Flooding The Formation Patents (Class 507/936)
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Patent number: 12209217Abstract: Provided is a composition including fluid carbon dioxide and a polyolefin thickener, wherein the polyolefin thickener includes a polymer of one or more olefin monomers having 8 or more carbon atoms, wherein at least 5 mol percent of the olefin monomers have 12 or more carbon atoms. Associated methods are also provided.Type: GrantFiled: April 19, 2024Date of Patent: January 28, 2025Assignee: The Lubrizol CorporationInventors: Binbin Guo, Abbas Firoozabadi
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Patent number: 11920084Abstract: Compositions and methods for chemical enhanced hydrocarbon recovery that utilize a nonionic surfactant that is a mixture of isomerized C9-11 ethoxylated alcohols.Type: GrantFiled: August 30, 2022Date of Patent: March 5, 2024Assignee: Pioneer Natural Resources USA, Inc.Inventors: Dustin L. Walker, Joshua W. Brownlow, Kyle D. Scott
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Patent number: 11708751Abstract: Provided are methods of recovering oil from a reservoir using carbon dioxide foam flooding in which a carbon dioxide foam of increased strength is used.Type: GrantFiled: August 13, 2021Date of Patent: July 25, 2023Assignee: Saudi Arabian Oil CompanyInventors: Kenneth Richard Kibodeaux, Huseyin Onur Balan, Anuj Gupta
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Patent number: 8997862Abstract: A method includes introducing a treatment fluid including a first polymer gel into a subterranean formation to generate a production fluid having an aqueous portion and a hydrocarbon portion, treating the aqueous portion of the production fluid with chlorine dioxide to separate additional hydrocarbons from the aqueous portion, and adjusting the viscosity of the treated aqueous portion prior to introducing the treated aqueous portion back into the subterranean formation.Type: GrantFiled: June 27, 2014Date of Patent: April 7, 2015Assignee: Sabre Intellectual Property Holdings LLCInventor: John Mason
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Patent number: 8991500Abstract: A method includes introducing a treatment fluid into a wellbore penetrating a subterranean formation, the treatment fluid including a polymer gel having a water-soluble polymer, a proppant, and a polymer gel-preserving amount of chlorine dioxide, the placing step includes applying the treatment fluid at a sufficient pressure and at a sufficient rate to fracture the subterranean formation.Type: GrantFiled: September 19, 2013Date of Patent: March 31, 2015Assignee: Sabre Intellectual Property Holdings LLCInventor: John Mason
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Patent number: 8969262Abstract: The present invention includes the use of anhydride compositions, including alkyl and aryl anhydrides, for use as a demulsifier in resolving emulsions of water and oil. In particular, the anhydride composition can be used alone or in a blend with other demulsifiers. Suitable anhydrides suitable for the present invention include acetic and propionic, with acetic anhydride being preferred. The anhydride composition can be added directly to crude oil or other compositions to be resolved. As such, the demulsifier composition includes an anhydride, such as acetic anhydride, alone or in combination with other demulsifiers. The anhydride can be used in an amount ranging between trace and 100% by weight of the demulsifier composition.Type: GrantFiled: June 4, 2008Date of Patent: March 3, 2015Assignee: Nalco CompanyInventors: Duncan E. Williams, Richard Mgla
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Patent number: 8887804Abstract: The present invention relates to a method for the assisted recovery of crude oil from an underground formation, comprising: a) injecting, via at least one injection means in contact with the underground formation containing the crude oil, a liquid containing a mixture of at least: i) a salty aqueous medium, ii) a mixture of two zwitterionic viscosising surfactants or a mixture of two populations of said surfactants having a bimodal characteristic of the narrow distribution of Ri groups as defined below, in a weight content of between 1 and 0.05 wt %, preferably between 0.5 and 0.1 wt %, and more preferably between 0.4 and 0.15 wt %, such that the liquid has an oil/water interface tension of about 10 mN/m (milinewton per meter) or less as measured at room temperature (25° C.) and a viscosity of about 3 cPs or more as measured at a temperature of 80° C.Type: GrantFiled: February 10, 2010Date of Patent: November 18, 2014Assignee: Rhodia OperationsInventors: Guillaume Degre, Mikel Morvan
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Patent number: 8789592Abstract: A method includes introducing a treatment fluid including a first polymer gel into a subterranean formation to generate a production fluid having an aqueous portion and a hydrocarbon portion, treating the aqueous portion of the production fluid with chlorine dioxide to separate additional hydrocarbons from the aqueous portion, and adjusting the viscosity of the treated aqueous portion prior to introducing the treated aqueous portion back into the subterranean formation.Type: GrantFiled: September 19, 2013Date of Patent: July 29, 2014Assignee: Sabre Intellectual Property Holdings LLCInventor: John Mason
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Patent number: 8709982Abstract: The invention relates to the use of quaternary polyamines having formula (I) for the recovery of oil from reservoirs formula (I), wherein n>=1 R1 represents H, CH3, CH2CH3, CnH2n+1 R2 represents H2CHOHCH2, CH2, CH2CH?CH2 R3 represents CH3, CH2CH3, CnH2n+1 R4 represents CH2, CH2CH?CH2 when R2 and R4 are allyl group, they can jointly form aliphatic cyclic structures, the ratio between the carbon atoms and nitrogen atoms (C/N) ranges from 2 to 30.Type: GrantFiled: April 2, 2008Date of Patent: April 29, 2014Assignee: ENI S.p.A.Inventors: Lucilla Del Gaudio, Thomas Paul Lockhart, Emanuele Vignati
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Patent number: 8691732Abstract: A water-based fluid, containing: a non-ionic surfactant, which is stable in a temperature range from 10 to 90° C. and soluble in water; and a salt, wherein the non-ionic surfactant contains an alkyl polyglucoside selected from the group consisting of a C8 alkyl polyglucoside, a C10 alkyl polyglucoside, and mixtures thereof, and the salt is present, and is present in an amount up to 60%. In addition, a process for preventing the formation of a W/O inverse emulsion or resolving a W/O inverse emulsion that has already formed in an oil well in which an oil-based mud has been employed by injecting the water-based fluid into the oil well.Type: GrantFiled: June 9, 2008Date of Patent: April 8, 2014Assignee: ENI S.p.A.Inventors: Lucilla Del Gaudio, Paola Albonico, Sandra Cobianco, Chiara Neva Emiliani, Giuseppe Ripa
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Patent number: 8584750Abstract: A process for mineral oil production, especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 8 to 30 ethoxy units, which has a polydispersity of from 1.01 to 1.12, and at least one further surfactant is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.Type: GrantFiled: October 13, 2010Date of Patent: November 19, 2013Assignee: BASF SEInventors: Christian Bittner, Oetter Günter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
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Patent number: 8584751Abstract: A process for mineral oil production especially Winsor type III microemulsion flooding, in which an aqueous surfactant formulation which comprises at least one nonionic surfactant having 11 to 40 ethoxy units and a hydrophobic radical having 8 to 32 carbon atoms and at least one further surfactant differing therefrom is forced through injection wells into a mineral oil deposit and crude oil is removed from the deposit through production wells.Type: GrantFiled: October 13, 2010Date of Patent: November 19, 2013Assignee: BASF SEInventors: Christian Bittner, Günter Oetter, Jack Tinsley, Christian Spindler, Gabriela Alvarez Jürgenson, Sophie Vogel
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Patent number: 8573299Abstract: A method for enhancing oil recovery is disclosed. The method includes providing a subsurface reservoir containing hydrocarbons therewithin and a wellbore in fluid communication with the subsurface reservoir. A solution for injection into the reservoir is formed by mixing a composition with at least one non-ionic chemical, at least one polymer, and at least one alkali. The non-ionic chemical can be alcohol alkoxylates such as alkylaryl alkoxy alcohols or alkyl alkoxy alcohols. The solution is solution is clear and aqueous stable when mixed. The solution is injected through the wellbore into the subsurface reservoir.Type: GrantFiled: October 21, 2010Date of Patent: November 5, 2013Assignee: Chevron U.S.A. Inc.Inventors: Varadarajan Dwarakanath, Taimur Malik, Adam Christopher Jackson, Ping Zhao, Oya A. Karazincir, Sophany Thach
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Patent number: 8524643Abstract: Use of a mixture comprising a surfactant and a cosurfactant in the form of an aqueous solution for flooding underground deposits of hydrocarbons for mobilizing and recovering the hydrocarbons from the underground deposits, the cosurfactant being a substance or a group of substances selected from the following list: an amphiphilic comb polymer having a backbone with two or more side chains attached to the backbone, the side chains differing from one another and/or the side chains differing from the backbone in their amphiphilic character, an amphiphilic polymer having one or more hydrophobic subunits [A2] based on a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged double bonds, and one or more hydrophilic subunits [B2], or an amphiphilic polymer having the general structural formulaType: GrantFiled: September 23, 2011Date of Patent: September 3, 2013Assignee: BASF SEInventors: Juergen Huff, Guenter Oetter, Angelika Kuehnle, Susanne Petrovic, Marcus Guzmann, Ingo Muenster, Gregor Brodt
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Patent number: 8465668Abstract: Surfactants with polyether sulfonate structure, which have a propanonylsulfonic acid group as a head group, a process for preparing such surfactants and their use for tertiary mineral oil extraction.Type: GrantFiled: October 15, 2008Date of Patent: June 18, 2013Assignee: BASF SEInventors: Christian Bittner, Oetter Günter, Ulrich Steinbrenner, Jürgen Huff, Marcus Guzmann
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Patent number: 8256511Abstract: A process is disclosed for using heavy petroleum fraction as a drive fluid in the recovery of hydrocarbons from a subterranean formation. The hydrocarbons may be in the form of bitumen or heavy oil. The heavy petroleum fraction may be injected into at least one injection well and hydrocarbons produced out of at least one distinct production well. The heavy petroleum fraction may be co-injected together with steam and/or hot water and/or solvent. The heavy petroleum fraction may be a heavy fraction of a process used to upgrade crude oil, such as a heavy asphaltene fraction produced from solvent deasphalting crude oil produced by this recovery process.Type: GrantFiled: June 18, 2008Date of Patent: September 4, 2012Assignee: ExxonMobil Upstream Research CompanyInventors: Thomas J. Boone, Mori Y. Kwan, J. Pierre Lebel, Brad C. Harker
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Patent number: 8240380Abstract: Compositions having shear-gelling and shear-thickening properties are based on an amphiphilic polymer combined with hydrophilic particles and polyethyleneoxide. The hydrophilic particles preferably consist of a hydrous sodium lithium magnesium silicate. The amphiphilic polymer may be a synthetic polymer, a hydrophobically modified biopolymer, or both. The compositions may be employed in enhanced oil recovery operations.Type: GrantFiled: September 13, 2007Date of Patent: August 14, 2012Assignee: Schlumberger Technology CorporationInventors: Jean-Philippe Caritey, Mélanie Cady
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Patent number: 8076272Abstract: A process for preparing an alkylaryl sulfonate comprising (a) reacting at least one meta-xylene compound with olefin or a mixture of olefins having from about 10 to about 20 carbon atoms, in the presence of an acid catalyst, wherein the resulting product comprises no more than 40 weight percent of 1-alkyl-2,4 dimethylsubstituted aromatic compound and at least about 60 weight percent of 1-alkyl-3,5 dimethyl substituted aromatic compound; (b) sulfonating the product of (a); and (c) neutralizing the product of (b) with a source of alkali or alkaline earth metal or ammonia.Type: GrantFiled: November 19, 2009Date of Patent: December 13, 2011Assignee: Chevron Oronite Company LLCInventors: Andrew J. Howes, Curtis Bay Campbell, Sophany Thach
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Patent number: 8053396Abstract: Use of a mixture comprising a surfactant and a cosurfactant in the form of an aqueous solution for flooding underground deposits of hydrocarbons for mobilizing and recovering the hydrocarbons from the underground deposits, the cosurfactant being a substance or a group of substances selected from the following list: an amphiphilic comb polymer having a backbone with two or more side chains attached to the backbone, the side chains differing from one another and/or the side chains differing from the backbone in their amphiphilic character, an amphiphilic polymer having one or more hydrophobic subunits [A2] based on a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged double bonds, and one or more hydrophilic subunits [B2], or an amphiphilic polymer having the general structural formulaType: GrantFiled: June 8, 2006Date of Patent: November 8, 2011Assignee: BASF SEInventors: Jürgen Huff, Günter Oetter, Angelika Kühnle, Susanne Petrovic, Marcus Guzmann, Ingo Münster, Gregor Brodt
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Patent number: 7987907Abstract: Method for increasing the recovery of crude oil from a reservoir containing at least one porous and permeable subterranean formation wherein the formation includes sandstone rock and at least one mineral that has a negative zeta potential under the reservoir conditions and wherein crude oil and connate water are present within the pores of the formation. The method is carried out by (A) injecting into the formation a slug of an aqueous displacement fluid that displaces crude oil from the surface of the pores of the formation wherein the pore volume (PV) of the slug of the aqueous displacement fluid is at least 0.Type: GrantFiled: September 5, 2007Date of Patent: August 2, 2011Assignees: BP Exploration Operating Company Limited, BP Corporation North America Inc.Inventors: Ian Ralph Collins, Gary Russell Jerauld
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Patent number: 7798219Abstract: Process and a method for enhancing recovery of petroleum from an underground source including injecting into the source, a petroleum displacement agent including fluids and modified liposomes. The liposomes and fluids merge the discrete oil droplets after waterflood into a continuous layer of oil (oil phase) eliminating b-pass of water through oil and employ mobility control through transition of gel phase to liquid crystalline phase.Type: GrantFiled: March 25, 2009Date of Patent: September 21, 2010Inventor: Gideon N. Harnoy
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Patent number: 7691790Abstract: The present invention includes a cost effective custom-designed blend of organic chemicals to stimulate oil production. The invention includes a chemical composition for use in drilling operations for oil recovery and the method of using the chemical composition. The chemical composition includes an ammonia compound, an alcohol, and aqueous carrier solution. The aqueous carrier solution is of sufficient volume such that it is operable to fully dissolve the ammonia compound and alcohol in the aqueous carrier solution.Type: GrantFiled: October 16, 2008Date of Patent: April 6, 2010Assignee: Coriba Technologies, L.L.C.Inventor: Harvey G. Cobb
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Patent number: 7373977Abstract: A process for recovering oil by injecting into a subterranean oil-bearing reservoir through one or more injection wells, an aqueous solution containing one or more amphoteric alkyl amido betaine surfactants that form a viscoelastic gel reducing interfacial tension and increasing the viscosity of the injection fluid simultaneously, displacing the solution into the reservoir, and recovering the oil from one or more production wells. These viscoelastic gels are tolerant to electrolytes and multivalent cations. They are shear reversible and adsorbed little onto the reservoir. Their viscosity is reduced when contacting certain hydrocarbons but remains high when contacting water or brine. This allows the fluid to preferentially penetrate the oil-bearing portions of the formation and resulting additional oil recovery.Type: GrantFiled: March 16, 2005Date of Patent: May 20, 2008Assignee: Oil Chem TechnologiesInventors: Paul Daniel Berger, Christie Huimin Berger
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Publication number: 20080011475Abstract: An oil recovery method employing amphoteric surfactants with the steps of: a) Injecting into one or more injection wells an aqueous solution containing a mixture of amphoteric surfactants containing mixture of amphoteric surfactants having a hydrocarbyl chain length between 8 and 26 and certain degree of unsaturation, and b) recovering the oil from one or more producing wells. The aqueous injection fluid may also contain one or more of the following: a thickening agent, an alkali, a co-solvent.Type: ApplicationFiled: July 14, 2007Publication date: January 17, 2008Inventors: Paul Daniel Berger, Christie Huimin Berger
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Publication number: 20040011526Abstract: A method of recovering oil or contaminants from subterranean reservoirs using a surfactant system where an adsorption reducing agent is injected before, after, and/or with the surfactant system. The adsorption reducing agent is formed by the reaction of an olefin sulfonic acid and phenol/aldehyde resin, the structure which is shown below where M may be Hydrogen or any cation, R is hydrogen, alkyl, alkenyl, etc., X is methylene or other aldehyde derived bridge, Y is hydrogen, ethylene oxide, propylene oxide, butylene oxide or mixtures of two or more of these, x+y is greater than 2 and n is equal or greater than 1.Type: ApplicationFiled: July 22, 2002Publication date: January 22, 2004Inventors: Paul D. Berger, Christie H. Berger
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Patent number: 6043391Abstract: New anionic surfactants and methods of preparation which are derived from aromatic or substituted aromatic molecules and alkenesulfonic acid. Wherein the aryl compound is alkylated and sulfonated in one-step with an alkene sulfonic acid prior to sulfonic acid neutralization. The methods allow the functional sulfonate group to be attached to the end of the alkyl chain rather than to the aromatic ring thus allowing for selective substituted groups, either branched, linear or alkoxylated or combinations thereof to be placed on the aryl compound prior to sulfonation and alkylation.Type: GrantFiled: January 20, 1998Date of Patent: March 28, 2000Inventors: Paul D. Berger, Christie H. Berger, Iris K. Hsu
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Patent number: 6022834Abstract: An improved concentrated surfactant formulation and process for the recovery of residual oil from subterranean petroleum reservoirs, and more particularly an improved alkali surfactant flooding process which results in ultra-low interfacial tensions between the injected material and the residual oil, wherein the concentrated surfactant formulation is supplied at a concentration above, at, or, below its CMC, also providing in situ formation of surface active material formed from the reaction of naturally occurring organic acidic components with the injected alkali material which serves to increase the efficiency of oil recovery.Type: GrantFiled: April 4, 1997Date of Patent: February 8, 2000Assignee: Oil Chem Technologies, Inc.Inventors: Oliver YeSung Hsu, Nelson SungNan Hsu
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Patent number: 5911276Abstract: A method for the enhanced recovery of oil comprises injecting into an oil-containing formation an aqueous surfactant system having at least (1) a blend containing an unmodified Kraft lignin, an oil-soluble amine and a water-soluble sulfonate, and (2) water; driving the surfactant system through the formation and producing the oil mobilized by the surfactant system. A surfactant composition useful for enhanced oil recovery methods is also provided having at least an unmodified Kraft lignin, an oil-soluble amine and a water-soluble sulfonate.Type: GrantFiled: May 27, 1997Date of Patent: June 15, 1999Assignee: Texaco IncInventor: Dan Edward Kieke
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Patent number: 5780395Abstract: A foam is provided having utility for improving sweep efficiency in subterranean oil-bearing formations and having specific utility for conformance improvement treatments and mobility control in such formations. The foam is a gel medium having a gas dispersed therein. The gel medium is made up of a crosslinkable polymer, a crosslinking agent, a surfactant and a liquid solvent.Type: GrantFiled: February 21, 1992Date of Patent: July 14, 1998Assignee: Marathon Oil CompanyInventor: Robert D. Sydansk
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Patent number: 5725771Abstract: Process for the treatment of drilling muds recovered at the surface of the ground, especially synthetic muds, characterized in that it comprises at least one stage of hydrolysis of said mud by means of a lipase.Type: GrantFiled: April 15, 1996Date of Patent: March 10, 1998Assignee: Elf Aquitaine ProductionInventors: Sophie Aliphat, Frederic Perie, Christian Zurdo, Alain Martignon
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Patent number: 5478802Abstract: A gelling composition and a process for wellbore treatment comprising injecting the composition into reservoirs are disclosed wherein the composition comprise a produced brine; a water-soluble polymer such as, for example, polyacrylamide; a crosslinker such as, for example, a complexed zirconium compound; and optionally a complexing ligand such as, for example, lactic acid.Type: GrantFiled: December 29, 1992Date of Patent: December 26, 1995Assignee: Phillips Petroleum CompanyInventor: Ahmad Moradi-Araghi
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Patent number: 5401425Abstract: A method for recovering surfactants from produced fluids by mixing with produced fluids about 0.1% to about 5% of a nonionic surfactant having a phase inversion temperature above the temperature of the produced fluids, heating the mixture above the phase inversion temperature, mixing the phase containing oil and the surfactants with water, and cooling the mixture below the phase inversion temperature to extract the surfactants into an aqueous phase, provided that if a sufficient concentration of the nonionic surfactant is already in the produced fluids, it need not be added.Type: GrantFiled: May 16, 1994Date of Patent: March 28, 1995Assignee: Texaco Inc.Inventor: Gabriel Prukop