Free Organic Or Inorganic Acid Component Patents (Class 510/253)
  • Patent number: 11492538
    Abstract: A method for inhibiting scale comprises adding to a fluid that causes scale formation a polycarboxylic acid or a salt thereof which has a star structure and at least 5 arms. A star polymer comprising a core based on 2,2?-[Oxybis(methylene)]bis[2-(hydroxymethyl)-1,3-propanediol] and 6 arms comprising linear polycarboxylic acids of degree of polymerization (DP) of the arm of at least 2 and in some embodiments up to 15 or more is useful in inhibiting scale formation.
    Type: Grant
    Filed: January 28, 2020
    Date of Patent: November 8, 2022
    Assignees: DOW GLOBAL TECHNOLOGIES LLC, ROHM AND HAAS COMPANY, THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    Inventors: Puspendu Deo, Antony K. Van Dyk, Paul Clark, David Lunn, Craig Hawker, Maria Simon, Sungbaek Seo, Alaina McGrath
  • Patent number: 9228159
    Abstract: A hard surface cleaning solution having improved cleaning and descaling properties. The cleaning solution includes the following components: a first organic acid, a second organic acid, a surfactant, a solvent and a diluent. The first organic acid is a carboxylic acid, preferably lactic acid, while the second organic acid is also a carboxylic acid, preferably gluconic acid. The surfactant is selected from the group consisting of amine oxides, preferably lauramine oxide. The solvent may be an alkoxylated alcohol, preferably selected from the propylene glycol ether class of compounds.
    Type: Grant
    Filed: September 27, 2013
    Date of Patent: January 5, 2016
    Assignee: Jelmar, LLC
    Inventor: Rosemary Gaudreault
  • Patent number: 8980815
    Abstract: Disclosed herein is a cleaner concentrate comprising: greater than 10 weight percent of a freezing point depressant, 0.5 to 35 weight percent of oxalic acid, and an azole compound, wherein weight percent is based on the total weight of the cleaner concentrate.
    Type: Grant
    Filed: February 24, 2012
    Date of Patent: March 17, 2015
    Assignee: Prestone Products Corporation
    Inventors: Bo Yang, Peter M. Woyciesjes
  • Patent number: 8901062
    Abstract: An oil-in-water emulsion comprising droplets of a molten hydrogenated castor oil, the droplets having a mean diameter of between 0.1 ?m and 4 ?m; and an anionic surfactant; and wherein the mean diameter is measured when the emulsion is at a temperature of between 85° C. and 95° C.
    Type: Grant
    Filed: August 13, 2013
    Date of Patent: December 2, 2014
    Assignee: The Procter & Gamble Company
    Inventors: Niels De Meirleir, Walter August Maria Broeckx, Linda Pellens
  • Patent number: 8859479
    Abstract: A stripping solution comprises a highly corrosive acid and an iron concentration of at least about 1.0 gram per liter (g/L). The stripping solution is air agitated to remove a coating from a metal article submerged therein.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: October 14, 2014
    Assignee: United Technologies Corporation
    Inventor: Eric W. Stratton
  • Patent number: 8845930
    Abstract: The invention provides a method for pre-treating a metal surface with a corrosion inhibitor prior to painting, a method for inhibiting corrosion in a cooling system, wherein the cooling system includes a metal surface and a coolant; and a method for inhibiting corrosion of a reinforcement steel in concrete wherein the method comprising the step of adding to a concrete mixture an anti-corrosive mixture.
    Type: Grant
    Filed: November 28, 2005
    Date of Patent: September 30, 2014
    Assignee: Pigmentan Ltd.
    Inventors: Gregory Pipko, Zvi Miller
  • Patent number: 8790670
    Abstract: Detergent compositions and detergent compositions dispersed in personal care products are provided herein. In one embodiment, a detergent composition is provided and comprises a sorbent carrier. The detergent composition also includes a sorbed component including an acid and a surfactant. The sorbed component is sorbed by the sorbent carrier.
    Type: Grant
    Filed: December 28, 2012
    Date of Patent: July 29, 2014
    Assignee: The Dial Corporation
    Inventors: Travis T. Yarlagadda, Sarah Moore, Tasha Zander, Elizabeth Nofen, Saiid Mohammed, Gerald Decker, Matthew Romaine, Chris Proulx, Chelsea Stanton
  • Patent number: 8765021
    Abstract: The present invention relates to an aqueous treatment composition for inhibiting corrosion and acid attack on metallic surfaces that comprises a thiourea organic derivative, a polyalkoxylated terpene nonionic surfactant and an acid. The invention also relates to a process for cleaning industrial metallic equipment, in particular heat exchangers in which a heat transfer fluid, generally based on air or on water, flows, with a view to cleaning them and removing scale and other soiling.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: July 1, 2014
    Assignee: Rhodia Operations
    Inventor: Jean-Emile Zanetto
  • Patent number: 8729006
    Abstract: The present invention includes methods and compositions that employ sodium carboxymethyl cellulose as a scale inhibitor. According to the invention, scale inhibiting compositions are disclosed which include, sodium carboxymethyl cellulose and a polymer such as polymaleic acid, polyacrylic acid or mixtures, copolymers or terpolymers of the same and optionally may also include a phosphonate. The scale control composition may be incorporated into a detergent/cleaning composition.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: May 20, 2014
    Assignee: Ecolab USA Inc.
    Inventors: Altony Miralles, Xin Sun, Michelle Fung, John Krueger
  • Patent number: 8722609
    Abstract: A cleaning composition including an acid component is provided, along with methods for using the composition to remove soil from hard surfaces. The concentrate cleaning composition includes between about 1 and about 70 wt % of methane sulfonic acid, about 0.1 to about 15 wt % of a surfactant component, up to about 90% of a solvent and other adjuvants.
    Type: Grant
    Filed: April 6, 2009
    Date of Patent: May 13, 2014
    Assignee: Ecolab Inc
    Inventors: Barbara G. Choczaj, Michael J. Bartelme, Steven E. Lentsch, Katherine O. Vetter, Marvin C. Trulsen, Erik C. Olson, Mark D. Levitt
  • Publication number: 20140066351
    Abstract: This invention refers to a stabilized pipe scaling remover and inhibitor compound, where a useful formulation is presented for the dissolution of scaling such as barium sulfate, calcium sulfate, calcium carbonate, magnesium carbonate, barium carbonate and ferric oxide. This formulation is made up by a stabilized group of organic and inorganic acids, in addition to amines or alcohols of a high molecular weight which make it a low-corrosion, highly-effective fluid. The possible fluids to be obtained from this document ensure the least amount of damage to the pipes used for its transportation and are friendly to different polymer materials. They progressively attack buildup scaling by solubilizing it in an aqueous medium and breaking down the carbonate ion. Its use in the oil industry is as scale inhibitor, inorganic scale inhibitor, or scale formation inhibitor (when applied in solution).
    Type: Application
    Filed: April 3, 2012
    Publication date: March 6, 2014
    Applicant: Geo Estratos, S.A. de C.V.
    Inventors: Vicente Gonzalez Davila, Edgardo Jonathan Suarez Dominguez
  • Patent number: 8648026
    Abstract: A composition for dissolving and/or inhibiting deposition of scale on a surface of a system comprises an acidic component, a wetting agent, and a corrosion inhibitor. The composition may further comprise water. The acidic component comprises an alkanesulfonic acid, e.g. methanesulfonic acid (MSA). The wetting agent comprises a surfactant. The corrosion inhibitor comprises an amphoteric surfactant. The alkanesulfonic acid is present in an amount of at least about 50 weight percent (wt %), the surfactant is present in an amount of from about 0.1 to about 30 wt %, and the amphoteric surfactant is present in an amount of from about 0.025 to about 20 wt %, each based on 100 wt % of the alkanesulfonic acid, the surfactant, and the amphoteric surfactant combined. A method of dissolving and/or inhibiting deposition of scale on the surface of the system comprises the step of contacting the surface of the system with the composition.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: February 11, 2014
    Assignee: BASF SE
    Inventors: Joseph P Borst, Keith Hirsch, Stephen F Gross
  • Patent number: 8586522
    Abstract: The present invention provides water-based cleaning formulations comprising one or more organic solvents having low solubility in water and an alkylene glycol dilevulinate for coupling the organic solvent with water.
    Type: Grant
    Filed: August 31, 2012
    Date of Patent: November 19, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: David C. Busby, Molly I. Busby, William Jack Kruper, Jr., Mark F. Sonnenschein
  • Patent number: 8575084
    Abstract: A hard surface cleaning solution having improved cleaning and descaling properties. In an embodiment, the cleaning solution comprises an organic acid, a surfactant, a solvent and a diluent. The first organic acid is a carboxylic acid, preferably lactic acid, while the surfactant is selected from the group consisting amine oxides, and the solvent is an alkoxylated alcohol, preferably selected from the propylene glycol ether class of compounds. The cleaning solutions may also include other components such as colorants, fragrance enhancers, corrosion inhibitors, nonionic surfactants or other additives.
    Type: Grant
    Filed: November 12, 2010
    Date of Patent: November 5, 2013
    Assignee: Jelmar, LLC
    Inventor: Rosemary Gaudreault
  • Patent number: 8569220
    Abstract: A hard surface cleaning solution having improved cleaning and descaling properties. The cleaning solution includes the following components: a first organic acid, a second organic acid, a surfactant, a solvent and a diluent. The first organic acid is a carboxylic acid, preferably lactic acid, while the second organic acid is also a carboxylic acid, preferably gluconic acid. The surfactant is selected from the group consisting of amine oxides, preferably lauramine oxide. The solvent may be an alkoxylated alcohol, preferably selected from the propylene glycol ether class of compounds.
    Type: Grant
    Filed: November 12, 2010
    Date of Patent: October 29, 2013
    Assignee: Jelmar, LLC
    Inventor: Rosemary Gaudreault
  • Patent number: 8563496
    Abstract: The present invention relates to a liquid acidic hard surface cleaning composition having a pH of above 2.0 and comprising formic acid, citric acid and an alkaline material.
    Type: Grant
    Filed: December 10, 2010
    Date of Patent: October 22, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Laura Cermenati, William Mario Laurent Verstraeten, Lucie Marie Cretieneau
  • Patent number: 8486882
    Abstract: The present invention is directed to a metal cleaner polisher and anti-tarnish solution which comprises the following ingredients per 32 fluid ounces: 5.00 to 10.00 percent mineral spirits by volume; 1.50 to 4.50 percent ethanol by volume; 0.50 to 1.50 percent ammonia by volume; 0.50 to 1.50 percent thiourea by volume; 0.25 to 1.00 percent sulfamic acid by volume; less than 0.20 percent disodium cocoampho-diproprionate by volume; and deionized water. Optionally, the following ingredients may be added individually, in any combination or all together: thickening/suspension agents; abrasive additives; and a modifying/stabilizing agent; and optionally varying amounts of fragrance and colorizing agents.
    Type: Grant
    Filed: October 6, 2011
    Date of Patent: July 16, 2013
    Inventors: Randy B. Bayless, Garen R. Bayless
  • Patent number: 8481474
    Abstract: A cleaning composition including an ionic liquid, and preferably no co-surfactants are provided. The compositions are substantially free of alkyl phenol ethoxylates, including nonyl phenol ethoxylates. The cleaning compositions provide superior cleaning efficacy for various soils, including proteins and food soils, providing an effective, biorenewable, environmentally friendly alternative to nonyl phenol ethoxylates.
    Type: Grant
    Filed: May 15, 2012
    Date of Patent: July 9, 2013
    Assignee: Ecolab USA Inc.
    Inventors: Amanda R. Blattner, Charles A. Hodge
  • Publication number: 20130137622
    Abstract: A composition for dissolving and/or inhibiting deposition of scale on a surface of a system comprises an acidic component, a wetting agent, and a corrosion inhibitor. The composition may further comprise water. The acidic component comprises an alkanesulfonic acid, e.g. methanesulfonic acid (MSA). The wetting agent comprises a surfactant. The corrosion inhibitor comprises an amphoteric surfactant. The alkanesulfonic acid is present in an amount of at least about 50 weight percent (wt %), the surfactant is present in an amount of from about 0.1 to about 30 wt %, and the amphoteric surfactant is present in an amount of from about 0.025 to about 20 wt %, each based on 100 wt % of the alkanesulfonic acid, the surfactant, and the amphoteric surfactant combined. A method of dissolving and/or inhibiting deposition of scale on the surface of the system comprises the step of contacting the surface of the system with the composition.
    Type: Application
    Filed: November 29, 2012
    Publication date: May 30, 2013
    Applicant: BASF SE
    Inventor: BASF SE
  • Patent number: 8431516
    Abstract: The compositions and methods for the removal of residues and contaminants from metal or dielectric surfaces comprises at least one alkyl diphosphonic acid, at least one second acidic substance at a mole ratio of about 1:1 to about 10:1 in water, and pH is adjusted to from about 6 to about 10 with a metal ion free base, and a surfactant. Particularly, a composition and method of cleaning residues after chemical mechanical polishing of a copper or aluminum surface of the semiconductor substrates.
    Type: Grant
    Filed: January 26, 2012
    Date of Patent: April 30, 2013
    Inventor: Wai Mun Lee
  • Patent number: 8426349
    Abstract: A chlorinated alkaline cleaning agent and methods for removing food soils with no resultant increase in foam generation. Particularly advantageous is that the addition of methanesulfonic acid in removing food soils with no resultant increase in foam generation.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: April 23, 2013
    Assignee: DeLaval Holding AB
    Inventor: Alan Monken
  • Patent number: 8415285
    Abstract: The present invention provides compositions, in particular blocks, tablets and gels, for the prevention or removal of insoluble salt deposits comprising: a) an organic acid with two carboxylic acid functional groups obtainable by fermentation, selected from the list of itaconic acid, itaconic acid anhydride, succinic acid, succinic anhydride and combinations thereof, and b) at least one compound determining the release of said acid from said composition, said compound is selected from a list comprising: i) a hygroscopic compound, ii) a carbonate source, iii) an acid solubility retarding compound, iv) a compound with melting point situated between 60° C.-95° C., and combinations thereof. The invention further provides uses of the compositions for the prevention or removal of insoluble salt deposits. The invention also provides a method of manufacturing such compositions and a method for the prevention or removal of insoluble salt deposits with a product of the invention.
    Type: Grant
    Filed: January 31, 2011
    Date of Patent: April 9, 2013
    Assignee: Ecover Coordination Center N.V.
    Inventors: Dirk Willem Godfried Develter, Luc Marc Leonie Lauryssen
  • Publication number: 20130072418
    Abstract: Provided is a method for treating scales (101) that have formed on the outer surface of a heat-conducting tube (111) and in a hole (112a) of a tube support plate (112) etc. of a steam generator of a nuclear power plant. The scales (101) are embrittled and also converted to a porous state by bringing the scales (101) into contact with a treatment solution, which contains 0.5 to 3.5 wt % of an organic acid and is at a pH of 2 to 3.5, for 2 to 30 days at 20° C. to 40° C.
    Type: Application
    Filed: January 31, 2011
    Publication date: March 21, 2013
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuo Ishihara, Hirokazu Miyata, Yasuhiko Shoda, Hiroyuki Fujiwara
  • Patent number: 8338353
    Abstract: The invention is directed toward improved aqueous hard surface cleaning compositions which include one or more polysulfonic acids The inclusion of one or more polysulfonic acids in a hard surface composition provides for improved removal of insoluble salt deposits resulting from hard water In an embodiment, the invention utilizes a foaming agent fragrance and a thickening agent.
    Type: Grant
    Filed: July 24, 2008
    Date of Patent: December 25, 2012
    Assignee: Arkema Inc.
    Inventors: Nicholas M. Martyak, Gary E. Stringer
  • Patent number: 8334251
    Abstract: The present invention relates to a process of treating a hard surface with a composition comprising polyalkoxylate trisiloxane. More specifically, it relates to a process of treating an horizontal hard surface, wherein a composition comprising polyalkoxylate trisiloxane is applied onto said hard surface.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: December 18, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Christopher Andrew Morrison, Robby Renilde François Keuleers, Thomas Delaere, Mercedes Labiano Ros
  • Publication number: 20120302484
    Abstract: The present invention provides compositions, in particular blocks, tablets and gels, for the prevention or removal of insoluble salt deposits comprising: a) an organic acid with two carboxylic acid functional groups obtainable by fermentation, selected from the list of itaconic acid, itaconic acid anhydride, succinic acid, succinic anhydride and combinations thereof, and b) at least one compound determining the release of said acid from said composition, said compound is selected from a list comprising: i) a hygroscopic compound, ii) a carbonate source, iii) an acid solubility retarding compound, iv) a compound with melting point situated between 60° C.-95° C., and combinations thereof. The invention further provides uses of the compositions for the prevention or removal of insoluble salt deposits. The invention also provides a method of manufacturing such compositions and a method for the prevention or removal of insoluble salt deposits with a product of the invention.
    Type: Application
    Filed: January 31, 2011
    Publication date: November 29, 2012
    Applicant: Ecover Coordination Center N.V.
    Inventors: Dirk Willem Godfried Develter, Luc Marc Leonie Lauryssen
  • Patent number: 8282743
    Abstract: Alkaline cleaning compositions that are useful to remove burnt-on and/or baked-on soil deposits and grease are described. The alkaline cleaning compositions comprise a buffering system of a strong base and an organic acid such that the pH is maintained in the range of about 10 to about 11.2. Also described are methods of removing burnt-on or baked on soil deposits or grease.
    Type: Grant
    Filed: December 18, 2007
    Date of Patent: October 9, 2012
    Assignee: Colgate-Palmolive Company
    Inventors: Genevieve Bonnechere, Baudouin Mertens
  • Patent number: 8227396
    Abstract: A method for cleaning process apparatus used for production of liquids, especially for cleaning filters, for example membrane filters. The apparatus is contacted with a solution of peroxydisulphate. It is especially preferred that the cleaning process is carried out at a temperature between 15 and 95° C.
    Type: Grant
    Filed: January 6, 2010
    Date of Patent: July 24, 2012
    Assignee: X-Flow B.V.
    Inventors: Arie Cornelis Besemer, Elmar Van Mastrigt, André Mepschen
  • Patent number: 8227397
    Abstract: The disclosure relates to an enzyme stabilization system, compositions with the enzyme stabilization system, and methods of using the enzyme composition. Preferred ratios of acid to amine are effective at stabilizing enzyme. Optional nonionic surfactants and solvents also positively contribute to enzyme stability. The compositions are useful in cleaning applications.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: July 24, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Brandon L. Herdt, Werner Strothoff, Alice Siegmann
  • Patent number: 8172951
    Abstract: The use of an aqueous composition comprising a semiconductor as cleaning agent for surfaces in the outdoors field and indoors field is proposed.
    Type: Grant
    Filed: December 7, 2009
    Date of Patent: May 8, 2012
    Inventor: Karl F. Massholder
  • Patent number: 8163102
    Abstract: A composition is provided for use in cleaning a surface of a cementitious material. The composition includes HCI, urea, complex substituted keto-amine-hydrochloride, an alcohol, an ethoxylate, and a ketone. A method of using the composition includes applying the composition to a surface from which it is desired to clean a cementitious material and removing the composition and released cementitious material from the surface. Methods are also provided for performing hydraulic fracturing of an oil or a gas well; for adjusting a pH of a drilling fluid; for adjusting and maintaining a pH of a process fluid; for solubilizing calcium carbonate in an aqueous suspension or dispersion of calcium carbonate; for removing a foulant in a fluid-handling element; adjusting a pH and lowering a salt level of turf.
    Type: Grant
    Filed: May 10, 2011
    Date of Patent: April 24, 2012
    Assignee: Green Products & Technologies, LLC
    Inventor: John T. MacDonald
  • Patent number: 8148310
    Abstract: The compositions and methods herein relate to the method for the removal of residues and contaminants from metal or dielectric surfaces. Particularly, a composition and method of cleaning residues after chemical mechanical polishing of a copper or aluminum surface of the semiconductor substrates.
    Type: Grant
    Filed: September 23, 2010
    Date of Patent: April 3, 2012
    Inventor: Wai Mun Lee
  • Patent number: 8148311
    Abstract: The compositions and methods for the removal of residues and contaminants from metal or dielectric surfaces comprises at least one alkyl diphosphonic acid, at least one second acidic substance at a mole ratio of about 1:1 to about 10:1 in water, and pH is adjusted to from about 6 to about 10 with a basic compound, and optionally a surfactant. Particularly, a composition and method of cleaning residues after chemical mechanical polishing of a copper or aluminum surface of the semiconductor substrates. One of the embodiment is the method of using the compositions in dilution, wherein the solution may be diluted with DI water at dilution ratios, for example, of up to 1:10, up to 1:50, up to 1:100, up to 1:150, up to 1:250, and up to about 1:500 or any ratios therein.
    Type: Grant
    Filed: June 20, 2011
    Date of Patent: April 3, 2012
    Inventor: Wai Mun Lee
  • Patent number: 8133854
    Abstract: The present invention relates to a liquid acidic hard surface cleaning composition comprising an acid system, wherein the acid system comprises formic acid and acetic acid.
    Type: Grant
    Filed: April 27, 2009
    Date of Patent: March 13, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Laura Cermenati, Christopher Andrew Morrison, William Mario Laurent Verstraeten
  • Patent number: 7964548
    Abstract: The disclosure relates to an enzyme stabilization system, compositions with the enzyme stabilization system, and methods of using the enzyme composition. Preferred ratios of acid to amine are effective at stabilizing enzyme. Optional nonionic surfactants and solvents also positively contribute to enzyme stability. The compositions are useful in cleaning applications.
    Type: Grant
    Filed: April 5, 2010
    Date of Patent: June 21, 2011
    Assignee: Ecolab USA Inc.
    Inventors: Brandon L. Herdt, Werner Strothoff, Alice Siegmann
  • Patent number: 7923425
    Abstract: Low-foaming industrial cleaning compositions comprising water; (A) at least one carboxylic acid; (B) one or more aromatic, water soluble or dispersible, non-ionic surfactants; and optionally, one or more of the following: (C) one or more salts of carboxylic acids selected from the group consisting of carboxylic acids that are the same as component (A), different from component (A) and mixtures thereof; and (D) an amount of hydrotrope material sufficient to produce a stable homogeneous solution or dispersion of components (A) through (C) in water; (E) a pH adjuster; (F) one or more polyhydric alcohols; and (G) one or more preservatives.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: April 12, 2011
    Assignee: Henkel AG & Co. KGaA
    Inventor: Theodore D. Held
  • Patent number: 7824503
    Abstract: The invention pertains to an aqueous composition having a pH of 3 or less and comprising the following ingredients, based on the total weight of the composition: a) 0.05-40 wt % of a polymeric thickener having —COOR groups, wherein R is independently chosen from H, OH, and a carbon-containing group, and b) 0.05-60 wt % of hydrogen peroxide, wherein the active oxygen content attributable to ingredient a) is at least 0.02 wt %, based on the total weight of the composition, with the proviso that (co)polymers prepared from (meth)acrylate monomers are absent.
    Type: Grant
    Filed: April 12, 2007
    Date of Patent: November 2, 2010
    Assignee: Akzo Nobel N.V.
    Inventors: Wasil Maslow, René Gerritsen, Bernhard De Vries, John Meijer, Paul Albert Iacobucci
  • Patent number: 7786063
    Abstract: The invention relates to a detergent composition for CIP, which comprises (A) a solvent having an SP value of 6 to 9 at 25° C. and (B) a surfactant such as a nonionic surfactant.
    Type: Grant
    Filed: October 5, 2009
    Date of Patent: August 31, 2010
    Assignee: Kao Corporation
    Inventors: Kiyoaki Yoshikawa, Nobuyuki Suzuki, Junichi Inokoshi, Shigeru Tamura
  • Patent number: 7776809
    Abstract: A method and a composition for remediating reticulation equipment such as a bore having biocontamination deposits is disclosed. In its most preferred form, the composition is formed by mixing dry solid oxalic acid, a cupric salt such as copper sulphate, and a solid acidic compound such as sodium bisulphate. Proportions of 94%, 2% and 4% respectively are suitable, while avoiding toxicity and contamination problems. After thorough mixing this mixture can be stored in a dry sealed container for future use. In use, the reticulation equipment is dosed with from 3 kg to 7 kg of mixture per hundred litres of water contained within the reticulation equipment.
    Type: Grant
    Filed: January 4, 2006
    Date of Patent: August 17, 2010
    Inventor: David Bennett
  • Publication number: 20100167976
    Abstract: A solid zeolite free soluble water softening composition comprises an effervescent system including an organic acid and an alkali which react together upon dissolution in water.
    Type: Application
    Filed: October 12, 2007
    Publication date: July 1, 2010
    Applicant: Reckitt Benckiser N.V.
    Inventors: Fabio Costiniti, Nassimo Pavan
  • Patent number: 7745384
    Abstract: The present invention relates to hard surface cleaning compositions useful in cleaning, and optionally a disinfecting or sanitizing benefit which are particularly adapted to clean lavatory appliances, particularly toilets and the like. The compositions are largely aqueous, thickened, acidic compositions which comprise an acid, a thickening constituent or constituents which form a thickener system, at least one detersive surfactant and at least one superwetter surfactant which is based on a narrow range ethoxylated alcohol nonionic surfactant having two cloud points.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: June 29, 2010
    Assignee: Reckitt Benckiser (UK) Limited
    Inventors: Lisa Perry, James Young
  • Patent number: 7731803
    Abstract: The present invention is directed to a composition, and a process employing same, for descaling, cleaning and inhibiting the corrosion of process equipment made of steel by including an inhibitory effective amount of acridine orange in the composition.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: June 8, 2010
    Assignee: Saudi Arabian Oil Company
    Inventor: Abdulghani Jaralla
  • Patent number: 7732395
    Abstract: The present invention relates to water-stable compositions and compounds formed by mixing an organosilane, optionally having a non-hydrolyzable organic group, but having one or more hydrolyzable groups, and an acidified stabilizing solution prepared from at least one acid, at least one glycol ether, and at least one cationic surfactant, preferably at least one quaternary ammonium salt (QAS), in water. The present invention also relates to methods of treating a substrate by mixing or contacting the substrate with the product, compound, or composition of this invention for a period of time sufficient for treatment of the substrate, methods of antimicrobially treating a food article, methods of antimicrobially coating a fluid container, methods of dyeing and treating a substrate, and methods of antimicrobially coating a latex medical article. The invention also pertains to a treated substrate having adhered thereto the product, compound, or composition of this invention.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: June 8, 2010
    Assignee: Vitec Specialty Chemicals Ltd.
    Inventors: Timothy C. Moses, Robert McMahon
  • Patent number: 7723281
    Abstract: The invention relates to an enzyme stabilization system, compositions with the enzyme stabilization system, and methods of using the enzyme composition. Preferred ratios of acid to amine are effective at stabilizing enzyme. Optional nonionic surfactants and solvents also positively contribute to enzyme stability. The compositions are useful in cleaning applications.
    Type: Grant
    Filed: January 20, 2009
    Date of Patent: May 25, 2010
    Assignee: Ecolab Inc.
    Inventors: Brandon L. Herdt, Werner Strothoff, Alice Siegmann
  • Patent number: 7718010
    Abstract: The present invention related to a method for treating a surface with a gel, as well as to a treatment gel. The treatment may be a decontamination, etching or surface degreasing treatment, for example. The method comprises in this order, the following steps: applying the treatment gel on the surface to be treated, maintaining the treatment gel on the surface to be treated at a temperature and relative humidity such that the gel dries by breaking up and that it has the time to treat the surface before forming a dry and solid residue, and removing the dry and solid residue from the treated surface by suction or brushing. The gel comprises a viscosing agent, a treatment agent and optional an oxidizing agent.
    Type: Grant
    Filed: August 9, 2005
    Date of Patent: May 18, 2010
    Assignees: Commissariat a L'Energie Atomique, Compagnie Generale des Matieres Nucleaires
    Inventors: Sylvain Faure, Bruno Fournel, Paul Fuentes, Yvan Lallot
  • Patent number: 7713357
    Abstract: The present invention relates to a method for treating a surface with a gel, as well as to a treatment gel. The treatment may be a decontamination, etching or surface degreasing treatment, for example. The method comprises in this order, the following steps: applying the treatment gel on the surface to be treated, maintaining the treatment gel on the surface to be treated at a temperature and relative humidity such that the gel dries by breaking up and that it has the time to treat the surface before forming a dry and solid residue, and removing the dry and solid residue from the treated surface by suction or brushing. The gel comprises a viscosing agent, a treatment agent and optionally an oxidizing agent.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: May 11, 2010
    Assignees: Commissariat a l'Energie Atomique, Compagnie Generale des Matieres Nucleaires
    Inventors: Sylvain Faure, Bruno Fournel, Paul Fuentes, Yvan Lallot
  • Patent number: 7696145
    Abstract: A cleaning composition with a limited number of natural ingredients contains alkyl polyglucoside, solvent, acetic acid and water. The cleaning composition optionally contains dyes, glycerol, builders, fatty acids, polymers, fragrances, colorants, anti-foaming agents and preservatives. The cleaning composition can be used to clean hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.
    Type: Grant
    Filed: January 8, 2009
    Date of Patent: April 13, 2010
    Assignee: The Clorox Company
    Inventor: Thomas W. Kaaret
  • Patent number: 7687449
    Abstract: A method and cleaning composition for removing engine deposits from turbine components, in particular turbine disks and turbine shafts. This method comprises the following steps: (a) providing a turbine component having a surface with engine deposits thereon, wherein the turbine component comprises a nickel and/or cobalt-containing base metal; and (b) treating the surface of the turbine component with a cleaning composition to convert the engine deposits thereon to a removable smut without substantially etching the base metal of the turbine component. The cleaning composition comprises an aqueous solution that is substantially free of acetic acid and comprising: a nitrate ion source in an amount, by weight of the nitrate ion, of from about 470 to about 710 grams/liter; and a bifluoride ion source in an amount, by weight of the bifluoride ion, of from about 0.5 to about 15 grams/liter.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: March 30, 2010
    Assignee: General Electric Company GE Aviation
    Inventors: John Matthew Powers, William Clarke Brooks
  • Patent number: 7632797
    Abstract: The present invention relates to water-stable compositions and compounds formed by mixing an organosilane, optionally having a non-hydrolyzable organic group, but having one or more hydrolyzable groups, and an acidified stabilizing solution prepared from at least one acid, at least one glycol ether, and at least one cationic surfactant, preferably at least one quaternary ammonium salt (QAS), in water. The present invention also relates to methods of treating a substrate by mixing or contacting the substrate with the product, compound, or composition of this invention for a period of time sufficient for treatment of the substrate, methods of antimicrobially treating a food article, methods of antimicrobially coating a fluid container, methods of dyeing and treating a substrate, and methods of antimicrobially coating a latex medical article. The invention also pertains to a treated substrate having adhered thereto the product, compound, or composition of this invention.
    Type: Grant
    Filed: March 1, 2007
    Date of Patent: December 15, 2009
    Assignee: Vitec Speciality Chemicals Limited
    Inventors: Timothy C. Moses, Robert McMahon
  • Patent number: RE41938
    Abstract: Methods, compositions and kits for masking and subsequent removal of oil, grease, rust and other stains from a variety of rough solid surfaces, including, but not limited to stone, concrete, asphalt, stucco brick, and ceramic. The methods include coating the stains with an opaque or translucent thin film of a composition that makes the stain practically indistinguishable against the background, exposing the coated stain to the elements, such as, sunlight, air, moisture, resulting in spontaneous transformation, degradation and subsequent removal of the stains from the solid surfaces. The compositions include a photocatalyst by itself or the photocatalyst combined with at least one of, a sensitizer, a dopant, a mediator, a co-reagent, a pigment and a binder. The role of a photocatalyst is to produce highly reactive species or radicals and initiate the degradation of a stain upon exposure to elements, such as, sunlight, air and ambient humidity. Artificial light sources can be used instead of sunlight.
    Type: Grant
    Filed: July 2, 2009
    Date of Patent: November 16, 2010
    Assignee: University of Central Florida Research Foundation, Inc.
    Inventor: Nazim Muradov