With Diverse Amine Oxide, Quaternary, Or Zwitterion Nitrogen Component Patents (Class 510/124)
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Patent number: 6264931Abstract: A 2-in-1 conditioning shampoo includes an anionic surfactant and a cationic hair conditioning agent. The cationic hair conditioning agent is a fatty aliphatic quaternary ammonium compound having ester linkages. The cationic hair conditioning agent can be prepared by reacting an alkanol amine with a fatty acid or fatty acid ester having an aliphatic group of from about 11 to about 24 carbon atoms and thereafter quaternizing the resulting esteramine with an alkylating agent.Type: GrantFiled: May 10, 1999Date of Patent: July 24, 2001Assignee: Akzo Nobel nv.Inventors: Ralph Franklin, Paul Iacobucci, Dale Steichen, Diana Tang, Phuong-Nga Trinh
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Patent number: 6255264Abstract: An aqueous liquid cleansing and moisturising composition comprising: a) a surface active agent selected from anionic, nonionic, zwitterionic and cationic surface active agents, soap and mixtures thereof; b) a benefit agent; and c) a cationic polymer characterised in that the cationic polymer is present in the composition at levels of 0.05-3.0% by weight, and that the benefit agent is present in the neat composition as aggregated particles.Type: GrantFiled: December 13, 1999Date of Patent: July 3, 2001Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Olivier Fleurot, Robert Stanley Lee
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Publication number: 20010004632Abstract: Hair conditioning formulations containing a particular combination of cationic surfactants, have improved hair care benefits while maintaining excellent in-use characteristics. The compositions contain a first cationic surfactant such as cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride and behenyl trimethyl ammonium chloride. A second hydrophilically substituted cationic surfactant such as cocamidopropyl-N-2-hydroxyethylcarbamoylmethyldimethylammonium chloride, and a lipid material such as cetyl alcohol. Although formulations of the invention are based principally on cationic surfactant, and generally contain no anionic or amphoteric surfactant, they provide an acceptable level of cleaning and lathering whilst still conveying the wet slippy feel desired by consumers in connection with conventional hair conditioners.Type: ApplicationFiled: December 15, 2000Publication date: June 21, 2001Inventor: Colin Christopher Giles
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Patent number: 6218345Abstract: Personal cleansing compositions comprising a thickening system consisting essentially of hydrophobically modified water-soluble associative polymer and polar oil having a required HLB of at least 12, a nonionic polyhydroxy fatty acid amide surfactant, a water-soluble surfactant other than the polyhydroxy fatty acid amide surfactant, and water, wherein the polar oil has an average carbon chain length of from about 12 to about 16 carbon atoms and wherein the water-soluble surfactants have an average carbon chain of from about 10 to about 18 carbon atoms. These compositions may also comprise a perfume or cosmetic oil, or a hydrotrope. The compositions of the present invention deliver excellent product thickening and rheological attributes, in storage, in dispensing and in use, in combination with good efficacy benefits such as excellent rinsibility, mildness, skin conditioning, skin moisturizing, product stability, cleansing and lathering.Type: GrantFiled: December 30, 1998Date of Patent: April 17, 2001Assignee: The Procter & Gamble CompanyInventors: Alan Brooks, Charles Marie Alain Du Reau
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Patent number: 6218346Abstract: Disclosed are hair care compositions and methods for preparing such compositions which provide the benefits of cleaning, conditioning, curl retention, styling and setting properties simultaneously to hair in the application of a single product. The hair care compositions contain fatty alkyl amine salts, long chain quaternary ammonium salts and mixtures thereof of anionic styling polymers in a non-anionic surfactant system, wherein the surfactant system contains nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof. The styling, setting and conditioning agents are present in the form of fatty alkyl amine salts or fatty quaternary ammonium salts which form anionic styling polymer particulate networks upon dilution in water. These networks are dispersed in the aqueous non-anionic surfactant system and are stabilized and thickened by optional swellable polymer thickening agents.Type: GrantFiled: October 3, 1997Date of Patent: April 17, 2001Assignee: Stepan CompanyInventors: Branko Sajic, Y. Kameshwer Rao
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Patent number: 6200937Abstract: Detergent compositions, including, but not limited to, anti-residue shampoos, are provided which include one or more anionic surfactants, an anionic polymer, a mono cationic conditioning agent, and a cationic polymer. These shampoos are preferably clear. Additionally, there is provided a recirculatory batch processor which includes a disperser and at least one pump selected from a supply pump and a return pump. The pump is in communication with the disperser. Furthermore, a recirculatory batch process is provided which includes the steps of delivering, at a first rate, a liquid from a tank to a recirculatory batch processor as described above; during the delivery, dispersing solids into the liquid to produce a liquid containing dispersed solids; and during the delivery, returning, at a second rate, the liquid containing dispersed solids to the tank; wherein the second rate is greater than the first rate.Type: GrantFiled: June 9, 1998Date of Patent: March 13, 2001Assignee: Neutrogena CorporationInventors: Robert Brennan, Abizer Gaslightwala, Nelson L. Perassinoto, Rafael Delgado, Arthur Pellegrino, Steve Aridgides, Charles L. Adams, Carol J. Collins
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Patent number: 6191083Abstract: Personal cleansing compositions comprise a thickening system consisting essentially of associative polymer which is a hydrophobically modified water-soluble associative polymer and polar oil having a required HLB of at least 12, a water-soluble surfactant, optionally a cationic polymeric skin conditioning agent, and water, wherein the polar oil has an average carbon chain length of from about 12 to about 16 carbon atoms and wherein the water-soluble surfactants have an average carbon chain of from about 10 to about 18 carbon atoms. These compositions may also comprise a hydrotrope. These compositions may optionally comprise a perfume or cosmetic oil. These compositions deliver excellent product thickening and rheological attributes, in storage, in dispensing and in use, in combination with good efficacy benefits such as mildness, a moisturized skin feel, rinsibility, skin conditioning, product stability and lather attributes.Type: GrantFiled: December 30, 1998Date of Patent: February 20, 2001Assignee: The Procter & Gamble CompanyInventors: Alan Brooks, Charles Marie Alain Du Reau
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Patent number: 6153569Abstract: This invention relates to the use of aminofunctional silicone microemulsions to make optically clear compositions. More particularly this invention is directed to optically clear shampoo compositions comprising (A) an aminofunctional silicone microemulsion having an average particle size of less than 0.06 microns, (B) at least one anionic detersive surfactant, (C) at least one foam boosting agent, (D) at least one pH adjusting agent, (E) at least one thickening agent, and (F) water. The optically clear silicone compositions of this invention are useful in the hair care industry, especially as shampoos.Type: GrantFiled: July 24, 1998Date of Patent: November 28, 2000Assignee: Dow Corning CorporationInventor: Daniel Joseph Halloran
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Patent number: 6147038Abstract: This invention relates to the use of aminofunctional silicone microemulsions to make optically clear hair conditioning compositions. More particularly this invention is directed to optically clear hair conditioning compositions comprising an aminofunctional microemulsion, at least one long-chain quaternary amine salt, and water. The optically clear silicone compositions of this invention are useful in the hair care industry, especially as hair conditioners.Type: GrantFiled: July 24, 1998Date of Patent: November 14, 2000Assignee: Dow Corning CorporationInventor: Daniel Joseph Halloran
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Patent number: 6117828Abstract: The invention discloses handwash or personal wash shampoo compositions comprising surfactant(s), cationic wheat protein and an antibacterial agent. The cationic wheat protein provides enhanced skin feel relative to other proteins.Type: GrantFiled: July 2, 1999Date of Patent: September 12, 2000Assignee: Unilever Home & Personal Care USAInventors: Sudhakar Puvvada, Michael Slayton
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Patent number: 6090773Abstract: A conditioning shampoo composition comprised of a mixture of anionic and amphoteric surfactants and optional conditioners which imparts cleansing, wet detangling, dry detangling and manageability to hair and which is relatively non-irritating and thus suitable for use by young children and adults having sensitive skin and eyes.Type: GrantFiled: January 24, 1997Date of Patent: July 18, 2000Assignee: Johnson & Johnson Consumer Products, Inc.Inventors: Elvin R. Lukenbach, Victoria F. Dole, Glenn A. Nystrand, Laura McCulloch, William D. Allan, Jonathan R. Hill, Charles J. Taylor
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Patent number: 6074996Abstract: A liquid personal cleansing composition comprising: (a) from about 1% to about 15% by weight of short chain alkyl sulphate surfactant having an average of from 8 to 10 carbon atoms in the alkyl chain and mixtures thereof; (b) from about 1% to about 60% by weight of water-soluble auxiliary surfactant selected from anionic surfactant other than C.sub.8 to C.sub.10 alkyl sulphate, nonionic, zwitterionic and amphoteric surfactants and mixtures thereof; (c) from about 0.01% to about 5% by weight of cationic polymeric skin conditioning agent; and (d) water. The products demonstrate excellent in-use efficacy benefits including mildness, a moisturised skin feel, excellent rinsibility and good product stability and lather attributes.Type: GrantFiled: November 26, 1997Date of Patent: June 13, 2000Assignee: The Procter & Gamble CompanyInventors: Russell Phillip Elliott, Matthew Thomas Green, Christopher David Leahy
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Patent number: 6046145Abstract: Cleansing surfactant compositions are provided which cleanse, condition and moisturize the skin and hair and which exhibit a low degree of irritation to the eyes. These cleansing compositions preferably contain the following components:a. a surfactant portion containing:1. a nonionic surfactant;2. an amphoteric surfactant; and3. an anionic surfactant;the total concentration of said nonionic, amphoteric and anionic surfactants being present in the composition in an amount from about 5 to about 20 percent by weight of said cleansing composition; andb. a substantive humectant present in the composition in an amount from about 0.01 to about 3 percent by weight of said cleansing composition.The substantive humectants used in the present invention are preferably cationically charged polyols derived from sugars or sugar derivatives and they further comprise a long chain alkyl or alkenyl group having from about 6 to about 22 carbon atoms.Type: GrantFiled: March 18, 1999Date of Patent: April 4, 2000Assignee: Johnson & Johnson Consumer Companies, Inc.Inventors: Delores M. Santora, Diana L. Friscia
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Patent number: 6043203Abstract: Detergent compositions comprised of an alkyl polyglycoside and an ester quat corresponding to formula (II) ##STR1## wherein R.sup.2 CO is an aliphatic acyl radical containing 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, n=2 or 3 and X stands for halide, methosulfate or methophosphate ion are provided which are useful for the production of surface-active agents and for the enhanced recovery of crude oil.Type: GrantFiled: September 11, 1998Date of Patent: March 28, 2000Assignees: Henkel Kommanditgesellschaft auf Aktien, Pulcra S.A., Henkel CorporationInventors: Allen D. Urfer, Oriol Ponsati Obiols, Nuria Bonastre
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Patent number: 6022836Abstract: A detergent hair composition of the type including, in a cosmetically acceptable medium, a washing base and at least one cationic polymer, and additionally comprising at least one water-soluble or water-dispersible silicone compound including a silicone main chain onto which at least one hydrocarbon group of anionic nature is grafted.This composition may be applied to clean, care and style hair and gives an improved styling effect.Type: GrantFiled: June 5, 1996Date of Patent: February 8, 2000Assignee: L'OrealInventors: Claude Dubief, Daniele Cauwet-Martin
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Patent number: 6017860Abstract: Disclosed are hair care compositions and methods for preparing such compositions which provide the benefits of cleaning, conditioning, curl retention, styling and setting properties simultaneously to hair in the application of a single product. The hair care compositions contain fatty alkyl amine salts, long chain quaternary ammonium salts and mixtures thereof of anionic styling polymers in a non-anionic surfactant system, wherein the surfactant system contains nonionic surfactants, semi-polar nonionic surfactants, amphoteric surfactants and mixtures thereof. The styling, setting and conditioning agents are present in the form of fatty alkyl amine salts or fatty quaternary ammonium salts which form anionic styling polymer particulate networks upon dilution in water. These networks are dispersed in the aqueous non-anionic surfactant system and are stabilized and thickened by optional swellable polymer thickening agents.Type: GrantFiled: April 15, 1996Date of Patent: January 25, 2000Assignee: Stepan CompanyInventors: Branko Sajic, Y. Kameshwer Rao
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Patent number: 6010990Abstract: The invention provides compositions for providing body, fullness and texture to otherwise fine or very fine keratinous fibers, particularly human hair. The compositions of the present invention have a high pH, e.g., about 8 to about 10 when the compositions contain cationic polymer, and a pH of about 8 to about 14, preferably about 8.5 to about 13, and more preferably, about 8.5 to about 10 when the compositions contain no cationic polymer. The compositions include one or more nonionic and/or cationic polymers, which, in combination with the high pH of the composition, lift the hair cuticle and allow the deposition of polymer, thus resulting in increased fullness and texture to the hair. The compositions of the present invention may be in the form of known hair care products such as, for example, shampoos, rinses and conditioners. In addition, the compositions can be formulated, for example, as lotions or creams, and the like, for consumer use.Type: GrantFiled: March 5, 1998Date of Patent: January 4, 2000Assignee: Bristol-Myers Squibb CompanyInventors: Peter J. Rousso, Paul S. Wallace
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Patent number: 5998344Abstract: Disclosed for cleaning hard surfaces is a detergent gel containing:(a) a detergent composition without thickeners having(i) a first surfactant, wherein the first surfactant is a non-ionic glycolipid, and(ii) a second surfactant, wherein the second surfactant is a charged surfactant, wherein the ratio of the first surfactant and the second surfactant is 1:10-10:1;(b) water, wherein the detergent composition is mixed with a sufficient amount of water to induce a phase change from a liquid phase to a gel phase; and(c) one or more enzymes.Type: GrantFiled: January 8, 1998Date of Patent: December 7, 1999Assignee: Novo Nordisk A/SInventors: Poul N.o slashed.rgaard Christensen, Bo Kalum, Otto Andresen
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Patent number: 5977036Abstract: Disclosed are hair styling shampoo compositions which comprise from about 5% to about 50% by weight of a surfactant selected from the group consisting of anionic surfactants, zwitterionic or amphoteric surfactants having an attached group that is anionic at the pH of the composition, and combinations thereof; from about 0.025% to about 3% by weight of an organic cationic polymer having a cationic charge density of from about 0.2 meq/gm to about 7 meq/gm and a molecular weight of from about 5,000 to about 10 million; from about 0.1% to about 10% by weight of a water-insoluble hair styling polymer; from about 0.1% to about 10% by weight of a water-insoluble volatile solvent; and from about 0.005% to about 2.0% by weight a crystalline hydroxyl-containing stabilizing agent; and from about 26.5% to about 94.9% by weight water. The composition provides improved spreading efficiency of the styling polymer onto hair, thus providing improved styling performance from the shampoo composition.Type: GrantFiled: February 3, 1998Date of Patent: November 2, 1999Assignee: The Procter & Gamble CompanyInventor: Susan Marie Guskey
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Patent number: 5977037Abstract: A personal cleansing product comprising:(a) from about 0.1% to about 20% of anionic surfactant,(b) from about 0.1% to about 20% of amphoteric surfactant,(c) from about 0.5% to about 25% of a vegetable oil adduct and,(d) water.The vegetable oil adduct can be made by Diels-Alder addition of a conjugated, elaidinized form of the vegetable oil with acrylic acid, fumaric acid or maleic anhydride. The preferred adduct is maleated soybean oil. The compositions provide excellent in-use and efficacy benefits including cleansing and lathering as well as improved mildness and skin conditioning.Type: GrantFiled: April 22, 1997Date of Patent: November 2, 1999Assignee: The Procter & Gamble CompanyInventors: Michel Joseph Giret, Anne Langlois, Roland Philip Duke
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Patent number: 5968890Abstract: An aqueous liquid detergent composition comprises a mixture of synthetic anionic and amphoteric surfactants in a weight ratio within the range 4:1 to 0.1:1 and a polyethylene glycol having a molecular weight of not more than 100,00. The later component boosts the lather of the composition during use. It may also enhance the mildness of the formulation.Type: GrantFiled: March 14, 1997Date of Patent: October 19, 1999Assignee: Lever Brothers CompanyInventors: John George Chambers, Izuma Kutsuwa, David Serridge
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Patent number: 5955406Abstract: The subject of the present invention is compositions for washing keratinous materials, in particular the hair and/or the skin, containing in an aqueous medium:A) at least one synthetic oil chosen from:the isoparaffins of the formula: ##STR1## where n is between 2 and 16 inclusive; B) an agent for suspending the oil defined under A), chosen from:(i) the compounds of formula:R--X (III)in which:R is a long carbon chain aliphatic radical, optionally interrupted by one or more oxygen atoms, and X is a carboxylic, sulphuric or phosphoric acid residue or a radical derived from a carboxylic acid or an amide;(ii) amine oxides;(iii) biopolysaccharides;C) a surface-active agent possessing detergent properties.Type: GrantFiled: March 25, 1996Date of Patent: September 21, 1999Assignee: L'OrealInventors: Claude Dubief, Daniele Cauwet
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Patent number: 5942478Abstract: This invention relates to microbicidal and sanitizing soap compositions. More particularly, the invention relates to microbicidal and sanitizing soap compositions that incorporate agents with tuberculocidal properties in ready-to-use form that has gel properties or thixotropic-properties and to soap concentrate compositions suitable for dilution in or with water or non-aqueous diluent to produce gel-like or thixotropic solutions or dispersions ranging from free flowing to solidified forms. The ready-to-use compositions and the concentrate compositions are applied for purposes of personal or animal hygiene or sanitizing on hair, hands and skin or other body parts, or are applied on inanimate surfaces and objects that need to be sanitized.Type: GrantFiled: September 4, 1997Date of Patent: August 24, 1999Inventor: John A. Lopes
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Patent number: 5942477Abstract: A personal cleansing product comprising:(a) from about 5% to about 50% by weight of a mixed surfactant system which comprises:(i) from about 1% to about 20% by weight of composition of anionic surfactant, and(ii) from about 1% to about 20% by weight of composition of amphoteric surfactant,(b) from about 3% to about 40% by weight of an insoluble nonionic oil or wax, and(c) water,wherein the anionic surfactant and amphoteric surfactant together comprise from about 5% to about 30% by weight of the composition, the weight ratio of anionic surfactant:amphoteric surfactant is in the range from about 1:5 to about 20:1, the weight ratio of total surfactant: nonionic oil or wax is in the range from about 10:1 to about 1:3, and wherein the composition is in the form of an oil-in-water emulsion having a viscosity in the range from 10,000 to 40,000 cps and a yield point of at least 50 dyne/cm.sup.2. The cleansing products demonstrate excellent lathering, mildness, stability, rinsibility and conditioning benefits.Type: GrantFiled: April 28, 1998Date of Patent: August 24, 1999Assignee: The Procter & Gamble CompanyInventors: Michel Joseph Giret, Anne Langlois, Roland Philip Duke
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Patent number: 5939378Abstract: This invention relates to a method of manufacturing a concentrated aqueous solution of an amine oxide and the use of the solution in cleaning compositions.Type: GrantFiled: July 30, 1998Date of Patent: August 17, 1999Assignee: Colgate Palmolive CompanyInventors: Orum D. Stringer, Syed Hasain Abbas, Ravi Subramanyam
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Patent number: 5939374Abstract: A blooming type, hard surface cleaning concentrate composition includes as a blooming system the following essential constituents: a cationic quaternary ammonium surfactant; an anionic carboxylated alcohol alkoxylate surfactant; a surfactant compatibilizing agent; and, water. Further optional constituents may also be included including additional anionic, cationic, nonionic, amphoteric and zwitterionic surfactants especially to provide a further detersive effect; organic solvents such as alcohols, ethers, glycol ethers to aid in stain solubilization, as well as conventional additves such as coloring agents including dyes, fragrances, and others. In preferred embodiment, the concentrate compositions and cleaning compositions also provide a germicidal effect to hard surfaces. The cleaning concentrates exhibit a charateristic bloom when admixed to a larger volume of water, yet are substantially clear and shelf stable as concentrate compositions.Type: GrantFiled: November 3, 1997Date of Patent: August 17, 1999Assignee: Reckitt & Colman Inc.Inventors: Alan Francis Richter, Frederic Albert Taraschi
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Patent number: 5925604Abstract: Novel ultra-mild cold pearlizing concentrates provide pearlescent personal hair and skin compositions such as shampoos and beauty soaps with added luster and sheen.Type: GrantFiled: July 9, 1996Date of Patent: July 20, 1999Assignee: Rhodia Inc.Inventors: Pu Chen, Joseph Niu, Siew Fang Yoong
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Patent number: 5922659Abstract: A cleanser composition comprising a phosphate type surfactant and an amide ether carboxylic acid as the essential components. This cleanser composition is lowly irritant to the skin etc., and excellent in lathering property, gives creamy foam in quality, and can give an excellent feeling to the skin cleansed even when it is used in hard water.Type: GrantFiled: January 27, 1997Date of Patent: July 13, 1999Assignee: Kao CorporationInventors: Chikako Matsumoto, Tadashi Moriyama, Takatoshi Kobayashi, Yuichi Hioki, Takashi Imamura
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Patent number: 5922672Abstract: This invention relates to a method of manufacturing a concentrated aqueous solution of an amine oxide and the use of the solution in cleaning compositions.Type: GrantFiled: September 3, 1998Date of Patent: July 13, 1999Assignee: Colgate-Palmolive CoInventors: Orum D. Stringer, Syed Hasain Abbas, Ravi Subramanyam
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Patent number: 5910477Abstract: An aqueous viscous composition comprises: (a) from 0.5% to 1.2% of an ingredient comprising an amine, amine oxide or a mixture thereof; (b) between 4% and 7% of an ingredient comprising a secondary alkyl sulfate, secondary alkyl sulfonate, primary monobranched alkyl sulfate, primary monobranched alkyl sulfonate or mixture thereof, (c) between 2% and 4% hydrotrope; and (d) between 4% and 8% citric acid. The amount of component (b) is in excess of component (a), and the composition has a pH of from 3 to 4. A 1.2%, by weight, aqueous solution of the composition has an average rate of foam collapse of from 1.00 to 1.50 cm/min.Type: GrantFiled: February 24, 1997Date of Patent: June 8, 1999Assignee: The Procter & Gamble CompanyInventor: Neil James Gordon
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Patent number: 5910472Abstract: A liquid personal cleansing composition comprising: (a) from about 5% to about 60% by weight of water-soluble surfactant selected from anionic, nonionic and amphoteric surfactants and mixtures thereof; and (b) from about 0.01% to about 10% by weight of a hydrophobically modified nonionic cellulose ether selected from C.sub.14 -C.sub.18 alkyl and alkenyl modified, hydroxyethyl cellulose ethers having a degree of nonionic substitution in the range of from about 2.2 to about 2.8 and a degree of hydrophobic substitution in the range of from about 0.4% to about 0.6% by weight; and (c) water, and wherein the composition displays a shear stress of about 150 Pa at a shear rate in the range from about 400 s.sup.-1 to about 600 s.sup.-1 at 25.degree. C. The products demonstrate excellent in-use efficacy benefits including mildness, a moisturised skin feel, good rinsibility and good product stability.Type: GrantFiled: June 2, 1997Date of Patent: June 8, 1999Assignee: The Procter & Gamble CompanyInventors: Russell Phillip Elliott, Matthew Thomas Green, Christopher David Leahy, Eleni Papadimitriou
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Patent number: 5905062Abstract: A liquid personal cleansing composition comprising: a) from about 5% to about 60% by weight of water-soluble surfactant selected from anionic, nonionic and amphoteric surfactants and mixtures thereof; b) from about 0.01% to about 10% by weight of a hydrophobically modified nonionic cellulose ether selected from C.sub.10 -C.sub.24 alkyl and alkenyl modified methyl, hydroxyethyl and hydroxypropyl cellulose ethers having a degree of nonionic substitution in the range of from about 1.8 to about 4 and a degree of hydrophobic substitution in the range of from about 0.1% to about 1% by weight; c) from about 0% to about 10% by weight of a water-soluble polyol; d) from about 0.01% to about 5% by weight of cationic polymeric skin conditioning agent; and e) water, and wherein the composition displays a shear stress of about 150 Pa at a shear rate in the range from about 100 s.sup.-1 to about 600 s.sup.-1 at 25.degree. C.Type: GrantFiled: September 23, 1997Date of Patent: May 18, 1999Assignee: The Procter & Gamble CompanyInventors: Russell Phillip Elliott, Matthew Thomas Green, Christopher David Leahy, Eleni Papadimitriou
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Patent number: 5900393Abstract: Mild aqueous detergent, e.g., shampoo, compositions are disclosed based on a mixture comprising anionic surfactant and amphoteric surfactant, such as betaines, present in the composition at a level of from about 0.75 to 1.25 parts by weight per part by weight of anionic surfactant. The compositions also contain one or a mixture of therapeutic agents such as climbazole or a mixture of climbazole and one or more co-therapeutics such as salicylic acid. The combination of mild surfactant system and therapeutic agent serve to prevent or treat mild skin disorders such as scalp itch and scalp irritation when applied to the scalp as a shampoo. Shampoo compositions also preferably contain one or more conditioning agents and suitable suspending agents.Type: GrantFiled: June 24, 1996Date of Patent: May 4, 1999Assignee: Colgate-Palmolive CompanyInventors: Pallassana Narayanier Ramachandran, Clarence Ralph Robbins, Amrit Manilal Patel
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Patent number: 5888956Abstract: All purpose cleaning or microemulsion compositions more environmentally friendly, which is especially effective in the removal of a mixture of oil and kaolin soil, contains a negatively charged complex, a Lewis base, neutral polymer, and water.Type: GrantFiled: September 26, 1997Date of Patent: March 30, 1999Assignee: Colgate Palmolive CompanyInventors: Patrick Durbut, Anne-Marie Misselyn, Guy Broze
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Patent number: 5879748Abstract: A protective non-silicone oil aqueous lubricant emulsion for web off-set lithographic printing comprises from about 30 wt % to about 70 wt % hydrocarbon oil, from about 1 wt % to about 8 wt % of a surfactant having an HLB factor less than about 6, from about 2 wt % to about 9 wt % of a surfactant having an HLB factor greater than about 11, and from about 25 wt % to 60 wt % water, the emulsion having an average particle diameter of from about 500 nm to about 1100 nm. The emulsion enhances control of the dimensional stability of inked sheets and of the coefficient of friction of the heatset web.Type: GrantFiled: April 29, 1997Date of Patent: March 9, 1999Assignee: Varn Products Company Inc.Inventors: Ronald S. Conti, John Schoell, Donatas Ramanauskas
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Composition containing a lamellar liquid crystalline phase which comprises betaines and amine oxides
Patent number: 5877143Abstract: A pumpable, fluid composition of amine oxide, betaine and/or sultaine is prepared with active concentration of about 36-45% of these materials by the addition of alkaline earth or aluminum salts.Type: GrantFiled: November 20, 1997Date of Patent: March 2, 1999Assignee: Colgate-Palmolive Co.Inventors: Syed Husain Abbas, Orum D. Stringer, Ravi Subramanyam -
Patent number: 5858955Abstract: This invention relates to a method of manufacturing a concentrated aqueous solution of an amine oxide and the use of the solution in cleaning compositions.Type: GrantFiled: December 16, 1997Date of Patent: January 12, 1999Assignee: Colgate Palmolive CompanyInventors: Orum D. Stringer, Syed Hasain Abbas, Ravi Subramanyam
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Patent number: 5840671Abstract: A cleaning solution for cleaning a contact lens, which includes at least one first component each consisting of a tertiary amine oxide which is represented by the formula given in the specification and at least one second component each consisting of an anionic surface active agent in the form of a triethanolamine salt, a total content of the at least one first component and the at least one second component being within a range of 0.1-20% by weight, a ratio of a total content of the at least one first component to a total content of the at least one second component being within a range from 1/4 to 30/1.Type: GrantFiled: December 8, 1995Date of Patent: November 24, 1998Assignee: Tomey Technology CorporationInventors: Atumi Fujimura, Kaoru Kamiya, Shinji Tanaka
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Patent number: 5783533Abstract: Amphoteric copolymers of general formula:(X).sub.a --(Y).sub.b --(Z).sub.cin whichX represents a monomer type with anionic charge;Y represents a monomer type with nonionic character;Z represents a monomer type with cationic charge;a is the weight % based on the total weight of monomers of X, and is between 95 and 15;b is the weight % based on the total weight of monomers of Y, and is between 0 and 65;c is the weight % based on the total weight of monomers of Z, and is between 5 and 60as rheological modifiers of lamellar phases of detergent or cosmetic (liquid or pasty) compositions are disclosed. Liquid washing detergent and liquid shampoos containing the amphoteric copolymers are also disclosed.Type: GrantFiled: March 22, 1996Date of Patent: July 21, 1998Assignee: Coatex S.A.Inventors: Yves Kensicher, Jean-Marc Suau
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Patent number: 5783534Abstract: A process for the production of a solid esterquat free from solvents comprising the steps ofA) forming a mixture comprising(i) at least one fatty acid triethanolamine ester corresponding to formula (I) ##STR1## in which R.sup.1 CO is a saturated and/or unsaturated acyl radical containing 6 to 22 carbon atoms, R.sup.2 and R.sup.3 independently of one another represent hydrogen or have the same meaning as R.sup.1 CO, and n, m and p together stand for O or for a number of from 1 to 10;(ii) at least one fatty alcohol polyglycol ether, and(iii) at least one fatty acid partial glyceride; andB) adding an alkylating agent to the above mixture to form said solid esterquat.Type: GrantFiled: July 15, 1996Date of Patent: July 21, 1998Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Wahle, Joaquim Bigorra Llosas, Rafael Pi, Antoni Soler Codina, Emili Brau Balague, Yvonne Reichert, Peter Waltenberger
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Patent number: 5776872Abstract: A personal cleansing product comprising: (a) from about 5% to about 50% by weight of a mixed surfactant system which comprises: (i) from about 1% to about 20% by weight of composition of anionic surfactant, and (ii) from about 1% to about 20% by weight of composition of amphoteric surfacant, (b) from about 3% to about 40% by weight of an insoluble nonionic oil or wax, and (c) water, wherein the anionic surfactant and amphoteric surfactant together comprises from about 5% to about 30% by weight of the composition, the weight ratio of anionic surfactant:amphoteric surfactant is in the range from about 1:5 to about 20:1, the weight ratio of total surfactant:nonionic oil or wax is in the range from about 10:1 to about 1:3, and wherein the composition is in the form of an oil-in-water emulsion having a viscosity in the range from 10,000 to 40,000 cps and a yield point of at least 50 dyne/cm.sup.2. The cleaning products demonstrate excellent lathering, mildness, stability, rinsibility and conditioning benefits.Type: GrantFiled: September 22, 1994Date of Patent: July 7, 1998Assignee: The Procter & Gamble CompanyInventors: Michel Joseph Giret, Anne Langlois, Roland Philip Duke
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Patent number: 5767051Abstract: A light duty liquid detergent with desirable cleansing properties and mildness to the human skin comprising: a nonionic surfactant, an alkali metal or ammonium salt of a C.sub.8-18 ethoxylated alkyl ether sulfate anionic surfactant, an amine oxide surfactant, a zwitterionic surfactant, an alkyl polyglucoside surfactant, and water.Type: GrantFiled: February 13, 1997Date of Patent: June 16, 1998Assignee: Colgate Palmolive CompanyInventors: Julien Drapier, Maria Galvez, Nicole Kerzmann, Gary Jakubicki
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Patent number: 5747436Abstract: The present invention provides an effective conditioning shampoo composition which is free of conditioning amounts of silicone conditioning agents. It comprises: A) about 5% to about 40% of a detersive surfactant mixture of an anionic detergent and an amphoteric surfactant, the weight ratio of the anionic detergent to the amphoteric surfactant being in the range of about 10:1 to 0.8:1; B) about 0.05% to about 6% of a conditioning agent selected from the group consisting of 0.05% to 5% of a complex of essentially equimolar amounts of a C.sub.8 -C.sub.18 (EtO).sub.1-10 carboxylic acid, and a C.sub.8 -C.sub.18 alkyl (EtO).sub.0-10 dimethyl amine; 0.05% to 1.0% of a polyquaternary compound selected from the group consisting of a quaternized cellulosic polymer and a mixture of the quaternized cellulosic polymer with a non-cellulosic quaternary conditioning polymer; and mixtures of the foregoing; C) 0.1% to 1% of a static control mixture of a quaternary ammonium salt having the formula R.sub.9, R.sub.10, R.sub.Type: GrantFiled: January 14, 1997Date of Patent: May 5, 1998Assignee: Colgate-Palmolive CompanyInventors: Amrit M. Patel, Suman K. Chopra
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Patent number: 5747435Abstract: Composition useful as 2-in-1 cleansing products are disclosed that are extremely mild to skin and hair, which use neutralized, essentially chargeless, ionic complexes of fatty amines and fatty acids to deliver various levels of conditioning; neutralized, essentially chargeless, ionic complexes of a detersive surfactant comprising a water soluble cationic surfactant and/or polymer complexed with one or more anionic surfactants; or an amphoteric surfactant complexed with one or more anionic surfactants; or a water soluble cationic surfactant and/or polymer complexed with one or more amphoteric surfactants; or a water soluble cationic surfactant and/or polymer complexed with one or more anionic surfactants and an amphoteric surfactant; detersive surfactant-soluble but water-insoluble silicones or derivatives thereof; and water. These products exhibit true 2-in- conditioning properties, and are lower in cost than current 2 in 1 products. Clear or opacified products can be formulated.Type: GrantFiled: July 17, 1996Date of Patent: May 5, 1998Assignee: Colgate-Palmolive CompanyInventor: Amrit M. Patel
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Patent number: 5726137Abstract: A mild, non-irriatating hair conditioning shampoo is disclosed comprising an aqueous dispersion of a water-insoluble lipid phase, an anionic hair cleansing surfactant, an amphoteric surfactant present at a level of at least about 0.75 parts by weight per part by weight of said anionic surfactant, at least one hair conditioning, film forming, polycationic polymer soluble in the aqueous dispersion and 0-6% by weight, based on the weight of the shampoo, of a water-insoluble, non-volatile hair conditioning silicone, the water-insoluble lipid phase comprising at least one lipid soluble, emulsifiable, monocationic, quaternary ammonium compound or amine solubilized in a water-insoluble long chain lipid compound, the weight ratio of monocationic compound to the lipid compound in the lipid phase being in the range of from about 5:1 to about 1:10 and the molar ratio of anionic surfactant to water-insoluble cationic compound is greater than 2:1.Type: GrantFiled: September 27, 1996Date of Patent: March 10, 1998Assignee: Colgate-Palmolive CompanyInventors: Amrit Patel, Clarence R. Robbins
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Patent number: 5723655Abstract: The present invention relates to an amine compound represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 represent individually a linear or branched C.sub.1 -C.sub.24 alkyl or alkenyl group which may be substituted by a hydroxyl group, X.sup.1 represents a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by a hydroxyl, sulfonic or carboxyl group, Y.sup.1 represents a carboxyl or sulfonic group, or a sulfuric acid residue, Y.sup.2 represents a hydroxyl group, a sulfuric acid residue or a group --OCO--X.sup.1 --COOH, Z represents a sulfoalkyl group or a group obtained by removing an amino group from an amino acid or a salt thereof, and n represents a number of 0 or 1, or a salt or quaternized product thereof, an intermediate useful for the preparation thereof, and detergent compositions containing such an amine compound.Type: GrantFiled: January 7, 1997Date of Patent: March 3, 1998Assignee: Kao CorporationInventors: Mitsuru Uno, Tomohito Kitsuki, Katsumi Kita
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Patent number: 5719113Abstract: A cleansing composition includes a salt of chlorhexidine such as chlorhexidine digluconate and at least one nonionic surfactant which does not include any polyoxypropylene/polyoxyethylene block copolymers. Also included in the composition is at least one amphoteric surfactant. Other additives such as viscosifiers or thickeners, emollients, fragrances, perfumes, coloring agents, preservatives, foaming agents, fungicides and the like may also be added. Preferably, the composition does not include alcohol as a carrier. The cleansing composition has been found to exhibit improved antibacterial properties while remaining mild on the skin.Type: GrantFiled: August 28, 1996Date of Patent: February 17, 1998Assignee: Gojo Industries, Inc.Inventors: Eleanor J. Fendler, Ronald A. Williams, Michael J. Dolan
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Patent number: 5714446Abstract: Disclosed are hair conditioning shampoo compositions comprising(a) from about 5% to about 50%, by weight, of an anionic surfactant component;(b) from about 0.1% to about 10%, by weight, of a dispersed, insoluble, nonionic silicone hair conditioning agent, said silicone hair conditioning agent comprising a non-volatile, insoluble, nonionic silicone fluid component;(c) from about 0.2% to about 10%, by weight, of a soluble cationic, amino or quaternary ammonium conditioning surfactant having a cationic nitrogen atom and at least one N-radical containing one or more hydrophilic moieties that are within 4 carbon atoms (inclusive) of a cationic nitrogen, said hydrophilic moieties being selected from the group consisting of alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, and alkylester moieties, and combinations thereof; and(d) an aqueous carrier.Type: GrantFiled: February 8, 1995Date of Patent: February 3, 1998Assignee: The Procter & Gamble CompanyInventors: Lisa Jo Bartz, James David Landgrebe, Robert Lee Wells
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Patent number: 5712232Abstract: An aqueous liquid cleansing composition, packaged in a foamer container, said composition comprising:(A) from 5 to 50% by weight of an anionic carboxylate surfactant; and(B) from 0.1 to 5% by weight of a salt.The aqueous liquid cleansing composition of the present invention shows an extremely low viscosity increase at a low temperature and can be easily pushed out from the foamer container even at a low temperature thus giving uniform foam. It is particularly suitable for a skin cleanser.Type: GrantFiled: September 14, 1995Date of Patent: January 27, 1998Assignee: Kao CorporationInventors: Masaaki Moriyama, Hisateru Tanabe, Hideyuki Hanazawa, Yasushi Kajihara
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Patent number: 5696069Abstract: A detergent, personal cleansing or cosmetic composition comprising: a) one or more surfactants selected from anionic, nonionic, amphoteric, zwitterionic, and mixtures thereof, and which comprises at least one surfactant having a structure incorporating acyl taurate, b) quaternium cation, c) low HLB nonionic surfactants; and d) water, and wherein low HLB nonionic surfactants are in the form of a solution or dispersion.Type: GrantFiled: November 21, 1995Date of Patent: December 9, 1997Assignee: The Andrew Jergens CompanyInventors: Tsukasa Ito, David Story, Tomohiko Sano