With Halogen, Oxygen, Or Nitrogen Containing Chemical Bleach, Oxidant, Antiseptic, Or Biocidal Component Patents (Class 510/286)
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Patent number: 6642196Abstract: There is provided a method of delivering a benefit agent whereby a benefit agent is first loaded to a surface and subsequently unloaded and transferred and delivered to a second surface. More in particular, the benefit agent is first loaded onto a garment during a laundering process, and subsequently delivered to another surface. The benefit agents can be fragrance agents, perfumes, colour enhancers, fabric softening agents, polymeric lubricants, photoprotective agents, latexes, resins, dye fixative agents, encapsulated materials, antioxidants, insecticides, soil repelling agents, soil release agents, and cellulose fibers.Type: GrantFiled: December 20, 2000Date of Patent: November 4, 2003Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Steven Howell, Julie Little, Cornelis Paul Van Der Logt, Neil James Parry
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Patent number: 6605580Abstract: A bleaching composition is provided comprising a) a bleach-effective amount of an inorganic bleaching agent; b) a bleach-compatible solvent c) 0 to 10 wt % of a surfactant; d) less than 10 wt % of a modifier; and e) an effective dry cleaning amount of densified carbon dioxide, said composition being essentially free of organic peracid or precursor thereof.Type: GrantFiled: December 20, 2000Date of Patent: August 12, 2003Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes Jacob Verhagen, Pieter van der Vlist
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Patent number: 6586380Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, this invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.Type: GrantFiled: February 1, 2002Date of Patent: July 1, 2003Assignee: Huntsman Petrochemical CorporationInventors: Edward T. Marquis, Robert E. Baldwin
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Patent number: 6586384Abstract: A method of delivering a benefit agent to a selected area of a fabric for exerting a predetermined activity, wherein the area is pre-treated with a multi-specific binding molecule which has a high binding affinity to said area through one specificity and is capable of binding to said benefit agent through another specificity, followed by contacting said pre-treated area with said benefit agent, to enhance said pre-determined activity to said area. Preferably, the binding molecule is an antibody or fragment thereof, or a fusion protein comprising a cellulose binding domain and a domain having a high binding affinity to another ligand which is directed to said benefit agent. The method is useful for stain removal, perfume delivery, and treating collars and cuffs for wear.Type: GrantFiled: December 20, 2000Date of Patent: July 1, 2003Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Sandra Hemmington, Steven Howell, Julie Little, Cornelis Paul Van Der Logt, Neil James Parry, Richard George Smith
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Patent number: 6579842Abstract: A method of delivering a benefit agent to fabric for exerting a pre-determined activity, wherein the fabric is pre-treated with a multi-specific binding molecule which has a high binding affinity to the fabric through one specificity and is capable of binding to the benefit agent through another specificity, followed by contacting the pre-treated fabric with the benefit agent, to enhance the pre-determined activity to the fabric. Preferably, the binding molecule is an antibody or fragment thereof, or a fusion protein comprising a cellulose binding domain and a domain having a high binding affinity to another ligand which is directed to said benefit agent. The method is useful for example for stain removal, perfume delivery, and treating collars and cuffs for wear.Type: GrantFiled: December 20, 2000Date of Patent: June 17, 2003Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Steven Howell, Julie Little, Cornelis Paul Van Der Logt, Neil James Parry
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Patent number: 6562774Abstract: A bleaching composition is provided comprising a) a bleach-effective amount of a low-active oxygen bleaching agent; b) a bleach-compatible solvent c) 0 to 10 wt % of a surfactant; d) less than 10 wt % of a modifier; and e) an effective dry cleaning amount of densified carbon dioxide, said composition being essentially free of carbon dioxide soluble organic peracid.Type: GrantFiled: December 20, 2000Date of Patent: May 13, 2003Assignee: Unilever Home & Personal Case USA, division of Conopco, Inc.Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes Jacob Verhagen, Pieter Van Der Vlist
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Publication number: 20030074742Abstract: A dry cleaning composition comprising a volatile siloxane and a mixture of different classes of organic surfactants and, optionally water, and a method for dry cleaning comprising contacting an article with a composition comprising a volatile siloxane and a mixture of different classes of organic surfactants.Type: ApplicationFiled: May 24, 2002Publication date: April 24, 2003Applicant: GENERAL ELECTRIC COMPANYInventors: Robert J. Perry, Donna Ann Riccio, Larry D. Ryan, John A. Kilgour
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Patent number: 6495502Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide, preferably held at 25° C. or less.Type: GrantFiled: December 20, 2000Date of Patent: December 17, 2002Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
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Publication number: 20020184715Abstract: An improved dry cleaning apparatus and method for the non-aqueous cleaning of fabric materials comprises the introduction of steam into a dryer chamber containing fabric materials previously washed in a non-aqueous organic cleaning solvent such as perchloroethylene. The steam is heated at a sufficient temperature for a duration of time, both of which are determined by the type of fabric and solvents involved. The heated steam volatilizes any excess cleaning solvent contained in or on said fabric creating a gaseous water/solvent mixture which is then subsequently separated from the fabric materials. The gaseous mixture can be condensed, its component parts separated and re-used in the cycle again.Type: ApplicationFiled: June 6, 2001Publication date: December 12, 2002Inventor: Robert E. Taylor
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Patent number: 6482786Abstract: The present invention relates to a liquid bleaching composition comprising a peroxygen bleach, a zwitterionic betaine surfactant, a sulphonated hydrotrope, and a nonionic surfactant. This composition is suitable to deliver excellent stain removal performance and bleaching performance on various surfaces including fabrics and hard-surfaces, with improved physical stability, especially at low temperatures.Type: GrantFiled: November 16, 2000Date of Patent: November 19, 2002Assignee: The Procter & Gamble CompanyInventors: Valerio Del Duca, Stefano Giunti, Nobuo Ishida
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Patent number: 6479447Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide.Type: GrantFiled: December 20, 2000Date of Patent: November 12, 2002Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
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Patent number: 6475246Abstract: An additive for introduction into a dry cleaning solvent, and a method of use thereof, which reduces static electricity, minimizes linting, fights acidity to reduce corrosion, deodorizes the solvent, and does not adversely affect the filtering operation. The additive contains sodium bicarbonate and an anti-static agent; preferably in the presence of an odorant.Type: GrantFiled: May 22, 2000Date of Patent: November 5, 2002Assignee: Pariser IndustriesInventors: Albert A. Pariser, Joel Speer
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Patent number: 6465409Abstract: The invention concerns an aqueous biocide system comprising: at least one water-soluble or water-dispersible biocidal agent, and at least a polyorganosiloxane with water-soluble or water-dispersible functions. The invention also concerns the use of the system for disinfecting hard surfaces, or a method for disinfecting hard surfaces using the system, with controlled release of the biocide when contacted with an aqueous medium of a hard surface whereon the aqueous medium has been deposited and dried.Type: GrantFiled: March 31, 2000Date of Patent: October 15, 2002Assignee: Rhodia ChimieInventors: John Frederic Carr, GĂ©rard Mignani, Louis Vovelle, Brian Davis, Caroll Vergelati
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Publication number: 20020133885Abstract: An process for treating or cleaning fabric articles, especially articles of clothing, linen and drapery, wherein the method comprises contacting the fabric articles to be cleaned or treated with a cleaning fluid comprising a lipophilic fluid and removing from the fabric articles a portion of the cleaning fluid.Type: ApplicationFiled: May 4, 2001Publication date: September 26, 2002Applicant: The Procter & Gamble CompanyInventors: Anna Vadimovna Noyes, John Cort Severns, Frederick Anthony Hartman, James Charles Theophile Roger Burckett-St. Laurent, Arseni V. Radomyselski, Paul Amaat France, Jeffrey John Scheibel, Christiaan Arthur Jacques Kamiel Thoen, John Christopher Deak, Phillip Kyle Vinson, Nabil Yaqub Sakkab
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Patent number: 6451746Abstract: An effervescent compound is disclosed which includes a liquid ingredient, an effervescent system and optionally a solvent. The solvent may be both hydrophilic and have low solubility with effervescent ingredients. The solvent may include an alcohol, a glycol or a glycol ether, for example, but not limited to, 2-butoxyethanol. The effervescent system used in the effervescent compound may be, for example, but is not limited to, expanded sodium perborate and/or a mixture of any or one or more of sodium bicarbonate, sodium carbonate, potassium bicarbonate and potassium carbonate. The effervescent compound may further include any one, or all, or any combination of the following ingredients: surfactants, bleaching compositions, anti-redeposition agents, binders, lubricants, colors, fragrances, and/or optical brighteners.Type: GrantFiled: March 21, 2001Date of Patent: September 17, 2002Assignee: ChemLink Laboratories, LLCInventors: Ryan Giffin Moore, Hilton G. Dawson, Richard A. DeSenna, Kenneth Scott Wiley
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Patent number: 6413929Abstract: Use of amines as bleaching efficiency boosters for textile detergent compositions, where the pKa of the amines is greater than the pH minus 1, preferably greater than the pH, particularly preferably at least 0.5 greater than the pH of the 1% by weight wash liquor obtained from the textile detergent composition.Type: GrantFiled: July 19, 2000Date of Patent: July 2, 2002Assignee: BASF AktiengesellschaftInventors: Thomas Wehlage, Dieter Boeckh, Werner Bertleff, Alfred Oftring
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Patent number: 6410497Abstract: Inorganic per compounds may be activated with oxime carbonates of the formula (I), A—O—CO—OR3, a hydroximide ester of formula (II): or polymeric hydroximide esters.Type: GrantFiled: August 4, 1999Date of Patent: June 25, 2002Assignee: BASF AktiengesellschaftInventors: Elisabeth Kappes, Thomas Wehlage, Alfred Oftring, Dieter Boeckh
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Patent number: 6407045Abstract: The invention set out to improve the oxidizing and bleaching effect of inorganic peroxygen compounds in dishwashing, more particularly machine dishwashing, in terms of their storage stability. This was essentially achieved by using particulate compounds corresponding to formula R1R2R3N−CH2CN X+, in which R1, R2, and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach-boosting agent.Type: GrantFiled: October 2, 2001Date of Patent: June 18, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Christian Nitsch, Horst-Dieter Speckmann, Juergen Haerer, Andreas Lietzmann, Susan P. Huestis
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Patent number: 6391838Abstract: The cleaning performance of bleach-containing detergents, especially against protein- and starch-containing soils and colored soils, was to be improved.Type: GrantFiled: March 31, 2000Date of Patent: May 21, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Horst-Dieter Speckmann, Joerg Poethkow
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Patent number: 6376452Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.Type: GrantFiled: March 31, 1999Date of Patent: April 23, 2002Assignee: 3M Innovative Properties CompanyInventors: Richard M. Flynn, Mark W. Grenfell, George G. I. Moore, John G. Owens, Dean S. Milbrath
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Patent number: 6372703Abstract: A liquid non-aqueous detergent is presented containing a nonionic surfactant, a builder, a bleaching agent, and a cationic stabilizer of formula I, II or III: where the groups R1 independently of one another are C1-6 alkyl, alkenyl or hydroxyalkyl groups, the groups R2 independently of one another are C8-28 alkyl or alkenyl groups, R3 has the same meaning as R1 or represents (CH2)n—T—R2, R4 has the same meaning as R1 or R2 or represents (CH2)n—T—R2, T represents —CH2—, —O—CO— or —CO—O— and n is an integer of from 0 to 5. The solid bleaching agents in the stabilized non-aqueous liquid detergent retain their activity after prolonged storage.Type: GrantFiled: July 15, 1999Date of Patent: April 16, 2002Assignee: Henkel Komanditgesellschaft auf AktienInventors: Bernd Richter, Ulrich Pegelow
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Patent number: 6297206Abstract: A method for dry-cleaning garments or fabrics in carbon dioxide comprises contacting a garment or fabric article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the article, said liquid dry-cleaning composition comprising a mixture of carbon dioxide, water, a first surfactant, and a second surfactant, and then separating the article from the liquid dry cleaning composition. The first surfactant comprises a CO2-philic group covalently joined to a hydrophilic group; and the second surfactant comprising a CO2-philic group covalently joined to a lipophilic group. In the alternative, a single surfactant containing all three of a CO2-philic group, a lipophilic group, and a hydrophilic group covalently joined to one another may also be employed. Systems useful for carrying out the foregoing are also disclosed.Type: GrantFiled: January 23, 2001Date of Patent: October 2, 2001Assignee: MiCell Technologies, Inc.Inventors: Timothy J. Romack, James P. DeYoung
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Patent number: 6239096Abstract: A powdered abrasive cleanser that exhibits superior soil removal properties and surface safety is provided. The cleanser includes a surfactant, an optional source of active chlorine, a borax pentahydrate compound that is preferably sodium tetraborate pentahydrate, and optionally an alkaline detergent builder and/or calcium carbonate.Type: GrantFiled: July 1, 1999Date of Patent: May 29, 2001Assignee: The Clorox CompanyInventors: Robert L. Blum, Denise A. Garner, Carl M. Kling
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Patent number: 6239090Abstract: A thickened composition and process useful for removing paint, comprising: a carbonate such as propylene carbonate or ethylene carbonate, a thickener such as polyvinyl pyrrolidone (PVP), hydrogen peroxide and water. The composition may include additional cosolvents such as glycol ethers and alcohols such as benzyl alcohol, and/or dibasic ester (DBE).Type: GrantFiled: December 10, 1999Date of Patent: May 29, 2001Assignee: Huntsman Petrochemical CorporationInventors: Edward T. Marquis, Robert E. Baldwin, James R. Machac, Jr., Katty Darragas, Susan Aileen Woodrum
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Publication number: 20010001479Abstract: The invention relates to an improved hide-curing additive comprising an effective biocidal amount of an essential oil and a non-ionic surfactant. The improved additive provides an effective cure for the hides, is environmentally safe and economical.Type: ApplicationFiled: September 23, 1998Publication date: May 24, 2001Applicant: Dana J. JohnsonInventors: DANA J. JOHNSON, TERRY L. MCANINCH, FREDERICK W. HOLZHAUER
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Patent number: 6235701Abstract: A stable fluid comprising compressed fluid carbon dioxide, an inert gas and a fluorochemical stabilizer is disclosed. The fluid composition is useful in cleaning of metals, glass, ceramics, natural and synthetic polymers, and fabrics and in the extraction of desirables substances, such as the extraction of essential oils from plants.Type: GrantFiled: April 26, 1999Date of Patent: May 22, 2001Assignee: 3M Innovative Properties CompanyInventor: Cheryl L. Senger Elsbernd
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Patent number: 6225274Abstract: A method for washing dishes containing colored soil is presented involving contacting the dish surface with a dishwashing detergent containing a peroxygen compound and an activator compound of the formula R1R2R3N+CH2CN X− where R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, and wherein R2 and R3 may be part of a heterocycle including the N atom, and X is an anion, to form an aqueous dishwashing detergent. The method is useful for washing colored stains from crockery and cutlery, and is effective at temperatures below 80° C.Type: GrantFiled: May 26, 1999Date of Patent: May 1, 2001Assignee: Henkel Kommandigesellschaft auf AktienInventors: Christian Nitsch, Rainer Jeschke
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Patent number: 6214782Abstract: Detergent formulations containing cationic nitriles are shown to exhibit reduced silver tarnishing as compared to similar formulations containing TAED.Type: GrantFiled: March 24, 2000Date of Patent: April 10, 2001Assignee: Unilever Home & Personal Care, USA, division of Conopco, Inc.Inventors: Catherine Chiou, Narish Dhirajlal Ghatlia
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Patent number: 6200943Abstract: A method for dry-cleaning garments or fabrics in carbon dioxide comprises contacting a garment or fabric article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the article, said liquid dry-cleaning composition comprising a mixture of carbon dioxide, water, a first surfactant, and a second surfactant, and then separating the article from the liquid dry cleaning composition. The first surfactant comprises a CO2-philic group covalently joined to a hydrophilic group; and the second surfactant comprising a CO2-philic group covalently joined to a lipophilic group. In the alternative, a single surfactant containing all three of a CO2-philic group, a lipophilic group, and a hydrophilic group covalently joined to one another may also be employed. Systems useful for carrying out the foregoing are also disclosed.Type: GrantFiled: May 27, 1999Date of Patent: March 13, 2001Assignee: MiCell Technologies, Inc.Inventors: Timothy J. Romack, James P. DeYoung
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Patent number: 6187738Abstract: There is provided an aqueous composition for cleaning fabrics and carpets and inhibiting the resoiling of fabric and carpets. The composition includes a peroxygen compound, a surfactant system, and a polymeric or copolymeric soil resist. The resulting compositions are particularly stable and non-turbid.Type: GrantFiled: February 2, 1999Date of Patent: February 13, 2001Assignee: Playtex Products, Inc.Inventors: Robert P. Micciche, Ann Marie Lynch, Uma Tripathi, Carol Belansky
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Patent number: 6165963Abstract: A detergent bleaching composition is provided comprising a compound inclug a specified pentadentate nitrogen-containing ligand. The compound can activate hydrogen peroxide or peroxyacids and provides favourable stain removal properties, particularly in the presence or iron, manganese or copper ions. In addition, an improved stability in alkaline aqueous environment has been obtained, in particular at the peroxy compound concentrations generally present in the fabric washing liquor.Type: GrantFiled: November 3, 1999Date of Patent: December 26, 2000Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Michel Gilbert Delroisse, Bernard Lucas Feringa, Ronald Hage, Roelant Mathijs Hermant, Robertus Everardus Kalmeijer, Jean Hypolites Koek, Christiaan Lamers, Minze Theunis Rispens, Stephen William Russell, Ronaldus Theodorus Vliet, Jane Whittaker
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Patent number: 6148644Abstract: A system for dry cleaning soils from fabrics comprising densified carbon dioxide and a surfactant in the densified CO.sub.2. The densified carbon dioxide is in a temperature range of about -78.5.degree. C. to about 100.degree. C. and a pressure range of about 14.7 to about 10,000 psi. At least 0.1% by volume of a modifier is preferably present. The surfactant has a polysiloxane, a branched polyalkylene oxide or a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.Type: GrantFiled: May 19, 1998Date of Patent: November 21, 2000Assignee: Lever Brothers Company, division of Conopco, Inc.Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Dennis Stephen Murphy
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Patent number: 6147043Abstract: In machine dishwashing using low-alkaline detergents, the protection of silver was to be guaranteed. This was achieved by using 3-amino-5-alkyl-1,2,4-triazoles and salts thereof as silver protectors in machine dishwashing detergents. In addition, the dishwashing detergents may contain bleaching agents and builders.Type: GrantFiled: January 15, 1998Date of Patent: November 14, 2000Assignee: Henkel Kommanditgesellschaft Auf AktienInventors: Hinrich Moeller, Helmut Blum, Christian Nitsch, Juergen Haerer
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Patent number: 6133216Abstract: The invention relates to coated bleach activator granules of ammonium nitriles, which have been obtained by coating ammonium nitrile base granules with a water-soluble coating substance. The base granules are preferably thermally conditioned during or after the coating with the coating substance.Type: GrantFiled: September 15, 1998Date of Patent: October 17, 2000Assignee: Clariant GmbHInventors: Matthias Loffler, Gerd Reinhardt
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Patent number: 6130198Abstract: Use of amines as bleaching efficiency boosters for textile detergent compositions, where the pK.sub.a of the amines is greater than the pH minus 1, preferably greater than the pH, particularly preferably at least 0.5 greater than the pH of the 1% by weight wash liquor obtained from the textile detergent composition.Type: GrantFiled: September 28, 1998Date of Patent: October 10, 2000Assignee: BASF AktiengesellschaftInventors: Thomas Wehlage, Dieter Boeckh, Werner Bertleff, Alfred Oftring
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Patent number: 6127331Abstract: The present invention relates to laundry detergent compositions which comprise an alkoxylated polyalkyleneimine soil dispersant having the formula: ##STR1## wherein R is C.sub.2 -C.sub.6 linear alkylene, C.sub.3 -C.sub.6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:--(R.sup.1 O).sub.m (R.sup.2 O).sub.n R.sup.3wherein R.sup.1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R.sup.2 is ethylene; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x, and y are each independently from about 4 to about 200; provided at least one --(R.sup.1 O) unit is attached to the backbone prior to attachment of an --(R.sup.2 O) unit and further provided m+n is at least 12, said dispersants are compatible with bleach. The disclosed alkoxylated polyalkyleneimines are also suitable for use as soil dispersant in bleach-containing laundry pre-soaks and bleaching agents.Type: GrantFiled: June 23, 1998Date of Patent: October 3, 2000Assignee: The Procter & Gamble CompanyInventors: James Albert Cleary, Shulin Zhang, Eugene Paul Gosselink
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Patent number: 6121219Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.Type: GrantFiled: August 10, 1999Date of Patent: September 19, 2000Assignee: Ecolab Inc.Inventors: Brandon L. Herdt, David A. Halsrud
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Patent number: 6114295Abstract: A system for dry cleaning soils from fabrics is described which contains densified carbon dioxide combined with a selected surfactant. The densified carbon dioxide is used in a temperature range of about -78.5.degree. C. to about 100.degree. C. and a pressure range of about 14.7 psi to about 10,000 psi. The surfactant is selected from one of two groups of compounds having a formula ##STR1## as described in the text or a second group of siloxane compounds having a formula [AB].sub.y as described. A process for using the dry cleaning system is also described.Type: GrantFiled: September 2, 1999Date of Patent: September 5, 2000Assignee: Lever Brothers CompanyInventor: Dennis Stephen Murphy
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Patent number: 6071871Abstract: Cotton soil release polymers comprising water soluble and/or dispersible, modified polyamines having functionalized backbone moieties and improved stability toward bleach. Also, laundry detergent compositions comprising these cotton soil release polymers having enhanced hydrophilic soil removal benefits.Type: GrantFiled: July 16, 1999Date of Patent: June 6, 2000Assignee: The Procter & Gamble CompanyInventors: Eugene Paul Gosselink, Kenneth Nathan Price
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Patent number: 6063135Abstract: The present invention comprises a dry cleaning system and method, in which dry cleaning machinery is used in conjunction with a specific solvent which is derived from an organic/inorganic hybrid (organo silicone). Such solvent is used in combination with an organic and/or organo-silicone-based detergent which is specifically tailored for working in conjunction with the solvent to afford optimal cleaning. In a preferred embodiment, the method comprises the steps of loading articles into a cleaning basket; agitating the articles in the solvent and detergent composition in which they are immersed; removing most of the solvent and detergent composition; centrifuging the articles; heating the articles and remaining composition and creating vapors, condensing vapors and optionally reducing the pressure to dry the articles, recovering and recycling solvent and removing the articles from the basket after cooling the articles.Type: GrantFiled: May 3, 1999Date of Patent: May 16, 2000Assignee: GreenEarth Cleaning LLCInventors: Dieter R. Berndt, John McLeod Griffiss
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Patent number: 6040284Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, this invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.Type: GrantFiled: May 22, 1998Date of Patent: March 21, 2000Assignee: Huntsman Petrochemical CorporationInventors: Edward T. Marquis, Robert E. Baldwin
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Patent number: 6008175Abstract: A method of cleaning carpets with a composition comprising a surfactant selected from amine oxides and acyl sarcosinates. The compositions are advantageous in that they do not leave a dulling film if not removed from the carpet after drying. Preferably, the compositions also contain a source of active oxygen for stain removal.Type: GrantFiled: September 4, 1998Date of Patent: December 28, 1999Assignee: The Proctor & Gamble CompanyInventors: Stefano Scialla, Floriana Raso, Lorena Silvaggi
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Patent number: 5977045Abstract: A system for dry cleaning soils from fabrics is described which contains densified carbon dioxide combined with a selected surfactant. The densified carbon dioxide is used in a temperature range of about -78.5.degree. C. to about 100.degree. C. and a pressure range of about 14.7 psi to about 10,000 psi. The surfactant is selected from one of two groups of compounds having a formula ##STR1## as described in the text or a second group of siloxane compounds having a formula [AB].sub.y as described. A process for using the dry cleaning system is also described.Type: GrantFiled: May 6, 1998Date of Patent: November 2, 1999Assignee: Lever Brothers CompanyInventor: Dennis Stephen Murphy
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Patent number: 5962390Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.Type: GrantFiled: May 17, 1996Date of Patent: October 5, 1999Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard M. Flynn, Mark W. Grenfell, George G. I. Moore, John G. Owens, Dean S. Milbrath
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Patent number: 5883067Abstract: A soil release agent for dry cleaning containing a copolymer having (A) a repeating unit derived from a polymerizable monomer having a fluorine atom; and (B) a repeating unit derived from a polymerizable monomer having a siloxane linkage and/or a polymerizable monomer (having no siloxane linkage) having a solubility parameter of 6 to 15 gives excellent soil release property using the dry cleaning.Type: GrantFiled: September 27, 1996Date of Patent: March 16, 1999Assignee: Daikin Industries, Ltd.Inventors: Motonobu Kubo, Takashi Enomoto
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Patent number: 5798329Abstract: Liquid laundry detergent compositions provide good detergency for the cleaning of garments and textiles, as well as further providing a germicidal action to textile fabrics in a domestic laundering process.Type: GrantFiled: June 20, 1996Date of Patent: August 25, 1998Assignee: Reckitt & Colman Inc.Inventors: Timothy J. Taylor, Alan F. Richter
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Patent number: 5683977Abstract: A system for dry cleaning soils from fabrics comprising densified carbon dioxide and a surfactant in the densified CO.sub.2. The surfactant has a polysiloxane, a branched polyalkylene oxide and a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.Type: GrantFiled: March 6, 1995Date of Patent: November 4, 1997Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Myongsuk Bae-Lee, Lisa Del Pizzo, Rosemarie Harris, Carol Resch, Cathy Wada
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Patent number: 5676705Abstract: A method of dry cleaning fabrics using a dry cleaning system is described. The system comprises densified carbon dioxide and a surfactant in the densified CO.sub.2. The surfactant has a polysiloxane, a branched polyalkylene oxide and a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.Type: GrantFiled: March 6, 1995Date of Patent: October 14, 1997Assignee: Lever Brothers Company, Division of Conopco, Inc.Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Myongsuk Bae-Lee, Lisa Del Pizzo, Rosemarie Harris, Carol Resch, Cathy Wada
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Patent number: 5584888Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising particular neutral or anionically charged substituted bleach activators are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits through the selection of perhydrolysis-selective bleach activators having specific leaving groups with a conjugate acid pK.sub.a above 13 and with specific ratios of the rate of perhydrolysis to the rate of hydrolysis and the rate of perhydrolysis to the rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.Type: GrantFiled: August 31, 1994Date of Patent: December 17, 1996Inventors: Gregory S. Miracle, Alan D. Willey, Kevin L. Kott, Michael E. Burns