Olefin Or Alpha, Beta-olefinically Unsaturated Carboxylate Is An Additional Monomer Of The Polymer (e.g., Fumarate-ethylene Or Fumarate-acrylate Copolymers, Etc.) Patents (Class 508/468)
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Patent number: 11525101Abstract: The invention relates to a lubricant composition comprising: at least one base oil for coming into contact with food, selected from the groups II, III or V according to the categories defined in the API classification or the equivalents thereof according to the ATIEL classification; at least one hydrogenated polyisobutylene; and at least one ester polymer.Type: GrantFiled: December 12, 2017Date of Patent: December 13, 2022Assignee: TOTAL MARKETING SERVICESInventors: Marie-Noëlle Valla, Julien Benito
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Patent number: 11261398Abstract: A hydraulic fluid includes an oil of lubricating viscosity and at least 2 wt. % of an ester of a carboxy group-containing interpolymer comprising units derived from a vinyl aromatic monomer and units derived from a carboxylic acid monomer. The interpolymer also contains nitrogen functionality. The hydraulic fluid is at least substantially free of polyacrylates and polymethacrylates.Type: GrantFiled: April 19, 2017Date of Patent: March 1, 2022Assignee: The Lubrizol CorporationInventors: Daniel J. Knapton, David Cressey, Daniel C. Visger
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Patent number: 11193053Abstract: An oil composition includes an oil and an effective amount of a wax inhibitor that includes at least one modified alpha-olefin maleic anhydride copolymer of the formula: wherein R1 is selected from hydrogen or hydrocarbyl groups containing 12-60 carbon atoms and an average carbon atom number of R1, if not hydrogen, in the copolymer is in a range from 20 to 32, R2 is selected from hydrocarbyl groups containing 6-12 carbon atoms, and n is a number of repeating units ranging from 1 to 100.Type: GrantFiled: December 27, 2017Date of Patent: December 7, 2021Assignee: BL Technologies, Inc.Inventors: Xiaoan Xie, Wenqing Peng, Kelly Scott Chichak
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Patent number: 11186788Abstract: Disclosed are methods and apparatuses for separating a wax product from a hydrocarbon feedstream by a) conducting a hydrocarbon feedstream to a membrane separation zone; b) retrieving at least one retentate product stream from the first side of the membrane element; c) retrieving at least one permeate product stream having a wax phase and an oil phase from a second side of the membrane element, wherein a pour point of the wax phase of the permeate product stream is higher than a pour point of the oil phase of permeate product stream; and d) separating a wax product from the wax phase of the permeate product stream.Type: GrantFiled: June 21, 2019Date of Patent: November 30, 2021Assignee: ExxonMobil Research and Engineering CompanyInventors: Benjamin A. McCool, Yogesh V. Joshi, Dhaval A. Bhandari, Roberto Garcia, Randall D. Partridge
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Patent number: 10145417Abstract: A ball bearing is filled with a grease composition. The grease composition contains a synthetic oil other than a synthetic hydrocarbon oil, a synthetic hydrocarbon oil, a mineral oil, and a urea compound. The synthetic oil other than the synthetic hydrocarbon oil is contained in an amount of 10% by mass or more and 60% by mass or less when the total of the synthetic oil other than the synthetic hydrocarbon oil, the synthetic hydrocarbon oil and the mineral oil is taken as 100% by mass.Type: GrantFiled: June 29, 2017Date of Patent: December 4, 2018Assignee: MINEBEA MITSUMI INC.Inventor: Motojiro Tsuna
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Patent number: 9624453Abstract: An object of the present invention is to provide a lubricating oil composition having a low viscosity and an extremely high viscosity index as well as an excellent shearing stability. The present invention relates to a lubricating oil composition including the following components (A) to (C): (A) a low-viscosity synthetic oil including a compound containing an ether bond in a molecule thereof and having a kinematic viscosity of less than 10 mm2/s as measured at 40° C., in which a ratio of the number of oxygen atoms to the number of carbon atoms as constituents of the compound (O/C ratio) and the kinematic viscosity (mm2/s) of the compound as measured at 40° C. satisfy the following formula (1): Kinematic Viscosity at 40° C.?12?[(O/C ratio)×30]??(1); (B) a high-viscosity synthetic oil as a hydrocarbon-based synthetic oil having a kinematic viscosity of 40 mm2/s or more as measured at 100° C.Type: GrantFiled: July 12, 2013Date of Patent: April 18, 2017Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Yoshitaka Tamoto, Toshihiko Ichihashi, Masato Yokomizo
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Patent number: 8710168Abstract: The present invention is a polymer having structural units, units of formula I, units of formula II and units of either formula IIIa or formula IIIb: The polymer improves the low-temperature properties of fuel oils from petroleum sources and especially from vegetable or animal sources.Type: GrantFiled: December 17, 2010Date of Patent: April 29, 2014Assignee: Infineum International LimitedInventors: Carl Waterson, Christopher J. Booth
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Publication number: 20140113847Abstract: A lubricating composition including a first base stock component including: one or more metallocene catalyzed polyalphaolefins (mPAOs), each mPAO having a kinematic viscosity (Kv100) from 40 cSt to 155 cSt and a viscosity index (VI) from 150 to 207; a second base stock including one or more polyalphaolefins (PAOs), each PAO having a kinematic viscosity (Kv100) less than 10 cSt and a VI from 130 to 145; and a viscosity modifier including a copolymer having units derived from monomers of (i) an ?-olefin and (ii) an ethylenically unsaturated carboxylic acid or derivatives thereof esterified with an alcohol. A lubricant including the above lubricating composition. A method for improving fuel efficiency, while maintaining or improving wear control, load carrying capacity and/or traction reduction in a driveline device, e.g., gears and transmissions, lubricated with a lubricating oil, by using as the lubricating oil the above lubricant.Type: ApplicationFiled: September 24, 2013Publication date: April 24, 2014Applicant: ExxonMobil Research and Engineering CompanyInventors: Willie Allan Givens, Percy Rohinton Kanga, Jared Michael Robillard
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Publication number: 20130310290Abstract: The present invention relates to a copolymer comprising units derived from monomers (i) an ?-olefin and (ii) an ethylenically unsaturated carboxylic acid or derivatives thereof esterified with a primary alcohol branched at the ?- or higher position, wherein the copolymer has a reduced specific viscosity of up to 0.08. The invention further provides for a lubricating composition containing said copolymer. The invention further provides a method and use of controlling viscosity index by supplying to an oil of lubricating viscosity the copolymer with pendant groups. In addition, the copolymer of the present invention may be useful as a base oil replacement.Type: ApplicationFiled: July 25, 2013Publication date: November 21, 2013Applicant: The Lubrizol CorporationInventors: David Price, William Barton, Daniel J. Visger
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Patent number: 8400030Abstract: A dispersant additive composition, a lubricant composition containing the dispersant additive, a transmission containing the dispersant additive, and a method of providing a versatile lubricating fluid. The dispersant includes a reaction product of a hydrocarbyl substituted carboxylic acid or anhydride and an amine. The reaction product has a nitrogen content up to 10,000 ppm by weight, and a boron plus phosphorus to nitrogen ((B+P)/N) weight ratio of from 0:1 to about 0.8:1. The dispersant additive composition is effective to provide an electrical conductivity to a lubricant composition containing the dispersant additive composition and a metal detergent of less than about 1700 pS/m.Type: GrantFiled: June 11, 2012Date of Patent: March 19, 2013Assignee: Afton Chemical CorporationInventors: Hong-Zhi Tang, Mark T. Devlin, Naresh Mathur, Lee D. Saathoff, Timothy J. Henly
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Publication number: 20120329694Abstract: The present invention relates to a lubricating composition containing (a) an oil of lubricating viscosity, (b) a star polymer and (c) a substantially linear polymer with a weight average molecular weight of 45,000 or less. The invention further provides a method of lubricating a mechanical device, typically a manual transmission with the lubricating composition.Type: ApplicationFiled: November 23, 2010Publication date: December 27, 2012Applicant: THE LUBRIZOL CORPORATIONInventors: Andrew Gelder, David Price, Gareth Brown, Simon Evans
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Patent number: 8236741Abstract: Haze formation in heavy Gas-to-Liquids (GTL) base stock is mitigated by the addition to said GTL base stock of one or more particular additives.Type: GrantFiled: November 14, 2008Date of Patent: August 7, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Marc-André Poirier, Charles Lambert Baker, Jr., Nicholas Anthony Hilder, Chung-Lai Wong, Dorothy Wong, legal representative, James William Gleeson, Vera Minak-Bernero
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Patent number: 7942941Abstract: The present invention generally relates to oil compositions, primarily to fuel oil and petroleum compositions produced there from susceptible to wax formation at low temperatures, to polymeric amides for use with such fuel oil compositions, and to methods for their manufacture.Type: GrantFiled: April 5, 2005Date of Patent: May 17, 2011Assignee: Akzo Nobel N.V.Inventors: Rodney Lee Cravey, Stephen L. Mead
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Patent number: 7863390Abstract: Esterified polyalkene/UAR copolymer reaction products useful as (1) a friction modifier for lubricating oils such as automatic transmission fluids to improve torque capacity and anti-shudder durability and for continuous variable transmissions (CVTs), (2) a friction modifier for fuels or (3) a cold flow improver for diesel fuels are provided. The esterified copolymer reaction product may be used as is or can be further derivatized (e.g., by post treatment of the esterified copolymer reaction product with, for example, ethylene carbonate or boric acid).Type: GrantFiled: March 17, 2009Date of Patent: January 4, 2011Assignee: Chevron Oronise Company LLCInventor: Kenneth D. Nelson
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Patent number: 7838569Abstract: The present invention relates to a method of surface cross-linking superabsorbent polymer particles using UV irradiation. The superabsorbent polymer particles for use in the method of the present invention have a relatively high degree of neutralization. Bronsted acids are selectively applied onto the surface of the superabsorbent polymer particles to selectively facilitate a relatively high number of protonated carboxyl groups at the surface of the superabsorbent polymer particles while the relatively high degree of neutralization in the core of the superabsorbent polymer particles remains substantially unaffected.Type: GrantFiled: August 22, 2006Date of Patent: November 23, 2010Assignee: Nippon Shokubai Co., LtdInventors: Andreas Flohr, Torsten Lindner, Yoshiro Mitsukami
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Patent number: 7691797Abstract: The present invention relates to acrylic block copolymers synthesized by a controlled radical process, and their use as thickeners in oil-based compositions. The acrylic copolymers are especially useful as viscosity index improvers in lubricating oil.Type: GrantFiled: October 15, 2004Date of Patent: April 6, 2010Assignee: Arkema Inc.Inventors: Scott Charles Schmidt, Peter Anthony Callais, Noah Eliot Macy, Olivier Guerrett
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Patent number: 7618928Abstract: An oil-soluble lubricating oil additive composition comprising (I) an oil-soluble lubricating oil additive prepared by the process which comprises reacting a copolymer, with at least one ether compound and with at least one aromatic amine and (II) at least one ashless dispersant other than the lubricating oil additive of (I), the method of making the same, a lubricating oil composition comprising the lubricating oil additive composition and a major amount of an oil of lubricating viscosity, and a method of making the same.Type: GrantFiled: August 31, 2005Date of Patent: November 17, 2009Assignee: Chevron Oronite Company LLCInventors: Casey D. Stokes, Willem Van Dam
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Patent number: 7572361Abstract: Lubricant blends and finished gear oils comprising a lubricant base oil fraction derived from highly paraffinic wax, a petroleum derived base oil, and a pour point depressant are provided. The lubricant base oil fraction derived from highly paraffinic wax comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at ?40° C.Type: GrantFiled: December 2, 2004Date of Patent: August 11, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Stephen J. Miller, Joseph M. Pudlak
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Publication number: 20090186787Abstract: Disclosed are lubricant compounds with a good shear stability defined by the loss of the kinematic viscosity at 100° C., containing base oil and a synthetic complex ester, the complex ester having a kinematic viscosity at 40° C. of greater than 400 and up to 50,000 mm2/s and being obtained by reaction of a) polyols and monocarboxylic acids and dicarboxylic acids, or of b) polyols and mono-alcohols and dicarboxylic acids, or of c) polyols and mono-alcohols and monocarboxylic acids and dicarboxylic acids. In addition the use of said lubricant compounds containing the complex esters as oils for vehicle transmission, axle, industrial drives, compressors, turbines or engines is described.Type: ApplicationFiled: June 2, 2007Publication date: July 23, 2009Applicant: Cognis IP Management GmbHInventors: Markus Scherer, Stefan Busch, Jürgen Röder, Rudolf Iking, Dirk Rettemeyer, Vasu Bala
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Publication number: 20090186786Abstract: Haze formation in heavy Gas-to-Liquids (GTL) base stock is mitigated by the addition to said GTL base stock of one or more particular additives.Type: ApplicationFiled: November 14, 2008Publication date: July 23, 2009Inventors: Marc-Andre Poirier, Charles Lambert Baker, JR., Nicholas Anthony Hilder, Dorothy Wong, Chung-Lai Wong, James William Gleeson, Vera Minak-Bernero
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Patent number: 7473345Abstract: Lubricant blends and finished gear oils comprising a lubricant base oil fraction derived from highly paraffinic wax, a petroleum derived base oil, and a pour point depressant are provided. The lubricant base oil fraction derived from highly paraffinic wax comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at ?40° C.Type: GrantFiled: December 2, 2004Date of Patent: January 6, 2009Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Stephen J. Miller, Joseph M. Pudlak
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Publication number: 20080312117Abstract: A copolymer suitable for the use in or as a lubricant, which copolymer includes an ?-olefin and a di-ester of an ?,? ethylenically unsaturated dicarboxylic acid. More particularly, a high molecular weight lubricating oil base fluid or additive includes a copolymer of ?-olefins with chain lengths, for example from 12 to 18 carbon atoms, and a di-ester of an ?,? ethylenically unsaturated dicarboxylic acid, with a C3-C7 alkylic alcohol, for example n-butanol, as an esterifying component, which is compatible with other low polar lubricating oil base fluids.Type: ApplicationFiled: June 10, 2008Publication date: December 18, 2008Applicant: ITALMATCH CHEMICALS S.P.A.Inventors: Uwe Wallfahrer, Lorenzo Soldavini
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Patent number: 7384536Abstract: Lubricant blends and finished gear oils comprising a Fischer-Tropsch derived lubricant base oil fraction, a petroleum derived base oil, and a pour point depressant are provided. The Fischer-Tropsch derived lubricant base oil fraction comprises less than 0.30 weight percent aromatics, greater than 5 weight percent molecules with cycloparaffinic functionality, and a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 15. The petroleum derived base oils comprises greater than 90 weight percent saturates and less than 300 ppm sulfur and is preferably selected from the group consisting of a Group II base oil, a Group III base oil, and mixtures thereof. These lubricant blends have surprising low Brookfield viscosities at ?40° C.Type: GrantFiled: May 19, 2004Date of Patent: June 10, 2008Assignee: Chevron U.S.A. Inc.Inventors: John M. Rosenbaum, Stephen J. Miller, Joseph M. Pudlak
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Publication number: 20080113889Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one ether compound, with at least one aliphatic compound, and with at least one aromatic compound.Type: ApplicationFiled: October 27, 2006Publication date: May 15, 2008Inventors: William R. Ruhe, Casey D. Stokes
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Publication number: 20080103075Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one ether compound and with at least one aromatic compound.Type: ApplicationFiled: October 27, 2006Publication date: May 1, 2008Inventors: Casey D. Stokes, William R. Ruhe
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Publication number: 20080103076Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one polyether aliphatic amine compound.Type: ApplicationFiled: October 27, 2006Publication date: May 1, 2008Inventors: William R. Ruhe, Casey D. Stokes
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Publication number: 20080103074Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises reacting a copolymer, with at least one polyether aromatic compound.Type: ApplicationFiled: October 27, 2006Publication date: May 1, 2008Inventors: Casey D. Stokes, William R. Ruhe
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Patent number: 7329635Abstract: A crude oil composition wherein fouling has been mitigating and a method for mitigating crude oil fouling. The composition includes crude oil and an improved dispersant material for mitigating fouling which comprises a reaction product of a polyamine and a polyisobutylene succinyl anhydride made with a polyisobutylene having a vinylidene double bond content of at least 50%. The reaction product has an active nitrogen atom content of at least about 2% by weight. The reaction product is prepared by thermally reacting the polyisobutylene with maleic anhydride to produce said polyisobutylene succinyl anhydride and thereafter reacting the polyisobutylene succinyl anhydride with a polyamine having 5 to 7 active nitrogen atoms. The method includes providing the dispersant material and dispersing the same in crude oil.Type: GrantFiled: December 6, 2006Date of Patent: February 12, 2008Assignee: Texas Petrochemicals LPInventors: Ghazi B. Dickakian, C. Edward Baxter, Jr., Jeffrey Quoc Truong
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Publication number: 20080004191Abstract: A thermal conductive grease used for diffusion of heat generated in electronic appliances is provided. The thermal conductive grease comprises: (A) a base oil having a viscosity of 112 to 770 mm2 at 40° C. and comprising a copolymer of an unsaturated dicarboxylic acid dibutyl ester and an ?-olefin; and (B) a thermal conductive filler filled in the base oil. The thermal conductive grease does not include conventionally used silicone oil so that insulating substances will not be formed in the thermal conductive grease.Type: ApplicationFiled: June 29, 2006Publication date: January 3, 2008Inventor: Tsukasa Ishigaki
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Patent number: 7256242Abstract: Esterified polyalkene/UAR copolymer reaction products useful as (1) a friction modifier for lubricating oils such as automatic transmission fluids to improve torque capacity and anti-shudder durability and for continuous variable transmissions (CVTs), (2) a friction modifier for fuels or (3) a cold flow improver for diesel fuels are provided. The esterified copolymer reaction product may be used as is or can be further derivatized (e.g., by post treatment of the esterified copolymer reaction product with, for example, ethylene carbonate or boric acid).Type: GrantFiled: June 27, 2003Date of Patent: August 14, 2007Assignee: Chevron Oronite Company, LLCInventor: Kenneth D. Nelson
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Patent number: 7189682Abstract: A composition of the following components: an oil of lubricating viscosity; a polymethacrylate viscosity modifier; an ester of a maleic acid/styrene copolymer; and optionally, an additive package that imparts to the fluid the capacity to meet bench and dynamometer tests specified by an equipment manufacturer, is suitable for use as a functional fluid such as a tractor hydraulic fluid, under a wide variety of climatic conditions.Type: GrantFiled: April 4, 2002Date of Patent: March 13, 2007Assignee: The Lubrizol CorporationInventor: Richard E. Gapinski
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Patent number: 7018957Abstract: Homopolymers and copolymers of an esterified reaction product of an epoxidized mono-hydroxyl alcohol and a free radical polymerizable monomer are highly effective demulsifying agents. The molecular weight of the polymer is between from about 10,000 to about 500,000. The epoxidized mono-hydroxyl alcohol is preferably a reaction product of a C6–C30 linear or branched alcohol and an alkylene oxide. The alkylene oxide is preferably either ethylene oxide, propylene oxide or butylenes oxide or a mixture thereof. The free radical polymerizable monomer is preferably a vinyl aromatic compound or an acrylic or methacrylic based monomer. The polymer preferably comprises a micellar assembly. Such polymers are highly effective in demulsifying crude oils having API gravities of from 8 to 28 or a crude oil having a viscosity between from about 3 to about 10,000 CPS @ at 25° C.Type: GrantFiled: February 21, 2003Date of Patent: March 28, 2006Assignee: BJ Services CompanyInventor: Harold Becker
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Patent number: 6821933Abstract: The invention relates to additives for improving the flowability of mineral oils, containing: A) 1-40 wt. % of at least one copolymer, which is oil-soluble and improves the cold flow properties of mineral oil, selected from A1) copolymers consisting of 80 to 96.5 mol % ethylene and 3.5-20 mol % vinyl esters of carboxylic acids with 1-20 C atoms and/or (meth)acrylic acid esters of alcohols with 1-8 C atoms, and A2) homopolymers or copolymers of esters, containing C10-C30 alkyl radicals, of ethylenically unsaturated carboxylic acids with up to 20 mol % of other olefinically unsaturated compounds, B) 20-80 wt. % of at least one poly-alpha-olefin with a molecular weight of 250-5000, derived from monoolefins with 3-5 C atoms, and C) 5-70 wt.Type: GrantFiled: December 13, 2002Date of Patent: November 23, 2004Assignee: Clariant International Ltd.Inventors: Michael Feustel, Matthias Krull, Hans-Jörg Oschmann
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Publication number: 20040110647Abstract: A composition of the following components: an oil of lubricating viscosity; a polymethacrylate viscosity modifier; an ester of a maleic acid/styrene copolymer; and optionally, an additive package that imparts to the fluid the capacity to meet bench and dynamometer tests specified by an equipment manufacturer, is suitable for use as a functional fluid such as a tractor hydraulic fluid, under a wide variety of climatic conditions.Type: ApplicationFiled: September 25, 2003Publication date: June 10, 2004Inventor: Richard E Gapinski
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Patent number: 6573224Abstract: Improved performance of two-cycle and four-cycle engines is achieved by adding to the oil or fuel of such engines a composition that contains a copolymer of an alpha-olefin and a dialkyl fumarate or maleate and/or a synthetic diester compound that has about 30 carbon atoms. For two-cycle engines, the composition preferably contains both chemicals, in addition to an octane booster such as methylcyclopentadienyl manganese tricarbonyl. For four-cycle engines, the composition contains at least one of the copolymer and diester, in addition to a molybdenum or bismuth salt, dimercapto 1,3,4-thiadiazole and sulfur-phosphorous EP and/or chlorinated paraffin. The composition can also act to improve gear and grease lubrication and provide improved lubricity to fuels.Type: GrantFiled: August 10, 2001Date of Patent: June 3, 2003Assignee: Bardahl Manufacturing CorporationInventors: Hugh A. McNeil, Arthur J. Kiehn, Mark Eskridge
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Publication number: 20030050197Abstract: The first lubricating oil composition of the invention comprises a polyol ester (A) as a base oil, a specific amount of a viscosity index improver (B) and a specific amount of an anti-wear agent (C), and the second lubricating oil composition of the invention comprises a paraffinic hydrocarbon oil (F) having at least 30 carbon atoms and a specific amount of a viscosity index improver (B), so that these compositions exert effects that they enable a life of watch battery to last long, they enable a watch to operate in the temperature range of −30 to 80° C. with one kind of a lubricating oil, and they are free from change of properties over a long period of time.Type: ApplicationFiled: October 9, 2001Publication date: March 13, 2003Inventor: Yuji Akao
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Patent number: 6475963Abstract: Compositions for improving at least the low temperature flow properties of high viscosity index, high saturates, low sulfur lubricating oils (also known as American Petroleum Institute Group II and Group III oils). The compositions comprise a mixture of lubricating oil flow improvers (LOFIs) that are specified first and second component copolymers of unsaturated dicarboxy esters, including a first component which is a polymer or copolymer of a carboxylate containing pendent ester groups wherein the average side chain carbon number is between 11.0 and 12.4, such as dialkyl fumarate/vinyl acetate copolymer, and a second component which also is a polymer or copolymer such as dialkyl fumarate/vinyl acetate copolymer, but wherein the average side chain carbon number is between 12.7 and 15.0.Type: GrantFiled: May 1, 2001Date of Patent: November 5, 2002Assignee: Infineum International Ltd.Inventors: Ricardo A. Bloch, David J. Martella
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Publication number: 20020042348Abstract: Improved performance of two-cycle and four-cycle engines is achieved by adding to the oil or fuel of such engines a composition that contains a copolymer of an alpha-olefin and a dialkyl fumarate or maleate and/or a synthetic diester compound that has about 30 carbon atoms. For two-cycle engines, the composition preferably contains both chemicals, in addition to an octane booster such as methylcyclopentadienyl manganese tricarbonyl. For four-cycle engines, the composition contains at least one of the copolymer and diester, in addition to a molybdenum or bismuth salt, dimercapto 1,3,4-thiadiazole and sulfur-phosphorous EP and/or chlorinated paraffin. The composition can also act to improve gear and grease lubrication and provide improved lubricity to fuels.Type: ApplicationFiled: August 10, 2001Publication date: April 11, 2002Inventors: Hugh A. McNeil, Arthur J. Kiehn, Mark Eskridge
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Publication number: 20010025094Abstract: Copolymers I carrying functional groups and comprisingType: ApplicationFiled: May 4, 2001Publication date: September 27, 2001Applicant: BASF AKTIENGESELLSCHAFTInventors: Wolfgang Gunther, Knut Oppenlander, Walter Denzinger, Heinrich Hartmann, Helmut Mach, Harald Schwahn, Hans Peter Rath
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Patent number: 6174843Abstract: This invention provides a composition and a method of using the composition for dispersing wax and improving the pour point of lubricating oils. The composition comprises an esterified styrene-maleic anhydride copolymer and an esterified alpha-olefin maleic anhydride copolymer.Type: GrantFiled: November 17, 1994Date of Patent: January 16, 2001Assignee: Nalco Chemical CompanyInventors: Kim B. Peyton, Sophia L. Wang
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Patent number: 6127325Abstract: A viscosity index improver for addition to lubricating oil or the like, which comprises a graft copolymer having structural units of an oil-soluble polymer (a) comprising an olefin polymer and structural units of a copolymer (b) of a monomer having a peroxide bond with a (meth)acrylate or the like or a copolymer (c) of a monomer having a peroxide bond with 2-hydroxyethyl(meth)acrylate or the like. The improver is excellent in the effect of improving the viscosity index, the thickening effect, the fluidity at low temperatures and the shear stability, and has no fear of causing phase separation in lubricating oil.Type: GrantFiled: October 5, 1998Date of Patent: October 3, 2000Assignee: NOF CorporationInventors: Shuji Suyama, Yoshiki Higuchi, Hidefumi Tochigi, Hiroshi Ohmura
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Patent number: 6025308Abstract: A method is disclosed for preparation of amine functionalized copolymers by reacting copolymers of alkyl methacrylate and maleic anhydride with N-phenyl-1,4-phenylenediamine in mineral oil and inert atmosphere at 40 to 75.degree. C. The copolymers are useful viscosity index improvers when incorporated into lubricating oils.Type: GrantFiled: September 10, 1998Date of Patent: February 15, 2000Assignee: R. T. Vanderbilt Company, Inc.Inventors: Hidehiko Matsuya, Thomas J. Karol
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Patent number: 5965498Abstract: A two-cycle oil composition comprising: (a) 10-20% of a first synthetic ester base stock oil (a copolymer of an alpha-olefin with an ester of a dicarboxylic acid, viscosity 20 to 50 cSt at 100.degree. C.); (b) 18-30% of a second synthetic ester base stock oil (an oxo alcohol of a dicarboxylic acid, viscosity 3 to 10 cSt at 100.degree. C.; (c) 30-40% of a polybutene polymer (Mn 300-1500); (d) 15-25% of a nor liquid solvent (boiling point up to 300.degree. C., flash point of 60 .degree.-120.degree. C.); (e) 0.2 to 2.0% of an oil soluble copper compound, and (f) 0 to 5% of other lubricating oil additives.Type: GrantFiled: May 14, 1998Date of Patent: October 12, 1999Assignee: Exxon Chemical Patents IncInventor: John Henry Smythe
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Patent number: 5939365Abstract: A lubricant which comprises: a mineral oil basestock which has been dewaxed via catalytic cracking and/or catalytic isomerization; an alkylene-alkylene copolymer; and a lubricating oil flow improver formed from the reaction product of: (a) an unsaturated carboxy ester formed via the esterification of an unsaturated carboxylic acid or its corresponding anhydride with a monohydric aliphatic alcohol having an average carbon number of between about 10 to 18, the unsaturated carboxy ester having the formula: ##STR1## wherein R' is selected from the group consisting of hydrogen and COOR and wherein R is a C.sub.6 to C.sub.22 alkyl group; and (b) a monomer selected from the group consisting of(i) a vinyl ester having the formula: ##STR2## wherein R.sub.1 comprises an alkyl group containing from 1 to 18 carbon atoms;(ii) an olefin having the formula ##STR3## wherein R.sub.1 and R.sub.2 can independently be hydrogen, an alkyl having from 1 to 28 carbon atoms, or a substituted aryl group, provided both R.sub.1 and R.Type: GrantFiled: December 20, 1996Date of Patent: August 17, 1999Assignee: Exxon Chemical Patents Inc.Inventors: John V. Redpath, Arunas T. Lapinas, David J. Martella, Albert Rossi, William M. Davis
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Patent number: 5910470Abstract: A grease to be sealed in bearings which shows good lubricating properties within a wide temperature range from low to high temperatures, whereby it can prevent bearing noise while it is cold, and maintain its good properties including excellent high-temperature durability for a long period of time. The grease contains a base oil made up of a synthetic hydrocarbon oil and an ester synthetic oil having eight or more ester groups arranged in a comb-like fashion on one side of an oil chain molecule made up of eight of more carbon atoms, as expressed by Formula below, the ratio of contents in weight of the synthetic hydrocarbon oil and the ester synthetic oil being 0.65-0.75:0.35-0.25, and 5-20 wt % of a urea thickening agent. The grease may further contain 0.1-10 wt % dithiophosphate as an extreme pressure agent. The grease may be used as grease to be sealed in a ball bearing for supporting a pulley engaging belts for transmitting automotive engine torque to prevent noise immediately after the engine is started.Type: GrantFiled: January 29, 1997Date of Patent: June 8, 1999Assignee: NTN CorporationInventors: Masami Minami, Takao Yoshimatsu, Hiroki Iwamatsu, Takahiro Koremoto
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Patent number: 5798054Abstract: A lubricant and combination lubricant and refrigerant composition for use in a refrigerating machine in which a substitute freon refrigerant, which lubricant contains a polymer of a fumaric ester or a fumaric ester and a copolymerizable alkylene, and optionally contains an organic carboxylic ester or a polyalkylene glycol with a kinematic viscosity of 2 to 30 cSt. The lubricant is compatible with substitute freon refrigerants such as hydrogen-containing halogenated hydrocarbons, particularly R 134a, in a wide temperature range, has a high viscosity index, is thermally and chemically stable, and has an excellent lubricity.Type: GrantFiled: September 30, 1996Date of Patent: August 25, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Takehisa Sato, Hironari Ueda, Toshiaki Kuribayashi, Satoshi Asano, Tadashi Niwa, Hiroshi Ueno, Takeaki Fujii, Sadakatsu Suzuki
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Patent number: 5747596Abstract: Gel-free dispersant additives for lubricating and fuel oil compositions comprise at least one adduct of (A) .alpha.-olefin homopolymer or interpolymer of 700 to 10,000 number average molecular weight, free radically grafted with an average of from about 0.Type: GrantFiled: August 5, 1996Date of Patent: May 5, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Jacob Emert, Robert Dean Lundberg, David John Lohse
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Patent number: 5716915Abstract: Additives having certain hydrocarbyl groups improve the low temperature properties of hydrocarbon oils.Type: GrantFiled: October 3, 1996Date of Patent: February 10, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Gerald Ivan Brown, Lain More, Robert Dryden Tack, Brian William Davies, Derek A. Towe
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Patent number: 5703023Abstract: Lubricants having a Brookfield viscosity at -40.degree. C. equal to or below 20,000 cP (preferably 15,000 or less) are formed from blends composed of a major amount of mineral oil in the range of about 90N to about 140N; and minor amounts of poly-.alpha.-olefin oligomer (PAO) formed from 1-alkene of 6 to 20 carbon atoms and having a kinematic viscosity of about 2 cSt at 100.degree. C.; and vinylaromatic-maleic ester polymeric viscosity index improver. Synergistic low temperature viscometric properties are exhibited by typical compositions of this type.Type: GrantFiled: November 21, 1995Date of Patent: December 30, 1997Assignee: Ethyl CorporationInventor: Sanjay Srinivasan
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Patent number: 5641734Abstract: A lubricant composition is described which is useful as a chain bar lubricant for chain saws. The composition comprises(A) at least one triglyceride wherein the ratio of the oleic acid moiety:linoleic acid moiety is from about 2 up to about 90,(B) at least one viscosity modifying additive, and(C) at least one tackifier.Optionally, the composition may also contain(D) at least one pour point depressant and(E) at least one antiwear agent.Type: GrantFiled: July 20, 1995Date of Patent: June 24, 1997Assignee: The Lubrizol CorporationInventor: Paul C. Naegely