The Phosphorus Is Bonded Indirectly To An Additional Diverse Metal Or To Carbonyl (e.g., Molybdenum-zinc Dialkyldithiophosphates, Etc.) Patents (Class 508/369)
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Patent number: 9725669Abstract: Anti-wear and/or friction reducing formulations that include a mixture of at least one first ionic liquid and at least one ashless antiwear compound. The ashless antiwear compound can be a second ionic liquid or an ashless thiophosphate compound. The formulation desirably provides synergistic anti-wear and/or friction reducing properties. The first IL can be a monocationic ionic liquid or a dicationic ionic liquid. The second IL is a dicationic ionic liquid. The ashless thiophosphate is desirably a thiophosphate, such as a fluorothiophosphate (FTP), an alkylphosphorofluoridothiolate, or an alkylthioperoxydithiophosphate. Antiwear and/or friction reduction formulations comprising the above mixtures diluted up to 25% by weight in a base oil.Type: GrantFiled: May 7, 2013Date of Patent: August 8, 2017Assignee: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEMInventors: Pranesh Aswath, Xin Chen, Vibhu Sharma, Maria Amaya Igartua, Francesco Pagano, Wolfgang Binder, Parvin Zare, Nicole Doerr
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Patent number: 9309478Abstract: The invention relates to a lubricating composition comprising (a) at least 0.05 wt % of a non-aromatic metal carboxylate, wherein the metal carboxylate is derived from a branched carboxylic acid, and (b) an oil of lubricating viscosity. The invention further provides for the use of the lubricating composition for lubricating a limited slip differential.Type: GrantFiled: October 21, 2009Date of Patent: April 12, 2016Assignee: The Lubrizol CorporationInventors: Stuart L. Bartley, Mark R. Baker
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Patent number: 8969267Abstract: Suggested is a method for enhancing energy efficiency of engines by applying to said engines a lubricant composition containing (A) carboxylic esters derived from the reaction of mono-, di- and/or poly alcohols with mono- and/or dicarboxylic acids, together with an additive blend (B) comprising at least two different additives (a) and (b) together, whereby compound (a) is selected from dithiophosphates, and compound (b) is selected from alkylated phosphorothionates, on condition that the total amount of the additive blend (B) is below 0.1 wt %, calculated on the weight of the whole composition.Type: GrantFiled: September 15, 2010Date of Patent: March 3, 2015Assignee: Cognis IP Management GmbHInventors: Ronny Rinklieb, Dirk Rettemeyer, Markus Scherer
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Patent number: 8901049Abstract: The purpose of the present invention is to provide: a sliding member having a lubricating film formed on the sliding surface thereof, and capable of exhibiting friction-reducing performance; and a friction reduction method for the same. To that end, the present invention entails coating the sliding surface with a titanium nitride-based material (for example, titanium carbon nitride, titanium nitride, or titanium aluminum nitride), adding a molybdenum dithiocarbamate with molybdenum in the amount of 600-1000 ppm to diesel engine oil, setting the arithmetic mean roughness of the sliding member to 2-10 nm, and upon converting the Sommerfeld number viscosity to Pa·s, the speed to s?1, and the load to mean Hertzian stress (Pa), then the lubrication conditions for use are within the range of 2.12365×10?19 to 5.94509×10?19.Type: GrantFiled: October 21, 2011Date of Patent: December 2, 2014Assignees: UD Trucks Corporation, Adeka CorporationInventors: Keisuke Yari, Sachiyo Ono, Masaru Iijima, Noriyoshi Tanaka, Kenji Yamamoto, Akihiro Kotaka
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Patent number: 8883696Abstract: The purpose of the present invention is to provide: a sliding mechanism having a lubricating film formed on the sliding surface thereof, and capable of exhibiting friction-reducing performance; and a friction reduction method for the same. To that end, the present invention entails coating the sliding surface with chromium nitride, adding a molybdenum dithiocarbamate with molybdenum in the amount of 600-1000 ppm to diesel engine oil, setting the arithmetic mean roughness of the sliding member to 2-60 nm, and upon converting the Sommerfeld number viscosity to Pa·s, the speed to s?1, and the load to mean Hertzian stress (Pa), then the lubrication conditions for use are within the range of 2.12365×10?20 to 5.94509×10?19.Type: GrantFiled: October 21, 2011Date of Patent: November 11, 2014Assignees: UD Trucks Corporation, Adeka CorporationInventors: Keisuke Yari, Sachiyo Ono, Masaru Iijima, Noriyoshi Tanaka, Kenji Yamamoto, Akihiro Kotaka
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Patent number: 8802604Abstract: The present invention provides a lubricating oil composition in contact with a silver-containing material, which comprises: a lubricant base oil made of a mineral base oil and/or a synthetic base oil; (A) metallic detergent; (B) one or more species of alkenyl succinimide and/or boron-containing alkenyl succinimide; and (C) zinc dialkyl dithiophosphate, wherein the content of these components to the total mass of the lubricating oil composition are defined as, (A) component: 0.12-2.0 mass % as metal content; (B) component: 0-0.03 mass % as boron content, 0.005 mass % to less than 0.08 mass % as nitrogen content, and the mass ratio (B/N) between the boron content (B) and the nitrogen content (N) is 0-0.55; and (C) component: 0.005-0.10 mass % as phosphorous content. As a lubricating oil in contact with silver-containing material, the lubricating oil composition can inhibit sulfidation corrosion of silver while containing zinc dialkyl dithiophosphate.Type: GrantFiled: August 20, 2009Date of Patent: August 12, 2014Assignee: JX Nippon Oil & Energy CorporationInventor: Kazuhiro Yagishita
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Patent number: 8784642Abstract: A lubricating oil composition of SAE viscosity grade 0W20 which comprises a base oil and additive components comprising a nitrogen-containing ashless dispersant, an alkaline earth metal-containing detergent, a phosphorus-containing wear inhibitor, an oxidation inhibitor and a viscosity index improver and which shows a viscosity index of 200-240, a HTHS viscosity of not less than 2.9 mPa·s s at 150° C. and a Noack evaporation loss of not more than 13% favorably gives a high fuel economy and high wear inhibition to a four cycle gasoline engine of motorcycles and a diesel engine mounted on motor cars equipped with an exhaust gas post-processing apparatus.Type: GrantFiled: November 11, 2011Date of Patent: July 22, 2014Assignee: Chevron Japan Ltd.Inventors: Hiroki Andoh, Morikuni Nakazato
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Patent number: 8778853Abstract: A functional fluid comprising a major amount of an oil of lubricating viscosity, and at least about 0.05 wt-% glycerol. A method of preparing a functional fluid comprising adding glycerol to a functional fluid, wherein the glycerol is not glycerol monooleate. A method of preparing an additive concentrate comprising adding glycerol to a diluent oil wherein the concentrate contains from about 1% to about 99% by weight of said diluent. A method of reducing wear comprising contacting a metal surface with a functional fluid comprising a major amount of an oil of lubricating viscosity and at least about 0.05 wt-% glycerol.Type: GrantFiled: November 11, 2011Date of Patent: July 15, 2014Assignee: Chevron Oronite Company LLC.Inventor: Yue-Rong Li
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Patent number: 8747650Abstract: Provided are formulations, methods of making, and methods of using one or more Fischer-Tropsch Base Oils of the present invention in a low sulfur, low sulfated ash, and low phosphorus engine lubricant to enhance thermal stability of the lubricant as well as the high-temperature performance of an engine housing the lubricant.Type: GrantFiled: December 21, 2006Date of Patent: June 10, 2014Assignee: Chevron Oronite Technology B.V.Inventors: Jeroen Van Leeuwen, Peter Kleijwegt
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Patent number: 8722597Abstract: Provided is a lubricating oil composition for an internal combustion engine, including as essential components the following component (A), component (B), and component (C), in which a phosphorus content of the composition is 50 ppm by mass to 1,000 ppm by mass: Component (A): a base oil; Component (B): a compound represented by the following general formula (1); and Component (C): a metal-containing antioxidant: where R1 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, Z represents a hydrocarbon group having 2 to 20 carbon atoms, and n represents a number of 1 to 10.Type: GrantFiled: May 18, 2011Date of Patent: May 13, 2014Assignee: Adeka CorporationInventors: Yukio Tatsumi, Kenji Yamamoto
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Patent number: 8703679Abstract: A functional fluid comprising a major amount of an oil of lubricating viscosity, and an oil soluble amount of glycerol carbonate or an oil soluble amount of a borated glycerol.Type: GrantFiled: November 15, 2011Date of Patent: April 22, 2014Inventors: Yue-Rong Li, Frank Plavac, Rawls Frazier
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Patent number: 8518864Abstract: A grease composition for constant-velocity joints which is inexpensive and which and which has an improved anti-flaking property without using materials which have environmental burdens, and a constant-velocity joint enclosing this grease are provided. A grease composition for constant-velocity joints comprising: (a) a base oil, (b) a diurea thickener, (c) a zinc dialkyldithiophosphate, (d) a sulfurized molybdenum dialkyldithiocarbamate, (e) a zinc dialkyldithiocarbamate, and (f) a sulfur-nitrogen extreme pressure additive is provided.Type: GrantFiled: May 30, 2008Date of Patent: August 27, 2013Assignees: Kyodo Yushi Co., Ltd., NTN CorporationInventors: Daigo Nagumo, Yuji Onuki, Shinya Kondo, Shin Tomogami, Shinichi Takabe
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Publication number: 20130040867Abstract: A trunk piston engine lubricating oil composition is disclosed comprising (a) a major amount of a base stock containing at least 90% by weight saturated hydrocarbons; and (b) a base stock selected from the group consisting of (i) an ester base stock wherein the ester base stock is present in an amount greater than 10% by weight and no greater than about 45% by weight, based on the total weight of the lubricating oil composition, and (ii) an alkylated aromatic base stock.Type: ApplicationFiled: October 15, 2012Publication date: February 14, 2013Applicant: Chevron Oronite Technology B.V.Inventor: Wilhelmus Petrus Antonie Van Houten
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Publication number: 20130012418Abstract: Provided is a lubricating oil composition for an internal combustion engine, including as essential components the following component (A), component (B), and component (C), in which a phosphorus content of the composition is 50 ppm by mass to 1,000 ppm by mass: Component (A): a base oil; Component (B): a compound represented by the following general formula (1); and Component (C): a metal-containing antioxidant: where R1 to R8 each independently represent a hydrogen atom or an alkyl group having 1 to 20 carbon atoms, Z represents a hydrocarbon group having 2 to 20 carbon atoms, and n represents a number of 1 to 10.Type: ApplicationFiled: May 18, 2011Publication date: January 10, 2013Inventors: Yukio Tatsumi, Kenji Yamamoto
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Publication number: 20130005622Abstract: An engine oil lubricant composition comprising a major amount of base oil and an effective amount of a zinc dialkyl dithio phosphate, a polymeric viscosity index improver and a mixture of alkaline earth metal detergents provides improved fuel efficiency while providing excellent wear in an engine.Type: ApplicationFiled: June 26, 2012Publication date: January 3, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Kristen A. Lyon, Kevin John Kelly, William L. Maxwell, Douglas Edward Deckman
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Patent number: 8334244Abstract: A universal synthetic water displacement multi-purpose penetrating lubricant with the capacity to protect metal surfaces against corrosion, with galvanic and electrolysis protection, while providing excellent lubrication properties. The lubricant actively penetrates the crystalline surface of the metal while exhibiting extreme pressure lubrication, non-migrating with lasting protection. The lubricant exhibits dielectric strength of over 14,000 volts, at the same time cleaning electrical contacts while reducing resistance and associated heat. A preferred embodiment comprises polymerized alpha-olefins, K-1 kerosene, and at least one base oil selected from the base oil group consisting of Hydroisomerized high base oils and HT severe hydro-cracked base oils. Various combinations of other optional ingredients are also disclosed.Type: GrantFiled: September 22, 2010Date of Patent: December 18, 2012Assignee: Bestline International Research, Inc.Inventor: Ronald J. Sloan
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Patent number: 8278253Abstract: The resistance to oxidation of a lubricating oil is enhanced by the addition to the lubricating oil of an additive amount of an ionic liquid.Type: GrantFiled: February 5, 2010Date of Patent: October 2, 2012Assignee: ExxonMobil Research and Engineering CompanyInventor: Jacob Joseph Habeeb
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Publication number: 20120165234Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.Type: ApplicationFiled: March 1, 2012Publication date: June 28, 2012Applicant: The Lubrizol CorporationInventors: Jody Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman, Patrick E. Mosier
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Publication number: 20120165235Abstract: A functional fluid comprising a major amount of an oil of lubricating viscosity, and greater than about 0.05 wt-% glycerol. A method of preparing a functional fluid comprising adding glycerol to a functional fluid, wherein the glycerol is not glycerol monooleate. A method of preparing an additive concentrate comprising adding glycerol to a diluent oil wherein the concentrate contains from about 1% to about 99% by weight of said diluent. A method of reducing friction comprising contacting a metal surface with a functional fluid comprising a major amount of an oil of lubricating viscosity and greater than about 0.05 wt-% glycerol.Type: ApplicationFiled: December 16, 2011Publication date: June 28, 2012Applicant: Chevron Oronite Company LLCInventors: Yue-Rong Li, Deane S. Walker, Patrick J. McDougall, Kenneth Nelson
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Patent number: 8207099Abstract: A crankcase lubricant, an additive concentrate and a method for improving water tolerance of a lubricant. The lubricant includes a) a major amount of a base oil; b) an alkali or alkaline earth metal-containing detergent; c) a phosphorus-based wear preventative; and d) a surfactant agent other than (b). The lubricant has a weight ratio of alkali or alkaline earth metal content to phosphorus content, based on a total mass of lubricant, ranging from about 1.6 to about 5.0.Type: GrantFiled: September 22, 2009Date of Patent: June 26, 2012Assignee: Afton Chemical CorporationInventor: John T. Loper
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Publication number: 20120132166Abstract: A lubricating oil composition of SAE viscosity grade 0W20 which comprises a base oil and additive components comprising a nitrogen-containing ashless dispersant, an alkaline earth metal-containing detergent, a phosphorus-containing wear inhibitor, an oxidation inhibitor and a viscosity index improver and which shows a viscosity index of 200-240, a HTHS viscosity of not less than 2.9 mPa·s s at 150° C. and a Noack evaporation loss of not more than 13% favorably gives a high fuel economy and high wear inhibition to a four cycle gasoline engine of motorcycles and a diesel engine mounted on motor cars equipped with an exhaust gas post-processing apparatus.Type: ApplicationFiled: November 11, 2011Publication date: May 31, 2012Applicant: Chevron Japan Ltd.Inventors: Hiroki Andoh, Morikuni Nakazato
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Publication number: 20120118258Abstract: A lubricating oil composition having a low sulfated ash content, a low P content, a low S content and a low Cl content and being favorably employable for lubricating a diesel engine operated using a hydrocarbon fuel oil having a low S content, comprising the following components a) to d) dissolved or dispersed in a base oil having a low S content: a) an ashless dispersant such as alkenyl- or alkyl succinimide or its derivative, b) a calcium alkylsalicylate detergent having a low S content and an organic acid calcium salt, which is an unsulfurized calcium alkylsalicylate detergent having a C14-C18 alkyl group, c) a zinc phosphate anti-wear agent, and d) an oxidation inhibitor.Type: ApplicationFiled: September 7, 2011Publication date: May 17, 2012Applicant: Chevron Japan, Ltd.Inventors: Yoshitaka Takeuchi, Toshimi Kawamura
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Publication number: 20120118259Abstract: A lubricating oil composition having a low sulfated ash content, a low P content, a low S content and a low Cl content and being favorably employable for lubricating a diesel engine operated using a hydrocarbon fuel oil having a low S content, comprises the following components a) to d) dissolved or dispersed in a base oil having a low S content: a) an ashless dispersant such as alkenyl- or alkylsuccinimide or its derivative, b) a calcium alkylsalicylate detergent having a low S content and containing an organic acid calcium salt, which is a mixture of an unsulfurized calcium alkylsalicylate detergent having a C14-C18 alkyl group and an unsulfurized calcium alkylsalicylate detergent having a C20-C28 alkyl group, c) a zinc phosphate anti-wear agent, and d) an oxidation inhibitor.Type: ApplicationFiled: September 7, 2011Publication date: May 17, 2012Applicant: Chevron Japan, Ltd.Inventors: Yoshitaka Takeuchi, Toshimi Kawamura
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Patent number: 8101558Abstract: A composition containing an oil of lubricating viscosity in a concentrate-forming or major amount; and, as an additive component, an oil-soluble or oil dispersible mononuclear molybdenum compound having a molybdenum atom having bonded thereto one or more diazenide ligands and one or more hydrocarbyl group-carrying ligands, other than diazenide ligands, the hydrocarbyl groups conferring oil-solubility or oil-dispersibility on the molybdenum compound.Type: GrantFiled: December 1, 2009Date of Patent: January 24, 2012Assignee: Infineum International LimitedInventors: Benjamin R. Elvidge, Aleka Hinni, Jonathan Dilworth
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Patent number: 8088720Abstract: The present invention is directed to method of making a green lubricant composition having improved wear protection and reduced phosphorus emissions.Type: GrantFiled: February 6, 2009Date of Patent: January 3, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Jacob J. Habeeb, Douglas E. Deckman, Brandon T. Weldon, William L. Maxwell
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Patent number: 8084403Abstract: The embodiments described herein relate to particular formulations and methods that provide reduced engine deposits. The lubricant composition includes a base oil having a NOACK volatility of from about 5 to about 15 and a zinc dialkyl dithio phosphate composition. The zinc dialkyl dithio phosphate composition has at least about 65 mole percent of zinc dialkyl dithio phosphate compounds derived from all primary alcohols, wherein the zinc dialkyl dithio phosphate composition has greater than about 40 mole percent zinc dialkyl dithio phosphate compounds having alkoxy moieties derived from alcohols having four carbon atoms.Type: GrantFiled: May 1, 2009Date of Patent: December 27, 2011Assignee: Afton Chemical CorporationInventors: William Y. Lam, Gregory H. Guinther
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Patent number: 8080501Abstract: The present invention is directed to green lubricant compositions comprising a base oil and an effective amount of premixed additives that improve wear protection and reduce phosphorus emissions.Type: GrantFiled: February 6, 2009Date of Patent: December 20, 2011Assignee: Exxonmobil Research and Engineering CompanyInventors: Jacob J. Habeeb, Douglas E. Deckman, Brandon T. Weldon, Steven P. Rucker, Michael E. Landis
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Patent number: 8048834Abstract: A method and compositions for lubricating surfaces with lubricating oils exhibiting increased phosphorous retention. The lubricated surface includes a lubricant composition containing a base oil of lubricating viscosity, an amount of a phosphorus-containing compound and an amount of at least one hydrocarbon soluble titanium compound that is effective to provide an aged catalyst temperature that converts at least fifty percent of exhaust gas hydrocarbons, carbon monoxide, and NOx that is lower than an aged catalyst temperature that converts at least fifty percent of exhaust gas hydrocarbons, carbon monoxide, and NOx of the lubricant composition devoid of the hydrocarbon soluble titanium compound.Type: GrantFiled: September 17, 2007Date of Patent: November 1, 2011Assignee: Afton Chemical CorporationInventors: Gregory H. Guinther, John T. Loper
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Patent number: 7989406Abstract: An additive to a fuel oil for a Diesel engine having a Diesel particulate filter (DPF), which comprises a molybdenum compound and having the function of improving the combustion property of a particulate matter (PM) trapped with DPF; a fuel oil comprising the additive; a lubricating oil composition for a Diesel engine having DPF, which has a sulfated ash content of 1.0% by weight or smaller, a sulfur content of 0.3% by weight or smaller and a molybdenum content of 100 ppm or greater; and DPF for removing PM in combustion gas discharged from a Diesel engine vehicle by trapping and burning PM, DPF comprising a filter supporting a molybdenum compound. The combustion property of PM trapped with the filter of DPF is improved, PM is burned at a low temperature with stability, the efficiency of removal of PM is improved and the life of DPF is increased.Type: GrantFiled: September 22, 2004Date of Patent: August 2, 2011Assignee: Idemitsu Kosan Co., Ltd.Inventor: Tadashi Katafuchi
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Patent number: 7988884Abstract: A novel manufacturing process is described for producing hindered phenolic alkyl esters, which may be useful as antioxidants. This process simplifies catalyst neutralization and removal during the preparation of hindered phenolic esters. Compositions that comprise the hindered phenolic esters produced according to these methods are also described.Type: GrantFiled: January 26, 2010Date of Patent: August 2, 2011Assignee: Albemarle CorporationInventors: Vincent J. Gatto, Hassan Y Elnagar, Chi Hung Cheng, J. Robert Adams
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Patent number: 7939478Abstract: The invention provides a method of lubricating a marine diesel engine, comprising supplying to said engine a marine diesel cylinder lubricant composition at a feed rate of 0.3 to less than 1.2 g/kW hr, wherein said lubricant composition has a ratio of /?(wt % overbased detergent)/?(wt % of boron from antiwear additives+wt % of phosphorus-containing antiwear additives) of greater than 12.5. The invention further provides a method capable of imparting improved cleanliness and decreased cylinder wear; and reduced deposits.Type: GrantFiled: October 13, 2006Date of Patent: May 10, 2011Assignee: The Lubrizol CorporationInventors: Alexandra Mayhew, Stephen J. Cook
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Patent number: 7871966Abstract: The present invention provides a lubricating oil composition, which is capable to maintain sufficient low-friction (i.e. fuel saving performance) even when the lubricating oil is contaminated with soot and metal abrasion powder, which is excellent in durability with regard to anti-wear property and detergency, as well as oxidation stability, and which is capable to lower the ash content and to sufficiently maintain the performance of exhaust-gas after-treatment device for a long term. The lubricating oil composition comprises a lubricant base oil containing a base oil (X) of which % CP is 70 or more, % CA is 1 or less, viscosity index is 115 or more, and CCS viscosity at ?35° C. is 3000 mPa·s or less, wherein the lubricant base oil, to total mass of the composition, contains following components (A)˜(D): (A) 0.01˜10 mass % of ashless friction modifier; (B) 0.01˜0.2 mass % of phosphorus-containing anti-wear agent as phosphorous content; (C) 0.01˜1 mass % of metallic detergent as metal content; and (D) 0.01˜0.Type: GrantFiled: March 18, 2008Date of Patent: January 18, 2011Assignee: Nippon Oil CorporationInventor: Shigeki Matsui
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Patent number: 7867957Abstract: The lubricating oil composition of the invention comprises a lubricating base oil with a urea adduct value of no greater than 4% by mass and a viscosity index of 100 or higher, an ashless friction modifier at 0.01-10% by mass and a phosphorus-containing anti-wear agent at 0.01-0.2% by mass as phosphorus, based on the total amount of the composition.Type: GrantFiled: March 28, 2008Date of Patent: January 11, 2011Assignee: Nippon Oil CorporationInventors: Shigeki Matsui, Kazuo Tagawa
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Publication number: 20100331224Abstract: Provided herein are lubricating oil compositions comprising a major amount of a base oil, at least one oil-soluble molybdenum compound and a zinc dialkyldithiophosphate compound, wherein the molybdenum content derived from the molybdenum compound is at least 10 ppm based on the total weight of the lubricating oil composition and the phosphorus content derived from the zinc dialkyldithiophosphate compound is about 200 to 500 ppm based on the total weight of the lubricating oil composition. The lubricating oil composition can further comprise at least one additive. Methods of making and using the lubricating oil compositions are also described.Type: ApplicationFiled: September 10, 2010Publication date: December 30, 2010Inventors: Alexander B. Boffa, Kenji Takeoka
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Publication number: 20100292113Abstract: The embodiments described herein relate to particular formulations and methods that may provide improved fuel economy characteristics for an engine lubricant. The compositions and methods include a (a) a base oil; (b) a zinc dialkyldithiophosphate compound; and (c) a hydrocarbon soluble metal compound. The hydrocarbon soluble metal compound is devoid of phosphorus and sulfur atoms and the metal is selected from the group consisting essentially of selected from the group consisting essentially of cobalt, nickel, zinc, zirconium, manganese, vanadium, scandium, yttrium, tungsten, gold, platinum, and iron. A weight ratio of total metal in the lubricant composition from the zinc dialkyl-dithiophosphate compound and the hydrocarbon soluble metal compound to phosphorus in the lubricant composition ranges from greater than about 1.5 to 1 to about 15 to 1.Type: ApplicationFiled: March 16, 2010Publication date: November 18, 2010Applicant: AFTON CHEMICAL CORPORATIONInventors: Jeffrey M. GUEVREMONT, Mark T. DEVLIN, Naresh C. MATHUR, Jason A. LAGONA
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Publication number: 20100279902Abstract: The embodiments described herein relate to particular formulations and methods that provide reduced engine deposits. The lubricant composition includes a base oil having a NOACK volatility of from about 5 to about 15 and a zinc dialkyl dithio phosphate composition. The zinc dialkyl dithio phosphate composition has at least about 65 mole percent of zinc dialkyl dithio phosphate compounds derived from all primary alcohols, wherein the zinc dialkyl dithio phosphate composition has greater than about 40 mole percent zinc dialkyl dithio phosphate compounds having alkoxy moieties derived from alcohols having four carbon atoms.Type: ApplicationFiled: May 1, 2009Publication date: November 4, 2010Applicant: Afton Chemical CorporationInventors: William Y. Lam, Gregory H. Guinther
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Publication number: 20100216675Abstract: The resistance to oxidation of a lubricating oil is enhanced by the addition to the lubricating oil of an additive amount of an ionic liquid.Type: ApplicationFiled: February 5, 2010Publication date: August 26, 2010Inventor: Jacob Joseph Habeeb
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Publication number: 20100130391Abstract: A novel manufacturing process is described for producing hindered phenolic alkyl esters, which may be useful as antioxidants. This process simplifies catalyst neutralization and removal during the preparation of hindered phenolic esters. Compositions that comprise the hindered phenolic esters produced according to these methods are also described.Type: ApplicationFiled: January 26, 2010Publication date: May 27, 2010Applicant: ALBEMARLE CORPORATIONInventors: Vincent J. Gatto, Hassan Y. Elnagar, Chi Hung Cheng, J. Robert Adams
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Publication number: 20080125337Abstract: The embodiments described herein relate to particular formulations and methods that provide reduced exhaust catalyst deactivation and/or reduced oil consumption.Type: ApplicationFiled: November 29, 2006Publication date: May 29, 2008Inventors: Gregory H. Guinther, William Y. Lam
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Patent number: 7074745Abstract: A process and method for manufacturing an improved engine oil comprising mixing ferric fluoride with ZDDP to form an additive mixture, heating the additive mixture to at least 125° C. for at least 4 hours to produce a pre-reacted mixture, and adding the pre-reacted mixture to a fully formulated engine oil not containing ZDDP. Also disclosed is an engine oil prepared by a process comprising mixing catalyst with ZDDP to form an additive mixture, heating the additive mixture to about 60° C. to produce a pre-reacted additive mixture, and adding the pre-heated additive mixture to a fully formulated engine oil not containing ZDDP.Type: GrantFiled: October 14, 2004Date of Patent: July 11, 2006Assignee: Platinum Intellectual Property, L.P.Inventors: Harold Shaub, Pranesh B. Aswath, Md. Zahedul Huq
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Patent number: 6894009Abstract: A grease composition for constant velocity joints, having a base oil and a urea-based thickener, which grease additionally contains, (A) molybdenum sulphide dialkyldithiocarbamate and (B) 5,5-dithiobis (1,3,4-thiadiazole-2-thiol); a method of lubricating a constant velocity joint including packing it with grease and a constant velocity joint packed with said grease.Type: GrantFiled: February 28, 2001Date of Patent: May 17, 2005Assignee: Shell Oil CompanyInventors: Yasushi Kawamura, Kouichi Nakazawa, Noriaki Shinoda, Keiji Tanaka, Tetsuo Nimura, Kouji Saitou, Tomoyasu Wada
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Patent number: 6852678Abstract: An aqueous lubricant is provided which by simple application onto metal surfaces forms lubricating films required for heavy working of metals, and which contains no oil. The aqueous lubricant is prepared by suspending or dispersing a metal chelate compound in water with a surfactant or the like. The metal chelate compound has a polydentate or multidentate chelate ligand, in which at least one of the coordinating atoms is sulfur, coordinated to the coordination site of at least one metal species selected from among zinc, manganese, iron, molybdenum, tin and antimony. When applied onto metal surfaces, the aqueous lubricant forms effective lubricating films on the metal surfaces. The lubricating films contain sulfur as coordinating atoms and therefore, extreme pressure produces sulfur radicals through decomposition by tribo-chemical reactions. The sulfur radicals are highly reactive and react rapidly with the metal surface to produce metal sulfides with a lubricating effect.Type: GrantFiled: November 19, 2001Date of Patent: February 8, 2005Assignees: MEC International Corporation, Toyota Jidosha Kabushiki KaishaInventors: Heijiro Ojima, Masahiko Takeuchi, Fumio Ikesue, Noritoshi Kaskimura, Fumio Kawahara, Mitsuru Tomono
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Patent number: 6444624Abstract: An SAE OW-30 or 5W-30 or 5W-20 lubricant has a Noack volatility of less than 15, optionally an M-111 fuel economy of 1.5% or less, and a chlorine content of less than 100 ppm. The lubricant comprises a basestock containing from 0 to less than 10% Group I and/or Group II basestocks, a molybdenum additive providing not greater than 1000 ppm of molybdenum to the lubricant, a calcium detergent providing 10 or greater mmoles of surfactant per kilogram of lubricant, one or more other additives, and a viscosity modifier.Type: GrantFiled: September 20, 2000Date of Patent: September 3, 2002Inventors: Juliet V. Walker, Ian A. Bell
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Patent number: 6423671Abstract: Organo molybdenum containing oils of lubricating viscosity having improved high temperature frictional properties are made using semi-packages of additives. The semi-packages contain: (A) a dispersant, a zinc salt, and a detergent and (B) an organo molybdenum compound. The packages are formed individually prior to mixing.Type: GrantFiled: October 6, 1998Date of Patent: July 23, 2002Assignee: The Lubrizol CorporationInventor: Junsuke Haruna
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Patent number: 6333297Abstract: A constant-velocity joint for a propeller shaft is provided which can be used with good durability without adding any organic lead compound, which is high in the effect of suppressing temperature rise of grease during high-speed rotation, and which can prevent deterioration of the grease.Type: GrantFiled: December 28, 2000Date of Patent: December 25, 2001Assignee: NTN CorporationInventor: Shinichi Takabe
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Publication number: 20010016563Abstract: A constant-velocity joint for a propeller shaft is provided which can be used with good durability without adding any organic lead compound, which is high in the effect of suppressing temperature rise of grease during high-speed rotation, and which can prevent deterioration of the grease.Type: ApplicationFiled: December 28, 2000Publication date: August 23, 2001Applicant: NTN CORPORATIONInventor: Shinichi Takabe
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Patent number: 6153564Abstract: A lubricating oil composition is provided comprising a major amount of an oil of lubricating viscosity and a minor amount of, as an additive, at least one compound comprising a metal core and bonded thereto one or more ligands capable of rendering the compound oil-soluble or oil-dispersible, at least one ligand having at least two hydrocarbyl groups of which one has 1 to 7 carbon atoms and the other or another has more carbon atoms.Type: GrantFiled: June 17, 1999Date of Patent: November 28, 2000Assignee: Infineum USA L.P.Inventors: Velautha-Cumaran Arunasalam, Ian A. W. Bell, John A. Cleverley, Ronald P. Wangner
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Patent number: 5837657Abstract: The present invention is directed to a method for improving the performance of a sooted diesel oil and controlling soot induced viscosity increase by adding to a major amount of a diesel oil a minor amount of a composition comprising at least one compound having the formula Mo.sub.3 S.sub.k L.sub.n Q.sub.z and mixtures thereof wherein the L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 through 10, Q is selected from the group of neutral electron donating compounds such as water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes nonstoichiometric values.Type: GrantFiled: December 2, 1997Date of Patent: November 17, 1998Inventors: Howard L. Fang, Jonathan M. McConnachie, Edward Ira Stiefel
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Patent number: 5763370Abstract: Pre-blended combinations and reaction products of at least one metallic dithiocarbamate and at least one metallic dithiophosphate provide the synergism of antiwear properties with friction-reducing properties for lubricants and greases.Type: GrantFiled: December 19, 1996Date of Patent: June 9, 1998Assignee: Mobil Oil CorporationInventors: John Phillips Doner, Liehpao Oscar Farng
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Patent number: 5627294Abstract: An alcohol and/or a carboxylic acid or carboxylate is used to reduce the proportion of sediment obtained in the manufacture of a metal or ammonium dihydrocarbyl dithiophosphate, for example, a zinc dihydrocarbyl dithiophosphate (ZDDP) for use as an antiwear agent/antioxidant in crankcase lubricating oils.Type: GrantFiled: February 24, 1995Date of Patent: May 6, 1997Assignee: Exxon Chemical Patents Inc.Inventors: David R. Adams, Patrick F. Ginnelly