Abstract: Fracturing fluids comprising a base fluid and substantially hydrated cement particulates. Methods of fracturing a subterranean formation comprising fracturing the subterranean formation so as to create or enhance one or more fractures in the subterranean formation; introducing a fracturing fluid comprising a base fluid and substantially hydrated cement particulates into the one or more fractures; and depositing at least a portion of the substantially hydrated cement particulates in the one or more fractures in the subterranean formation. Methods of gravel packing comprising providing a gravel packing fluid comprising a base fluid and substantially hydrated cement particulates, introducing the gravel packing fluid into a subterranean formation, and depositing at least a portion of the substantially hydrated cement particulates in the subterranean formation so as to form a gravel pack. Gravel packing fluids that comprise a base fluid, and gravel comprising substantially hydrated cement particulates.

Abstract: The present invention is directed to an improved thermoplastic material-coated particulate composition useful for hydraulic fracturing treatments, gravel packing for sand control or other well formation treatments and especially the related methods of its use and is particularly directed to using a thermoplastic material as part of a particulate composition in a method for enhancing the stabilization of and reducing particulate flowback and fines transport in a well formation.

Abstract: A proppant material is provided that is in the form of generally rigid, elastic plate-like particles having a maximum to minimum dimension ratio of more than about 5. The proppant may be formed from a corrosion resistant material or having a corrosion resistant material formed thereon. The plate-like particles may be substantially non-deformable and may be formed from stainless steel or carbon steel provided with a corrosion resistant coating. The particles may have a thickness of from about 100 to about 300 ?m and may be in the form of a grating. A method of hydraulic fracturing in a formation penetrated by a wellbore is also provided wherein proppant material in the form of generally rigid, elastic plate-like particles having a maximum to minimum dimension ratio of more than about 5 are introduced into the wellbore. The particles may be formed from a corrosion resistant material or having a corrosion resistant material formed thereon.

Abstract: Methods are provided including a method comprising: providing a treatment fluid comprising particulates at least partially coated with a polymer, wherein the polymer is deposited on the particulates by at least partially coating the particulates with a polymer solution comprising the polymer and a solvent and then exposing the particulates to an aqueous medium such that the solvent substantially dissociates from the polymer solution and such that the polymer substantially remains on the particulates; introducing the treatment fluid into a portion of a subterranean formation; and, depositing at least a portion of the particulates in the portion of the subterranean formation.

Abstract: The present invention relates to carbon foam particulates and their use in subterranean applications such as production enhancement and completion. One embodiment of the present invention provides a method of treating a subterranean formation using a servicing fluid comprising providing a slurry comprising a carrier fluid and open-cell carbon foam particulates; and, placing the slurry into a portion of a subterranean formation. Another embodiment of the present invention provides a particulate suitable for use as proppant or gravel in a subterranean application comprising a foamed, cellular structure.

Abstract: The present invention relates to high porosity propped fractures and methods of creating high porosity propped fractures in portions of subterranean formations. Another embodiment of the present invention provides a method of forming a high porosity propped fracture in a subterranean formation, comprising providing a slurry comprising a fracturing fluid and proppant particulates coated with an adhesive substance; introducing the slurry into a portion of a fracture within the subterranean formation; and, depositing the proppant particulates into the portion of the fracture within the subterranean formation so as to form a high porosity propped fracture. Another embodiment of the present invention provides a high porosity propped fracture comprising proppant particulates substantially coated with an adhesive substance wherein the propped fracture has a porosity of at least about 50%.

Abstract: Improved methods and compositions for consolidating proppant in subterranean fractures are provided. In certain embodiments, the hardenable resin compositions may be especially suited for consolidating proppant in subterranean fractures having temperatures above about 200° F. Improved methods include providing proppant particles coated with a hardenable resin composition mixed with a gelled liquid fracturing fluid, and introducing the fracturing fluid into a subterranean zone. The fracturing fluid may form one or more fractures in the subterranean zone and deposit the proppant particles coated with the resin composition therein. Thereafter, the hardenable resin composition on the proppant particles is allowed to harden by heat and to consolidate the proppant particles into degradation resistant permeable packs. The hardenable resin composition may include a liquid bisphenol A-epichlorohydrin resin, a 4,4?-diaminodiphenyl sulfone hardening agent, a solvent, a silane coupling agent, and a surfactant.

Abstract: Methods of treating a portion of a subterranean formation comprising: providing partitioned, coated particulates that comprise particulates, an adhesive substance, and a partitioning agent, and wherein the adhesive substance comprises an aqueous tackifying agent or a silyl modified polyamide; substantially slurrying the partitioned, coated particulates in a treatment fluid to create a particulate slurry; and, placing the particulate slurry into the portion of the subterranean formation.

Abstract: Methods of treating a portion of a subterranean formation comprising: providing partitioned, coated particulates that comprise particulates, an adhesive substance, and a partitioning agent, and wherein the partitioning agent comprises a subterranean treatment chemical; substantially slurrying the partitioned, coated particulates in a treatment fluid to create a particulate slurry; and, placing the particulate slurry into the portion of the subterranean formation.

Abstract: Methods for controlling particulate segregation comprising providing a mixture of an aqueous tackifying composition with a treatment fluid; slurrying the mixture with a first type of solid particulates and a second type of solid particulates and wherein the first type of solid particulates have a tendency to segregate from the second type of solid particulates when slurried into a liquid; and, placing the slurry into a portion of a subterranean formation. Methods for controlling particulate segregation comprising providing a treatment fluid; at least partially coating with an aqueous tackifying composition: a first type of solid particulates and a second type of solid particulates and wherein the first type of solid particulates have a tendency to segregate from the second type of solid particulates when slurried into a liquid; slurrying the two types of particulates into the treatment fluid; and, placing the slurry into a portion of a subterranean formation.

Abstract: Methods of treating subterranean formations using foamed treatment fluids comprising water, a gas, and a foaming and foam stabilizing surfactant mixture comprising a plurality of alkali salts of alkyl ether sulfates wherein the alkyl group in each of the alkyl ether sulfates has in the range of from 4 carbon atoms to 10 carbon atoms, an alkyl amidopropyl hydroxysultaine or an alkyl amidopropyl betaine, and an alkyl amidopropyl dimethylamine oxide.

Abstract: Methods of forming a high porosity propped fracture comprising: providing a slurry comprising a fracturing fluid, proppant particulates, and a weighting agent; introducing the slurry into a portion of a fracture within the subterranean formation; and, depositing the proppant particulates into the portion of the fracture within the subterranean formation so as to form a high porosity propped fracture. Methods of fracturing a subterranean formation to form a high porosity propped fracture comprising: creating at least one fracture within a portion of a subterranean formation; placing a slurry comprising a fracturing fluid, high density plastic particulates, and a weighting agent into at least a portion of the created fracture; and, depositing the high density plastic proppant particulates into a portion of the fracture so as to form a high porosity propped fracture. Slurries suitable for use in subterranean fracturing operations comprising: a fracturing fluid, proppant particulates, and a weighting agent.

Abstract: The invention relates to enhancing the conductivity of fractures in a subterranean formation so as to enhance fluid flow therethrough. In one embodiment, the present invention provides a method comprising: providing a proppant matrix composition, the proppant matrix composition comprising at least a plurality of proppant particulates and at least a plurality of composite particles, the composite particles comprising a degradable material and a filler material; introducing the proppant matrix composition to the fracture so as to form a proppant matrix in the fracture; and allowing the degradable material of the composite particles to degrade so as to form at least one void in the proppant matrix.

Abstract: An increase in effective propped lengths is evidenced in hydraulic fracturing treatments by the use of ultra lightweight (ULW) proppants. The ULW proppants have a density less than or equal to 2.45 g/cc and may be used as a mixture in a first proppant stage wherein at least one of the proppants is a ULW proppant. Alternatively, sequential proppant stages may be introduced into the formation wherein at least one of the proppant stages contain a ULW proppant and where at least one of the following conditions prevails: (i.) the density differential between the first proppant stage and the second proppant stage is greater than or equal to 0.2 g/cc; (ii.) both the first proppant stage and the second proppant stage contain a ULW proppant; (iii.) the rate of injection of the second proppant stage into the fracture is different from the rate of injection of the first proppant stage; or (iv.) the particle size of the second proppant stage is different from the particle size of the first proppant stage.

Abstract: A method of hydraulically fracturing a hydrocarbon-bearing subterranean formation ensures that the conductivity of water inflow below the productive zone of the subterranean formation is reduced. The method consists of two principal steps. In the first step, a fracture in and below the productive zone of the formation is initiated by introducing into the subterranean formation a fluid, free of a proppant, such as salt water, fresh water, brine, liquid hydrocarbon, and/or nitrogen or other gases. The proppant-free fluid may further be weighted. In the second step, a proppant laden slurry is introduced into the subterranean formation which contains a relatively lightweight density proppant. Either the fluid density of the proppant-free fluid is greater than the fluid density of the proppant laden slurry or the viscosity of the proppant-free fluid is greater than the viscosity of the proppant laden slurry.

Abstract: Water soluble nonionic friction reducers and added to coacervate gels having excellent shear viscosities and other properties. A preferred gel comprises poly diallyl dimethyl ammonium chloride, a lesser amount of sodium lauryl sulfonate, and lauryl alcohol. Excellent friction reducing properties are manifested; a particularly practical use for the compositions is in subterranean formation fracturing.

Abstract: The present invention provides compositions and methods for enhancing subterranean well productivity by enhancing fracture conductivity. A method of increasing the conductivity of a fracture in a portion of a subterranean formation comprising providing a slurry comprising a fracturing fluid, a degradable material, and proppant particulates coated with a tackifying agent; allowing the degradable material to become at least temporarily attached to the tackifying agent coated onto the proppant particulates so as to avoid substantial segregation of the degradable material from the proppant particulates within the slurry; introducing the slurry to the fracture and allowing the proppant particulates and degradable material to form a substantially uniform particulate pack; and, allowing the degradable material to degrade and produce a particulate pack having voids therein.

Abstract: In one embodiment, the present invention provides a method of reducing the viscosity of a viscosified treatment fluid comprising contacting the viscosified treatment fluid with an acid generated from an orthoester composition that comprises an orthoester. In another embodiment, the present invention provides a method of reducing the pH of a viscosified treatment fluid comprising providing an orthoester composition that comprises an orthoester; contacting the viscosified treatment fluid with the orthoester composition; allowing the orthoester to generate a generated acid; and allowing the generated acid to at least partially reduce the pH of the viscosified treatment fluid. Embodiments of fracturing and gravel packing methods also are disclosed.

Abstract: Small spheres, commonly referred to as proppants, are manufactured from sol-gel ceramics, preferably aluminosilicates or phosphates, and include chemical composites termed geopolymers. In the preferred manufacturing process, the required chemical components are blended, and the proppant particles are shaped and cured at low temperatures. The proppant particles have high compressive strength, are chemically inert, and a low specific gravity, making them particularly suited for hydraulic fracturing.

Abstract: The present invention relates to methods and compositions for treating subterranean formations, and more specifically, to improved methods and compositions for generating acids for use downhole, for example, to at least partially degrade the acid-soluble portions of filter cakes deposited in subterranean formations. In one embodiment, the present invention provides a method of degrading an acid-soluble portion of a filter cake comprising contacting the acid-soluble portion of the filter cake with an acid generated from an orthoester.

Abstract: A method of the preparation and utilization of polymerized alpha-hydroxycarboxylic-acid-coated proppants for gravel pack and removal of filter cake that was deposited by reservoir drilling fluid. In a preferred example, polyglycolic-acid-coated sand is used to replace conventional gravel pack sand typically used for gravel packing. Under downhole conditions, the acidic by-product generated from the hydration of polyglycolic-acid-coated sand can break down acid-soluble and/or acid-breakable components embedded in the filter cake. This reaction enhances the filter cake removal and the flow of hydrocarbon from the producing formation. The polyglycolic-acid-coated sand may be produced by polymerizing a glycolic acid with a natural or synthetic proppant like 20–40 mesh commercial sand, at temperatures of about 210° F. or higher.

Abstract: Improved methods and compositions for degrading filter cake deposited in a subterranean formation are provided. These methods and compositions utilize particulates coated with acid-releasing degradable material wherein the released acid is used to degrade a filter cake.

Abstract: The present invention provides reduced-density coated particulates and methods for enhancing the transport of such particulates into well bores and fractures, and for enhancing the conductivity and permeability of subterranean formations using such particulates, and for sand control treatments using such particulates. The reduced-density, coated particulates of the present invention generally comprise particulate having a surface and a coating wherein the surface comprises a porous or partially hollow geometry and coating is capable of trapping a fluid between the particulate's surface and the coating.

Abstract: Methods are presented to induce a screenout during a subterranean formation fracturing or combined fracturing and gravel packing treatment having a viscoelastic surfactant-based carrier fluid by laying down a filter cake at least a portion of which is a base-soluble material, injecting proppant slurry, and causing hydrolysis and dissolution of the solid base-soluble material by adding base so that leak-off increases, the concentration of proppant in the fracture increases, and the proppant screens out. A method of gravel packing with a viscoelastic surfactant-based carrier fluid by laying down a filter cake at least a portion of which is a base-soluble material, injecting gravel, and causing hydrolysis and dissolution of the solid base-soluble material by adding base. Methods of slowing or accelerating the hydrolysis and dissolution are given, and addition of bridging-promoting materials is included.

Abstract: A proppant mixture with an extended particle size distribution exhibits improved properties, such as crush strength and conductivity, as compared with a conventional product with a narrow size distribution.

Abstract: The present invention involves methods of preparing coated particulates and using such coated particulates in subterranean applications such as production enhancement and sand control. One embodiment of the present invention provides a method of preparing coated particulates comprising the steps of coating particulates with a resin or a tackifying agent to create pre-coated particulates; and, covering the pre-coated particulates with a partitioning agent to create coated particulates.

Abstract: The present invention relates to enhancing fluid flow from subterranean formations. More particularly, this invention relates to providing improved proppant matrixes within fractures in a subterranean formation. An example of the methods of increasing the conductivity of a fracture in a subterranean formation comprises the steps of providing a fracturing treatment fluid comprising a proppant composition, the proppant composition comprising proppant particulates and a degradable material capable of undergoing an irreversible degradation downhole; introducing the proppant composition to the fracture; and allowing the proppant composition to form a proppant matrix having voids in the fracture.

Abstract: A low density, spherical proppant made from kaolin clay having an alumina content distributed homogeneously throughout the pellets, an apparent specific gravity of from about 1.60 to about 2.10 g/cc, and a bulk density of from about 0.95 to about 1.30 g/cc. The low density is achieved by controlling the time and temperature of the firing process to be from about 1200 to about 1350° C. This low density proppant is useful in hydraulic fracturing of shallow oil and gas wells.

Abstract: Disclosed is a method of determining the extent of recovery of materials injected into oil wells or subsurface formations. The method includes injection of one or more tracers into an oil well or into a formation. Included in the method are the steps of introducing a material of interest into the oil well or into the subsurface formation associated with the bore of the oil well; introducing a tracer into the oil well or into the subsurface formation associated with the bore of the oil well; recovering from the oil well a production fluid, analyzing the production fluid for a concentration of the chemical tracer present in the production fluid; and calculating the amount of material of interest recovered from the oil well using the concentration of the chemical tracer present in the production fluid as a basis for the calculation.

Abstract: The present invention involves enhancing the conductivity of subterranean propped fractures penetrating formations while controlling proppant flowback. More particularly, the present invention relates to improved consolidation performance of resin-coated proppants and their use in controlling proppant flowback. Some embodiments of the present invention provide methods of controlling proppant flowback from a fracture in a subterranean zone comprising the steps of providing resin coated proppant; providing tackifying composition; coating the tackifying composition onto at least a portion of the resin coated proppant to create tackified resin coated proppant; introducing the tackified resin coated proppant into a subterranean fracture; and, allowing the tackified resin coated proppant to substantially cure.

Abstract: Improved methods and compositions for consolidating proppant in fractures formed in subterranean zones are provided. An improvement of this invention comprises using proppant particles having a coating of hardenable resin including a gel breaker. The gel breaker facilitates removal of gelled carrier fluid from the surface of the proppant particles.

Abstract: Light weight high strength particles and methods of treating subterranean producing zones utilizing the particles are provided. The light weight high strength particles of the invention are basically comprised of sintered mixtures of a base material and hollow microspheres.

Abstract: Methods are presented to induce a screenout during a subterranean formation fracturing or combined fracturing and gravel packing treatment by laying down a filter cake early in the treatment, then injecting proppant slurry, and then while proppant slurry injection continues chemically damaging the filter cake with one or more filter cake degradation agents so that leak-off increases, the concentration of proppant in the fracture increases, and the proppant screens out. The additional use of filter cake degradation agent aids and bridging-promoting materials is included.

Abstract: Methods and compositions for preventing fracture proppant particle flowback from subterranean zones penetrated by well bores are provided. The methods basically comprise the following steps. One or more fractures are formed in a subterranean zone and proppant particles coated with a curable liquid composition for consolidating the proppant particles into resilient permeable masses are deposited in the fractures. The curable liquid composition is a mixture of a tackifying compound liquid and a curable resin. After the coated proppant particles have been deposited, the curable liquid composition is allowed to cure.

Abstract: Improved methods and compositions for consolidating proppant in subterranean fractures are provided. In accordance with a method of the invention, proppant particles coated with a furfuryl alcohol resin composition are mixed with a gelled liquid fracturing fluid and the fracturing fluid is pumped into a subterranean zone. The fracturing fluid forms one or more fractures in the subterranean zone and deposits the proppant particles coated with the resin composition therein. Thereafter, the hardenable resin composition on the proppant particles is allowed to harden by heat and consolidate the proppant particles into chemical and thermal degradation resistant permeable packs.

Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.

Abstract: Methods of fracturing subterranean zones with less pumping are provided. The methods basically comprise the steps of providing an aqueous fracturing fluid comprised of a brine having a density in the range of from about 9 to about 19 pounds per gallon, pumping the aqueous fracturing fluid into the subterranean zone at a rate and pressure sufficient to fracture the subterranean zone and recovering the aqueous fracturing fluid from the subterranean zone.

Abstract: Light weight high strength particles and methods of treating subterranean producing zones utilizing the particles are provided. The light weight high strength particles of the invention are basically comprised of sintered mixtures of a base material and hollow microspheres.

Abstract: Methods and compositions for placing particulate materials in subterranean zones penetrated by well bores are provided. The methods basically comprise the following steps. A pumpable compacted particulate material fluid is prepared or provided comprising compacted particulate material and a foam within the pore spaces of the compacted particulate material. The foam comprises a pressurized gas and a liquid solution of a foam forming surfactant. After being prepared or provided, the compacted particulate material fluid is pumped into a subterranean zone by way of a well bore penetrating the zone.

Abstract: Improved methods and compositions for consolidating proppant in subterranean fractures are provided. In accordance with the methods of the invention, proppant particles coated with a hardenable bisphenol A-epichlorohydrin resin composition are mixed with a gelled liquid fracturing fluid and the fracturing fluid is pumped into a subterranean zone. The fracturing fluid forms one or more fractures in the subterranean zone and deposits the proppant particles coated with the resin composition therein. Thereafter, the hardenable resin composition on the proppant particles is allowed to harden by heat and consolidate the proppant particles into degradation resistant permeable packs. The hardenable bisphenol A-epichlorohydrin resin compositions of the invention are storable for long periods of time before use.

Abstract: Methods of reducing or preventing particulate flow-back in subterranean zones are provided. In accordance with the methods, a treating fluid having a mixture of reticulated foam fragments and particulate solids suspended therein is provided. The treating fluid is introduced into a subterranean zone and the mixture of the reticulated foam fragments and the particulate solids are deposited in the subterranean zone whereby the reticulated foam fragments retard or prevent the flow-back of the particulate solids and the transport of formation fines from the subterranean zone upon the flowing-back of fluid from the zone.

Abstract: A proppant mixture with an extended particle size distribution exhibits improved properties, such as crush strength and conductivity, as compared with a conventional product with a narrow size distribution.

Abstract: Methods and compositions useful for sand control and/or hydraulic fracturing of subterranean formations that utilize relatively lightweight and/or substantially neutrally buoyant particles as particulate sand control or proppant material. Particles that may be employed include particulates of naturally-occurring materials that may be optionally strengthened or hardened by exposure to a modifying agent. Effectiveness of a modifying agent may be optionally enhanced by facilitating interaction between a modifying agent and one or more components present in a naturally occurring material by using enhancing agents and/or by using conditions that enhance interaction.

Abstract: A proppant mixture with an extended particle size distribution exhibits improved properties, such as crush strength and conductivity, as compared with a conventional product with a narrow size distribution.

Abstract: An improved lightweight and highly permeable proppant composition for use in increasing the productivity of a gas or oil well. The proppant composition includes equal amounts by weight of uncalcined bauxite, uncalcined shale and quartz, held together with a binder formed of wollastonite and talc in an amount of less than 10% by weight of the composition. The proppant composition has an alumina content of less than 25% by weight of the composition and a silica content of over 45% by weight of the composition.

Abstract: Methods of reducing proppant flowback during production of fluids form subterranean formations are provided. Compressed sieves made from a shape memory material are introduced into hydraulic fracturing opera into hydraulic fractures in subterranean formations during hydraulic fracturing operations or subsequent thereto. The heat of the formation, or introduced heat, triggers the return of the sieves to their previous uncompressed shape and size. The sieves thereby wedge themselves into position within the fractures and serve to filter proppant and formation fines from produced fluids.

Abstract: Compositions and methods for determining the source of treatment fluids being produced from a production formation having multiple zones by introducing a treatment composition having a tracking material into a zone in the subterranean formation, and detecting the tracking material in treatment composition that flows back from the subterranean formation.

Abstract: A method of the preparation and utilization of polymerized alpha-hydroxycarboxylic-acid-coated proppants for gravel pack and removal of filter cake that was deposited by reservoir drilling fluid. In a preferred example, polyglycolic-acid-coated sand is used to replace conventional gravel pack sand typically used for gravel packing. Under downhole conditions, the acidic by-product generated from the hydration of polyglycolic-acid-coated sand can break down acid-soluble and/or acid-breakable components embedded in the filter cake. This reaction enhances the filter cake removal and the flow of hydrocarbon from the producing formation. The polyglycolic-acid-coated sand may be produced by polymerizing a glycolic acid with a natural or synthetic proppant like 20-40 mesh commercial sand, at temperatures of about 210° F. or higher.

Abstract: Improved methods of forming fractures containing resilient proppant particle packs which prevent the production of sand and fines with produced fluids and prevent proppant flow-back in a subterranean zone penetrated by a well bore are provided. As the fractures are formed, a liquid hardenable resin component is mixed with a liquid hardening agent component and a liquid rubber component to form a hardenable resin composition. The hardenable resin composition is coated onto dry proppant particles which are suspended in the fracturing fluid and placed in the fractures. The hardenable resin composition on the resin composition coated proppant particles is allowed to harden and consolidate the proppant particles into high strength resilient permeable packs.

Abstract: Viscoelastic surfactant based aqueous fluid systems useful as thickening agents in various applications, e.g. to suspend particles produced during the excavation of geologic formations. The surfactants are zwitterionic/amphoteric surfactants such as dihydroxyl alkyl glycinate, alkyl ampho acetate or propionate, alkyl betaine, alkyl amidopropyl betaine and alkylimino mono- or di-propionates derived from certain waxes, fats and oils. The thickening agent is used in conjunction with an inorganic water-soluble salt or organic additive such as phthalic acid, salicylic acid or their salts.