Plural Phosphori Bonded To The Same Chalcogen Or Chain Of Chalcogens (e.g., Pyrophosphates, Etc.) Patents (Class 508/424)
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Patent number: 11384308Abstract: A lubricant composition comprising an oil of lubricating viscosity and 0.01 to 5 percent by weight of a substantially sulfur-free alkyl phosphate amine salt, where at least 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure, exhibits good antiwear performance. In the phosphate amine salt, at least 80 mole percent of the alkyl groups are typically secondary alkyl groups of 3 to 12 carbon atoms.Type: GrantFiled: July 17, 2017Date of Patent: July 12, 2022Assignee: The Lubrizol CorporationInventors: William R. S. Barton, Daniel J. Saccomando, Jamal Kassir, Paul E. Adams, Lisa Blanazs, Michael R. Sutton, Stephen J. Cook, Paul R. Vincent, Ewan E. Delbridge, Yanshi Zhang
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Patent number: 10519396Abstract: A lubricant composition comprising an oil of lubricating viscosity and 0.01 to 5 percent by weight of a substantially sulfur-free alkyl phosphate amine salt, where at least 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure, exhibits good antiwear performance, even in the presence of corrosion inhibitor additives. In the phosphate amine salt, at least 80 mole percent of the alkyl groups are typically secondary alkyl groups of 3 to 12 carbon atoms.Type: GrantFiled: November 4, 2016Date of Patent: December 31, 2019Assignee: The Lubrizol CorporationInventors: Suzanne Patterson, Brian B. Filippini, Tomoya Higuchi, William R. S. Barton
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Publication number: 20110306530Abstract: Provided is a continuously variable transmission oil composition that can markedly increase the coefficient of friction between a metal belt or a chain and a pulley, that can maintain the high coefficient of friction over a long period of time, and that causes no clogging of the clutch plate. The continuously variable transmission oil composition includes 0.005-0.15 mass %, as phosphorous compound-derived phosphorus content with respect to the total amount of the composition, of at least one type of phosphorous compound represented by general formula (1) in a lubricating oil base. (1) In general formula (1), R1, R2, R3 and R4 each represents a hydrocarbyl with carbon number 1-30 or a hydrogen atom, R5 represents a hydrocarbylene group with carbon number 1-30, X1 and X2 represent an oxygen atom or a sulfur atom, and n represents an integer 1-10.Type: ApplicationFiled: February 8, 2010Publication date: December 15, 2011Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Yoshitaka Manabe, Shin Saeki
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Patent number: 8063003Abstract: A cyclic phosphazene compound complying with formula (I) or (II): wherein: Rfand R?frepresent independently a (per)fluoropolyoxyalkylene chain comprising recurring units Ro, said recurring units, distributed randomly through the (per)fluoropolyoxyalkylene chain, being chosen among; (i)—CFXO—, X being F or CF3; (ii) —CF2CFXO—, X being F or CF3; (iii) —CF2CF2CF2O—; (iv) —CF2CF2CF2CF2O—; Z and Z? represent a polar group of formula —O?M+, M being chosen among hydrogen, a monovalent metal, or an ammonium radical of formula NR1R2R3R4, or represent a polar group of formula —O?)2M?2+, M? being a divalent metal; nZ is an integer from 1 to 3; nZ? is an integer from 1 to 4; nf? is an integer such that nZ?+nf? is equal to 8; and nfis an integer such that nZ+nfis equal to 6.Type: GrantFiled: June 22, 2007Date of Patent: November 22, 2011Assignee: Solvay Solexis S.p.A.Inventors: Antonella Di Meo, Rosaldo Picozzi
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Publication number: 20110091408Abstract: Fluoroalkyl phosphates containing a tertiary carbon and a nonfluorinated chain are useful as surfactants and additives. The f can be used to alter a surface property of a medium and to provide resistance to blocking, open time extension, or oil repellency to a substrate.Type: ApplicationFiled: October 20, 2009Publication date: April 21, 2011Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: Anilkumar Raghavanpillai
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Patent number: 7122508Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.Type: GrantFiled: October 31, 2002Date of Patent: October 17, 2006Assignee: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Publication number: 20040087450Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.Type: ApplicationFiled: October 31, 2002Publication date: May 6, 2004Inventor: Alexander B. Boffa
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Patent number: 6466029Abstract: A power line testing device has a signal generator that is adapted to be connected to one of a plurality of AC branch circuits, and generates an identification signal. This identification signal will be strongest in the branch circuit of origin. A receiver of the testing device senses the strength of the identification signal, compares that strength to a stored identification signal, and is therefore able to identify to which AC branch circuit the transmitter is connected.Type: GrantFiled: April 4, 2001Date of Patent: October 15, 2002Assignee: Contact Technology Systems, Inc.Inventors: John E. Stroth, Peter Stroth, Joachim Wottrich
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Patent number: 5912212Abstract: A lubricating oil composition comprises (A) a base oil, (B) a 3-methyl-5-tert-butyl-4-hydroxyphenyl substituted fatty acid ester in an amount of 0.1-5 percent by mass and (C) an auxiliary component, said auxiliary component being one member of the group of (a) a nitrogen-containing compound in an amount of 0.001-1 percent by mass, (b) a sulfur and/or phosphorus-containing compound in an amount of 0.1-5.0 percent by mass or (c) a phenolic compound in an amount of 0.1-5.0 percent by mass. This composition features the combination with a base oil of these specified components whereby there is provided synergistic effect conducive to inhibition or prevention of both oxidation and sludge formation while in use under elevated temperature conditions over extended periods of time.Type: GrantFiled: December 18, 1996Date of Patent: June 15, 1999Assignee: Nippon Oil Co., Ltd.Inventors: Jinichi Igarashi, Yoko Matsuyama, Yutaka Shikatani, Toshio Yoshida
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Patent number: 5726132Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.Type: GrantFiled: February 28, 1997Date of Patent: March 10, 1998Assignee: The Lubrizol CorporationInventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
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Patent number: 5712230Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.Type: GrantFiled: March 10, 1997Date of Patent: January 27, 1998Assignee: The Lubrizol CorporationInventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5705458Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), G.sup.1 and G.sup.2 are independently R, OR, SR or NRR wherein each R is independently a hydrocarbyl group, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.Type: GrantFiled: October 24, 1996Date of Patent: January 6, 1998Assignee: The Lubrizol CorporationInventors: Stephen H. Roby, James A. Supp, William D. Abraham, John S. Manka
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Patent number: 5693598Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.Type: GrantFiled: September 3, 1996Date of Patent: December 2, 1997Assignee: The Lubrizol CorporationInventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5674820Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.Type: GrantFiled: September 5, 1996Date of Patent: October 7, 1997Assignee: The Lubrizol CorporationInventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton