With Halogen, Oxygen, Or Nitrogen Containing Chemical Bleach, Oxidant, Antiseptic, Or Biocidal Component Patents (Class 510/286)
  • Patent number: 6642196
    Abstract: There is provided a method of delivering a benefit agent whereby a benefit agent is first loaded to a surface and subsequently unloaded and transferred and delivered to a second surface. More in particular, the benefit agent is first loaded onto a garment during a laundering process, and subsequently delivered to another surface. The benefit agents can be fragrance agents, perfumes, colour enhancers, fabric softening agents, polymeric lubricants, photoprotective agents, latexes, resins, dye fixative agents, encapsulated materials, antioxidants, insecticides, soil repelling agents, soil release agents, and cellulose fibers.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: November 4, 2003
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Steven Howell, Julie Little, Cornelis Paul Van Der Logt, Neil James Parry
  • Patent number: 6605580
    Abstract: A bleaching composition is provided comprising a) a bleach-effective amount of an inorganic bleaching agent; b) a bleach-compatible solvent c) 0 to 10 wt % of a surfactant; d) less than 10 wt % of a modifier; and e) an effective dry cleaning amount of densified carbon dioxide, said composition being essentially free of organic peracid or precursor thereof.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: August 12, 2003
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes Jacob Verhagen, Pieter van der Vlist
  • Patent number: 6586380
    Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, this invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: July 1, 2003
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Edward T. Marquis, Robert E. Baldwin
  • Patent number: 6586384
    Abstract: A method of delivering a benefit agent to a selected area of a fabric for exerting a predetermined activity, wherein the area is pre-treated with a multi-specific binding molecule which has a high binding affinity to said area through one specificity and is capable of binding to said benefit agent through another specificity, followed by contacting said pre-treated area with said benefit agent, to enhance said pre-determined activity to said area. Preferably, the binding molecule is an antibody or fragment thereof, or a fusion protein comprising a cellulose binding domain and a domain having a high binding affinity to another ligand which is directed to said benefit agent. The method is useful for stain removal, perfume delivery, and treating collars and cuffs for wear.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: July 1, 2003
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Sandra Hemmington, Steven Howell, Julie Little, Cornelis Paul Van Der Logt, Neil James Parry, Richard George Smith
  • Patent number: 6579842
    Abstract: A method of delivering a benefit agent to fabric for exerting a pre-determined activity, wherein the fabric is pre-treated with a multi-specific binding molecule which has a high binding affinity to the fabric through one specificity and is capable of binding to the benefit agent through another specificity, followed by contacting the pre-treated fabric with the benefit agent, to enhance the pre-determined activity to the fabric. Preferably, the binding molecule is an antibody or fragment thereof, or a fusion protein comprising a cellulose binding domain and a domain having a high binding affinity to another ligand which is directed to said benefit agent. The method is useful for example for stain removal, perfume delivery, and treating collars and cuffs for wear.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: June 17, 2003
    Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.
    Inventors: Steven Howell, Julie Little, Cornelis Paul Van Der Logt, Neil James Parry
  • Patent number: 6562774
    Abstract: A bleaching composition is provided comprising a) a bleach-effective amount of a low-active oxygen bleaching agent; b) a bleach-compatible solvent c) 0 to 10 wt % of a surfactant; d) less than 10 wt % of a modifier; and e) an effective dry cleaning amount of densified carbon dioxide, said composition being essentially free of carbon dioxide soluble organic peracid.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: May 13, 2003
    Assignee: Unilever Home & Personal Case USA, division of Conopco, Inc.
    Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes Jacob Verhagen, Pieter Van Der Vlist
  • Publication number: 20030074742
    Abstract: A dry cleaning composition comprising a volatile siloxane and a mixture of different classes of organic surfactants and, optionally water, and a method for dry cleaning comprising contacting an article with a composition comprising a volatile siloxane and a mixture of different classes of organic surfactants.
    Type: Application
    Filed: May 24, 2002
    Publication date: April 24, 2003
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Robert J. Perry, Donna Ann Riccio, Larry D. Ryan, John A. Kilgour
  • Patent number: 6495502
    Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide, preferably held at 25° C. or less.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: December 17, 2002
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
  • Publication number: 20020184715
    Abstract: An improved dry cleaning apparatus and method for the non-aqueous cleaning of fabric materials comprises the introduction of steam into a dryer chamber containing fabric materials previously washed in a non-aqueous organic cleaning solvent such as perchloroethylene. The steam is heated at a sufficient temperature for a duration of time, both of which are determined by the type of fabric and solvents involved. The heated steam volatilizes any excess cleaning solvent contained in or on said fabric creating a gaseous water/solvent mixture which is then subsequently separated from the fabric materials. The gaseous mixture can be condensed, its component parts separated and re-used in the cycle again.
    Type: Application
    Filed: June 6, 2001
    Publication date: December 12, 2002
    Inventor: Robert E. Taylor
  • Patent number: 6482786
    Abstract: The present invention relates to a liquid bleaching composition comprising a peroxygen bleach, a zwitterionic betaine surfactant, a sulphonated hydrotrope, and a nonionic surfactant. This composition is suitable to deliver excellent stain removal performance and bleaching performance on various surfaces including fabrics and hard-surfaces, with improved physical stability, especially at low temperatures.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: November 19, 2002
    Assignee: The Procter & Gamble Company
    Inventors: Valerio Del Duca, Stefano Giunti, Nobuo Ishida
  • Patent number: 6479447
    Abstract: A bleaching composition is provided for effective bleaching with a bleach catalyst at low temperatures. The bleaching composition comprises of a) from 0.05 microM to 50 mM of an organic substance which forms a complex with a transition metal; b) a source of active oxygen corresponding to 0.05 to 100 mM of active oxygen; and c) an effective amount of liquid carbon dioxide.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: November 12, 2002
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Dirk Johannes Bijl, Ronald Hage, Jan Kevelam, Jean Hypolites Koek, Dennis Stephen Murphy, Irene Erica Smit, Johannes J. Verhagen, Pieter van der Vlist
  • Patent number: 6475246
    Abstract: An additive for introduction into a dry cleaning solvent, and a method of use thereof, which reduces static electricity, minimizes linting, fights acidity to reduce corrosion, deodorizes the solvent, and does not adversely affect the filtering operation. The additive contains sodium bicarbonate and an anti-static agent; preferably in the presence of an odorant.
    Type: Grant
    Filed: May 22, 2000
    Date of Patent: November 5, 2002
    Assignee: Pariser Industries
    Inventors: Albert A. Pariser, Joel Speer
  • Patent number: 6465409
    Abstract: The invention concerns an aqueous biocide system comprising: at least one water-soluble or water-dispersible biocidal agent, and at least a polyorganosiloxane with water-soluble or water-dispersible functions. The invention also concerns the use of the system for disinfecting hard surfaces, or a method for disinfecting hard surfaces using the system, with controlled release of the biocide when contacted with an aqueous medium of a hard surface whereon the aqueous medium has been deposited and dried.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: October 15, 2002
    Assignee: Rhodia Chimie
    Inventors: John Frederic Carr, GĂ©rard Mignani, Louis Vovelle, Brian Davis, Caroll Vergelati
  • Publication number: 20020133885
    Abstract: An process for treating or cleaning fabric articles, especially articles of clothing, linen and drapery, wherein the method comprises contacting the fabric articles to be cleaned or treated with a cleaning fluid comprising a lipophilic fluid and removing from the fabric articles a portion of the cleaning fluid.
    Type: Application
    Filed: May 4, 2001
    Publication date: September 26, 2002
    Applicant: The Procter & Gamble Company
    Inventors: Anna Vadimovna Noyes, John Cort Severns, Frederick Anthony Hartman, James Charles Theophile Roger Burckett-St. Laurent, Arseni V. Radomyselski, Paul Amaat France, Jeffrey John Scheibel, Christiaan Arthur Jacques Kamiel Thoen, John Christopher Deak, Phillip Kyle Vinson, Nabil Yaqub Sakkab
  • Patent number: 6451746
    Abstract: An effervescent compound is disclosed which includes a liquid ingredient, an effervescent system and optionally a solvent. The solvent may be both hydrophilic and have low solubility with effervescent ingredients. The solvent may include an alcohol, a glycol or a glycol ether, for example, but not limited to, 2-butoxyethanol. The effervescent system used in the effervescent compound may be, for example, but is not limited to, expanded sodium perborate and/or a mixture of any or one or more of sodium bicarbonate, sodium carbonate, potassium bicarbonate and potassium carbonate. The effervescent compound may further include any one, or all, or any combination of the following ingredients: surfactants, bleaching compositions, anti-redeposition agents, binders, lubricants, colors, fragrances, and/or optical brighteners.
    Type: Grant
    Filed: March 21, 2001
    Date of Patent: September 17, 2002
    Assignee: ChemLink Laboratories, LLC
    Inventors: Ryan Giffin Moore, Hilton G. Dawson, Richard A. DeSenna, Kenneth Scott Wiley
  • Patent number: 6413929
    Abstract: Use of amines as bleaching efficiency boosters for textile detergent compositions, where the pKa of the amines is greater than the pH minus 1, preferably greater than the pH, particularly preferably at least 0.5 greater than the pH of the 1% by weight wash liquor obtained from the textile detergent composition.
    Type: Grant
    Filed: July 19, 2000
    Date of Patent: July 2, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Wehlage, Dieter Boeckh, Werner Bertleff, Alfred Oftring
  • Patent number: 6410497
    Abstract: Inorganic per compounds may be activated with oxime carbonates of the formula (I), A—O—CO—OR3, a hydroximide ester of formula (II): or polymeric hydroximide esters.
    Type: Grant
    Filed: August 4, 1999
    Date of Patent: June 25, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Elisabeth Kappes, Thomas Wehlage, Alfred Oftring, Dieter Boeckh
  • Patent number: 6407045
    Abstract: The invention set out to improve the oxidizing and bleaching effect of inorganic peroxygen compounds in dishwashing, more particularly machine dishwashing, in terms of their storage stability. This was essentially achieved by using particulate compounds corresponding to formula R1R2R3N−CH2CN X+, in which R1, R2, and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, in addition to which the groups R2 and R3 may even be part of a heterocycle including the N atom and optionally other hetero atoms, and X is a charge-equalizing anion. Dishwashing detergents, more particularly machine dishwashing detergents, contain about 1% by weight to 10% by weight of this bleach-boosting agent.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: June 18, 2002
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Christian Nitsch, Horst-Dieter Speckmann, Juergen Haerer, Andreas Lietzmann, Susan P. Huestis
  • Patent number: 6391838
    Abstract: The cleaning performance of bleach-containing detergents, especially against protein- and starch-containing soils and colored soils, was to be improved.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: May 21, 2002
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Horst-Dieter Speckmann, Joerg Poethkow
  • Patent number: 6376452
    Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: April 23, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Richard M. Flynn, Mark W. Grenfell, George G. I. Moore, John G. Owens, Dean S. Milbrath
  • Patent number: 6372703
    Abstract: A liquid non-aqueous detergent is presented containing a nonionic surfactant, a builder, a bleaching agent, and a cationic stabilizer of formula I, II or III: where the groups R1 independently of one another are C1-6 alkyl, alkenyl or hydroxyalkyl groups, the groups R2 independently of one another are C8-28 alkyl or alkenyl groups, R3 has the same meaning as R1 or represents (CH2)n—T—R2, R4 has the same meaning as R1 or R2 or represents (CH2)n—T—R2, T represents —CH2—, —O—CO— or —CO—O— and n is an integer of from 0 to 5. The solid bleaching agents in the stabilized non-aqueous liquid detergent retain their activity after prolonged storage.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: April 16, 2002
    Assignee: Henkel Komanditgesellschaft auf Aktien
    Inventors: Bernd Richter, Ulrich Pegelow
  • Patent number: 6297206
    Abstract: A method for dry-cleaning garments or fabrics in carbon dioxide comprises contacting a garment or fabric article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the article, said liquid dry-cleaning composition comprising a mixture of carbon dioxide, water, a first surfactant, and a second surfactant, and then separating the article from the liquid dry cleaning composition. The first surfactant comprises a CO2-philic group covalently joined to a hydrophilic group; and the second surfactant comprising a CO2-philic group covalently joined to a lipophilic group. In the alternative, a single surfactant containing all three of a CO2-philic group, a lipophilic group, and a hydrophilic group covalently joined to one another may also be employed. Systems useful for carrying out the foregoing are also disclosed.
    Type: Grant
    Filed: January 23, 2001
    Date of Patent: October 2, 2001
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, James P. DeYoung
  • Patent number: 6239096
    Abstract: A powdered abrasive cleanser that exhibits superior soil removal properties and surface safety is provided. The cleanser includes a surfactant, an optional source of active chlorine, a borax pentahydrate compound that is preferably sodium tetraborate pentahydrate, and optionally an alkaline detergent builder and/or calcium carbonate.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: May 29, 2001
    Assignee: The Clorox Company
    Inventors: Robert L. Blum, Denise A. Garner, Carl M. Kling
  • Patent number: 6239090
    Abstract: A thickened composition and process useful for removing paint, comprising: a carbonate such as propylene carbonate or ethylene carbonate, a thickener such as polyvinyl pyrrolidone (PVP), hydrogen peroxide and water. The composition may include additional cosolvents such as glycol ethers and alcohols such as benzyl alcohol, and/or dibasic ester (DBE).
    Type: Grant
    Filed: December 10, 1999
    Date of Patent: May 29, 2001
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Edward T. Marquis, Robert E. Baldwin, James R. Machac, Jr., Katty Darragas, Susan Aileen Woodrum
  • Publication number: 20010001479
    Abstract: The invention relates to an improved hide-curing additive comprising an effective biocidal amount of an essential oil and a non-ionic surfactant. The improved additive provides an effective cure for the hides, is environmentally safe and economical.
    Type: Application
    Filed: September 23, 1998
    Publication date: May 24, 2001
    Applicant: Dana J. Johnson
    Inventors: DANA J. JOHNSON, TERRY L. MCANINCH, FREDERICK W. HOLZHAUER
  • Patent number: 6235701
    Abstract: A stable fluid comprising compressed fluid carbon dioxide, an inert gas and a fluorochemical stabilizer is disclosed. The fluid composition is useful in cleaning of metals, glass, ceramics, natural and synthetic polymers, and fabrics and in the extraction of desirables substances, such as the extraction of essential oils from plants.
    Type: Grant
    Filed: April 26, 1999
    Date of Patent: May 22, 2001
    Assignee: 3M Innovative Properties Company
    Inventor: Cheryl L. Senger Elsbernd
  • Patent number: 6225274
    Abstract: A method for washing dishes containing colored soil is presented involving contacting the dish surface with a dishwashing detergent containing a peroxygen compound and an activator compound of the formula R1R2R3N+CH2CN X− where R1, R2 and R3 independently of one another represent an alkyl, alkenyl or aryl group containing 1 to 18 carbon atoms, and wherein R2 and R3 may be part of a heterocycle including the N atom, and X is an anion, to form an aqueous dishwashing detergent. The method is useful for washing colored stains from crockery and cutlery, and is effective at temperatures below 80° C.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: May 1, 2001
    Assignee: Henkel Kommandigesellschaft auf Aktien
    Inventors: Christian Nitsch, Rainer Jeschke
  • Patent number: 6214782
    Abstract: Detergent formulations containing cationic nitriles are shown to exhibit reduced silver tarnishing as compared to similar formulations containing TAED.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: April 10, 2001
    Assignee: Unilever Home & Personal Care, USA, division of Conopco, Inc.
    Inventors: Catherine Chiou, Narish Dhirajlal Ghatlia
  • Patent number: 6200943
    Abstract: A method for dry-cleaning garments or fabrics in carbon dioxide comprises contacting a garment or fabric article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the article, said liquid dry-cleaning composition comprising a mixture of carbon dioxide, water, a first surfactant, and a second surfactant, and then separating the article from the liquid dry cleaning composition. The first surfactant comprises a CO2-philic group covalently joined to a hydrophilic group; and the second surfactant comprising a CO2-philic group covalently joined to a lipophilic group. In the alternative, a single surfactant containing all three of a CO2-philic group, a lipophilic group, and a hydrophilic group covalently joined to one another may also be employed. Systems useful for carrying out the foregoing are also disclosed.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: March 13, 2001
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, James P. DeYoung
  • Patent number: 6187738
    Abstract: There is provided an aqueous composition for cleaning fabrics and carpets and inhibiting the resoiling of fabric and carpets. The composition includes a peroxygen compound, a surfactant system, and a polymeric or copolymeric soil resist. The resulting compositions are particularly stable and non-turbid.
    Type: Grant
    Filed: February 2, 1999
    Date of Patent: February 13, 2001
    Assignee: Playtex Products, Inc.
    Inventors: Robert P. Micciche, Ann Marie Lynch, Uma Tripathi, Carol Belansky
  • Patent number: 6165963
    Abstract: A detergent bleaching composition is provided comprising a compound inclug a specified pentadentate nitrogen-containing ligand. The compound can activate hydrogen peroxide or peroxyacids and provides favourable stain removal properties, particularly in the presence or iron, manganese or copper ions. In addition, an improved stability in alkaline aqueous environment has been obtained, in particular at the peroxy compound concentrations generally present in the fabric washing liquor.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: December 26, 2000
    Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.
    Inventors: Michel Gilbert Delroisse, Bernard Lucas Feringa, Ronald Hage, Roelant Mathijs Hermant, Robertus Everardus Kalmeijer, Jean Hypolites Koek, Christiaan Lamers, Minze Theunis Rispens, Stephen William Russell, Ronaldus Theodorus Vliet, Jane Whittaker
  • Patent number: 6148644
    Abstract: A system for dry cleaning soils from fabrics comprising densified carbon dioxide and a surfactant in the densified CO.sub.2. The densified carbon dioxide is in a temperature range of about -78.5.degree. C. to about 100.degree. C. and a pressure range of about 14.7 to about 10,000 psi. At least 0.1% by volume of a modifier is preferably present. The surfactant has a polysiloxane, a branched polyalkylene oxide or a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: November 21, 2000
    Assignee: Lever Brothers Company, division of Conopco, Inc.
    Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Dennis Stephen Murphy
  • Patent number: 6147043
    Abstract: In machine dishwashing using low-alkaline detergents, the protection of silver was to be guaranteed. This was achieved by using 3-amino-5-alkyl-1,2,4-triazoles and salts thereof as silver protectors in machine dishwashing detergents. In addition, the dishwashing detergents may contain bleaching agents and builders.
    Type: Grant
    Filed: January 15, 1998
    Date of Patent: November 14, 2000
    Assignee: Henkel Kommanditgesellschaft Auf Aktien
    Inventors: Hinrich Moeller, Helmut Blum, Christian Nitsch, Juergen Haerer
  • Patent number: 6133216
    Abstract: The invention relates to coated bleach activator granules of ammonium nitriles, which have been obtained by coating ammonium nitrile base granules with a water-soluble coating substance. The base granules are preferably thermally conditioned during or after the coating with the coating substance.
    Type: Grant
    Filed: September 15, 1998
    Date of Patent: October 17, 2000
    Assignee: Clariant GmbH
    Inventors: Matthias Loffler, Gerd Reinhardt
  • Patent number: 6130198
    Abstract: Use of amines as bleaching efficiency boosters for textile detergent compositions, where the pK.sub.a of the amines is greater than the pH minus 1, preferably greater than the pH, particularly preferably at least 0.5 greater than the pH of the 1% by weight wash liquor obtained from the textile detergent composition.
    Type: Grant
    Filed: September 28, 1998
    Date of Patent: October 10, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Wehlage, Dieter Boeckh, Werner Bertleff, Alfred Oftring
  • Patent number: 6127331
    Abstract: The present invention relates to laundry detergent compositions which comprise an alkoxylated polyalkyleneimine soil dispersant having the formula: ##STR1## wherein R is C.sub.2 -C.sub.6 linear alkylene, C.sub.3 -C.sub.6 branched alkylene, and mixtures thereof; B is a continuation by branching; E is an alkyleneoxy unit having the formula:--(R.sup.1 O).sub.m (R.sup.2 O).sub.n R.sup.3wherein R.sup.1 is 1,2-propylene, 1,2-butylene, and mixtures thereof; R.sup.2 is ethylene; R.sup.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, and mixtures thereof; m is from about 1 to about 10; n is from about 10 to about 40; w, x, and y are each independently from about 4 to about 200; provided at least one --(R.sup.1 O) unit is attached to the backbone prior to attachment of an --(R.sup.2 O) unit and further provided m+n is at least 12, said dispersants are compatible with bleach. The disclosed alkoxylated polyalkyleneimines are also suitable for use as soil dispersant in bleach-containing laundry pre-soaks and bleaching agents.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: October 3, 2000
    Assignee: The Procter & Gamble Company
    Inventors: James Albert Cleary, Shulin Zhang, Eugene Paul Gosselink
  • Patent number: 6121219
    Abstract: The invention relates to compositions and methods for cleaning typically organic beverage and food soils. The cleaning composition is formulated to remove carbohydrate and proteinaceous soils from hard surfaces. The formulations of the invention are directed to remove carbohydrate and proteinaceous soils from beverage manufacturing locations such as soils arising in the manufacture of malt beverages, fruit juices, dairy products, etc.
    Type: Grant
    Filed: August 10, 1999
    Date of Patent: September 19, 2000
    Assignee: Ecolab Inc.
    Inventors: Brandon L. Herdt, David A. Halsrud
  • Patent number: 6114295
    Abstract: A system for dry cleaning soils from fabrics is described which contains densified carbon dioxide combined with a selected surfactant. The densified carbon dioxide is used in a temperature range of about -78.5.degree. C. to about 100.degree. C. and a pressure range of about 14.7 psi to about 10,000 psi. The surfactant is selected from one of two groups of compounds having a formula ##STR1## as described in the text or a second group of siloxane compounds having a formula [AB].sub.y as described. A process for using the dry cleaning system is also described.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: September 5, 2000
    Assignee: Lever Brothers Company
    Inventor: Dennis Stephen Murphy
  • Patent number: 6071871
    Abstract: Cotton soil release polymers comprising water soluble and/or dispersible, modified polyamines having functionalized backbone moieties and improved stability toward bleach. Also, laundry detergent compositions comprising these cotton soil release polymers having enhanced hydrophilic soil removal benefits.
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: June 6, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Eugene Paul Gosselink, Kenneth Nathan Price
  • Patent number: 6063135
    Abstract: The present invention comprises a dry cleaning system and method, in which dry cleaning machinery is used in conjunction with a specific solvent which is derived from an organic/inorganic hybrid (organo silicone). Such solvent is used in combination with an organic and/or organo-silicone-based detergent which is specifically tailored for working in conjunction with the solvent to afford optimal cleaning. In a preferred embodiment, the method comprises the steps of loading articles into a cleaning basket; agitating the articles in the solvent and detergent composition in which they are immersed; removing most of the solvent and detergent composition; centrifuging the articles; heating the articles and remaining composition and creating vapors, condensing vapors and optionally reducing the pressure to dry the articles, recovering and recycling solvent and removing the articles from the basket after cooling the articles.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: May 16, 2000
    Assignee: GreenEarth Cleaning LLC
    Inventors: Dieter R. Berndt, John McLeod Griffiss
  • Patent number: 6040284
    Abstract: This invention concerns a composition useful as a paint remover, comprising: alkylene carbonate such as propylene carbonate or ethylene carbonate, hydrogen peroxide, and water, and optionally an alcohol such as benzyl alcohol. In another broad respect, this invention concerns a process for removing paint, comprising: applying a composition containing alkylene carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint. In another broad respect, this invention is a composition useful as a paint remover, comprising: dialkyl carbonate, hydrogen peroxide, and water, optionally containing an alcohol, optionally containing a glycol ether. In another broad respect, this invention is a process for removing paint, comprising: applying a composition containing dialkyl carbonate, hydrogen peroxide, and water to a painted surface for a time and under conditions effective to cause blistering or bubbling of the paint.
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: March 21, 2000
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Edward T. Marquis, Robert E. Baldwin
  • Patent number: 6008175
    Abstract: A method of cleaning carpets with a composition comprising a surfactant selected from amine oxides and acyl sarcosinates. The compositions are advantageous in that they do not leave a dulling film if not removed from the carpet after drying. Preferably, the compositions also contain a source of active oxygen for stain removal.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: December 28, 1999
    Assignee: The Proctor & Gamble Company
    Inventors: Stefano Scialla, Floriana Raso, Lorena Silvaggi
  • Patent number: 5977045
    Abstract: A system for dry cleaning soils from fabrics is described which contains densified carbon dioxide combined with a selected surfactant. The densified carbon dioxide is used in a temperature range of about -78.5.degree. C. to about 100.degree. C. and a pressure range of about 14.7 psi to about 10,000 psi. The surfactant is selected from one of two groups of compounds having a formula ##STR1## as described in the text or a second group of siloxane compounds having a formula [AB].sub.y as described. A process for using the dry cleaning system is also described.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: November 2, 1999
    Assignee: Lever Brothers Company
    Inventor: Dennis Stephen Murphy
  • Patent number: 5962390
    Abstract: A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: October 5, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard M. Flynn, Mark W. Grenfell, George G. I. Moore, John G. Owens, Dean S. Milbrath
  • Patent number: 5883067
    Abstract: A soil release agent for dry cleaning containing a copolymer having (A) a repeating unit derived from a polymerizable monomer having a fluorine atom; and (B) a repeating unit derived from a polymerizable monomer having a siloxane linkage and/or a polymerizable monomer (having no siloxane linkage) having a solubility parameter of 6 to 15 gives excellent soil release property using the dry cleaning.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: March 16, 1999
    Assignee: Daikin Industries, Ltd.
    Inventors: Motonobu Kubo, Takashi Enomoto
  • Patent number: 5798329
    Abstract: Liquid laundry detergent compositions provide good detergency for the cleaning of garments and textiles, as well as further providing a germicidal action to textile fabrics in a domestic laundering process.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: August 25, 1998
    Assignee: Reckitt & Colman Inc.
    Inventors: Timothy J. Taylor, Alan F. Richter
  • Patent number: 5683977
    Abstract: A system for dry cleaning soils from fabrics comprising densified carbon dioxide and a surfactant in the densified CO.sub.2. The surfactant has a polysiloxane, a branched polyalkylene oxide and a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: November 4, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Myongsuk Bae-Lee, Lisa Del Pizzo, Rosemarie Harris, Carol Resch, Cathy Wada
  • Patent number: 5676705
    Abstract: A method of dry cleaning fabrics using a dry cleaning system is described. The system comprises densified carbon dioxide and a surfactant in the densified CO.sub.2. The surfactant has a polysiloxane, a branched polyalkylene oxide and a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: October 14, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Myongsuk Bae-Lee, Lisa Del Pizzo, Rosemarie Harris, Carol Resch, Cathy Wada
  • Patent number: 5584888
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising particular neutral or anionically charged substituted bleach activators are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits through the selection of perhydrolysis-selective bleach activators having specific leaving groups with a conjugate acid pK.sub.a above 13 and with specific ratios of the rate of perhydrolysis to the rate of hydrolysis and the rate of perhydrolysis to the rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: December 17, 1996
    Inventors: Gregory S. Miracle, Alan D. Willey, Kevin L. Kott, Michael E. Burns