Organic -c(=x)x- Compound, Wherein The Xs Are The Same Or Diverse Chalcogens, With At Least One X Being Sulfur Patents (Class 508/443)
  • Patent number: 10377963
    Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition is formulated to be resistant to turbocharger deposit formation in the boosted internal combustion engine, as shown by its ability to ensure a TCO Temperature Increase of less than 9.0% as measured using the 2015 version of the General Motors Dexos1® Turbocharger Coking Test. The lubricating oil composition may also have a low NOACK volatility, as measured by the method of ASTM D-5800 at 250° C.
    Type: Grant
    Filed: January 18, 2017
    Date of Patent: August 13, 2019
    Assignee: Afton Chemical Corporation
    Inventors: Kongsheng Yang, Kristin Fletcher, William Y. Lam, Jeremy Styer
  • Publication number: 20130210688
    Abstract: The invention provides a lubricating grease composition with a worked penetration of 400 to 500 for a machine tool equipped with an automatic lubricator, containing a base oil having a kinematic viscosity at 40° C. of 10 to 200 mm2/s and 0.1 to 10 mass % of solid particles insoluble in the base oil. The lubricating grease composition of the invention can be fed using the automatic lubricator attached to the machine tool, and can prevent the stick-slip from occurring on the sliding lubrication portion of the machine tool.
    Type: Application
    Filed: October 26, 2011
    Publication date: August 15, 2013
    Applicant: KYODO YUSHI CO., LTD
    Inventors: Takayuki Ariyasu, Daming Dong, Hiroshi Ozeki, Minoru Namiki, Terasu Yoshinari
  • Patent number: 8293689
    Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and polymer with pendant groups. The invention further provides for a method of controlling viscosity index by supplying to an oil of lubricating viscosity the polymer with pendant groups.
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: October 23, 2012
    Assignee: The Lubrizol Corporation
    Inventors: Bryan A. Grisso, Mark R. Baker, Daniel C. Visger, Marina Baum, Barton J. Schober, Calvin A. James
  • Patent number: 8268760
    Abstract: The anti-wear and anti-friction performance of a lubricating oil is improved by the addition thereto of an additive amount of ionic liquids.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: September 18, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Jacob Joseph Habeeb, Jessica Lee Prince, Michael Eugene Landis
  • Patent number: 8158565
    Abstract: The present invention provides a molybdenum pentakis-alkylxanthate having general formula (1) which is indicated below. In this formula R1 to R5 each represent a group individually selected from linear chain or branched alkyl groups which have from 1 to 30 carbon atoms.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: April 17, 2012
    Assignee: Shell Oil Company
    Inventors: Eiji Nagatomi, Noriaki Shinoda, Yoshihiko Aihara
  • Publication number: 20100227783
    Abstract: The anti-wear and anti-friction performance of a lubricating oil is improved by the addition thereto of an additive amount of ionic liquids.
    Type: Application
    Filed: February 5, 2010
    Publication date: September 9, 2010
    Inventors: Jacob Joseph Habeeb, Jessica Lee Prince, Michael Eugene Landis
  • Patent number: 7772170
    Abstract: Antimony dithiocarbamate is known to provide extreme pressure (EP) protection in lubricating compositions, such as grease. However, there is a desire to reduce the amount of antimony used in such compositions, while still maintaining acceptable EP performance. It has now been found by using small amounts of either ammonium dithiocarbamate or zinc dithiocarbamate in combination with the antimony dithiocarbamate (SbDTC), a lower amount of SbDTC can be used in the lubricating composition while still maintaining excellent or exceptional EP protection. To counteract the corrosive effects of the SbDTC and ammonium dithiocarbamate composition, it has been found that compounds containing a carboxylic acid group are effective in avoiding copper corrosion.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: August 10, 2010
    Assignee: R.T. Vanderbilt Company, Inc.
    Inventors: Ronald J. Hiza, Gaston A. Aguilar, Steven G. Donnelly, Francis S. Cheng, Ronald J. Tepper
  • Publication number: 20100197537
    Abstract: A lubricant composition with improved antioxidant capability is provided by way of an additive composition containing a metal free sulfur-containing compound, an aromatic amine, and a hindered amine. Particularly effective metal-free sulfur-containing compounds include ashless dithiocarbamates, such as methylenebis(dibutyldithiocarbamate), and sulfurized fatty acids.
    Type: Application
    Filed: January 28, 2010
    Publication date: August 5, 2010
    Applicant: R.T. VANDERBILT COMPANY, INC.
    Inventors: KEVIN J. CHASE, BRIAN W. STUNKEL
  • Publication number: 20100144570
    Abstract: The present invention provides a molybdenum pentakis-alkylxanthate having general formula (1) which is indicated below. In this formula R1 to R5 each represent a group individually selected from linear chain or branched alkyl groups which have from 1 to 30 carbon atoms.
    Type: Application
    Filed: February 1, 2008
    Publication date: June 10, 2010
    Inventors: Eiji Nagatomi, Noriaki Shinoda, Yoshihiko Aihara
  • Publication number: 20100113314
    Abstract: To provide a gear oil composition containing a base oil, and compounded therein, (A) an ashless dithiocarbamate compound and (B) an ester of pentaerythritol and a C12 to C20 branched fatty acid, the ester having a hydroxyl value of 20 to 100 mg KOH/g. The gear oil composition has a high transmission efficiency and shows both of resistance to sludge formation and extreme pressure property.
    Type: Application
    Filed: March 19, 2008
    Publication date: May 6, 2010
    Applicant: Idemitsu Kosan Co., Ltd
    Inventors: Tahei Okada, Shigeo Hara
  • Patent number: 7683016
    Abstract: The inventive composition comprises compatible combinations of methyl esters of fatty acids or triglycerides and polar non-chlorine extreme pressure additives, the composition being either (a) a working strength straight oil, (b) a soluble oil concentrate dilutable to a working strength soluble oil, the composition when at working strength effectively lubricating metal parts during high performance metalworking, and providing environmental and safety advantages.
    Type: Grant
    Filed: August 13, 2002
    Date of Patent: March 23, 2010
    Assignee: United Soybean Board
    Inventors: James P. King, Neil M. Canter
  • Patent number: 7678746
    Abstract: A lubricating composition containing (a). at least 3 weight percent of an overbased sulphonate detergent with a metal ratio of 12.5:1 to 40:1; (b). at least 1.5 weight percent of a sulphur containing phenate detergent with a metal ratio of not more than 2.5; and (c). an oil of lubricating viscosity, wherein the sulphur containing phenate contains oligomers of hydrocarbyl phenol with at least 50 wt % of said oligomers in the form of the tetramer or higher oligomers. The composition is suitable for internal combustion engines, particularly marine diesel applications to provide improved cleanliness decreased cylinder wear and reduced deposits.
    Type: Grant
    Filed: May 13, 2005
    Date of Patent: March 16, 2010
    Assignee: The Lubrizol Corporation
    Inventors: James P. Roski, Richard Leahy, Stephen J. Cook, Alexandra Mayhew
  • Publication number: 20090016652
    Abstract: The lubricant composition of this invention comprises a base oil and an additive, which is at least one selected from the group consisting of an organic sulfonate, a carboxylate, a thiocarbamate and a thiophosphoric acid ester salt. The lubricant composition can effectively suppress hydrogen embrittlement-caused flaking of an element, such as a rolling bearing, a sliding bearing, a gear, a ball thread, a linear guide, a linear bearing, a cam and various joints in a high concentration hydrogen environment. The invention provides also a rolling bearing, a sliding bearing, a gear, a ball thread, a linear guide, a linear bearing, a cam and various joints using the lubricant composition.
    Type: Application
    Filed: September 29, 2008
    Publication date: January 15, 2009
    Inventors: Toshiaki ENDO, Da Ming Dong, Yutaka Imai
  • Publication number: 20090003742
    Abstract: An object of the invention is to provide a grease composition capable of keeping a good lubrication condition for a long period of time even when water has mixed therein, thereby inhibiting white structure flaking and corrosion. Another object is to provide a vehicular hub unit bearing which hardly suffers from white structure flaking and corrosion even when used in an environment where water may penetrate into it and which therefore has a long life. The invention provides a rolling bearing with, sealed up therein, a grease composition containing a waterproof film-forming additive added thereto; a grease composition for hub unit bearings, containing a base oil that comprises at least one of mineral oil and synthetic oil as the main ingredient thereof, and a thickener and a flaking inhibitor; and a vehicular hub unit bearing with the grease composition sealed up therein.
    Type: Application
    Filed: January 24, 2006
    Publication date: January 1, 2009
    Applicants: NSK LTD., KYODO YUSHI CO., LTD.
    Inventors: Shinya Nakatani, Jun Kuraishi, Tomoaki Matsumoto, Minoru Namiki, Ryo Aida, Toshiaki Endo
  • Publication number: 20080194439
    Abstract: A non-chlorine type lubricant in which a sulfur type extreme pressure additive, an organic zinc compound, a calcium type additive, and an ester compound are blended with a base oil for the lubricant, and having a kinetic viscosity from 5 to 50 mm2/s at 40° C.
    Type: Application
    Filed: February 1, 2008
    Publication date: August 14, 2008
    Applicant: TOYOTA BOSHOKU KABUSHIKI KAISHA
    Inventors: Mami KATO, Teruo FUKAYA
  • Patent number: 7183241
    Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.
    Type: Grant
    Filed: September 19, 2003
    Date of Patent: February 27, 2007
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Stanley James Cartwright
  • Patent number: 6887295
    Abstract: The present invention relates to improved metallurgical powder compositions that incorporate solid lubricants, methods for preparing and using the same, and methods of making compacted parts. Ejection properties, such as stripping pressure and sliding pressure, of compacted parts can be improved by using the solid lubricants. The solid lubricants contain functionalized polyalkylene glycol lubricants that contain a phosphate group, phosphite group, hypophosphate group, hypophosphite group, polyphosphate group, thiophosphate group, dithiophosphate group, thiocarbamate group, dithiocarbamate group, borate group, thiosulfate group, sulfate group, a sulfonate group or combinations thereof.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: May 3, 2005
    Assignee: Hoeganaes Corporation
    Inventors: George Poszmik, Sydney Luk
  • Publication number: 20040248745
    Abstract: An ashless natural gas engine lubricating composition which has enhanced resistance to oxidation, nitration and viscosity increase employs as additives in a lubricating oil basestock a combination of phenolic and alkylthiocarbamoyl antioxidants and an ashless phosphorous antiwear additive.
    Type: Application
    Filed: April 23, 2004
    Publication date: December 9, 2004
    Inventor: S. James Cartwright
  • Patent number: 6767872
    Abstract: A lubricant compound for use for both boundary and elastohydrodynamic lubrication utilize a hydrocarbon boundary lubricant linked to one or more fluorocarbon elastohydrodynamic lubricants and may be employed alone or as an additive. The lubricant compound lubricates surfaces on which it is disposed over a range of conditions. The boundary lubricant and the elastohydrodynamic lubricant are substituted such that they react with and/or provide desirable lubrication properties for particular surfaces.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: July 27, 2004
    Assignee: The Charles Stark Draper Laboratory, Inc.
    Inventor: John R. Williams
  • Publication number: 20040110646
    Abstract: A long life lubricating oil, as evidenced by a reduction in oil thickening, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents and at least one trinuclear molybdenum compound.
    Type: Application
    Filed: October 10, 2003
    Publication date: June 10, 2004
    Inventor: Stanley James Cartwright
  • Publication number: 20040048753
    Abstract: Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines equipped with EGR systems can be ameliorated by selection of viscosity modifier, lubricating oil flow improvers, detergents and/or dispersants.
    Type: Application
    Filed: September 10, 2002
    Publication date: March 11, 2004
    Inventors: Andrew J.D. Ritchie, Jai G. Bansal, Jacob Emert, Glen P. Fetterman, Antonio Gutierrez, Matthew D. Irving, Christopher J. Locke, Michael T. Minotti
  • Publication number: 20030096713
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity with an iodine number less than about 9, (A) one or more antioxidant, and (B) from about 0.01% to about 3% by weight of at least one dispersant or detergent, wherein the total amount of antioxidant is at least about 2% by weight. The additives are useful act controlling oxidation of lubricants. Further, these lubricants have reduced viscosity increase caused by oxidation, while maintaining favorable carbon/varnish ratings.
    Type: Application
    Filed: September 5, 1996
    Publication date: May 22, 2003
    Inventors: ERIC R. SCHNUR, ROBERT C. RICHARDSON, JAMES J. SCHWIND
  • Publication number: 20030040442
    Abstract: The invention aims to provide a rolling bearing that secures a sufficient bearing life economically even when used under such conditions that water from the outside or water formed by moisture condensation may seep into the lubricant or the bearing is affected by the vibrations, and particularly a rolling bearing suited to the electric parts and accessaries of au automobile engine, such as an alternator. To accomplish the object, the hydrogen ion exponent pH of the grease sealed into the inside of the bearing is adjusted in a range of from 7 to 13. For the same purpose, the hydrogen ion exponent pH of the grease is adjusted in a range of from 5 to 13 where a prescribed amount of an organic metal salt or ADTC is added to the grease, where a prescribed amount of an inorganic compound having an average particle size of 2 □m or smaller is added to the grease, or where a diurea compound containing an aromatic amine or a mixture of the diurea compound is added to the grease as a thickener.
    Type: Application
    Filed: March 7, 2002
    Publication date: February 27, 2003
    Applicant: NSK LTD.
    Inventors: Atsushi Yokouchi, Youichi Matsumoto, Kenichi Iso, Kouichi Hachiya, Hideki Koizumi, Michiharu Naka
  • Publication number: 20020119895
    Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) an antiwear improving amount of at least one molybdenum containing composition, and (B) at least one member selected from the group consisting of (i) at least one borated overbased metal salt of an acidic organic compound, provided that (A) and (Bi) are not the same, (ii) a combination of (a) at least one organic polysulfide or at least one ashless dithiocarbamate containing composition and (b) at least one component selected from the group consisting of a metal thiophosphate, a phosphoric acid ester or salt thereof, a phosphorus-containing carboxylic acid, ester, ether, or amide, a borated dispersant, an alkali metal borate, a borated fatty amine, a borated phospholipid, a borate ester, and mixtures thereof, and (iii) a combination of (i) and (ii).
    Type: Application
    Filed: May 26, 1995
    Publication date: August 29, 2002
    Inventors: SUSAN P. COOK, JAMES J. SCHWIND, BERNARD CONSTANS, HENRI BOURGOGNON
  • Publication number: 20020111278
    Abstract: An aqueous lubricant is provided which by simple application onto metal surfaces forms lubricating films required for heavy working of metals, and which contains no oil. The aqueous lubricant is prepared by suspending or dispersing a metal chelate compound in water with a surfactant or the like. The metal chelate compound has a polydentate or multidentate chelate ligand, in which at least one of the coordinating atoms is sulfur, coordinated to the coordination site of at least one metal species selected from among zinc, manganese, iron, molybdenum, tin and antimony. When applied onto metal surfaces, the aqueous lubricant forms effective lubricating films on the metal surfaces. The lubricating films contain sulfur as coordinating atoms and therefore, extreme pressure produces sulfur radicals through decomposition by tribo-chemical reactions. The sulfur radicals are highly reactive and react rapidly with the metal surface to produce metal sulfides with a lubricating effect.
    Type: Application
    Filed: November 19, 2001
    Publication date: August 15, 2002
    Inventors: Heijiro Ojima, Masahiko Takeuchi, Fumio Ikesue, Noritoshi Kashimura, Fumio Kawahara, Mitsuru Tomono
  • Publication number: 20020103089
    Abstract: A lubricant composition for a surface treatment of a steel filament comprises at least one specified compound as a lubricant component and a rubber-steel filament composite body is prepared by using a steel filament treated with the lubricant composition.
    Type: Application
    Filed: June 29, 2001
    Publication date: August 1, 2002
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Yasuo Fukushima, Hajime Kondo
  • Publication number: 20020032293
    Abstract: A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions.
    Type: Application
    Filed: August 7, 2001
    Publication date: March 14, 2002
    Inventors: Charles P. Bryant, Bryan A. Grisso, Robert Cantiani
  • Publication number: 20010034308
    Abstract: The invention relates to additives for improving lubricating properties of fuel oils, comprising
    Type: Application
    Filed: March 16, 2001
    Publication date: October 25, 2001
    Applicant: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 6172013
    Abstract: Lubricating oil compositions having enhanced friction coefficient and wear properties are provided by compositions of an oil of lubricating viscosity with additives of molybdenum and diesters of aliphatic or aromatic dicarboxylic acids.
    Type: Grant
    Filed: September 17, 1997
    Date of Patent: January 9, 2001
    Assignee: Exxon Chemical Patents Inc
    Inventors: David G. L. Holt, Daniel P. Leta
  • Patent number: 6165951
    Abstract: The present invention relates to a lubricating composition comprising a hydrocarbon lubricant base oil in combination with (a) a phenyl-naphthylamine, (b) a thiophosphate, and (c) a diphenyl amine, preferably in combination with (d) an aspartic acid ester. Further, the invention relates to the use of the lubricating composition for lubricating a combination of a gas turbine and a steam turbine.
    Type: Grant
    Filed: March 10, 1999
    Date of Patent: December 26, 2000
    Assignee: Shell Oil Company
    Inventor: Helmut Leonhardt
  • Patent number: 6001782
    Abstract: An antiwear/extreme pressure composition is disclosed that comprises a metal overbased amine of the structureR.sup.1 R.sup.2 NH(MA).sub.xwherein R.sup.1 and R.sup.2 are each independently hydrogen, or a hydrocarbyl group, amino-substituted hydrocarbyl group, hydroxy-substituted hydrocarbyl group, alkoxy-substituted hydrocarbyl group or amino groups wherein the hydrocarbyl group contains from 4 to 50 carbon atoms, provided that R.sup.1 and R.sup.2 are not both hydrogen, M is a metal, A is carbonate, sulfite, sulfate, thiosulfate, phosphite, phosphate, or mixtures thereof, and x has a value of from 1.1 to 40;wherein said metal overbased amine is reacted with carbon disulfide to form a sulfur derivative of a metal overbased amine, an epoxide followed by phosphorus pentoxide to form a phosphorus derivative of a metal overbased amine or wherein the sulfur derivative is further reacted with an epoxide followed by phosphorus pentoxide to form a sulfur and phosphorus derivative of a metal overbased amine.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: December 14, 1999
    Assignee: The Lubrizol Corporation
    Inventor: Nai Z. Huang
  • Patent number: 5821374
    Abstract: A process for oxidizing primary and secondary alcohols to the corresponding aldehydes and ketones is disclosed. The oxidation is carried out by reacting the primary or secondary alcohol with an organic N-chloro compound oxidizing agent in the presence of a catalyst of the formula: ##STR1## wherein the substituent groups are as defined in the specification.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: October 13, 1998
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Christian-Johannes Jenny, Bruno Lohri, Markus Schlageter
  • Patent number: 5767046
    Abstract: A hydrocarbon composition functionalized via the Koch reaction which is the reaction product of at least one hydrocarbon having a number average molecular weight of less than 500 and at least one ethylenic double bond per molecule, with carbon monoxide and a nucleophilic trapping agent. The hydrocarbon is usefully functionalized and derivatized, producing, in particular, lubricants suitable for use in two-cycle engines.
    Type: Grant
    Filed: May 15, 1997
    Date of Patent: June 16, 1998
    Assignee: Exxon Chemical Company
    Inventors: Joseph V. Cusumano, William D. Diana, William B. Eckstrom, Jacob I. Emert, Keith R. Gorda, Michael J. Keenan, Richard H. Schlosberg
  • Patent number: 5736490
    Abstract: An automotive lubricant composition comprises a white oil basestock and at least one polyisoalkylene compound. The polyisoalkylene, e.g. polyisobutylene, acts as an antioxidant. The lubricant is used, for example, as an engine oil, gear oil or automatic transmission fluid. The lubricant may contain one or more additional antioxidants and other lubricant additives.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: April 7, 1998
    Assignee: Exxon Research and Engineering Company
    Inventors: Alain Gabriel Bouffet, Marcel Alphonse Ostyn
  • Patent number: 5726132
    Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: March 10, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
  • Patent number: 5712230
    Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: January 27, 1998
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5705458
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), G.sup.1 and G.sup.2 are independently R, OR, SR or NRR wherein each R is independently a hydrocarbyl group, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: January 6, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Roby, James A. Supp, William D. Abraham, John S. Manka
  • Patent number: 5693598
    Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.
    Type: Grant
    Filed: September 3, 1996
    Date of Patent: December 2, 1997
    Assignee: The Lubrizol Corporation
    Inventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
  • Patent number: 5674820
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: October 7, 1997
    Assignee: The Lubrizol Corporation
    Inventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton
  • Patent number: 5643859
    Abstract: A dispersant derivatized from a functionalized hydrocarbon and a polyamine having one primary amine and 1-10, preferably 3-8 secondary or tertiary amines; preferably where said functionalized hydrocarbon is a Koch-derived hydrocarbon.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: July 1, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Antonio Gutierrez, Jacob I. Emert, James P. Stokes, Warren A. Thaler, William D. Diana, Keith R. Gorda, William B. Eckstrom, David C. Dankworth, Joseph V. Cusumano
  • Patent number: 5629434
    Abstract: A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least one ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.
    Type: Grant
    Filed: September 25, 1995
    Date of Patent: May 13, 1997
    Assignee: Exxon Chemical Patents Inc
    Inventors: Joseph V. Cusumano, William D. Diana, Jacob Emert, Keith R. Gorda, Richard H. Schlosberg, David A. Young, William B. Eckstrom, Edris E. Manry, Michael J. Kennan
  • Patent number: 5605880
    Abstract: A lubricating oil composition is provided which is obtained by containing in (A) a base oil in which the content of the aromatic ingredients is 3.0% by weight or less, N is 50 ppm by weight or less, S is 50 ppm by weight, and the viscosity is 2.0-50.0 mm.sup.2 /s, based on the total weight of the composition, (B) 0.05-2.0% by weight of alkyldiphenylamine(s) and/or phenyl-.alpha.-naphthylamine(s) and (C) MoDTC of C.sub.8-23 and/or C.sub.3-18 in an amount of 50-2,000 ppm by weight in terms of the amount of molybdenum. Such a lubricating oil composition has high heat-resistant properties, a high stability to oxidation, and improved friction characteristics, and is suitably used especially as a lubricating oil for internal combustion engines.
    Type: Grant
    Filed: February 9, 1996
    Date of Patent: February 25, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Katsuya Arai, Hirotaka Tomizawa