Abstract: A lubricating composition comprises an amide and at least one additive. The amide is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant composition.
Abstract: Antidegradant compounds are disclosed, and methods of making them, that are represented by the formula I: wherein each X is independently selected from the group consisting of ethyl, methyl, or hydrogen. Also disclosed are diimine intermediates corresponding to formula III: wherein each X is independently selected from the group consisting of ethyl, methyl, or hydrogen. These intermediates themselves exhibit antidegradant activity.
Type:
Grant
Filed:
June 9, 2017
Date of Patent:
January 1, 2019
Assignee:
Eastman Chemical Company
Inventors:
Matthew Allen Boone, Donald L. Fields, Jr., Frederick Ignatz-Hoover
Abstract: A method of making antidegradant compounds is disclosed, in which a p-phenylenediamine is reacted with an alpha-hydroxy carbonyl compound to thereby obtain an enediamine, which is reduced to thereby obtain a mixture comprising the antidegradant compound.
Type:
Grant
Filed:
June 9, 2017
Date of Patent:
December 25, 2018
Assignee:
Eastman Chemical Company
Inventors:
Matthew Allen Boone, Donald L. Fields, Jr., Frederick Ignatz-Hoover
Abstract: Methods of making antidegradant compounds are disclosed in which a p-phenylenediamine is reacted with a diol to obtain mixtures comprising the antidegradant compounds.
Type:
Grant
Filed:
June 9, 2017
Date of Patent:
December 25, 2018
Assignee:
Eastman Chemical Company
Inventors:
Matthew Allen Boone, Donald L. Fields, Jr., Frederick Ignatz-Hoover
Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition that contains (i) a lubricating oil base stock comprising at least one ester including at least one group selected from the group consisting of Formula (1), Formula (2), and Formula (3): The lubricating oils of this disclosure are useful as passenger vehicle engine oil (PVEO) products.
Type:
Grant
Filed:
June 30, 2016
Date of Patent:
November 6, 2018
Assignee:
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
Inventors:
Jason Z. Gao, Eugine Choi, Matthew W. Boland, Luca Salvi
Abstract: A lubricant composition useful for automotive engines, comprising: (A) at least one polyalkylene glycol suitable for use as a lubricant in an automotive engine, (B) an additive package which comprises an acid scavenger, wherein the acid scavenger is an aspartic acid ester, aspartic acid amide, a Group V aspartic acid salt, or a combination thereof.
Abstract: This invention relates to a low cost, wear inhibitor containing novel dithiocarbamates with alkylthio and hydroxy substituents that can be used to formulate low phosphorus lubricants. In addition to wear inhibition, the dithiocarbamate compositions of the invention provide substantial oxidation protection to lubricating oils and are not detrimental to fuel economy.
Abstract: The present invention describes an improved lubricant composition comprising a particularly effective combination of components comprising ashless antiwear and rust inhibitor additives with an antioxidant liquid mixture formed by reacting an olefin with a mixture of diphenylamines and phenothiozines.
Type:
Application
Filed:
March 17, 2004
Publication date:
September 30, 2004
Applicant:
ExxonMobil Research and Engineering Company
Inventors:
Walter D. Vann, Liehpao Oscar Farng, Angela S. Galiano-Roth, Marcia G. Rogers, Paul Dubs, Miles J. Hutchings
Abstract: The invention relates to a lubricating oil composition having improved antioxidant properties, and which contains a molybdenum compound and an alkylated phenothiazine. Further, it may also include a secondary diarylamine, preferably an alkylated diphenylamine. This combination of additives provides improved oxidation control and friction modifier performance to the lubricating oil. The composition is particularly suited for use as a crankcase lubricant, or a transmission lubricant, including low levels and zero levels of phosphorus.
Abstract: The invention relates to a lubricating oil composition having improved antioxidant properties, and which contains a molybdenum compound and an alkylated phenothiazine. Further, it may also include a secondary diarylamine, preferably an alkylated diphenylamine. This combination of additives provides improved oxidation control and friction modifier performance to the lubricating oil. The composition is particularly suited for use as a crankcase lubricant, or a transmission lubricant, including low levels and zero levels of phosphorus.
Abstract: It has unexpectedly been found that the combination of (1) an alkylated diphenylamine, (2) a sulfurized olefin/fatty oil and/or an ashless dialkyldithiocarbamate, and (3) an alkylated phenothiazine, is highly effective at controlling crankcase lubricant oxidation and deposit formation. The present invention includes lubricating compositions, lubricating additives, and methods for improving the antioxidancy and/or deposit formation properties of a lubricating composition.
Type:
Grant
Filed:
July 12, 2002
Date of Patent:
July 29, 2003
Assignee:
Ethyl Corporation
Inventors:
Carl K. Esche, Jr., Vincent J. Gatto, William Y. Lam
Abstract: This invention relates to a low cost, wear inhibitor containing novel dithiocarbamates with alkylthio and hydroxy substituents that can be used to formulate low phosphorus lubricants. In addition to wear inhibition, the dithiocarbamate compositions of the invention provide substantial oxidation protection to lubricating oils and are not detrimental to fuel economy.
Abstract: Crankcase lubricant compositions for use in automobile or truck engines comprise a major proportion of a lubricating oil, and an antioxidant system comprising added copper present in oil-soluble form and at least one oil-soluble phenothiazine.
Abstract: The oxidation stability of polyol ester based lithium soap thickened greases is improved by use of a synergistic antioxidant combination comprising a mixture of (alkylated) diphenyl amine and phenothiazine.