Benzene Ring Bonded Directly To The Carbon Of The -c(=o)o- Group (e.g., Aluminum Complex Salts, Etc.) Patents (Class 508/525)
  • Patent number: 12077722
    Abstract: The present invention describes a water based semi-synthetic metal working fluid comprising a base oil, an organic acid, emulsifiers, optionally a concentrate additive, water and a microbial growth control agent which comprises a glycol ether amine.
    Type: Grant
    Filed: August 24, 2021
    Date of Patent: September 3, 2024
    Assignee: Dow Global Technologies LLC
    Inventors: Chao Zhao, Xue Chen
  • Patent number: 12071596
    Abstract: A microbial growth control agent and method of controlling microbial growth in metal working fluids, wherein the agent comprises at least a glycol ether amine.
    Type: Grant
    Filed: August 24, 2021
    Date of Patent: August 27, 2024
    Assignee: Dow Global Technologies LLC
    Inventors: Chao Zhao, Xue Chen
  • Patent number: 11198830
    Abstract: The invention provides a grease composition, being a grease composition containing a base oil and, as a thickener a calcium complex soap, and being a grease composition using for the carboxylic acids forming the aforementioned calcium complex soap substituted or unsubstituted C18-22 straight-chain higher fatty acids, aromatic monocarboxylic aromatic acids having substituted or unsubstituted benzene rings and C2-4 straight-chain saturated lower fatty acids, wherein the aforementioned substituted or unsubstituted C18-22 straight-chain higher fatty acids include behenic acid and the amount of behenic acid used, as a mass ratio in terms of the total amount of the aforementioned substituted or unsubstituted C18-22 straight-chain higher fatty acids used, is from 25 mass % up to 70 mass %.
    Type: Grant
    Filed: November 30, 2017
    Date of Patent: December 14, 2021
    Assignee: SHELL OIL COMPANY
    Inventors: Keiji Tanaka, Kazuya Watanabe
  • Patent number: 10829714
    Abstract: The present invention provides a grease composition for constant velocity joints, which includes a lubricating base oil, a thickener including a nitrogen-containing compound, a triglyceride, a diester, and a boron nitride, wherein a total content of the triglyceride and the diester is 1 to 5 mass % based on a total amount of the grease composition, and a mass ratio of a content of the triglyceride to a content of the diester (triglyceride/diester) is 0.3 to 1.5.
    Type: Grant
    Filed: June 22, 2017
    Date of Patent: November 10, 2020
    Assignees: JXTG NIPPON OIL & ENERGY CORPORATION, NTN CORPORATION
    Inventors: Takashi Arai, Yasuha Tokumo, Minoru Ishijima, Takeyoshi Konomoto
  • Patent number: 10190069
    Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and an ashless thiocarbamate compound having an optionally-substituted hydrocarbyl group on an S-atom and an optionally-substituted hydrocarbyl group on an N-atom. The invention further relates to a method of the lubricating an internal combustion engine with the lubricating composition.
    Type: Grant
    Filed: March 7, 2012
    Date of Patent: January 29, 2019
    Assignee: The Lubrizol Corporation
    Inventors: Yanshi Zhang, Seth L. Crawley, Richard Yodice
  • Patent number: 9938482
    Abstract: A lubricating oil composition for an internal combustion engine according to the present invention contains a lubricating base oil, (A1) a basic calcium salicylate having a TBN of 200 mgKOH/g or more, (A2) a basic sodium sulfonate having a TBN of 200 mgKOH/g or more and/or a basic calcium sulfonate having a TBN of 50 mgKOH/g or less, (B) a binuclear organic molybdenum compound and/or a trinuclear organic molybdenum compound, and (C) a polyalkyl (meth)acrylate having an SSI of 30 or less, a total content of molybdenum derived from the binuclear and trinuclear organic molybdenum compounds being 0.025 mass % or more relative to the whole amount of the composition and the lubricating oil composition having predetermined values of a high-temperature high-shear viscosity and a NOACK value (250° C., 1 hr).
    Type: Grant
    Filed: January 26, 2015
    Date of Patent: April 10, 2018
    Assignee: IDEMITSU KOSAN CO., LTD.
    Inventor: Toshimasa Utaka
  • Publication number: 20150141307
    Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and an amine or ammonia salt of a carboxylic acid compound where said carboxylic acid is characterized in that it is functionalized with a hydroxy-substituted aromatic moiety. The invention further relates to methods of lubricating an internal combustion engine by supplying the described lubricating composition to the internal combustion engine. The invention further relates to the use of the salt of the carboxylic acid compound as an antiwear agent or an antioxidant.
    Type: Application
    Filed: June 14, 2012
    Publication date: May 21, 2015
    Applicant: The Lubrizol Corporation
    Inventors: Patrick E. Mosier, Scott Capitosti, Ewan E. Delbridge
  • Patent number: 8946134
    Abstract: The present invention provides a grease composition or a lubricating oil composition which is capable of effectively preventing hydrogen brittleness-caused peeling from occurring on a rolling surface of a rolling bearing, is excellent in durability in a high temperature and speed operation, and can be used for a long time. A grease-packed bearing (1) has an inner ring (2), an outer ring (3), and a plurality of rolling elements (4). A sealing member (6) for sealing a grease composition (7) is provided at openings (8a) and (8b) disposed at both axial ends of the inner ring (2) and the outer ring (3). The grease composition (7) includes a base grease composed of a base oil and a thickener and an additive added to the base grease. The additive contains at least one compound selected from among plant-derived polyphenolic compounds and compounds formed by decomposition thereof.
    Type: Grant
    Filed: February 24, 2010
    Date of Patent: February 3, 2015
    Assignee: NTN Corporation
    Inventors: Hidenobu Mikami, Yosuke Taguchi, Takayuki Kawamura
  • Publication number: 20140287970
    Abstract: Marine engine (two- or four-stroke) lubrication is effected by a composition comprising a major amount of an oil of lubricating viscosity blended with minor amounts of one or more additives and a star polymer or olefin co-polymer viscosity modifier dispersed in a heavy basestock diluent oil.
    Type: Application
    Filed: March 21, 2014
    Publication date: September 25, 2014
    Inventors: John H. Smythe, Dhanesh Goberdhan
  • Patent number: 8383563
    Abstract: The resistance to oxidation and nitration of a gas engine oil is improved by the use of a combination of a hindered phenolic antioxidant and an (alkylated) phenyl-?-naphthylamine antioxidant. The additional use of an organo molybdenum compound further enhances the resistance to oxidation and nitration.
    Type: Grant
    Filed: August 5, 2008
    Date of Patent: February 26, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Marc-André Poirier, Kathleen Hoard Tellier, Stanley James Cartwright
  • Publication number: 20120156123
    Abstract: A water-soluble cutting fluid for slicing silicon ingots is characterized in that it includes a monoprotic or diprotic aliphatic carboxylic acid (A) having a carbon number (including the carbon in the carbonyl group) of 4˜10, and either a polyprotic organic acid (B) with ?pKa of 0.9˜2.3 as defined by the following formula (1) or a salt (BA) of said organic acid (B) as essential components: ?pKa=(pKa2)?(pKa1) ??(1) wherein the dissociation stage, at which the organic acid (B) denoted as n-protic acid HnA, becomes Hn-1A+H+ is numbered 1 with an acid dissociation constant expressed as pKa1, and the dissociation stage at which the organic acid (B) becomes Hn-2A+H+ is numbered as 2 with an acid dissociation constant expressed as pKa2.
    Type: Application
    Filed: August 30, 2010
    Publication date: June 21, 2012
    Applicant: SANYO CHEMICAL INDUSTRIES, LTD.
    Inventors: Aki Hidaka, Yoshitaka Katsukawa, Tsuyoshi Okamoto
  • Publication number: 20120004149
    Abstract: An ECOLOGICAL, BIODEGRADABLE, FLUID LUBRICANT AND ANTI-FREEZING COMPOSITION FOR HYDRAULIC SYSTEMS, contains glycol, corrosion inhibitors and antifoaming agents, and must be diluted in water, either before or after it is fed into the hydraulic system, including shock absorber, preferably in a concentration of 30% to 70% by volume of the composition and of 30% to 70% by volume of water.
    Type: Application
    Filed: February 12, 2010
    Publication date: January 5, 2012
    Applicant: Promax Produtos Maximos S/A Industria E Comercio
    Inventor: Roberto Andrade Galvão
  • Publication number: 20110082062
    Abstract: Lubricating oil used for the lubrication of engines run on biodiesel fuels are improved in their resistance to oxidation by the addition to said to lubricating oil of particular detergents, and premixed mixtures of particular detergents and anti-oxidants.
    Type: Application
    Filed: September 28, 2010
    Publication date: April 7, 2011
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Jacob J. Habeeb, Ramesh Varadaraj, Steven M. Jetter
  • Patent number: 7851420
    Abstract: A corrosion protection agent for functional fluids is disclosed, comprising 5 to 80 wt. % of at least one fatty acid alkanolamide, based on saturated or unsaturated fatty acids with 10 to 20 carbon atoms, 5 to 80 wt. % of at least one alcohol with 2 to 14 carbon atoms and 5 to 80 wt. % of at least one aromatic moncarboxylic acid or an aliphatic dicarboxylic acid with 10 to 12 carbon atoms, whereby the sum of said components amounts to 100 wt. % and the wt. % is based on the weight of the corrosion protection agent, a water-miscible concentrate, containing said corrosion protection agent, for functional fluids based on water and use thereof for the production of lubricants, abrasive agents, hydraulic fluids and cooling lubricants for metal working and metal cutting.
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: December 14, 2010
    Assignee: Helmut Theunissen
    Inventors: Helmut Theunissen, Sabine Theunissen
  • Publication number: 20100256030
    Abstract: A lubricating oil composition containing a combination of oil of lubricating viscosity, one or more block copolymers of hydrogenated poly(monovinyl aromatic hydrocarbon) and poly(conjugated diene) as a viscosity modifier, and one or more one or more optionally substituted bridged hydrocarbyl phenol condensates, or metal salts thereof, as a detergent.
    Type: Application
    Filed: April 6, 2009
    Publication date: October 7, 2010
    Inventors: Rolfe J. Hartley, Peter D. Watts
  • Publication number: 20090264326
    Abstract: A tubular threaded joint for connecting tubing or casing used to excavate oil wells have a lubricating coating formed from a lubricating coating composition comprising one or more basic lubricants selected from a basic sulfonate salt, a basic salicylate salt, a basic phenate salt, and a basic carboxylate salt and having biodegradability value (BOD) of at least 20% when measured after 28 days in seawater. The joint can be used without application of a compound grease containing heavy metals even in a country or region having severe environmental regulations.
    Type: Application
    Filed: April 10, 2009
    Publication date: October 22, 2009
    Inventors: Ryuichi Imai, Kunio Goto
  • Publication number: 20080153726
    Abstract: A method for operating a two-stroke engine using low sulfur fuels. Blended cylinder oil is produced by blending base oil and at least one additive where the total base number (“TBN”) of the blended cylinder oil ranges from 1 TBN to 20 TBN. The engine is operated by supplying the blended cylinder oil and a fuel having less than 1.0% sulfur to the engine cylinders. The additive includes a low TBN calcium salts at a weight ratio ranging from 90:10 to 10:90; or any combination thereof. A method for operating a 4-stroke engine using low and high sulfur fuels. Blended oil, having a TBN that is greater than 20 TBN, is produced by blending base oil and at least one additive. The engine is operated by exchanging a low sulfur fuel having less than 1.0% sulfur with a high sulfur fuel. The engine lubricating system is switched to the blended cylinder oil in accordance with switching the fuel from a low sulfur fuel to a high sulfur fuel.
    Type: Application
    Filed: December 11, 2007
    Publication date: June 26, 2008
    Inventors: Klaus-Werner Damm, Richard Leahy
  • Publication number: 20080026962
    Abstract: The pour points of lubricating compositions are significantly improved when Group III and GTL base stocks are formulated with alkyl alkaline earth metal detergents. In a preferred embodiment, calcium alkyl salicylate detergents are used.
    Type: Application
    Filed: July 24, 2007
    Publication date: January 31, 2008
    Inventor: Marc-Andre Poirier
  • Patent number: 6919301
    Abstract: A grease composition with a thickener of a calcium sulfonate complex and a second thickener component in a base oil. The second thickener component may be, for instance, polyurea, a metallic soap, a complex metallic soap or an N-substituted terephthalamic acid metal salt. Alternatively, a grease composition with a thickener of an N-substituted terephthalamic acid metal salt and a second thickener component in a base oil. Furthermore, a grease composition with a thickener component of polyurea and complex metallic soap in an ester oil. Still further, a grease composition with a thickener of polyurea and a complex metallic soap in a base oil.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: July 19, 2005
    Assignee: NSK Ltd.
    Inventors: Shinya Nakatani, Hirotoshi Miyazima, Michita Hokao
  • Publication number: 20040235688
    Abstract: The use, in a minor amount, of a detergent composition comprising one or more metal detergents which comprises metal salts of organic acids, wherein the detergent composition comprises more than 50 mole %, based on the moles of the metal salts of organic acids in the detergent composition, of:
    Type: Application
    Filed: June 22, 2004
    Publication date: November 25, 2004
    Inventors: Christopher J. Locke, Mark G. Stevens, Peter Wrench, Stephen Arrowsmith, Rebecca C. Castle, Jane R. Galsworthy
  • Patent number: 6602832
    Abstract: An oil-soluble lubricant additive composition comprising: (a) at least one compound of formula I:  wherein R1, R2, R3 and R4 are independently hydrogen, alkyl, alkenyl, aryl or aralkyl; or R1 and R2, or R3 and R4, combine with the carbon atom to which they are attached to form an alkyl or alkenyl ring; and (b) an acid having the formula RCO2H, wherein R is C1-C25 alkyl, C2-C25 alkenyl, C2-C25 alkynyl, C5-C25 aryl or C5-C25 aralkyl.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: August 5, 2003
    Assignee: Crompton Corporation
    Inventors: Ravindranath Mukkamala, Rajiv Manohar Banavali
  • Patent number: 6596674
    Abstract: The invention is a liquid composition of matter useful as a metal working lubricant. The composition comprises a primary lubricity component, such as a polyether or polyether ester, and dissolved salts of carboxylic acids. The composition preferably contains not more than 0.2 percent of any element except carbon, hydrogen, oxygen, alkaline earth metals, alkali metals, inorganically bonded halogens, inorganically bonded nitrogen, inorganically bonded sulfur, and inorganically bonded phosphorus.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: July 22, 2003
    Assignee: Henkel Corporation
    Inventor: Frank K. Botz
  • Publication number: 20030134758
    Abstract: The use of an effective amount of one or more compounds capable of reducing friction coefficients under mixed lubrication or boundary lubrication conditions in a heavy duty diesel engine lubricating oil composition for improving the fuel economy of a heavy duty diesel engine.
    Type: Application
    Filed: December 12, 2002
    Publication date: July 17, 2003
    Inventors: Charles H. Bovington, Stephen Arrowsmith, Rebecca C. Castle, Peter Wrench
  • Publication number: 20030096716
    Abstract: The use, in a minor amount, of a detergent composition comprising one or more metal detergents which comprises metal salts of organic acids, wherein the detergent composition comprises more than 50 mole %, based on the moles of the metal salts of organic acids in the detergent composition, of:
    Type: Application
    Filed: May 9, 2002
    Publication date: May 22, 2003
    Inventors: Christopher J. Locke, Mark G. Stevens, Peter Wrench, Stephen Arrowsmith, Rebecca C. Castle, Jane R. Galsworthy
  • Publication number: 20020142921
    Abstract: A compound of formula I: 1
    Type: Application
    Filed: January 22, 2002
    Publication date: October 3, 2002
    Inventor: Ravindranath Mukkamala
  • Publication number: 20020137638
    Abstract: An oil-soluble lubricant additive composition comprising:
    Type: Application
    Filed: January 22, 2002
    Publication date: September 26, 2002
    Inventors: Ravindranath Mukkamala, Rajiv Manohar Banavali
  • Publication number: 20020103089
    Abstract: A lubricant composition for a surface treatment of a steel filament comprises at least one specified compound as a lubricant component and a rubber-steel filament composite body is prepared by using a steel filament treated with the lubricant composition.
    Type: Application
    Filed: June 29, 2001
    Publication date: August 1, 2002
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Yasuo Fukushima, Hajime Kondo
  • Publication number: 20020004465
    Abstract: The invention is a liquid composition of matter useful as a metal working lubricant. The composition comprises a primary lubricity component, such as a polyether or polyether ester, and dissolved salts of carboxylic acids. The composition preferably contains not more than 0.2 percent of any element except carbon, hydrogen, oxygen, alkaline earth metals, alkali metals, inorganically bonded halogens, inorganically bonded nitrogen, inorganically bonded sulfur, and inorganically bonded phosphorus.
    Type: Application
    Filed: February 27, 2001
    Publication date: January 10, 2002
    Inventor: Frank K. Botz
  • Patent number: 6159911
    Abstract: Disclosed is a diesel engine oil composition containing a lube oil base and one or more metallic detergent-dispersants selected from among a perbasic alkaline earth metal sulfonate, phenolate, and salicylate. The total phosphorus content of the composition is suppressed to 100 ppm by weight or less, to thereby provide diesel engine oil compositions having excellent oxidation stability and wear resistance.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: December 12, 2000
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Tadashi Katafuchi
  • Patent number: 5863874
    Abstract: The invention includes lubricant concentrate and use solution compositions having an amine compound of the formula,R.sub.1 --O--R.sub.2 --NH.sub.2,R.sub.1 --O--R.sub.2 --NH--R.sub.3 --NH.sub.2,and mixtures thereofwherein R.sub.1 may be a linear saturated or unsaturated C.sub.6 -C.sub.18 alkyl, R.sub.2 is a linear or branched C.sub.1 -C.sub.8 alkyl, and R.sub.3 may be a linear or branched C.sub.1 -C.sub.8 alkyl. The concentrate also comprises an acidulant, optionally a stabilizing hydrotrope, and a surfactant. The lubricant use solution resulting from dilution of the concentrate has an amine compound in a concentration ranging from about 10 ppm to 10000 ppm. Also disclosed is a method of lubricating a conveyor system which includes providing a use solution of the lubricant concentrate composition.
    Type: Grant
    Filed: September 10, 1997
    Date of Patent: January 26, 1999
    Assignee: Ecolab Inc.
    Inventors: Kimberly L. Person Hei, Michael E. Besse, Bruce E. Schmidt, Christopher S. Sykes, Timothy A. Gutzmann
  • Patent number: 5808145
    Abstract: Dispersant detergent additives for lubricating oils prepared by neutralization, carboxylation, sulfurization-overalkalinization, carbonation, distillation, filtering and degassing from alkyl phenols containing 35-85% by weight of linear alkyl substituents. The process does not require, during the neutralizing phase, the presence of a third solvent, which, by forming an azeotropic mixture with water promotes the elimination of water arising from the neutralizing reaction. The additives of the invention have improved stability to hydrolysis and improved dispersion properties, improved compatibility and improved foaming properties.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: September 15, 1998
    Inventors: Jean-Louis Le Coent, Jacques Cazin, Thierry Triconnet, William W. Willis, Jr.
  • Patent number: 5607906
    Abstract: A grease composition for constant velocity joints which consists essentially of: (a) a base oil; (b) an urea thickener; (c) molybdenum disulfide; and (d) a metal salt or an overbasic metal salt selected from the group consisting of metal salts or overbasic metal salts of oxidized waxes, petroleum sulfonates, alkyl aryl sulfonates, salicylate, and phenates. In addition to (a) to (d), it may further contain, (e) an extreme pressure agent selected from the group consisting of a metal-free sulfur-phosphorus extreme pressure agent and molybdenum dithiophosphate, or (f) molybdenum dithiocarbamate. The grease composition exhibits excellent wear-resistance and pitting-inhibitory effect.
    Type: Grant
    Filed: April 22, 1996
    Date of Patent: March 4, 1997
    Assignee: Kyodo Yushi Co., Ltd.
    Inventors: Takashi Okaniwa, Hisayuki Osawa
  • Patent number: 5585335
    Abstract: A grease composition comprises an effective amount of a lubricating oil containing an imide or pyrrolidone thickening agent or an imide or pyrrolidone thickening agent comprising a metal salt of a carboxylic acid in combination with a bimetal phthalate complexing agent, such as dilithium terephthalate. The presence of the complexing agent results in a grease having properties superior to that of a similar grease without the complexing agent. Preferred complexing agents are dimetal terephthalates in which the metal is an alkali or alkaline earth metal and is the same metal as is present in the thickener. An example is a combination of a calcium or lithium salt of the reaction product of trimellitic anhydride with a hydrogenated rapeseed amine and a dilithium terephthalate complexing agent.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: December 17, 1996
    Assignee: Exxon Research and Engineering Company
    Inventors: David L. Andrew, David A. Slack