Having -c(=x)-, Wherein X Is Chalcogen, Attached Directly To The Nitrogen (e.g., Amides, Polyureas, Etc.) Patents (Class 508/528)
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Patent number: 12006486Abstract: A method of limiting the chemical degradation of hydrocarbonaceous liquids due to nitrogen dioxide contamination at elevated temperature comprises the addition thereto of an ionic liquid composed of a cation and a boron- and halogen-free, multi-functional aromatic anion, the ionic liquid serving to inhibit the nitration of hydrocarbonaceous liquid components that initiates degradation.Type: GrantFiled: October 26, 2022Date of Patent: June 11, 2024Assignee: Infineum International LimitedInventors: David Robert Coultas, Matthew David Irving, Nathan Hollingsworth, Adam Greer, Christopher Hardacre
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Patent number: 11859149Abstract: An ionic liquid composed of nitrogen-free cations and aromatic halogen- and boron-free anions is useful as an additive to prolong the service life of hydrocarbonaceous liquids exposed to nitrogen dioxide contamination, and to provide friction and wear reduction.Type: GrantFiled: October 26, 2022Date of Patent: January 2, 2024Assignee: Infineum International LimitedInventors: David Robert Coultas, Matthew David Irving, Nathan Hollingsworth, Adam Greer, Christopher Hardacre
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Patent number: 11365367Abstract: The invention provides a lubricating composition comprising a low viscosity base oil and a synergistic mixture of a functionalized ethylene-?-olefin copolymer, a poly(meth)acrylate polymer, and a metal-free anti-wear agent. The invention also provides a method of lubricating an internal combustion engine using such a lubricating composition.Type: GrantFiled: June 26, 2018Date of Patent: June 21, 2022Assignee: The Lubrizol CorporationInventors: Paul R. Vincent, Timothy R. Smith, Eugene Pashkovski, Reid A. Patterson
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Patent number: 11215604Abstract: In a method for predicting deterioration of grease, the grease is applied between a semiconductor module and a cooler. The semiconductor module accommodates a semiconductor element. The method for predicting deterioration includes predicting deterioration of the grease after specified heat cycles by using: a variable G1/G2 that is acquired by dividing an initial storage modulus G1 of the grease by an initial loss modulus G2 of the grease at an expected maximum use temperature of the semiconductor element; and distortion dD of the grease at the time when the initial storage modulus G1 and the initial loss modulus G2 have the same value.Type: GrantFiled: February 25, 2019Date of Patent: January 4, 2022Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Tomo Sasaki, Kazunori Uchiyama, Naoki Hakamada, Tadafumi Yoshida
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Patent number: 10018106Abstract: An engine system is provided. The engine system includes a rotatable intake port circumferentially surrounding at least a portion of a stem of an intake valve coupled to a cylinder, the rotatable intake port having a first curved section extending inward toward or outward from a rotational axis of the rotatable intake port. The engine system further includes an intake port actuator coupled to the rotatable intake port configured to rotate the rotatable intake port about the rotational axis based on engine operating conditions.Type: GrantFiled: October 21, 2016Date of Patent: July 10, 2018Assignee: Ford Global Technologies, LLCInventor: Xiaogang Zhang
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Patent number: 9012386Abstract: The invention provides a grease composition for a hub unit bearing employing an angular contact ball bearing, containing (a) as a thickener a mixture of diurea compounds represented by formula (I): R1—NHCONH—R2—NHCONH—R1, formula (II): R1—NHCONH—R2—NHCONH—R3, and formula (III): R3—NHCONH—R2—NHCONH—R3 wherein R1 is cyclohexyl group, R2 is a divalent aromatic hydrocarbon group having 6 to 15 carbon atoms, R3 is a straight-chain or branched alkyl group having 12 to 20 carbon atoms, and (R1/(R1+R3))×100=85 to 95 mol %; (b) a base oil; (c) a molybdenum dialkyldithiocarbamate; and (d) a calcium sulfonate. The grease composition of the invention, when used in the hub unit bearing, shows minimum leakage, excellent anti-flaking properties and satisfactory bearing lubrication life.Type: GrantFiled: February 28, 2011Date of Patent: April 21, 2015Assignee: Kyodo Yushi Co., Ltd.Inventors: Osamu Saita, Takashi Azuma, Masamichi Yamamoto
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Patent number: 8981150Abstract: Novel ether-amide compounds are described. Uses of the compounds, in particular as solvents, for example in phytosanitary formulations are also described.Type: GrantFiled: October 18, 2010Date of Patent: March 17, 2015Assignee: Rhodia OperationsInventors: Thierry Vidal, Massimo Guglieri, Olivier Jentzer
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Patent number: 8889604Abstract: Provided is a method for preparing a grease composition, which comprises mixing grease components under high pressure and high flow rate impingement. In one embodiment, a first mixture of an amine in a lubricating base oil is mixed with an isocyanate in a lubricating base oil under high pressure and high flow impingement. In another embodiment, the mixing and reaction occurs in a reaction injection molding device. The orifice size through which each of the mixtures is introduced into a reaction/mixing zone is less than 0.030 inch (0.0762 centimeter) in diameter. The resulting grease composition is an extremely low noise grease, being virtually clear of any urea thickener particles, and/or can exhibit good high temperature resistance and mechanical stability.Type: GrantFiled: March 28, 2011Date of Patent: November 18, 2014Assignee: Chevron U.S.A. Inc.Inventors: David S. Lee, Susan M. Abernathy
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Patent number: 8859470Abstract: A lubricating grease composition comprising (A) a base oil, (B) 5 to 10 wt. % of a urea compound, (C) 0.5 to 20 wt. % of at least one phosphorous compound selected from the group consisting of a phosphoric acid salt etc., and (D) 0.5 to 40 wt. % of a fatty acid metal salt. Aforementioned lubricating grease composition allows it to reduce the friction coefficient and prolong the endurance life significantly when it is applied onto surfaces of the sliding pair consisting of metal and plastic (especially glass-fiber-reinforced plastic) parts.Type: GrantFiled: April 27, 2007Date of Patent: October 14, 2014Assignee: Dow Corning Toray Company, Ltd.Inventor: Atsushi Ikezawa
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Patent number: 8841244Abstract: A use of a lubricant comprising at least one reaction product of mono-di- and/or poly-isocyanate with unbranced and/or branced, unsaturated and/or saturated, alicyclic poly-amine with carbon numbers from 5 to 24, at least between at lease two elements, which are movable against each other.Type: GrantFiled: November 23, 2005Date of Patent: September 23, 2014Assignee: AB SKFInventors: Ebbe Malmstedt, Walter Holweger, Hubertus Peek, Ingemar Strandell, Arno Stubenrauch, Bernhard Bauer, Frank Fiddelaers, Albert Van Den Kommer
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Patent number: 8835368Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity and a product obtainable from a 1,4-conjugate addition of an aminocarboxylic acid to an activated olefin. The invention further relates to a method of lubricating an internal combustion engine by lubricating the engine with the lubricating composition. The invention further relates to the use of the product disclosed herein as a lead corrosion inhibitor.Type: GrantFiled: February 8, 2010Date of Patent: September 16, 2014Assignee: The Lubrizol CorporationInventors: Jody A. Kocsis, Matthew D. Gieselman, Seth L. Crawley, Douglas M. Barr
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Patent number: 8809243Abstract: Water-based lubricants for the lubrication of frictional partners in drive elements, as well as their use. In particular, a water-based lubricant that contains 5 to 80% by weight of water-soluble polyalkylene glycol that is selected from the group that is composed of statistically distributed polyoxyethylene units and/or polyoxypropylene units and/or other polyoxyalkylene components, a block polymer that that is composed of polyoxyethylene units and/or polyoxypropylene units and/or other polyoxyalkylene components, 0.5 to 20% by weight of foaming or non-foaming emulsifiers from the class of anionic, non-ionic, or cationic surfactants, water-soluble or water-emulsifiable carboxylic acid esters, 0.5 to 50% by weight of anti-icing additives, selected from the group that is composed of alkylene glycol, glycerol, salts or ionic liquids, 0.05 to 10% by weight of corrosion additives, 0.001 to 1% by weight of additives for preventing the formation of foam, and 0.Type: GrantFiled: August 23, 2010Date of Patent: August 19, 2014Assignee: Klüber Lubrication München KGInventors: Martin Schmid-Amelunxen, Martin Schweigkofler, Thomas Kilthau, Jochen Muehlemeier
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Publication number: 20140199009Abstract: The present invention relates to: a grease composition that includes a base oil which has a pressure-viscosity coefficient as measured at 40° C. of 33 GPa?1 or less and a thickener which is contained in a projected-area proportion of 10% by area or higher; and a rolling device packed with the grease composition.Type: ApplicationFiled: August 24, 2012Publication date: July 17, 2014Applicant: NSK LTD.Inventors: Noriyuki Inami, Atsushi Yokouchi, Michita Hokao, Shinya Nakatani, Haruka Kanda, Kazuhiro Soga, Takayuki Miyagawa
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Patent number: 8722602Abstract: Grease which includes a base oil containing at least 50% by mass of a specific diester compound of a glycol with a branched carboxylic acid, and a specific diurea compound as a thickener. The grease is excellent in low-temperature performance and has low oil separation tendency. In particular, when used in a rotation transmission device having a built-in one-way clutch, the grease can provide satisfactory clutch engagement performance (intermeshing) at low temperatures and is less apt to cause oil separation under high centrifugal force.Type: GrantFiled: October 24, 2007Date of Patent: May 13, 2014Assignee: Idemitsu Kosan Co., Ltd.Inventors: Yukitoshi Fujinami, Hitoshi Hata, Shinya Nakatani, Atsushi Yokouchi
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Patent number: 8703671Abstract: The invention provides for a process for preparing a urea grease including: (a) introducing a first feed component to a first feeding zone; (b) introducing a second feed component to a second feeding zone; (c) first reacting-mixing in a first reacting-mixing zone; and (d) cooling-mixing in a cooling-mixing zone. The invention also provides for a process for preparing a urea grease including: (a) introducing a first feed component to a first feeding zone; (b) introducing a second feed component to a second feeding zone; (c) first reacting-mixing in a first reacting-mixing zone; (d) introducing a third feed component to a third feeding zone; (e) second reacting-mixing in a second reacting-mixing zone; and (f) cooling-mixing in a cooling-mixing zone. The invention also provides for an apparatus for preparing a urea grease comprising: (a) a first feeding zone; (b) a second feeding zone; (c) a first reacting-mixing zone; and (d) a cooling-mixing zone.Type: GrantFiled: December 5, 2007Date of Patent: April 22, 2014Assignee: Shell Oil CompanyInventors: Jean-luc Pierre André Brossaud, David Edmund Code, Jerome Dabos, Ronald David Harris, Charles Montgomery Harris, Aimin Huang, Krishna Rangraj Kaushik, Catherine Maillard, Howard Brian Mead, Raghunath Gopal Menon, Jean-paul Saint
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Patent number: 8629090Abstract: The present invention provides a rust resisting grease composition showing an excellent rust resisting performance without using nitrites and the grease composition-enclosed bearing. The rust resisting grease composition contains a base oil, a thickener, and a rust resisting component. The rust resisting component contains a metallic salt of a polybasic acid, a polyvalent alcohol in which a part of a hydroxyl group is blocked, and at least one compound selected from an organic sulfonate and a fatty ester. The content of the component is 0.1 to 10 parts by weight based on the total amount of the base oil and the thickener. The base oil contains at least one oil selected from synthetic hydrocarbon oil and ether oil. The thickener is a urea thickener. The content of the thickener is 5 to 30 parts by weight based on the total amount of the base oil and the thickener.Type: GrantFiled: March 25, 2005Date of Patent: January 14, 2014Assignee: NTN CorporationInventor: Takayuki Kawamura
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Patent number: 8513171Abstract: A lubricant composition, which is low in friction, does not have an attacking property against polyamide resin, etc., is excellent in heat resistance, and especially does not undergo deterioration or loss of the respective characteristics in a short term when used under a high temperature environment, is provided along with a speed reduction gear and an electric power steering apparatus that use the lubricant composition. The lubricant composition has blended therein a synthetic hydrocarbon oil, a urea thickener, zinc stearate, and a sulfur-based antioxidant. A speed reduction gear has a portion of engagement of a small gear and a large gear filled with the lubricant composition. In an electric power steering apparatus, an output of a steering assisting electric motor is speed reduced and transmitted to a steering mechanism via the speed reduction gear.Type: GrantFiled: October 14, 2009Date of Patent: August 20, 2013Assignees: JTEKT Corporation, Kyodo Yushi Co., Ltd.Inventors: Ryuji Nakata, Miwa Hokii, Mitsuhiro Kakizaki, Daisuke Tsutsui
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Patent number: 8476204Abstract: A Lubricant comprises a carboxylic-acid-amide which is based on aliphatic unbranched, alicyclic and/or aromatic chains with chain length from 2 to 60 carbon atoms.Type: GrantFiled: November 23, 2005Date of Patent: July 2, 2013Assignee: AB SKFInventors: Ebbe Malmstedt, Walter Holweger, Hubertus Peek, Ingemar Strandell, Arno Stubenrauch, Bernhard Bauer, Frank Fiddelaers, Albert Van Den Kommer
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Patent number: 8377858Abstract: The invention provides a grease composition for constant velocity joint containing the components (a) to (g) below and a constant velocity joint containing said composition. (a) a diurea thickening agent having the following formula (1): R1NH—CO—NH—C6H4-p-CH2—C6H4-p-NH—CO—NHR2??(1) wherein R1 and R2 may be the same or different and represent C8-C20 alkyl groups, (b) an ester synthetic oil, (c) a mineral oil and/or a synthetic hydrocarbon oil, (d) a molybdenum dialkyldithiocarbamate, (e) molybdenum disulfide, (f) a polytetrafluoroethylene, and (g) a zinc dithiophosphate compound. The grease composition of the invention reduces variations in rotational resistance of the constant velocity joint at a low temperature.Type: GrantFiled: May 21, 2008Date of Patent: February 19, 2013Assignees: Kyodo Yushi Co., Ltd., NTN CorporationInventors: Mitsuhiro Kakizaki, Shinya Kondo, Shinichi Takabe, Takaaki Shibata
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Patent number: 8242065Abstract: A grease composition, which comprises a base oil selected from at least one of synthetic hydrocarbon oil, ester-based synthetic oil, and ether-based synthetic oil; a thickening agent selected from at least one of lithium-based soap, lithium-based complex soap, and a urea-based compound; polytetrafluoroethylene resin powders having a number average molecular weight Mn of 20,000-100,000; and zinc dialkyldithiophosphate having straight or branched alkyl groups of at least 3 carbon atoms, preferably 5-13 carbon atoms, and more preferably 8-12 carbon atoms, has not only a distinguished lubricability, when applied to plastic members, but also a distinguished durability as given by change in friction coefficient and wear loss, after the sliding test.Type: GrantFiled: October 2, 2007Date of Patent: August 14, 2012Assignee: NOK Kluber Co., Ltd.Inventors: Wataru Sawaguchi, Toshio Nitta
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Patent number: 8241415Abstract: The present invention is directed to a wax formulation for use in lignocellulosic products, which impart improved properties such as dimensional stability when the products are exposed to moisture. The wax formulations include a wax and a surface tension/interfacial tension reducing agent comprising one or more of a fluorinated compound having two to six carbon atoms, an alkylphenol alkoxylate or an ethoxylated acetylenic diol.Type: GrantFiled: June 23, 2006Date of Patent: August 14, 2012Assignee: Momentive Specialty Chemicals Inc.Inventors: Steven J. Wantling, Bonnie Zepka, Michael A. Greno, Thomas Michael Donlon
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Patent number: 8242063Abstract: A lubricating grease composition comprising base oil and a blended thickener which comprises, as the thickener constituents, (a) one or more urea-type compounds; (b) one or more fatty acid metal salts; and (c) at least one type of amide compound selected from the group comprised of aliphatic amides and aliphatic bisamides shown by the general formulae (1) and (2): R1CONH2??(1) R1CONHR2NHCOR1??(2) wherein R1 denotes a saturated or unsaturated alkyl group having from 15 to 17 carbon atoms and R2 denotes a methylene group or an ethylene group and wherein the blending weight proportions of (a), (b) and (c) are in the ratio of a/(b+c) is in the range of from 0.20 to 10 wherein (1) constituent (a) has a blending weight ratio in the range of from 1 to 10; (2) constituent (b) has a blending weight ratio in the range of from 0.5 to 2.5; and (3) constituent (c) has a blending weight ratio in the range of from 0.5 to 2.5.Type: GrantFiled: April 26, 2006Date of Patent: August 14, 2012Assignee: Shell Oil CompanyInventors: Yasushi Kawamura, Toshiki Satou, Keiji Tanaka
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Patent number: 8183191Abstract: A grease composition containing a lubricant base oil, diurea compounds represented by the following general formulas (1) to (3), and at least one species selected from the group consisting of paraffin oxides and phosphorus compounds; wherein respective contents of the diurea compounds represented by the following general formulas (1) to (3) satisfy conditions defined by the following expressions (4) and (5); and wherein the total content of the paraffin oxides and phosphorus compounds is 0.1 to 15 mass % based on the total amount of the grease composition: where R1 is a hydrocarbon group containing an aromatic ring, R2 is a divalent hydrocarbon group, and R3 is a hydrocarbon group containing an aliphatic ring; 5?W1+W2+W3?30??(4) 0.3?(W1+0.5×W2)/(W1+W2+W3)?0.7??(5) where W1, W2, and W3 are respective contents (mass %) of the diurea compounds represented by general formulas (1) to (3) based on the total amount of the grease composition.Type: GrantFiled: April 22, 2003Date of Patent: May 22, 2012Assignee: Nippon Oil CorporationInventors: Hirotsugu Kinoshita, Souichi Nomura, Takashi Arai, Kiyomi Sakamoto
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Patent number: 8044005Abstract: A rolling bearing, for use in household appliances, having a high degree of quietness, an excellent durability at high temperatures and rotational speeds, a low torque, and excellent fretting property; and a lubricant composition which can be sealed into the rolling bearing. The lubricant composition includes a base oil and a thickening agent. The base oil is a mixed oil having the following characteristics of (a) to (c): (a) The base oil consists essentially of a synthetic hydrocarbon oil and an ester oil; (b) A kinematic viscosity of the mixed oil at 40° C. is 40 to 70 mm2/second; (c) A mixing weight ratio between the ester oil of the mixed oil and the synthetic hydrocarbon oil thereof is 30:70 to 70:30. The thickening agent comprises a diurea compound shown by a formula (1): where R1 and R3 are a straight-chain alkyl groups having 9 to 22 carbon atoms respectively, and R2 is an aromatic hydrocarbon group having 6 to 15 carbon atoms. The lubricant composition is sealed into the rolling bearing.Type: GrantFiled: May 24, 2004Date of Patent: October 25, 2011Assignee: NTN CorporationInventors: Hidenobu Mikami, Seiji Okamura, Hiroki Iwamatsu, Masashi Mitsuoka
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Patent number: 7923421Abstract: Polyurea compounds are prepared by reacting amines and polyisoyanates in the presence of a liquid diluent in a high-pressure impingement mixing device under conditions sufficient to produce polyurea compounds having the consistency of a powder and in which diluent is dispersed.Type: GrantFiled: January 23, 2007Date of Patent: April 12, 2011Assignee: ExxonMobil Research and Engineering CompanyInventor: Mark W. Baum
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Patent number: 7833954Abstract: The present application is directed to a lubricant composition comprising a major amount of a base oil; and a lead corrosion inhibiting amount of a reaction product of a hydrocarbyl carbonyl compound and an amine compound chosen from guanidines, ureas and thioureas; with the proviso that the lubricant is essentially free of zinc dialkyldithiophosphate wear inhibitors, and substantially free of chlorinated paraffins and calcium mannich phenate.Type: GrantFiled: February 11, 2008Date of Patent: November 16, 2010Assignee: Afton Chemical CorporationInventor: David A. Hutchison
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Patent number: 7790661Abstract: Reaction of a carboxylic acid-containing polymer with certain aromatic amines results in dispersant viscosity modifiers with improved soot handling performance in heavy-duty diesel engines, compared with reaction with non-aromatic amines.Type: GrantFiled: July 29, 2005Date of Patent: September 7, 2010Assignee: The Lubrizol CorporationInventors: Michael J. Covitch, John K. Pudelski, Christopher Friend, Matt D. Gieselman, Renee A. Eveland, Mary Galic Raguz, Barton J. Schober
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Patent number: 7709427Abstract: Disclosed are a lubricant composition to which is added as buffer particles to a lubricant polyurethane resin particles obtained by reacting and synthesizing long-chain polyol having a number-average molecular weight of not less than 500, a crosslinking agent having three or more active hydrogen groups in one molecule, and polyisocyanate as buffer particles, a speed reduction gear filled with the lubricant composition, and an electric power steering apparatus having the speed reduction gear incorporated therein, wherein noise produced by the speed reduction gear can be made lower than ever before irrespective of the magnitude of backlash in a case where a worm and a worm wheel are combined with each other and without complicating the configuration of the speed reduction gear by the buffer action of the buffer particles added to the lubricant composition, thereby making it possible to reduce noise produced in an automobile due to the electric power steering apparatus at low cost.Type: GrantFiled: March 17, 2005Date of Patent: May 4, 2010Assignees: Koyo Seiko Co., Ltd., Nippon Polyurethane Industry Co., Ltd.Inventors: Kouji Kitahata, Naoki Uchida, Mitsuo Yoneda, Masahiro Hayashi
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Publication number: 20100084597Abstract: The invention relates to the defoaming of ionic liquids and also to compositions comprising at least one ionic liquid and at least one antifoam and, if appropriate, a solvent and/or further auxiliaries or additives.Type: ApplicationFiled: February 3, 2009Publication date: April 8, 2010Inventors: Peter Schwab, Christian Mund, Kerstin Kugel, Hans-Juergen Koehle, Rene Haensel
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Patent number: 7414014Abstract: A method and system to reduce fuel consumption and environmental impact in a two-stroke engine. Fresh system oil having a TBN less than 10 is provided and used in the two-stroke engine to produce partially used system oil. The partially used system oil is withdrawn from the two stroke engine and at least one friction modifier is added to at least some of the withdrawn partially used system oil, wherein the addition of the at least one friction modifier reduces the friction coefficient of the withdrawn system oil, resulting in a system oil having reduced friction. The system oil with reduced friction is combined with partially used system oil remaining in said two-stroke and the combined system oil is used to lubricate pistons of said two-stroke engine.Type: GrantFiled: December 30, 2004Date of Patent: August 19, 2008Assignee: A.P. Moeller-Maersk/ASInventors: Giuseppe Natoli, Giulio Giovanni Pometto, Alfio Bonciolini, Hans Heinrich Petersen, Jørn Dragsted, Claus Martin Olesen, Klaus-Werner Damm
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Patent number: 7329302Abstract: Particulate lubricants are disclosed which comprise discrete particles of a fatty monoamide, especially oleamide and discrete particles of at least one other powder metallurgy lubricant, which provide a synergistic free-flowing composition; there are also provided novel compositions of matter for forming sintered metal components comprising a mixture of sinterable powdered metal and the particulate lubricants.Type: GrantFiled: November 5, 2004Date of Patent: February 12, 2008Assignee: H. L. Blachford Ltd./LteeInventor: James M. McCall
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Patent number: 7271135Abstract: A rolling bearing, for application in electric auxiliaries for a car, durable owing to high resistance to high temperatures and capable of restraining noises from being generated at low temperatures; and lubricant grease, for low and high temperature application, which can be sealed in the rolling bearing. The lubricant grease includes 100 parts by weight of a mixture of fluorine-containing lubricant grease containing perfluoropolyether oil as a base oil thereof and fluorocarbon resin powder as a thickening agent thereof and urea-containing lubricant grease containing polyester oil as a base oil thereof and a urea compound as a thickening agent thereof; and 3 to 30 parts by weight of polyolefin oil added to the mixed grease. The polyolefin oil has a pour point of not more than ?50° C. and a kinematic viscosity of 10 to 70 mm2/s at 40° C.Type: GrantFiled: April 8, 2004Date of Patent: September 18, 2007Assignee: NTN CorporationInventors: Mitsunari Asao, Masaki Egami
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Patent number: 6780209Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermeType: GrantFiled: January 24, 2000Date of Patent: August 24, 2004Assignee: The Lubrizol CorporationInventors: Brian B. Filippini, Richard M. Lange, Bryan A. Grisso, Bryn Hird
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Patent number: 6444622Abstract: Mixtures of the reaction product of at least one C5-C60 carboxylic acid and at least one amine selected from the group consisting of guanidine, aminoguanidine, urea, thioruea and salts thereof and a phosphorus-containing dispersant are useful as gear oil additives. Lubricant formulations containing said mixtures exhibit excellent low and high temperature rheology and are particularly suited for use in automotive and industrial gear applications. Lubricants of the present invention exhibit improved performance properties such as increased axle efficiencies and lower axle temperatures compared to lubricant formulations that do not contain said mixtures.Type: GrantFiled: September 11, 2001Date of Patent: September 3, 2002Assignee: Ethyl CorporationInventor: Vasudevan Balasubramaniam
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Patent number: 6413919Abstract: The invention concerns a process for the preparation of a lubricant combination including to steps of selecting a first and a second lubricant; mixing the lubricants and subjecting the mixture to conditions for adhering the particles of the second lubricant to the particles of the first lubricant in order to form a lubricant combination of aggregate particles having a core of the first lubricant, the surface of the core being coated with particles of the second lubricant. The invention also concerns a surface modified lubricant combination including a core of a first lubricant, the surface of which is coated with particles of a second lubricant.Type: GrantFiled: January 26, 2001Date of Patent: July 2, 2002Assignee: Höganäs ABInventor: Hilmar Vidarsson
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Patent number: 6303547Abstract: The reaction product of at least one C5-C60 carboxylic acid and at least one amine selected from the group consisting of guanidine, aminoguanidine, urea, thioruea and salts thereof is useful as a gear oil additive. The lubricant formulations exhibit excellent low and high temperature rheology and are particularly suited for use in automotive and industrial gear applications. Lubricants of the present invention exhibit improved performance properties, such as increased axle efficiencies and lower axle temperatures, improved limited slip performance, reduced chatter, improved frictional durability and/or improved power divider performance compared to lubricant formulations that do not contain said reaction products.Type: GrantFiled: September 19, 2000Date of Patent: October 16, 2001Assignee: Ethyl CorporationInventor: Vasudevan Balasubramaniam
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Publication number: 20010027170Abstract: The invention concerns a process for the preparation of a lubricant combination including to steps of selecting a first and a second lubricant; mixing the lubricants and subjecting the mixture to conditions for adhering the particles of the second lubricant to the particles of the first lubricant in order to form a lubricant combination of aggregate particles having a core of the first lubricant, the surface of the core being coated with particles of the second lubricant. The invention also concerns a surface modified lubricant combination including a core of a first lubricant, the surface of which is coated with particles of a second lubricant.Type: ApplicationFiled: January 26, 2001Publication date: October 4, 2001Inventor: Hilmar Vidarsson
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Patent number: 6231635Abstract: The invention concerns a lubricant for powder metallurgical compositions containing 10-60% by weight of a lithium salt of a fatty acid; 0-40% by weight of a zinc salt of a fatty acid and 40-90% by weight of a fatty acid bis-amide. 10-60% by weight of the lubricant is made up by the lithium and the zinc salt.Type: GrantFiled: February 1, 1999Date of Patent: May 15, 2001Assignee: Höganäs ABInventors: Masaaki Suzuki, Toshio Serita, Norio Ukai, Hiroyasu Saitoh
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Patent number: 5783531Abstract: A method is disclosed for improving the thickener yield in soap thickened polyalphaolefin base oil greases comprising the steps of (a) producing a simple or complex soap thickener in a quantity of a first PAO of viscosity lower than that of the base oil component in the final grease composition to produce a thickened PAO and (b) adding to the thickened PAO a quantity of a second PAO of viscosity higher than that desired of the base oil component in the final grease composition sufficient to produce a final grease product having the desired base oil viscosity.Type: GrantFiled: March 28, 1997Date of Patent: July 21, 1998Assignee: Exxon Research and Engineering CompanyInventors: David Leslie Andrew, Brian Leslie Slack
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Patent number: 5639716Abstract: Oil-soluble dispersant additives are disclosed. The additives comprise the reaction product of a functionalized 1-butene copolymer and at least one nucleophilic reactant selected from amines, amino alcohols, alcohols, and reactive metal compounds. The functionalized copolymer has within its structure at least one acyl functional group selected from the group consisting of C.sub.4 to C.sub.10 dicarboxylic acids and derivatives thereof and C.sub.3 to C.sub.10 monocarboxylic acids and derivatives thereof. The 1-butene copolymer is derived from 1-butene and at least one other .alpha.-olefin of formula CH.sub.2 .dbd.CHR', wherein R' is methyl or a C.sub.3 to C.sub.12 linear or branched alkyl group. The copolymer has a number average molecular weight of at least about 700, a molecular weight distribution of less than 5, and ethenylidene groups terminating at least about 30% of all polymer chains.Type: GrantFiled: June 9, 1994Date of Patent: June 17, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Albert Rossi, Jacob I. Emert, Warren A. Thaler