With Phosphorus Compound Patents (Class 508/159)
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Patent number: 11760766Abstract: An ionic liquid composition having the following generic structural formula: wherein Z is N or P, and R1, R2, R3, and R4 are independently selected from hydrogen atom and hydrocarbon groups having one to four carbon atoms with optional interconnection to form a cyclic group that includes Z, and wherein R1, R2, R3, and R4 are all hydrocarbon groups when Z is P, and X? is a phosphorus-containing or carboxylate anion, particularly an organophosphate, organophosphonate, or organophosphinate anion, or a thio-substituted analog thereof containing hydrocarbon groups with at least three carbon atoms. Also described are lubricant compositions comprising the above ionic liquid and a base lubricant, wherein the ionic liquid is dissolved in the base lubricant. Further described are methods for applying the ionic liquid or lubricant composition onto a mechanical device for which lubrication is beneficial, with resulting improvement in friction reduction, wear rate, and/or corrosion inhibition.Type: GrantFiled: October 23, 2020Date of Patent: September 19, 2023Assignee: UT-Battelle, LLCInventors: Jun Qu, Huimin Luo, Xin He
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Patent number: 11591537Abstract: The invention relates to lubricating greases based on alkali metal soaps and/or earth-alkali metal soaps and metal complex soaps based on (R)-10-hydroxyoctadecanoic acid and to the use thereof.Type: GrantFiled: April 24, 2020Date of Patent: February 28, 2023Assignee: FUCHS PETROLUB SEInventors: Thomas Litters, Florian Hahn, Rolf Luther, Markus Urban, Angela Robben
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Patent number: 10214703Abstract: A lubricating oil composition and method of for providing an acceptable number of low-speed pre-ignition events in a boosted internal combustion engine using the lubricating oil composition. The lubricating oil composition includes greater than 50 wt. % of a base oil of lubricating viscosity, and an additive composition that includes an overbased calcium-containing detergent having a TBN greater than 225 mg KOH/g, and one or more zinc dialkyl dithiophosphate compounds are derived from a molar ratio of secondary alcohol to primary alcohol of 20:100 to about 100:0 and have an average total carbon content of greater than 10 carbon atoms per mole of phosphorous. The lubricating oil compositions contains the overbased calcium-containing detergent in an amount to provide greater than 900 ppm to less than 2400 ppm by weight calcium, and at least 0.01 wt. % of the zinc dialkyl dithiophosphate, both amounts based on the total weight of the lubricating oil composition.Type: GrantFiled: May 5, 2016Date of Patent: February 26, 2019Assignee: AFTON CHEMICAL CORPORATIONInventors: Kristin Fletcher, William Y. Lam, Kongsheng Yang, Jeremy Styer
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Publication number: 20130123154Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.Type: ApplicationFiled: December 18, 2012Publication date: May 16, 2013Applicant: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Publication number: 20120329687Abstract: An extreme pressure additive for a lubricant may include one or more phosphorous containing compounds and one or more boron containing compounds. The ratio of weight of phosphorous to boron in the extreme pressure additive may vary between about 1 to about 30.Type: ApplicationFiled: June 23, 2011Publication date: December 27, 2012Inventors: NATHAN SHISSLER, Dean Athans, Doug Hunsicker, Jeff St. Aubin
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Publication number: 20110152141Abstract: A lubricating composition with improved storage stability comprising a major amount of an oil of lubricating viscosity, at least one alkali metal borate, at least one polysulfide mixture having at least 40% dihydrocarbyl tetrasulfide or higher sulfides, and at least one non-acidic phosphorus compound comprised of a trihydrocarbyl phosphate and a dihydrocarbyl dithiophosphate derivative is disclosed. In addition to improved storage stability, the composition has improved wear performance when the ratio of polysulfides is controlled.Type: ApplicationFiled: March 1, 2011Publication date: June 23, 2011Inventors: John A. Zakarian, Michael J. Haire
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Publication number: 20110086787Abstract: A lubricating oil composition having superior storage stability and load-carrying effect is disclosed. The composition comprises four components: (1) an alkali metal borate; (2) an oil-soluble sulfur compound; (3) a trialkyl hydrogen phosphite; and (4) a mixture of greater than 50% neutralized acidic phosphates that are essentially free of monothiophosphates.Type: ApplicationFiled: December 17, 2010Publication date: April 14, 2011Inventors: John A. Zakarian, Michael J. Haire
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Patent number: 7919440Abstract: A lubricating composition with improved storage stability comprising a major amount of an oil of lubricating viscosity, at least one alkali metal borate, at least one polysulfide mixture having at least 40% dihydrocarbyl tetrasulfide or higher sulfides, and at least one non-acidic phosphorus compound comprised of a trihydrocarbyl phosphate and a dihydrocarbyl dithiophosphate derivative is disclosed. In addition to improved storage stability, the composition has improved wear performance when the ratio of polysulfides is controlled.Type: GrantFiled: May 4, 2005Date of Patent: April 5, 2011Assignee: Chevron U.S.A. Inc.Inventors: John A. Zakarian, Michael J. Haire
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Patent number: 7879773Abstract: A lubricating oil composition having superior storage stability and load-carrying effect is disclosed. The composition comprises four components: (1) an alkali metal borate; (2) an oil-soluble sulfur compound; (3) a trialkyl hydrogen phosphite; and (4) a mixture of greater than 50% neutralized acidic phosphates that are essentially free of monothiophosphates.Type: GrantFiled: May 4, 2005Date of Patent: February 1, 2011Assignee: Chevron U.S.A., Inc.Inventors: John A. Zakarian, Michael J. Haire
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Patent number: 7786058Abstract: A rolling device employing a lubricating grease composition containing a thickener which is a mixture of (a) one or more diurea compounds made from one or more primary amines and a diisocyanate; (b) at least one fatty acid metal salt; (c) at least one amide compound selected from the group consisting of aliphatic amides and bisamides, where the proportions of (a), (b) and (c) satisfy the relationship: a/(b+c)=0.2?10 provided that (1) the proportion of ingredient (a) is 1-10, (2) the proportion of ingredient (b) is 0.5-2.5, and (3) the proportion of ingredient (c) is 0.5-2.5, and the amount of the thickener is 2 to 30% by weight, based on the lubricating grease composition; (d) a base oil which is a lube base oil having a pour point of ?36 to ?67.7° C. that includes a synthetic hydrocarbon oil as the main component; and (e) 1-7% by weight of an additive mixture containing an organomolybdenum complex, an organozinc compound of a dithiocarbamic acid, and an organozinc compound of dithiophosphoric acid.Type: GrantFiled: April 27, 2006Date of Patent: August 31, 2010Assignee: JTEKT CorporationInventors: Hirofumi Kuwabara, Shigeyuki Sugimori, Toshihiro Asakura
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Publication number: 20100173808Abstract: Disclosed is a lubricant composition comprising a) a lubricant, b) a triazole metal deactivator, c) a borate ester and optionally d) an amine phosphate. The lubricants, e.g. engine oils or functional fluids exhibit low corrosion of lead, copper, iron and zinc. The metal deactivators are 1,2,4-triazoles, for example 1-(di-isooctylaminomethyl)-1,2,4-triazole or 1-(di-(2-ethylhexyl)aminomethyl)-1,2,4-triazole, or are benzotriazoles, for example 1-(2-methoxyprop-2-yl)tolyltriazole, 1-(1-cyclohexyloxypropyl)tolyltriazole, 1-(1-cyclohexyloxyheptyl)tolyltriazole or 1-(1-cyclohexyloxybutyl)tolyltriazole or 1-[bis(2-ethylhexyl)aminomethyl-4-methylbenzotriazole. The borate esters are for example triethyl borate, tripropyl borate, triisopropyle borate, tributyl borate, tripentyl borate, trihexyl borate, tricyclohexyl borate, trioctyl borate, triisooctyl borate, tridecyl borate, tri(C8C10) borate, tri (C12-C15) borate or oleyl borate.Type: ApplicationFiled: March 15, 2010Publication date: July 8, 2010Inventors: David E. Chasan, Marc Ribeaud
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Patent number: 7479177Abstract: The invention involves a composition for forming a combined conversion and lubricating coating on a metal substrate with which the composition is brought into contact. The composition comprises (a) an oxyethylated aliphatic alcohol whose aliphatic hydrocarbon moiety contains 18 or more carbon atoms and (b) dissolved phosphate anions. Preferably the composition also comprises inorganic boron, an alkali metal salt of a fatty acid, and an accelerator for phosphate coating.Type: GrantFiled: February 27, 2004Date of Patent: January 20, 2009Assignee: Henkel AG & Co. KGaAInventor: Richard J. Church
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Patent number: 7122508Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.Type: GrantFiled: October 31, 2002Date of Patent: October 17, 2006Assignee: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Patent number: 7026273Abstract: A crankcase lubricating oil composition comprises an oil of lubricating viscosity, in a major amount, and, in respective minor amounts, a boron-containing additive and one or more co-additives, wherein the lubricating oil composition has greater than 200 ppm by mass of boron, less than 600 ppm by mass of phosphorus and less than 4000 ppm by mass of sulfur, based on the mass of the oil composition. Such compositions demonstrate provide improved wear performance.Type: GrantFiled: October 22, 2002Date of Patent: April 11, 2006Assignee: Infineum International LimitedInventors: Robert Robson, Roger W. Glyde, Alisdair J. Brown, Simon S. M. Chung, Stephen Arrowsmith
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Patent number: 6734147Abstract: A process is disclosed for manufacturing a lubricant composition comprising combining a superabsorbent polymer with a material for decreasing friction between moving surfaces. The superabsorbent polymer absorbs from about 25 to greater than 100 times its weight in water and may comprise a polymer of acrylic acid, an acrylic ester, acrylonitrile or acrylamide, including co-polymers thereof or starch graft co-polymers thereof or mixtures thereof. A product produced by the process includes the material for decreasing friction comprising a petroleum lubricant containing an additive, water containing an additive, synthetic lubricant, grease, solid lubricant or metal working lubricant, wherein the synthetic lubricant, grease, solid lubricant or metal working lubricant optionally contain an additive. A process comprising controlling the delivery of a lubricant to at least one of two moving surfaces in order to decrease friction between said moving surfaces, is also disclosed.Type: GrantFiled: October 3, 1997Date of Patent: May 11, 2004Assignee: LCC County Mosquito ControlInventor: Richard Levy
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Publication number: 20040002428Abstract: Disclosed is a method for reducing wear and metal fatigue during high temperature operation of a gear set, which method comprises operating the gear set with a dispersed hydrated sodium borate composition.Type: ApplicationFiled: June 28, 2002Publication date: January 1, 2004Inventors: James J. Harrison, Kenneth D. Nelson, Juan A. Buitrago
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Publication number: 20030162671Abstract: This invention relates to novel water soluble metal working fluid compositions, their use to work metal, a process for working metal using such compositions and the metal worked article of manufacture. More particularly, this invention relates to fluid compositions useful in cutting, grinding, shaping and other metal working operations which require a lubricant. The terms “first Group A” and “second Group B” are used herein to denote different groups and not to indicate any sequence of use or selection as any possible combination or sequence of use of a component(s) is envisioned without limit of any kind. The disclosed fluid compositions are also anticorrosive and environmentally more acceptable than current oil based fluids.Type: ApplicationFiled: February 24, 1999Publication date: August 28, 2003Inventors: DENNIS J. KALOTA, YUETING CHOU, TIMOTHY K. HIRZEL, DAVID C. SILVERMAN, JACOB S. TOU, WINSOR R. CHO
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Publication number: 20030148895Abstract: A crankcase lubricating oil composition comprises an oil of lubricating viscosity, in a major amount, and, in respective minor amounts, a boron-containing additive and one or more co-additives, wherein the lubricating oil composition has greater than 200 ppm by mass of boron, less than 600 ppm by mass of phosphorus and less than 4000 ppm by mass of sulfur, based on the mass of the oil composition. Such compositions demonstrate provide improved wear performance.Type: ApplicationFiled: October 22, 2002Publication date: August 7, 2003Inventors: Robert Robson, Roger W. Glyde, Alisdair J. Brown, Simon S. M. Chung, Stephen Arrowsmith
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Publication number: 20020019320Abstract: A lubricating oil composition having a low P content of 0.01 to 0.1 wt. %, and a sulfated ash of 0.1 to 1 wt. %, which is composed of a) a major amount of mineral base oil having a low S content of at most 0.1 wt. %; b) an ashless alkenyl or alkyl-succinimide dispersant; c) a metal-containing detergent (non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid and/or non-sulfurized alkali metal or alkaline earth metal salt of an alkylphenol derivative having a Mannich base structure); d) Zn-DTP; e) an oxidation inhibitor (phenol compound and/or amine compound) and wherein the sulfur content is 0.01 to 0.3 wt %. The lubricating oil composition shows good high temperature detergency notwithstanding its low S, P, and sulfated ash content, and is favorably employable in diesel engines using fuel of an extremely low sulfur content.Type: ApplicationFiled: May 30, 2001Publication date: February 14, 2002Inventors: Morikuni Nakazato, Shigeru Iwamoto, Satoshi Hirano
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Patent number: 5801128Abstract: A dry Non-Oil metalworking lubricant that can be applied by a hot melt application. This dry lubricant is completely water soluble, provides rust protection, cleans from surfaces with plain room temperature water, and is more environmentally safe than other lubricants. A polyethylene glycol of sufficiently high molecular weight to be solid at room temperature is combined with amines, rust inhibitors, and metalworking additives to produce a thin film that provides protection for the part and the tooling in a metalworking operation. This lubricant provides further benefits to the overall process such as; easy to clean, weld through capability, excellent paint system compatibility, and environmentally superior to other lubricants.Type: GrantFiled: October 23, 1995Date of Patent: September 1, 1998Assignee: International Refining and Manufacturing CompanyInventors: Thomas S. Overstreet, Arthur E. Dampts
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Patent number: 5710112Abstract: A lubricant composition comprising from 0.1 to 10% by weight of a phosphate glass, characterized in that said phosphate glass comprises from 45 to 75 mole % of P.sub.2 O.sub.5, from 10 to 35 mole % of M.sub.2 O (M represents alkaline metals) and from 0 to 45 mole % of B.sub.2 O.sub.3. Phosphate glasses are in the form of powder with white to ash-colored appearance, and do not cause dirt of working surroundings. Phosphate glasses are less expensive than solid lubricants which are conventionally used, and also excellent load carrying capacity can be attained by adding a small amount of phosphate glass to a lubricant composition. Accordingly, the lubricant composition of the present invention shows better load carrying capacity than a conventional lubricant composition.Type: GrantFiled: September 22, 1995Date of Patent: January 20, 1998Assignee: Kyodo Yushi Co., Ltd.Inventors: Ko Yaegashi, Yoshiaki Oikawa, Hiroshi Kamiyashiki, Hiroshi Kimura
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Patent number: 5620948Abstract: This invention relates to a composition, comprising: (A) a Mannich dispersant having a base number in the range of about 45 to about 90; (B) a boron compound; and (C) an organic phosphorus acid or ester, or derivative of said phosphorus acid or ester. In one embodiment, this composition further comprises (D) a thiocarbamate. In one embodiment, this composition further comprises (E) a nitrogen-containing ester of a carboxy-containing interpolymer. These compositions are useful as additives for lubricants and functional fluids, and are particularly useful as additives for automatic transmission fluids for enhancing the torque characteristics such automatic transmission fluids.Type: GrantFiled: June 20, 1996Date of Patent: April 15, 1997Assignee: The Lubrizol CorporationInventor: Craig D. Tipton
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Patent number: 5576272Abstract: A grease composition for construction equipment comprises a lubricating grease, a) 1 to 5% by weight of phosphate glass and b) 1 to 5% by weight of a sulfur-phosphorus extreme-pressure additive; as well as c) 0.5 to 3% by weight of an aromatic sulfonic acid salt and d) 0.1 to 3% by weight of a triazole compound as optional components based on the total weight of the grease composition. The grease composition exhibits considerably high resistance to load and accordingly, can be applied to construction equipment which require high resistance to load, such as a hydrauric excavator and a wheel loader.Type: GrantFiled: March 19, 1996Date of Patent: November 19, 1996Assignees: Komatsu Ltd., Kyodo Yushi Co., Ltd.Inventors: Satoshi Okawa, Akimi Kimura, Hiroshi Kimura
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Patent number: 5534172Abstract: An aqueous-based cutting fluid for machining photoreceptor substrates contains:(A) at least one antioxidant;(B) one or more surfactants, at least one of which is a polysiloxane surfactant;(C) at least one lubricant; and(D) water.The cutting fluid can also optionally contain one or more biocides. The cutting fluid is environmentally safe, non-toxic and biodegradable and can be removed in a postmachining cleaning process using only high quality distilled water.Type: GrantFiled: March 14, 1995Date of Patent: July 9, 1996Assignee: Xerox CorporationInventors: Phillip G. Perry, Gene W. O'Dell, Ronny W. F. van Asten
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Patent number: RE44475Abstract: A lubricating composition with improved storage stability comprising a major amount of an oil of lubricating viscosity, at least one alkali metal borate, at least one polysulfide mixture having at least 40% dihydrocarbyl tetrasulfide or higher sulfides, and at least one non-acidic phosphorus compound comprised of a trihydrocarbyl phosphate and a dihydrocarbyl dithiophosphate derivative is disclosed. In addition to improved storage stability, the composition has improved wear performance when the ratio of polysulfides is controlled.Type: GrantFiled: February 24, 2012Date of Patent: September 3, 2013Assignee: Chevron U.S.A. Inc.Inventors: John A. Zakarian, Michael J. Haire