Plural Phosphori Bonded To The Same Chalcogen Or Chain Of Chalcogens (e.g., Pyrophosphates, Etc.) Patents (Class 508/424)
  • Patent number: 11384308
    Abstract: A lubricant composition comprising an oil of lubricating viscosity and 0.01 to 5 percent by weight of a substantially sulfur-free alkyl phosphate amine salt, where at least 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure, exhibits good antiwear performance. In the phosphate amine salt, at least 80 mole percent of the alkyl groups are typically secondary alkyl groups of 3 to 12 carbon atoms.
    Type: Grant
    Filed: July 17, 2017
    Date of Patent: July 12, 2022
    Assignee: The Lubrizol Corporation
    Inventors: William R. S. Barton, Daniel J. Saccomando, Jamal Kassir, Paul E. Adams, Lisa Blanazs, Michael R. Sutton, Stephen J. Cook, Paul R. Vincent, Ewan E. Delbridge, Yanshi Zhang
  • Patent number: 10519396
    Abstract: A lubricant composition comprising an oil of lubricating viscosity and 0.01 to 5 percent by weight of a substantially sulfur-free alkyl phosphate amine salt, where at least 30 mole percent of the phosphorus atoms are in an alkyl pyrophosphate salt structure, exhibits good antiwear performance, even in the presence of corrosion inhibitor additives. In the phosphate amine salt, at least 80 mole percent of the alkyl groups are typically secondary alkyl groups of 3 to 12 carbon atoms.
    Type: Grant
    Filed: November 4, 2016
    Date of Patent: December 31, 2019
    Assignee: The Lubrizol Corporation
    Inventors: Suzanne Patterson, Brian B. Filippini, Tomoya Higuchi, William R. S. Barton
  • Publication number: 20110306530
    Abstract: Provided is a continuously variable transmission oil composition that can markedly increase the coefficient of friction between a metal belt or a chain and a pulley, that can maintain the high coefficient of friction over a long period of time, and that causes no clogging of the clutch plate. The continuously variable transmission oil composition includes 0.005-0.15 mass %, as phosphorous compound-derived phosphorus content with respect to the total amount of the composition, of at least one type of phosphorous compound represented by general formula (1) in a lubricating oil base. (1) In general formula (1), R1, R2, R3 and R4 each represents a hydrocarbyl with carbon number 1-30 or a hydrogen atom, R5 represents a hydrocarbylene group with carbon number 1-30, X1 and X2 represent an oxygen atom or a sulfur atom, and n represents an integer 1-10.
    Type: Application
    Filed: February 8, 2010
    Publication date: December 15, 2011
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Yoshitaka Manabe, Shin Saeki
  • Patent number: 8063003
    Abstract: A cyclic phosphazene compound complying with formula (I) or (II): wherein: Rfand R?frepresent independently a (per)fluoropolyoxyalkylene chain comprising recurring units Ro, said recurring units, distributed randomly through the (per)fluoropolyoxyalkylene chain, being chosen among; (i)—CFXO—, X being F or CF3; (ii) —CF2CFXO—, X being F or CF3; (iii) —CF2CF2CF2O—; (iv) —CF2CF2CF2CF2O—; Z and Z? represent a polar group of formula —O?M+, M being chosen among hydrogen, a monovalent metal, or an ammonium radical of formula NR1R2R3R4, or represent a polar group of formula —O?)2M?2+, M? being a divalent metal; nZ is an integer from 1 to 3; nZ? is an integer from 1 to 4; nf? is an integer such that nZ?+nf? is equal to 8; and nfis an integer such that nZ+nfis equal to 6.
    Type: Grant
    Filed: June 22, 2007
    Date of Patent: November 22, 2011
    Assignee: Solvay Solexis S.p.A.
    Inventors: Antonella Di Meo, Rosaldo Picozzi
  • Publication number: 20110091408
    Abstract: Fluoroalkyl phosphates containing a tertiary carbon and a nonfluorinated chain are useful as surfactants and additives. The f can be used to alter a surface property of a medium and to provide resistance to blocking, open time extension, or oil repellency to a substrate.
    Type: Application
    Filed: October 20, 2009
    Publication date: April 21, 2011
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Anilkumar Raghavanpillai
  • Patent number: 7122508
    Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: October 17, 2006
    Assignee: Chevron Oronite Company LLC
    Inventor: Alexander B. Boffa
  • Publication number: 20040087450
    Abstract: Disclosed are methods and lubricant compositions for reducing wear in internal combustion engines lubricated with a low phosphorous content lubricating oil. The lubricant compositions of this invention comprise a synergistic combination of a dispersed, hydrated, alkali metal borate and at least one phosphorous-containing compound wherein the total phosphorous employed in the composition is no more than about 0.08 weight percent based on the total weight of the composition.
    Type: Application
    Filed: October 31, 2002
    Publication date: May 6, 2004
    Inventor: Alexander B. Boffa
  • Patent number: 6466029
    Abstract: A power line testing device has a signal generator that is adapted to be connected to one of a plurality of AC branch circuits, and generates an identification signal. This identification signal will be strongest in the branch circuit of origin. A receiver of the testing device senses the strength of the identification signal, compares that strength to a stored identification signal, and is therefore able to identify to which AC branch circuit the transmitter is connected.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: October 15, 2002
    Assignee: Contact Technology Systems, Inc.
    Inventors: John E. Stroth, Peter Stroth, Joachim Wottrich
  • Patent number: 5912212
    Abstract: A lubricating oil composition comprises (A) a base oil, (B) a 3-methyl-5-tert-butyl-4-hydroxyphenyl substituted fatty acid ester in an amount of 0.1-5 percent by mass and (C) an auxiliary component, said auxiliary component being one member of the group of (a) a nitrogen-containing compound in an amount of 0.001-1 percent by mass, (b) a sulfur and/or phosphorus-containing compound in an amount of 0.1-5.0 percent by mass or (c) a phenolic compound in an amount of 0.1-5.0 percent by mass. This composition features the combination with a base oil of these specified components whereby there is provided synergistic effect conducive to inhibition or prevention of both oxidation and sludge formation while in use under elevated temperature conditions over extended periods of time.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: June 15, 1999
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Jinichi Igarashi, Yoko Matsuyama, Yutaka Shikatani, Toshio Yoshida
  • Patent number: 5726132
    Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: March 10, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
  • Patent number: 5712230
    Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: January 27, 1998
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5705458
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), G.sup.1 and G.sup.2 are independently R, OR, SR or NRR wherein each R is independently a hydrocarbyl group, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: January 6, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, William D. Abraham, John S. Manka
  • Patent number: 5693598
    Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 2, 1997
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5674820
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: October 7, 1997
    Assignee: The Lubrizol Corporation
    Inventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton