Preventing Contaminant Deposits In Petroleum Oil Conduits Patents (Class 507/90)
  • Patent number: 5256740
    Abstract: Polymer with a number average molecular weight of 400 to 20,000 having amino-substituted groups in its molecule and resulting from the reaction of at least one compound having a secondary amine function with 1 to 60 carbon atoms on an unsaturated polyester resulting from the condensation of an unsaturated, aliphatic dicarboxylic compound having at least one alpha ethylene unsaturation of one of the carboxylic groups on at least one epoxidized compound having 2 to 62 carbon atoms chosen from among epoxyalkenes, ethers, epoxyalcohol esters and epoxyacid esters. Middle distillate composition having a distillation range of 150.degree. to 450.degree. C. and incorporating a minor proportion, preferably 0.001 to 2% by weight, of at least one of the aforementioned polymers.
    Type: Grant
    Filed: April 30, 1992
    Date of Patent: October 26, 1993
    Assignee: IFP et Elf France
    Inventors: Jacques Denis, Alain Forestiere, Beatrice Bonardi, Bernard Damin
  • Patent number: 5244878
    Abstract: A process for delaying the formation and/or reducing the agglomeration tendency of hydrates in conditions under which a hydrate may be formed, these hydrates being formed from water and gas.The process according to the invention wherein, in particular, an additive comprising at least one amphiphilic compound chosen from the group of esters of polyols and substituted or unsubstituted carboxylic acids is used.Application of the process according to the invention to processes using gases and water, which form hydrates between them, in particular in the petroleum or gas industry.
    Type: Grant
    Filed: July 10, 1991
    Date of Patent: September 14, 1993
    Assignee: Institut Francais du Petrole
    Inventors: Andre Sugier, Paul Bourgmayer, Jean-Pierre Durand
  • Patent number: 5223160
    Abstract: The deposition of elemental sulfur in a conduit through which a sulfur containing gas is flowing is reduced by providing, as a novel sulfur dispersant, an ether alcohol component produced from primary alcohol and epichlorohydrin mixed with an aliphatic amine component, the dispersant being employed in the presence of liquid water. When the conduit is normally vulnerable to the corrosion caused by contact with the sulfur-containing gas, the sulfur dispersant is optionally employed in conjunction with a corrosion inhibitor.
    Type: Grant
    Filed: August 16, 1991
    Date of Patent: June 29, 1993
    Assignee: Nalco Chemical Company
    Inventor: Daniel H. Emmons
  • Patent number: 5183581
    Abstract: A process, based on the Nitrogen Generating System/Emulsion in the presence of organic solvents, which is useful for the dewaxing of producing formations, is disclosed. The heat generation with the nitrogen reaction system and organic solvents gives rise to a thermo-chemical, synergistic system for long lasting removal of paraffinic damage, oil production rates being restored and even increased. The process is relatively easy to implement and of low cost.
    Type: Grant
    Filed: April 13, 1992
    Date of Patent: February 2, 1993
    Assignee: Petroleo Brasileiro S.A.
    Inventors: Carlos N. Khalil, Regis K. Romeu, Andre Rabinovitz
  • Patent number: 5171460
    Abstract: While many materials have been used to inhibit scale formation previously, none have been fully satisfactory to prevent scale formation and precipitation of totally dissolved solids (TDS) in fluids used in well drilling, completion and workovers when the fluids contain divalent metal cations and when the formation contains carbon dioxide. Since many wells are completed into such formations, a continuing search has been directed to an improved method for preventing the formation of such scale. According to the present invention, metal carbonate scale formation and TDS precipitation in a well penetrating a subterranean formation wherein a fluid containing calcium, magnesium, barium or zinc is used in the presence of carbon dioxide is prevented by maintaining the fluid at a pH from about 2 to about 9 and adding from about 1 to about 5000 parts per million of a phosphonomethylated oxyalkyleneamine material having a molecular weight from about 150 to about 3000 to the fluid.
    Type: Grant
    Filed: May 29, 1991
    Date of Patent: December 15, 1992
    Assignee: Atlantic Richfield Company
    Inventor: David R. Underdown
  • Patent number: 5128022
    Abstract: Methods and compositions are provided for inhibiting the formation of polymers in petroleum or petrochemical processes that subsequently foul heat transfer surfaces. The compositions comprise a combination of N-Phenyl-N'-(1,3-dimethylbutyl)-p-phenylenediamine (PDA) and an organic acid. The methods comprise adding from 1 to 2500 ppm PDA and 1 to 3500 ppm organic acid to the system experiencing the fouling problem.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: July 7, 1992
    Assignee: Betz Laboratories, Inc.
    Inventor: Dwight K. Reid
  • Patent number: 5106515
    Abstract: Disclosed is a polymer of average molecular weight ranging from 400 to 20,000 comprising amino substituted groups in its molecule and resulting from the reaction of at least one compound with a primary amine function having 1 to 60 carbon atoms with an unsaturated polyester resulting from the condensation of an unsaturated aliphatic dicarboxylic compound, comprising at least one ethylenic unsaturation in the alpha position of one of the carboxyl groups, with at least one epoxidated compound having 4 to 62 carbon atoms chosen from ethers and esters of epoxyalcohols and esters of epoxyacids.Also disclosed is a middle distillate composition having a distillation range from 150.degree. to 450.degree. C. and comprising a minor proportion, preferably from 0.001 to 2% in weight, of at least one of the polymers defined hereinabove.
    Type: Grant
    Filed: November 27, 1990
    Date of Patent: April 21, 1992
    Assignees: Institut Francais du Petrole, Elf France
    Inventors: Jacques Denis, Jacques Garapon, Bernard Damin, Robert Leger
  • Patent number: 5104557
    Abstract: A composition is disclosed for dissolving sulfur and preventing or removing sulfur plugs from sour gas and oil wells or other conduits through which sulfur bearing liquids flow which comprises a major proportion of a liquid or gaseous mercaptan, a minor proportion of a catalyst which is a substantially water-insoluble amine, and minor amount of an activator which is a compound of the formula ##STR1## where R is hydrogen, alkyl, aryl or alkaryl and the alkyl moieties have from 1 to 24 carbon atoms, and x and y are independent values between 0 and 24 provided that x or y is at least 1; a method is also disclosed wherein said composition in an effective amount is injected into a conduit to prevent or remove sulfur plugging, and the composition containing dissolved sulfur is optionally recovered.
    Type: Grant
    Filed: June 29, 1990
    Date of Patent: April 14, 1992
    Assignee: Elf Atochem North America, Inc.
    Inventor: Michael J. Lindstrom