For Semipermeable Membrane Or Ion-exchange Resin Or Equipment Patents (Class 510/162)
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Patent number: 11529588Abstract: A cleaning solution for accelerated cleaning of a membrane having an enzyme and an agent having a pH that is compatible with the enzyme. The cleaning solution may additionally include one or both of a binding agent and a surfactant. Once the cleaning solution has been included in a solution that is used to contact the membrane for a defined period of time, one or both of a binding agent and a reducing agent may be added to the solution that has contacted the membrane. Optionally, one or both of increasing a pH of the solution and increasing a temperature of the solution may be used to reduce an activity of the enzyme.Type: GrantFiled: June 29, 2018Date of Patent: December 20, 2022Assignee: Diversey, Inc.Inventors: Flemming Skou, Sandy te Poele, Harry Kany
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Patent number: 11414626Abstract: Surfactants capable of releasing and/or dissolving polymers to form water-soluble or water-dispersible polymer solutions are disclosed. In addition, polymer compositions containing a water-in-oil emulsion comprising the surfactant are provided and can be used, for example, in methods of dissolving a polymer. Also disclosed are detergent compositions and methods of cleaning articles and/or membranes using the surfactants herein. These surfactants and polymer compositions can be used in various industries including for water clarification, papermaking, sewage and industrial water treatment, drilling mud stabilizers, and enhanced oil recovery.Type: GrantFiled: December 2, 2019Date of Patent: August 16, 2022Assignee: Ecolab USA Inc.Inventors: Ashish Dhawan, Carter Martin Silvernail, Sukhwan Soontravanich, Keith Allen Monk, Michael L. Braden, Paige Mary Owens, Kerrie Elizabeth Walters, Ali Marie Bichler, Izabela A. Owsik, David Myers
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Patent number: 11400420Abstract: A solution-type water treatment chemical, includes, as one, gluconic acid (salt) and a surfactant having an HLB determined by the following equation (1) satisfying the following equation (2), wherein in a relationship between concentrations of the gluconic acid (salt) and the surfactant and a molecular weight and HLB of the surfactant, the gluconic acid (salt) and the surfactant are contained such that the water treatment chemical does not form a gel or precipitate. HLB=(?inorganic value/?organic value)×10??(1) Molecular weight>?34.Type: GrantFiled: February 28, 2018Date of Patent: August 2, 2022Assignee: KURITA WATER INDUSTRIES LTD.Inventor: Kazuki Ishii
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Patent number: 10780400Abstract: Provided is an agent and a liquid for cleaning an RO membrane to remove effectively foulants that can not be sufficiently removed with conventional cleaning agents when an RO membrane particularly an aromatic polyamide RO membrane has been used for water treatment and has become fouled resulting in degradation of performance such as permeation flux, pressure difference, and salt rejection rate. The agent for cleaning an RO membrane includes an aliphatic amide and/or an aromatic amide. Also provided is a method for cleaning an RO membrane with the cleaning agent or the cleaning liquid. The aliphatic amide and/or the aromatic amide particularly an aliphatic amide and/or an aromatic amide being soluble in water and having a relatively low molecular weight remove effectively foulants adhered on an aromatic polyamide RO membrane.Type: GrantFiled: March 23, 2016Date of Patent: September 22, 2020Assignee: KURITA WATER INDUSTRIES LTD.Inventors: Kazuki Ishii, Takahiro Kawakatsu
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Patent number: 10676697Abstract: The present invention relates to a biodegradable detergent composition, which can contain viable cells or enzymes and acts as a replacement for the chemical detergents. The biodegradable detergent composition, comprising of: bio surfactant; polyols; biopolymer; organic acid; small chain peptide; essential oil; and stabilizers. The biodegradable detergent composition has a pH value of less than about 3.60, Titratable Acidity % between about 9.0-12.0, HLB value between about 14 to about 16.5, E24 value between about 73 and about 79. The biodegradable detergent composition has MALDI-TOF MS spectra in the m/z range from about 513.1 to about 2847.7 with peak mass value range from about 1375.8 m/z to about 2009.2 m/z. Further, the present invention relates to a method of manufacturing the biodegradable detergent composition.Type: GrantFiled: December 16, 2016Date of Patent: June 9, 2020Assignees: PROKLEAN TECHNOLOGIES PVT. LTD, SUSTAINABLE COMMUNITY DEVELOPMENT, LLCInventors: Sivaramakrishna Pillai Sankarakumara Pillai, Chandrasekhar B., Matthew T. Wood, Narin Tipsrisukond
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Patent number: 9145508Abstract: An aqueous composition for removing scale deposits, especially on subsea equipment and a method of using the same. The aqueous composition comprises (a) a potassium phosphate compound; and (b) acetic acid. The composition is capable of dissolving away into seawater and poses little or no risk to the environment.Type: GrantFiled: May 18, 2012Date of Patent: September 29, 2015Inventor: Ian D. Smith
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Patent number: 8981148Abstract: An esteramide compound of the following formula (I): R1OOC-A-CONR2R3??(I) is described, wherein: A is a covalent bond or a methylene group —CH2—; R1 is an optionally substituted, saturated or unsaturated aliphatic or cycloaliphatic hydrocarbon group including from 5 to 36 carbon atoms, R2 and R3, either identical or different, are groups selected from a hydrogen atom, and optionally substituted hydrocarbon groups, preferably including from 1 to 36 carbon atoms, and R2 and R3 not being simultaneously hydrogen atoms. Also described, are applications for using the esteramide compound, notably as a solvent.Type: GrantFiled: March 17, 2011Date of Patent: March 17, 2015Assignee: Rhodia OperationsInventors: Massimo Guglieri, Thierry Vidal
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Publication number: 20150045276Abstract: The invention provides cleaning agents, cleaning liquids and cleaning methods that effectively remove contaminants which are impossible to remove sufficiently with conventional cleaning liquids at the occurrence of a decrease in performances such as permeation flux and salt rejection rate due to contamination of permeable membranes, in particular aromatic polyamide RO membranes used in water treatment. Permeable membranes are cleaned with a cleaning liquid which is an aqueous solution including a chloramine compound and an alkali agent and having a pH of 10 or above. The chloramine compound is preferably one obtained by mixing a compound having a primary amino group with hypochlorous acid and/or a hypochlorite.Type: ApplicationFiled: April 9, 2013Publication date: February 12, 2015Applicant: KURITA WATER INDUSTRIES LTDInventors: Tetsuya Aoki, Takahiro Kawakatsu, Kunihiro Hayakawa
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Patent number: 8933009Abstract: The present invention relates to the field of membrane separation processes and clean in place compositions for cleaning such membranes. The cleaning compositions can remove proteins, fats, and other food, beverage, and brewery based soils and offer an environmentally friendly alternative surfactant system to NPE. According to the invention, surfactants and polymers useful for this process are unpredictable and specific surfactants, polymers, and combinations of the same are disclosed for use alone, as part of a cleaning composition. Methods of use of the same are also included.Type: GrantFiled: March 12, 2013Date of Patent: January 13, 2015Assignee: Ecolab USA Inc.Inventors: Paul Schacht, Jeffrey Weilage, Eric Schmidt, Joseph P. Curran, Ralf Krack, Victor Fuk-Pong Man, Charles Allen Hodge
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Patent number: 8506723Abstract: An alkaline detergent composition for hard surface comprises an alkaline agent (component A), a nonionic surfactant (component B), a chelating agent (component C), water (component D), at least one carboxylic acid compound (component E) selected from the group consisting of compounds represented by general formula (1) and general formula (2), and at least one anionic surfactant (component F) selected from the group consisting of surfactants represented by general formula (3) and salts thereof. Therein, the content ratio [component E (weight %)/component B (weight %)] is 1/1.5-15/1, the content ratio [component F (weight %)/component B (weight %)] is 10/1-1/5, and the pH at 25° C. is 12 or greater.Type: GrantFiled: December 27, 2010Date of Patent: August 13, 2013Assignee: KAO CorporationInventors: Atsushi Tamura, Sadaharu Miyamoto
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Patent number: 8227396Abstract: A method for cleaning process apparatus used for production of liquids, especially for cleaning filters, for example membrane filters. The apparatus is contacted with a solution of peroxydisulphate. It is especially preferred that the cleaning process is carried out at a temperature between 15 and 95° C.Type: GrantFiled: January 6, 2010Date of Patent: July 24, 2012Assignee: X-Flow B.V.Inventors: Arie Cornelis Besemer, Elmar Van Mastrigt, André Mepschen
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Patent number: 8211842Abstract: The present invention relates to an agent for the preventive and/or curative cleaning of materials in contact with water, characterized in that it includes sodium chloride and at least one dispersant detergent and/or a non-ionic surfactant having at least one detergent action and at least one oxidizing agent, characterized in that the oxidizing agent is selected from solid-form precursors of hydrogen peroxide and in that the cleaning agent is in solid form, such as pellets, granules, bars tablets, large pellets or powder, the salt(s) being used as binders between the various components. Another objective of the present invention is to provide a method for agglomerating the various ingredients according to the present invention, even when they are present in a liquid form. The present invention also relates to the use of the cleaning agent for the preventive and/or curative cleaning of materials in contact with water.Type: GrantFiled: September 14, 2007Date of Patent: July 3, 2012Inventors: Roman Gerusz, Antoine Vanlaer
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Publication number: 20100204077Abstract: A method for cleaning process apparatus used for production of liquids, especially for cleaning filters, for example membrane filters. The apparatus is contacted with a solution of peroxydisulphate. It is especially preferred that the cleaning process is carried out at a temperature between 15 and 95° C.Type: ApplicationFiled: January 6, 2010Publication date: August 12, 2010Applicant: X-FLOW B.V.Inventors: Arie Cornelis Besemer, Elmar Van Mastrigt, André Mepschen
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Patent number: 7700531Abstract: There is provided a cleaning agent comprising a lactone represented by the following formula (1): wherein R1 is an alkylene group having 3 to 6 carbon atoms. The cleaning agent is useful for cleaning an organic electroluminescence material, photosensitive resin, liquid crystal or wax.Type: GrantFiled: December 14, 2005Date of Patent: April 20, 2010Assignee: Tokuyama CorporationInventors: Hisahiko Iwamoto, Yoshifumi Inoue, Masaaki Nakashima, Masafumi Kasai
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Patent number: 7540292Abstract: A detergent and a method for washing applicable to selectively permeable membranes for proposed, which can attain washing of selectively permeable membranes deteriorated in its membrane performance, such as the flux, in an efficient manner within a brief time at a higher detergent effect without causing deterioration of the selectively permeable membranes and without damaging safety to human and to environment with superior handling aspect. The detergent contains a polyol having a molecular weight not higher than 400 and, if necessary, an organic solvent.Type: GrantFiled: February 23, 2004Date of Patent: June 2, 2009Assignee: Kurita Water Industries Ltd.Inventors: Takahiro Kawakatsu, Nobuhiro Orita, Naoto Hitotsuyanagi
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Patent number: 7144847Abstract: A detergent for removing deposits on a mold for use in molding a thermoplastic resin, comprising limonene and ethanol is disclosed. Provided, is a detergent for removing mold deposits, said detergent being capable of easily removing deposits (the so-called mold deposits) and anticorrosive agents, releasing agents, lubricants and the like from the surface of a mold in the process of molding the thermoplastic resin. Furthermore, the detergent is preferable from the viewpoint of the work environment, and said detergent can be apply to a wide range of thermoplastic resins.Type: GrantFiled: December 5, 2001Date of Patent: December 5, 2006Assignee: Asahi Kasei Chemicals CorporationInventors: Mikihiko Itoh, Kazuyuki Hamada
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Patent number: 6448062Abstract: A composition for simultaneous cleaning and decontaminating a device. The composition is a per-compound oxidant in an amount effective for decontaminating the device and an enzyme in an amount effective for cleaning the device. The device may be a medical device such as an endoscope or kidney dialyzer and a plurality of devices can be cleaned using the same composition. The composition may additionally contain a corrosion inhibitor in an amount effective to prevent corrosion of a metal, a chelator, a buffer, a dye and combinations thereof.Type: GrantFiled: October 29, 1999Date of Patent: September 10, 2002Assignee: Metrex Research CorporationInventors: Stanley William Huth, Zhi-Jian Yu
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Patent number: 6235692Abstract: This invention relates to a foaming enzyme composition and delivery method useful for the cleaning and maintenance of moist conditions of the surfaces of soiled instruments, utensils and other devices prior to final cleaning and/or sterilization. The aqueous composition preferably consists of a combination of: (1) an enzyme cleaning solution, (2) foam-building ingredients; (3) a corrosion inhibitor; and (4) an antimicrobial agent. The composition may be dispensed from a pump spray as a stable foam which covers the surfaces of the instrument to be cleaned, and remains on the surface of the instrument for at least 30 minutes, and preferably until the instruments are finally cleaned and sterilized. The composition and delivery method of the present invention is particularly useful for the pre-cleaning of complex medical instruments such as endoscopes.Type: GrantFiled: September 20, 1999Date of Patent: May 22, 2001Assignee: Cottrell International, LLCInventors: John R. Scoville, Inna A. Novicova
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Patent number: 5998342Abstract: This invention relates to a foaming enzyme composition and delivery method useful for the cleaning and maintenance of moist conditions of the surfaces of soiled instruments, utensils and other devices prior to final cleaning and/or sterilization. The aqueous composition preferably consists of a combination of: (1) an enzyme cleaning solution, (2) foam-building ingredients; (3) a corrosion inhibitor; and (4) an antimicrobial agent. The composition may be dispensed from a pump spray as a stable foam which covers the surfaces of the instrument to be cleaned, and remains on the surface of the instrument for at least 30 minutes, and preferably until the instruments are finally cleaned and sterilized. The composition and delivery method of the present invention is particularly useful for the pre-cleaning of complex medical instruments such as endoscopes.Type: GrantFiled: August 26, 1998Date of Patent: December 7, 1999Assignee: Cottrell International, LLCInventors: John R. Scoville, Jr., Inna A. Novicova
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Patent number: 5985810Abstract: A cleaning composition comprising at least one low molecular weight polyorganosiloxane selected from the group consisting of straight chain polydiorganosiloxane represented by a general formula: ##STR1## (wherein R.sup.1 is an organic group of single valence substituted by the same or different group or unsubstituted, and l is an integer from 0 to 5), and cyclic polydiorganosiloxane represented by a general formula: ##STR2## (wherein R.sup.1 is an organic group of single valence substituted by the same or different group or unsubstituted, and m is an integer from 3 to 7). To use it as a water system cleaning agent, polyoxyalkylene group containing polyorganosiloxane, a surfactant, and water are additionally mixed. Accordingly, a cleaning effect free from environmental destruction and contamination, equivalent to flon containing cleaning agents, and satisfactorily stable in terms of dispersion as a water system cleaning agent can be obtained.Type: GrantFiled: June 7, 1995Date of Patent: November 16, 1999Assignee: Toshiba Silicone Co., Ltd.Inventors: Minoru Inada, Kimiaki Kabuki, Yasutaka Imajo, Takayuki Oguni, Noriaki Yagi, Nobuhiro Saitoh, Akitsugu Kurita, Yoshiaki Takezawa
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Patent number: 5810944Abstract: The invention relates to a cleanser concentrate having the following composition: 0.5-8.0% by weight of at least one C.sub.5 -C.sub.12 -alkyl sulphate salt, 4.0-15.0% by weight of at least one formulation aid, 4.0-10% by weight of at least one alkanolamine, and at least one commercially conventional proteolytic enzyme in an amount of 0.005-0.1 Anson and, if appropriate, conventional acids or bases for pH adjustment, conventional complexing agents and conventional preservatives, remainder, to 100% by weight, water. A process for cleaning surgical instruments has the following steps: applying a 0.5-100% strength aqueous solution of a cleanser concentrate according to one of claims 1-6 which has a pH of 8-9, allowing the solution to act at a temperature of room temperature to 55.degree. C. for a period of 2 s-20 min, rinsing, thermal disinfection, if appropriate.Type: GrantFiled: October 29, 1996Date of Patent: September 22, 1998Assignee: Chemische Fabrik Dr. Weigert (GmbH & Co.)Inventors: Petra Smitkowski, Olaf Schreiber, Jurgen Staffeldt
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Patent number: 5801133Abstract: An aqueous, biodegradable acid-based cleaner employing a dicarboxylic acid selected from oxalic acid, malonic acid, and tartaric acid and a tricarboxylic acid selected from citric acid and ascorbic acid is disclosed. A method for cleaning a filter used to filter biguanide-treated recreational water is also disclosed.Type: GrantFiled: May 8, 1995Date of Patent: September 1, 1998Assignee: Buckman Laboratories International Inc.Inventors: Percy A. Jaquess, Luis Fernando Del Corral