Organic Contaminant Is Asphaltic Patents (Class 507/930)
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Patent number: 8877689Abstract: Of the many compositions and methods provided herein, one example composition includes a treatment fluid comprising: an aqueous fluid; and a tar stabilizing polymer comprising at least one polymer selected from the group consisting of a styrene polymer, an acrylate polymer, a styrene-acrylate polymer, and any combination thereof.Type: GrantFiled: July 23, 2012Date of Patent: November 4, 2014Assignee: Haliburton Energy Services, Inc.Inventors: Philip Wayne Livanec, Greg Paul Perez
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Patent number: 8778850Abstract: Formulation for a natural product as a replacement for the use of traditional acidic chemical stimulation methods for the emulsification, removal and release of paraffin and asphaltenes from low producing or pumped off wells and reservoirs with the use of traditional methodologies. Also a method of use of formulation for stimulating an oil well consisting of introducing into the wellbore a biodegradable, non-reactive fluid system containing a water-miscible fatty acid solvent, a solution of fatty acids, an amino alcohol, and at least one non-ionic surfactant. The fluid system may be further in the form of a nanoemulsion that is formed by combining a colloidal solution with one or more emulsifiers, an alcohol, and water. The fluid system may be used in well remediation and stimulation as well as additional, alternative applications such as the cleaning of surface and/or downhole equipment.Type: GrantFiled: October 24, 2013Date of Patent: July 15, 2014Assignee: Green Earth Technologies, Inc.Inventor: Paul Andrecola
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Patent number: 8741816Abstract: Of the many compositions and methods provided herein, one method includes a method comprising: contacting tar resident in a well bore with a tar stabilizing polymer comprising at least one polymer selected from the group consisting of a styrene polymer, an acrylate polymer, a styrene-acrylate polymer, and any combination thereof; and allowing the tar stabilizing polymer to interact with the tar to at least partially reduce the tendency of the tar to adhere to a surface.Type: GrantFiled: February 8, 2012Date of Patent: June 3, 2014Assignee: Halliburton Energy Services, Inc.Inventors: Philip Wayne Livanec, Greg Paul Perez
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Patent number: 8603951Abstract: Of the many compositions and methods provided herein, one method includes a method comprising: contacting tar resident in a well bore with a treatment fluid comprising a styrene-acrylate polymer; and allowing the styrene-acrylate polymer to interact with the tar to at least partially reduce the tendency of the tar to adhere to a surface. Another method provided herein includes a method for treating tar sand comprising: contacting the tar sand with a treatment fluid comprising an aqueous fluid and a styrene-acrylate polymer, the tar sand comprising tar and sand; and allowing the styrene-acrylate polymers to interact with the tar to at least partially separate the tar from the sand.Type: GrantFiled: December 3, 2009Date of Patent: December 10, 2013Assignee: Halliburton Energy Services, Inc.Inventor: Gregory P. Perez
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Patent number: 7497261Abstract: A method for cleaning oil wells to increase the flow of oil thereof by use of a unique aqueous cleaning emulsion comprising of water, hydrocarbon solvent, and detergent. This one step method provides for the simultaneously cleaning/removal of asphaltene and/or paraffin and scale. This method can be used alone or with the assistance of a wash tool which is a combination pressure and surge wash tool having a nipple assembly. A by-pass port is coupled to the nipple assembly and a diverter cup is coupled to the by-pass port. A plurality of pressure wash cups are positioned on the tool. A pressure wash port is located between the plurality of pressure wash cups and a pump shoe assembly is coupled to a bottom pressure wash cup.Type: GrantFiled: October 1, 2007Date of Patent: March 3, 2009Inventor: Richard J. Dyer
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Patent number: 7455111Abstract: Fluid producing wells may be treated with a water-in-oil emulsion for the removal or inhibition of unwanted solid particulates, including pipe dope, asphaltenes and paraffins. Such emulsions are of particular applicability in the displacement of oil base drilling muds and/or residues from such muds from producing wells. The water-in-oil emulsions may optionally contain a dispersing agent as well as a surfactant.Type: GrantFiled: February 2, 2007Date of Patent: November 25, 2008Assignee: BJ Services CompanyInventors: Qi Qu, Richard F. Stevens, Jr., David Alleman
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Patent number: 7392846Abstract: Methods and compositions for use in subterranean operations, and more particularly, additives comprising one or more silicates used to treat tar resident in a well bore, and methods of use, are provided. In one embodiment, the method comprises a method of treating tar resident in a well bore comprising providing a tar-treating additive comprising one or more silicates introducing the tar-treating additive into the well bore; and allowing the tar-treating additive to react with the tar resident in the well bore so as to at least partially reduce the adhesiveness of the tar.Type: GrantFiled: January 22, 2007Date of Patent: July 1, 2008Assignee: Halliburton Energy Services, Inc.Inventor: Gregory P. Perez
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Patent number: 7311158Abstract: The present invention relates to methods and compositions for use in subterranean operations. More particularly, the present invention relates to additives comprising one or more silicates used to treat tar resident in a well bore, and methods of use. In one embodiment, the present invention provides a method of treating tar resident in a well bore comprising providing a tar-treating additive comprising one or more silicates introducing the tar-treating additive into the well bore; and allowing the tar-treating additive to react with the tar resident in the well bore so as to at least partially reduce the adhesiveness of the tar.Type: GrantFiled: December 30, 2004Date of Patent: December 25, 2007Assignee: Halliburton Energy Services, Inc.Inventor: Gregory P. Perez
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Patent number: 7296627Abstract: A method for cleaning oil wells to increase the flow of oil thereof by use of a unique aqueous cleaning emulsion comprising of water, hydrocarbon solvent, detergent and mineral acid. This one step method provides for the simultaneously cleaning/removal of asphaltine and/or paraffin and scale. This method can be used alone or with the assistance of a wash tool which is a combination pressure and surge wash tool having a nipple assembly. A by-pass port is coupled to the nipple assembly and a diverter cup is coupled to the by-pass port. A plurality of pressure wash cups are positioned on the tool. A pressure wash port is located between the plurality of pressure wash cups and a pump shoe assembly is coupled to a bottom pressure wash cup.Type: GrantFiled: March 29, 2005Date of Patent: November 20, 2007Inventor: Richard J. Dyer
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Publication number: 20070251693Abstract: A composition is provided for delivering an organic solvent to a downhole portion of a wellbore for the production of hydrocarbon or to a portion of a pipeline for the transmission of hydrocarbon. The composition comprises: (A) water; (B) a weighting agent; (C) an organic solvent that is immiscible with water; and (D) a surfactant adapted for forming an oil-external emulsion of the organic solvent and the water, wherein the surfactant is unstable to hydrolysis. The composition is formed to be an oil-external emulsion. The density of the composition is formulated to be greater than that of pure water at standard temperature and pressure. A method is provided for delivering an organic solvent to a downhole portion of a wellbore for the production of hydrocarbon or to a portion of a pipeline for the transmission of hydrocarbon. The method comprises the steps of: (A) forming a composition according to the invention; and (B) introducing the composition into the wellbore or into the pipeline.Type: ApplicationFiled: April 18, 2007Publication date: November 1, 2007Inventors: Gary J. Cheramie, Richard W. Pauls
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Patent number: 6723683Abstract: The present invention relates to biodegradable chemical compositions wherein core substrates, particularly oil well chemicals, are adsorbed onto particulate starch, particularly granular starch, providing a stable, controlled release formulation suitable for use in oil field applications. The invention further relates to the process of preparing obtaining these compositions.Type: GrantFiled: August 7, 2001Date of Patent: April 20, 2004Assignee: National Starch and Chemical Investment Holding CorporationInventors: Martin C. Crossman, James A. Rosie, Daniel B Solarek
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Patent number: 6702022Abstract: An oil well capsule to reduce the paraffin and asphaltene which accumulate on the walls of the pipes which are used to bring the oil up from underground deposits, and a method of using the oil well capsule. An oil well capsule having a shell encapsulating a chemically active mass wherein the chemically active mass consists essentially of alkaline or alkaline earth metal.Type: GrantFiled: June 20, 2001Date of Patent: March 9, 2004Inventors: Gennady V. Kattsyn, Boris E. Kogai
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Patent number: 6630428Abstract: The use of high flash point, low vapor pressure compositions for injection into, and coating of, gas and oil wells and surrounding underground hydrocarbon bearing formations and processing equipment for the purpose of removing scale, paraffins, tars, and other viscous constituents. Treatment results in increased flow of gas and/or oil and decreased adhesion of soil and scale in all aspects of oil and gas recovery, including hydrocarbon bearing formations, casings, lines and pumping equipment. The composition contains about 40 to 99 wt. % of a fatty acid alkyl ester blend and about 1 to 25 wt. % of at least one lower alkyl glycol ether.Type: GrantFiled: September 28, 2000Date of Patent: October 7, 2003Assignee: United Energy CorporationInventors: Harvey A. Furman, Kenneth R. Cioletti
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Publication number: 20030024703Abstract: This disclosure relates to a method and composition for cleaning and inhibiting solid, bitumin tar, and viscous fluid deposition in well equipment used in conjunction with a water-based well fluid which includes mixing an effective amount of a miscible terpene in the well fluid. In one embodiment, a method for cleaning and inhibiting deposits in and on well equipment used in conjunction with a water-based well fluid which includes mixing an effective amount of d-limonene into the well fluid is disclosed.Type: ApplicationFiled: July 16, 2001Publication date: February 6, 2003Inventors: Neil McKenzie, John Ewanek
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Patent number: 6467492Abstract: A method of preventing corrosion in pipelines comprising draining pipeline of all residual compounds, blowing through with nitrogen and rinsing with a corrosion inhibiting rinsing agent.Type: GrantFiled: February 23, 2001Date of Patent: October 22, 2002Assignee: Illinois Tool Works, Inc.Inventors: William Hopkins, Christopher Nettleship
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Patent number: 6440330Abstract: The invention involves the demulsification and liquefaction of hydrocarbon based sludges. A demulsifier and a liquefaction agent and methods of using the same are disclosed. In a preferred embodiment, the demulsifier contains a salt of DDBSA, polypropylene glycol, and citrene. In a preferred embodiment, the liquefaction agent contains a glycol ether and sodium silicate. In another preferred embodiment, the liquefaction agent contains a glycol ether and citrene. In preferred practice, the sludge is treated with the liquefaction agent, circulated, treated with the demulsifier, and circulated further. An object of the invention is to provide a hydrocarbon based sludge that is sufficiently liquefied to be pumped and which is sufficiently demulsified to allow the waters, oils, and solids in the sludge to separate.Type: GrantFiled: March 8, 2000Date of Patent: August 27, 2002Assignee: TexChem Group International, LLCInventor: Gale Campbell
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Patent number: 5690176Abstract: Process for the dissolution of asphaltene sediments in oil wells which consists in introducing a solubilizing composition for the above asphaltenes into the oil wells, characterized in that the solubilizing composition comprises:(a) a basically hydrocarbon fraction consisting of at least 70%, preferably at least 80% by weight, of aromatic and alkyl aromatic hydrocarbons, the alkyl group being from C.sub.1 to C.sub.4 ;(b) a fraction basically consisting of quinoline and isoquinoline as such or alkyl substituted, preferably as such, the alkyl group being from C.sub.1 to C.sub.4 ; the weight ratio between fraction (a) and (b) being from 97.5/2.5 to 75/25, preferably from 97/3 to 90/10.Type: GrantFiled: March 12, 1996Date of Patent: November 25, 1997Assignee: Agip S.p.A.Inventors: Alberto Delbianco, Fabrizio Stroppa
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Patent number: 5670460Abstract: A concentrate for use with an oil or water carrier for injection into a well to enhance production and a method of well treatment are disclosed. The five part concentrate contains xylene, an aliphatic hydrocarbon solvent such as kerosene, a non-ionic emulsifier, a non-ionic surfactant and an amphoteric detergent. The xylene and kerosene create a solvent hole in the materials restricting flow. The surfactant expands the holes while the detergent and emulsifier assist in dispersing the removed material to thereby stimulate production from the well. The injection of the concentrate and carrier mixture can take place during shut-in of the well or during continued production.Type: GrantFiled: January 16, 1996Date of Patent: September 23, 1997Inventors: Jerry S. Neely, Richard D. Neely
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Patent number: 5622921Abstract: This invention relates to anionic compositions, containing an alkyl aryl sulfonic acid or salt thereof, a nonethoxylated glycol and an acetylenic alcohol in an alkyl alcohol solvent, that have proved effective for controlling sludge and emulsion formation during acid stimulation and treatment of hydrocarbon wells.Type: GrantFiled: January 21, 1993Date of Patent: April 22, 1997Assignee: Nowsco Well Service, Inc.Inventor: Richard J. Dyer
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Patent number: 5438039Abstract: Particular hydrocarbon composition constituted by saturated species, alkylbenzenes and polyaromatics, useful for dissolving asphaltenic residues present in oil wells.Type: GrantFiled: August 3, 1994Date of Patent: August 1, 1995Assignees: AGIP S.p.A., Eniricherche S.p.A.Inventors: Alberto Del Bianco, Fabrizio Stroppa