Inorganic Acid Component (e.g., Sodium Bisulfate, Etc.) Patents (Class 510/269)
  • Publication number: 20150140704
    Abstract: A cleaning solution and a method for manufacturing a display device, the cleaning solution including about 2 wt % to about 12 wt % of nitric acid; about 0.5 wt % to about 15 wt % of an organic acid; about 0.1 wt % to about 10 wt % of a salt compound; about 0.01 wt % to about 3 wt % of an inorganic salt that includes fluorine; and a balance of water, all amounts being based on a total weight of the cleaning solution.
    Type: Application
    Filed: June 11, 2014
    Publication date: May 21, 2015
    Inventors: Jong-Hyun CHOUNG, In-Bae KIM, Hongsick PARK, Hyeonjeong SANG, Jaewoo JEONG, Byung uk KIM, Suk Il YOON, Se Hwan JUNG, Soon Beom HUH
  • Publication number: 20140334965
    Abstract: The present invention relates to an acidic aqueous solution suitable for the pickling of stainless steel grades that comprises accelerators based on water soluble inorganic compounds comprising at least one nitrogen atom in an oxidation state in the range of ?2 to ??. The present invention further encompasses a process for the pickling of stainless steel that makes use of a pickling solution comprising the above-mentioned accelerators.
    Type: Application
    Filed: July 29, 2014
    Publication date: November 13, 2014
    Inventors: Ioannis DEMERTZIS, Mauro RIGAMONTI, Paolo GIORDANI
  • Patent number: 8859479
    Abstract: A stripping solution comprises a highly corrosive acid and an iron concentration of at least about 1.0 gram per liter (g/L). The stripping solution is air agitated to remove a coating from a metal article submerged therein.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: October 14, 2014
    Assignee: United Technologies Corporation
    Inventor: Eric W. Stratton
  • Patent number: 8791057
    Abstract: A multi-phase surface cleaning composition. A first phase comprises an acidic cleaning formulation. A second phase comprises an alkaline cleaning formulation. The second phase includes a synthetic clay component.
    Type: Grant
    Filed: June 3, 2009
    Date of Patent: July 29, 2014
    Assignee: Reckitt & Colman (Overseas) Limited
    Inventors: David Acher, Vikki Louise Binns, Mark Ward
  • Patent number: 8632955
    Abstract: A method of conditioning the surface of a work piece, particularly of a strip or sheet, more particularly of a lithostrip or lithosheet, including an aluminum alloy is provided. The method for conditioning the surface of a work piece and a work piece including an aluminum alloy enabling an increasing manufacturing speed in electro-chemically graining and maintaining at the same time a high quality of the grained surface, includes a conditioning method which comprises at least the two steps, degreasing the surface of the work piece with a degreasing medium and subsequently cleaning the surface of the work piece by pickling.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: January 21, 2014
    Assignee: Hydro Aluminium Deutschland GmbH
    Inventors: Bernhard Kernig, Henk Jan Brinkman
  • Publication number: 20130338053
    Abstract: The present invention relates to compacted solid detergent compositions, generally in the form of pills or tablets for all types of cleaning tasks such as cleaning floors and glass, using washing machines, dishwashers, air fresheners, etc. This invention also relates to the use of the detergent composition according to the invention for producing effervescent tablets or compacted powders that can be used in detergent compositions that disaggregate immediately when they come into contact with an aqueous solution.
    Type: Application
    Filed: October 6, 2011
    Publication date: December 19, 2013
    Inventor: Jordi Caparros Casco
  • Patent number: 8426349
    Abstract: A chlorinated alkaline cleaning agent and methods for removing food soils with no resultant increase in foam generation. Particularly advantageous is that the addition of methanesulfonic acid in removing food soils with no resultant increase in foam generation.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: April 23, 2013
    Assignee: DeLaval Holding AB
    Inventor: Alan Monken
  • Patent number: 8227397
    Abstract: The disclosure relates to an enzyme stabilization system, compositions with the enzyme stabilization system, and methods of using the enzyme composition. Preferred ratios of acid to amine are effective at stabilizing enzyme. Optional nonionic surfactants and solvents also positively contribute to enzyme stability. The compositions are useful in cleaning applications.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: July 24, 2012
    Assignee: Ecolab USA Inc.
    Inventors: Brandon L. Herdt, Werner Strothoff, Alice Siegmann
  • Patent number: 8216992
    Abstract: The present invention discloses an improved cleaning composition for cleaning metal surfaces such as aluminum and aluminum-containing alloys. The cleaning composition of the present invention comprises water and an ethoxylate of an alcohol having Formula R1—OH wherein R1 is a saturated or unsaturated, straight-chain or branched aliphatic having from 12 to 80 carbon atoms; an inorganic pH adjusting component; and at least one surfactant that is different than the ethoxylate set forth above. The cleaning composition of the present invention also has an average water-break-free percent reduction of less than 50% after 7 days aging of a working composition prepared from the cleaning composition. The present invention also provides a method of cleaning a metal surface with the cleaning composition of the invention.
    Type: Grant
    Filed: January 23, 2004
    Date of Patent: July 10, 2012
    Assignee: Henkel KGaA
    Inventors: Andrew M. Hatch, Gary L. Rochfort, Richard D. Banaszak
  • Patent number: 8211622
    Abstract: A method of conditioning the surface of a work piece, particularly of a strip or sheet, more particularly of a lithostrip or lithosheet, including an aluminum alloy is provided. The method for conditioning the surface of a work piece and a work piece including an aluminum alloy enabling an increasing manufacturing speed in electro-chemically graining and maintaining at the same time a high quality of the grained surface, includes a conditioning method which comprises at least the two steps, degreasing the surface of the work piece with a degreasing medium and subsequently cleaning the surface of the work piece by pickling.
    Type: Grant
    Filed: April 5, 2006
    Date of Patent: July 3, 2012
    Assignee: Hydro Aluminium Deutschland GmbH
    Inventors: Bernhard Kernig, Henk Jan Brinkman
  • Patent number: 8192556
    Abstract: The use of complex fluoride ions of elements of groups 4, 13, or 14 of the periodic table of the chemical elements (preferably selected from complex fluoride ions of the elements B, Si, Ti, and Zr) in concentrations from 30 t 500 millimoles per liter in process solutions for pickling steel or for bleaching and/or passivating pickled surfaces of stainless steel; a process solution for pickling steel or bleaching and/or passivating pickled surfaces of stainless steel comprising: a) one or more strong acids, b) one or more oxidizing agents in the bleaching/passisvating process, c) complex fluoride ions of elements of groups 4, 13 or 14 of the periodic table of the chemical elements in concentrations from 50 to 500 mmoles per liter; replenisher or concentrate containing a combination of active substances thereof; a process for pickling steel or for brightening and/or passivating of pickled surfaces of stainless steel, wherein the surfaces are brought into contact with such a process solution.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: June 5, 2012
    Assignee: Henkel KGaA
    Inventors: Paolo Giordani, Valentino Gasparetto, Mauro Rigamonti
  • Patent number: 8163102
    Abstract: A composition is provided for use in cleaning a surface of a cementitious material. The composition includes HCI, urea, complex substituted keto-amine-hydrochloride, an alcohol, an ethoxylate, and a ketone. A method of using the composition includes applying the composition to a surface from which it is desired to clean a cementitious material and removing the composition and released cementitious material from the surface. Methods are also provided for performing hydraulic fracturing of an oil or a gas well; for adjusting a pH of a drilling fluid; for adjusting and maintaining a pH of a process fluid; for solubilizing calcium carbonate in an aqueous suspension or dispersion of calcium carbonate; for removing a foulant in a fluid-handling element; adjusting a pH and lowering a salt level of turf.
    Type: Grant
    Filed: May 10, 2011
    Date of Patent: April 24, 2012
    Assignee: Green Products & Technologies, LLC
    Inventor: John T. MacDonald
  • Publication number: 20110257057
    Abstract: A cleaning solution for cleaning stainless steels etched by ferric or ferrous salt solution is provided. The cleaning solution including: one or more ingredients selected from a group consisting of inorganic acid, inorganic alkali metal salt, and inorganic alkaline-earth metal salt in a concentration of about 200-600 g/L; complexant being capable of complexing with ferric or ferrous ions in a concentration of about 26-275 g/L; and one of carboxylic acid and carboxylate, or a combination thereof, in a concentration of about 75-250 g/L. A method for cleaning the stainless steels is also described there.
    Type: Application
    Filed: December 21, 2010
    Publication date: October 20, 2011
    Applicants: FIH (HONG KONG) LIMITED, SHENZHEN FUTAIHONG PRECISION INDUSTRY CO., LTD.
    Inventors: WEI HUANG, LING-QIAN CAI
  • Publication number: 20110253169
    Abstract: A solution and method for removing titanium-containing coatings from the surface of substrates using the solution are provided. The solution includes 90-1000 g/L organic or inorganic acid; 70-500 g/L accelerant, the accelerant being acid or salt which contains fluorinion; 15-200 g/L secondary accelerator, the secondary accelerator being generic amino alcohols which can combine with titanium ion; 2-8 g/L inhibiter, the inhibiter being selected from one or more of the group consisting of thiourea, thiourea derivatives, and carbamide. The method for removing titanium-containing coating on the substrate mainly includes contacting the substrate with the titanium-containing coating with the solution.
    Type: Application
    Filed: December 21, 2010
    Publication date: October 20, 2011
    Applicants: FIH (HONG KONG) LIMITED, SHENZHEN FUTAIHONG PRECISION INDUSTRY CO., LTD.
    Inventors: WEI HUANG, HONG-LI GONG
  • Publication number: 20100294307
    Abstract: The invention relates to a acidic composition for cleaning surfaces of metal or alloys which are susceptible to corrosion comprising i) an ester of phosphoric acid, diphosphoric acid or polyphosphoric acid, ii) a benzotriazole derivative of the general formula (I) in which each of the groups R1, R2, R3, R4 and R5 is the same or different and is hydrogen atom, an alkyl group, an alkenyl group, or an acyl group, iii) a phosphonic acid of the general formula R6—PO—(OH)2 (II) in which the group R6 is alkyl group, alkenyl group, aryl group, or arylalkyl group and iv) an acidic source. The invention further relates to a use solution and to a method for cleaning.
    Type: Application
    Filed: May 8, 2006
    Publication date: November 25, 2010
    Applicant: ECOLAB INC.
    Inventor: Thomas Tyborski
  • Patent number: 7776809
    Abstract: A method and a composition for remediating reticulation equipment such as a bore having biocontamination deposits is disclosed. In its most preferred form, the composition is formed by mixing dry solid oxalic acid, a cupric salt such as copper sulphate, and a solid acidic compound such as sodium bisulphate. Proportions of 94%, 2% and 4% respectively are suitable, while avoiding toxicity and contamination problems. After thorough mixing this mixture can be stored in a dry sealed container for future use. In use, the reticulation equipment is dosed with from 3 kg to 7 kg of mixture per hundred litres of water contained within the reticulation equipment.
    Type: Grant
    Filed: January 4, 2006
    Date of Patent: August 17, 2010
    Inventor: David Bennett
  • Patent number: 7718010
    Abstract: The present invention related to a method for treating a surface with a gel, as well as to a treatment gel. The treatment may be a decontamination, etching or surface degreasing treatment, for example. The method comprises in this order, the following steps: applying the treatment gel on the surface to be treated, maintaining the treatment gel on the surface to be treated at a temperature and relative humidity such that the gel dries by breaking up and that it has the time to treat the surface before forming a dry and solid residue, and removing the dry and solid residue from the treated surface by suction or brushing. The gel comprises a viscosing agent, a treatment agent and optional an oxidizing agent.
    Type: Grant
    Filed: August 9, 2005
    Date of Patent: May 18, 2010
    Assignees: Commissariat a L'Energie Atomique, Compagnie Generale des Matieres Nucleaires
    Inventors: Sylvain Faure, Bruno Fournel, Paul Fuentes, Yvan Lallot
  • Patent number: 7713357
    Abstract: The present invention relates to a method for treating a surface with a gel, as well as to a treatment gel. The treatment may be a decontamination, etching or surface degreasing treatment, for example. The method comprises in this order, the following steps: applying the treatment gel on the surface to be treated, maintaining the treatment gel on the surface to be treated at a temperature and relative humidity such that the gel dries by breaking up and that it has the time to treat the surface before forming a dry and solid residue, and removing the dry and solid residue from the treated surface by suction or brushing. The gel comprises a viscosing agent, a treatment agent and optionally an oxidizing agent.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: May 11, 2010
    Assignees: Commissariat a l'Energie Atomique, Compagnie Generale des Matieres Nucleaires
    Inventors: Sylvain Faure, Bruno Fournel, Paul Fuentes, Yvan Lallot
  • Patent number: 7687449
    Abstract: A method and cleaning composition for removing engine deposits from turbine components, in particular turbine disks and turbine shafts. This method comprises the following steps: (a) providing a turbine component having a surface with engine deposits thereon, wherein the turbine component comprises a nickel and/or cobalt-containing base metal; and (b) treating the surface of the turbine component with a cleaning composition to convert the engine deposits thereon to a removable smut without substantially etching the base metal of the turbine component. The cleaning composition comprises an aqueous solution that is substantially free of acetic acid and comprising: a nitrate ion source in an amount, by weight of the nitrate ion, of from about 470 to about 710 grams/liter; and a bifluoride ion source in an amount, by weight of the bifluoride ion, of from about 0.5 to about 15 grams/liter.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: March 30, 2010
    Assignee: General Electric Company GE Aviation
    Inventors: John Matthew Powers, William Clarke Brooks
  • Patent number: 7517844
    Abstract: A composition comprising a mixing product of: (i) a first acid having a pKa of less than 3, in an amount by weight of 1-10%, (ii) a second acid having a pKa of greater than 3, in an amount by weight of 1-10%, (iii) a nonionic surfactant in an amount by weight of 1-7%; and (iv) water; wherein the composition has a pH of less than 2.5. The composition can be used for the removal of grease, lime scale, soap scum, and rust on hard surfaces.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: April 14, 2009
    Assignee: Colgate-Palmolive Company
    Inventors: Patrick Diet, Jean Massaux, Isabelle Leonard
  • Patent number: 7470652
    Abstract: A cleaning implement with a handle and a removable cleaning pad can be used to effectively clean surfaces. The cleaning pad is impregnated with an acidic cleaning composition. The cleaning pad may be dry to the touch. The cleaning implement may be a manual tool or a motorized tool. Examples of suitable cleaning implements include a hard surface floor mop, a carpet mop, an auto cleaning device, a toilet cleaning device, a bathroom cleaning device, and a shower cleaning device.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: December 30, 2008
    Inventors: Andrew Kilkenny, Maha Y. El-Sayed, Lafayette D. Foland, Shona L. Nelson, Cheryl Rodriquez, David R. Scheuing
  • Patent number: 7470653
    Abstract: A light duty liquid cleaning composition comprising at least one ammonium or metal salt of a C8-C16 linear alkyl benzene sulfonate surfactant, at least one ammonium or metal salt of an ethoxylated C8-C18 alkyl ether sulfate surfactant having 1 to 30 moles of ethylene oxide, and at least one betaine surfactant; wherein (a) a total amount of surfactant in the composition is at least 30 weight %, (b) the composition has a pH less than 7 and a viscosity of less than 75 cPs measured at 25° C., (c) if a magnesium salt of a C8-C16 linear alkyl benzene sulfonate surfactant is present in the composition, it is present in an amount of 0.1 to less than 3 or greater than 16% by weight of the composition, and (d) the composition does not contain an inorganic magnesium salt.
    Type: Grant
    Filed: April 7, 2006
    Date of Patent: December 30, 2008
    Assignee: Colgate-Palmolive Company
    Inventors: Joan Ethel Gambogi, Cynthia McCullar Murphy, David Frank Suriano
  • Patent number: 7449436
    Abstract: A light duty liquid cleaning composition comprising at least one ammonium or metal salt of a C8-C16 linear alkyl benzene sulfonate surfactant, at least one ammonium or metal salt of an ethoxylated C8-C18 alkyl ether sulfate surfactant having 1 to 30 moles of ethylene oxide, and at least one betaine surfactant; wherein (a) a total amount of surfactant in the composition is at least 30 weight %, (b) the composition has a pH less than 7 and a viscosity of less than 75 cPs measured at 25° C. (c) if a magnesium salt of a C8-C16 linear alkyl benzene sulfonate surfactant is present in the composition, it is present in an amount of 0.
    Type: Grant
    Filed: October 8, 2007
    Date of Patent: November 11, 2008
    Assignee: Colgate-Palmolive Company
    Inventors: Joan Ethel Gambogi, Cynthia McCullar Murphy, David Frank Suriano
  • Patent number: 7446082
    Abstract: A cleaning implement with a handle and a removable cleaning pad can be used to effectively clean surfaces. The cleaning pad is impregnated with an acidic cleaning composition. The cleaning pad may be dry to the touch. The cleaning implement may be a manual tool or a motorized tool. Examples of suitable cleaning implements include a hard surface floor mop, a carpet mop, an auto cleaning device, a toilet cleaning device, a bathroom cleaning device, and a shower cleaning device.
    Type: Grant
    Filed: April 20, 2007
    Date of Patent: November 4, 2008
    Assignee: The Clorox Company
    Inventors: Andrew Kilkenny, Maha Y. El-Sayed, Lafayette D. Foland, Shona L. Nelson, Cheryl Rodriguez, David R. Scheuing
  • Patent number: 7402553
    Abstract: A buffered acid composition created by the combination of liquid ammonia and an acid and a method for making the composition. The buffered acid composition is for use as a cleaning agent and for balancing the pH of a fluid.
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: July 22, 2008
    Inventor: Stephen C. Perry
  • Patent number: 7387991
    Abstract: The compositions of this invention are microemulsions having a. a surfactant consisting essentially of a mixture of one or more alkoxylated amines or alkoxylated quaternary ammonium salts and one or more preferably branched carboxylic acids or salts thereof, b. a solvent or oil that is liquid at 25° C. and is insoluble in water, and c. water, wherein an optically clear isotropic microemulsion is formed.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: June 17, 2008
    Inventor: Alice P. Hudson
  • Patent number: 7384901
    Abstract: A process for cleaning (e.g., desmutting) an aluminum surface, using compositions free of nitric acid and chromic acid and comprising, in one embodiment, an oxidant and at least one mineral acid salt. In another embodiment, the process uses a composition free of nitric acid and chromic acid and comprising an oxidant, at least one mineral acid salt, and a complexing agent which is a salt of an organic acid. Due at least in part to the absence of nitric and chromic acids, and in particular, strong mineral acids, the cleaning processes of the present invention remove smut residues from aluminum surfaces without significant etching of the aluminum.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: June 10, 2008
    Assignee: Atotech Deutschland GmbH
    Inventors: Nayan H. Joshi, Maulik D. Mehta
  • Patent number: 7348302
    Abstract: A cleaning composition including a metal bisulfate and metal inorganic salt acid package, and at least one surfactant. The cleaning composition can be a one-step wheel cleaner/brightener. The composition preferably contains no HF, no bifluoride, no oxalic acid, or other poisonous and highly toxic materials commonly found in both industrial and consumer wheel cleaners. Further, the wheel cleaner/brightener composition matches or exceeds the performance of those hazardous formulations and does not damage aluminum wheels even when applied to hot metal. The composition can be a foam composition, provided in a foam dispenser. The foam dispenser includes a container and a mechanical foaming head. The container includes a cleaning composition containing a metal bisulfate and metal sulfate acid package, and at least one surfactant, water, and a foam-boosting solvent.
    Type: Grant
    Filed: November 4, 2005
    Date of Patent: March 25, 2008
    Assignee: Ecolab Inc.
    Inventor: Kim R. Smith
  • Patent number: 7323436
    Abstract: An adduct that has an acidic solution of sparingly-soluble Group IIA complexes (“AGIIS”) and at least one additive. The AGIIS can be prepared by mixing a mineral acid (such as sulfuric acid), and a Group IIA hydroxide (such as calcium hydroxide) or a Group IIA salt of a dibasic acid (such as calcium sulfate), or a mixture of the two Group IIA compounds, followed by removing the solid formed. The additives can be an alcohol, an organic acid or a surface active agent. The composition has various uses, including cleaning, food production, decontamination, bioremediation, agricultural application, medical application, and detoxification of substances.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: January 29, 2008
    Assignee: Mionix Corporation
    Inventors: Maurice Clarence Kemp, Robert B. Lalum, Zhong Wei Xie, Michael A. Cunha, Robert H. Carpenter, Zhang Shu, Yao Yu, David E. Lewis
  • Patent number: 7291586
    Abstract: The present invention is directed to a sprayable, acidic hard surface cleaning and/or disinfecting composition which contains suspended inclusions which appear as visibly discernible, discrete particulate materials, preferably where said discrete particulate materials are based on alginates which are present as two or more classes of particulate materials.
    Type: Grant
    Filed: February 23, 2004
    Date of Patent: November 6, 2007
    Assignee: Reckitt Benckiser Inc.
    Inventors: Pamela Boone, Delford Ian Christmas, Lisa Ann Napolitano, Virginia Lee Urban
  • Patent number: 7288512
    Abstract: The present invention is directed to a sprayable, acidic hard surface cleaning and/or disinfecting composition which contains suspended inclusions which appear as visibly discernible, discrete particulate materials, preferably where said discrete particulate materials are based on alginates. The composition contains a thiclcener which comprises both gellan gum and Xanthan gum.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: October 30, 2007
    Assignee: Reckitt Benckiser Inc.
    Inventors: Pamela Boone, Virginia Lee Urban
  • Patent number: 7256167
    Abstract: The present invention is directed to a pourable acidic hard surface cleaning and/or disinfecting composition which contains suspended inclusions which appear as visibly discernible, discrete particulate materials, preferably where said discrete particulate materials are based on alginates.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: August 14, 2007
    Assignee: Reckitt Benckiser Inc.
    Inventors: Tak Wai Cheung, Edward Fu, Pamela A. Boone, Steven Wu, Benjamin Costa
  • Patent number: 7196046
    Abstract: The present invention is directed to a pourable acidic hard surface cleaning and/or disinfecting composition which contains suspended inclusions which appear as visibly discernible, discrete particulate materials, preferably where said discrete particulate materials are based on alginates.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: March 27, 2007
    Assignee: Reckitt Benckiser Inc.
    Inventors: Tak Wai Cheung, Edward Fu, Pamela A. Boone, Steven Wu, Benjamin Costa
  • Patent number: 7186676
    Abstract: The present invention is directed to a pourable acidic hard surface cleaning and/or disinfecting composition which contains suspended inclusions which appear as visibly discernible, discrete particulate materials, preferably where said discrete particulate materials are based on alginates.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: March 6, 2007
    Assignee: Reckitt Benckiser Inc.
    Inventors: Pamela A. Boone, Tak Wai Cheung, Benjamin J. Costa, Edward Fu, Steven Wu, Carolyn Martinez
  • Patent number: 7160847
    Abstract: A method for chemical etching is disclosed for taking away oxidized film and removing cut as well as punched edge burs of harden-treated carbon steel (SK3, SK4 and SK5). Thereby, the fillet edge of the cut section is achieved. An oxidized film with a thickness of several micrometers is formed when a cut and punched steel is quenched and tempered at high temperature. Due to high strength and hardness of the steel, the oxidized film and edge burs are difficult to be removed by mechanical grinding. Therefore, a suitable electrolyte composes of only a little chemical reagent and oxidizer in deionized water is used to remove the oxidized film and punched bur simultaneously using chemical etching method.
    Type: Grant
    Filed: April 22, 2003
    Date of Patent: January 9, 2007
    Assignee: Chang Gung University
    Inventors: Ching-An Huang, Chun-Ching Hsu
  • Patent number: 7119055
    Abstract: The present invention is directed to a sprayable, acidic hard surface cleaning and/or disinfecting composition which contains suspended inclusions which appear as visibly discernible, discrete particulate materials, preferably where said discrete particulate materials are based on alginates.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: October 10, 2006
    Assignee: Reckitt Benckiser Inc.
    Inventors: Tak Wai Cheung, Pamela A. Boone, Delford I. Christmas, Lisa A. Napolitano, Benjamin Costa, Virginia L. Urban
  • Patent number: 7091166
    Abstract: An aqueous liquid composition comprising water; at least one acid selected from the group consisting of carboxylic acids, hydroxycarboxylic acids, and inorganic acids other than phosphoric acid wherein the at least one acid is present in an amount from about 1.0 to about 30 milliequivalents per kilogram of total composition (“mEq/kg”); and an amphoteric surfactant wherein the amphoteric surfactant is present in an amount from about 0.01 to about 20 grams per kilogram of total composition (“g/kg”), the aqueous liquid composition having a pH from about 2.0 to about 6.1 and having a reduced etch attack on metal as compared to an aqueous composition comprising from about 1.0 to about 30 milliequivalents per kilogram of total composition (“mEq/kg”) of acids selected from the group consisting of carboxylic, hydroxycarboxylic, and inorganic acids, and not containing the amphoteric surfactant.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: August 15, 2006
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventor: Theodore D. Held, III
  • Patent number: 7041629
    Abstract: The inventive aqueous pickling agent on the basis of sulfuric acid or phosphoric acid and hydrogen fluoride for stainless steels, which pickling agent is free of wetting and emulsifying agents, contains (each as 100 wt-% substance) 1.5 to 16 wt-% sulfuric acid or 2.0 to 30 wt-% phosphoric acid as well as 0.5 to 14 wt-% hydrogen fluoride and 0.5 to 15.5 wt-% acid-soluble aromatic nitro compound. An iron(III) compound is not supplied to said pickling agent. Merely in the starting phase, an oxidizing agent can be supplied, which oxidizes iron(II) to form iron(III). As acid-soluble aromatic nitro compound m-nitrobenzene sulfonate and/or 3-nitrophthalate are particularly advantageous. The inventive pickling agent can be used as bath pickle and —when adding 2.5 to 5.5 wt-% magnesium and/or magnesium compound (calculated as Mg)—also as spraying pickle or brush pickle.
    Type: Grant
    Filed: August 26, 2003
    Date of Patent: May 9, 2006
    Assignee: Chemetall GmbH
    Inventors: Eckart Schonfelder, Gunther Schwane, Harald Werner
  • Patent number: 7037379
    Abstract: An aqueous solution that has the capacity for removing tarnish and other soil from copper, silver, gold and other noble metals and alloys thereof comprises an acid, thiourea and a transition metal salt. The aqueous material can be used to treat the surfaces of such articles for the purpose of removing tarnish. Such tarnish is removed by the composition and the composition treats the metal surface to retard the re-appearance of tarnish contaminants.
    Type: Grant
    Filed: February 23, 2005
    Date of Patent: May 2, 2006
    Assignee: For Your Ease Only, Inc.
    Inventor: Scott M. Croce
  • Patent number: 6992053
    Abstract: The present invention encompasses a composition, suitable for cleaning hard surfaces, comprising a bleaching agent and a silicone glycol.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: January 31, 2006
    Assignee: The Procter & Gamble Company
    Inventors: Laura Cermenati, Vincenzo Tomarchio
  • Patent number: 6982242
    Abstract: An aqueous detergent composition is provided containing phosphoric acid or salt thereof, an organic phosphate surfactant, a nonionic surfactant, and water. The aqueous detergent composition may be employed to improved the adhesion of a coating to a substrate. Also provided is a method of improving the adhesion of a coating to a substrate.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: January 3, 2006
    Assignee: Rohm and Haas Company
    Inventors: Audrey Brenda Liss, Joseph Martin Rokowski, Thomas James Ennis
  • Patent number: 6982241
    Abstract: A cleaning composition is provided according to the invention. The cleaning composition includes a product of mixing an acid component, a source of phosphoric acid component, and an oxidant component. The molar ratio of oxidant component to phosphoric acid component is preferably between about 2:1 and about 1:2, and the molar ratio of oxidant component to acid component is preferably between about 1:3 and about 1:5. A method of cleaning an aluminum surface is provided. The method includes a step of applying the cleaning composition to an aluminum surface, and rinsing the cleaning composition from the aluminum surface.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: January 3, 2006
    Assignee: Ecolab Inc.
    Inventors: Kim R Smith, Robert D P. Hei, Michael E Besse, Jerry D. Hoyt
  • Patent number: 6896739
    Abstract: An aqueous solution that has the capacity for removing tarnish and other soil from copper, silver, gold and other noble metals and alloys thereof comprises an acid, thiourea and a transition metal salt. The aqueous material can be used to treat the surfaces of such articles for the purpose of removing tarnish. Such tarnish is removed by the composition and the composition treats the metal surface to retard the re-appearance of tarnish contaminants.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: May 24, 2005
    Assignee: For Your Ease Only, Inc.
    Inventor: Scott M. Croce
  • Patent number: 6841525
    Abstract: A cleaning method in a semiconductor fabrication process includes providing a dilute composition consisting essentially of phosphoric acid and acetic acid and exposing a surface, e.g., aluminum, to the dilute composition. For example, the dilute composition includes phosphoric acid at a concentration of about 5% or less by volume and acetic acid at a concentration of about 30% or less by volume. Further, the cleaning method may use a composition comprising phosphoric acid and acetic acid, wherein the composition includes phosphoric acid at a concentration of X %, wherein X is about 5% by volume or less, and acetic acid at a concentration of about (100-X %) by volume or less. The cleaning method may be used, for example, in fabricating interconnect structures, aluminum containing structures, and multilevel interconnect structures. Cleaning compositions for use in the cleaning methods are also provided.
    Type: Grant
    Filed: August 22, 2001
    Date of Patent: January 11, 2005
    Assignee: Micron Technology, Inc.
    Inventors: Max Hineman, Guy T. Blalock
  • Patent number: 6793738
    Abstract: A method for preparing a solution for treating an article, a treatment solution made thereby, and a method for treating an article with the solution are presented with, for example, the treatment method comprising providing a quantity of treatment solution, the treatment solution comprising an acid having the formula HxAF6, wherein A is selected from the group consisting of Si, Ge, Ti, Zr, Al, and Ga, and x is in the range from about 1 to about 6; determining a concentration of free acid contaminant in the treatment solution; and removing the concentration of free acid contaminant.
    Type: Grant
    Filed: March 28, 2002
    Date of Patent: September 21, 2004
    Assignee: General Electric Company
    Inventors: Lawrence Bernard Kool, James Anthony Ruud, Ralph James Carl, Jr., Gabriel Kwadwo Ofori-Okai
  • Patent number: 6767874
    Abstract: A cleaning composition for removing organic deposits from hard to reach surfaces. In its basic embodiment, the cleaning composition comprises: a) a water miscible solvent; b) an inorganic salt in crystal form; and c) water. The inorganic salt in crystal form comprises from about 30 to about 70% weight of the total composition.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: July 27, 2004
    Inventor: Gustavo M. Gonzalez
  • Patent number: 6617298
    Abstract: A composition for the removal of grease and oil spots from concrete, asphalt surfaces, etc., comprises a degreaser and a diatomaceous earth. The degreaser comprises a number of ingredients of respective percentage ranges to emulsify the grease or oil which is then absorbed by the diatomaceous earth.
    Type: Grant
    Filed: December 31, 2002
    Date of Patent: September 9, 2003
    Inventors: Dennis S. Morrow, William T. Morrow, Kishor Pathak
  • Patent number: 6537962
    Abstract: The present invention pertains to a composite powder comprising (A) an alkali metal silicate particle having an average particle size of from 1 to 500 &mgr;m; and (B) a water-soluble salt particle having an average particle size of from 0.01 to 50 &mgr;m, of which solubility to water at 20° C. is 1 g/100 g or more, wherein the alkali metal silicate particle has a composition formula in an anhydride form represented by: xM2O.ySiO2.zMeO (I) wherein M stands for Na and/or K; Me stands for Ca and/or Mg; y/x is from 0.5 to 4.0; z/x is from 0 to 1.0; and Mg/Ca in MeO is from 0 to 10, and wherein the composite powder has a (A)/(B) weight ratio of from 1/9 to 99/1; and a detergent composition comprising the composite powder. The composite powder is a composite powder having a remarkably enhanced storage stability of the alkali metal silicate without impairing the ion exchange capacity owned by the alkali metal silicate.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: March 25, 2003
    Assignee: Kao Corporation
    Inventors: Kazuo Oki, Takashi Miyaji, Kazuhiro Otsuka, Mikio Sakaguchi
  • Patent number: 6494960
    Abstract: A method for removing an aluminide coating from a substrate includes the steps of contacting the surface of the substrate with at least one stripping composition to degrade the coating. The stripping composition includes an aliphatic or aromatic sulfonic acid, and at least one additive. The coating is then removed.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: December 17, 2002
    Assignee: General Electric Company
    Inventors: Leo Spitz Macdonald, D. Sangeeta, Mark Alan Rosenzweig
  • Patent number: 6489281
    Abstract: A cleaning composition is provided according to the invention. The cleaning composition includes a product of mixing an acid component, a source of phosphoric acid component, and an oxidant component. The molar ratio of oxidant component to phosphoric acid component is preferably between about 2:1 and about 1:2, and the molar ratio of oxidant component to acid component is preferably between about 1:3 and about 1:5. A method of cleaning an aluminum surface is provided. The method includes a step of applying the cleaning composition to an aluminum surface, and rinsing the cleaning composition from the aluminum surface.
    Type: Grant
    Filed: September 12, 2000
    Date of Patent: December 3, 2002
    Assignee: Ecolab Inc.
    Inventors: Kim R. Smith, Robert D. P. Hei, Michael E. Besse, Jerry D. Hoyt