Sulfur-containing Anionically Substituted Surfactant Patents (Class 510/290)
  • Patent number: 6258766
    Abstract: A method for dry-cleaning articles such as fabrics and clothing in carbon dioxide comprises contacting an article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the fabric. The liquid dry-cleaning composition comprises a mixture of carbon dioxide, a surfactant, and an organic co-solvent. After the contacting step, the article is separated from the liquid dry cleaning composition. The method is preferably carried out at ambient temperature. The surfactant is preferably one that does not contain a CO2-philic group. The organic co-solvent is preferably an alkane and has a flash point above 140° F.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: July 10, 2001
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, David F. Cauble, James B. McClain
  • Patent number: 6218353
    Abstract: A liquid composition useful for suspending and dispensing a solid particulate comprises carbon dioxide, a surfactant, an organic co-solvent, and the solid particulate to be suspended. The composition may optionally contain water. The composition is useful as a propellant in an aerosol container for spraying the solid particulate from the container.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: April 17, 2001
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, David F. Cauble, Jr., James B. McClain
  • Patent number: 6211141
    Abstract: A high-density powdered detergent composition which has a bulk density of 0.6 to 1.2 g/ml and which comprises 0.5 to 30% by weight of (a) a glycine-N,N-diacetic acid derivative, 5 to 45% by weight of (b) a nonionic surfactant having an HLB value of 10.5 to 15.0, 0.5 to 18% by weight of (c) an anionic surfactant and 1 to 30% by weight of (d) an aluminosilicate, each percentage being based on the total weight of the composition, and the weight ratio of the component (b) to the component (c) lying between 90:1 and 60:40. This composition contains both a glycine-N,N-diacetic acid derivative which is a builder excellent in biodegradability and sequestering power and an inorganic builder such as zeolite or crystalline silicate, and exhibits high detergency.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: April 3, 2001
    Assignee: Kao Corporation
    Inventors: Shu Yamaguchi, Hiromitsu Hayashi, Masaki Tsumadori, Masaaki Yamamura, Noboru Moriyama
  • Patent number: 6207633
    Abstract: A granular detergent composition which includes a surfactant system containing linear alkylbenzene sulfonate, acyclic quaternary ammonium salt, alkyl sulfate and alkyl ethoxy sulfate surfactants in selected molar ratios is provided. The composition has improved performance in cold temperature (i.e., 5° C. to 30° C.) laundering operations.
    Type: Grant
    Filed: December 16, 1999
    Date of Patent: March 27, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Darla Bonar Kettenacker, Eugene Joseph Pancheri, Jacqueline Westfield, Rose Marie Weitzel
  • Patent number: 6200352
    Abstract: A method for dry-cleaning articles such as fabrics and clothing in carbon dioxide comprises contacting an article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the fabric. The liquid dry-cleaning composition comprises a mixture of carbon dioxide, a surfactant, and an organic co-solvent. After the contacting step, the article is separated from the liquid dry cleaning composition. The method is preferably carried out at ambient temperature. The surfactant is preferably one that does not contain a CO2-philic group. The organic co-solvent is preferably an alkane and has a flash point above 140° F.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: March 13, 2001
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, David F. Cauble, James B. McClain
  • Patent number: 6200943
    Abstract: A method for dry-cleaning garments or fabrics in carbon dioxide comprises contacting a garment or fabric article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the article, said liquid dry-cleaning composition comprising a mixture of carbon dioxide, water, a first surfactant, and a second surfactant, and then separating the article from the liquid dry cleaning composition. The first surfactant comprises a CO2-philic group covalently joined to a hydrophilic group; and the second surfactant comprising a CO2-philic group covalently joined to a lipophilic group. In the alternative, a single surfactant containing all three of a CO2-philic group, a lipophilic group, and a hydrophilic group covalently joined to one another may also be employed. Systems useful for carrying out the foregoing are also disclosed.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: March 13, 2001
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, James P. DeYoung
  • Patent number: 6191100
    Abstract: This invention relates to a detergent composition comprising an anionic surfactant and a cationic surfactant, an acid source and an alkali source capable of reacting together in the presence of water to produce a gas.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: February 20, 2001
    Assignee: The Procter & Gamble Company
    Inventors: Stuart Clive Askew, Graham Alexander Sorrie
  • Patent number: 6187738
    Abstract: There is provided an aqueous composition for cleaning fabrics and carpets and inhibiting the resoiling of fabric and carpets. The composition includes a peroxygen compound, a surfactant system, and a polymeric or copolymeric soil resist. The resulting compositions are particularly stable and non-turbid.
    Type: Grant
    Filed: February 2, 1999
    Date of Patent: February 13, 2001
    Assignee: Playtex Products, Inc.
    Inventors: Robert P. Micciche, Ann Marie Lynch, Uma Tripathi, Carol Belansky
  • Patent number: 6184196
    Abstract: The invention relates to the synthesis of sulfonated sucrose compounds, surfactants and intermediate cyclic sulfates.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: February 6, 2001
    Assignee: University of Iowa Research Foundation
    Inventors: Helene G. Bazin, Tulay Polat, Robert J. Linhardt
  • Patent number: 6179880
    Abstract: This invention relates to dry-cleaning systems which include anhydrous dry-cleaning compositions which contain polysulfonic acid, and a bag for the cleaning and containment of soiled fabric articles. In a first embodiment, the dry-cleaning compositions includes organic solvents, polysulfonic acid, and not more than about 10 wt % water. In a second embodiment, the dry-cleaning compositions includes organic solvents and polysulfonic acid, and not more than 1 about wt % water. The invention also relates to methods of using the dry-cleaning system and dry-cleaning composition.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: January 30, 2001
    Assignee: Custom Cleaner, Inc.
    Inventor: James A. Smith
  • Patent number: 6165972
    Abstract: A solid surfactant mixture, comprising one or more fatty acid polyhydroxyamides of the formula IRCONR.sup.1 Z (1)in which R is C.sub.7 -C.sub.31 -alkyl or C.sub.7 -C.sub.31 -alkenyl, Z is a polyhydroxyhydrocarbon group having at least two hydroxyl groups, which may also be alkoxylated, and R.sup.1 is C.sub.1 -C.sub.8 -alkyl or a group of the formula --(CH.sub.2).sub.x NR.sup.2 R.sup.3 or R.sup.4 O(CH.sub.2).sub.n --, R.sup.2 and R.sup.3 are C.sub.1 -C.sub.4 -alkyl or C.sub.2 -C.sub.4 -hydroxyalkyl, R.sup.4 is C.sub.1 -C.sub.4 -alkyl and x is a number from 1 to 10 and n is a number from 2 to 4, one or more other nonionic surfactants and/or one or more anionic surfactants.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: December 26, 2000
    Assignee: Clariant GmbH
    Inventors: Frank Weinelt, Helmut Keck
  • Patent number: 6156721
    Abstract: The present invention relates to the use of anionic gemini tensides of the formula (I) ##STR1## in which R.sup.1 and R.sup.3 are, mutually independently, a hydrocarbon radical with 1 to 22 carbon atoms, R.sup.2 is a spacer containing 0 to 100 alkoxy groups, and X and Y, mutually independently, are functional groups and the degree of substitution Z=1 to 10, in washing, cleaning and body care agents in which the proportion of said tensides amounts to at least 0.1%.
    Type: Grant
    Filed: October 23, 1998
    Date of Patent: December 5, 2000
    Assignee: RWE-DEA Aktiengesellschaft fuer Mineraloel und Chemie
    Inventors: Klaus Kwetkat, Michael Brock, Herbert Koch
  • Patent number: 6086634
    Abstract: This invention relates to dry-cleaning systems which include dry-cleaning compositions which contain polysulfonic acid and water, and a bag for the cleaning and containment of soiled fabric articles. The invention also relates to methods of using the dry-cleaning system and dry-cleaning composition.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: July 11, 2000
    Assignee: Custom Cleaner, Inc.
    Inventor: James A. Smith
  • Patent number: 6053952
    Abstract: The invention provides dry cleaning liquid formulations and methods for their use based on a highly fluorinated organic solvent which contains at least one hydrogen atom per molecule, in particular, highly fluorinated hydrocarbons or highly fluorinated ethers. In a preferred embodiment the cleaning liquid contains an HFC or HFE in combination with dichloroethylene. The addition of a surfactant enhances the ability of the liquid to remove water-soluble soils.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: April 25, 2000
    Assignee: Entropic Systems, Inc.
    Inventor: Robert Kaiser
  • Patent number: 6017874
    Abstract: The present disclosure relates to a liquid detergent composition comprising a surfactant system which is free of linear alkyl benzene sulfonate. The detergent composition comprises a selected quaternary ammonium surfactant, and an anionic surfactant selected from the group consisting of alkyl alkoxy sulfates and alkyl sulfates.
    Type: Grant
    Filed: March 27, 1998
    Date of Patent: January 25, 2000
    Assignee: The Procter & Gamble Company
    Inventors: Dimitris Lappas, Rajan Keshav Panandiker, Thomas Wilhelm Horner
  • Patent number: 6008175
    Abstract: A method of cleaning carpets with a composition comprising a surfactant selected from amine oxides and acyl sarcosinates. The compositions are advantageous in that they do not leave a dulling film if not removed from the carpet after drying. Preferably, the compositions also contain a source of active oxygen for stain removal.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: December 28, 1999
    Assignee: The Proctor & Gamble Company
    Inventors: Stefano Scialla, Floriana Raso, Lorena Silvaggi
  • Patent number: 5972869
    Abstract: A mildly acidic laundry detergent composition is provided for the improved protection of fine fabrics during washing and enhanced removal of generated foam during rinsing in hand wash comprising:a) at least one anionic surfactant; and/orb) at least one nonionic surfactant;c) a rinse-active, pH-sensitive foam control agent comprising a fatty acid; whereby the fatty acid foam control agent remains substantially in acid form at the mildly acidic pH of the wash water so as to be essentially inoperative to suppress foam during washing, and whereby upon rinsing of the laundry with tap water having a pH of from about 7.5 to 8.5 at least of portion of said fatty acid is converted to a soap which functions to suppress foam during rinsing.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: October 26, 1999
    Assignee: Colgate-Palmolive Co
    Inventors: Hoai-Chau Cao, Marie-Christine Houben, Patricia Pagnoul
  • Patent number: 5922670
    Abstract: Dimer alcohol bis-sulfates, trimer alcohol tris-sulfates and ether sulfates thereof are prepared by reacting dimer alcohols, trimer alcohols, or alkylene oxide adducts thereof with a sulfating agent, and then neutralizing the reaction product with an aqueous base material.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: July 13, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Alfred Westfechtel, Gerhard Hermanns, Rainer Hoffmann, Hans-Christian Raths
  • Patent number: 5891197
    Abstract: The present invention encompasses a stain receiver article and its use in a fabric cleaning process. The invention also encompasses a kit, comprising: (a) an aqueous fabric cleaning/refreshment composition which is, optionally, releasably contained on a carrier substrate; a re-usable, preferably vapor-venting, containment bag; a stain receiver article according to this invention; optionally, but preferably, a fabric cleaning device, as disclosed herein; optionally, a re-usable holding tray; and optionally, a non-aqueous cleaning composition. The invention also encompasses the stain receiver article, itself.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: April 6, 1999
    Assignee: The Proctor & Gamble Company
    Inventors: Terrill Alan Young, John Richard Noel, Maxwell Gregory Davis
  • Patent number: 5876461
    Abstract: Method includes the steps of (1) treating the textile with a predetermined amount of a non-durable sacrificial repellent material before putting the textile in service; (2) cleaning the textile with a mixture of a non-polar solvent and at least one cleaning additive to remove non-polar solvent soluble, insoluble and resistant contaminants from the textile; (3) washing the textile with a mixture of a polar solvent and at least one washing additive to remove polar solvent soluble contaminants from the textile; and (4) maintaining a predetermined amount of a non-durable sacrificial repellent material on the textile. The non-polar solvent may be perchloroethylene or the like, while the cleaning additive is a mixture of a dialkyl ketone, a carboxylic ester and a glycol ether. A second cleaning additive may be used to enhance contaminant removal. The polar solvent used is water, while the washing additive is a blend of surfactants.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: March 2, 1999
    Assignee: R. R. Street & Co. Inc.
    Inventors: Timothy L. Racette, James E. Schulte, Manfred Wentz
  • Patent number: 5858022
    Abstract: A method for dry-cleaning articles such as fabrics and clothing in carbon dioxide comprises contacting an article to be cleaned with a liquid dry cleaning composition for a time sufficient to clean the fabric. The liquid dry-cleaning composition comprises a mixture of carbon dioxide, water, a surfactant, and an organic co-solvent. After the contacting step, the article is separated from the liquid dry cleaning composition. The method is preferably carried out at ambient temperature. The surfactant may be either one that contains a CO.sub.2 -philic group or one that does not contain a CO.sub.2 -philic group. The organic co-solvent is preferably an alkane that has a flash point above 140.degree. F.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: January 12, 1999
    Assignee: MiCell Technologies, Inc.
    Inventors: Timothy J. Romack, David F. Cauble, James B. McClain
  • Patent number: 5827815
    Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising an ethoxylated fatty alcohol nonionic surfactant, a sulfated ethoxylated fatty alcohol anionic surfactant, and an N-alkyl and/or unsaturated hydrocarbyl amine of an alkanoic acid or salt thereof as an amphoteric surfactant.
    Type: Grant
    Filed: April 29, 1997
    Date of Patent: October 27, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
  • Patent number: 5821216
    Abstract: Carbonate built laundry detergents having improved cleaning properties and comprising a sulfated ethoxylated fatty alcohol anionic surfactant and two ethoxylated fatty alcohol nonionic surfactants having different average numbers of carbon atoms in the fatty alcohol and average numbers of ethoxy groups.
    Type: Grant
    Filed: April 21, 1997
    Date of Patent: October 13, 1998
    Assignee: Church & Dwight Co., Inc.
    Inventors: Francis R. Cala, Charles D. Carr, Bruce R. Conley
  • Patent number: 5798329
    Abstract: Liquid laundry detergent compositions provide good detergency for the cleaning of garments and textiles, as well as further providing a germicidal action to textile fabrics in a domestic laundering process.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: August 25, 1998
    Assignee: Reckitt & Colman Inc.
    Inventors: Timothy J. Taylor, Alan F. Richter
  • Patent number: 5767051
    Abstract: A light duty liquid detergent with desirable cleansing properties and mildness to the human skin comprising: a nonionic surfactant, an alkali metal or ammonium salt of a C.sub.8-18 ethoxylated alkyl ether sulfate anionic surfactant, an amine oxide surfactant, a zwitterionic surfactant, an alkyl polyglucoside surfactant, and water.
    Type: Grant
    Filed: February 13, 1997
    Date of Patent: June 16, 1998
    Assignee: Colgate Palmolive Company
    Inventors: Julien Drapier, Maria Galvez, Nicole Kerzmann, Gary Jakubicki
  • Patent number: 5739093
    Abstract: Laundry detergent compositions containing a detergent surfactant, a detergent builder, and from about 0.1% to about 50% by weight ethylene aspartate cysteate sequestrants or its acid form are disclosed. These compositions provide enhanced removal of organic stains, such as food and beverage stains particularly polyphenolic stains such as wine, blueberry, tea, coffee, morello juice and the like.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: April 14, 1998
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Eddie Nelson Gutierrez, Shang-Ren Wu, Robert Charles Vermeer
  • Patent number: 5733858
    Abstract: Solutions comprising at least one polyamino disuccinic acid and one or more polyamino monosuccinic acids are useful in gas conditioning (preferably as the iron chelate). The copper chelates are also useful in electroless copper plating. Another aspect of the invention includes the use of the aminosuccinic acid mixtures in laundry detergent compositions.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: March 31, 1998
    Assignee: The Dow Chemical Company
    Inventors: David A. Wilson, Druce K. Crump
  • Patent number: 5711764
    Abstract: A composition is provided for improving decolorizing and desizing garments and fabrics with a reducing agent in a washer. A surfactant is added so as to improve wet out and to reduce the surface tension of the water.
    Type: Grant
    Filed: October 3, 1996
    Date of Patent: January 27, 1998
    Inventor: Eric M. Wasinger
  • Patent number: 5712240
    Abstract: Aqueous carpet cleaning compositions are described which provide an effective cleaning effect and further impart water and oil repellent characteristics to carpet surfaces and carpet fibers treated with the same. Processes for the production of such compositions, as well as methods for their application are also disclosed.
    Type: Grant
    Filed: October 1, 1996
    Date of Patent: January 27, 1998
    Assignee: Reckitt & Colman Inc.
    Inventors: Michael Richard Tyerech, Jeanne Marie Weller, Andrew Francis Colurciello, Jr., Tracy Ann Ryan
  • Patent number: 5712238
    Abstract: A multipurpose cleaning agent containing 6.5-8% sodium alkyl sulfate, 2.7-4% fatty acid coconut diethanolamide, 0.38-0.42% citric acid, 0.38-0.42% ethylene diamine tetraacetic acid, 0.42-0.48% sodium citrate, 2.88-3.2% water, 1.88-2.5% sodium polyoxyethylene alkyl ether sulfate, 0.5-1% sodium carboxy methyl cellulose, 0.2-0.4% sodium percarbonate, 2-5% sodium tripoly phosphate, 40.38-35.89% low density sodium carbonate, 40.38-35.89% Na.sub.2 SO.sub.4.H.sub.2 O, 0.4-0.8%, savinase 40T, and 1-2% celluzyme 0.7T.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: January 27, 1998
    Inventor: Wu Hsiung Chan
  • Patent number: 5683473
    Abstract: A method of dry cleaning fabrics using a dry cleaning system is described. The system comprises densified carbon dioxide, preferably in a liquid phase, and a selected surfactant which is soluble in the densified CO.sub.2. The surfactant has a polysiloxane, a branched polyalkylene oxide or a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: November 4, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Rosemarie Harris
  • Patent number: 5676705
    Abstract: A method of dry cleaning fabrics using a dry cleaning system is described. The system comprises densified carbon dioxide and a surfactant in the densified CO.sub.2. The surfactant has a polysiloxane, a branched polyalkylene oxide and a halocarbon group which is a functional CO.sub.2 -philic moiety connected to a CO.sub.2 -phobic functional moiety. The surfactant either exhibits an HLB of less than 15 or has a ratio of siloxyl to substituted siloxyl groups of greater than 0.5:1.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: October 14, 1997
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Sharon Harriott Jureller, Judith Lynne Kerschner, Myongsuk Bae-Lee, Lisa Del Pizzo, Rosemarie Harris, Carol Resch, Cathy Wada
  • Patent number: 5584888
    Abstract: Bleaching compositions, laundry and automatic dishwashing detergent compositions comprising particular neutral or anionically charged substituted bleach activators are provided. More specifically, the invention relates to compositions which provide enhanced cleaning/bleaching benefits through the selection of perhydrolysis-selective bleach activators having specific leaving groups with a conjugate acid pK.sub.a above 13 and with specific ratios of the rate of perhydrolysis to the rate of hydrolysis and the rate of perhydrolysis to the rate of diacylperoxide production. Included are preferred activator compounds and methods for washing fabrics, hard surfaces, and tableware using the activators.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: December 17, 1996
    Inventors: Gregory S. Miracle, Alan D. Willey, Kevin L. Kott, Michael E. Burns