With Organic Phosphorus Compound (e.g., Phosphate Esters, Etc.) Patents (Class 508/408)
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Patent number: 9196472Abstract: There are provided a processing liquid that is capable of suppressing pattern collapse of a fine metal structure, such as a semiconductor device and a micromachine, and a method for producing a fine metal structure using the same. The processing liquid for suppressing pattern collapse of a fine metal structure, contains a phosphate ester and/or a polyoxyalkylene ether phosphate ester, and the method for producing a fine metal structure, uses the same.Type: GrantFiled: July 21, 2010Date of Patent: November 24, 2015Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Masaru Ohto, Hiroshi Matsunaga, Kenji Yamada
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Patent number: 9029305Abstract: Provided is a lubricating oil composition containing a base oil which includes a mineral oil and/or a synthetic oil, and compounded therein, (A) at least one phosphorus-containing compound selected from phosphoric acid monoesters, phosphoric acid diesters and phosphorous acid monoesters, each having a C1 to C8 hydrocarbon group or groups and (B) a tertiary amine compound having C6 to C10 hydrocarbon groups as substituents thereof. The lubricating oil composition provides both a high metal to metal friction coefficient and an excellent wear resistance and is suitably used in a continuously variable transmission.Type: GrantFiled: January 9, 2009Date of Patent: May 12, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventor: Keiichi Narita
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Patent number: 8962540Abstract: To provide a lubricating oil composition including a base oil which is composed of a mineral oil and/or a synthetic oil and which has a viscosity index of 95 or higher, and (A) an alkenylsuccinimide in an amount of 0.1 to 2.0 mass %, (B) an acidic phosphite diester having a C6 to C10 hydrocarbon group in an amount of 0.1 to 2.0 mass %, and (C) at least one species selected from among a perbasic alkaline earth metal sulfonate, a perbasic alkaline earth metal phenate, and a perbasic alkaline earth metal salycilate, in an amount of 0.001 to 0.3 mass %, with respect to the total amount of the composition.Type: GrantFiled: April 21, 2009Date of Patent: February 24, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventor: Masatoshi Toda
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Publication number: 20150048271Abstract: A lubricating oil composition for a refrigerating machine according to the present invention includes: a base oil including as a main component at least one kind of oxygen-containing compound selected from polyoxyalkylene glycols, polyvinyl ethers, copolymers of poly(oxy)alkylene glycols or monoethers thereof and polyvinyl ethers, polyol esters, and polycarbonates; a sulfonic acid metal salt having a hydrocarbyl group; and a phosphoric acid ester.Type: ApplicationFiled: March 7, 2013Publication date: February 19, 2015Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Masato Kaneko, Takeo Tokiai
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Patent number: 8895489Abstract: The invention provides a grease composition for hub unit bearing, containing (a) an aromatic diurea thickener, (b) a base oil, (c) a metal salt of oxidized wax, (d) diphenyl hydrogen phosphate, and (e) at least one rust preventive selected from the group consisting of sulfonate rust preventives and carboxylic acid rust preventives. The grease composition of the invention shows excellent anti-fretting properties at low temperature, and at the same time, exhibit excellent rust preventing properties.Type: GrantFiled: September 2, 2011Date of Patent: November 25, 2014Assignees: Kyodo Yushi Co., Ltd., NTN CorporationInventors: Takashi Azuma, Yoshihisa Imamoto, Motohiro Ito, Yasushi Shibata
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Patent number: 8778855Abstract: A lubricating base oil contains: an overbased calcium sulfonate having a different base number provided such that a total base number is in a range of 280 to 500 mgKOH/g and a calcium concentration in a total amount is in a range of 280 to 3000 mass ppm (in terms of calcium); and orthophosphates that is at least one selected from phosphates and acid phosphates and provided such that a phosphorus concentration is 50 mass ppm or more. A high friction coefficient of 0.11 or more and a favorable wear resistance of a specific wear rate of less than 2.0×10?8 mm3/Nm are obtained, thereby reliably providing a high power transmission capacity for a long period of time, particularly in a belt-type continuously variable transmission equipped with a metallic belt.Type: GrantFiled: February 6, 2008Date of Patent: July 15, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventor: Toshihiko Ichihashi
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Publication number: 20140038866Abstract: The present invention relates to a lubricating composition containing: an oil of lubricating viscosity, a non-borated dispersant, a detergent, and an antiwear package comprising (a) a derivative of a hydroxycarboxylic acid, (b) an amine salt of a phosphoric acid ester, and (c) a phosphite having at least one hydrocarbyl group with 4 or more carbon atoms. The invention further provides for a method of lubricating a driveline device application by employing a lubricating composition containing the antiwear package.Type: ApplicationFiled: February 15, 2012Publication date: February 6, 2014Applicant: THE LUBRIZOL CORPORATIONInventor: William R. S. Barton
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Publication number: 20130172223Abstract: Provided herein are compositions comprising at least one estolide compound of formula: in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 1; R1, independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3 and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are uses of the compositions described herein.Type: ApplicationFiled: January 30, 2013Publication date: July 4, 2013Applicant: BIOSYNTHETIC TECHNOLOGIES, LLCInventor: Biosynthetic Technologies, LLC
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Publication number: 20130157915Abstract: The invention provides a grease composition for huh unit bearing, containing (a) an aromatic diurea thickener, (b) a base oil, (c) a metal salt of oxidized wax, (d) diphenyl hydrogen phosphate, and (e) at least one rust preventive selected from the group consisting of sulfonate rust preventives and carboxylic acid rust preventives. The grease composition of the invention shows excellent anti-fretting properties at low temperature, and at the same time, exhibit excellent rust preventing properties.Type: ApplicationFiled: September 2, 2011Publication date: June 20, 2013Applicants: NTN CORPORATION, KYODO YUSHI CO., LTD.Inventors: Takashi Azuma, Yoshihisa Imamoto, Motohiro Ito, Yasushi Shibata
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Publication number: 20120329692Abstract: A wet friction clutch-lubricant system wherein a wet friction clutch having a cellulose-based friction lining, or a device including such a clutch, is lubricated with a lubricant composition a major amount of oil of lubricating viscosity and minor effective amounts of performance enhancing additives including (a) one or more ashless dispersant; (b) one or more organic phosphorus compound and (c) one or more sodium salt of an organic acid; and optionally, (d) an auxiliary friction modifier.Type: ApplicationFiled: February 19, 2010Publication date: December 27, 2012Inventors: Joe R. Noles, JR., Hirokazu Saito, Philip Skinner, Raymond F. Watts, Keiji Hayashi, Atsushi Suzuki, Koji Saito
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Publication number: 20120196778Abstract: The invention provides a lubricating composition containing (a) an oil of lubricating viscosity, (b) a phosphite having at least one hydrocarbyl group that has 4 or more carbon atoms, and (c) a compound derived from a hydroxy-carboxylic acid. The invention further relates to the use of the lubricating composition in an internal combustion engine.Type: ApplicationFiled: August 11, 2010Publication date: August 2, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Matthew D. Gieselman, Patrick E. Mosier, Michael R. Sutton, Mark C. Davies, William R.S. Barton
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Publication number: 20110053816Abstract: Provided is a lubricating oil composition containing a base oil which includes a mineral oil and/or a synthetic oil, and compounded therein, (A) at least one phosphorus-containing compound selected from phosphoric acid monoesters, phosphoric acid diesters and phosphorous acid monoesters, each having a C1 to C8 hydrocarbon group or groups and (B) a tertiary amine compound having C6 to C10 hydrocarbon groups as substituents thereof. The lubricating oil composition provides both a high metal to metal friction coefficient and an excellent wear resistance and is suitably used in a continuously variable transmission.Type: ApplicationFiled: January 9, 2009Publication date: March 3, 2011Applicant: IDEMITSU KOSAN Co., Ltd.Inventor: Keiichi Narita
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Patent number: 7820076Abstract: The invention relates to an oleaginous mildew and corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion and mildew. The composition comprises, in parts by weight, from about 20 to 60 parts of an oleaginous material such as a lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.0 to 5.0 parts of a water-displacing compound, an effective amount of a mildew-inhibiting compound, and from 0.0 to 1.0 part of a heterocyclic metal deactivator.Type: GrantFiled: December 20, 2005Date of Patent: October 26, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: El Sayed S. Arafat, Craig A. Matzdorf, James A. Whitfield
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Patent number: 7776233Abstract: The invention relates to an oleaginous corrosion-inhibiting composition, and the use of said composition to protect metal from corrosion. The composition comprises, in parts by weight, from about 20 to 60 parts of lubricating oil, 10 to 40 parts of organic solvent, 20 to 60 parts of corrosion-inhibitor consisting of a sulfonic acid-carboxylic acid metal complex or a mixture of said metal complex with a small but effective amount of an oil soluble alkyl phosphate, from 0.1 to 2.0 parts of an oil soluble antioxidant, from 0.1 to 5.0 parts of a water-displacing compound and from 0.0 to 1.0 part of a metal deactivator.Type: GrantFiled: October 27, 2005Date of Patent: August 17, 2010Assignee: The United States of America as represented by the Secretary of the NavyInventors: El Sayed Arafat, Judy Butler-Kowalik, Kenneth Clark, David L. Gauntt
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Patent number: 6919300Abstract: A protective lubricating composition is provided which will penetrate readily to closely fitting frictional parts and form a protective non-migrating lubricating film improving lubrication between the moving parts reducing friction and wear and preventing corrosion. The lubricant composition may be combined with solvents and propellants to make a sprayable lubricant composition.Type: GrantFiled: July 2, 2002Date of Patent: July 19, 2005Assignee: Ashland Inc.Inventors: Michael A. Dituro, Richard J. Baumgart, Mandeep S. Saini, Christopher J. Nonevski
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Patent number: 6828285Abstract: An oil composition for heat treatment of a gear which comprises mineral oil having a kinematic viscosity of 5 to 40 mm2/second at 100° C. as a base oil and, based on a total amount of the composition, 0.01 to 5% by weight of (a) a phosphoric acid ester compound and, where necessary, 0.5 to 10% by weight of (b) one compound selected from alkenylsuccinimide compounds, alkylsuccinimide compounds and addition products of boron with alkenylsuccinimide compounds or alkylsuccinimide compounds and 0.5 to 10% by weight of (c) at least one compound selected from salicylates, phenates and sulfonates of alkaline earth metals. A coating film is formed on the surface of a gear simultaneously with hardening of the gear and the gear can be provided with resistance to pitching.Type: GrantFiled: February 14, 2003Date of Patent: December 7, 2004Assignee: Idemitsu Kosan Co., Ltd.Inventor: Eiichi Nakamura
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Patent number: 6790813Abstract: Oil compositions and formulated crankcase engine oils demonstrate improved fuel economy performance when comprising an overbased sulfonate detergent having a total base number greater than about 450 and which contain at least one other additive which includes a succinimide type dispersant. Methods for improving fuel economy employing such high TBN sulfonates and engine oil formulations and concentrates containing such are disclosed.Type: GrantFiled: November 21, 2002Date of Patent: September 14, 2004Assignee: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Publication number: 20040121918Abstract: The lubricating compositions of the present invention are designed for use in a four stroke outboard marine engine and contain an oil of lubricating viscosity, an ashless dispersant, a metal detergent, a rust inhibitor system comprising a combination of certain rust inhibitors with an ethoxylated alkyl phenol, a relatively high amount of ZDDP, and an amount of a molybdenum compound sufficient to provide the composition with 15-1,000 ppm by mass of molybdenum. An amount of about 15 ppm to 1,000 ppm by mass of molybdenum from a molybdenum compound has been found to be effective as an antiwear agent in combination with the high levels of ZDDP.Type: ApplicationFiled: September 8, 2003Publication date: June 24, 2004Inventors: Salvatore Rea, Malcolm Waddoups, Rolfe J. Hartley, Ricardo A. Bloch, Michael D. Hoey, George C. L'Heureux
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Publication number: 20040102336Abstract: Oil compositions and formulated crankcase engine oils demonstrate improved fuel economy performance when comprising an overbased sulfonate detergent having a total base number greater than about 450 and which contain at least one other additive which includes a succinimide type dispersant. Methods for improving fuel economy employing such high TBN sulfonates and engine oil formulations and concentrates containing such are disclosed.Type: ApplicationFiled: November 21, 2002Publication date: May 27, 2004Applicant: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Patent number: 6649575Abstract: A low-phosphorus lubricant comprises: an oil of lubricating viscosity; a nitrogen-containing and a nitrogen-free dispersant; a metal dihydrocarbyl dithiophosphate; and a hydrocarbyl-substituted carboxylic acid derivative, the ratio of the dispersants being such as to provide suitable fluoroelastomer seal compatibility.Type: GrantFiled: December 5, 2001Date of Patent: November 18, 2003Assignee: Infineum International Ltd.Inventor: Robert Robson
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Patent number: 6642188Abstract: The lubricating compositions of the present invention are designed for use in a four stroke outboard marine engine and contain an oil of lubricating viscosity, an ashless dispersant, a metal detergent, a rust inhibitor, a relatively high amount of ZDDP, and an amount of a molybdenum compound sufficient to provide the composition with 15-1,000 ppm by mass of molybdenum. An amount of about 15 ppm to 1,000 ppm by mass of molybdenum from a molybdenum compound has been found to be effective as an antiwear agent in combination with the high levels of ZDDP.Type: GrantFiled: July 8, 2002Date of Patent: November 4, 2003Assignee: Infineum International Ltd.Inventors: Rolfe J. Hartley, Salvatore Rea, Malcolm Waddoups
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Publication number: 20030162671Abstract: This invention relates to novel water soluble metal working fluid compositions, their use to work metal, a process for working metal using such compositions and the metal worked article of manufacture. More particularly, this invention relates to fluid compositions useful in cutting, grinding, shaping and other metal working operations which require a lubricant. The terms “first Group A” and “second Group B” are used herein to denote different groups and not to indicate any sequence of use or selection as any possible combination or sequence of use of a component(s) is envisioned without limit of any kind. The disclosed fluid compositions are also anticorrosive and environmentally more acceptable than current oil based fluids.Type: ApplicationFiled: February 24, 1999Publication date: August 28, 2003Inventors: DENNIS J. KALOTA, YUETING CHOU, TIMOTHY K. HIRZEL, DAVID C. SILVERMAN, JACOB S. TOU, WINSOR R. CHO
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Patent number: 6503872Abstract: This invention relates to a manual transmission lubricants comprising a major amount of an oil of lubricating viscosity, (A) at least one metal thiophosphate, (B) at least one phosphite, and (C) at least one basic salt of an acidic organic compound. In another embodiment, the manual transmission further comprises at least metal salt of a phenol. The lubricants provide the antiwear and extreme pressure protection needed for the manual transmission without harming the manual transmission components.Type: GrantFiled: August 22, 2000Date of Patent: January 7, 2003Assignee: The Lubrizol CorporationInventor: Joseph A. Tomaro
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Patent number: 6482778Abstract: Transmission fluid compositions comprising a zinc detergent and at least one phosphorus-containing additive have enhanced performance capabilities. The use of the zinc detergent and the phosphorus-containing additive provide transmission fluids that exhibit high steel-on-steel coefficients of friction, particularly useful in continuously variable transmissions (CVT).Type: GrantFiled: August 11, 1999Date of Patent: November 19, 2002Assignee: Ethyl CorporationInventors: Samuel H. Tersigni, Sanjay Srinivasan, David L. Strait
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Patent number: 6426323Abstract: To provide a lubricating oil composition for continuously variable transmission which ensures both a high coefficient of friction between metals required for a push belt-type CTV oil and an excellent wear preventing property relative to a belt and a pulley. A lubricating oil composition for continuously variable transmission is provided, which comprises a lubricating base oil made of a mineral oil and/or a synthetic oil formulated with a metal detergent and a phosphorus-based wear preventive characterized in that a ratio between a content (ppm) of a metal derived from said metal detergent and based on the total weight of the lubricating oil composition and a total base number (mg KOH/g) ranges 0.75-4.5 (ppm/mg KOH/g), and a ratio between the content (ppm) of the metal derived from said metal detergent and a content of phosphorus derived from said phosphorus-based wear preventive ranges 0.5-2.0 (ppm/ppm).Type: GrantFiled: June 5, 2001Date of Patent: July 30, 2002Assignee: TonenGeneral Sekiyu K.K.Inventors: Takehisa Sato, Takanori Kugimiya
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Publication number: 20020002120Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, (A) an antiwear improving amount of at least one molybdenum containing composition, (B) at least one phosphorus antiwear or extreme pressure agent, and (C) at least one dispersant, provided that the lubricating composition is free of polysulfurized olefins. The lubricating compositions have improved antiwear properties. When the lubricating composition is used in a manual transmission, the amount of brass wear is reduced.Type: ApplicationFiled: December 22, 2000Publication date: January 3, 2002Inventor: Michael P. Gahagan
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Patent number: 6127323Abstract: The anti-shudder durability of power transmitting fluids, particularly automatic transmission fluids, is improved by incorporating a combination of alkyl phosphonates, ashless dispersants and metallic detergents.Type: GrantFiled: April 21, 1997Date of Patent: October 3, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Raymond Frederick Watts, David Edward Gindelberger
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Patent number: 6046144Abstract: Disclosed are synergistic antioxidant compositions composed of (1) amine salts of alkyl phosphates and (2) ethylenediamine, ammonium or metal salts of alkylarylsulfonates.The antioxidant compositions are useful for formulating zinc-free antiwear hydraulic fluids and gear lubricating oils in conjunction with thiophosphate type antiwear agents, corrosion and rust inhibitors.Type: GrantFiled: June 2, 1997Date of Patent: April 4, 2000Assignee: R.T. Vanderbilt Co., Inc.Inventors: Thomas J. Karol, Steven G. Donnelly, Brian W. Stunkel
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Patent number: 5922656Abstract: The lubricant composition of the present invention can be used in automatic transmissions and contains 0.05 to 2% of a metallic salt of organic acid (component (A)), such as calcium sulfonate, 0.15 to 4% of a specific polyamide compound (component (B)) and 0.05 to 1.5% of acid phosphate or acid phosphite ester (component (C)) which are added to a lubricant base oil, wherein all percentages are by weight in the total lubricant composition. The lubricant composition for automatic transmissions can show high anti-shudder property, high anti-shudder durability for an extended period, high property of preventing clogging of the friction material, and sufficient transmission torque capacity, while retaining the lubricant characteristic requirements for use in automatic transmissions.Type: GrantFiled: March 23, 1998Date of Patent: July 13, 1999Assignees: Tonen Corporation, Toyota Jidosha Kabushiki KaishaInventors: Narihiko Yoshimura, Takanori Kugimiya, Takanori Nakada, Fumio Ueda, Yasushi Ando
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Patent number: 5792731Abstract: A lubricant composition for continuous variable transmissions which comprises a base oil and auxiliaries incorporated therein which are a sulfur-based extreme pressure additive (A), a phosphorus-based extreme pressure additive (B), and an alkaline earth metal-based detergent (C) It is superior in wear resistance and extreme pressure properties and keeps the coefficient of friction high for a long period of time, so that it is capable of transmitting a large capacity of torque when it is applied to an continuous variable transmission. It is particularly suitable for a transmission of metal belt type.Type: GrantFiled: June 5, 1997Date of Patent: August 11, 1998Assignee: Idemitsu Kosan Co., Ltd.Inventors: Toshihiko Ichihashi, Hideo Igarashi, Noboru Sonoda
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Patent number: 5656582Abstract: The rust preventive lubricating oil of the present invention concerns a base oil and a rust-preventive agent in an amount of 2-20% by weight on the basis of the whole rust preventive lubricating oil, wherein the base oil contains an ether oil in an amount of at least 20% by weight on the basis of the whole rust preventive lubricating oil. The rust preventive lubricating oil can be applied to the surface of raceway tracks of inner and outer rings, cages for bearings, as well as to bearings, to prevent development of rust, to inhibit generation of cage sound, and to obtain good lubricity, while retaining good compatibility with a grease to be later charged.Type: GrantFiled: June 21, 1996Date of Patent: August 12, 1997Assignee: NSK LimitedInventors: Emiko Shiraishi, Hiroyuki Ito, Masao Yamamoto, Michiharu Naka, Akira Suzuki, Shigeki Maehara
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Patent number: 5531911Abstract: Functional fluids comprising an oil of lubricating viscosity, the reaction product of an amine and a sulfonic acid, and at least one sulfur-containing compound of the structure(RX).sub.3 P.dbd.Xwhere X is sulfur or oxygen exhibit good anti-rust and antiwear performance.Type: GrantFiled: June 7, 1995Date of Patent: July 2, 1996Assignee: The Lubrizol CorporationInventors: Paul E. Adams, Thomas G. Hach, James N. Vinci