subterranean formation fractions. Proppant formulations using one or more proppants. Methods to prop open subterranean formation fractions and other uses for the proppants, as well as methods of making the proppants.
    Type: Grant
    Filed: July 18, 2008
    Date of Patent: November 1, 2011
    Assignee: Oxane Materials, Inc.
    Inventors: Robert D. Skala, John R. Loscutova, Christopher E. Coker
  • Publication number: 20110237467
    Abstract: The present invention is directed to completion fluid compositions and methods of making same. Such completion fluids are unique in that they utilize nanoparticles as weighting (densification) agents that increase the specific gravity (or density) of the fluid into which they are dispersed. Depending on their properties, such nanoparticulate weighting agents can vastly broaden the types of base fluid used in the completion fluid, permitting the use of non-aqueous and even hydrocarbon base fluids. Additionally, such nanoparticle-densified completion fluids can provide reduced environmental risks, and the nanoparticle weighting agents used therein can be more easily recovered from the based fluids into which they are dispersed.
    Type: Application
    Filed: March 25, 2010
    Publication date: September 29, 2011
    Applicant: Chevron U.S.A. Inc.
    Inventors: H. Mitchell Cornette, Craig Gardner, Ben Bloys, Earl Coludrovich, Thomas G. Corbett, Henry Bergeron
  • Patent number: 7998906
    Abstract: Methods and compositions useful in treating subterranean formations, and more particularly, breaker compositions that may be useful in treating subterranean formations wherein synthetic polymers are used, are provided. Of the many methods and compositions provided herein, one composition comprises a source of hydrogen peroxide and an activator. One method comprises providing a polymer breaker composition comprising a source of hydrogen peroxide and an activator; introducing the polymer breaker composition into a well bore which penetrates a subterranean formation; allowing the activator to activate the source of hydrogen peroxide to create an oxidizing species; and allowing the oxidizing species to break synthetic polymers present in the subterranean formation.
    Type: Grant
    Filed: August 21, 2008
    Date of Patent: August 16, 2011
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Rajesh K. Saini, Michael W. Sanders, Fong-Fong Foo, Jeff L. Mundy
  • Patent number: 7994103
    Abstract: Disclosed is a method for introducing additives into formation fluid from an oil and gas well in or moving through equipment and systems located downstream from the oil and gas well. The method is practiced using pellets having a density sufficient to suspend the pellet at an interface of two phases of fluid within the Downstream Equipment. The pellets are prepared from a pellet matrix, such as an ethoxylated wax, and, optionally, a weighting agent as well as an additive. By varying the amount of weighting agent, the density of the pellet can be varied to suspend it at a desired point for a time sufficient to deliver the additive to the desired point within the Downstream Equipment. The method of the invention may also be used with Refinery Equipment such as a fuel distribution system or a waste water treatment system.
    Type: Grant
    Filed: November 10, 2006
    Date of Patent: August 9, 2011
    Assignee: Baker Hughes Incorporated
    Inventors: Samuel Everett Campbell, Kenneth J. Tacchi
  • Publication number: 20110177984
    Abstract: A proppant particle comprising a sintered proppant composition that comprises a non-radioactive, detectable tracer uniformly distributed throughout a ceramic composition, wherein the tracer is one or more tracer metal oxides and the tracer metals are selected from a group consisting of lanthanides, strontium, barium, gallium, germanium, tantalum, vanadium, and manganese.
    Type: Application
    Filed: March 1, 2011
    Publication date: July 21, 2011
    Applicant: CARBO CERAMICS INC.
    Inventors: Brett A. Wilson, Robert Duenckel, Thomas C. Palamara
  • Patent number: 7972555
    Abstract: Methods for fabricating compressible object are described. These compressible objects may be utilized in drilling mud and with a drilling system to manage the density of the drilling mud. The method includes selecting an architecture for a compressible object; selecting a wall material for the compressible object; and fabricating the compressible object, wherein the compressible object has a shell that encloses an interior region, and has an internal pressure (i) greater than about 200 pounds per square inch at atmospheric pressure and (ii) selected for a predetermined external pressure, wherein external pressures that exceed the internal pressure reduce the volume of the compressible object.
    Type: Grant
    Filed: October 16, 2008
    Date of Patent: July 5, 2011
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Richard S. Polizzotti, Dennis George Peiffer, Ramesh Gupta, Norman M. Pokutylowicz, Barbara Carstensen, Michael J. Luton, Paul Matthew Spiecker
  • Publication number: 20110136707
    Abstract: An engineered dispersed particle-cellular nanomatrix composite material is disclosed. The engineered dispersed particle-cellular nanomatrix composite material is configured for contact with a fluid and configured to provide a selectable and controllable transition from one of a first strength condition to a second strength condition that is lower than a functional strength threshold, or a first weight loss amount to a second weight loss amount that is greater than a weight loss limit, as a function of a time in contact with the fluid.
    Type: Application
    Filed: December 8, 2009
    Publication date: June 9, 2011
    Inventors: Zhiyue Xu, Gaurav Agrawal
  • Patent number: 7946342
    Abstract: A method for oil recovery whereby an exothermic water reactant (EWR) encapsulated in a water soluble coating is placed in water and pumped into one or more oil wells in contact with an oil bearing formation. After the water carries the EWR to the bottom of the injection well, the water soluble coating dissolves and the EWR reacts with the water to produce heat, an alkali solution, and hydrogen. The heat from the EWR reaction generates steam, which is forced into the oil bearing formation where it condenses and transfers heat to the oil, elevating its temperature and decreasing the viscosity of the oil. The aqueous alkali solution mixes with the oil in the oil bearing formation and forms a surfactant that reduces the interfacial tension between the oil and water. The hydrogen may be used to react with the oil at these elevated temperatures to form lighter molecules, thus upgrading to a certain extent the oil in situ.
    Type: Grant
    Filed: April 30, 2009
    Date of Patent: May 24, 2011
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Eric P. Robertson
  • Publication number: 20110111990
    Abstract: A synthetic ceramic proppant composition contains an aluminate-borate phase or an aluminate-borate-silicate phase or both and at least one additional phase that adds strength and decreases apparent specific gravity and is formed because of the inclusion of certain inorganic salts and/or metallic oxides in the precursor mixture either as separate components or as impurities in the starting materials. Compositions, methods of manufacture, and uses are given.
    Type: Application
    Filed: April 28, 2008
    Publication date: May 12, 2011
    Inventors: Elena Mikhailovna Pershikova, Zinaida Yurievna Usova, Svetlana Anatolyevna Naydukova
  • Patent number: 7825075
    Abstract: Piezoelectric crystal particles (which include pyroelectric crystal particles) enhance the viscosity of aqueous fluids that have increased viscosity due to the presence of viscoelastic surfactants (VESs). In one non-limiting theory, when the fluid containing the viscosity enhancers is heated and/or placed under pressure, the particles develop surface charges that associate, link, connect, or relate the VES micelles thereby increasing the viscosity of the fluid. The higher fluid viscosity is beneficial to crack the formation rock during a fracturing operation, reduce fluid leakoff, and carry high loading proppants to maintain the high conductivity of fractures.
    Type: Grant
    Filed: June 9, 2009
    Date of Patent: November 2, 2010
    Assignee: Baker Hughes Incorporated
    Inventor: Tianping Huang