With Alkali Metal Hydroxide, Carbonate, Bicarbonate, Or Sesquicarbonate Component Patents (Class 510/233)
  • Patent number: 10671192
    Abstract: Described is a process for the production of a layered body S2 comprising: i. provision of a layered body S1 comprising a substrate and an electrically conductive layer which is applied to the substrate and comprises an electrically conductive polymer P1; ii. partial covering of a part of the electrically conductive layer with a covering layer D, comprising a polymer P2 contained therein, from a covering phase to obtain at least one covered region Dd and at least one non-covered region Du of the electrically conductive layer; iii. reduction of the electrical conductivity of the electrically conductive layer in at least a part of the at least one non-covered region Du compared with the electrical conductivity of the electrically conductive layer in the at least one covered region Dd; iv. at least partial removal of the covering layer D by an alkaline aqueous treatment.
    Type: Grant
    Filed: July 6, 2012
    Date of Patent: June 2, 2020
    Assignee: Heraeus Deutschland GmbH & Co. KG
    Inventors: Udo Guntermann, Detlef Gaiser, Myriam Grasse, Akio Ishikawa
  • Patent number: 8809249
    Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.
    Type: Grant
    Filed: June 7, 2013
    Date of Patent: August 19, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Carter M. Silvernail, Erik C. Olson, Elizabeth R. Kiesel
  • Patent number: 8697622
    Abstract: Synergistic combinations of extended chain surfactants and co-surfactants, emulsions or microemulsions and cleaning compositions incorporating the same are provided. In certain embodiments a surfactant system is disclosed which includes extended nonionic surfactants, and a linker surfactant. This system forms stable emulsions or microemulsions with oils, including non-trans fats and fatty acids and these emulsions or microemulsions are stable, irreversible and can be created at low temperature. The cleaning compositions may include the surfactant system alone, a stable emulsion or microemulsion with oil and the surfactant system, a pre-spotter or other pre-treatment or soft surface and hard surface cleaning compositions comprising the surfactant combination.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: April 15, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Victor Fuk-Pong Man, Yvonne Marie Killeen, Steven Eugene Lentsch, Michael Charles DeNoma
  • Patent number: 8663496
    Abstract: The invention relates to a double-layered compacted solid water-purification product, comprising at least one first layer and at least one second layer, characterized in that the first layer comprises at least one flocculating system and at least one dispersion system, the second layer comprises at least one disinfectant which liberates free chlorine on contact with water and at least one excipient for the disinfectant, whereby said excipient releases the disinfectant into the water at a controlled rate such that the combination of excipient and disinfectant releases 0.1 to 100 mg/l of free chlorine per hour. The invention further relates to the method for production of such a product.
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: March 4, 2014
    Assignee: Eurotab
    Inventors: Paul Branlard, Philippe Desmarescaux, Murielle Moneron
  • Patent number: 8623151
    Abstract: A cleaning composition includes an alkali metal silicate, a polymer including maleic acid, vinyl acetate and alkyl acrylate monomers, and optionally water. The cleaning composition can include approximately 10% and approximately 90% by weight of at least one alkali metal silicate, greater than or equal to approximately 0.1% by weight of the polymer containing maleic acid, vinyl acetate and alkyl acrylate monomers, and approximately 0% to approximately 80% by weight water.
    Type: Grant
    Filed: March 23, 2012
    Date of Patent: January 7, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Erik C. Olson, Carter Silvernail
  • Patent number: 8481473
    Abstract: A detergent composition for preventing scale on various surfaces includes a threshold system, a caustic and a surfactant system. The threshold system includes a sulfonate/acrylate copolymer, an acrylate homopolymer and a phosphonoalkane carboxylic acid with a sulfonate/acrylate copolymer to acrylate homopolymer weight ratio of between about 2:1 to about 1:2. The pH of the detergent composition is between about 10 and about 13.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: July 9, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Carter Silvernail, Erik C. Olson, Elizabeth Kiesel
  • Patent number: 8440601
    Abstract: A mixed powder or mixed granule for use in detergent formulations for machine dishwashing contains the following components: a) from 10 to 95% by weight of a copolymer of a1) from 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of acrylic acid, a2) from 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid, and a3) from 2 to 20 mol % of at least one nonionic monomer, wherein monomers a1) to a3) are copolymerized in a random or block manner, b) from 5 to 80% by weight of a complexing agent selected from the group consisting of a glycine-N,N-diacetic acid derivative and glutamic acid N,N-diacetic acid and salts thereof, c) from 0 to 20% by weight of a polyethylene glycol, of a nonionic surfactant or of a mixture thereof.
    Type: Grant
    Filed: December 14, 2011
    Date of Patent: May 14, 2013
    Assignee: BASF SE
    Inventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
  • Patent number: 8420586
    Abstract: Cleaner compositions, associated cleaners, and associated methods are disclosed. The cleaner compositions are capable for use in making thickened cleaners that are capable of removing from vertical and inverted surfaces fresh, greasy soils and baked-on soils encountered in the food service industry. The cleaner compositions include one or more alkalinity sources, one or more chelants, one or more surfactants, one or more thickening agents, one or more buffers, and as a remainder, water. Cleaner compositions of the invention are substantially free of phosphates and have a low caustic content making them user and environmentally friendly. Yet the cleaners of the invention are surprisingly effective at removing tenacious baked-on soils encountered in the food service industry. Compositions of the invention have a viscosity of about 700 cps and are applied using a foaming or misting dispenser.
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: April 16, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Thomas J. Vinson, Karen O. Rigley, Tami J. Tadrowski
  • Patent number: 8399393
    Abstract: A warewashing detergent composition is provided including an alkalinity source, a corrosion inhibitor and optionally, a cleaning agent. The glass corrosion inhibitor includes at least a soluble lithium salt and optionally includes a soluble aluminum salt and/or a soluble silicate salt. The warewashing detergent composition has a pH of at least about 8.
    Type: Grant
    Filed: May 3, 2010
    Date of Patent: March 19, 2013
    Assignee: Ecolab USA Inc.
    Inventor: Altony Miralles
  • Patent number: 8361342
    Abstract: The present invention relates to a compacted solid product for water purification comprising:—at least a first layer comprising at least a coagulant/flocculant system comprising at least one polyvalent inorganic salt, at least one water-soluble cationic polymer and at least one high-molecular-weight anionic polymer,—at least a second layer comprising at least one disinfectant that releases active chlorine on contact with water, characterized in that said coagulant/flocculant system moreover comprises a sodium alginate. The invention also relates to the method for preparing such a product.
    Type: Grant
    Filed: October 4, 2007
    Date of Patent: January 29, 2013
    Assignee: Eurotab
    Inventors: Paul Branlard, Gilles Rubinstenn
  • Patent number: 8329630
    Abstract: Cleaner compositions, methods of making cleaners, and methods of use are disclosed. Disclosed is a method of formulating a ready-to-use degreaser composition that has extended to infinite cling time. The method of making the cleaner results in thickened compositions that are capable of removing from vertical and inverted surfaces fresh, greasy and baked-on soils encountered in the food industry. The compositions include one or more alkalinity sources, one or more chelants, one or more surfactants, one or more thickening agents, one or more solvents, one or more buffers, and as a remainder, water. Compositions prepared according to the method of the invention are substantially free of phosphorous and have a low caustic content making them user friendly, having a lower pH than commercially available cleaners. Yet the cleaners prepared according to the method of the invention are surprisingly effective at removing tenacious baked-on soils encountered in the food service industry.
    Type: Grant
    Filed: January 26, 2012
    Date of Patent: December 11, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Jeremy B. Finison, Daniel L. Moran, Stephen T. Smith, Thomas J. Vinson, Karen O. Rigley
  • Patent number: 8193139
    Abstract: The invention relates to a phosphate-free cleaning formulation for machine dishwashing, comprising as components: a) 1 to 20% by weight of copolymers of a1) 50 to 93 mol % acrylic acid and/or of a water-soluble salt of acrylic acid, a2) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of methacrylic acid and a3) 2 to 20 mol % of at least one nonionic monomer of the formula (I), b) 1 to 50% by weight of complexing agents chosen from the group consisting of glycine-N,N-diacetic acid derivatives and glutamic acid-N,N-diacetic acid and salts thereof, c) 1 to 15% by weight of low-foaming nonionic surfactants, d) 0 to 30% by weight of bleaches and optionally bleach activators, e) 0 to 60% by weight of further builders, f) 0 to 8% by weight of enzymes, g) 0 to 50% by weight of one or more further additives, such as anionic or zwitterionic surfactants, bleach catalysts, alkali carriers, corrosion inhibitors, antifoams, dyes, fragrances, fillers, organic solvents and water, where the sum of components
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: June 5, 2012
    Assignee: BASF Aktiengesellschaft
    Inventors: Tanja Seebeck, Juergen Tropsch, Lars Kissau
  • Patent number: 7964547
    Abstract: Cleaner concentrates, associated cleaners, and associated methods are disclosed. The cleaner concentrates are capable for use in making cleaners that are capable of removing from surfaces fresh, greasy soils and polymerized soils more recently encountered in the food service industry originating from non-trans-fat oils. The cleaner concentrates include one or more alkalinity sources, one or more chelants, one or more surfactants, and as a remainder, water. The one or more alkalinity sources may be present in an amount sufficient to provide a free alkalinity (expressible as Na2O) of greater than about 3.6 wt % and a total alkalinity (expressible as Na2O) of greater than about 6.1 wt %, based on the total weight of the cleaner concentrate. The one or more chelants may be present in an amount sufficient to permit a use of a water having a hardness number up to about 600 ppm (600 mg/L) or more.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: June 21, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Danielle E. Underwood, Tami J. Tadrowski, Karen O. Rigley
  • Patent number: 7960329
    Abstract: The present invention relates to compositions including a water soluble magnesium salt, water soluble calcium salt, and silicate or carbonate, which have a beneficial effect on corrosion during cleaning. The present compositions can reduce corrosion of glass or aluminum. The present invention also relates to methods employing these compositions.
    Type: Grant
    Filed: May 2, 2008
    Date of Patent: June 14, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Michael E. Besse, Michael Bartelme, Michel M. Lawrence
  • Patent number: 7858574
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and at least one of a source of calcium ion or a source of magnesium ion. The amounts of calcium ion or magnesium ion can be selected depending upon the hardness of the water of dilution. Methods for using a warewashing detergent composition are provided.
    Type: Grant
    Filed: June 8, 2010
    Date of Patent: December 28, 2010
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Michael J. Bartelme, Keith E. Olson
  • Patent number: 7838484
    Abstract: Cleaner concentrates, associated cleaners, and associated methods are disclosed. The cleaner concentrates are capable for use in making cleaners that are capable of removing from surfaces fresh, greasy soils and polymerized soils more recently encountered in the food service industry originating from non-trans-fat oils. The cleaner concentrates include one or more alkalinity sources, one or more chelants, one or more surfactants, and as a remainder, water. The one or more alkalinity sources may be present in an amount sufficient to provide a free alkalinity (expressible as Na2O) of greater than about 3.6 wt % and a total alkalinity (expressible as Na2O) of greater than about 6.1 wt %, based on the total weight of the cleaner concentrate. The one or more chelants may be present in an amount sufficient to permit a use of a water having a hardness number up to about 600 ppm (600 mg/L) or more.
    Type: Grant
    Filed: April 18, 2008
    Date of Patent: November 23, 2010
    Assignee: Ecolab Inc.
    Inventors: Danielle Elise Underwood, Tami Jo Tadrowski, Karen Odom Rigley
  • Patent number: 7829516
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: November 12, 2009
    Date of Patent: November 9, 2010
    Assignee: Ecolab USA Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7759299
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and at least one of a source of calcium ion or a source of magnesium ion. The amounts of calcium ion or magnesium ion can be selected depending upon the hardness of the water of dilution. Methods for using a warewashing detergent composition are provided.
    Type: Grant
    Filed: July 24, 2006
    Date of Patent: July 20, 2010
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Michael J. Bartelme, Keith E. Olson
  • Patent number: 7713920
    Abstract: Detergent compositions containing azo initiator compounds are provided. More particularly, detergent compositions containing azo initiator compounds having improved bleaching performance and stain-removal benefits, and methods of using the same, are provided. Composition of matter and articles of manufacture are also provided.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: May 11, 2010
    Assignee: The Procter & Gamble Company
    Inventors: Francis Cornelio Ford, Peter Robert Foley, Alan David Willey
  • Patent number: 7638473
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: October 13, 2008
    Date of Patent: December 29, 2009
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7578968
    Abstract: Processes for effecting biocidal activity in subterranean oil and gas wells being drilled, completed, worked over or produced are described. In general the process comprises blending with aqueous well fluid a biocidally-effective amount of a sulfamate stabilized, bromine-based biocide. Compositions comprised of aqueous well fluid blended with such aqueous biocides are also described.
    Type: Grant
    Filed: May 3, 2002
    Date of Patent: August 25, 2009
    Assignee: Albemarle Corporation
    Inventors: Christopher J. Nalepa, Joel F. Carpenter
  • Patent number: 7531490
    Abstract: The present invention relates to a detergent composition containing (a) 2 to 30% by weight of an inorganic alkali, (b) 0.5 to 20% by weight of at least one surfactant selected from an anionic surfactant and a nonionic surfactant, (c) 0.01 to 2% by weight (based on calcium ion) of a calcium salt, (d) 0.1 to 15% by weight of a calcium ion-sequestering agent, (e) 1 to 30% by weight of a water-soluble organic solvent and (f) 20 to 95% by weight of water.
    Type: Grant
    Filed: September 29, 2005
    Date of Patent: May 12, 2009
    Assignee: Kao Corporation
    Inventors: Junji Kondo, Yasunori Horio
  • Patent number: 7524803
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use solution having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: April 28, 2009
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Michael J. Bartelme, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7517846
    Abstract: The invention is a solid chemical concentrate system of at least two cooperative shapes. The first shape is an inwardly curved bar having an inner opening. The second shape is an insert which is capable of interlocking with the bar by insertion into the bar inner opening. The solid chemical concentrate provides chemical systems having active constituents which may be the same, different but compatible or functionally and chemically incompatible combined within one matrix to provide at least one substantially continuous surface. The system may also comprise an aqueous soluble or dispersible polymeric film cover.
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: April 14, 2009
    Assignee: Ecolab Inc.
    Inventors: Elizabeth J. Gladfelter, Tina O. Outlaw, James L. Copeland, Rhonda K. Schulz, Daniel K. Boche, Jeff W. Peterson
  • Patent number: 7507697
    Abstract: A method for cleaning the surfaces of food processing equipment that are heavily soiled with food processing byproducts, such as grease, starch and proteinaceous materials. The cleaning method consists of applying two separate aqueous cleaning solutions that are mixed together. One solution contains an aqueous oxidizing agent and the other solution contains a source of aqueous hydroxide ions. Both solutions are mixed together immediately prior to being applied to the soiled surfaces. The combined formulation utilizes the weak Bronsted acidity of the oxidizing agents in interaction with the hydroxide ions to generate perhydroxyl ions and other active oxygen species, which are significantly more effective at cleaning heavily soiled food processing equipment than each cleaning solution alone.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: March 24, 2009
    Assignee: Rochester Midland Corporation
    Inventors: Joel Terry Shertok, Jack David Fox
  • Patent number: 7452853
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: November 18, 2008
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7435714
    Abstract: The invention relates to liquid detergent and cleaning agent compositions of high storage stability. They comprise a liquid medium with a water content of up to 15 wt. % and particulate coating bleaching agents suspended therein. The bleaching agent has a dissolving time of at least 5 minutes and a coating of at least two layers: The innermost layer comprises one or more hydrate-forming inorganic salts as the main component(s), and an outer layer, which makes up 0.2 to 5 wt. % of the coated bleaching agent, comprises alkali metal silicate(s) with a modulus of SiO2 to M2O (M=alkali metal) of greater than 2.5 as the main component(s). Preferred compositions comprise sodium percarbonate with an innermost layer of substantially sodium sulfate and an outermost layer of substantially 0.5 to 1.5 wt. % sodium silicate (modulus 3.2 to 4.2) as the bleaching agent.
    Type: Grant
    Filed: December 11, 2003
    Date of Patent: October 14, 2008
    Assignee: Evonik Degussa GmbH
    Inventors: Ulrike Kottke, Silke Stoschek, Klaus Zimmermann, Ralph Overdick, Michael Fender, Harald Jakob
  • Patent number: 7341987
    Abstract: A solid functional material comprises a functional agent such as a cleaning composition, a sanitizing agent, where a rinse agent, etc. in a solid block format. The solid block is formed by a binding agent that forms the active ingredients into a solid block. The binding agent comprises a phosphonate or amino acetate sequestrant, a carbonate salt and water in an E-Form hydrate. These materials at a specific mole ratio form a novel binding agent that can form functional materials into a solid matrix form.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: March 11, 2008
    Assignee: Ecolab Inc.
    Inventors: G. Jason Wei, Steven E. Lentsch, Keith E. Olson, Victor F. Man
  • Patent number: 7326674
    Abstract: New cleaning compositions and methods of forming and using those compositions are provided. In a preferred embodiment, the compositions are in tablet form, with the tablets being dissolvable in water at the point-of-use for ease of storing and shipping. The compositions comprise sodium bicarbonate, citric acid, an alkali metal alkylbenzene sulfonate, an ingredient selected from the group consisting of a trialkyl glycol monoalkyl ether, limonene, and mixtures thereof, and other ingredients depending upon the embodiment. The diluted cleaner has a very low impact on the environment due to the low levels of surfactants in the diluted solution. Furthermore, the cleaning solution performs well on protein stains due to the production of CO2 and the presence of sodium perborate. The inventive composition can be used on a wide range of substrates, from hard surfaces to fabrics.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: February 5, 2008
    Assignee: Kegel, LLC
    Inventors: Dennis Sheirs, Brandy Padilla, Donald Wall
  • Patent number: 7282472
    Abstract: An automatic dishwashing composition in unit dose form for delivery into the main-wash cycle of an automatic dishwashing machine, the composition comprising a phosphate or non-phosphate detergency builder and a sulfonated anti-scaling polymer.
    Type: Grant
    Filed: November 15, 2005
    Date of Patent: October 16, 2007
    Assignee: The Procter & Gamble Company
    Inventors: Neha Kapur, Anju Deepali Massey Brooker, James Iain Kinloch, Alison Lesley Main
  • Patent number: 7255112
    Abstract: A process for removing colored stains from hydrophobic surfaces characterized in that the process involves the use of a formulation which comprises a salt of sulphophenyl alkyl carbonate is described. Also a process of removing color stains from a plastics material, characterized in that the stained plastics material is treated in a dishwashing machine with a formulation comprising a salt of sulphophenyl alkyl carbonate is described.
    Type: Grant
    Filed: November 18, 2003
    Date of Patent: August 14, 2007
    Assignee: Reckitt Benckiser N.V.
    Inventors: Laurence Geret, Gunnar Noeding
  • Patent number: 7196044
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: March 27, 2007
    Assignee: Ecolab, Inc.
    Inventors: Kim R. Smith, Keith E. Olson, Howie Kestell, Michael J. Bartelme, Steven E. Lentsch, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7196045
    Abstract: A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use solution having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. Methods for using and manufacturing a warewashing detergent composition are provided.
    Type: Grant
    Filed: February 2, 2006
    Date of Patent: March 27, 2007
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Michael J. Bartelme, Victor F. Man, Burton M. Baum, Terence P. Everson
  • Patent number: 7087569
    Abstract: The dimensionally stable alkaline solid block warewashing detergent uses an E-form binder forming a solid comprising a sodium carbonate source of alkalinity, a metal corrosion protecting alkali metal silicate composition, a sequestrant, a surfactant package and other optional material. The solid block is dimensionally stable and highly effective in removing soil from the surfaces of dishware in the institutional and industrial environment. The E-form hydrate comprises an organic phosphonate and a hydrated carbonate.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: August 8, 2006
    Assignee: Ecolab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Keith E. Olson
  • Patent number: 6998375
    Abstract: An automatic dishwashing composition in unit dose form for delivery into the main-wash cycle of an automatic dishwashing machine, the composition comprising a phosphate or non-phosphate detergency builder and a sulfonated anti-scaling polymer.
    Type: Grant
    Filed: November 14, 2002
    Date of Patent: February 14, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Neha Kapur, Anju Deepali Massey Brooker, James Iain Kinloch, Alison Lesley Main
  • Patent number: 6919305
    Abstract: Solid laundry detergents, dishwashing detergents and cleaners which are obtained by mixing gemini surfactants of the formula (I), R1CH(OH)CHR3(OCH2CH2)nOCHR4CH(OH)R2??(I) in which R1 and R2,independently of one another, are linear or branched alkyl and/or alkenyl radicals having 4 to 22 carbon atoms, R3 and R4, independent of one another, each represents a hydrogen or an alk(en)yl radical having from 1 to 22 carbon atoms and n is a number from 5 to 400, with inorganic or organic carriers.
    Type: Grant
    Filed: January 28, 2004
    Date of Patent: July 19, 2005
    Assignee: Cognis Deutschland GmbH & Co. KG
    Inventors: Ditmar Kischkel, Manfred Weuthen, Michael Elsner
  • Patent number: 6911422
    Abstract: A process of imparting transparency or translucency to a liquid or gel type automatic dishwashing detergent product is disclosed. The process includes the steps of providing a liquid or gel type automatic dishwashing detergent composition expressly free from (i) potassium tripolyphosphate and (ii) mixture of sodium tripolyphosphate and potassium tripolyphosphate, adding one or more of potassium sources to the liquid or gel type automatic dishwashing detergent composition, the potassium sources being expressly free of potassium tripolyphosphate, and maintaining a K:Na weight ratio greater than at least about 0.5:1.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: June 28, 2005
    Assignee: The Procter & Gamble Company
    Inventors: Brian Xiaoqing Song, Peter Robert Foley, Melissa Dee Aquino
  • Patent number: 6812195
    Abstract: The present invention is directed to a grease-cutting detergent composition that exhibits a stable foaming profile when used with non-enclosed automatic dishwashers. The composition can be sold in a concentrated form or in ready-to-use (RTU) diluted form. The concentrated compositions are formulated to be diluted with water before use. The RTU formulas are intended for as-is usage. In one embodiment the concentrated compositions comprises a) from about 0.25% to about 10% of a surfactant, b) from about 4% to about 8% of an alkalinity source, c) from about 0.1% to about 4.0% of a hydrotrope, d) from about 0.001% to about 2.0% of a builder, and e) from about 0.01% to about 3.0% of a thickener. In another embodiment an RTU formulation comprises a) from about 50 ppm to about 80 ppm of a surfactant, b) from about 45 ppm to about 75 ppm of an alkalinity source, c) from about 20 ppm to about 45 ppm of a hydrotrope, d) from about 0.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: November 2, 2004
    Assignee: The Procter & Gamble Co.
    Inventors: Thomas James Wierenga, James August Weikel
  • Patent number: 6660707
    Abstract: The dimensionally stable alkaline solid block warewashing detergent uses an E-form binder forming a solid comprising a sodium carbonate source of alkalinity, a metal corrosion protecting alkali metal silicate composition, a sequestrant, a surfactant package and other optional material. The solid block is dimensionally stable and highly effective in removing soil from the surfaces of dishware in the institutional and industrial environment. The E-form hydrate comprises an organic phosphonate and a hydrated carbonate.
    Type: Grant
    Filed: June 24, 2002
    Date of Patent: December 9, 2003
    Assignee: EcoLab Inc.
    Inventors: Steven E. Lentsch, Victor F. Man, Keith E. Olson
  • Patent number: 6632291
    Abstract: The present invention relates to methods for cleaning, rinsing, and/or antimicrobial treatment of medical carts, medical cages, and other medical instruments, devices or equipment. The method for cleaning employs a solid alkaline, for example a solid carbonate, cleaning composition for cleaning the medical cart, cage, instrument, device, or equipment. The method for rinsing employs a solid neutral or neutralizing rinse composition for rinsing the medical cart, cage, instrument, device, or equipment. The method for antimicrobial treatment employs a solid, for example a solid quaternary ammonium or solid halogen, antimicrobial composition, for antimicrobial treatment of the medical cart, cage, instrument, device, or equipment.
    Type: Grant
    Filed: March 23, 2001
    Date of Patent: October 14, 2003
    Assignee: Ecolab Inc.
    Inventors: Reid Rabon, Sally K. Swart, Denise Chandler, Terrence P. Everson
  • Patent number: 6622736
    Abstract: A water soluble glass is used in dishwashing machines as corrosion protection for glassware. The water soluble glass consists of at least one compound which, in the cleaning and/or rinsing cycles, releases an agent that protects glassware against corrosion. Each of the compounds accounts for no more than 85 molar % of the glass and the solubility of the water soluble glass is defined by a mass loss of at least 0.5 mm under the conditions specified in DIN ISO 719.
    Type: Grant
    Filed: August 15, 2001
    Date of Patent: September 23, 2003
    Assignee: Reckitt Benckiser N.V.
    Inventor: Karlheinz Hahn
  • Patent number: 6610645
    Abstract: A detergent composition containing an inexpensive detergent builder in the form of a selected crystalline calcium carbonate is provided. Specifically, the crystalline calcium carbonate has a substantially rhombohedral crystal structure with {1,0-1,1} crystallographic indices. The crystalline calcium carbonate can be calcite that has been specially modified to a rhombohedral crystal structure with {1,0-1,1} indices. The crystalline calcium carbonate of the present invention is extremely inexpensive because it can be readily formed from inexpensive naturally occurring calcite, and it performs well even when used at large median particle sizes.
    Type: Grant
    Filed: September 10, 1999
    Date of Patent: August 26, 2003
    Inventors: Eugene Joseph Pancheri, Robert Henry Rohrbaugh, Scott William Capeci, William Marion Hoffman, Rose Marie Weitzel
  • Patent number: 6602837
    Abstract: Alkaline liquid detergent compositions comprising a diacyl peroxide, solvent and chelant are disclosed. The solvent is preferably selected based upon the solubility parameter of the diacyl peroxide present. Preferred compositions are for use in automatic dishwashing detergents, are substantially phosphate free and contain detersive enzymes. The compositions are effective in removing stains, especially carotenoid, under various temperature and pH conditions from plastics.
    Type: Grant
    Filed: October 9, 1996
    Date of Patent: August 5, 2003
    Assignee: The Procter & Gamble Company
    Inventor: Rashesh Naresh Patel
  • Publication number: 20030134765
    Abstract: An automatic dishwashing composition in unit dose form for delivery into the main-wash cycle of an automatic dishwashing machine, the composition comprising a phosphate or non-phosphate detergency builder and a sulfonated anti-scaling polymer.
    Type: Application
    Filed: November 14, 2002
    Publication date: July 17, 2003
    Inventors: Neha Kapur, Anju Deepali Massey Brooker, James Iain Kinloch, Alison Lesley Main
  • Publication number: 20030114329
    Abstract: The present invention is directed to a grease-cutting detergent composition that exhibits a stable foaming profile when used with non-enclosed automatic dishwashers. The composition can be sold in a concentrated form or in ready-to-use (RTU) diluted form. The concentrated compositions are formulated to be diluted with water before use. The RTU formulas are intended for as-is usage. In one embodiment the concentrated compositions comprises a) from about 0.25% to about 10% of a surfactant, b) from about 4% to about 8% of an alkalinity source, c) from about 0.1% to about 4.0% of a hydrotrope, d) from about 0.001% to about 2.0% of a builder, and e) from about 0.01% to about 3.0% of a thickener. In another embodiment an RTU formulation comprises a) from about 50 ppm to about 80 ppm of a surfactant, b) from about 45 ppm to about 75 ppm of an alkalinity source, c) from about 20 ppm to about 45 ppm of a hydrotrope, d) from about 0.
    Type: Application
    Filed: September 16, 2002
    Publication date: June 19, 2003
    Inventors: Thomas James Wierenga, James August Weikel
  • Publication number: 20030045437
    Abstract: A method of washing cookware/tableware in an automatic dishwashing machine having a pre-wash, main-wash and one or more rinse cycles wherein one or more dishwashing products are dosed into the one or more rinse cycles and wherein the dosing regime is such as to provide a rinse cycle concentration factor (Cr) of at least about 1.3×104, preferably at least about 1.8×104 more preferably at least about 2.4×104 and especially 3.
    Type: Application
    Filed: May 14, 2002
    Publication date: March 6, 2003
    Applicant: The Procter & Gamble Company
    Inventor: Glenn Steven Ward
  • Publication number: 20030022804
    Abstract: The present invention is a non-corrosive, low-fuming oven cleaning composition that can be used easily on vertical oven surfaces. The present invention is a cleaning composition containing a tripolyphosphate and a thickening agent to promote in adherence to vertical surfaces.
    Type: Application
    Filed: April 18, 2001
    Publication date: January 30, 2003
    Inventors: Tami Jo Tadrowski, Karen Odom Rigley
  • Patent number: 6465413
    Abstract: This invention discloses laundering and dishwashing products which can be incorporated in a single compartment water soluble film sachet, the formulation comprising a granulated percarbonate compound mixed with and encapsulated in an encapsulating blend comprising sulfate, carboxy methyl cellulose and nonionic surfactant, wherein the detergent composition does not include zeolites or perborates.
    Type: Grant
    Filed: July 9, 1999
    Date of Patent: October 15, 2002
    Inventor: Gerald Thomas Hinton
  • Patent number: 6462006
    Abstract: A solid-form dishwasher detergent that contains a builder combination of conventional phosphates and crystalline layer silicates. Despite its phosphate content, the detergent provides improved protection to sensitive tableware, more particularly glasses and decorated tableware, and improved cleaning performance.
    Type: Grant
    Filed: December 22, 2000
    Date of Patent: October 8, 2002
    Assignees: Henkel Kommanditgesellschaft auf Aktien, Clariant GmbH
    Inventors: Rainer Sorg, Christian Nitsch, Juergen Haerer, Harald Volk, Thomas Mueller-Kirschbaum, Peter Krings, Harald Bauer, Josef Holz, Guenther Schimmel, Lothar Westermann
  • Patent number: RE38262
    Abstract: We have found an alkaline warewashing detergent composition that can contain a critical amount of a nonionic rinse agent that when used in automatic warewashing machines permits the use of a potable water rinse without the addition of a separate rinse agent. Sufficient residual nonionic surfactant from the alkaline detergent remains on the surface ware and internal machine and rack surfaces after washing to promote adequate sheeting in the rinse cycle. The residual nonionic surfactant on internal surfaces dissolves in the rinse water to create an effective aqueous rinse agent. The nonionic rinse agents can be a single nonionic for both foam reduction cleaning and sheeting or can be a blend of nonionic materials providing these functions. The detergent can be in the form of a particulate, pelletized or block solid.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: October 7, 2003
    Assignee: Ecolab Inc.
    Inventors: John J. Rolando, Terry J. Klos