Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one friction reducing agent selected from the group consisting of guar gums, polyacrylamides, hydratable cellulosic materials, viscoelastic surfactants, and mixtures thereof. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for use in fracturing subterranean formations. Methods for inhibiting formation and/or precipitation of metal oxides in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: Fluid treatment systems and compositions are provided including (a) at least one material including (1) at least one carboxylic acid functional group and (2) at least one sulfur-containing group selected from the group consisting of sulfonyl functional groups, sulfonate functional groups and mixtures thereof; and (b) at least one scale control agent. The fluid treatment systems and compositions can be used to treat aqueous systems, for example as fracturing fluids for treating aqueous compositions found in subterranean formations. Methods for inhibiting formation and/or precipitation of calcium salts in an aqueous composition using the fluid treatment systems or compositions also are provided.

Abstract: A method for releasing a stuck drill string in the borehole of an underground formation employing an non-aqueous drilling fluid, the illustrative method including contacting the stuck drill string with a non-emulsion based, homogeneous additive composition effective in reducing the annular pressure exerted by the drilling fluid or mud cake against the stuck drill string and releasing the stuck drill string, the additive composition formulated to include a mutual solvent and a viscosifying agent. In one illustrative embodiment the mutual solvent is a C2 to C22 glycol or a C2 to C22 glycol ether or mixtures or combinations of these and similar compounds known to one of skill in the art. Alternatively and preferably, the mutual solvent may be selected from the group consisting of: diethylene glycol, propoxy propanol, butyl cellosolve, butyl carbitol and mixtures or combinations of these and similar compounds known to one of skill in the art.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alterative embodiment, calcium chloride and water may be substituted for glycerin.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.

Abstract: The present invention relates to a well fluid for releasing tubular elements stuck in the well. The fluid comprises a part A consisting of one or more esters obtained by reaction of a linear or branched monocarboxylic acid (A.1) having between 8 and 24 carbon atoms and a linear or branched polyol (A.2) having between 2 and 20 carbon atoms, a part B consisting of one or more linear or branched monocarboxylic acids having between 8 and 24 carbon atoms, where the carboxylic acid (A.1 and part B) is a mixture of at least 80% carboxylic acids having between 1 and 3 insaturations, and a part C consisting of a different ester or olefins, the quantity of part C is determined in relation to the other components in such a way that the viscosity of the fluid is lower than 40 mPa·s at 40° C. The invention also relates to a method for releasing drillpipes stuck in a well.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.

Abstract: A new composition for a spotting fluid and a method of using such spotting fluid for freeing differential stuck pipe in a subterranean well drilling operation is disclosed. The composition comprises an invert water-in-oil emulsion comprising iso-butyl oleate as its external phase and glycerin as the internal phase. In an alternative embodiment, calcium chloride and water may be substituted for glycerin.

Abstract: The method for releasing the stuck pipe of the present invention uses a combination of components which oxidize the mud cake and generated gas bubbles to create an upward buoyancy for the oxidized mud cake. The spotting method of the present invention comprises adding to the borehole in the region of the stuck pipe: 1) an oxidizer which oxidizes the mud cake; and 2) at least one component which reacts in the borehole to generate a gas. Optionally, but preferably, the spotting method further uses a lubricant which is added to the borehole in the region of the stuck pipe. The lubricant acts to lubricate the oxidized parts of the mud cake. Also disclosed is a spotting fluid system including 1) an oxidizer which oxidizes the mud cake, 2) at least one component which reacts in the borehole to generate a gas, and, optionally a lubricant which acts to lubricate the oxidized parts of the mud cake.

Abstract: Aphron-containing spotting fluids and their use in releasing pipe or tools stuck in the filter cake on the sides of a borehole are disclosed. The spotting fluids comprise a liquid, either aqueous, oleaginous, or mixtures thereof, a viscosifier which imparts a low shear rate viscosity to the fluids of at least 10,000 centipoise, an aphron-generating surfactant, and aphrons. The spotting fluids are used in a conventional method of releasing pipes or tools stuck in the filter cake on the sides of a borehole during conventional drilling or well servicing operations.

Abstract: The present invention relates to a method and a solution for use in downhole drilling to reduce the torque necessary to rotate the drill string. The solution comprises a phosphate and a sulfonate according to the formula (RSO.sub.3).sub.x Me.sup.x, where R is selected from the group consisting of an alkyl group, an aryl group, an alkylaryl group, and mixtures thereof having a molecular weight between about 280 and about 650, x is the number of (RSO.sub.3) groups, and Me.sup.x is a metal ion having a valence x. The phosphate is preferably a phosphate ester, ether phosphate, or soluble phosphate having a molecular weight in the range of about 300 to bout 900. The phosphate is able to operate at temperatures prevailing in drilling mud systems. The solution is pumped down a drill string as a slug in order to coat solids which accumulate in the well and allow them to be removed along with the drilling fluid.

Abstract: An essentially non-polluting, substantially non-toxic drilling fluid composition has been discovered that is particularly useful as a lubricant or spotting fluid in drilling oil and gas wells. The fluid comprises silicone which may be is mixed with an emulsifier for application in the water base mud system.

Abstract: A composition and method for use in freeing differentially stuck pipes is presented, comprising a hydrocarbon, acetic acid and a surfactant. The composition frees stock pipes quickly, thus reducing down-time during the process of drilling a subterranean well.

Abstract: An additive for a water-based fluid which is to be used when the likelihood of differential sticking is high and which reduces the sticking tendency of the fluid and mud cake. An additive according to the invention comprises a well dispersed-particulate phase such as an emulsion, a fine emulsion, a microemulsion, a micellar phase or a polymeric phase having a particle size comparable with the pore throat size of a mud cake and comprising a material which forms easily deformable particles and which reduces the sticking propensity of the mud. One embodiment of the invention comprises a microemulsion of an oil which is well dispersed, substantially stable and has a substantial portion of the particle size distribution in the range 5-500 nm. An alternative embodiment comprises a micellar phase comprising one or more surfactants. The additive is typically used at a level of about 5% by volume in the drilling fluid.

Abstract: A method and combination of materials for freeing stuck pipe involves first the spotting of a clear brine, preferably calcium chloride, calcium bromide or zinc bromide, or mixtures thereof, for a given period of time, preferably at least about 8 hours, in the stuck region of the pipe, followed by the spotting of a spotting agent selected from wetting agents, surfactants, lubricants, or mixtures thereof, in the region of the stuck pipe.

Abstract: A method and combination of materials for freeing stuck pipe involves first the spotting of a clear brine, preferably calcium chloride, calcium bromide or zinc bromide, or mixtures thereof, for a given period of time, preferably at least about 8 hours, in the stuck region of the pipe, followed by the spotting of a spotting agent selected from wetting agents, surfactants, lubricants, or mixtures thereof, in the stuck region of the pipe.