Organic -c(=x)x- Compound, Wherein The Xs Are The Same Or Diverse Chalcogens, With At Least One X Being Sulfur Patents (Class 508/443)
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Patent number: 10377963Abstract: A lubricating oil composition and method of operating a boosted internal combustion engine. The lubricating oil composition is formulated to be resistant to turbocharger deposit formation in the boosted internal combustion engine, as shown by its ability to ensure a TCO Temperature Increase of less than 9.0% as measured using the 2015 version of the General Motors Dexos1® Turbocharger Coking Test. The lubricating oil composition may also have a low NOACK volatility, as measured by the method of ASTM D-5800 at 250° C.Type: GrantFiled: January 18, 2017Date of Patent: August 13, 2019Assignee: Afton Chemical CorporationInventors: Kongsheng Yang, Kristin Fletcher, William Y. Lam, Jeremy Styer
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Publication number: 20130210688Abstract: The invention provides a lubricating grease composition with a worked penetration of 400 to 500 for a machine tool equipped with an automatic lubricator, containing a base oil having a kinematic viscosity at 40° C. of 10 to 200 mm2/s and 0.1 to 10 mass % of solid particles insoluble in the base oil. The lubricating grease composition of the invention can be fed using the automatic lubricator attached to the machine tool, and can prevent the stick-slip from occurring on the sliding lubrication portion of the machine tool.Type: ApplicationFiled: October 26, 2011Publication date: August 15, 2013Applicant: KYODO YUSHI CO., LTDInventors: Takayuki Ariyasu, Daming Dong, Hiroshi Ozeki, Minoru Namiki, Terasu Yoshinari
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Patent number: 8293689Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and polymer with pendant groups. The invention further provides for a method of controlling viscosity index by supplying to an oil of lubricating viscosity the polymer with pendant groups.Type: GrantFiled: May 7, 2007Date of Patent: October 23, 2012Assignee: The Lubrizol CorporationInventors: Bryan A. Grisso, Mark R. Baker, Daniel C. Visger, Marina Baum, Barton J. Schober, Calvin A. James
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Patent number: 8268760Abstract: The anti-wear and anti-friction performance of a lubricating oil is improved by the addition thereto of an additive amount of ionic liquids.Type: GrantFiled: February 5, 2010Date of Patent: September 18, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Jacob Joseph Habeeb, Jessica Lee Prince, Michael Eugene Landis
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Patent number: 8158565Abstract: The present invention provides a molybdenum pentakis-alkylxanthate having general formula (1) which is indicated below. In this formula R1 to R5 each represent a group individually selected from linear chain or branched alkyl groups which have from 1 to 30 carbon atoms.Type: GrantFiled: February 1, 2008Date of Patent: April 17, 2012Assignee: Shell Oil CompanyInventors: Eiji Nagatomi, Noriaki Shinoda, Yoshihiko Aihara
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Publication number: 20100227783Abstract: The anti-wear and anti-friction performance of a lubricating oil is improved by the addition thereto of an additive amount of ionic liquids.Type: ApplicationFiled: February 5, 2010Publication date: September 9, 2010Inventors: Jacob Joseph Habeeb, Jessica Lee Prince, Michael Eugene Landis
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Patent number: 7772170Abstract: Antimony dithiocarbamate is known to provide extreme pressure (EP) protection in lubricating compositions, such as grease. However, there is a desire to reduce the amount of antimony used in such compositions, while still maintaining acceptable EP performance. It has now been found by using small amounts of either ammonium dithiocarbamate or zinc dithiocarbamate in combination with the antimony dithiocarbamate (SbDTC), a lower amount of SbDTC can be used in the lubricating composition while still maintaining excellent or exceptional EP protection. To counteract the corrosive effects of the SbDTC and ammonium dithiocarbamate composition, it has been found that compounds containing a carboxylic acid group are effective in avoiding copper corrosion.Type: GrantFiled: February 10, 2006Date of Patent: August 10, 2010Assignee: R.T. Vanderbilt Company, Inc.Inventors: Ronald J. Hiza, Gaston A. Aguilar, Steven G. Donnelly, Francis S. Cheng, Ronald J. Tepper
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Publication number: 20100197537Abstract: A lubricant composition with improved antioxidant capability is provided by way of an additive composition containing a metal free sulfur-containing compound, an aromatic amine, and a hindered amine. Particularly effective metal-free sulfur-containing compounds include ashless dithiocarbamates, such as methylenebis(dibutyldithiocarbamate), and sulfurized fatty acids.Type: ApplicationFiled: January 28, 2010Publication date: August 5, 2010Applicant: R.T. VANDERBILT COMPANY, INC.Inventors: KEVIN J. CHASE, BRIAN W. STUNKEL
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Publication number: 20100144570Abstract: The present invention provides a molybdenum pentakis-alkylxanthate having general formula (1) which is indicated below. In this formula R1 to R5 each represent a group individually selected from linear chain or branched alkyl groups which have from 1 to 30 carbon atoms.Type: ApplicationFiled: February 1, 2008Publication date: June 10, 2010Inventors: Eiji Nagatomi, Noriaki Shinoda, Yoshihiko Aihara
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Publication number: 20100113314Abstract: To provide a gear oil composition containing a base oil, and compounded therein, (A) an ashless dithiocarbamate compound and (B) an ester of pentaerythritol and a C12 to C20 branched fatty acid, the ester having a hydroxyl value of 20 to 100 mg KOH/g. The gear oil composition has a high transmission efficiency and shows both of resistance to sludge formation and extreme pressure property.Type: ApplicationFiled: March 19, 2008Publication date: May 6, 2010Applicant: Idemitsu Kosan Co., LtdInventors: Tahei Okada, Shigeo Hara
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Patent number: 7683016Abstract: The inventive composition comprises compatible combinations of methyl esters of fatty acids or triglycerides and polar non-chlorine extreme pressure additives, the composition being either (a) a working strength straight oil, (b) a soluble oil concentrate dilutable to a working strength soluble oil, the composition when at working strength effectively lubricating metal parts during high performance metalworking, and providing environmental and safety advantages.Type: GrantFiled: August 13, 2002Date of Patent: March 23, 2010Assignee: United Soybean BoardInventors: James P. King, Neil M. Canter
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Patent number: 7678746Abstract: A lubricating composition containing (a). at least 3 weight percent of an overbased sulphonate detergent with a metal ratio of 12.5:1 to 40:1; (b). at least 1.5 weight percent of a sulphur containing phenate detergent with a metal ratio of not more than 2.5; and (c). an oil of lubricating viscosity, wherein the sulphur containing phenate contains oligomers of hydrocarbyl phenol with at least 50 wt % of said oligomers in the form of the tetramer or higher oligomers. The composition is suitable for internal combustion engines, particularly marine diesel applications to provide improved cleanliness decreased cylinder wear and reduced deposits.Type: GrantFiled: May 13, 2005Date of Patent: March 16, 2010Assignee: The Lubrizol CorporationInventors: James P. Roski, Richard Leahy, Stephen J. Cook, Alexandra Mayhew
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Publication number: 20090016652Abstract: The lubricant composition of this invention comprises a base oil and an additive, which is at least one selected from the group consisting of an organic sulfonate, a carboxylate, a thiocarbamate and a thiophosphoric acid ester salt. The lubricant composition can effectively suppress hydrogen embrittlement-caused flaking of an element, such as a rolling bearing, a sliding bearing, a gear, a ball thread, a linear guide, a linear bearing, a cam and various joints in a high concentration hydrogen environment. The invention provides also a rolling bearing, a sliding bearing, a gear, a ball thread, a linear guide, a linear bearing, a cam and various joints using the lubricant composition.Type: ApplicationFiled: September 29, 2008Publication date: January 15, 2009Inventors: Toshiaki ENDO, Da Ming Dong, Yutaka Imai
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Publication number: 20090003742Abstract: An object of the invention is to provide a grease composition capable of keeping a good lubrication condition for a long period of time even when water has mixed therein, thereby inhibiting white structure flaking and corrosion. Another object is to provide a vehicular hub unit bearing which hardly suffers from white structure flaking and corrosion even when used in an environment where water may penetrate into it and which therefore has a long life. The invention provides a rolling bearing with, sealed up therein, a grease composition containing a waterproof film-forming additive added thereto; a grease composition for hub unit bearings, containing a base oil that comprises at least one of mineral oil and synthetic oil as the main ingredient thereof, and a thickener and a flaking inhibitor; and a vehicular hub unit bearing with the grease composition sealed up therein.Type: ApplicationFiled: January 24, 2006Publication date: January 1, 2009Applicants: NSK LTD., KYODO YUSHI CO., LTD.Inventors: Shinya Nakatani, Jun Kuraishi, Tomoaki Matsumoto, Minoru Namiki, Ryo Aida, Toshiaki Endo
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Publication number: 20080194439Abstract: A non-chlorine type lubricant in which a sulfur type extreme pressure additive, an organic zinc compound, a calcium type additive, and an ester compound are blended with a base oil for the lubricant, and having a kinetic viscosity from 5 to 50 mm2/s at 40° C.Type: ApplicationFiled: February 1, 2008Publication date: August 14, 2008Applicant: TOYOTA BOSHOKU KABUSHIKI KAISHAInventors: Mami KATO, Teruo FUKAYA
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Patent number: 7183241Abstract: A lubricating oil with very low phosphorus content, and having long life as evidenced by a reduction in viscosity increase, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents, at least a zinc dialkyldithiocarbamate and a zinc dialkyldithiophosphate antiwear additive and at least a dihydrocarbylthiocarbamoyl.Type: GrantFiled: September 19, 2003Date of Patent: February 27, 2007Assignee: ExxonMobil Research and Engineering CompanyInventor: Stanley James Cartwright
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Patent number: 6887295Abstract: The present invention relates to improved metallurgical powder compositions that incorporate solid lubricants, methods for preparing and using the same, and methods of making compacted parts. Ejection properties, such as stripping pressure and sliding pressure, of compacted parts can be improved by using the solid lubricants. The solid lubricants contain functionalized polyalkylene glycol lubricants that contain a phosphate group, phosphite group, hypophosphate group, hypophosphite group, polyphosphate group, thiophosphate group, dithiophosphate group, thiocarbamate group, dithiocarbamate group, borate group, thiosulfate group, sulfate group, a sulfonate group or combinations thereof.Type: GrantFiled: October 25, 2002Date of Patent: May 3, 2005Assignee: Hoeganaes CorporationInventors: George Poszmik, Sydney Luk
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Publication number: 20040248745Abstract: An ashless natural gas engine lubricating composition which has enhanced resistance to oxidation, nitration and viscosity increase employs as additives in a lubricating oil basestock a combination of phenolic and alkylthiocarbamoyl antioxidants and an ashless phosphorous antiwear additive.Type: ApplicationFiled: April 23, 2004Publication date: December 9, 2004Inventor: S. James Cartwright
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Patent number: 6767872Abstract: A lubricant compound for use for both boundary and elastohydrodynamic lubrication utilize a hydrocarbon boundary lubricant linked to one or more fluorocarbon elastohydrodynamic lubricants and may be employed alone or as an additive. The lubricant compound lubricates surfaces on which it is disposed over a range of conditions. The boundary lubricant and the elastohydrodynamic lubricant are substituted such that they react with and/or provide desirable lubrication properties for particular surfaces.Type: GrantFiled: May 10, 2002Date of Patent: July 27, 2004Assignee: The Charles Stark Draper Laboratory, Inc.Inventor: John R. Williams
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Publication number: 20040110646Abstract: A long life lubricating oil, as evidenced by a reduction in oil thickening, oxidation and nitration, comprises a major amount of a base oil of lubricating viscosity and a minor amount of a mixture of neutral and overbased metallic detergents and at least one trinuclear molybdenum compound.Type: ApplicationFiled: October 10, 2003Publication date: June 10, 2004Inventor: Stanley James Cartwright
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Publication number: 20040048753Abstract: Soot induced kinematic viscosity increase of lubricating oil compositions for diesel engines equipped with EGR systems can be ameliorated by selection of viscosity modifier, lubricating oil flow improvers, detergents and/or dispersants.Type: ApplicationFiled: September 10, 2002Publication date: March 11, 2004Inventors: Andrew J.D. Ritchie, Jai G. Bansal, Jacob Emert, Glen P. Fetterman, Antonio Gutierrez, Matthew D. Irving, Christopher J. Locke, Michael T. Minotti
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Publication number: 20030096713Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity with an iodine number less than about 9, (A) one or more antioxidant, and (B) from about 0.01% to about 3% by weight of at least one dispersant or detergent, wherein the total amount of antioxidant is at least about 2% by weight. The additives are useful act controlling oxidation of lubricants. Further, these lubricants have reduced viscosity increase caused by oxidation, while maintaining favorable carbon/varnish ratings.Type: ApplicationFiled: September 5, 1996Publication date: May 22, 2003Inventors: ERIC R. SCHNUR, ROBERT C. RICHARDSON, JAMES J. SCHWIND
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Publication number: 20030040442Abstract: The invention aims to provide a rolling bearing that secures a sufficient bearing life economically even when used under such conditions that water from the outside or water formed by moisture condensation may seep into the lubricant or the bearing is affected by the vibrations, and particularly a rolling bearing suited to the electric parts and accessaries of au automobile engine, such as an alternator. To accomplish the object, the hydrogen ion exponent pH of the grease sealed into the inside of the bearing is adjusted in a range of from 7 to 13. For the same purpose, the hydrogen ion exponent pH of the grease is adjusted in a range of from 5 to 13 where a prescribed amount of an organic metal salt or ADTC is added to the grease, where a prescribed amount of an inorganic compound having an average particle size of 2 □m or smaller is added to the grease, or where a diurea compound containing an aromatic amine or a mixture of the diurea compound is added to the grease as a thickener.Type: ApplicationFiled: March 7, 2002Publication date: February 27, 2003Applicant: NSK LTD.Inventors: Atsushi Yokouchi, Youichi Matsumoto, Kenichi Iso, Kouichi Hachiya, Hideki Koizumi, Michiharu Naka
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Publication number: 20020119895Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and (A) an antiwear improving amount of at least one molybdenum containing composition, and (B) at least one member selected from the group consisting of (i) at least one borated overbased metal salt of an acidic organic compound, provided that (A) and (Bi) are not the same, (ii) a combination of (a) at least one organic polysulfide or at least one ashless dithiocarbamate containing composition and (b) at least one component selected from the group consisting of a metal thiophosphate, a phosphoric acid ester or salt thereof, a phosphorus-containing carboxylic acid, ester, ether, or amide, a borated dispersant, an alkali metal borate, a borated fatty amine, a borated phospholipid, a borate ester, and mixtures thereof, and (iii) a combination of (i) and (ii).Type: ApplicationFiled: May 26, 1995Publication date: August 29, 2002Inventors: SUSAN P. COOK, JAMES J. SCHWIND, BERNARD CONSTANS, HENRI BOURGOGNON
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Publication number: 20020111278Abstract: An aqueous lubricant is provided which by simple application onto metal surfaces forms lubricating films required for heavy working of metals, and which contains no oil. The aqueous lubricant is prepared by suspending or dispersing a metal chelate compound in water with a surfactant or the like. The metal chelate compound has a polydentate or multidentate chelate ligand, in which at least one of the coordinating atoms is sulfur, coordinated to the coordination site of at least one metal species selected from among zinc, manganese, iron, molybdenum, tin and antimony. When applied onto metal surfaces, the aqueous lubricant forms effective lubricating films on the metal surfaces. The lubricating films contain sulfur as coordinating atoms and therefore, extreme pressure produces sulfur radicals through decomposition by tribo-chemical reactions. The sulfur radicals are highly reactive and react rapidly with the metal surface to produce metal sulfides with a lubricating effect.Type: ApplicationFiled: November 19, 2001Publication date: August 15, 2002Inventors: Heijiro Ojima, Masahiko Takeuchi, Fumio Ikesue, Noritoshi Kashimura, Fumio Kawahara, Mitsuru Tomono
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Publication number: 20020103089Abstract: A lubricant composition for a surface treatment of a steel filament comprises at least one specified compound as a lubricant component and a rubber-steel filament composite body is prepared by using a steel filament treated with the lubricant composition.Type: ApplicationFiled: June 29, 2001Publication date: August 1, 2002Applicant: BRIDGESTONE CORPORATIONInventors: Yasuo Fukushima, Hajime Kondo
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Publication number: 20020032293Abstract: A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions.Type: ApplicationFiled: August 7, 2001Publication date: March 14, 2002Inventors: Charles P. Bryant, Bryan A. Grisso, Robert Cantiani
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Publication number: 20010034308Abstract: The invention relates to additives for improving lubricating properties of fuel oils, comprisingType: ApplicationFiled: March 16, 2001Publication date: October 25, 2001Applicant: Clariant GmbHInventors: Matthias Krull, Werner Reimann
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Patent number: 6172013Abstract: Lubricating oil compositions having enhanced friction coefficient and wear properties are provided by compositions of an oil of lubricating viscosity with additives of molybdenum and diesters of aliphatic or aromatic dicarboxylic acids.Type: GrantFiled: September 17, 1997Date of Patent: January 9, 2001Assignee: Exxon Chemical Patents IncInventors: David G. L. Holt, Daniel P. Leta
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Patent number: 6165951Abstract: The present invention relates to a lubricating composition comprising a hydrocarbon lubricant base oil in combination with (a) a phenyl-naphthylamine, (b) a thiophosphate, and (c) a diphenyl amine, preferably in combination with (d) an aspartic acid ester. Further, the invention relates to the use of the lubricating composition for lubricating a combination of a gas turbine and a steam turbine.Type: GrantFiled: March 10, 1999Date of Patent: December 26, 2000Assignee: Shell Oil CompanyInventor: Helmut Leonhardt
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Patent number: 6001782Abstract: An antiwear/extreme pressure composition is disclosed that comprises a metal overbased amine of the structureR.sup.1 R.sup.2 NH(MA).sub.xwherein R.sup.1 and R.sup.2 are each independently hydrogen, or a hydrocarbyl group, amino-substituted hydrocarbyl group, hydroxy-substituted hydrocarbyl group, alkoxy-substituted hydrocarbyl group or amino groups wherein the hydrocarbyl group contains from 4 to 50 carbon atoms, provided that R.sup.1 and R.sup.2 are not both hydrogen, M is a metal, A is carbonate, sulfite, sulfate, thiosulfate, phosphite, phosphate, or mixtures thereof, and x has a value of from 1.1 to 40;wherein said metal overbased amine is reacted with carbon disulfide to form a sulfur derivative of a metal overbased amine, an epoxide followed by phosphorus pentoxide to form a phosphorus derivative of a metal overbased amine or wherein the sulfur derivative is further reacted with an epoxide followed by phosphorus pentoxide to form a sulfur and phosphorus derivative of a metal overbased amine.Type: GrantFiled: December 17, 1998Date of Patent: December 14, 1999Assignee: The Lubrizol CorporationInventor: Nai Z. Huang
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Patent number: 5821374Abstract: A process for oxidizing primary and secondary alcohols to the corresponding aldehydes and ketones is disclosed. The oxidation is carried out by reacting the primary or secondary alcohol with an organic N-chloro compound oxidizing agent in the presence of a catalyst of the formula: ##STR1## wherein the substituent groups are as defined in the specification.Type: GrantFiled: November 12, 1996Date of Patent: October 13, 1998Assignee: Hoffmann-La Roche Inc.Inventors: Christian-Johannes Jenny, Bruno Lohri, Markus Schlageter
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Patent number: 5767046Abstract: A hydrocarbon composition functionalized via the Koch reaction which is the reaction product of at least one hydrocarbon having a number average molecular weight of less than 500 and at least one ethylenic double bond per molecule, with carbon monoxide and a nucleophilic trapping agent. The hydrocarbon is usefully functionalized and derivatized, producing, in particular, lubricants suitable for use in two-cycle engines.Type: GrantFiled: May 15, 1997Date of Patent: June 16, 1998Assignee: Exxon Chemical CompanyInventors: Joseph V. Cusumano, William D. Diana, William B. Eckstrom, Jacob I. Emert, Keith R. Gorda, Michael J. Keenan, Richard H. Schlosberg
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Patent number: 5736490Abstract: An automotive lubricant composition comprises a white oil basestock and at least one polyisoalkylene compound. The polyisoalkylene, e.g. polyisobutylene, acts as an antioxidant. The lubricant is used, for example, as an engine oil, gear oil or automatic transmission fluid. The lubricant may contain one or more additional antioxidants and other lubricant additives.Type: GrantFiled: April 24, 1996Date of Patent: April 7, 1998Assignee: Exxon Research and Engineering CompanyInventors: Alain Gabriel Bouffet, Marcel Alphonse Ostyn
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Patent number: 5726132Abstract: This invention relates to compositions for improving fuel efficiency in internal combustion engines. The composition comprises a lubricant having an oil of lubricating viscosity and (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate.Type: GrantFiled: February 28, 1997Date of Patent: March 10, 1998Assignee: The Lubrizol CorporationInventors: Stephen H. Roby, James A. Supp, John S. Manka, William D. Abraham
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Patent number: 5712230Abstract: This invention relates to a composition, comprising: (AT) reaction products of compounds represented by the formula (A)and compounds selected to reduce the polysulfide components of (A); and ##STR1## wherein in Formula (A), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3 (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol.Type: GrantFiled: March 10, 1997Date of Patent: January 27, 1998Assignee: The Lubrizol CorporationInventors: William D. Abraham, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5705458Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), G.sup.1 and G.sup.2 are independently R, OR, SR or NRR wherein each R is independently a hydrocarbyl group, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms. In one embodiment, the inventive composition further comprises (C) a phosphorus compound. In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxylic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.Type: GrantFiled: October 24, 1996Date of Patent: January 6, 1998Assignee: The Lubrizol CorporationInventors: Stephen H. Roby, James A. Supp, William D. Abraham, John S. Manka
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Patent number: 5693598Abstract: This invention relates to a low-viscosity lubricating oil and functional fluid compositions, comprising: a major amount of an oil having a kinematic viscosity of up to about 4 cST at 100.degree. C.; and a minor antiwear amount of(A) a compound represented by the formulaR.sup.1 R.sup.2 N--C(X)S--(CR.sup.3 R.sup.4).sub.a Z (A-I)wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrogen or hydrocarbyl groups, provided that at least one of R.sup.1 and R.sup.2 is a hydrocarbyl group; X is O or S; a is zero, 1 or 2; and Z is a hydrocarbyl group, a hetero group, a hydroxy hydrocarbyl group, an activating group, or a --(S).sub.b C(X)--NR.sup.1 R.sup.2 group wherein b is zero, 1 or 2; provide that when a is 2, Z is an activating group; and when a is zero, Z can be an ammonium, amine or metal cation. In one embodiment this composition further comprises (B) a phosphorus compound.Type: GrantFiled: September 3, 1996Date of Patent: December 2, 1997Assignee: The Lubrizol CorporationInventors: William D. Abraham, Brent R. Dohner, John S. Manka, Stephen H. Roby, James A. Supp
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Patent number: 5674820Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula ##STR1## wherein in Formula (A-I), R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently hydrocarbyl groups, X.sup.1 and X.sup.2 are independently O or S, and n is zero to 3; and (B) an acylated nitrogen-containing compound having a substituent of at least 10 aliphatic carbon atoms, In one embodiment, the inventive composition further comprises (C) a second phosphorus compound other than (A), said second phosphorus compound being a phosphorus acid, phosphorus acid ester, phosphorus acid salt, or derivative thereof, In one embodiment, the inventive composition further comprises (D) an alkali or alkaline earth metal salt of an organic sulfur acid, carboxytic acid or phenol. In one embodiment, the inventive composition further comprises (E) a thiocarbamate. These compositions are useful in providing lubricating compositions and functional fluids with enhanced antiwear properties.Type: GrantFiled: September 5, 1996Date of Patent: October 7, 1997Assignee: The Lubrizol CorporationInventors: John S. Manka, William D. Abraham, Stephen H. Roby, James A. Supp, Craig D. Tipton
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Patent number: 5643859Abstract: A dispersant derivatized from a functionalized hydrocarbon and a polyamine having one primary amine and 1-10, preferably 3-8 secondary or tertiary amines; preferably where said functionalized hydrocarbon is a Koch-derived hydrocarbon.Type: GrantFiled: June 17, 1994Date of Patent: July 1, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Antonio Gutierrez, Jacob I. Emert, James P. Stokes, Warren A. Thaler, William D. Diana, Keith R. Gorda, William B. Eckstrom, David C. Dankworth, Joseph V. Cusumano
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Patent number: 5629434Abstract: A Koch functionalized product which is the reaction product of at least one polymer having a number average molecular weight of at least 500 and at least one ethylenic double bond per polymer chain, with carbon monoxide and a nucleophilic trapping agent. The invention includes functionalized polymer, derivatives thereof and methods of making the same.Type: GrantFiled: September 25, 1995Date of Patent: May 13, 1997Assignee: Exxon Chemical Patents IncInventors: Joseph V. Cusumano, William D. Diana, Jacob Emert, Keith R. Gorda, Richard H. Schlosberg, David A. Young, William B. Eckstrom, Edris E. Manry, Michael J. Kennan
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Patent number: 5605880Abstract: A lubricating oil composition is provided which is obtained by containing in (A) a base oil in which the content of the aromatic ingredients is 3.0% by weight or less, N is 50 ppm by weight or less, S is 50 ppm by weight, and the viscosity is 2.0-50.0 mm.sup.2 /s, based on the total weight of the composition, (B) 0.05-2.0% by weight of alkyldiphenylamine(s) and/or phenyl-.alpha.-naphthylamine(s) and (C) MoDTC of C.sub.8-23 and/or C.sub.3-18 in an amount of 50-2,000 ppm by weight in terms of the amount of molybdenum. Such a lubricating oil composition has high heat-resistant properties, a high stability to oxidation, and improved friction characteristics, and is suitably used especially as a lubricating oil for internal combustion engines.Type: GrantFiled: February 9, 1996Date of Patent: February 25, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Katsuya Arai, Hirotaka Tomizawa